CN101125514A - A kind of stainless steel antique posthumous portrait manufacturing method - Google Patents
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
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- 239000000463 material Substances 0.000 abstract description 7
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 4
- 239000011888 foil Substances 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 2
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- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
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- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
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Abstract
本发明涉及一种不锈钢仿古遗像制作方法，在厚度0.01～3mm的镜面、拉丝或哑光不锈钢板/箔，通过在含CrO3和H2SO4的不锈钢着色溶液中着色处理，把遗像通过印刷或感光成像，在不锈钢表面上形成遗像中间保护膜；再进行去膜处理，在不锈钢上形成仿古遗像。这种制作方法简单方便，而由此制作出来的不锈钢仿古遗像表面富丽堂皇、高雅美观，怀旧感强；既具有不锈钢原有的各种优越性，同时其耐蚀性能、耐风化、耐紫外线照射性能和外观装饰效果远优于普通不锈钢，可以永久性保存。本发明既克服了在纸质或塑质材料上的普通彩色或黑白照相技术的耐老化性能差不能长期保存的缺点，又克服了陶瓷材料易破碎不好保存的缺点；还满足人们对黑白、棕白照片的怀旧情绪。The invention relates to a method for making stainless steel antique posthumous images. The mirror surface, wire drawing or matte stainless steel plate/foil with a thickness of 0.01-3mm is colored in a stainless steel coloring solution containing CrO3 and H2SO4 , and the posthumous images are printed Or photosensitive imaging to form an intermediate protective film on the surface of the stainless steel; and then remove the film to form an antique portrait on the stainless steel. This kind of production method is simple and convenient, and the surface of the stainless steel antique portrait made by it is magnificent, elegant and beautiful, with a strong sense of nostalgia; it not only has the original advantages of stainless steel, but also its corrosion resistance, weather resistance, and ultraviolet radiation resistance. The performance and appearance decoration effect are far superior to ordinary stainless steel, and can be preserved permanently. The invention not only overcomes the disadvantages of poor aging resistance of ordinary color or black-and-white photographic technology on paper or plastic materials and cannot be stored for a long time, but also overcomes the disadvantage that ceramic materials are easily broken and difficult to preserve; Nostalgia for brown and white photos.
Description
技术领域 technical field
本发明涉及一种遗像制作方法，尤其是一种不锈钢仿古遗像制作方法。The invention relates to a method for making a portrait, in particular to a method for making a stainless steel antique portrait.
背景技术 Background technique
目前，除雕塑外的遗像制作技术一般都是在纸质或塑质材料上的普通彩色或黑白照相技术，由于成相材料和基材耐老化性能差，它们的保存期限都不长。近年来，采用陶瓷印像烧结技术制作遗像克服了上述问题，因此不到几年其应用已非常普遍；然而，由于陶瓷材料容易破碎不好保存，特别是在长期无人照料的墓碑上容易被他人损坏，一旦损坏，要复原很困难。另外，彩色相片已经流行几十年历史，人们对曾经被淘汰过的黑白照片的怀旧情绪已经越来越强烈。At present, posthumous image production techniques other than sculpture are generally ordinary color or black and white photography techniques on paper or plastic materials. Due to the poor aging resistance of imaging materials and substrates, their shelf life is not long. In recent years, the use of ceramic printing and sintering technology to make posthumous images has overcome the above problems, so its application has become very common in less than a few years; however, because ceramic materials are easy to break and are not easy to preserve, especially on tombstones that have not been cared for for a long time, they are easy to be damaged. Once damaged by others, it is very difficult to recover. In addition, color photography has been popular for decades, and people's nostalgia for the once obsolete black-and-white photos has grown stronger.
