CN101126602A - Magnesium alloy melting pool type crucible electrical resistance furnace - Google Patents
Magnesium alloy melting pool type crucible electrical resistance furnace Download PDFInfo
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- CN101126602A CN101126602A CNA2006101023190A CN200610102319A CN101126602A CN 101126602 A CN101126602 A CN 101126602A CN A2006101023190 A CNA2006101023190 A CN A2006101023190A CN 200610102319 A CN200610102319 A CN 200610102319A CN 101126602 A CN101126602 A CN 101126602A
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- crucible
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- pond shape
- magnesium alloy
- heater
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- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 31
- 238000002844 melting Methods 0.000 title claims description 9
- 230000008018 melting Effects 0.000 title claims description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 25
- 238000007670 refining Methods 0.000 claims description 59
- 238000005266 casting Methods 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- 238000013019 agitation Methods 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 239000000155 melt Substances 0.000 abstract description 5
- 230000001360 synchronised effect Effects 0.000 abstract description 3
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 8
- 229910052749 magnesium Inorganic materials 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000010813 municipal solid waste Substances 0.000 description 6
- 238000005192 partition Methods 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000007872 degassing Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 241000370738 Chlorion Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 244000144985 peep Species 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
The utility model relates to a molten-pool pot resistance furnace of magnesium alloy, comprising heating modules of which two heating modules which are positioned up and down respectively on the inner wall of the furnace body are formed into a group; wherein, a group of two lateral face heating modules are positioned up and down on the left and the right inner wall of the furnace body which are corresponding to the front end and the back end of the pool-type pot; and two or more groups of frontal heating modules which are corresponding to the position of two or more chambers in the pool-type pot are positioned respectively on the front and the back inner wall of the furnace body which are corresponding to two side ends of the pool-type pot. The pool-type pot is divided into three temperature regions of temperature region I, temperature region II, and temperature region III when the pool-type pot is seen from the front; wherein, an up temperature region and a down temperature region form a subarea, thus forming synchronous heating regions which are mutually independent to maintain the flow of continuous and high-quality melts and satisfy the refined thermodynamic and dynamic conditions of the melts via precisely regulating the crafting parameters.
Description
Technical field
The present invention relates to a kind of magnesium alloy refining equipment, be specially a kind of magnesium alloy melting pool type crucible electrical resistance furnace.
Technical background
In recent years, magnesium alloy has been a kind of new material with development and application potentiality, have specific strength and specific stiffness height, heat-conductivity conducting good, have good damping shock absorption and capability of electromagnetic shielding concurrently; Simultaneously good, the good casting property of machinability, serial advantage such as easy to be recycled, along with the breakthrough of process technology and the decline significantly of price, magnesium alloy more and more is used to various fields.
In view of the various advantages of magnesium alloy, magnesium material manufacturing enterprise is also increasing.China is magnesium resource big country in the world, magnesium output has accounted for (70~80) % in the whole world, yet but not magnesium industry power, the exploitation level of technology and equipment is compared gap with international most advanced level very big, and because magnesium alloy chemical character is active, belong to Equipment of Flammable and Explosive Materials, the production equipment that can satisfy this requirement at all specific (special) requirements of magnesium alloy in the market but remains to be developed, and this also is a key factor that hinders the development of China magnesium alloy manufacturing enterprise.
Metal that contains in the magnesium alloy and nonmetallic inclusion can have a strong impact on the quality and the reliability of products of magnesium alloy, therefore magnesium must carry out refining treatment, the purpose of refining is non-metallic inclusion and the dissolved gases of eliminating in the alloy, obtaining purer metal, thus improve magnesium alloy mechanical performance and corrosion resisting property.
In the magnesium alloy refining process, following several important step is arranged:
One, degasification and the purpose of removing the field trash degasification are to get rid of the gas in the alloy, and these gases and field trash have increased the sponginess of foundry goods under certain condition, and the magnesium alloy performance can be therefore and serious the reduction.
Two, the control of temperature controlling rational and effective temperature also is the key factor that realizes good magnesium alloy performance.
Three, the protection magnesium alloy of atmosphere belongs to inflammable and explosive metal material, and the protection of atmosphere can prevent to burn and effective scaling loss scope of controlling magnesium.
