CN101058701A - Water soluble adhesive - Google Patents
Water soluble adhesive Download PDFInfo
- Publication number
- CN101058701A CN101058701A CN 200710069130 CN200710069130A CN101058701A CN 101058701 A CN101058701 A CN 101058701A CN 200710069130 CN200710069130 CN 200710069130 CN 200710069130 A CN200710069130 A CN 200710069130A CN 101058701 A CN101058701 A CN 101058701A
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- CN
- China
- Prior art keywords
- water soluble
- soluble adhesive
- adhesive according
- powder
- orders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 21
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 39
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003292 glue Substances 0.000 claims abstract description 15
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- 229920002678 cellulose Polymers 0.000 claims abstract description 11
- 239000001913 cellulose Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- 240000003183 Manihot esculenta Species 0.000 claims description 14
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 14
- 235000013312 flour Nutrition 0.000 claims description 14
- 230000008719 thickening Effects 0.000 claims description 14
- 239000004816 latex Substances 0.000 claims description 11
- 229920000126 latex Polymers 0.000 claims description 11
- 235000010980 cellulose Nutrition 0.000 claims description 10
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 229920002522 Wood fibre Polymers 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000004568 cement Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 229920000881 Modified starch Polymers 0.000 abstract 2
- 241001597008 Nomeidae Species 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000012372 quality testing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a water-soluble adhesive, which comprises the following parts: 30-65% pregelatinized starch, 10-20% 2488 polyvinyl alcohol, 13-37% cellulose and its derivant, 0-20% redispersion emulsion powder, 0. 15-0. 5% thickener and 0. 3-0. 8% high-activity zinc oxide, wherein each component is stirred evenly under the drying condition to form the product; the grain size of pregelatinized starch is 20-40 or 80-100 order, which can be allocated into gel powder to form common glue with 6% water after stirring 30min or interior-exterior wall putty powder adhesive after blending diflying powder or cement with weight at 0. 2: 10 directly.
Description
Technical field
The present invention relates to a kind of chemical bonding agent class, especially a kind of water soluble adhesive.
Background technology
Along with expanding economy and growth in the living standard, people more and more pay attention to the quality and the class of house finishing.Chemical bonding agent continues desirable with its bonding strength height, good stability, used raw material, working life is long and particularly building materials and building trade are especially decorated and decorateed engineering and adopt by industry.For example body of wall finishing aspect generally adopts dry powder to mix 107 or 801 glue; Putty powder; Add ripe rubber powder and other caking agent for building of suitable 107 glue.Though these materials have satisfied certain requirement of material of construction, certain mildew-resistant, moisture-proof role have been played, but the integral adhesive intensity difference of glue, putty ftractures easily, comes off, and water retention property is relatively poor, and too high causing again of easy peeling, foaming, viscosity is difficult for constructing during use, and complex process, cost are higher, particularly contain a large amount of objectionable impuritiess such as formaldehyde, not only bigger to human body harm, and also environmental pollution more can not be despised.
Summary of the invention
The objective of the invention is to avoid the defective of prior art and provide that a kind of high viscosity, production cost are low, compliance with environmental protection requirements, widely used water soluble adhesive.
Purpose of the present invention is achieved through the following technical solutions:
A kind of water soluble adhesive is characterized in that the weight percent of described adhesive material component is:
Pre-gelatinization tapioca (flour) 30～65%
2488 polyvinyl alcohol 10～20%
Mierocrystalline cellulose and derivative 13～37% thereof
Redispersion latex powder 0～20%
Thickening material 0.15～0.5%
High-active zinc oxide 0.3～0.8%
By component do to mix stir product.
The particle diameter of described pre-gelatinization tapioca (flour) is 20～40 orders, is made into aqueous solution glue, or particle diameter is that 80～100 orders are made into powder.
The particle diameter of described 2488 polyvinyl alcohol is 100～120 orders.
Described Mierocrystalline cellulose and derivative thereof are that wood fibre or carboxymethyl cellulose or hydroxyl two ylmethyl Mierocrystalline celluloses or methylcellulose gum are at least a.
