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CN101050038A - Technique for treating purification in the late stage of seawater desalination - Google Patents

Technique for treating purification in the late stage of seawater desalination Download PDF

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Publication number
CN101050038A
CN101050038A CNA2007100211110A CN200710021111A CN101050038A CN 101050038 A CN101050038 A CN 101050038A CN A2007100211110 A CNA2007100211110 A CN A2007100211110A CN 200710021111 A CN200710021111 A CN 200710021111A CN 101050038 A CN101050038 A CN 101050038A
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Prior art keywords
natural mineral
seawater
seawater desalination
desalination
ion
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CNA2007100211110A
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CN100503481C (en
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陶韬
许庆华
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Physical Water Treatments (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

This invention discloses a purification process in late seawater desalting treatment. The process comprises: adding primarily desalted seawater into a natural mineral ion exchange device, mixing with natural mineral ion exchanger for ion exchange, transporting into a natural mineral purification and filtration device for purification and filtration, sterilizing in an ultraviolet sterilizer, and canning. The process has such advantages as easy operation, low cost, and no pollution, and is suitable for purification of seawater in late seawater desalting treatment, and purification of brackish water in China northwestern regions in late seawater desalting treatment.

Description

The sea water desalination later purification treatment process
Technical field:
The present invention relates to sea water desaltination, be specifically related to a kind of sea water desalination later purification treatment process.
Background technology:
Though the tellurian water yield is very big, 97% is seawater, and fresh water only accounts for 3%, and skewness, the some places Freshwater resources very lack, and especially lack the island and the landlocked arid area of tap water for some, and fresh water has become the major issue of people, animal existence.Investigation shows that coastal and landlocked underground brackish water is China second potential water source, and this water of long-term drinking can cause people, animal osteoporosis, tooth blackspot, but serious also cause cancer.
Along with rapid development of modern science and technology, people more and more pay attention to the development and use of seawater fresh water and underground brackish water.Through constantly exploring, the method for sea water desaltination has: distillation method, subzero fractionation method, reverse osmosis method, electroosmose process, pressure are oozed method, hydrate and solvent extration etc., and what use the most extensively at present is distillation method and reverse osmosis method.
Distillation method is that the seawater heating is made it explosive evaporatoin, becomes vapor condensation the process of fresh water to be distillation method again.Desalination effect behind the single flash is bad, still contains salts substances such as a spot of sodium-chlor, Repone K, sodium sulfate and yellow soda ash in the aqueous solution after its desalination, and mouthfeel is relatively poor, need repeatedly distill, and consumes more energy.Distillation method has methods such as vertical tube distillation, multistage flash evaporation, multistage single flash, vapour compression distillation and solar distilling.Report according to pertinent data: drink distilled water for a long time, found that the small white mouse growth is slower, weight loss, osteoporosis, amyotrophy, pituitary gland and kidney glandular system function are destroyed.
Reverse osmosis method is to adopt a kind of membrane sepn desalination process, force seawater to pass through fine and closely woven film, under pressurized conditions, film only allows water pass through, and materials such as salt are refused outside film, reverse osmosis method is that molecules of salt is separated from seawater, what obtain is pure water, the original mineral substance to the human body beneficial that exists in the water has also been filtered, lack necessary mineral substance of human body and trace elements such as calcium, magnesium, iron, strontium, zinc, fluorine, iodine, selenium in the pure water, the long-term drinking pure water can reduce the absorption of beneficial element, is unfavorable for HUMAN HEALTH.
Summary of the invention:
The objective of the invention is to overcome weak point in the prior art, a kind of sea water desalination later purification treatment process is provided.
The sea water desalination later purification treatment process is: the seawater after at first will tentatively desalinating joins in the ion exchange unit of natural mineral for seawater desalination and carries out ion-exchange with ion exchanger of natural mineral for seawater desalination, be transported to then in the filtration equipment for clarifying of natural mineral for seawater desalination and carry out purification filtering with purified filtering agent for seawater desalination by using natural mineral, re-use the ultraviolet radiation for sterilizing and disinfecting device and carry out disinfection, canned is finished product.
