CN101096449B - A kind of PC/ABS alloy material - Google Patents
A kind of PC/ABS alloy material Download PDFInfo
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- CN101096449B CN101096449B CN200610036256A CN200610036256A CN101096449B CN 101096449 B CN101096449 B CN 101096449B CN 200610036256 A CN200610036256 A CN 200610036256A CN 200610036256 A CN200610036256 A CN 200610036256A CN 101096449 B CN101096449 B CN 101096449B
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- alloy material
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- abs alloy
- oxidation inhibitor
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- 239000000956 alloy Substances 0.000 title claims abstract description 27
- 229920007019 PC/ABS Polymers 0.000 title claims abstract description 26
- 239000003063 flame retardant Substances 0.000 claims abstract description 22
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 3
- 239000004417 polycarbonate Substances 0.000 claims description 23
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical group O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000003112 inhibitor Substances 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 15
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 229920000515 polycarbonate Polymers 0.000 claims description 12
- SOGFHWHHBILCSX-UHFFFAOYSA-J prop-2-enoate silicon(4+) Chemical compound [Si+4].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C SOGFHWHHBILCSX-UHFFFAOYSA-J 0.000 claims description 12
- 239000004593 Epoxy Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 6
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims description 2
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims description 2
- 229930188012 Bromoether Natural products 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- -1 antimony peroxide Chemical class 0.000 claims description 2
- HJCMMOODWZOXML-UHFFFAOYSA-N bromo hypobromite Chemical compound BrOBr HJCMMOODWZOXML-UHFFFAOYSA-N 0.000 claims description 2
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 229920001577 copolymer Polymers 0.000 abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000001746 injection moulding Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
一种PC/ABS合金材料，其主要包括以下组分，以重量份数表示为：PC40～60份、ABS25～40份、有机硅-丙烯酸酯共聚物3～8份、溴系阻燃剂6～15份、锑系阻燃剂2～5份、环氧树脂0.1～1份、抗氧剂0.1～0.3份。本发明提供的PC/ABS合金材料，使用了有机硅-丙烯酸酯共聚物作增韧剂，在改善材料韧性的同时，可有效防止材料燃烧时的熔滴现象，无须另外加入防滴落剂。因此，该PC/ABS合金材料其配方简单，成本较低，具有很好的经济效益。A PC/ABS alloy material, which mainly includes the following components, expressed in parts by weight: 40-60 parts of PC, 25-40 parts of ABS, 3-8 parts of silicone-acrylate copolymer, 6 parts of brominated flame retardant ～15 parts, 2～5 parts of antimony-based flame retardant, 0.1～1 part of epoxy resin, 0.1～0.3 parts of antioxidant. The PC/ABS alloy material provided by the invention uses a silicone-acrylate copolymer as a toughening agent, which can effectively prevent the droplet phenomenon when the material is burned while improving the toughness of the material, without additional anti-dripping agent. Therefore, the PC/ABS alloy material has simple formula, low cost and good economic benefits.
Description
Technical field
The present invention relates to a kind of macromolecular material Ji Intraoperative field, particularly relate to a kind of high molecule alloy material.
Background technology
PC/ABS is a kind of plastic alloy material of excellent property, and it not only has favorable mechanical performance and moulding processability, and product surface good luster, attractive in appearance, thereby is widely used in electronics, household electric appliances.
When the PC/ABS alloy is used to make electronics zero member, often require material to have flame retardant properties, to this, people adopt the method for adding fire retardant to improve the flame retardant properties of material usually.For preventing that further the molten drop phenomenon from appearring in material when carrying out combustion testing, it is fire-retardant to make material reach the UL94V-0 level, generally also need to cooperate a certain amount of Antidrip agent of adding, but the adding of Antidrip agent, the serious deterioration that can cause PC/ABS alloy material mechanical property (especially notched Izod impact strength), and the complexity that becomes of filling a prescription, formulation cost also can improve.
Summary of the invention
In view of above problem, the object of the present invention is to provide a kind of PC/ABS alloy material, this PC/ABS alloy material good mechanical performance, fire-retardant nothing drippage, combustionproperty reaches the UL94V-0 level.
For achieving the above object, PC/ABS alloy material provided by the invention, it mainly comprises following component, is expressed as with parts by weight:
PC 40～60
ABS 25～40
Organic silicon-acrylate multipolymer 3～8
Bromide fire retardant 6～15
Sb system fire retardant 2～5
Resins, epoxy 0.1～1
Oxidation inhibitor 0.1～0.3
Wherein, described bromide fire retardant can be brominated polycarbonate, decabromodiphynly oxide, eight bromo ether, tetrabromo-bisphenol, tetrabromobisphenol a polycarbonate oligopolymer, hexabromocyclododecane or environment-friendly type bromide fire retardant TDE etc.
Described Sb system fire retardant can be antimonous oxide, antimony peroxide or sodium antimonate etc.
