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CN101066890A - Process of forming decorative marble patterns on ceramic product - Google Patents

Process of forming decorative marble patterns on ceramic product Download PDF

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Publication number
CN101066890A
CN101066890A CN 200710015841 CN200710015841A CN101066890A CN 101066890 A CN101066890 A CN 101066890A CN 200710015841 CN200710015841 CN 200710015841 CN 200710015841 A CN200710015841 A CN 200710015841A CN 101066890 A CN101066890 A CN 101066890A
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China
Prior art keywords
color glaze
glaze slurry
ceramic product
ground
marblized
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Granted
Application number
CN 200710015841
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Chinese (zh)
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CN100497264C (en
Inventor
王国红
王长江
王孝元
贾希文
卜祥孟
于杰
刘晓金
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SHANDONG MAOHUA SILICON INDUSTRY Co Ltd
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SHANDONG MAOHUA SILICON INDUSTRY Co Ltd
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Priority to CNB200710015841XA priority Critical patent/CN100497264C/en
Publication of CN101066890A publication Critical patent/CN101066890A/en
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Publication of CN100497264C publication Critical patent/CN100497264C/en
Expired - Fee Related legal-status Critical Current
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Abstract

The process of forming decorative marble patterns on ceramic product includes the following steps: 1. applying one bottom glaze layer on ceramic biscuit; 2. preparing color glaze slurry, adding foaming agent and leading gas into the color glaze slurry to produce bubble; 3. dipping the ceramic biscuit in the color glaze slurry with bubble, and lifting the ceramic biscuit for the bubbles to break to form marble patterns; and 4. drying and sintering to obtain ceramic product with decorative marble patterns. The process is simple, practical, low in cost and high in production efficiency, and can form clear marble patterns with high decoration effect.

Description

On ceramic product, form marblized trailing
Technical field
The present invention relates to a kind of marblized trailing that on ceramic product, forms, belong to the ceramic production technology field.
Background technology
Forming marbled method on domestic ceramic product surface has multiplely, as look mud method, with multiple color pug mixing, with revolving embryo or the rolling forming mode is shaped, makes its marblizing, executes transparent then and burns till; Or simply mix with multiple coloured mud and to inject plaster mould, make base substrate form similar marble pattern, execute transparent then and burn till; These two kinds of methods can cause a large amount of coloured roach, can't be recycled.And over-glaze decoration or under glazed mode all need to use a large amount of manpower hand drawings, directly influence the raising of productivity effect.Or in the color glaze slip that contains the another kind of not cellulose of cellulosic thickness glaze slip adding, simple agitation is glazing again, along with continuous glazing, two kinds of glaze slips can mix gradually, the texture that produces is fuzzy gradually, finally no longer produce texture, finally cause glaze slip can not continue to use, cause glaze slip to waste in a large number.The transcription print process is arranged in addition, and this kind method only limits to simple body and uses, and can't be applicable on the complicated body of device shape, prints or the like as the bundle surfaces externally and internally at cup.
Summary of the invention
The object of the present invention is to provide a kind of marblized trailing that on ceramic product, forms, simple and feasible, good decorating effect, cost is low, the production efficiency height, once-firing, and can not produce too much coloured roach, and save glaze slip, conformability is strong.
Of the present inventionly on ceramic product, form marblized trailing, carry out according to the following step:
(1) on ceramic paste preforms, executes one deck ground-coat enamel, preparation ground-coat enamel base;
(2) prepare the color glaze slurry, in the color glaze slurry, add whipping agent, and feeding gas makes the color glaze slurry produce the color glaze slurry bubble in the color glaze slurry;
(3) ground-coat enamel base surface is picked the color glaze slurry bubble, the color glaze slurry bubble can be adsorbed on the outside surface of ground-coat enamel base, and after waiting to lift the ground-coat enamel base, the color glaze slurry bubble that is attracted on the ground-coat enamel blank outer surface just vanishes, on the ground-coat enamel blank outer surface, stay the vestige of color glaze slurry bubble, form marbling, preparation figure decoration base substrate;
(4) treat to burn till behind the figure decoration body drying, make and have marblized ceramic product.