发明内容 Contents of the invention
本发明的目的为了克服现在技术存在上述问题和不足，而提供一种不锈钢仿古遗像制作方法，本发明不仅克服了在纸质或塑质材料上的普通彩色或黑白照相技术的耐老化性能差不能长期保存的缺点，还克服了陶瓷材料容易破碎不好保存的缺点；同时还满足了人们对曾经被淘汰的黑白、棕白照片的怀旧情绪。这很有可能在遗像制作史上形成一股新潮流。The purpose of the present invention is to overcome the above-mentioned problems and deficiencies in the existing technology, and to provide a stainless steel imitation posthumous image production method, the present invention not only overcomes the poor aging resistance of ordinary color or black and white photographic technology on paper or plastic materials. The shortcoming of long-term preservation also overcomes the shortcoming of ceramic materials that are easy to break and not easy to preserve; at the same time, it also satisfies people's nostalgia for black-and-white and brown-and-white photos that were once eliminated. This is likely to form a new trend in the history of portrait production.
本发明是采用这样的技术方案来解决上述问题的：The present invention adopts such technical scheme to solve the above problems:
不锈钢仿古遗像，其特征在于把遗像通过化学处理制作到了不锈钢板/箔上。一种不锈钢仿古遗像制作方法，按以下步骤进行：步骤(1)：把厚度在0.01～3mm的镜面、拉丝或哑光不锈钢板/箔洗净，然后放入含有CrO3：120～250g/l和H2SO4：300～600g/l的不锈钢着色溶液中，通过化学或电化学氧化着色，在不锈钢表面上形成不同的色彩，以黑色、古铜色为主；该彩色膜为一层结合力很强的、其耐蚀性能、耐风化性能、耐紫外光照射性能都远优于普通银白色不锈钢的高强度光干涉氧化膜、其厚度约为5-400nm。The stainless steel antique posthumous portrait is characterized in that the posthumous portrait is made on a stainless steel plate/foil through chemical treatment. A method for making stainless steel antique posthumous portraits, which is carried out according to the following steps: Step (1): Clean the mirror surface , wire drawing or matt stainless steel plate/foil with a thickness of 0.01 ~ 3mm, and then put into And H 2 SO 4 : 300~600g/l stainless steel coloring solution, through chemical or electrochemical oxidation coloring, different colors are formed on the surface of stainless steel, mainly black and bronze; the color film is a layer of strong adhesion Strong, its corrosion resistance, weathering resistance, and ultraviolet light resistance are far superior to the high-intensity light interference oxide film of ordinary silver-white stainless steel, and its thickness is about 5-400nm.
步骤(2)：此步骤为可选项，在含有化学成分CrO3：250g/l和H2SO4：2.5g/l的电解坚膜溶液中，在外加阴极电流的条件下通电10-20钟，使上述彩色膜固化牢固；Step (2): This step is optional. In the electrolytic hardening solution containing chemical components CrO 3 : 250g/l and H 2 SO 4 : 2.5g/l, electrify for 10-20 minutes under the condition of external cathodic current , so that the above-mentioned color film is solidified;
步骤(3)：此步骤为可选项，把由步骤(1)(2)形成的彩色不锈钢放入浓度为10％的Na2SiO3水溶液中，进行封闭处理，由此形成更坚固耐磨的光干涉氧化膜；Step (3): This step is optional. Put the colored stainless steel formed by steps (1) and (2) into a 10% Na 2 SiO 3 aqueous solution for sealing treatment, thereby forming a stronger and wear-resistant stainless steel. Light interference oxide film;
步骤(4)：将上述光干涉彩色不锈钢待成相表面的氧化膜表面，洗净、烘干便于后用，该表面不能有任何污垢或水渍；Step (4): Wash and dry the surface of the oxide film on the surface of the light-interference colored stainless steel to be formed for later use, without any dirt or water stains on the surface;
步骤(5)：形成遗像中间保护膜：①将拍摄好的遗像制作成菲林片；②制作丝网版；③用金属防腐油墨把上述遗像印刷在步骤(4)的彩色不锈钢待成相表面上，形成遗像中间保护膜，按照该油墨的要求对其进行光或热固化；该步骤还可以采用感光成像技术：将上述防腐油墨换成防腐感光胶，直接涂布到彩色不锈钢待成相表面上，然后经过感光、显影、定影、固化形成遗像中间保护膜；Step (5): Form the intermediate protective film of the portrait: ① make the photographed portrait into a film; ② make a screen plate; ③ print the above portrait on the colored stainless steel surface to be formed in step (4) with metal anti-corrosion ink , form the intermediate protective film of the posthumous image, and light or heat cure it according to the requirements of the ink; this step can also use photosensitive imaging technology: replace the above anti-corrosion ink with anti-corrosion photosensitive glue, and directly coat it on the surface of the colored stainless steel to be phased , and then undergo photosensitization, development, fixing, and curing to form an intermediate protective film for the portrait;