The staple length of described wood fibre is 200 μ m～1000 μ m.
Described carboxymethyl cellulose particle diameter is 100～120 orders, and viscosity is 800～1200MPaS.
The particle diameter of described Vltra tears, methylcellulose gum is 100～120 orders, and viscosity is 60000～200000MPaS.
The particle diameter of described redispersion latex powder is 100～120 orders, and viscosity is 5～10PaS.
Described thickening material is a polyacrylamide, and anionic, molecular weight are 1200～2,000 ten thousand, or polyoxyethylene, and molecular weight is 100～1,000 ten thousand.
Described high-active zinc oxide granularity is 10～45 μ m.
Compared with prior art, the present invention is except having high adhesion, strong adhesion, product stability is good, resistance to cleavage is good, outside the advantage of acid and alkali-resistance, also have favorable environment protection energy and antimildew and antibacterial performance simultaneously, do not contain any benzene, formaldehyde etc. are to people's objectionable impurities, production cost is low, can be widely used in building inside and outside wall putty, building coating, sand-cement slurry, wall heat insulation material, waterproof building material, dry powder paint, fields such as paper plate bonding, can replace polyvinyl alcohol glue, sodium silicate, ripe rubber powder etc., because environmental protection safe in utilization, so its market outlook are boundless, be the renewal product of traditional architecture with glue.
Embodiment
Water soluble adhesive is formed the tackiness agent rubber powder by pre-gelatinization tapioca (flour), 2488 polyvinyl alcohol, ether of cellulose, redispersion latex powder, thickening material, high-active zinc oxide.The weight percent of each component is: pre-gelatinization tapioca (flour) 30～65%, 2488 polyvinyl alcohol 10～20%, Mierocrystalline cellulose and derivative 13～37% thereof, redispersion latex powder 0～20%, thickening material 0.15～0.5%, high-active zinc oxide 0.3～0.8%, doing mixed stirring by component is the cost product.Pre-gelatinization tapioca (flour) in prescription is white powder or small-particle, plays bonding, thickening power; 2488 polyvinyl alcohol are white powder, and cementability is strong, the film forming piece, and weathering resistance is good, stable performance; Mierocrystalline cellulose and derivative thereof are white powder or velvet-like slightly, play thickening, film forming, cracking resistance, anti-layering, improve the viscosity effect; The redispersion latex powder is white free flowing powder, and its pliable and tough resistance to compression, cracking resistance, wear-resistant, bonding water retention capacity are strong; Thickening material is polyacrylamide or polyoxyethylene, and white powder plays thickening, levelling effect, promotes construction; High-active zinc oxide is the micro-yellow powder shape, plays mildew-resistant, anticorrosion, enhancement.
According to the particle diameter difference of the pre-gelatinization tapioca (flour) in the set of dispense ratio, can be made into different glue or rubber powder during use.When select pre-gelatinization tapioca (flour) particle diameter be 20～40 orders be made into this product rubber powder the time, can be made into 6% the aqueous solution (i.e. 6 parts of these products, 94 parts of water), stirs after 30 minutes water soluble glue, can be by the pure glue use of common polythene; When select pre-gelatinization tapioca (flour) particle diameter be 80～100 orders be made into this product rubber powder the time, can directly mix with dry powder or cement, add water after mixing by 0.2: 10 (i.e. 0.2 part of this product, 10 parts of dry powders or cement) then and stir promptly wall putty in batch, also can be used as the tackiness agent of inner, external wall putty powder.