The method of refining of magnesium alloy fused mass is handled in industrial common employing solvent refined method at present, and this solvent can form the refractory metal intermediate compound and fall to furnace bottom with field trash absorption or with other high-melting-point impurity.The solubility of these infusibility impurity in magnesium alloy is little; fusing point is also high; and proportion is bigger than magnesium; though this method can be removed the fusible impurity in the alloy; but do not get rid of the secondary pollution to melt, absorption of what is more important field trash and precipitation need the long time, and adopt the effectively degasification of solvent refined method; cause the gas shield difficulty simultaneously, the amount of expending is big, processing step is loaded down with trivial details, greatly reduces production efficiency.
Summary of the invention
Technical problem to be solved by this invention provide a kind of can move continuously and but thereby A.T.C reaches the refining purpose, can save energy consumption, to the operator provide safe and reliable safeguard measure, be applicable to that magnesium alloy produces employed magnesium alloy melting pool type crucible electrical resistance furnace
The present invention adopts following technical scheme:
The present invention includes body of heater, be arranged on the pond shape crucible in the body of heater, be arranged on feed arrangement and quantitative rear pump on the shape crucible of pond, at pond shape crucible inner route clapboard every being set to two or more chambers that are connected, it is characterized in that it is one group heating module that inboard wall of furnace body is provided with two of being discrete up and down, be respectively arranged with on its corresponding body of heater left and right sides, neutralization pond shape crucible front and back end inwall one group be respectively arranged with on the inwall before and after discrete up and down two side heat modules and the corresponding body of heater of two sides of pond shape crucible with pond shape crucible in corresponding two groups or more the front heating module in the position of two or more chambers.
The present invention is set as feed compartment, one-level refining chamber, secondary refining chamber and casting chamber by a Room dividing plate, two Room dividing plates and the three Room dividing plates that are provided with pond shape crucible branch after by forward direction in the shape crucible of pond, corresponding with feed compartment and one-level refining chamber, secondary refining chamber, casting position, chamber in the shape crucible of pond respectively on the inwall before and after the body of heater, be provided with three groups of front heating modules.
The present invention is provided with by be connected rotatable of breather pipe and air agitation device in the one-level refining chamber of pond shape crucible and secondary refining chamber and feeds the rotor of refining gas.
The present invention is provided with in the shape crucible of pond by feed arrangement, the quantitative input and output material system that forms of rear pump, and feed arrangement is installed on the bell on the feed compartment, and quantitatively rear pump is installed on the bell on the chamber of casting.
The present invention is liquid level thermocouple and following liquid level thermocouple on one-level refining chamber, secondary refining chamber and indoor being respectively arranged with of casting, and is respectively arranged with lower hearth thermocouple and upper furnace thermocouple outside the shape crucible remote holder end of pond.
Good effect of the present invention is as follows: it is one group heating module that apparatus of the present invention inboard wall of furnace body is provided with two of being discrete up and down, be respectively arranged with on its corresponding body of heater left and right sides, neutralization pond shape crucible front and back end inwall one group be respectively arranged with on the inwall before and after discrete up and down two side heat modules and the corresponding body of heater of two sides of pond shape crucible with pond shape crucible in corresponding two groups or more the front heating module in the position of two or more chambers.It promptly is the array mode of heating, see that from shape crucible front, pond heating divides I, II, three warm areas of III, wherein each subregion is made up of two warm areas up and down, form the separate synchronous thermal treatment zone, with keep continuously, the flowing of high-quality melt, by the accuracy controlling technological parameter, satisfy the thermodynamics and kinetics condition of melt refining.
The present invention compared with prior art mainly contains following advantage:
1, apparatus of the present invention can be removed all kinds of different densities and big or small field trash in the melt at short notice, and when continuous pouring, the production capacity of stove is actually the restriction of the production capacity that is subjected to casting machine and pump.
2, the refining process of apparatus of the present invention is to finish under the atmosphere protection condition of no flux, and with this understanding, the scaling loss of magnesium can control to lower scope.
3, apparatus of the present invention productivity ratio open well formula crucible furnace is big 5~6 times, and energy consumption reduces about 15~20%, and behaviour has better working condition when doing.
4, apparatus of the present invention can provide good dynamics and thermodynamic condition simultaneously for the magnesium alloy fused mass refining.
5, apparatus of the present invention can obtain high-quality magnesium alloy ingot material with utmost point protoxide, chlorion and iron ion by multistage refining by monitoring liquid level, temperature, refining parameter and teeming rate process for stabilizing.
