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CN101043784B - hybrid plasma reactor - Google Patents

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CN101043784B
CN101043784B CN2007100868758A CN200710086875A CN101043784B CN 101043784 B CN101043784 B CN 101043784B CN 2007100868758 A CN2007100868758 A CN 2007100868758A CN 200710086875 A CN200710086875 A CN 200710086875A CN 101043784 B CN101043784 B CN 101043784B
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CN101043784A (en
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李元默
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Weihai Dianmei Shiguang Electromechanical Co Ltd
DMS Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31105Etching inorganic layers
    • H01L21/31111Etching inorganic layers by chemical means
    • H01L21/31116Etching inorganic layers by chemical means by dry-etching
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    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
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    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/3065Plasma etching; Reactive-ion etching
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    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32082Radio frequency generated discharge
    • H01J37/32091Radio frequency generated discharge the radio frequency energy being capacitively coupled to the plasma
    • HELECTRICITY
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    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32082Radio frequency generated discharge
    • H01J37/321Radio frequency generated discharge the radio frequency energy being inductively coupled to the plasma
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32082Radio frequency generated discharge
    • H01J37/32137Radio frequency generated discharge controlling of the discharge by modulation of energy
    • H01J37/32155Frequency modulation
    • H01J37/32165Plural frequencies
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    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67017Apparatus for fluid treatment
    • H01L21/67063Apparatus for fluid treatment for etching
    • H01L21/67069Apparatus for fluid treatment for etching for drying etching

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Abstract

Provided is a hybrid plasma reactor. The hybrid plasma reactor includes an ICP (Inductively Coupled Plasma) source unit and a bias RF (Radio Frequency) power supply unit. The ICP source unit includes a chamber, an antenna coil unit, and a source power supply unit. The chamber includes a chamber body whose top is opened and a dielectric window covering the opened top of the chamber body. The antenna coil unit is disposed outside of the dielectric window. The source power supply unit supplies a source power to the antenna coil unit. The bias RF power supply unit supplies a bias RF power to a cathode. The cathode is installed within the chamber and mounts a target wafer on its top.

Description

混合等离子体反应器 hybrid plasma reactor

技术领域technical field

本发明涉及一种在半导体制造工艺中使用的设备,并且尤其涉及等离子体反应器。 The present invention relates to an apparatus used in a semiconductor manufacturing process, and in particular to a plasma reactor. the

背景技术Background technique

通常地,使用等离子体执行干蚀刻工艺的等离子体反应器依赖于在腔室内产生等离子体的方法而被分类为容性耦合等离子体(CCP)类型等离子体反应器和感性耦合等离子体(ICP)类型等离子体反应器。如同本领域中所公知的,在CCP类型等离子体反应器中,等离子体腔室内的离子流能量随着提供给上电极或者阴极的射频(RF)功率的频率变低而成比例的提高。并且,在CCP类型等离子体反应器中,离子密度随着提供给上位电极或者阴极的RF功率的频率变高而增加。在ICP类型等离子体反应器中,随着提供给天线线圈的RF功率增加可以在腔室内提供低电离条件和高电离条件。反应气体的电离程度(degree of dissociation)在低电离条件中更低,并且在高电离条件中更高。在ICP类型等离子体反应器在各个低电离条件和高电离条件下执行蚀刻工艺时,目标晶圆显示出互不相同的物理属性。更具体的说,当ICP类型等离子体反应器在低电离条件下执行蚀刻工艺时,目标晶圆显示出类似于当CCP类型等离子体反应器执行蚀刻工艺时的物理属性。当ICP类型等离子体反应器在高电离条件下执行蚀刻工艺时,随着提供给阴极的偏移RF功率的频率变得更低,提供给天线线圈的RF功率的增加导致腔室内的等离子体离子能量的突然降低。 Generally, plasma reactors that perform a dry etching process using plasma are classified into a capacitively coupled plasma (CCP) type plasma reactor and an inductively coupled plasma (ICP) depending on a method of generating plasma in a chamber. type plasma reactor. As is known in the art, in a CCP type plasma reactor, the ion flow energy within the plasma chamber increases proportionally as the frequency of the radio frequency (RF) power supplied to the top electrode or cathode decreases. And, in the CCP type plasma reactor, the ion density increases as the frequency of RF power supplied to the upper electrode or the cathode becomes higher. In an ICP type plasma reactor, low ionization conditions and high ionization conditions can be provided within the chamber as the RF power supplied to the antenna coil is increased. The degree of dissociation of the reactant gas is lower in low ionization conditions and higher in high ionization conditions. When an ICP type plasma reactor performs an etching process under respective low ionization conditions and high ionization conditions, a target wafer exhibits physical properties different from each other. More specifically, when an ICP type plasma reactor performs an etching process under low ionization conditions, a target wafer exhibits physical properties similar to when a CCP type plasma reactor performs an etching process. When an ICP type plasma reactor performs an etching process under high ionization conditions, as the frequency of the offset RF power supplied to the cathode becomes lower, an increase in the RF power supplied to the antenna coil results in plasma ions in the chamber A sudden drop in energy. the

对于使用等离子体实现的干蚀刻工艺,存在绝缘薄膜(氧化物)蚀刻工艺和聚乙烯(poly)/金属蚀刻工艺。绝缘薄膜蚀刻工艺主要基于物理蚀刻 工艺。因此,绝缘薄膜主要使用窄隙CCP类型等离子体反应器进行蚀刻,其中多频率RF功率被提供给上电极或者阴极。这种CCP类型等离子体反应器的优点在于能够使用高电场产生高能量离子。然而,CCP类型等离子体反应器导致了由于离子碰撞引起的工艺装置损坏,并且导致了由于高等离子体电势的特性引发的电弧问题。低电离降低了实时腔室清洁(ICC)的效率,因此,腔室清洁之间平均时间(MTBC)实现为很短。CCP类型等离子体反应器在硬件设计和提供高频率功率给上电极或者阴极所需的成本方面存在问题。 As for the dry etching process realized using plasma, there are insulating film (oxide) etching process and polyethylene (poly)/metal etching process. The insulating film etching process is mainly based on the physical etching process. Therefore, an insulating thin film is mainly etched using a narrow-gap CCP type plasma reactor in which multi-frequency RF power is supplied to an upper electrode or a cathode. The advantage of this CCP type plasma reactor is the ability to generate high energy ions using high electric fields. However, CCP type plasma reactors cause process equipment damage due to ion collisions, and cause arcing problems due to the high plasma potential characteristic. Low ionization reduces the efficiency of real-time chamber cleaning (ICC), therefore, the mean time between chamber cleanings (MTBC) is realized to be very short. The CCP type plasma reactor has problems in terms of hardware design and cost required to supply high frequency power to the upper electrode or cathode. the

与绝缘薄膜蚀刻工艺不同,通常基于相对的化学蚀刻方式的聚乙烯/金属蚀刻工艺主要使用ICP类型等离子体反应器。这是因为ICP类型等离子体反应器可以独立控制腔室内的等离子体离子密度和能量,促进在低压下产生高密度和大规模的等离子体,并且通过小的等离子体离子能量而充分地蚀刻设备,从而降低设备损耗。 Unlike the insulating film etching process, the polyethylene/metal etching process, which is generally based on the relative chemical etching method, mainly uses an ICP type plasma reactor. This is because the ICP type plasma reactor can independently control the plasma ion density and energy in the chamber, promote high-density and large-scale plasma generation at low pressure, and sufficiently etch devices with small plasma ion energy, Thereby reducing equipment loss. the

实现ICP类型等离子体反应器的非常重要的参数为由于提供给天线线圈的高电压导致的介电窗口的损坏,高/低等离子体离子密度以及大范围区域中的均匀性,过量基团浓度控制,可调离子能量,以及宽的离子能量分布。 Very important parameters to realize ICP type plasma reactors are damage of dielectric window due to high voltage supplied to antenna coil, high/low plasma ion density and uniformity in a wide area, excess radical concentration control , adjustable ion energy, and wide ion energy distribution. the

然而,目前为止制造的ICP类型等离子体反应器可以产生高密度等离子体离子,但是不能控制过量基团的浓度,不能控制等离子体离子能量,并且不能扩展等离子体离子能量分布。因此,ICP类型等离子体反应器显示出了比CCP类型等离子体反应器更差的工艺性能,尽管它比CCP类型等离子体反应器更有效。因此,ICP类型等离子体反应器很难在保证很高的光敏(PR)选择性的同时执行高纵横比工艺。 However, the ICP-type plasma reactors manufactured so far can generate high-density plasma ions, but cannot control the concentration of excess radicals, cannot control the plasma ion energy, and cannot expand the plasma ion energy distribution. Therefore, the ICP type plasma reactor shows worse process performance than the CCP type plasma reactor although it is more efficient than the CCP type plasma reactor. Therefore, it is difficult for an ICP type plasma reactor to perform a high aspect ratio process while ensuring high photosensitive (PR) selectivity. the

在ICP类型等离子体反应器执行干蚀刻工艺的情况下,在提供低频RF功率给阴极时反应气体的高电离和源电源功率增大导致等离子体离子能量的突然降低。因此会出现某些现象,例如蚀刻停止、腔室匹配、低PR选择性、以及窄的工艺窗口。 In the case of an ICP type plasma reactor performing a dry etching process, high ionization of a reaction gas and an increase in source power supply cause a sudden decrease in plasma ion energy when low frequency RF power is supplied to a cathode. As a result certain phenomena such as etch stop, chamber matching, low PR selectivity, and narrow process window occur. the

发明内容Contents of the invention

本发明示例实施例的一个方面是为了至少解决所述问题和/或缺陷,并且至少提供下述优点。因此,本发明示例实施例的一个方面提供了一种混合等离子体反应器,用于提供混合了高频RF功率和低频RF功率的偏移RF功率给阴极并且控制提供给天线线圈的源电源,从而在提供低频RF功率给阴极时补偿由于源电源功率增大导致的等离子体离子能量的突然降低,并且将等离子体离子密度和能量维持在设定范围之内。 An aspect of exemplary embodiments of the present invention is to address at least the problems and/or disadvantages and to provide at least the advantages described below. Accordingly, an aspect of an exemplary embodiment of the present invention provides a hybrid plasma reactor for supplying offset RF power mixed with high frequency RF power and low frequency RF power to a cathode and controlling source power supplied to an antenna coil, Therefore, when the low frequency RF power is supplied to the cathode, the sudden decrease of the plasma ion energy due to the increase of the source power is compensated, and the plasma ion density and energy are maintained within the set range. the

