CN101113570B - Organosilicon softening and smoothing agent and preparation process thereof - Google Patents
Organosilicon softening and smoothing agent and preparation process thereof Download PDFInfo
- Publication number
- CN101113570B CN101113570B CN2007100292531A CN200710029253A CN101113570B CN 101113570 B CN101113570 B CN 101113570B CN 2007100292531 A CN2007100292531 A CN 2007100292531A CN 200710029253 A CN200710029253 A CN 200710029253A CN 101113570 B CN101113570 B CN 101113570B
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- CN
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- Prior art keywords
- emulsion
- silicone oil
- smoothing agent
- organosilicon
- oil emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000009499 grossing Methods 0.000 title claims abstract 5
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 48
- -1 Fatty acid triethanolamine ester Chemical class 0.000 claims description 17
- 239000004593 Epoxy Substances 0.000 claims description 14
- 229920002545 silicone oil Polymers 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920013822 aminosilicone Polymers 0.000 claims 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 1
- 150000002191 fatty alcohols Chemical class 0.000 claims 1
- 229940051841 polyoxyethylene ether Drugs 0.000 claims 1
- 229920000056 polyoxyethylene ether Polymers 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 11
- 239000004753 textile Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract 2
- 230000007547 defect Effects 0.000 abstract 1
- 230000001066 destructive effect Effects 0.000 abstract 1
- 238000004945 emulsification Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 21
- OBFQBDOLCADBTP-UHFFFAOYSA-N aminosilicon Chemical compound [Si]N OBFQBDOLCADBTP-UHFFFAOYSA-N 0.000 description 10
- 239000004816 latex Substances 0.000 description 10
- 229920000126 latex Polymers 0.000 description 10
- 229910052710 silicon Inorganic materials 0.000 description 10
- 239000010703 silicon Substances 0.000 description 10
- AYAUBWSUZRFVQO-UHFFFAOYSA-N 2-[2-(4-phenyl-5-sulfanylidene-1h-1,2,4-triazol-3-yl)ethyl]benzo[de]isoquinoline-1,3-dione Chemical compound O=C1C(C=23)=CC=CC3=CC=CC=2C(=O)N1CCC1=NNC(=S)N1C1=CC=CC=C1 AYAUBWSUZRFVQO-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010002 mechanical finishing Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of a soft smoothing agent, in particular to an organosilicon soft smoothing agent and a preparation process thereof, and provides a new raw material formula and a new secondary emulsification process aiming at the defects of easy layering, poor emulsion stability, easy emulsion breaking, high requirement on the use environment, easy oil floating in the use process, destructive damage to textiles and the like of the organosilicon smoothing agent on the market in the background technology; the produced product is not layered when being stored for a long time, has stable performance and simple use and operation, and effectively and comprehensively improves the serviceability and the added value of the textile.
Description
Technical field:
The present invention relates to a kind of flexible smooth agent technical field, refer in particular to a kind of organosilicon flexible smooth agent and preparation technology thereof.
Background technology:
In order to make fabric have softness, lubricious or plentiful feel, except adopting mechanical finishing, also can in the finishing process of textile production, add flexible smooth agent and put in order.Early stage silicone softening agent is the mechanical impurity of dimethicone and containing hydrogen silicone oil, and this organosilicon does not contain active gene, combine with fabric firm inadequately, come off easily and feel poor.Present smooth agent on the market belongs to organosilicon flexible smooth agent more, and this type of smooth agent effect is general, but existence is prone to layering, and stability of emulsion is poor, and breakdown of emulsion requires height to environment for use easily, and easy floating oil can damage textiles in the use.
Summary of the invention:
The objective of the invention is to, a kind of organosilicon flexible smooth agent and preparation technology thereof are provided to the deficiency of prior art.
For achieving the above object, the present invention takes following technical scheme:
Each component of said invention comprises following composition by weight percentage:
Amino silicon oil emulsion A 15%～25%,
Amino silicon oil emulsion B 20%～30%,
Epoxy radicals silicone oil emulsion 6%～15%,
107 latex solutions 25%～45%,
Fatty acid triethanolamine ester 3%～8%,
AEO 2%～6%,
α-Qiang Jibingsuan 0.5%～2%,
Deionized water 15%～25%.