Described oxidation inhibitor can be antioxidant 1010, oxidation inhibitor 2921 etc.
Preferably, PC/ABS alloy material provided by the invention, its component is expressed as with parts by weight:
PC 40
ABS 32
Organic silicon-acrylate multipolymer 8
Brominated polycarbonate 15
Antimonous oxide 5
Resins, epoxy 0.5
Oxidation inhibitor 0.2
Preferably, PC/ABS alloy material provided by the invention, its component is expressed as with parts by weight:
PC 50
ABS 29
Organic silicon-acrylate multipolymer 5
Brominated polycarbonate 12
Antimonous oxide 4
Resins, epoxy 0.8
Oxidation inhibitor 0.2
Preferably, PC/ABS alloy material provided by the invention, its component is expressed as with parts by weight:
PC 60
ABS 25
Organic silicon-acrylate multipolymer 3
Brominated polycarbonate 9
Antimonous oxide 3
Resins, epoxy 1
Oxidation inhibitor 0.2
PC/ABS alloy material provided by the invention has used the organic silicon-acrylate multipolymer to make toughner, and when improving toughness of material, the molten drop phenomenon in the time of can effectively preventing material combustion need not add Antidrip agent in addition.Therefore, its prescription of this PC/ABS alloy material is simple, and cost is lower, has good economic benefits.
Embodiment
Embodiment 1
Take by weighing following raw materials according by weight:
PC 40
ABS 32
Organic silicon-acrylate multipolymer 8
Brominated polycarbonate 15
Antimonous oxide 5
Resins, epoxy 0.5
Oxidation inhibitor 0.2
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, by the mechanical property of standard GB 13525/T-92 test gained finished product and by its flame retardant properties of the U.S. UL94 of electrician association standard testing, its result as shown in Figure 1 at last.
Table 1: embodiment 1 gained PC/ABS alloy material performance
| Project | Measured value |
| Shock strength (kJ/M 2) | 28.3 |
| Project | Measured value |
| Tensile strength (MPa) | 56.05 |
| Flexural strength (MPa) | 86.67 |
| Flame retardant resistance (UL94) | V-0 |
Embodiment 2
Take by weighing following raw materials according by weight:
PC 50
ABS 29
Organic silicon-acrylate multipolymer 5
Brominated polycarbonate 12
Antimonous oxide 4
Resins, epoxy 0.8
Oxidation inhibitor 0.2
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, by the mechanical property of standard GB 13525/T-92 test gained finished product and by its flame retardant properties of the U.S. UL94 of electrician association standard testing, its result as shown in Figure 2 at last.
Table 2: embodiment 2 gained PC/ABS alloy material performances
| Project | Measured value |
| Shock strength (kJ/M 2) | 33.2 |
| Tensile strength (MPa) | 58.39 |
| Flexural strength (MPa) | 87.66 |
| Flame retardant resistance (UL94) | V-0 |
Embodiment 3
Take by weighing following raw materials according by weight:
PC 60
ABS 25
Organic silicon-acrylate multipolymer 3
Brominated polycarbonate 9
Antimonous oxide 3
Resins, epoxy 1
Oxidation inhibitor 0.2
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, by the mechanical property of standard GB 13525/T-92 test gained finished product and by its flame retardant properties of the U.S. UL94 of electrician association standard testing, its result as shown in Figure 3 at last.
Table 3: embodiment 3 gained PC/ABS alloy material performances
| Project | Measured value |
| Shock strength (kJ/M 2) | 46.8 |
| Tensile strength (MPa) | 62.27 |
| Flexural strength (MPa) | 89.66 |
| Flame retardant resistance (UL94) | V-0 |
Above embodiment is the detailed description that the present invention is done.Notice that these embodiments are not in order to limit the present invention, for those skilled in the art, the improvement of being made and additional should be considered as within protection scope of the present invention without departing from the spirit of the invention.
Claims (7)
1. a PC/ABS alloy material is characterized in that, mainly comprises following component, is expressed as with parts by weight:
PC 40～60；
ABS 25～40；
Organic silicon-acrylate multipolymer 3～8;
Bromide fire retardant 6～15;
Sb system fire retardant 2～5;
Resins, epoxy 0.1～1;
Oxidation inhibitor 0.1～0.3.
2. PC/ABS alloy material according to claim 1 is characterized in that, described bromide fire retardant is brominated polycarbonate, decabromodiphynly oxide, eight bromo ether, tetrabromo-bisphenol, hexabromocyclododecane or environment-friendly type bromide fire retardant TDE.
3. PC/ABS alloy material according to claim 1 is characterized in that, described Sb system fire retardant is antimonous oxide, antimony peroxide or sodium antimonate.
4. PC/ABS alloy material according to claim 1 is characterized in that, described oxidation inhibitor is antioxidant 1010, oxidation inhibitor 2921.