根据本发明示例实施例的一个方面,提供了一种混合等离子体反应器。所述混合等离子体反应器包括ICP(感性耦合等离子体)源单元和偏移RF(射频)电源单元。所述ICP源单元包括腔室,天线线圈单元,以及源电源单元。所述腔室包括顶部开口(opened)的腔室主体以及覆盖所述腔室主体的开口顶部的介电窗口。所述天线线圈单元置于所述介电窗口外侧。所述源电源单元提供源电源给所述天线线圈单元。所述偏移RF电源单元提供偏移RF功率给阴极。所述阴极安装在所述腔室内,并且在阴极顶部上安装目标晶圆。当大于设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子密度大于当小于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子密度。当小于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子能量大于当大于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子能量。为了提高所述设定功率并且扩展所述源电源的可调范围,所述偏移RF电源单元提供混合了高频RF功率和低频RF功率的偏移RF功率给阴极,从而对当提供给所述天线线圈单元的源电源功率增加到大于所述设定功率时发生的所述腔室内的等离子体离子能量突然降低进行补偿,或者从而将所述腔室内的等离子体离子密度和能量保持在设定范围内。 According to an aspect of an exemplary embodiment of the present invention, a hybrid plasma reactor is provided. The hybrid plasma reactor includes an ICP (Inductively Coupled Plasma) source unit and an offset RF (Radio Frequency) power supply unit. The ICP source unit includes a chamber, an antenna coil unit, and a source power unit. The chamber includes an open top chamber body and a dielectric window covering the open top of the chamber body. The antenna coil unit is placed outside the dielectric window. The source power unit supplies source power to the antenna coil unit. The offset RF power supply unit provides offset RF power to the cathode. The cathode is mounted within the chamber, and a target wafer is mounted on top of the cathode. When the source power greater than the set power is supplied to the antenna coil unit, the plasma ion density in the chamber is greater than that in the chamber when the source power less than the set power is supplied to the antenna coil unit. plasma ion density. When the source power less than the set power is supplied to the antenna coil unit, the plasma ion energy in the chamber is greater than when the source power greater than the set power is supplied to the antenna coil unit. Plasma ion energy in the chamber. In order to increase the set power and expand the adjustable range of the source power supply, the offset RF power supply unit provides offset RF power mixed with high-frequency RF power and low-frequency RF power to the cathode, so as to The power of the source power supply of the antenna coil unit increases to more than the set power to compensate for the sudden decrease in the plasma ion energy in the chamber, or thereby maintain the plasma ion density and energy in the chamber at the set value within a certain range. the

根据本发明示例实施例的另一个方面,提供了一种混合等离子体反应器。所述混合等离子体反应器包括ICP源单元和高频RF电源单元。所述ICP源单元包括腔室,天线线圈单元,以及源电源单元。所述腔室包括顶部开口的腔室主体以及覆盖所述腔室主体的开口顶部的介电窗口。所述天线线圈单元置于所述介电窗口外侧。所述源电源单元提供源电源给所述天线线圈单元。所述高频RF电源单元提供高频RF功率给阴极。所述阴极安装在所述腔室内,并且在阴极顶部上安装目标晶圆。低频RF电源单元并行于高频RF电源单元连接到所述阴极,并且提供低频RF功率给所述阴极。当大于设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子密度大于当小于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子密度。当小于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子能量大于当大于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子能量。为了提高所述设定功率并且扩展所述源电源的可调范围,所述高频RF电源单元和低频RF电源单元一起工作并且提供混合了高频RF功率和低频RF功率的偏移RF功率给所述阴极,从而对当提供给所述天线线圈单元的源电源功率增加到大于所述设定功率时发生的所述腔室内的等离子体离子能量突然降低进行补偿,或者从而将所述腔室内的等离子体离子密度和能量保持在设定范围内。According to another aspect of example embodiments of the present invention, a hybrid plasma reactor is provided. The hybrid plasma reactor includes an ICP source unit and a high frequency RF power supply unit. The ICP source unit includes a chamber, an antenna coil unit, and a source power unit. The chamber includes an open top chamber body and a dielectric window covering the open top of the chamber body. The antenna coil unit is placed outside the dielectric window. The source power unit supplies source power to the antenna coil unit. The high frequency RF power supply unit provides high frequency RF power to the cathode. The cathode is mounted within the chamber, and a target wafer is mounted on top of the cathode. A low-frequency RF power supply unit is connected to the cathode in parallel to the high-frequency RF power supply unit, and supplies low-frequency RF power to the cathode. When the source power greater than the set power is supplied to the antenna coil unit, the plasma ion density in the chamber is greater than that in the chamber when the source power less than the set power is supplied to the antenna coil unit. plasma ion density. When the source power less than the set power is supplied to the antenna coil unit, the plasma ion energy in the chamber is greater than when the source power greater than the set power is supplied to the antenna coil unit. Plasma ion energy in the chamber. In order to increase the set power and expand the adjustable range of the source power supply, the high-frequency RF power supply unit and the low-frequency RF power supply unit work together and provide offset RF power mixed with high-frequency RF power and low-frequency RF power to the cathode, thereby compensating for a sudden drop in plasma ion energy in the chamber that occurs when the source power supplied to the antenna coil unit is increased above the set power, or thereby turning the chamber The plasma ion density and energy are kept within the set range.

根据本发明示例实施例的又一个方面,提供了一种混合等离子体反应器。所述混合等离子体反应器包括ICP源单元,高频RF电源单元,低频RF电源单元,以及源电源切换单元。所述ICP源单元包括腔室,天线线圈单元,以及源电源单元。所述腔室包括顶部开口的腔室主体以及覆盖所述腔室主体的开口顶部的介电窗口。所述天线线圈单元置于所述介电窗口外侧。所述源电源单元提供源电源给所述天线线圈单元。所述高频RF电源单元提供高频RF功率给阴极。所述阴极安装在所述腔室内,并且在阴极顶部上安装目标晶 圆。低频RF电源单元并行于高频RF电源单元连接到所述阴极,并且提供低频RF功率给所述阴极。所述源电源切换单元并行于所述高频RF电源单元连接到所述阴极。所述源电源切换单元切换开启以通过所述源电源切换单元将所述阴极选择性地连接至接地,从而从所述源电源单元产生的高频RF功率被选择性地提供给所述阴极。 According to yet another aspect of example embodiments of the present invention, a hybrid plasma reactor is provided. The hybrid plasma reactor includes an ICP source unit, a high frequency RF power supply unit, a low frequency RF power supply unit, and a source power switching unit. The ICP source unit includes a chamber, an antenna coil unit, and a source power unit. The chamber includes an open top chamber body and a dielectric window covering the open top of the chamber body. The antenna coil unit is placed outside the dielectric window. The source power unit supplies source power to the antenna coil unit. The high frequency RF power supply unit provides high frequency RF power to the cathode. The cathode is mounted within the chamber and a target wafer is mounted on top of the cathode. A low-frequency RF power supply unit is connected to the cathode in parallel to the high-frequency RF power supply unit, and supplies low-frequency RF power to the cathode. The source power switching unit is connected to the cathode in parallel with the high frequency RF power supply unit. The source power switching unit is switched on to selectively connect the cathode to ground through the source power switching unit so that high frequency RF power generated from the source power unit is selectively supplied to the cathode. the

当所述阴极通过所述源电源切换单元连接到接地时形成闭合回路,所述闭合回路包括所述源电源单元,所述天线线圈单元,所述阴极,所述源电源切换单元以及接地。所述源电源是具有高于所述高频RF功率频率的频率的RF功率、具有低于所述低频RF功率频率的频率的RF功率、以及具有所述低频RF功率频率和高频RF功率频率之间的频率的RF功率中的任何一者。 When the cathode is connected to the ground through the source power switching unit, a closed loop is formed, and the closed loop includes the source power unit, the antenna coil unit, the cathode, the source power switching unit and ground. The source power is RF power having a frequency higher than the high frequency RF power frequency, RF power having a frequency lower than the low frequency RF power frequency, and the low frequency RF power frequency and the high frequency RF power frequency any one of the frequencies in between the RF power. the

当大于设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子密度大于当小于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子密度。当小于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子能量大于当大于所述设定功率的源电源被提供给所述天线线圈单元时所述腔室内的等离子体离子能量。 When the source power greater than the set power is supplied to the antenna coil unit, the plasma ion density in the chamber is greater than that in the chamber when the source power less than the set power is supplied to the antenna coil unit. plasma ion density. When the source power less than the set power is supplied to the antenna coil unit, the plasma ion energy in the chamber is greater than when the source power greater than the set power is supplied to the antenna coil unit. Plasma ion energy in the chamber. the

为了提高所述设定功率并且扩展所述源电源的可调范围,所述高频RF电源单元、所述低频RF电源单元以及所述源电源切换单元一起工作并且提供通过将高频RF功率和低频RF功率与所述源电源混合而获得的偏移RF功率给所述阴极,从而对当提供给所述天线线圈单元的源电源功率增加到大于所述设定功率时发生的所述腔室内的等离子体离子能量突然降低进行补偿,或者从而将所述腔室内的等离子体离子密度和能量保持在设定范围内。 In order to increase the set power and expand the adjustable range of the source power supply, the high frequency RF power supply unit, the low frequency RF power supply unit and the source power switching unit work together and provide The offset RF power obtained by mixing the low-frequency RF power with the source power is supplied to the cathode, thereby affecting the inside of the chamber that occurs when the source power supplied to the antenna coil unit is increased above the set power. to compensate for the sudden decrease in plasma ion energy, or thereby maintain the plasma ion density and energy in the chamber within a set range. the

附图说明Description of drawings

结合附图帮助理解,本发明的上述和其他目标、特征和优点通过下面的 结合附图的详细描述可以更加明白,其中: In conjunction with the accompanying drawings to help understand, the above-mentioned and other objects, features and advantages of the present invention can be more clearly understood through the following detailed description in conjunction with the accompanying drawings, wherein:

图1显示了根据本发明第一示例实施例的等离子体反应器的构造; Fig. 1 shows the construction of the plasma reactor according to the first exemplary embodiment of the present invention;

图2显示了图1所示的天线线圈单元的截面图,以及当提供源电源给天线线圈单元时在天线线圈单元周围产生的磁场的分布; Fig. 2 shows the sectional view of the antenna coil unit shown in Fig. 1, and the distribution of the magnetic field generated around the antenna coil unit when source power is supplied to the antenna coil unit;