步骤(6)：把经过上述步骤处理好的彩色不锈钢待成相表面放入到浓度为5～30％H2SO4和浓度为5～30％H3PO4的溶液中，在外加直流电为V＝3～36v，I＝5～80A/dm2的条件下，使该彩色不锈钢板待成相表面为阳极，铅版或不锈钢板为阴极，去掉未被中间保护膜保护的彩色氧化膜；本步骤还可以根据不同客户的要求延长去膜时间或用不锈钢腐蚀法来形成一种腐蚀的效果；Step (6): Put the surface of the colored stainless steel that has been processed through the above steps into a solution with a concentration of 5-30% H 2 SO 4 and a concentration of 5-30% H 3 PO 4 . Under the condition of V=3～36v, I=5～80A/dm2, the surface of the colored stainless steel plate to be phased is used as the anode, and the lead plate or stainless steel plate is used as the cathode, and the colored oxide film not protected by the intermediate protective film is removed; The steps can also extend the film removal time according to the requirements of different customers or use stainless steel corrosion to form a corrosion effect;
步骤(7)：去掉上述中间保护膜，方法是在浓度为1～20％的NaOH碱性溶液中洗掉上述油墨或感光胶，然后洗净、烘干；通过以上步骤便制造成了一幅不锈钢仿古遗像了；它们是两种不同风格的遗像：一种是白底黑图，另一种是黑底白图；Step (7): remove the above-mentioned intermediate protective film, the method is to wash off the above-mentioned ink or photosensitive adhesive in a NaOH alkaline solution with a concentration of 1 to 20%, then wash and dry; through the above steps, a picture is made. Stainless steel antique portraits; they are two different styles of portraits: one is a black picture on a white background, and the other is a white picture on a black background;
步骤(8)：为了进一步增强上述不锈钢仿古遗像的整体耐老化和抗腐蚀性能，我们必须对步骤(6)去掉了未被中间保护膜保护的彩色氧化膜的新鲜表面进行再着色或者钝化处理：该步骤有两种方法：A法：把经过步骤(7)的不锈钢仿古遗像直接放入步骤(1)的不锈钢着色溶液或含有浓度为1～30％HNO3的不锈钢钝化溶液中进行以不损坏不锈钢仿古遗像为前提的再次着色或钝化；B法：在进行步骤(7)前把还附着中间保护膜的不锈钢仿古遗像直接放入步骤(1)的不锈钢着色溶液或含有浓度为1～30％HNO3的不锈钢钝化溶液中进行以不损坏中间保护膜和不锈钢仿古遗像为前提的再次着色或钝化；然后再经过步骤(7)；Step (8): In order to further enhance the overall anti-aging and anti-corrosion properties of the stainless steel antique portrait, we must recolor or passivate the fresh surface of the step (6) that has removed the colored oxide film that is not protected by the intermediate protective film : this step has two kinds of methods: A method: directly put into the stainless steel coloring solution of step (1) or contain the stainless steel passivation solution that concentration is 1～30% HNO3 through the stainless steel antique posthumous image of step (7) and carry out following Re-coloring or passivation on the premise of not damaging the stainless steel antique portrait; B method: before performing step (7), put the stainless steel antique portrait with the intermediate protective film directly into the stainless steel coloring solution of step (1) or contain a concentration of 1 Carry out in the stainless steel passivation solution of ～ 30 %HNO Carry out recoloring or passivation on the premise of not damaging the intermediate protective film and the antique portrait of stainless steel; Then go through step (7);
为了进一步增强上述不锈钢仿古遗像的抗污和整体耐老化和抗腐蚀性能，可以再在上述不锈钢仿古遗像表面上涂装上一层结合力和耐老化性能很强的透明高分子保护膜。最后，还可以对其进行满足顾客要求的装裱。这样就制作成了一幅完整的不锈钢仿古遗像了。In order to further enhance the anti-fouling and overall aging resistance and corrosion resistance of the above-mentioned stainless steel antique portraits, a transparent polymer protective film with strong adhesion and aging resistance can be coated on the surface of the above-mentioned stainless steel antique portraits. Finally, it can also be framed to meet customer requirements. In this way, a complete stainless steel antique portrait is made.