Wherein:
Whipping agent is an organic surface active agent, can produce bubble and can at high temperature disappear, as ethoxylated alkyl sulfate, lauric acid amide of ethanol, sulfosuccinic acid monoesters disodium (MES) or commercially available liquid detergent etc.
In the color glaze slurry, add thickening material, strengthen tack, the aqueous solution of thickening material preferably carboxymethyl cellulose, the weight ratio of carboxymethyl cellulose and water is preferably (0.3~2): 100, the add-on of thickening material is that 2~10% of color glaze slurry weight suits.
The foaming operation of color glaze slurry: can put into the color glaze slurry to the perforated tube that connects air compressor machine, make the color glaze slurry produce the color glaze slurry bubble, perforated tube is connected air compressor machine by reducing valve, moderate by adjusting reducing valve adjusting air pressure, meet the requirements the size of the size decision marbling texture of bubble until the bubble size that blows afloat.
The operation that ground-coat enamel base surface is picked the color glaze slurry bubble repeats, and is stained with the color glaze slurry bubble until the ground-coat enamel blank outer surface, guarantees the whole decorative effect of product.
Improvements of the present invention mainly are a kind of glazing working method, do not relate to base substrate of ceramic product own and glaze layer preparation of raw material, the batching of ceramic body and glaze layer and the preparation of ceramic product can directly be continued to use the existing conventional technology and be got final product, as conventional ceramic base substrate, ceramic whiteware ceramic body, feldspar ceramics base substrate, quartz-ceramics base substrate, steatite ceramics base substrate, sclerotin porcelain ceramic body and stoneware base substrate etc. are arranged respectively, whiteware glaze, crystalline ceramics glaze, shades of colour ceramic glaze and various ground-coat enamel, cover-coat enamel etc., common process control is as follows:
Enamel frit makeing: raw material selection-batching--ball milling-deironing--sieve glaze slip, standby.Glaze slip fineness 250 mesh screen residues 0.02~0.03%, ground-coat enamel moisture content 40~47%, cover-coat enamel (froth and use glaze) moisture content 50~65%.
The production preparation of ceramic product: raw material selection-batching-ball milling-filter mud-old-pugging-moulding-repaired biscuit-glazing-drying-burn till-finished product, therefore, the present invention only relates to glazing operation part.
Consist of as a kind of weight percent commonly used:
Base substrate batching: quartz 20~25%, feldspar 18~25%, flint clay 36~42%, Jiexiu soil 5~8%, clay 7~10% and talcum 2~4%.
The glaze proportioning:
Bright glaze: quartz 12~20%, feldspar 45~55%, Stalactitum 8~12%, barium carbonate 3~5%, zinc oxide 0~5%, little white spirit 3~5%, Suzhou soil 2~4% and talcum 2~5%, colorant adds 0~25%.
Matt glaze: feldspar 48~57%, Stalactitum 6~15%, Datong District's soil 8~15%, barium carbonate 18~26% and talcum 2~8%, colorant adds 0~25%.
The equal market of various toners is on sale, directly buys to get final product.
Porcelain situation according to ceramic product is determined firing temperature, determines to get final product according to common requirement and principle, is generally 1200~1240 ℃.
The present invention forms marblized trailing on ceramic product, simple and feasible, grasps easily, randomness is strong, and glaze is level and smooth, clean mark, shape such as marble grain pattern, good decorating effect, cost is low, the production efficiency height, once-firing, and can not produce too much coloured roach, there is not waste, save glaze slip, conformability is strong, can be applicable to the ceramic product of type complexity.
Can on a kind of glaze, form the texture of more than one colors by this method, also can be formed with the combination texture of light and no light effect simultaneously.
Embodiment:
The present invention is further illustrated below in conjunction with embodiment.