图3是显示依赖于在图2所示的天线线圈单元中包含的初级天线线圈组和次级天线线圈组的各个半径(R)以及初级天线线圈组和次级天线线圈组之间的长度(L)的磁场强度的图示; FIG. 3 is a diagram showing the dependence on each radius (R) of the primary antenna coil group and the secondary antenna coil group contained in the antenna coil unit shown in FIG. 2 and the length between the primary antenna coil group and the secondary antenna coil group ( Graphical representation of the magnetic field strength of L);

图4为显示通过图1所示的等离子体反应器实现的蚀刻程序的流程图; Figure 4 is a flow chart showing the etching procedure achieved by the plasma reactor shown in Figure 1;

图5显示了根据本发明第二示例实施例的等离子体反应器的构造; Fig. 5 has shown the construction according to the plasma reactor of the second exemplary embodiment of the present invention;

图6为显示通过图5所示的等离子体反应器实现的蚀刻程序的流程图; Figure 6 is a flow chart showing the etching procedure achieved by the plasma reactor shown in Figure 5;

图7显示了根据本发明第三示例实施例的等离子体反应器的构造; Fig. 7 shows the construction of the plasma reactor according to the third exemplary embodiment of the present invention;

图8为显示通过图7所示的等离子体反应器实现的蚀刻程序的流程图; Figure 8 is a flow chart showing the etching procedure achieved by the plasma reactor shown in Figure 7;

图9为显示依赖于源电源功率增加的等离子体离子密度特性的图示; Figure 9 is a graph showing the plasma ion density characteristics dependent on the source power increase;

图10是显示根据本发明的当提供2MHz的偏移RF功率给等离子体反应器的阴极时阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示; 10 is a graph showing the self-offset variation (-VDC) formed in the cathode relative to the source supply power variation when an offset RF power of 2 MHz is provided to the cathode of a plasma reactor according to the present invention;

图11是显示根据本发明的当提供12.56MHz的偏移RF功率给等离子体反应器的阴极时阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示; 11 is a graph showing the self-offset variation (-VDC) formed in the cathode relative to the source power supply power variation when an offset RF power of 12.56 MHz is provided to the cathode of a plasma reactor according to the present invention;

图12是显示根据本发明的当提供27.12MHz的偏移RF功率给等离子体反应器的阴极时阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示; 12 is a graph showing the self-offset variation (-VDC) formed in the cathode relative to the source power supply power variation when an offset RF power of 27.12 MHz is provided to the cathode of a plasma reactor in accordance with the present invention;

图13是显示根据本发明的在分别提供单频率偏移RF功率和混合频率偏移RF功率给等离子体反应器的阴极的情况下阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示; 13 is a graph showing the self-offset variation (-VDC) formed in the cathode relative to the source power in the case of providing single frequency offset RF power and mixed frequency offset RF power to the cathode of the plasma reactor, respectively, according to the present invention. Graphical representation of power variation;

图14是显示根据本发明的当提供600W的源电源功率给等离子体反应器 的天线线圈单元时蚀刻速度变化相对于提供给阴极的偏移RF功率的频率混合比率的变化的图示;以及 14 is a graph showing the change in etching rate relative to the change in the frequency mixing ratio of the offset RF power supplied to the cathode when a source power supply power of 600W is provided to the antenna coil unit of the plasma reactor according to the present invention; and

图15是显示根据本发明的当提供1500W的源电源功率给等离子体反应器的天线线圈单元时蚀刻速度变化相对于提供给阴极的偏移RF功率的频率混合比率的变化的图示。 15 is a graph showing a change in etching rate with respect to a change in frequency mixing ratio of offset RF power supplied to a cathode when a source power supply of 1500 W is supplied to an antenna coil unit of a plasma reactor according to the present invention. the

在所有附图中,相同附图参考数字表示相同元件、特征和结构。 Throughout the drawings, the same drawing reference numbers represent the same elements, features, and structures. the

具体实施方式Detailed ways

现在参考附图更加详细的描述本发明的示例实施例。在下面的描述中,为了简化起见省略在此包含的公知功能和结构的详细描述。 Exemplary embodiments of the present invention will now be described in more detail with reference to the accompanying drawings. In the following description, detailed descriptions of well-known functions and constructions incorporated herein are omitted for simplicity. the

本发明提供制造半导体、液晶二极管(LCD)以及其他集成电路的工艺所需的等离子体属性(例如可调等离子体离子密度,可调离子能量分布,可调离子能量,可调基团,以及低离子损耗等离子体)的混合类型等离子体生成设备以及方法。这些等离子体属性可以使用多天线线圈结构、柱体类型介电窗口、在腔室上方提供的感性耦合等离子体(ICP)源单元以及提供给阴极的混合频率偏移而控制。 The present invention provides plasma properties (such as tunable plasma ion density, tunable ion energy distribution, tunable ion energy, tunable radicals, and low Ion-depleting plasma) hybrid type plasma generation apparatus and method. These plasma properties can be controlled using a multi-antenna coil structure, a pillar type dielectric window, an inductively coupled plasma (ICP) source unit provided above the chamber, and a hybrid frequency offset provided to the cathode. the

图1显示了根据本发明第一示例实施例的等离子体反应器的构造。参考图1,等离子体反应器包括感性耦合等离子体(ICP)源单元1,以及偏移RF电源单元,偏移RF电源单元包括低频射频(RF)电源单元20和高频RF电源单元30。ICP源单元1包括腔室5,天线线圈单元7,以及源电源单元10。腔室5包括腔室主体13,以及柱体类型介电窗口11。腔室主体13在其顶部开口。介电窗口11覆盖腔室主体13的开口顶部。天线线圈单元7包括初级天线线圈组21和次级天线线圈组23。初级天线线圈组21设置在介电窗口11外侧位于介电窗口11周围的上部。次级天线线圈组23设置在介电窗口11外侧位于介电窗口11周围的下部。屏蔽部分3依附到腔室主体13的外围 侧壁的上部,环绕介电窗口11和天线线圈单元7以将介电窗口11和天线线圈单元7与外部屏蔽。 FIG. 1 shows the configuration of a plasma reactor according to a first exemplary embodiment of the present invention. Referring to FIG. 1 , a plasma reactor includes an inductively coupled plasma (ICP) source unit 1 , and an offset RF power unit including a low frequency radio frequency (RF) power unit 20 and a high frequency RF power unit 30 . The ICP source unit 1 includes a chamber 5 , an antenna coil unit 7 , and a source power unit 10 . The chamber 5 includes a chamber body 13 , and a pillar type dielectric window 11 . The chamber main body 13 is open at its top. A dielectric window 11 covers the open top of the chamber body 13 . The antenna coil unit 7 includes a primary antenna coil group 21 and a secondary antenna coil group 23 . The primary antenna coil group 21 is disposed outside the dielectric window 11 at an upper portion around the dielectric window 11 . The secondary antenna coil group 23 is disposed outside the dielectric window 11 at a lower portion around the dielectric window 11 . The shielding part 3 is attached to the upper portion of the peripheral side wall of the chamber main body 13, surrounds the dielectric window 11 and the antenna coil unit 7 to shield the dielectric window 11 and the antenna coil unit 7 from the outside. the

介电窗口11在其顶部具有气体注入口31。气体注入系统(未显示)通过气体注入口31注入反应气体到腔室5中。阴极部件支撑15设置在腔室5内。阴极部件支撑15物理固定到腔室主体13,并且电接地。阴极17置于阴极部件支撑15上。绝缘体19置于阴极部件支撑15和阴极17之间。绝缘体19在阴极部件支撑15和阴极17之间进行电绝缘。晶圆(W)作为加工目标被安装在阴极17上。更具体的说,使用在阴极17上设置的陶瓷静电卡盘(CESC)对晶圆(W)进行固定。 The dielectric window 11 has a gas injection port 31 at its top. A gas injection system (not shown) injects reaction gas into the chamber 5 through the gas injection port 31 . A cathode component support 15 is disposed within the chamber 5 . The cathode component support 15 is physically fixed to the chamber body 13 and is electrically grounded. The cathode 17 is placed on the cathode member support 15 . An insulator 19 is interposed between the cathode part support 15 and the cathode 17 . The insulator 19 electrically insulates between the cathode part support 15 and the cathode 17 . A wafer (W) is mounted on the cathode 17 as a processing target. More specifically, the wafer (W) is fixed using a ceramic electrostatic chuck (CESC) provided on the cathode 17 . the

源电源单元10提供各个源电源给初级天线线圈组21和次级天线线圈组23。源电源单元10包括源阻抗匹配电路22用于源阻抗匹配,以及源高频发生器26。源阻抗匹配电路22将初级天线线圈组21和次级天线线圈组23与源高频发生器26连接。源高频发生器26连接到接地。当源电源单元10提供源电源给初级天线线圈组21和次级天线线圈组23,在初级天线线圈组21和次级天线线圈组23附近产生磁场。因此,在腔室5内感应RF电场。 The source power supply unit 10 supplies respective source power supplies to the primary antenna coil group 21 and the secondary antenna coil group 23 . The source power supply unit 10 includes a source impedance matching circuit 22 for source impedance matching, and a source high frequency generator 26 . A source impedance matching circuit 22 connects the primary antenna coil set 21 and the secondary antenna coil set 23 with a source high frequency generator 26 . The source high frequency generator 26 is connected to ground. When the source power supply unit 10 supplies source power to the primary antenna coil group 21 and the secondary antenna coil group 23 , a magnetic field is generated near the primary antenna coil group 21 and the secondary antenna coil group 23 . Accordingly, an RF electric field is induced within the chamber 5 . the

低频RF电源单元20是偏移RF电源单元,提供低频RF功率给阴极17。低频RF电源单元20包括偏移阻抗匹配电路/低通滤波器(LF匹配/LPF)24和偏移低频发生器27。LF匹配/LPF 24匹配阻抗并且选择性地仅通过低频RF功率。偏移低频发生器27产生低频RF功率。 The low-frequency RF power supply unit 20 is an offset RF power supply unit that supplies low-frequency RF power to the cathode 17 . The low-frequency RF power supply unit 20 includes an offset impedance matching circuit/low-pass filter (LF matching/LPF) 24 and an offset low-frequency generator 27 . LF Matching/LPF 24 matches impedance and selectively passes only low frequency RF power. Offset low frequency generator 27 generates low frequency RF power. the