Description of drawings
Accompanying drawing 1 is structural representation of the present invention
Accompanying drawing 2 is front of the present invention heating module structural representation
Accompanying drawing 3 is provided with view for heating module of the present invention
Accompanying drawing 4 is provided with view for thermocouple of the present invention
In the accompanying drawings: liquid level thermocouple on 1 body of heater, 2 connecting grooves, 3 pond shape crucibles, 4 one Room dividing plates, 5 feed arrangements, 6,7 breather lines, 8 two Room dividing plates, 9 air agitation devices, 10 3 Room dividing plates, 11 quantitative rear pumps, 12 times liquid level thermocouple, 13 side heating modules, 14 heat-preservation cotton, 15 lower hearth thermocouple, 16 upper furnace thermocouple, 17 front heating modules, 18 feed compartments, 19 one-level refining chamber, 20 secondary refining chamber, casting chambers 21,22 breather pipes, 23 rotors.
The specific embodiment
For example shown in the accompanying drawing 1,2,3,4, apparatus of the present invention are by body of heater 1, pond shape crucible 3, temperature control system, gas protection system, rectification systems for the invention process, and the input and output material system forms.Described body of heater 1 comprises furnace shell, heat-resistant insulation material, heated die plate, bell, liquid level indicator and electric control gear etc., wherein be equipped with charging aperture, thermocouple socket, peep hole, slagging-off sealed composite lid, purifier putting hole, discharging opening etc. on the bell, described liquid level indicator can be monitored liquid level, temperature, refining parameter and teeming rate process for stabilizing.Fill heat-resistant insulation material between furnace shell and heated die plate, pond shape crucible 3 is installed in body of heater 1 center.
Shown in accompanying drawing 3,4, the temperature control system of apparatus of the present invention is made up of electrothermal template and thermocouple etc., correspondingly with shape crucible 3 front and back ends, pond on body of heater 1 inwall be discrete up and down two the side heat modules 13 that are respectively arranged with, discretely on body of heater 1 inwall and about the feed compartment 18 in the pond shape crucible 3 and one-level refining chamber 19, secondary refining chamber 20,21 corresponding being of chamber of casting be respectively arranged with six front heating modules 17.Promptly be provided with two and be discrete front heating module 17 up and down with feed compartment 18 is corresponding with one-level refining chamber 19 positions; Correspondingly with secondary refining chamber 20 positions be provided with two and be discrete front heating module 17 up and down; Correspondingly with casting 21 positions, chamber be provided with two and be up and down discrete front heating module 17; In one-level refining chamber 19, be respectively arranged with liquid level thermocouple 6 and following liquid level thermocouple 12 in secondary refining chamber 20 and the casting chamber 21, outside shape crucible 3 front ends of pond, be respectively arranged with lower hearth thermocouple 15 and upper furnace thermocouple 16, apparatus of the present invention are array mode of heatings, front from pond shape crucible 3, heating divides I, II, three warm areas of III, wherein each subregion is made up of two warm areas up and down, form the separate synchronous thermal treatment zone, to keep continuously, flowing of high-quality melt, by the accuracy controlling technological parameter, satisfy the thermodynamics and kinetics condition of melt refining.
Gas protection system among the present invention is formed by stirring pump, gas flow meter and aspirating pipeline, in one-level refining chamber and secondary refining chamber, stirs exhaust pump by driven by motor rotation and feeding protective gas, reaches the action effect of exhaust and protection.In the one-level refining chamber 19 of pond shape crucible 3 and secondary refining chamber 20, be provided with by be connected rotatable of breather pipe 22 and air agitation device 9 and feed the rotor 23 that protective gas reaches exhaust and protective effect, gas protection system is made up of two stirring pumps, can effectively evenly get rid of the gas that is dissolved in the alloy, adopt gas shield and do not adopt solvent;
Rectification systems among the present invention is by dividing plate pond shape crucible to be separated, and reaches the effect of refining by physical effect and stirring scavenging action.In pond shape crucible 3, by a Room dividing plate 4, two Room dividing plates 8 and the three Room dividing plates 10 that are provided with pond shape crucible was set as feed compartment 18, one-level refining chamber 19, secondary refining chamber 20 and casting chamber 21 in 3 minutes after by forward direction.Crucible is divided into three molten chambers promptly reinforced and one-level refining chamber, secondary refining chamber and pump chamber, two thermocouple in every chamber, detect the temperature of top and the bottom melt respectively, wherein each chamber is separated by dividing plate and has a flowing hole, internal partition mainly acts on, and to be the melt that makes injection enter the one-level fining cell in the mode of rising pouring, with steady injection melt and obstruct cast oxidation impurities, the top perforate of side partition wall, melt with the overcurrent cleaning, secondary refining chamber is reached by partition wall and forms every bank, intercepting field trash, is casting room so that the good melt of refining flows into pump chamber.