The raw materials used chemical weight percentage composition of embodiment sees the following form:
Title SiO 2 Ai 2O 3 CaO MgO Fe 2O 3 TiO 2 K 2O Burn and lose
Quartzy 99.07 0.57 -- -- 0.11 -- -- 0.24
Feldspar 68.70 17.23 0.06 0.32 0.10 0.07 13.06 0.46
Flint clay 50.56 37.08 -- -- 0.34 0.19 -- 12.01
Jiexiu soil 53.28 34.17 1.51 0.38 0.82 0.27 -- 16.39
Clay 39.51 21.34 0.59 0.11 1.17 0.52 -- 15.62
Talcum 60.32 1.46 0.90 31.76 0.43 -- -- 5.54
Stalactitum 1.0 0.24 54.96 0.27 0.1 -- -- 43.43
Little white spirit 61.55 2.87 2.34 4.75 0.48 0.19 -- 27.63
Suzhou soil 46.83 37.3 0.66 0.26 0.13 -- 0.11 14.78
Zinc oxide Be technical pure ZnO content 98.5%
Barium carbonate Be technical pure BaCO 3Content 98.1%
Zirconium silicate 33.86 ZrO 2 6500 -- -- 0.21 0.18 -- --
It is as follows to test the percentage composition of used ceramic body ingredients by weight:
Quartz 25%, feldspar 20%, flint clay 40%, Jiexiu soil 5%, clay 8% and talcum 2%.
According to domestic ceramics factory common process, make ceramic paste preforms, standby after the refine.
Embodiment 1
Produce the unglazed black glaze ceramic product that outside surface has unglazed white texture:
The percentage composition of white matt glaze ingredients by weight is as follows:
Feldspar 55%, Stalactitum 9%, Datong District's soil 8%, barium carbonate 23% and talcum 5% add 12% zirconium silicate.
Glaze slip fineness: 250 mesh screen residues 0.02%, moisture content 52%.
The percentage composition of black matt glaze ingredients by weight is as follows:
Feldspar 55%, Stalactitum 9%, Datong District's soil 9%, barium carbonate 24% and talcum 3 add 8% commercial black developing agent.
Glaze slip fineness: 250 mesh screen residues 0.03%, moisture content 43%.
The glazing operating process is as follows:
(1) execute the black matt glaze with the smart base of getting ready earlier, make it to become the ground-coat enamel base, standby.
(2) add the matt glaze of white in the glazing basin, add 2 ‰ the commercially available liquid detergent thickening material as whipping agent and 3% again, wherein in the thickening material, the weight ratio of carboxymethyl cellulose and water is 1: 100, stirs, and is standby.
(3) reducing valve and perforated tube are connected air compressor machine, perforated tube is put into the glaze slip of glazing basin, blows, and adjusts air pressure, makes being of the required size of bubble.
(4) with the above-mentioned ground-coat enamel base of having executed the black matt glaze, go to pick white matt glaze slurry bubble, and then continue to be stained with bubble and be stained with, obtain marbling and decorate base substrate until the base substrate outside surface in the position of not being stained with bubble.
(5) go into klining after the drying, 1200 ℃ of firing temperatures obtain the unglazed black glaze ceramic product that outside surface has unglazed white marble grain.
Embodiment 2
Produce the blackish green glaze ceramic product of gloss that outside surface has gloss black texture:
The percentage composition of gloss black glaze ingredients by weight is as follows:
Quartz 15%, feldspar 55%, Stalactitum 12%, barium carbonate 5%, little white spirit 5%, Suzhou soil 4% and talcum 4% add 8% outsourcing black developing agent.
Glaze slip fineness: 250 mesh screen residues 0.02%, moisture content 60%.
The percentage composition of the blackish green color glaze ingredients by weight of gloss is as follows:
Quartzy 13%, feldspar 57%, Stalactitum 12%, barium carbonate 7%, little white spirit 5%, Suzhou soil 4% and talcum 2% add 3.5% the blackish green toner of outsourcing.
Glaze slip fineness: 250 mesh screen residues 0.02%, moisture content 42%.
The glazing operating process is as follows:
(1) execute the black matt glaze with the smart base of getting ready earlier, make it to become the ground-coat enamel base, standby.