Embodiment 1: the special-purpose powder glue of preparation 60kg interior wall
A, pre-gelatinization tapioca (flour) 36kg
B, 2488 polyvinyl alcohol 6kg
D, redispersion latex powder 0kg
E, thickening material (polyacrylamide) 0.3kg
F, high-active zinc oxide 0.2kg
Embodiment 2: exterior wall dual-purpose powder glue in the preparation 60kg
A, pre-gelatinization tapioca (flour) 34kg
B, 2488 polyvinyl alcohol 10kg
C, Mierocrystalline cellulose and derivative thereof-Vltra tears 8kg
D, redispersion latex powder 7.5kg
E, thickening material (polyacrylamide) 0.15kg
F, high-active zinc oxide 0.35kg
Embodiment 3: the special-purpose powder glue of preparation 60kg exterior wall
A, pre-gelatinization tapioca (flour) 20kg
B, 2488 polyvinyl alcohol 10kg
D, redispersion latex powder 7.5kg
E, thickening material (polyacrylamide) 0.15kg
F, high-active zinc oxide 0.35kg
Embodiment 4: the multi-functional powder glue of preparation 80kg
A, pre-gelatinization tapioca (flour) 25kg
B, 2488 polyvinyl alcohol 15kg
D, redispersion latex powder 14.5kg
E, thickening material (polyacrylamide) 0.15kg
F, high-active zinc oxide 0.35kg
Prepared product detects through Ningbo City's building material product quality testing station, and every performance index are as shown in table 1:
Table 1
| Sequence number | Test item | Technical standard order (no aldehyde type) | The result | Conclusion |
| 1 | Bonding strength, Mpa | ≥0.5 | 0.5 | Qualified |
| 2 | Low-temperature stability (0 ℃, 24h) | Return to flow state under the room temperature | By | Qualified |
| 3 | Free formaldehyde, g/kg | ≤0.1 | Do not detect | Qualified |
| 4 | Benzene, g/kg | ≤0.2 | Do not detect | Qualified |
| 5 | Toluene+dimethylbenzene, g/kg | ≤10 | Do not detect | Qualified |
| 6 | Total volatile organism g/L | ≤50 | 12 | Qualified |
Claims (10)
1, a kind of water soluble adhesive is characterized in that the weight percent of described adhesive material component is:
Pre-gelatinization tapioca (flour) 30～65%
2488 polyvinyl alcohol 10～20%
Mierocrystalline cellulose and derivative 13～37% thereof
Redispersion latex powder 0～20%
Thickening material 0.15～0.5%
High-active zinc oxide 0.3～0.8%
By component do to mix stir product.
2, water soluble adhesive according to claim 1 is characterized in that the particle diameter of described pre-gelatinization tapioca (flour) is 20～40 orders, is made into aqueous solution glue, or particle diameter is that 80～100 orders are made into powder.
3, water soluble adhesive according to claim 1, the particle diameter that it is characterized in that described 2488 polyvinyl alcohol is 100～120 orders.
4, water soluble adhesive according to claim 1 is characterized in that described Mierocrystalline cellulose and derivative thereof are that wood fibre or carboxymethyl cellulose or hydroxyl two ylmethyl Mierocrystalline celluloses or methylcellulose gum are at least a.
5, water soluble adhesive according to claim 4, the staple length that it is characterized in that described wood fibre are 200 μ m～1000 μ m.
6, water soluble adhesive according to claim 4 is characterized in that described carboxymethyl cellulose particle diameter is 100～120 orders, and viscosity is 800～1200MPaS.
7, water soluble adhesive according to claim 4, the particle diameter that it is characterized in that described Vltra tears, methylcellulose gum is 100～120 orders, viscosity is 60000～200000MPaS.
8, water soluble adhesive according to claim 1, the particle diameter that it is characterized in that described redispersion latex powder is 100～120 orders, viscosity is 5～10PaS.
9, water soluble adhesive according to claim 1 is characterized in that described thickening material is a polyacrylamide, and anionic, molecular weight are 1200～2,000 ten thousand, or polyoxyethylene, and molecular weight is 100～1,000 ten thousand.