高频RF电源单元30包括偏移阻抗匹配电路/高通滤波器(HF匹配/HPF)25和偏移高频发生器28。HF匹配/HPF 25匹配阻抗并且选择性地仅通过高频RF功率。偏移高频发生器28产生高频RF功率。偏移RF功率是低频RF功率和高频RF功率的混合,在低频RF电源单元20和高频RF电源单元30一起工作时被提供给阴极17。 The high-frequency RF power supply unit 30 includes an offset impedance matching circuit/high-pass filter (HF matching/HPF) 25 and an offset high-frequency generator 28 . HF Matching/HPF 25 matches impedance and selectively passes only high frequency RF power. Offset high frequency generator 28 generates high frequency RF power. The offset RF power is a mixture of low frequency RF power and high frequency RF power, and is supplied to the cathode 17 when the low frequency RF power supply unit 20 and the high frequency RF power supply unit 30 work together. the

当大于设定功率(下面称之为“转折点功率”)的源电源功率被提供给 天线线圈单元7时腔室5内的等离子体离子密度远大于当提供小于设定功率的源电源功率给天线线圈单元7时腔室5内的离子密度。转折点功率是划分低电离区域和高电离区域的标准。参考图9,当大于转折点功率的源电源功率被提供给天线线圈单元7时的反应气体的电离程度远大于当提供小于转折点功率的源电源功率被提供给天线线圈单元7时的反应气体的电离程度。例如,在加工具有200mm直径的晶圆的等离子体反应器中,转折点功率可以设置在大约500W至700W的范围内。转折点功率依赖于等离子体反应器的尺寸、类型和工艺条件可以更大或者更小。 When the source power supply power greater than the set power (hereinafter referred to as "turning point power") is provided to the antenna coil unit 7, the plasma ion density in the chamber 5 is much greater than when the source power supply power less than the set power is provided to the antenna Coil unit 7 is the ion density in chamber 5 . The turning point power is the criterion for dividing the low ionization region and the high ionization region. Referring to FIG. 9, the degree of ionization of the reaction gas when the source power supply power greater than the turning point power is supplied to the antenna coil unit 7 is much greater than the ionization of the reaction gas when the source power supply power less than the turning point power is supplied to the antenna coil unit 7. degree. For example, in a plasma reactor processing a wafer having a diameter of 200mm, the breakpoint power may be set in the range of approximately 500W to 700W. The breakpoint power can be larger or smaller depending on the size, type and process conditions of the plasma reactor. the

当小于设定功率的源电源功率被提供给天线线圈单元7时腔室5内的等离子体离子能量远大于当提供大于设定功率的源电源功率给天线线圈单元7时腔室5内的离子能量。当包括低频RF电源单元20和高频RF电源单元30的偏移RF电源单元提供混合了低频RF功率和高频RF功率的偏移RF功率给阴极17时,设定功率可以提高。因此,低电离区域中源电源功率的可调范围可以进一步扩展。例如,当仅提供低频RF功率给阴极17并且提供大于设定功率的源电源功率给天线线圈单元7时会发生腔室5内的等离子体离子能量突然降低的现象。并且,当仅提供高频RF功率给阴极17时,腔室5内的等离子离子能量降低到使得尽管提高源电源功率仍然不能正常进行蚀刻工艺的程度。然而,当提供混合了低频RF功率和高频RF功率的偏移RF功率给阴极17时,腔室5内的等离子体离子能量的突降可以被补偿,并且等离子体离子能量可以保持在设定范围之内,能够正常进行蚀刻工艺。 When the source power supply power less than the set power is provided to the antenna coil unit 7, the plasma ion energy in the chamber 5 is much greater than the ions in the chamber 5 when the source power supply power greater than the set power is provided to the antenna coil unit 7 energy. When the offset RF power supply unit including the low frequency RF power supply unit 20 and the high frequency RF power supply unit 30 supplies offset RF power mixed with low frequency RF power and high frequency RF power to the cathode 17, the set power can be increased. Therefore, the adjustable range of source power in the low ionization region can be further expanded. For example, when only low-frequency RF power is supplied to the cathode 17 and a source power greater than a set power is supplied to the antenna coil unit 7, a phenomenon in which plasma ion energy in the chamber 5 suddenly decreases occurs. Also, when only high-frequency RF power is supplied to the cathode 17, the plasma ion energy in the chamber 5 is reduced to such an extent that the etching process cannot be normally performed despite increasing the power of the source power. However, when the offset RF power mixed with the low frequency RF power and the high frequency RF power is supplied to the cathode 17, the sudden drop of the plasma ion energy in the chamber 5 can be compensated, and the plasma ion energy can be maintained at the set Within the range, the etching process can be performed normally. the

根据本发明,ICP等离子体源单元1包括天线线圈单元7。如图2和图3所示,天线线圈单元7提供了均匀磁场属性和图9所示的等离子体属性。这样可以选择性的使用低电离和高电离区域,以及稍后描述的均匀离子密度。 According to the present invention, the ICP plasma source unit 1 includes an antenna coil unit 7 . As shown in FIGS. 2 and 3 , the antenna coil unit 7 provides uniform magnetic field properties and plasma properties as shown in FIG. 9 . This allows selective use of low and high ionization regions, as well as uniform ion density as described later. the

柱体介电窗口11保证了在主(bulk)等离子体和阴极17上的陶瓷静电卡盘(CESC)(未显示)之间的恒定距离从而放置作为工艺目标的晶圆,从 而支持独立控制等离子体离子密度和能量。因此,柱体介电窗口11最小化了物理损耗,同时支持有效蚀刻加工目标。 The cylindrical dielectric window 11 ensures a constant distance between the bulk plasma and the ceramic electrostatic chuck (CESC) (not shown) on the cathode 17 to place the wafer as process target, thereby supporting independent control Plasma ion density and energy. Thus, the pillar dielectric window 11 minimizes physical losses while supporting efficient etch process objectives. the

天线线圈单元7设置在柱体介电窗口11外侧。柱体介电窗口11具有顶部平坦表面的结构。气体注入系统设在介电窗口11中提供的气体注入口31处。气体注入系统通过排放孔有效排出蚀刻中产生的蚀刻副产品。因此,反应气体在加工目标的整个表面上可以具有恒定的驻留时间,从而保证宽范围的加工窗口。而且,由于监视系统可以安装在介电窗口11上方的空间中,硬件设计可以很灵活。 The antenna coil unit 7 is arranged outside the cylindrical dielectric window 11 . The pillar dielectric window 11 has a top flat surface structure. A gas injection system is provided at a gas injection port 31 provided in the dielectric window 11 . The gas injection system effectively exhausts the etching by-products generated during etching through the exhaust holes. As a result, the reactive gas can have a constant residence time over the entire surface of the processing target, guaranteeing a wide range of processing windows. Also, since the monitoring system can be installed in the space above the dielectric window 11, the hardware design can be flexible. the

如图2所示,天线线圈单元7包括初级天线线圈组21和次级天线线圈组23。初级天线线圈组21和次级天线线圈组23均具有并行连接的多个天线线圈。次级天线线圈组23定位于保持距离初级天线线圈组21的距离为线圈半径(R)或者小于或大于线圈半径(R)。当两个天线线圈组21和23之间的长度(L)被控制时,腔室5中产生的磁场强度可以适当被控制。这样提供了很灵活的腔室设计,用于获得离子密度均匀性/强度以及均匀蚀刻速度。图3是当天线线圈绕组21和23之间长度(L)小于线圈半径(R)、当其等于线圈半径(R)以及当其大于线圈半径(R)的情况下腔室5内产生的磁场强度的分布的图示。如图3所示,当长度(L)等于或者小于半径(R)时磁场强度增加。当天线线圈单元7满足上述条件并且各个天线线圈绕组21和23在电流方向上彼此相同时,可以产生相比传统的螺线管类型天线线圈具有更好的均匀性和更大的强度的磁场。这样可以在腔室5内实现均匀的并且很高的等离子体离子密度。 As shown in FIG. 2 , the antenna coil unit 7 includes a primary antenna coil group 21 and a secondary antenna coil group 23 . Each of the primary antenna coil group 21 and the secondary antenna coil group 23 has a plurality of antenna coils connected in parallel. The secondary antenna coil group 23 is positioned to maintain a distance of the coil radius (R) from the primary antenna coil group 21 or smaller or larger than the coil radius (R). When the length (L) between the two antenna coil groups 21 and 23 is controlled, the strength of the magnetic field generated in the chamber 5 can be properly controlled. This provides very flexible chamber design for ion density uniformity/intensity and uniform etch rate. Fig. 3 is the magnetic field generated in the chamber 5 when the length (L) between the antenna coil windings 21 and 23 is less than the coil radius (R), when it is equal to the coil radius (R) and when it is greater than the coil radius (R) Graphical representation of the distribution of intensities. As shown in FIG. 3, the magnetic field strength increases when the length (L) is equal to or smaller than the radius (R). When the antenna coil unit 7 satisfies the above conditions and the respective antenna coil windings 21 and 23 are identical to each other in the current direction, a magnetic field with better uniformity and greater strength than conventional solenoid type antenna coils can be generated. This makes it possible to achieve a uniform and very high plasma ion density within the chamber 5 . the

分别由多个线圈组成的初级天线线圈组21和次级天线线圈组23具有低阻抗值。因此,相对很小的源电源电压被耗散,并且被提供给多个线圈。这样可以降低在腔室5内发生的溅射(sputtering)(即低溅射效应),并且将由溅射导致的介电窗口11的损坏和污染最小化。 The primary antenna coil group 21 and the secondary antenna coil group 23 each composed of a plurality of coils have a low impedance value. Therefore, a relatively small source supply voltage is dissipated and supplied to multiple coils. This reduces sputtering (ie low sputtering effect) occurring in the chamber 5 and minimizes damage and contamination of the dielectric window 11 by sputtering. the

在低于20W的低RF功率下产生并且保持等离子体是可能的。当混合了高频和低频RF功率的偏移RF功率被提供给阴极17时,设定电源功率(即转折点)作为划分低电离区域和高电离区域的标准,该点如图9所示从点(P1)移动到点(P2)。由于这种移动,可以在相对很宽范围内保证低电离和高电离区域,并且可以保证绝缘薄膜蚀刻工艺的灵活性。换言之,可以通过控制ICP类型等离子体反应器的高电离属性而控制基团浓度。可以实现低损耗和高效率的实时腔室清洁(ICC),从而将腔室清洁之间平均时间(MTBC)最大化,因为可以在恒定RF功率(大约500W至700W或者更大)下获得高等离子体离子密度和高电离条件。并且,可以提供对慢性腔室电弧和容性耦合等离子体(CCP)类型等离子体反应器的工艺装置损坏问题的有效解决方案。 It is possible to generate and maintain a plasma at low RF power below 20W. When offset RF power mixed with high-frequency and low-frequency RF power is supplied to the cathode 17, the power supply (i.e., turning point) is set as a criterion for dividing the low-ionization region and the high-ionization region, which point is shown in FIG. 9 from point (P1) moves to point (P2). Due to this movement, low-ionization and high-ionization regions can be secured in a relatively wide range, and flexibility in the insulating film etching process can be secured. In other words, the radical concentration can be controlled by controlling the high ionization properties of the ICP type plasma reactor. Enables low-loss and high-efficiency real-time chamber cleaning (ICC), maximizing mean time between chamber cleanings (MTBC) as high plasma can be achieved at constant RF power (approximately 500W to 700W or greater) Bulk ion density and high ionization conditions. Also, an effective solution to the process equipment damage problem of chronic chamber arcing and capacitively coupled plasma (CCP) type plasma reactors can be provided. the