本发明所提供的不锈钢仿古遗像制作方法具有以下优点：本不锈钢仿古遗像图像表面富丽堂皇、高雅美观，怀旧感强；它不仅具有不锈钢原有的各种优越性不怕摔、砸，同时其耐蚀性能、耐风化、耐紫外线照射性能和外观装饰效果远优于普通不锈钢；按照理论推测在正常保存的前提下，其保存期应该可以达到上百年以上的历史。因此不锈钢仿古遗像既克服了在纸质或塑质材料上的普通彩色或黑白照相技术的耐老化性能差不能长期保存的缺点，同时也克服了陶瓷材料容易破碎不好保存的缺点；另外，还满足了人们对曾经被淘汰的黑白、棕白照片的怀旧情绪。The method for making antique stainless steel portraits provided by the present invention has the following advantages: the surface of the stainless steel antique portraits is magnificent, elegant and beautiful, and has a strong sense of nostalgia; it not only has various original advantages of stainless steel and is not afraid of falling and smashing, but also has corrosion resistance Performance, weathering resistance, UV radiation resistance and appearance decoration are far superior to ordinary stainless steel; according to theory, under the premise of normal preservation, its preservation period should reach more than a hundred years of history. Therefore, stainless steel antique portraits not only overcome the disadvantages of poor aging resistance and poor long-term preservation of ordinary color or black and white photographic technology on paper or plastic materials, but also overcome the disadvantages of ceramic materials that are easy to break and not easy to preserve; Satisfies people's nostalgia for black-and-white and brown-and-white photos that were once eliminated.
具体实施方式 Detailed ways
实施例1：Example 1:
银白色不锈钢板材作为基材：(1)不锈钢板前处理：镜面磨光、除油、清洗；(2)将不锈钢板放在含有化学成分和浓度分别为CrO3：250g/l和H2SO4：300g/l的化学着色溶液中，反应温度为70℃的条件下进行化学处理，通过化学氧化着色，在不锈钢表面上形成黑色光干涉色的氧化膜；(3)将着色过的不锈钢板放在含有化学成分和浓度分别为CrO3：250g/l和H2SO4：2.5g/l的电解坚膜溶液中，在外加直流电流密度为I＝0.6A/dm2的条件下通电十分钟；(4)再将上述处理的着色的不锈钢板放在化学成分为：Na2SiO3，浓度为：10％的水溶液中，反应温度为65℃的条件下进行封闭处理；(5)将上述光干涉彩色不锈钢待成相表面洗净、烘干后，用金属防腐油墨印刷上一层事先订制好的遗像的中间保护膜；具体实施步骤：①将拍摄好的遗像制作成菲林片；②制作丝网版；③用金属防腐油墨把上述遗像的印刷在彩色不锈钢待成相表面上；④按照该油墨的要求对其进行热固化；(6)把经过上述步骤处理好的彩色不锈钢待成像板放入到含有浓度为10％H2SO4和浓度为5％H3PO4的溶液中，在外加直流电为V＝12v，I＝5A/dm2的条件下，该彩色不锈钢板为阳极，铅版为阴极，去掉未被中间保护膜保护的彩色氧化膜；(7)去掉上述中间保护膜，在浓度为10％的NaOH碱性溶液中，80℃下洗掉上述油墨，然后洗净、烘干；(8)把上述不锈钢仿古遗像直接放入步骤(1)的不锈钢着色溶液着成淡棕色；(9)喷涂上一层结合力和耐老化性能很强的透明高分子聚酯漆保护膜；(10)按顾客要求装裱。这样就制作成了一幅黑色照片棕色底的不锈钢仿古遗像了。Silver-white stainless steel plate as the base material: ( 1 ) pre-treatment of stainless steel plate : mirror polishing, degreasing, cleaning; : In the chemical coloring solution of 300g/l, chemical treatment is carried out under the condition of reaction temperature of 70°C, through chemical oxidation coloring, an oxide film of black light interference color is formed on the stainless steel surface; (3) the colored stainless steel plate is placed In the electrolytic hardening solution containing chemical composition and concentration of CrO 3 : 250g/l and H 2 SO 4 : 2.5g/l, apply electricity for ten minutes under the condition of external DC current density I=0.6A/dm 2 (4) Put the above-mentioned colored stainless steel plate in the chemical composition: Na 2 SiO 3 , the concentration is: 10% aqueous solution, and the reaction temperature is 65°C for