10, water soluble adhesive according to claim 1 is characterized in that described high-active zinc oxide granularity is 10～45 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710069130A CN101058701B (en) | 2007-05-30 | 2007-05-30 | Water soluble adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710069130A CN101058701B (en) | 2007-05-30 | 2007-05-30 | Water soluble adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101058701A true CN101058701A (en) | 2007-10-24 |
| CN101058701B CN101058701B (en) | 2010-05-26 |
Family
ID=38865009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710069130A Expired - Fee Related CN101058701B (en) | 2007-05-30 | 2007-05-30 | Water soluble adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101058701B (en) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629058B (en) * | 2009-08-25 | 2011-06-08 | 江阴市北国新型建筑材料厂 | Solid rubber powder for man-made boards |
| CN102604001A (en) * | 2012-04-01 | 2012-07-25 | 天津市职业大学 | Preparation method of organosilicon modified oxidized starch antibacterial paint |
| CN102618187A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | Cold water fast dissolving rubber powder for buildings |
| CN102618191A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | High-polymer instant-dissolving environment-friendly binder powder |
| CN102877360A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN101580359B (en) * | 2009-06-18 | 2013-01-16 | 江阴市北国新型建筑材料厂 | Rubber power for building |
| CN102964091A (en) * | 2012-11-05 | 2013-03-13 | 成都新柯力化工科技有限公司 | Porous granular instant building glue powder and preparation method thereof |
| CN103555036A (en) * | 2013-10-11 | 2014-02-05 | 湖州光博生物科技有限公司 | Silver ion anti-bacterial glue and preparation method thereof |
| CN103555225A (en) * | 2013-10-11 | 2014-02-05 | 湖州光博生物科技有限公司 | Preparation method for silver ion anti-bacterial glue |
| CN103788889A (en) * | 2014-02-21 | 2014-05-14 | 武汉优邦新材料化工有限公司 | Putty adhesive for plant modified polymerization and preparation method thereof |
| CN104228479A (en) * | 2014-08-16 | 2014-12-24 | 中山艺展装饰工程有限公司 | Self-maintenance leak repairing honeycomb type automobile tire |
| CN105110761A (en) * | 2015-09-10 | 2015-12-02 | 吉林大学 | Environment-friendly diatom ooze composite and preparation method thereof |
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| CN105623165A (en) * | 2015-12-24 | 2016-06-01 | 陕西省万安药业有限公司 | Antibacterial silver ion reagent for gynecological medical mat and preparation method of antibacterial silver ion reagent |
| CN107216829A (en) * | 2017-06-14 | 2017-09-29 | 安徽友捷包装材料有限公司 | A kind of water-soluble building powder glue formula |
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| CN102618187A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | Cold water fast dissolving rubber powder for buildings |
| CN102618191A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | High-polymer instant-dissolving environment-friendly binder powder |
| CN102604001A (en) * | 2012-04-01 | 2012-07-25 | 天津市职业大学 | Preparation method of organosilicon modified oxidized starch antibacterial paint |
| CN102877360B (en) * | 2012-09-05 | 2015-02-25 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
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| CN105368386A (en) * | 2015-11-18 | 2016-03-02 | 广德县永彬竹木工艺品厂 | Biomass-based bamboo wood processing adhesive and preparation process thereof |
| CN105623165A (en) * | 2015-12-24 | 2016-06-01 | 陕西省万安药业有限公司 | Antibacterial silver ion reagent for gynecological medical mat and preparation method of antibacterial silver ion reagent |
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| CN107353873A (en) * | 2017-08-23 | 2017-11-17 | 四川楼雕建材贸易有限公司 | Ceramic tile bonded structure glue composition and preparation method thereof |
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| CN108641458A (en) * | 2018-05-24 | 2018-10-12 | 薛紫璇 | A kind of plank is squeegeeed with rubber powder and its application |
| CN109468094A (en) * | 2018-11-23 | 2019-03-15 | 福建闽华建材科技发展有限公司 | Multifunctional building adhesive compounding and preparation |
| CN110055805A (en) * | 2019-03-08 | 2019-07-26 | 浙江景兴纸业股份有限公司 | A kind of production method of the double-deck solvable tissue of pure wood pulp |
| CN112592665A (en) * | 2020-12-31 | 2021-04-02 | 常德环创力达环保科技有限公司 | Interior and exterior wall putty interface adhesive and preparation method thereof |
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| CN101058701B (en) | 2010-05-26 |
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