Described amino silicon oil emulsion A is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.6～0.8, viscosity 1500～3000mP.s.
Described amino silicon oil emulsion B is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.2～0.4, viscosity 15000～20000mP.s.
Described epoxy radicals silicone oil emulsion is the emulsion that contains epoxy radicals silicone oil 30%, and epoxide number is 0.3～0.6, viscosity 1500～3000mP.s.
Described 107 latex solutions are the emulsion that contains 107 latex solutions 30%.
The technology of preparation organosilicon flexible smooth agent is: at first, deionized water, AEO, fatty acid triethanolamine ester are dropped in the agitated reactor successively, and heated and stirred makes its dissolving; Second step when the temperature in the agitated reactor is raised to 40 ℃, added amino silicon oil emulsion A, amino silicon oil emulsion B, epoxy radicals silicone oil emulsion, 107 latex solutions, and heating is simultaneously stirred, and temperature remains on 40～50 ℃, and mixing speed is 60～100r/min; In the 3rd step, when temperature was raised to 50～55 ℃, mixing speed was 90～130r/min; In the 4th step, persistently overheating 1 hour, insulation was 30 minutes after temperature rose to 55～70 ℃, and mixing speed is after the above-mentioned reaction of 150～190r/min is accomplished, and with below the cooling water rapid cooling to 40 ℃, mixing speed reduces with temperature; At last, temperature remains on 36～40 ℃, and mixing speed remains on reacted under 20～40r/min condition 30～60 minutes, filters discharging.
The invention has the beneficial effects as follows that this organosilicon flexible smooth agent long-term storage is not stratified, stable performance; Use simple; Be difficult for breakdown of emulsion,, set up new emulsion equilibrium system stable performance through this technology to the textiles excellent affinity; Use simple to operately, improved the taking and the added value of textiles effectively comprehensively.
The specific embodiment:
Embodiment 1, forms each component of the present invention by weight percentage, comprises following composition:
Amido silicon oil 30% latex A 16%,
Amido silicon oil 30% emulsion B 20%,
Epoxy radicals silicone oil 30% emulsion 8%,
107 glue, 30% emulsion 32%,
Fatty acid triethanolamine ester 3%,
AEO 2%,
α-Qiang Jibingsuan 1%,
Deionized water 15%.
Described amino silicon oil emulsion A is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.6～0.8, viscosity 1500～3000mP.s.
Described amino silicon oil emulsion B is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.2～0.4, viscosity 15000～20000mP.s.
Described epoxy radicals silicone oil emulsion is the emulsion that contains epoxy radicals silicone oil 30%, and epoxide number is 0.3～0.6, viscosity 1500～3000mP.s.
Described 107 latex solutions are the emulsion that contains 107 latex solutions 30%.
Preparation technology of the present invention is: at first, deionized water, AEO, fatty acid triethanolamine ester are dropped in the agitated reactor successively, and heated and stirred makes its dissolving; Second step when the temperature in the agitated reactor is raised to 40 ℃, added amino silicon oil emulsion A, amino silicon oil emulsion B, epoxy radicals silicone oil emulsion, 107 latex solutions, and heating is simultaneously stirred, and temperature remains on 40～50 ℃, and mixing speed is 60～100r/min; In the 3rd step, when temperature was raised to 50～55 ℃, mixing speed was 90～130r/min; In the 4th step, persistently overheating 1 hour, insulation was 30 minutes after temperature rose to 55～70 ℃, and mixing speed is 150～190r/min; After above-mentioned reaction was accomplished, with below the cooling water rapid cooling to 40 ℃, mixing speed reduced with temperature; At last, temperature remains on 36～40 ℃, and mixing speed remains on reacted under 20～40r/min condition 30～60 minutes, filters discharging.