图4是显示通过图1所示等离子体反应器实现的蚀刻工艺的流程图。 FIG. 4 is a flowchart showing an etching process performed by the plasma reactor shown in FIG. 1. Referring to FIG. the

参考图4,当等离子体反应器执行干蚀刻时,作为加工目标的晶圆(W)通过阴极17上提供的CESC(未显示)而固定。反应气体通过气体注入口31而提供到腔室5内。真空泵(未显示)和压力控制单元(未显示)将腔室5内的压力保持在工作压力。 Referring to FIG. 4 , when the plasma reactor performs dry etching, a wafer (W) as a processing target is fixed by a CESC (not shown) provided on the cathode 17 . The reaction gas is supplied into the chamber 5 through the gas injection port 31 . A vacuum pump (not shown) and a pressure control unit (not shown) maintain the pressure in the chamber 5 at the working pressure. the

在物理/化学方面,通过ICP等离子体源单元1产生的等离子体可以获得两种模式:CCP模式和ICP模式。如图9所示,随着ICP源功率增加,在低电离区域(CCP模式)中特定等离子体离子密度不会显著增加,而在高电离区域(ICP模式)中突然发生电离。 In terms of physics/chemistry, plasma generated by the ICP plasma source unit 1 can obtain two modes: CCP mode and ICP mode. As shown in Fig. 9, as the ICP source power increases, the specific plasma ion density does not increase significantly in the low ionization region (CCP mode), while ionization occurs suddenly in the high ionization region (ICP mode). the

更具体的说,在恒定RF源电源功率(即转折点功率)以下不会发生突然电离,等离子体反应器显示出CCP属性。在恒定RF源电源功率之上发生突然电离,等离子体反应器显示出ICP的内部属性。当腔室5内的压力达到工艺所需压力时,等离子体反应器可以依赖于蚀刻模式的工艺特点选择性地工作在CCP模式和ICP模式中的任何一者中。 More specifically, no sudden ionization occurs below a constant RF source power (ie, breakpoint power), and the plasma reactor exhibits CCP properties. Sudden ionization occurs above a constant RF source supply power, and the plasma reactor exhibits the intrinsic properties of ICP. When the pressure in the chamber 5 reaches the pressure required by the process, the plasma reactor can selectively work in any one of the CCP mode and the ICP mode depending on the process characteristics of the etching mode. the

当在低电离区域中进行蚀刻工艺时,源电源功率被设置在转折点功率之 下。当在高电离区域中进行蚀刻工艺时,源电源功率被设置在转折点功率之上。一旦源电源设置完成,则源电源单元10、低频RF电源单元20,以及高频RF电源单元30开启。因此,源电源单元10提供恒定RF功率(也就是源电源)给天线线圈单元7,同时在腔室5内形成等离子体。低频/高频RF功率被混合并且提供给阴极17。 When the etch process is performed in the low ionization region, the source power is set below the breakpoint power. When the etch process is performed in a high ionization region, the source power is set above the breakpoint power. Once the source power setting is completed, the source power unit 10, the low frequency RF power unit 20, and the high frequency RF power unit 30 are turned on. Therefore, the source power unit 10 supplies constant RF power (ie, source power) to the antenna coil unit 7 while forming plasma in the chamber 5 . Low frequency/high frequency RF power is mixed and supplied to cathode 17 . the

换言之,上部ICP等离子体源单元1产生适合于工艺特性的等离子体,并且同时按照适合于工艺特性的混合频率方式提供高频/低频RF功率给阴极17,从而实现所需工艺。并且,离子能量强度的突降/离子密度/基团浓度可以通过适当控制ICP源电源和在低电离区域和高电离区域中提供给阴极的低频/高频RF功率而被控制。因此,可以保证高蚀刻速度、高光敏(PR)选择性、以及宽的工艺窗口。 In other words, the upper ICP plasma source unit 1 generates plasma suitable for process characteristics, and at the same time supplies high frequency/low frequency RF power to cathode 17 in a mixed frequency manner suitable for process characteristics, thereby realizing desired processes. Also, the dip in ion energy intensity/ion density/radical concentration can be controlled by properly controlling the ICP source power and low/high frequency RF power supplied to the cathode in low and high ionization regions. Therefore, a high etch rate, high photosensitive (PR) selectivity, and a wide process window can be secured. the

在蚀刻工艺期间,蚀刻副产品通过排放系统而排放出腔室5外,并且其部分沉积在腔室5的内壁上。沉积在腔室5的内壁上的蚀刻副产品改变了工艺特性并且同时作为杂质,导致加工对象的严重污染问题,从而降低质量和生产率。为了解决该问题,对等离子体反应器实现使用等离子体的ICC。 During the etching process, the etching by-products are discharged out of the chamber 5 through the discharge system, and part of them are deposited on the inner wall of the chamber 5 . The etching by-products deposited on the inner wall of the chamber 5 change process characteristics and at the same time act as impurities, causing serious contamination problems of processed objects, thereby reducing quality and productivity. In order to solve this problem, ICC using plasma is implemented for a plasma reactor. the

当等离子体反应器处于ICC清洁模式中时,它仅使用ICP源电源即使用来自源电源单元10的RF功率执行无晶圆的高密度干清洁过程(recipe)。更具体的说,当等离子体反应器工作在ICC清洁模式中时,源电源单元10提供源电源给天线线圈单元7,并且偏移RF电源单元(即低频RF电源单元20和高频RF电源单元30)停止提供偏移RF功率给阴极17。由此,等离子体反应器在目标晶圆(W)没有安装在阴极17上的情况下使用高密度等离子体执行ICC工艺。 When the plasma reactor is in the ICC cleaning mode, it performs a wafer-less high-density dry cleaning recipe using only the ICP source power, ie, RF power from the source power unit 10 . More specifically, when the plasma reactor works in the ICC cleaning mode, the source power supply unit 10 provides source power to the antenna coil unit 7, and offsets the RF power supply units (i.e., the low frequency RF power supply unit 20 and the high frequency RF power supply unit 30) Stop supplying offset RF power to cathode 17. Thus, the plasma reactor performs an ICC process using high-density plasma without a target wafer (W) mounted on the cathode 17 . the

图5显示了根据本发明第二实施例的等离子体反应器的构造。 Fig. 5 shows the configuration of a plasma reactor according to a second embodiment of the present invention. the

参考图5,基于若干差异而描述等离子体反应器的构造和详细操作,因为它们几乎与根据本发明第一实施例的等离子体反应器相同。一个差异是RF电源单元50仅产生高频RF功率和低频RF功率中的一者,连接到阴极17。换言之,高频RF电源单元或者低频RF电源单元连接到阴极17。另一个差异是源电源切换单元42并行于RF电源单元50连接到阴极17。源电源切换单元42支持阴极17通过源电源切换单元42选择性地连接到接地,从而通过源电源单元40产生的高频或者低频RF功率被选择性地提供给阴极17。当阴极17通过源电源切换单元42连接到接地时,形成包括源电源单元40、天线线圈单元7、阴极17、源电源切换单元42以及接地在内的闭合回路。源电源切换单元42包括源电源滤波器37和开关39。源电源滤波器37通过阴极17对从天线线圈单元7接收到的源电源进行滤波,由此具有不同于源电源频率的其他频率的信号被排除在源电源之外。开关39将源电源滤波器37电连接到接地,或者与接地断开连接。当阴极17通过源电源切换单元42连接到接地并且偏移RF电源单元50和源电源单元40工作时,混合了高频RF功率和低频RF功率的偏移RF功率被提供给阴极17。因此,包括低频或者高频RF电源单元的偏移RF电源单元50和源电源切换单元42提供偏移RF功率给阴极17。Referring to FIG. 5 , the configuration and detailed operation of the plasma reactor are described based on several differences because they are almost the same as the plasma reactor according to the first embodiment of the present invention. One difference is that the RF power supply unit 50 generates only one of high frequency RF power and low frequency RF power, connected to the cathode 17 . In other words, a high-frequency RF power supply unit or a low-frequency RF power supply unit is connected to the cathode 17 . Another difference is that the source power switching unit 42 is connected to the cathode 17 in parallel with the RF power unit 50 . The source power switching unit 42 supports the cathode 17 to be selectively connected to ground through the source power switching unit 42 so that high frequency or low frequency RF power generated through the source power unit 40 is selectively supplied to the cathode 17 . When the cathode 17 is connected to the ground through the source power switching unit 42, a closed loop including the source power unit 40, the antenna coil unit 7, the cathode 17, the source power switching unit 42 and the ground is formed. The source power switching unit 42 includes a source power filter 37 and a switch 39 . The source power filter 37 filters the source power received from the antenna coil unit 7 through the cathode 17, whereby signals having other frequencies than the source power frequency are excluded from the source power. A switch 39 electrically connects the source power filter 37 to ground, or disconnects it from ground. When the cathode 17 is connected to ground through the source power switching unit 42 and the offset RF power supply unit 50 and the source power supply unit 40 operate, offset RF power in which high frequency RF power and low frequency RF power are mixed is supplied to the cathode 17 . Therefore, the offset RF power supply unit 50 including a low frequency or high frequency RF power supply unit and the source power switching unit 42 supply offset RF power to the cathode 17 .