Seawater after the preliminary desalination is meant the aqueous solution that obtains after seawater is through methods such as distillation method, subzero fractionation method or reverse osmosis methodes.
Ion exchanger of natural mineral for seawater desalination is made up of montmorillonite, attapulgite, zeolite, medical stone and sepiolite.The preparation method of ion exchanger of natural mineral for seawater desalination is: batching is soaked, pushes airing, abrasive dust, is packaged as finished product; Purified filtering agent for seawater desalination by using natural mineral is made up of attapulgite, montmorillonite, zeolite, diatomite, medical stone and sepiolite; The preparation method of purified filtering agent for seawater desalination by using natural mineral is: batching is soaked, is pushed airing, crushing and screening, roasting cooling, is packaged as finished product; The ultraviolet radiation for sterilizing and disinfecting device is the conventional products of market supply.Ion exchanger of natural mineral for seawater desalination and purified filtering agent for seawater desalination by using natural mineral separate case application patent of invention.
Ion exchanger of natural mineral for seawater desalination in the ion exchange unit of natural mineral for seawater desalination not only can effectively carry out ion-exchange with sodium and the potassium ion in the seawater, can also reach the purpose of ion exchanger of natural mineral for seawater desalination being carried out modification, indexs such as the blue amount of colloid index, expansion capacity, suction of the sea-changed back of process ion exchanger of natural mineral for seawater desalination, cation exchange capacity, all improved largely, can be used to produce the higher byproduct of class, realize the waste zero release.
In the filtration equipment for clarifying of natural mineral for seawater desalination purified filtering agent for seawater desalination by using natural mineral, granule interior has a large amount of micropores, better than the long-pending hard intensity of table, the purification filtering effect is remarkable.Purified filtering agent for seawater desalination by using natural mineral can further reduce the content of salts substances such as sodium-chlor in the seawater, Repone K, sodium sulfate and yellow soda ash, heavy metal and objectionable impuritiess such as muriate and residues of banned pesticides such as mercury, lead, arsenic in the purifying filtered water.
The present invention is achieved by following technical proposals:
1, the seawater after the preliminary desalination enters in the settling chamber from the water inlet pipe of ion exchange unit of natural mineral for seawater desalination and mixes with ion exchanger of natural mineral for seawater desalination, sodium in the seawater and potassium ion and ion exchanger of natural mineral for seawater desalination carry out ion-exchange, discharge from rising pipe through the aqueous solution after the precipitation clarification, overflow pipe is capacity and the discharged air that is used for observing the aqueous solution in the ion exchange unit of natural mineral for seawater desalination, and upper cover plate is used for placing and the cleaning ion exchanger of natural mineral for seawater desalination.
2, the rising pipe of ion exchange unit of natural mineral for seawater desalination links by the water inlet pipe of pipeline and filtration equipment for clarifying of natural mineral for seawater desalination, the process ion exchange unit of natural mineral for seawater desalination carries out the aqueous solution after the ion-exchange, enter in the filtration equipment for clarifying of natural mineral for seawater desalination from water inlet pipe, by following stainless steel woven wire, filter cloth, purified filtering agent for seawater desalination by using natural mineral and last stainless steel woven wire, discharge from rising pipe, upper cover plate is used for placing and the cleaning purified filtering agent for seawater desalination by using natural mineral.
3, the rising pipe of filtration equipment for clarifying of natural mineral for seawater desalination links by pipeline and ultraviolet radiation for sterilizing and disinfecting device.Seawater after the preliminary desalination obtains a kind of as clear as crystal, pure tasty and refreshing weakly alkaline mineralized water after ion exchange unit of natural mineral for seawater desalination, filtration equipment for clarifying of natural mineral for seawater desalination and ultraviolet radiation for sterilizing and disinfecting device combined treatment, canned is finished product.
4, the seawater after the preliminary desalination, is discharged from the waste sludge discharge pipe because the effect of gravity sinks in the settling chamber carrying out the waste residue that ion-exchange and precipitation clarification back produce.Through the trace impurity that the aqueous solution after the ion-exchange produces in carrying out the adsorption filtration process,, discharge from wastewater discharge pipe because the effect of gravity sinks in the settling chamber.