5. PC/ABS alloy material according to claim 1 is characterized in that, its component is expressed as with parts by weight:
PC 40；
ABS 32；
Organic silicon-acrylate multipolymer 8;
Brominated polycarbonate 15;
Antimonous oxide 5;
Resins, epoxy 0.5;
Oxidation inhibitor 0.2.
6. PC/ABS alloy material according to claim 1 is characterized in that its component is expressed as with parts by weight
PC 50；
ABS 29；
Organic silicon-acrylate multipolymer 5;
Brominated polycarbonate 12;
Antimonous oxide 4;
Resins, epoxy 0.8;
Oxidation inhibitor 0.2.
7. PC/ABS alloy material according to claim 1 is characterized in that its component is expressed as with parts by weight
PC 60；
ABS 25；
Organic silicon-acrylate multipolymer 3;
Brominated polycarbonate 9;
Antimonous oxide 3;
Resins, epoxy 1;
Oxidation inhibitor 0.2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610036256A CN101096449B (en) | 2006-06-30 | 2006-06-30 | A kind of PC/ABS alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610036256A CN101096449B (en) | 2006-06-30 | 2006-06-30 | A kind of PC/ABS alloy material |
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| Publication Number | Publication Date |
|---|---|
| CN101096449A CN101096449A (en) | 2008-01-02 |
| CN101096449B true CN101096449B (en) | 2010-05-26 |
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| CN200610036256A Expired - Fee Related CN101096449B (en) | 2006-06-30 | 2006-06-30 | A kind of PC/ABS alloy material |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001626A (en) * | 2015-07-22 | 2015-10-28 | 东莞市吉鑫高分子科技有限公司 | Extrusion grade thermoplastic polyurethane elastomer and manufacturing method thereof |
| CN108192267A (en) * | 2017-12-21 | 2018-06-22 | 宁波凯耀电器制造有限公司 | A kind of crack resistence PC/ABS plastic alloys and its Shooting Technique |
| CN113912975A (en) * | 2021-09-27 | 2022-01-11 | 江苏金发科技新材料有限公司 | Flame-retardant ABS composite material and preparation method and application thereof |
| CN114316554A (en) * | 2021-12-01 | 2022-04-12 | 金发科技股份有限公司 | High-spherical-pressure flame-retardant PC/ABS material and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03182542A (en) | 1989-12-13 | 1991-08-08 | Asahi Chem Ind Co Ltd | Flame-retardant resin composition |
| JPH0468047A (en) | 1990-07-09 | 1992-03-03 | Japan Synthetic Rubber Co Ltd | Flame-retardant resin composition |
| EP1003810A1 (en) * | 1997-08-11 | 2000-05-31 | Bayer Aktiengesellschaft | Abs mouldable materials containing polycarbonate, non-flammable and resistant to stress crack |
| US6084054A (en) * | 1998-03-30 | 2000-07-04 | General Electric Company | Flame retardant polycarbonate resin/ABS graft copolymer blends having low melt viscosity |
| CN1459470A (en) * | 2002-05-24 | 2003-12-03 | 东莞银禧塑胶有限公司 | Halogenless flaming retarding cold resistant PC/ABS alloy |
| CN1760257A (en) * | 2004-10-11 | 2006-04-19 | 佛山市顺德区汉达精密电子科技有限公司 | Fire retardant PC/ABS alloy |
| CN1789332A (en) * | 2005-12-20 | 2006-06-21 | 苏州市凯米克新材料有限公司 | High-performance fire-retardant polymer PC/ABS alloy |
-
2006
- 2006-06-30 CN CN200610036256A patent/CN101096449B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03182542A (en) | 1989-12-13 | 1991-08-08 | Asahi Chem Ind Co Ltd | Flame-retardant resin composition |
| JPH0468047A (en) | 1990-07-09 | 1992-03-03 | Japan Synthetic Rubber Co Ltd | Flame-retardant resin composition |
| EP1003810A1 (en) * | 1997-08-11 | 2000-05-31 | Bayer Aktiengesellschaft | Abs mouldable materials containing polycarbonate, non-flammable and resistant to stress crack |
| US6084054A (en) * | 1998-03-30 | 2000-07-04 | General Electric Company | Flame retardant polycarbonate resin/ABS graft copolymer blends having low melt viscosity |
| CN1459470A (en) * | 2002-05-24 | 2003-12-03 | 东莞银禧塑胶有限公司 | Halogenless flaming retarding cold resistant PC/ABS alloy |
| CN1760257A (en) * | 2004-10-11 | 2006-04-19 | 佛山市顺德区汉达精密电子科技有限公司 | Fire retardant PC/ABS alloy |
| CN1789332A (en) * | 2005-12-20 | 2006-06-21 | 苏州市凯米克新材料有限公司 | High-performance fire-retardant polymer PC/ABS alloy |
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| Publication number | Publication date |
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| CN101096449A (en) | 2008-01-02 |
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