在偏移RF电源单元50包括低频RF电源单元并且提供低频RF功率给阴极17的情况下,源电源单元40包括高频RF电源单元并且通过源电源切换单元42选择性地提供高频RF功率给阴极17。 In the case where the offset RF power supply unit 50 includes a low-frequency RF power supply unit and supplies low-frequency RF power to the cathode 17, the source power supply unit 40 includes a high-frequency RF power supply unit and selectively supplies high-frequency RF power to the cathode 17 through the source power switching unit 42. Cathode 17. the

在偏移RF电源单元50包括高频RF电源单元并且提供高频RF功率给阴极17的情况下,源电源单元40包括低频RF电源单元并且通过源电源切换单元42选择性地提供低频RF功率给阴极17。 In the case where the offset RF power supply unit 50 includes a high-frequency RF power supply unit and supplies high-frequency RF power to the cathode 17, the source power supply unit 40 includes a low-frequency RF power supply unit and selectively supplies low-frequency RF power to the cathode 17 through the source power switching unit 42. Cathode 17. the

源电源滤波器37被调谐到通过源电源单元40产生的源电源频率。 The source power filter 37 is tuned to the frequency of the source power generated by the source power unit 40 . the

图6是显示通过如图5所示的等离子体反应器实现的蚀刻程序的流程图。参考图6,当腔室5内的压力达到工艺所需压力时,等离子体反应器可以依赖于蚀刻模式的工艺特性,按照与根据本发明第一示例实施例的等离子体反应器的类似方式,选择性地工作在CCP模式和ICP模式中任何一者。 FIG. 6 is a flowchart showing an etching procedure performed by the plasma reactor shown in FIG. 5 . Referring to FIG. 6, when the pressure in the chamber 5 reaches the required pressure of the process, the plasma reactor can depend on the process characteristics of the etching mode, in a similar manner to the plasma reactor according to the first exemplary embodiment of the present invention, Selectively work in any one of CCP mode and ICP mode. the

当在低电离区域中进行蚀刻工艺时,提供给天线线圈单元7的源电源功率被设置在转折点功率以下。当在高电离区域中进行蚀刻工艺时,提供给天线线圈单元7的源电源功率被设置在转折点功率之上。一旦源电源设置完成,源电源单元40、源电源切换单元42以及偏移RF电源单元50开启。因此,当RF电源单元50提供高频或者低频偏移RF功率给阴极17时,源电源单元40通过天线线圈单元7提供源电源给阴极17。此时,阴极17通过源电源切换单元42连接到接地。 When the etching process is performed in the low ionization region, the source power supplied to the antenna coil unit 7 is set below the break point power. When the etching process is performed in a high ionization region, the source power supplied to the antenna coil unit 7 is set above the breakpoint power. Once the source power setting is completed, the source power unit 40, the source power switching unit 42, and the offset RF power unit 50 are turned on. Therefore, when the RF power unit 50 provides high frequency or low frequency offset RF power to the cathode 17 , the source power unit 40 provides source power to the cathode 17 through the antenna coil unit 7 . At this time, the cathode 17 is connected to ground through the source power switching unit 42 . the

当等离子体反应器处于蚀刻模式中时,源电源切换单元42切换开启并且执行蚀刻工艺。当等离子体反应器处于ICC清洁模式中时,源电源切换单元42切换关断并且源电源仅被提供给天线线圈单元7。根据本发明第二示例实施例的等离子体反应器提供了降低成本和设备尺寸的优点,因为它可以获得对应于根据本发明第一示例实施例的等离子体反应器的性能,同时通过两个RF功率发生器33和35以及两个阻抗匹配电路/滤波器29和31替代三个RF发生器和三个阻抗匹配电路/滤波器。 When the plasma reactor is in the etching mode, the source power switching unit 42 is switched on and performs an etching process. When the plasma reactor is in the ICC cleaning mode, the source power switching unit 42 is switched off and the source power is supplied to the antenna coil unit 7 only. The plasma reactor according to the second exemplary embodiment of the present invention provides the advantages of reducing the cost and size of the equipment because it can obtain the performance corresponding to the plasma reactor according to the first exemplary embodiment of the present invention while passing two RF Power generators 33 and 35 and two impedance matching circuits/filters 29 and 31 replace three RF generators and three impedance matching circuits/filters. the

转折点功率大于第一示例实施例的转折点功率,因为它支持ICP源电源被双重提供给ICP源单元1的天线线圈单元7和阴极17。 The inflection point power is greater than that of the first exemplary embodiment because it supports ICP source power being dually supplied to the antenna coil unit 7 and the cathode 17 of the ICP source unit 1 . the

图7显示了根据本发明第三示例实施例的等离子体反应器的构造。参考图7,等离子体反应器具有与根据本发明第一和第二示例实施例的等离子体反应器的组合类似的结构。该等离子体反应器与根据本发明第一示例实施例的等离子体反应器的类似之处在于偏移RF电源单元包括低频RF电源单元20和高频RF电源单元30。该等离子体反应器与根据本发明第二示例实施例的等离子体反应器的类似之处在于它进一步包括源电源切换单元42以选择性地提供源电源给阴极17。 Fig. 7 shows the configuration of a plasma reactor according to a third exemplary embodiment of the present invention. Referring to FIG. 7, the plasma reactor has a structure similar to the combination of the plasma reactors according to the first and second exemplary embodiments of the present invention. The plasma reactor is similar to the plasma reactor according to the first exemplary embodiment of the present invention in that the offset RF power supply unit includes a low frequency RF power supply unit 20 and a high frequency RF power supply unit 30 . This plasma reactor is similar to the plasma reactor according to the second exemplary embodiment of the present invention in that it further includes a source power switching unit 42 to selectively supply source power to the cathode 17 . the

更具体的说,低频RF电源单元20和高频RF电源单元30并行地电连接到阴极17,从而低频/高频RF功率被混合并且提供给阴极17。源电源切换 单元42被构造为选择性地提供源电源给阴极17。 More specifically, the low frequency RF power supply unit 20 and the high frequency RF power supply unit 30 are electrically connected to the cathode 17 in parallel so that low frequency/high frequency RF power is mixed and supplied to the cathode 17 . The source power switching unit 42 is configured to selectively supply source power to the cathode 17. the

在包含在偏移RF电源单元中的低频RF电源单元20和高频RF电源单元30分别提供低频RF功率和高频RF功率给阴极17的情况下,源电源单元10可以通过源电源切换单元42选择性地提供低频RF功率,该功率低于提供给阴极17的低频RF功率。 In the case where the low-frequency RF power supply unit 20 and the high-frequency RF power supply unit 30 included in the offset RF power supply unit respectively supply low-frequency RF power and high-frequency RF power to the cathode 17, the source power supply unit 10 can pass through the source power supply switching unit 42 Low frequency RF power, which is lower than the low frequency RF power supplied to the cathode 17, is selectively supplied. the

在包含在偏移RF电源单元中的低频RF电源单元20和高频RF电源单元30分别提供低频RF功率和高频RF功率给阴极17的情况下,源电源单元10可以使用源电源切换单元42选择性地提供低频RF功率,该功率大于提供给阴极17的低频RF功率并且低于提供给阴极17的高频RF功率。 In the case where the low-frequency RF power supply unit 20 and the high-frequency RF power supply unit 30 included in the offset RF power supply unit supply low-frequency RF power and high-frequency RF power to the cathode 17, respectively, the source power supply unit 10 can use the source power supply switching unit 42 Low frequency RF power is selectively supplied which is greater than the low frequency RF power supplied to the cathode 17 and lower than the high frequency RF power supplied to the cathode 17 . the

在包含在偏移RF电源单元中的低频RF电源单元20和高频RF电源单元30分别提供低频RF功率和高频RF功率给阴极17的情况下,源电源单元10可以使用源电源切换单元42选择性地提供高频RF功率,该功率大于提供给阴极17的高频RF功率。 In the case where the low-frequency RF power supply unit 20 and the high-frequency RF power supply unit 30 included in the offset RF power supply unit supply low-frequency RF power and high-frequency RF power to the cathode 17, respectively, the source power supply unit 10 can use the source power supply switching unit 42 High-frequency RF power that is greater than the high-frequency RF power supplied to the cathode 17 is selectively supplied. the

图8是显示通过图7所示等离子体反应器实现的蚀刻程序的流程图。 FIG. 8 is a flowchart showing an etching procedure performed by the plasma reactor shown in FIG. 7. Referring to FIG. the

参考图8,当腔室5内的压力达到工艺所需压力时,等离子体反应器可以依赖于蚀刻模式的工艺特性,按照与根据本发明第一示例实施例的等离子体反应器的类似方式,选择性地工作在CCP模式和ICP模式中任何一者。 Referring to FIG. 8, when the pressure in the chamber 5 reaches the required pressure of the process, the plasma reactor can depend on the process characteristics of the etching mode, in a similar manner to the plasma reactor according to the first exemplary embodiment of the present invention, Selectively work in any one of CCP mode and ICP mode. the

当在低电离区域中进行蚀刻工艺时,提供给天线线圈单元7的源电源功率被设置在转折点功率以下。当在高电离区域中进行蚀刻工艺时,提供给天线线圈单元7的源电源功率被设置在转折点功率之上。一旦源电源功率设置完成,则源电源单元10、低频RF电源单元20和高频RF电源单元30以及源电源切换单元42开启。因此,低频RF电源单元20和高频RF电源单元30提供低频/高频RF功率的混合给阴极17,并且源电源单元40通过天线线圈单元17提供源电源功率给阴极17。此时,阴极17通过源电源切换单元42连接到接地。 When the etching process is performed in the low ionization region, the source power supplied to the antenna coil unit 7 is set below the break point power. When the etching process is performed in a high ionization region, the source power supplied to the antenna coil unit 7 is set above the breakpoint power. Once the source power setting is completed, the source power unit 10 , the low frequency RF power unit 20 and the high frequency RF power unit 30 and the source power switching unit 42 are turned on. Therefore, the low frequency RF power supply unit 20 and the high frequency RF power supply unit 30 supply mixed low frequency/high frequency RF power to the cathode 17 , and the source power supply unit 40 supplies source power to the cathode 17 through the antenna coil unit 17 . At this time, the cathode 17 is connected to ground through the source power switching unit 42 . the

当等离子体反应器处于蚀刻模式中时,源电源切换单元42切换开启并且执行蚀刻工艺。当等离子体反应器处于ICC清洁模式中时,在源电源切换单元42切换关断并且源电源仅被提供给天线线圈单元7的状态下执行无晶圆的高密度ICC过程。根据本发明第三示例实施例的等离子体反应器是为了扩展大规模晶圆(300mm,450mm)的目的而提供。该等离子体反应器可以降低成本和设备尺寸,因为它通过三个RF发生器26、27和28以及三个阻抗匹配电路/滤波器22、24和25替代四个RF功率发生器和四个阻抗匹配电路/滤波器。 When the plasma reactor is in the etching mode, the source power switching unit 42 is switched on and performs an etching process. When the plasma reactor is in the ICC cleaning mode, a waferless high-density ICC process is performed in a state where the source power switching unit 42 is switched off and the source power is supplied to the antenna coil unit 7 only. The plasma reactor according to the third exemplary embodiment of the present invention is provided for the purpose of expanding large-scale wafers (300mm, 450mm). This plasma reactor can reduce cost and equipment size because it replaces four RF power generators and four impedance matching circuit/filter. the