(2) add the black glossy glaze in the glazing basin, add 5 ‰ the ethoxylated alkyl sulfate thickening material as whipping agent and 7% again, wherein in the thickening material, the weight ratio of carboxymethyl cellulose and water is 0.5: 100, stirs, and is standby.
(3) reducing valve and perforated tube are connected air compressor machine, perforated tube is put into the glaze slip of glazing basin, blows, and adjusts air pressure, makes being of the required size of bubble.
(4) with the above-mentioned ground-coat enamel blank outer surface of having executed blackish green bright glaze, go to pick black glaze slurry bubble, and then continue to be stained with bubble and be stained with, obtain marbling and decorate base substrate until the base substrate outside surface in the position of not being stained with bubble.
(5) go into klining after the drying, 1220 ℃ of firing temperatures obtain the blackish green glaze ceramic product of gloss that outside surface has gloss black marble texture.
Embodiment 3
Production has the blackish green glaze ceramic product of gloss of unglazed black texture and gloss white pigment figure reason:
The percentage composition of black matt glaze ingredients by weight is as follows:
Feldspar 51%, Stalactitum 9%, Datong District's soil 15%, barium carbonate 22% and talcum 3% add 10% outsourcing black developing agent.
Glaze slip fineness: 250 mesh screen residues 0.02%, moisture content 60%.
The percentage composition of gloss white color glaze ingredients by weight is as follows:
Quartzy 18%, feldspar 56%, Stalactitum 12%, barium carbonate 3%, zinc oxide 2%, little white spirit 5%, Suzhou soil 2% and talcum 2% add 25%% zirconium silicate.
Glaze slip fineness: 250 mesh screen residues 0.03%, moisture content 56%.
The percentage composition of blackish green bright glaze ingredients by weight is as follows:
Quartzy 13%, feldspar 57%, Stalactitum 12%, barium carbonate 7%, little white spirit 5%, Suzhou soil 4% and talcum 2% add 3.5% blackish green toner.
Glaze slip fineness: 250 mesh screen residues 0.02%, moisture content 43%.
The glazing operating process is as follows:
(1) executes blackish green bright glaze with ready smart base earlier, obtain the ground-coat enamel base.
(2) add the black matt glaze in the glazing basin, add 5 ‰ the lauric acid amide of ethanol thickening material as whipping agent and 7% again, wherein in the thickening material, the weight ratio of carboxymethyl cellulose and water is 1.5: 100, stirs, and is standby.
(3) reducing valve and perforated tube are connected air compressor machine, perforated tube is put into the glaze slip of glazing basin, blows, and adjusts air pressure, makes being of the required size of bubble.
(4) with the above-mentioned ground-coat enamel base of having executed blackish green bright glaze, go to pick black matt glaze slurry bubble, and then continue to be stained with bubble and be stained with until the outside surface of ground-coat enamel base in the position of not being stained with bubble.
(5) add white bright glaze in another glazing basin, add 4 ‰ the commercially available liquid detergent thickening material as whipping agent and 2% again, wherein in the thickening material, the weight ratio of carboxymethyl cellulose and water is 1.8: 100, stirs, and is standby.
(6) again perforated tube is put into the glazing basin that fills white bright glaze, blow, adjust air pressure, make being of the required size of bubble.
(7) continue to pick white bright glaze bubble again with the above-mentioned secondary ground-coat enamel base of being stained with black matt glaze slurry bubble, be stained with, like this, can on glazed body, enclose one deck white bright glaze texture again again until the base substrate outside surface.
(8) go into klining after the drying, 1200 ℃ of firing temperatures obtain the blackish green glaze ceramic product of gloss that outside surface has unglazed black marble grain and gloss white marble grain.
Embodiment 4
Produce the unglazed white glaze ceramic product that outside surface has the unglazed black texture:
The percentage composition of white matt glaze ingredients by weight is as follows:
Feldspar 55%, Stalactitum 9%, Datong District's soil 8%, barium carbonate 23% and talcum 5% add 12% zirconium silicate.