Magnesium alloy fused mass at first steadily injects 1 grade of refining chamber by the feed compartment internal partition, and melt is carried out refining.When the next group melt injected in one-level refining chamber 19, the opening of clean melt through partition wall top after the refining treatment overflowed to secondary refining chamber 20; Simultaneously, purifier carries out purified treatment once more to the melt of the secondary refining chamber 20 that flows through.Said process makes melt obtain the secondary refining, thereby finishes the purification of flux and oxide inclusion.Melt through the secondary refining is a casting room 21 by the inflow of chute between bank and partition wall pump chamber.
Input and output material system among the present invention is made up of feeding device 5, quantitative rear pump 11, feeding device 5 is installed on the bell with quantitative rear pump 11, in pond shape crucible 3, be provided with the input and output material system that forms by feed arrangement 5, quantitative rear pump 11, feed arrangement 5 is installed on the bell on the feed compartment 18, and quantitatively rear pump 11 is installed on the bell on the casting chamber 21.To treat that the refined magnesium alloy melt enters feed compartment 18, and flow into successively after each chamber refining melt to be outputed in the continuous casting machine and go that discharge system adopts the commercialization constant displacement pump, can select helicoidal pump, electromagnetic pump or pulsometer by discharge system.
Claims (5)
1. magnesium alloy melting pool type crucible electrical resistance furnace, it comprises body of heater (1), be arranged on the pond shape crucible (3) in the body of heater (1), be arranged on feed arrangement (5) and quantitative rear pump (11) on the pond shape crucible (3), at pond shape crucible (3) inner route clapboard every being set to two or more chambers that are connected, it is characterized in that it is one group heating module that body of heater (1) inwall is provided with two of being discrete up and down, be respectively arranged with on its corresponding body of heater in neutralization pond shape crucible (3) front and back end (1) left and right sides inwall one group be respectively arranged with on the inwall before and after discrete up and down two side heat modules (13) and (3) two the corresponding bodies of heater of side of pond shape crucible (1) with pond shape crucible (3) in corresponding two groups or more the front heating module (17) in the position of two or more chambers.
2. a kind of magnesium alloy melting pool type crucible electrical resistance furnace according to claim 1, Room dividing plate (4) by being provided with after it is characterized in that in pond shape crucible (3) by forward direction, two Room dividing plates (8) and three Room dividing plates (10) are set as feed compartment (18) with pond shape crucible (3) branch, one-level refining chamber (19), secondary refining chamber (20) and casting chamber (21), before and after the body of heater (1) on the inwall respectively with pond shape crucible (3) in feed compartment (18) and one-level refining chamber (19), secondary refining chamber (20), casting position, chamber (21) is corresponding, is provided with three groups of front heating modules (17).
3. a kind of magnesium alloy melting pool type crucible electrical resistance furnace according to claim 1 and 2 is characterized in that being provided with in the one-level refining chamber (19) of pond shape crucible (3) and secondary refining chamber (20) by be connected rotatable of breather pipe (22) and air agitation device (9) and feeds the rotor (23) of refining gas.
4. a kind of magnesium alloy melting pool type crucible electrical resistance furnace according to claim 1 and 2, it is characterized in that in pond shape crucible (3), being provided with the input and output material system that forms by feed arrangement (5), quantitative rear pump (11), feed arrangement (5) is installed on the bell on the feed compartment (18), and quantitatively rear pump (11) is installed on the bell on the casting chamber (21).