该转折点功率比第一示例实施例中的转折点功率更大,因为它支持ICP源电源被双重地提供给ICP源单元1的天线线圈单元7和阴极17。 This inflection point power is greater than that in the first exemplary embodiment because it supports ICP source power being doubly supplied to the antenna coil unit 7 and the cathode 17 of the ICP source unit 1 . the

图9中显示了ICP属性的图示,从而详细描述本发明的操作。参考图9,提供了低电离区域和高电离区域。随着提供给天线线圈单元7的RF源电源功率提高,反应气体在低电离区域中不会突然电离,并且在高电离区域中突然电离。更具体的说,等离子体反应器在低于恒定RF源电源功率时不发生突然电离的情况下显示出CCP属性。并且等离子体反应器在高于恒定RF源电源功率时发生突然电离的情况下显示出ICP内部属性。 A graphical representation of the ICP attributes is shown in FIG. 9 to describe the operation of the present invention in detail. Referring to Figure 9, low ionization regions and high ionization regions are provided. As the power of the RF source power supplied to the antenna coil unit 7 is increased, the reaction gas is not suddenly ionized in the low ionization region, and is suddenly ionized in the high ionization region. More specifically, the plasma reactor exhibits CCP properties without sudden ionization below constant RF source power. And the plasma reactor exhibits ICP intrinsic properties in the case of sudden ionization above a constant RF source supply power. the

除了ICP源电源功率,偏移功率应当提供给阴极17以加工置于阴极17上的晶圆。在具有互不相同的频率(低频/中频/高频)的偏移功率和具有混合频率的偏移功率分别被提供给阴极17的情况下,ICP等离子体的两个属性即确定低电离区域和高电离区域中离子能量的自偏移(-VDC)的属性被比较,并且预测在各种情况下是否获得任何加工结果。这样,可以理解为什么作为采用传统ICP类型等离子体反应器的一种蚀刻设备的绝缘薄膜蚀刻设备不能提供良好结果,以及为什么很多系统从生产线上被撤下。 In addition to the ICP source power, offset power should be supplied to the cathode 17 to process the wafer placed on the cathode 17 . In the case where the bias power with mutually different frequencies (low frequency/medium frequency/high frequency) and the bias power with mixed frequency are respectively supplied to the cathode 17, two properties of the ICP plasma that determine the low ionization region and The properties of the self-deviation (-VDC) of ion energies in regions of high ionization were compared and predicted whether any processing results were obtained in each case. Thus, it can be understood why an insulating film etching apparatus, which is one type of etching apparatus using a conventional ICP type plasma reactor, cannot provide good results, and why many systems are withdrawn from production lines. the

图10是显示根据本发明的当提供2MHz的偏移RF功率给等离子体反应器的阴极时阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示。 图11是显示根据本发明的当提供12.56MHz的偏移RF功率给等离子体反应器的阴极时阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示。图12是显示根据本发明的当提供27.12MHz的偏移RF功率给等离子体反应器的阴极时阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示。 10 is a graph showing the self-offset variation (-VDC) formed in the cathode versus the source supply power variation when 2 MHz offset RF power is supplied to the cathode of the plasma reactor according to the present invention. 11 is a graph showing the self-offset variation (-VDC) formed in the cathode relative to the source supply power variation when an offset RF power of 12.56 MHz is provided to the cathode of a plasma reactor in accordance with the present invention. 12 is a graph showing the self-offset variation (-VDC) developed in the cathode versus the source supply power variation when 27.12 MHz offset RF power is supplied to the cathode of a plasma reactor in accordance with the present invention. the

图10至图12的图示表示在将反应气体CF4以150标准立方厘米/分钟(SCCM)的速度注入腔室5并且腔室5具有大约50毫托的内部压力的加工条件下测量的值。 The graphs of FIGS. 10-12 represent values measured under process conditions in which the reaction gas CF is injected into the chamber 5 at a rate of 150 standard cubic centimeters per minute (SCCM) and the chamber 5 has an internal pressure of approximately 50 millitorr. .

低电离区域 low ionization area

在图9中的低于恒定ICP源RF功率(大约500W至700W)的区域中,离子密度不会随着RF功率增加而突然增加。在此区域中,不会突然发生电离。 In the region below constant ICP source RF power (approximately 500W to 700W) in Figure 9, the ion density does not increase abruptly with increasing RF power. In this region, no sudden ionization occurs. the

确定等离子体离子能量的自偏移(-VDC)属性可以依赖于提供给阴极的偏移功率的低频2.0MHz、中频12.56MHz以及高频27.12MHz而变化,从而加工置于阴极上的晶圆。这些属性显示于图10至图12中。通过这些图示,可以理解,自偏移(-VDC)随着低于恒定ICP源电源功率(大约500W至700W)的区域中源电源功率增加而增加。并且,等离子体离子能量随着提供给阴极的偏移功率的频率的降低而增大。等离子体离子能量随着提供给阴极的偏移功率的频率升高而减小。 The self-bias (-VDC) property, which determines the plasma ion energy, can be varied in dependence on the low frequency 2.0MHz, medium frequency 12.56MHz, and high frequency 27.12MHz of bias power supplied to the cathode to process wafers placed on the cathode. These properties are shown in Figures 10-12. From these graphs, it can be understood that self-offset (-VDC) increases with increasing source power in the region below constant ICP source power (approximately 500W to 700W). Also, the plasma ion energy increases as the frequency of the offset power supplied to the cathode decreases. Plasma ion energy decreases with increasing frequency of bias power supplied to the cathode. the

图13是显示根据本发明的在分别提供单频率偏移RF功率和混合频率偏移RF功率给等离子体反应器的阴极的情况下阴极中形成的自偏移变化(-VDC)相对于源电源功率变化的图示。在图13中,“◆”标记线表示在低频偏移RF功率被提供给阴极时自偏移(-VDC)(对应于等离子体离子能量)的变化。“▲”标记线表示当高频偏移RF功率被提供给阴极时自偏移(-VDC)的变化。“X”标记线表示当混合了低频和高频RF功率的偏移RF功率被提供给阴极时自偏移(-VDC)的变化。通过各个线条可以理解,当混合频率偏移 RF功率被提供给阴极时,离子能量大约等于低频/高频RF功率被提供给阴极时的能量值的平均值。 13 is a graph showing the self-offset variation (-VDC) formed in the cathode relative to the source power in the case of providing single frequency offset RF power and mixed frequency offset RF power to the cathode of the plasma reactor, respectively, according to the present invention. Graphical representation of power changes. In FIG. 13, the "◆" marked line represents the change in self-bias (-VDC) (corresponding to plasma ion energy) when low-frequency offset RF power is supplied to the cathode. The "▲" marked line indicates the change in self-offset (-VDC) when high-frequency offset RF power is supplied to the cathode. The "X" marked line represents the change in self-offset (-VDC) when an offset RF power that mixes low frequency and high frequency RF power is supplied to the cathode. As can be understood by the various lines, when mixed frequency offset RF power is supplied to the cathode, the ion energy is approximately equal to the average of the energy values when low frequency/high frequency RF power is supplied to the cathode. the

在图13的图示中,测量值未显示,但是等离子体离子密度可以依赖于频率大小和低电离区域中的偏移功率量而具有更大值。 In the illustration of Fig. 13, the measured values are not shown, but the plasma ion density may have larger values depending on the magnitude of the frequency and the amount of offset power in the low ionization region. the

因此,反应气体不会随着低电离区域中源电源功率的增加而突然电离。由于离子能量强度和离子密度相对依赖于频率和偏移功率量,可以对过量基团进行浓度控制。并且可以获得宽的工艺窗口和稳定的工艺。 Therefore, the reaction gas is not suddenly ionized as the power of the source power is increased in the low ionization region. Since ion energy intensity and ion density are relatively dependent on frequency and amount of offset power, concentration control of excess groups is possible. And a wide process window and stable process can be obtained. the

在显示绝缘薄膜(Si02)的蚀刻速度的图14中,当提供相同的偏移功率量时,蚀刻速度在混合频率下最高。这是由于提供给阴极的低频导致的高离子能量和高频导致的高离子密度而产生的。在此条件下,蚀刻速度和蚀刻速度不均匀性更加依赖于偏移功率。 In FIG. 14 showing the etching rate of the insulating film (Si0 2 ), when the same amount of offset power is supplied, the etching rate is highest at the mixing frequency. This is due to high ion energy due to low frequency and high ion density due to high frequency supplied to the cathode. Under this condition, etch rate and etch rate non-uniformity are more dependent on offset power.