Glaze slip fineness: 250 mesh screen residues 0.02%, moisture content 52%.
The percentage composition of black matt glaze ingredients by weight is as follows:
Feldspar 55%, Stalactitum 9%, Datong District's soil 9%, barium carbonate 24% and talcum 3 add 8% commercial black developing agent.
Glaze slip fineness: 250 mesh screen residues 0.03%, moisture content 43%.
The glazing operating process is as follows:
(1) execute white matt glaze with the smart base of getting ready earlier, make it to become the ground-coat enamel base, standby.
(2) add the matt glaze of black in the glazing basin, add 8 ‰ the sulfosuccinic acid monoesters disodium thickening material as whipping agent and 3% again, wherein in the thickening material, the weight ratio of carboxymethyl cellulose and water is 1: 100, stirs, and is standby.
(3) reducing valve and perforated tube are connected air compressor machine, perforated tube is put into the glaze slip of glazing basin, blows, and adjusts air pressure, makes being of the required size of bubble.
(4) with the above-mentioned ground-coat enamel base of having executed white matt glaze, go to pick black matt glaze slurry bubble, and then continue to be stained with bubble and be stained with, obtain marbling and decorate base substrate until the base substrate outside surface in the position of not being stained with bubble.
(5) go into klining after the drying, 1200 ℃ of firing temperatures obtain the unglazed white glaze ceramic product that outside surface has the unglazed black marble grain.

Claims (9)

1, a kind ofly on ceramic product, form marblized trailing, it is characterized in that carrying out according to the following step:
(1) on ceramic paste preforms, executes one deck ground-coat enamel, preparation ground-coat enamel base;
(2) prepare the color glaze slurry, in the color glaze slurry, add whipping agent, and feeding gas makes the color glaze slurry produce the color glaze slurry bubble in the color glaze slurry;
(3) ground-coat enamel base surface is picked the color glaze slurry bubble, the color glaze slurry bubble can be adsorbed on the outside surface of ground-coat enamel base, and after waiting to lift the ground-coat enamel base, the color glaze slurry bubble that is attracted on the ground-coat enamel blank outer surface just vanishes, on the ground-coat enamel blank outer surface, stay the vestige of color glaze slurry bubble, form marbling, preparation figure decoration base substrate;
(4) treat to burn till behind the figure decoration body drying, make and have marblized ceramic product.
2, according to claim 1ly form marblized trailing on ceramic product, it is characterized in that whipping agent is an organic surface active agent, add-on is 1 ‰~1% of a color glaze slurry weight.
3, according to claim 2ly on ceramic product, form marblized trailing, it is characterized in that being added with thickening material in the color glaze slurry.
4, according to claim 3ly on ceramic product, form marblized trailing, it is characterized in that thickening material is the aqueous solution of carboxymethyl cellulose.
5, according to claim 4ly on ceramic product, form marblized trailing, it is characterized in that in the thickening material that the weight ratio of carboxymethyl cellulose and water is (0.3~2): 100, the add-on of thickening material be color glaze starch weight 2~10%.
6, according to claim 1ly on ceramic product, form marblized trailing, it is characterized in that a perforated tube that connects air compressor machine is put into the color glaze slurry, make the color glaze slurry produce the color glaze slurry bubble.
7, according to claim 6ly on ceramic product, form marblized trailing, it is characterized in that perforated tube connects air compressor machine by reducing valve, regulate air pressure, meet the requirements until the bubble size that blows afloat by adjusting reducing valve.
8, on ceramic product, form marblized trailing according to the arbitrary claim of claim 1-7 is described, it is characterized in that the operation that ground-coat enamel base surface is picked the color glaze slurry bubble repeats, and is stained with the color glaze slurry bubble until the ground-coat enamel blank outer surface.
9, according to claim 8ly on ceramic product, form marblized trailing, it is characterized in that 1200~1240 ℃ of firing temperatures.
CNB200710015841XA 2007-06-01 2007-06-01 Process of forming decorative marble patterns on ceramic product Expired - Fee Related CN100497264C (en)

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