5. a kind of magnesium alloy melting pool type crucible electrical resistance furnace according to claim 1 and 2, it is characterized in that in one-level refining chamber (19), secondary refining chamber (20) and casting chamber (21), being respectively arranged with liquid level thermocouple (6) and following liquid level thermocouple (12), outside pond shape crucible (3) remote holder end, be respectively arranged with lower hearth thermocouple (15) and upper furnace thermocouple (16).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN200610102319A CN100595507C (en) | 2006-12-22 | 2006-12-22 | Magnesium alloy melting pool type crucible electrical resistance furnace |
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CN200610102319A CN100595507C (en) | 2006-12-22 | 2006-12-22 | Magnesium alloy melting pool type crucible electrical resistance furnace |
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CN101126602A true CN101126602A (en) | 2008-02-20 |
CN100595507C CN100595507C (en) | 2010-03-24 |
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CN200610102319A Expired - Fee Related CN100595507C (en) | 2006-12-22 | 2006-12-22 | Magnesium alloy melting pool type crucible electrical resistance furnace |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102384646A (en) * | 2010-09-02 | 2012-03-21 | 方强 | Crucible, furnace body and crucible resistor furnace for realizing internally heating |
CN103017518A (en) * | 2011-09-22 | 2013-04-03 | 品达科技股份有限公司 | Metal melting furnace and metal melting method |
CN103123222A (en) * | 2012-11-09 | 2013-05-29 | 江苏淘镜有限公司 | Low-temperature alloy recovery furnace |
CN103615888A (en) * | 2013-09-30 | 2014-03-05 | 深圳市亚美联合压铸设备有限公司 | Dissolution device of rare earth magnesium alloy |
CN104654783A (en) * | 2015-03-06 | 2015-05-27 | 宋振亚 | Upper part immersed heating and melting heat-preserving furnace |
CN107976063A (en) * | 2017-11-29 | 2018-05-01 | 天津镁特威科技有限公司 | A kind of magnesium alloy melting and heat preservation stove with recycling |
CN108193053A (en) * | 2018-03-07 | 2018-06-22 | 江苏中翼汽车新材料科技有限公司 | The online recycling processing unit and treatment process of a kind of magnesium alloy pressure-casting clout waste material |
CN115007830A (en) * | 2022-06-20 | 2022-09-06 | 江苏凯特汽车部件有限公司 | A kind of manufacturing technology of graphene rare earth composite strengthening automobile aluminum wheel |
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2006
- 2006-12-22 CN CN200610102319A patent/CN100595507C/en not_active Expired - Fee Related
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102384646A (en) * | 2010-09-02 | 2012-03-21 | 方强 | Crucible, furnace body and crucible resistor furnace for realizing internally heating |
CN103017518A (en) * | 2011-09-22 | 2013-04-03 | 品达科技股份有限公司 | Metal melting furnace and metal melting method |
CN103017518B (en) * | 2011-09-22 | 2014-12-10 | 品达科技股份有限公司 | Metal melting furnace and metal melting method |
CN103123222A (en) * | 2012-11-09 | 2013-05-29 | 江苏淘镜有限公司 | Low-temperature alloy recovery furnace |
CN103123222B (en) * | 2012-11-09 | 2014-12-10 | 江苏淘镜有限公司 | Low-temperature alloy recovery furnace |
CN103615888B (en) * | 2013-09-30 | 2015-09-02 | 深圳市亚美联合压铸设备有限公司 | A kind of dissolver of magnesium-rare earth |
CN103615888A (en) * | 2013-09-30 | 2014-03-05 | 深圳市亚美联合压铸设备有限公司 | Dissolution device of rare earth magnesium alloy |
CN104654783A (en) * | 2015-03-06 | 2015-05-27 | 宋振亚 | Upper part immersed heating and melting heat-preserving furnace |
CN104654783B (en) * | 2015-03-06 | 2016-11-02 | 宋振亚 | An upper submerged heating, melting and holding furnace |
CN107976063A (en) * | 2017-11-29 | 2018-05-01 | 天津镁特威科技有限公司 | A kind of magnesium alloy melting and heat preservation stove with recycling |
CN108193053A (en) * | 2018-03-07 | 2018-06-22 | 江苏中翼汽车新材料科技有限公司 | The online recycling processing unit and treatment process of a kind of magnesium alloy pressure-casting clout waste material |
CN115007830A (en) * | 2022-06-20 | 2022-09-06 | 江苏凯特汽车部件有限公司 | A kind of manufacturing technology of graphene rare earth composite strengthening automobile aluminum wheel |
CN115007830B (en) * | 2022-06-20 | 2024-09-17 | 江苏凯特汽车部件有限公司 | Manufacturing method of graphene rare earth composite reinforced automobile aluminum wheel |
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