Embodiment 2, and the preparation technology of present embodiment is identical with embodiment 1, no longer repeat here, and different is the percentage difference of forming material of the present invention, specific as follows:
Amido silicon oil 30% latex A 18%,
Amido silicon oil 30% emulsion B 22%,
Epoxy radicals silicone oil 30% emulsion 7%,
107 glue, 30% emulsion 30%,
Fatty acid triethanolamine ester 5%,
AEO 2%,
α-Qiang Jibingsuan 1%,
Deionized water 15%.
Embodiment 3, and the preparation technology of present embodiment is identical with embodiment 1, no longer repeat here, and different is the percentage difference of forming material of the present invention, specific as follows:
Amido silicon oil 30% latex A 22%,
Amido silicon oil 30% emulsion B 20%,
Epoxy radicals silicone oil 30% emulsion 10%,
107 glue, 30% emulsion 25%,
Fatty acid triethanolamine ester 4%,
AEO 3%,
α-Qiang Jibingsuan 1%,
Deionized water 15%.
Certainly; The embodiment of the above is a preferred embodiments of the present invention, is not to limit practical range of the present invention; So all equivalences of doing according to the described prescription of claim of the present invention, technology change or modify, and include in claim of the present invention.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100292531A CN101113570B (en) | 2007-07-20 | 2007-07-20 | Organosilicon softening and smoothing agent and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100292531A CN101113570B (en) | 2007-07-20 | 2007-07-20 | Organosilicon softening and smoothing agent and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101113570A CN101113570A (en) | 2008-01-30 |
| CN101113570B true CN101113570B (en) | 2012-11-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100292531A Expired - Fee Related CN101113570B (en) | 2007-07-20 | 2007-07-20 | Organosilicon softening and smoothing agent and preparation process thereof |
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| CN (1) | CN101113570B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102787502A (en) * | 2012-07-24 | 2012-11-21 | 苏州市华元化工有限公司 | Composite smoothing agent |
| CN102839545B (en) * | 2012-09-01 | 2014-08-06 | 中山市巴斯基化工有限公司 | Ice-feeling silicone oil for continuous padding process |
| CN106400508B (en) * | 2016-09-14 | 2019-05-07 | 清远市宏图助剂有限公司 | A kind of nylon-cotton fabric sliding bullet finishing agent and preparation method thereof |
| CN106835713B (en) * | 2017-02-10 | 2019-07-09 | 深圳天鼎新材料有限公司 | A kind of organosilicon high-elastic smooth finishing agent and preparation method thereof |
| CN108385386A (en) * | 2018-04-10 | 2018-08-10 | 清远市恩科材料科技有限公司 | Super fluffy silicon soft oil and preparation method thereof |
| CN110791965A (en) * | 2019-10-12 | 2020-02-14 | 苏州联胜化学有限公司 | Fabric softener and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0469316A2 (en) * | 1990-08-01 | 1992-02-05 | Pfersee Chemie GmbH | Silicone-based aqueous dispersion, its preparation and use |
| CN1584191A (en) * | 2004-05-28 | 2005-02-23 | 刘国平 | Nanometer softening smoothing agent and preparing method thereof |
| CN1916271A (en) * | 2006-09-07 | 2007-02-21 | 浙江传化股份有限公司 | Method for preparing smoothing agent for fabric of organosilicon |
-
2007
- 2007-07-20 CN CN2007100292531A patent/CN101113570B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0469316A2 (en) * | 1990-08-01 | 1992-02-05 | Pfersee Chemie GmbH | Silicone-based aqueous dispersion, its preparation and use |
| CN1584191A (en) * | 2004-05-28 | 2005-02-23 | 刘国平 | Nanometer softening smoothing agent and preparing method thereof |
| CN1916271A (en) * | 2006-09-07 | 2007-02-21 | 浙江传化股份有限公司 | Method for preparing smoothing agent for fabric of organosilicon |
Non-Patent Citations (1)
| Title |
|---|
| 姜西等.GH系列丝光羊毛平滑剂的研制.《印染助剂》.2006,第21卷(第3期),27-28. * |
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| CN101113570A (en) | 2008-01-30 |
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