In the aqueous solution after ion-exchange and the adsorption filtration, the ion and a large amount of various useful natural mineral matters that need of retained part human body still meet the drinking water standard of national regulation, help HUMAN HEALTH.In the process of whole later purification treatment process, simple to operate, expense is cheap, does not have contaminate environment, compliance with environmental protection requirements.
The sea water desalination later purification treatment process is applicable to the purification in sea water desaltination later stage, also is applicable to the purification in the brackish water desalination later stage of the Northwest's different concns, and the Freshwater resources of sustainable use are provided.
Description of drawings:
Fig. 1 is the synoptic diagram of sea water desalination later purification treatment process.
As shown in the figure: the 1st, the water inlet pipe of ion exchange unit of natural mineral for seawater desalination, the 2nd, the settling chamber, the 3rd, upper cover plate, the 4th, overflow pipe, the 5th, ion exchange unit of natural mineral for seawater desalination, the 6th, rising pipe, the 7th, the water inlet pipe of filtration equipment for clarifying of natural mineral for seawater desalination, the 8th, ion exchanger of natural mineral for seawater desalination, the 9th, waste sludge discharge pipe, the 10th, the duct coupling between ion exchange unit of natural mineral for seawater desalination rising pipe and the filtration equipment for clarifying of natural mineral for seawater desalination water inlet pipe, the 11st, upper cover plate, the 12nd, rising pipe, the 13rd, last stainless steel woven wire, the 14th, filtration equipment for clarifying of natural mineral for seawater desalination, the 15th, purified filtering agent for seawater desalination by using natural mineral, the 16th, filter cloth, the 17th, following stainless steel woven wire, the 18th, settling chamber's wastewater discharge pipe, the 19th, wastewater discharge pipe, the 20th, the duct coupling between filtration equipment for clarifying of natural mineral for seawater desalination rising pipe and the ultraviolet radiation for sterilizing and disinfecting device, the 21st, ultraviolet radiation for sterilizing and disinfecting device, the 22nd, ultraviolet radiation for sterilizing and disinfecting device rising pipe.
Embodiment:
Below in conjunction with embodiment, the invention will be further described:
1, the seawater after the preliminary desalination enters in the settling chamber 2 from the water inlet pipe 1 of ion exchange unit of natural mineral for seawater desalination 5 and mixes with ion exchanger of natural mineral for seawater desalination 8, sodium in the seawater and potassium ion and ion exchanger of natural mineral for seawater desalination carry out ion-exchange, discharge from rising pipe 6 through the aqueous solution after the precipitation clarification, overflow pipe 4 is capacity and the discharged air that are used for observing the aqueous solution in the ion exchange unit of natural mineral for seawater desalination, and upper cover plate 3 is used for placing and cleaning ion exchanger of natural mineral for seawater desalination 8.
2, the rising pipe 6 of ion exchange unit of natural mineral for seawater desalination links by the water inlet pipe 7 of pipeline 10 with filtration equipment for clarifying of natural mineral for seawater desalination 14, process ion exchange unit of natural mineral for seawater desalination 5 carries out the aqueous solution after the ion-exchange, enter in the filtration equipment for clarifying of natural mineral for seawater desalination 14 from water inlet pipe 7, by following stainless steel woven wire 17, filter cloth 16, purified filtering agent for seawater desalination by using natural mineral 15 and last stainless steel woven wire 13, discharge from rising pipe 12, upper cover plate 11 is used for placing and cleaning purified filtering agent for seawater desalination by using natural mineral 15.
3, the rising pipe 12 of filtration equipment for clarifying of natural mineral for seawater desalination 14 links by pipeline 20 and ultraviolet radiation for sterilizing and disinfecting device 21, and as clear as crystal, pure tasty and refreshing weakly alkaline mineralized water is discharged from ultraviolet radiation for sterilizing and disinfecting device rising pipe 22, and canned is finished product.
4, the seawater after the preliminary desalination, is discharged from waste sludge discharge pipe 9 because the effect of gravity sinks in the settling chamber 2 carrying out the waste residue that ion-exchange and precipitation clarification back produce.Through the trace impurity that the aqueous solution after the ion-exchange produces in carrying out the adsorption filtration process,, discharge from wastewater discharge pipe 19 because the effect of gravity sinks in the settling chamber 18.