sealing treatment; (5) Put the above-mentioned After the light-interference color stainless steel surface is cleaned and dried, a layer of intermediate protective film for the pre-made portrait is printed with metal anti-corrosion ink; specific implementation steps: ① Make the photographed portrait into a film; ② Make the screen version; ③ print the above-mentioned posthumous image on the surface of the colored stainless steel to be formed with metal anti-corrosion ink; ④ heat-cure it according to the requirements of the ink; (6) process the colored stainless steel to be imaged through the above steps The plate is placed in a solution containing 10% H 2 SO 4 and 5% H 3 PO 4 . Under the conditions of V=12v and I=5A/dm 2 , the colored stainless steel plate is the anode , the stereotype is the cathode, remove the color oxide film that is not protected by the intermediate protective film; (7) remove the above-mentioned intermediate protective film, wash off the above-mentioned ink in a NaOH alkaline solution with a concentration of 10% at 80 ° C, and then wash , drying; (8) directly put the above-mentioned stainless steel antique posthumous image into the stainless steel coloring solution of step (1) and become light brown; (9) spray the very strong transparent macromolecular polyester lacquer of one deck binding force and anti-aging performance Protective film; (10) Mounting according to customer requirements. In this way, a stainless steel antique posthumous portrait with a black photo brown background has been made.
实施例2：Example 2:
银白色不锈钢板材作为基材：(1)不锈钢板前处理：镜面磨光、除油、清洗；(2)在含有化学成分和浓度分别为CrO3：120g/l和H2SO4：600g/l的化学着色溶液中，反应温度为90℃的条件下进行化学处理，通过化学氧化着色，在不锈钢表面上形成黑色光干涉色的氧化膜；(3)在含有化学成分和浓度分别为CrO3：250g/l和H2SO4：2.5g/l的电解坚膜溶液中，在外加直流电流密度为I＝0.6A/dm2的条件下通电约十分钟；(4)将上述处理的着色不锈钢板放在化学成分为：Na2SiO3，浓度为10％的水溶液中，反应温度为65℃的条件下进行封闭处理；(5)将上述光干涉彩色不锈钢待成相表面洗净、烘干后，涂布上一层市售丝网印刷制版用感光胶，然后把事先制作好的遗像菲林片放入其上按照感光胶的要求进行感光、冲洗、烘干，形成遗像的中间保护膜；(6)把经过上述四个步骤处理好的彩色不锈钢待成像板放入到含有浓度为10％H2SO4和浓度为5％H3PO4的溶液中，在外加直流电为V＝12v，I＝5A/dm2的条件下，该彩色不锈钢板为阳极，铅版为阴极，去掉未被中间保护膜保护的彩色氧化膜；(7)在浓度为10％的NaOH碱性溶液中，80℃下洗掉上述油墨，然后洗净、烘干；(8)把上述不锈钢仿古遗像放入含有浓度为浓度为10％HNO3的不锈钢钝化溶液中，反应温度为25℃下钝化10分钟；(9)喷涂上一层结合力和耐老化性能很强的透明高分子聚酯漆保护膜；(10)按顾客要求装裱，这样就制作成了一幅黑色照片白底的不锈钢仿古遗像了。Silver-white stainless steel plate as the base material: (1) Pre-treatment of stainless steel plate: mirror polishing, degreasing, cleaning; (2) The chemical composition and concentration are respectively CrO 3 : 120g/l and H 2 SO 4 : 600g/l In the chemical coloring solution, the chemical treatment is carried out under the condition of the reaction temperature of 90 ° C, and the oxidation film of black light interference color is formed on the stainless steel surface through chemical oxidation coloring; (3) the chemical composition and concentration are respectively CrO 3 : 250g/l and H 2 SO 4 : 2.5g/l electrolytic film hardening solution, under the condition that the external DC current density is I=0.6A/dm 2 , it is energized