高电离区域 high ionization area

在图9中高于恒定ICP源RF功率(大约500W至700W)的区域中,离子密度随着RF功率提高而突然增大。在该区域中,突然发生电离。 In the region of Figure 9 above constant ICP source RF power (approximately 500W to 700W), the ion density increases abruptly with increasing RF power. In this region, ionization occurs suddenly. the

图10至图12是显示依赖于施加给阴极以加工安装在阴极上的晶圆的偏移功率的低频2.0MHz、中频12.56MHz以及高频27.12MHz而确定等离子体离子能量的自偏移(-VDC)的属性的图示。通过这些图示,可以理解,自偏移(-VDC)随着在高于恒定ICP源功率(大约500W至700W)的区域中源电源功率增加而大大改变。换言之,可以理解,随着该区域中源电源功率增加,自偏移(-VDC)突然变得更小。并且,随着频率变小,自偏移突然变得更小。随着频率变得更大,自偏移逐渐变得更小。 Figures 10 to 12 are graphs showing the self-offset of plasma ion energy (- An illustration of the properties of VDC). From these illustrations, it can be understood that the self-offset (-VDC) varies greatly with increasing source power in the region above constant ICP source power (approximately 500W to 700W). In other words, it can be understood that the self-offset (-VDC) suddenly becomes smaller as the power of the source power increases in this region. And, as the frequency gets smaller, the self-offset suddenly becomes smaller. As the frequency becomes larger, the self-offset becomes progressively smaller. the

图13是显示自偏移(-VDC)之间关系的图示,即离子能量和单个以及混合频率。混合频率下的离子能量强度大约等于低频/高频下离子能量强度的平均值。在低频2.0MHz下离子能量的突降可以通过添加高频27.12MHz而 很大程度上被平滑。 Figure 13 is a graph showing the relationship between self-bias (-VDC), ie ion energy and single and mixed frequencies. The ion energy intensity at the mixed frequency is approximately equal to the average of the ion energy intensity at low/high frequencies. The sudden drop in ion energy at the low frequency of 2.0 MHz can be largely smoothed out by adding the high frequency of 27.12 MHz. the

此处,测量值未显示,但是等离子体离子密度可能依赖于频率大小和高电离区域中偏移功率量而具有更大值。 Here, the measured value is not shown, but the plasma ion density may have a larger value depending on the magnitude of the frequency and the amount of offset power in the high ionization region. the

因此,随着高电离区域中源电源功率增大,反应气体突然电离。添加并且施加高频率以保证稳定并且宽的处理窗口,因为随着提供给阴极的频率变低离子能量强度突然改变。 Therefore, as the power of the source power increases in the high ionization region, the reaction gas is suddenly ionized. A high frequency is added and applied to ensure a stable and wide process window because the ion energy intensity changes abruptly as the frequency supplied to the cathode becomes lower. the

在显示绝缘薄膜(SiO2)的蚀刻速率的图15中,当施加相同量的偏移功率时,蚀刻速率在低频和混合频率下几乎相同。可以理解,高电离区域中的蚀刻速率变化与低电离区域中蚀刻速率变化大大不同。这是因为等离子体反应器的离子密度更加依赖于ICP源电源功率。突然降低的离子能量强度/离子密度/基团浓度可以通过适当控制ICP源功率和在高电离区域中提供给阴极的低频/高频RF功率而被控制。因此,可以保证高蚀刻速率、高选择性以及宽的处理窗口。 In FIG. 15 showing the etching rate of the insulating film (SiO 2 ), when the same amount of offset power is applied, the etching rate is almost the same at low frequency and mixed frequency. It can be appreciated that the change in etch rate in regions of high ionization is much different than the change in etch rate in regions of low ionization. This is because the ion density of the plasma reactor is more dependent on the power of the ICP source. The sudden decrease in ion energy intensity/ion density/radical concentration can be controlled by proper control of ICP source power and low/high frequency RF power supplied to the cathode in the high ionization region. Therefore, a high etch rate, high selectivity, and a wide process window can be guaranteed.

如上所述,本发明提供了混合等离子体反应器用于同时实现容性和感性耦合功能,从而加倍提高工艺性能和生产率。更具体的说,本发明可以通过混合频率偏移RF功率而适当协调具有高离子密度属性以及低离子能量属性的ICP源电源,从而改善工艺性能,例如可调离子密度,可调离子能量以及离子能量分布,基团浓度控制以及提高生产率,例如MTBC的显著改善。 As described above, the present invention provides a hybrid plasma reactor for simultaneous capacitive and inductive coupling functions, thereby doubling process performance and productivity. More specifically, the present invention can improve process performance by properly coordinating ICP source power with high ion density properties and low ion energy properties by mixing frequency offset RF power, such as tunable ion density, tunable ion energy, and ion Energy distribution, group concentration control, and increased productivity, such as dramatic improvements in MTBC. the

根据本发明,当ICP类型反应器实现干蚀刻工艺时,高频率被附加添加,从而补偿当施加低频率给阴极时在高电离区域中随着ICP源功率提高而发生的离子能量强度突降。这样,本发明可以提供对ICP类型反应器的蚀刻停止、腔室匹配、低PR选择性以及窄工艺窗口等缺陷的解决方案。本发明可以在低电离区域中添加高频率到低频率,从而保证高离子能量和离子密度,并且提高蚀刻速度。 According to the present invention, when an ICP type reactor implements a dry etching process, a high frequency is additionally added to compensate for the sudden drop in ion energy intensity that occurs with increasing ICP source power in high ionization regions when low frequencies are applied to the cathode. Thus, the present invention can provide solutions to the drawbacks of etch stop, chamber matching, low PR selectivity, and narrow process window of ICP type reactors. The present invention can add high frequency to low frequency in the low ionization region, thereby ensuring high ion energy and ion density, and increasing the etching speed. the

本发明可以最大限度的利用ICP类型反应器的优点,例如高效率,低离 子损耗,以及解耦(decoupled)效果,并且与CCP类型反应器相比可以有效执行无晶圆ICC。本发明可以提供对在CCP类型等离子体反应器中发生的慢性电弧问题的解决方案。 The present invention can maximize the advantages of ICP type reactors, such as high efficiency, low ion loss, and decoupled effect, and can effectively perform waferless ICC compared with CCP type reactors. The present invention can provide a solution to the problem of chronic arcing that occurs in CCP type plasma reactors. the

本发明的等离子体反应器可以抑制反应气体的过度电离,保持高等离子体离子密度,并且在低频率被提供给阴极时在恒定ICP源功率以上补偿离子能量强度的突然降低。 The plasma reactor of the present invention can suppress excessive ionization of the reactant gas, maintain a high plasma ion density, and compensate for sudden drops in ion energy intensity above constant ICP source power when low frequencies are supplied to the cathode. the

尽管参考特定优选实施例显示并且描述了本发明,本领域技术人员可以理解,可以对其作出各种形式和细节上的改变而不背离由所附权利要求限定的本发明的实质和范围。 Although the present invention has been shown and described with reference to certain preferred embodiments, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. the

Claims (9)

1. hybrid plasma reactor comprises:
The ICP source unit, described ICP source unit comprises:
Chamber, described chamber comprise open-topped chamber body and the dielectric window that covers the open top of described chamber body;
Antenna unit places the described dielectric window outside; With
The source current unit is used to provide source current to described antenna unit; And
Skew RF power subsystem is used to provide the bias RF power of having mixed high-frequency RF power and low frequency RF power to negative electrode, and described negative electrode is installed in the described chamber, and on the top of described negative electrode the installation targets wafer, described skew RF power subsystem comprises:
The high-frequency RF power subsystem is used to provide high-frequency RF power to described negative electrode; With
The low frequency RF power subsystem is parallel to described high-frequency RF power subsystem and is connected to described negative electrode,
And provide low frequency RF power to described negative electrode;
Wherein when the source current greater than setting power is provided for described antenna unit the plasma ion density in the described chamber greater than the plasma ion density in the described chamber when the source current less than described setting power is provided for described antenna unit
Wherein when the source current less than described setting power is provided for described antenna unit the plasma ion energy in the described chamber greater than the plasma ion energy in the described chamber when the source current greater than described setting power is provided for described antenna unit, and
Wherein said skew RF power subsystem provides the bias RF power of having mixed high-frequency RF power and low frequency RF power to negative electrode, thereby the plasma ion energy in the described chamber that takes place when being increased to greater than described setting power when the source current that offers described antenna unit reduces suddenly and compensates, thereby perhaps plasma ion density in the described chamber and energy is remained in the setting range.
2. reactor according to claim 1 wherein depends on the degree of ionization that injects the reacting gas in the described chamber and etch process is provided and etch process is provided in the high ionization zone at low ionized space,
Wherein when the source current less than described setting power is provided for described antenna unit, described plasma reactor is carried out etch process in described low ionized space, and when the source current greater than described setting power is provided for described antenna unit, described plasma reactor is carried out etch process in described high ionization zone, and
When described skew RF power subsystem provides the bias RF power of having mixed high-frequency RF power and low frequency RF power during to negative electrode, described setting power improves and described low ionized space expansion.
3. reactor according to claim 1, wherein when described plasma reactor was carried out etch process to the wafer with 200mm diameter, described setting power was in the scope of 500W to 700W.
4. reactor according to claim 1, wherein when described plasma reactor is carried out the real time chamber clean operation, described source current unit provides source current to described antenna unit, and described skew RF power subsystem stops to provide bias RF power to described negative electrode, and described plasma reactor is carried out the high density plasma chamber cleaning course under the situation that wafer is not installed on the described negative electrode.
5. reactor according to claim 1, wherein said skew RF power subsystem also comprises:
The source current switch unit is parallel to described high-frequency RF power subsystem and is connected to described negative electrode,
Wherein said source current switch unit switches to be opened so that described negative electrode is connected to ground connection by described source current switch unit, thereby is provided for described negative electrode by the source current that described source current unit produces when described source current switch unit is opened, and
Wherein form the closed-loop path when described negative electrode is connected to ground connection by described source current switch unit, this closed-loop path comprises described source current unit, described antenna unit, described negative electrode, described source current switch unit and described ground connection.
6. reactor according to claim 5, wherein said source current unit produce have the frequency that is lower than described low frequency RF power-frequency additional RF power as source current,
Wherein said skew RF power subsystem produces by described high-frequency RF power is mixed the bias RF power that obtains with described low frequency RF power, and
Wherein when described negative electrode is connected to ground connection and described high-frequency RF power subsystem and the work of low frequency RF power subsystem by described source current switch unit, described additional RF power and be provided for described negative electrode by described high-frequency RF power is mixed the bias RF power that obtains with described low frequency RF power.
7. reactor according to claim 5, wherein said source current unit produce have the frequency that is higher than described low frequency RF power-frequency and is lower than described high-frequency RF power-frequency additional RF power as source current,
Wherein said skew RF power subsystem produces by described high-frequency RF power is mixed the bias RF power that obtains with described low frequency RF power, and
Wherein when described negative electrode is connected to ground connection and described high-frequency RF power subsystem and the work of low frequency RF power subsystem by described source current switch unit, described additional RF power and be provided for described negative electrode by described high-frequency RF power is mixed the bias RF power that obtains with described low frequency RF power.
8. reactor according to claim 5, wherein said source current unit produce have the frequency that is higher than described high-frequency RF power-frequency additional RF power as source current,
Wherein said skew RF power subsystem produces by described high-frequency RF power is mixed the bias RF power that obtains with described low frequency RF power, and
Wherein when described negative electrode is connected to ground connection and described high-frequency RF power subsystem and the work of low frequency RF power subsystem by described source current switch unit, described additional RF power and be provided for described negative electrode by described high-frequency RF power is mixed the bias RF power that obtains with described low frequency RF power.
9. reactor according to claim 5, wherein said source current switch unit comprises:
The source current filter is used for getting rid of other frequency signals except the source current frequency to carrying out filtering by described negative electrode from the source current that described aerial coil receives; And
Switch is used for described source current filter being electrically connected to ground connection or being connected with ground connection disconnection.
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