Claims (1)

1, a kind of sea water desalination later purification treatment process, it is characterized in that, (1) seawater after the preliminary desalination enters in the settling chamber from the water inlet pipe of ion exchange unit of natural mineral for seawater desalination and mixes with ion exchanger of natural mineral for seawater desalination, sodium in the seawater and potassium ion and ion exchanger of natural mineral for seawater desalination carry out ion-exchange, discharge from rising pipe through the aqueous solution after the precipitation clarification; (2) rising pipe of ion exchange unit of natural mineral for seawater desalination links by the water inlet pipe of pipeline and filtration equipment for clarifying of natural mineral for seawater desalination, the process ion exchange unit of natural mineral for seawater desalination carries out the aqueous solution after the ion-exchange, enter in the filtration equipment for clarifying of natural mineral for seawater desalination from water inlet pipe, by following stainless steel woven wire, filter cloth, purified filtering agent for seawater desalination by using natural mineral and last stainless steel woven wire, discharge from rising pipe; (3) rising pipe of filtration equipment for clarifying of natural mineral for seawater desalination links by pipeline and ultraviolet radiation for sterilizing and disinfecting device; Seawater after the preliminary desalination obtains a kind of as clear as crystal, pure tasty and refreshing weakly alkaline mineralized water after ion exchange unit of natural mineral for seawater desalination, filtration equipment for clarifying of natural mineral for seawater desalination and ultraviolet radiation for sterilizing and disinfecting device combined treatment, canned is finished product; (4) seawater after the preliminary desalination, is discharged from the waste sludge discharge pipe because the effect of gravity sinks in the settling chamber carrying out the waste residue that ion-exchange and precipitation clarification back produce; Through the trace impurity that the aqueous solution after the ion-exchange produces in carrying out the adsorption filtration process,, discharge from wastewater discharge pipe because the effect of gravity sinks in the settling chamber.
CNB2007100211110A 2007-03-29 2007-03-29 Technique for seawater desalination late stage purification treatment Expired - Fee Related CN100503481C (en)

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CNB2007100211110A CN100503481C (en) 2007-03-29 2007-03-29 Technique for seawater desalination late stage purification treatment

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CN100503481C CN100503481C (en) 2009-06-24

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103771660A (en) * 2014-01-16 2014-05-07 江苏大学 Rural domestic sewage treatment system
CN105461124A (en) * 2014-08-26 2016-04-06 李雄春 Seawater is converted into mineral direct drinking water equipment
CN106745905A (en) * 2017-01-23 2017-05-31 福建海西滤水龙头研究中心有限公司 A kind of desalinization integral type composite filter element
CN111392934A (en) * 2020-03-16 2020-07-10 青岛百发海水淡化有限公司 Double-membrane seawater desalination process
CN111392935A (en) * 2020-03-16 2020-07-10 青岛百发海水淡化有限公司 Mineralization device in double-membrane seawater desalination process
CN116161831A (en) * 2023-04-23 2023-05-26 青岛市市政工程设计研究院有限责任公司 Natural mineral sea water desalination, purification and filtration device

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103771660A (en) * 2014-01-16 2014-05-07 江苏大学 Rural domestic sewage treatment system
CN103771660B (en) * 2014-01-16 2015-08-26 江苏大学 A kind of rural domestic sewage treatment system
CN105461124A (en) * 2014-08-26 2016-04-06 李雄春 Seawater is converted into mineral direct drinking water equipment
CN106745905A (en) * 2017-01-23 2017-05-31 福建海西滤水龙头研究中心有限公司 A kind of desalinization integral type composite filter element
CN111392934A (en) * 2020-03-16 2020-07-10 青岛百发海水淡化有限公司 Double-membrane seawater desalination process
CN111392935A (en) * 2020-03-16 2020-07-10 青岛百发海水淡化有限公司 Mineralization device in double-membrane seawater desalination process
CN116161831A (en) * 2023-04-23 2023-05-26 青岛市市政工程设计研究院有限责任公司 Natural mineral sea water desalination, purification and filtration device

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Assignee: Jiangsu Golden Stone Attapulgite R&D Center

Assignor: Tao Tao

Contract record no.: 2010320001100

Denomination of invention: Technique for treating purification in the late stage of seawater desalination

Granted publication date: 20090624

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Termination date: 20120329