for about ten minutes; (4) the colored stainless steel treated above The plate is placed in an aqueous solution with a chemical composition of Na 2 SiO 3 and a concentration of 10%, and the reaction temperature is 65°C for sealing treatment; (5) Wash and dry the surface of the above-mentioned light interference colored stainless steel to be phased Finally, apply one layer of commercially available photosensitive glue for screen printing plate making, then put the photosensitive film sheet made in advance on it according to the requirements of the photosensitive glue, rinse, dry, and form the middle protective film of the portrait; (6) Put the colored stainless steel plate to be imaged which has been processed through the above four steps into a solution containing 10% H 2 SO 4 and 5% H 3 PO 4 , and apply a direct current of V=12v, Under the condition of I=5A/dm 2 , the colored stainless steel plate is the anode, and the cliche is the cathode, and the colored oxide film not protected by the intermediate protective film is removed; (7) in a NaOH alkaline solution with a concentration of 10%, 80 Wash off the above-mentioned ink at ℃, then wash and dry; (8) put the above-mentioned stainless steel antique portrait into the stainless steel passivation solution that contains 10% HNO3 , and the reaction temperature is 25 ℃ for passivation for 10 minutes (9) Spray a layer of transparent polymer polyester paint protective film with strong bonding force and aging resistance; (10) Mount according to customer requirements, so that a stainless steel antique portrait with a black photo and a white background is made .
Claims (8)
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| CNA2007100535124A CN101125514A (en) | 2007-10-09 | 2007-10-09 | A kind of stainless steel antique posthumous portrait manufacturing method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173121A (en) * | 2010-11-26 | 2011-09-07 | 珠海拾比佰彩图板有限公司 | Stainless steel wire-drawing sheet |
| CN102887031A (en) * | 2011-07-22 | 2013-01-23 | 比亚迪股份有限公司 | Method for forming machining textures on surface of stainless steel |
| CN109023500A (en) * | 2018-06-27 | 2018-12-18 | 湖北大学 | A kind of environment-friendly preparation method thereof of stainless base steel colour super-hydrophobic self-cleaning surface |
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2007
- 2007-10-09 CN CNA2007100535124A patent/CN101125514A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173121A (en) * | 2010-11-26 | 2011-09-07 | 珠海拾比佰彩图板有限公司 | Stainless steel wire-drawing sheet |
| CN102887031A (en) * | 2011-07-22 | 2013-01-23 | 比亚迪股份有限公司 | Method for forming machining textures on surface of stainless steel |
| CN109023500A (en) * | 2018-06-27 | 2018-12-18 | 湖北大学 | A kind of environment-friendly preparation method thereof of stainless base steel colour super-hydrophobic self-cleaning surface |
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