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CN100588734C - High-strength shipbuilding section and production method thereof - Google Patents

High-strength shipbuilding section and production method thereof Download PDF

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CN100588734C
CN100588734C CN200710192423A CN200710192423A CN100588734C CN 100588734 C CN100588734 C CN 100588734C CN 200710192423 A CN200710192423 A CN 200710192423A CN 200710192423 A CN200710192423 A CN 200710192423A CN 100588734 C CN100588734 C CN 100588734C
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CN101177760A (en
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曹志强
张爱兵
罗登
肖大恒
吴清明
李曲全
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Hunan Hualing Xiangtan Iron and Steel Co Ltd
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Hunan Hualing Xiangtan Iron and Steel Co Ltd
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Abstract

The invention discloses a high strength ship plate and a production method thereof, and the mass percents of the main chemical compositions of the high strength ship plate are that: carbon is equal to0.05 percent to 0.10 percent, silicon is equal to 0.30 percent to 0.50 percent, manganese is equal to 1.20 percent to 1.60 percent, P is less than or equal to 0.02 percent, sulfur is less than or equal to 0.010 percent, niobium is equal to 0.02 percent to 0.05 percent, titanium is equal to 0.008 percent to 0.02 percent, aluminum is equal to 0.02 percent to 0.06 percent, nickel is equal to 0.0 percent to 0.40 percent, chromium is equal to 0 percent to 0.70 percent, molybdenum is equal to 0 percent to 0.60 percent, copper is equal to 0 percent to 0.70 percent, vanadium is equal to 0.0 percent to 0.05 percent, nitrogen is less than or equal to 0.008 percent. The production process flow is: preparation of raw materials (1), bessemerizing (2), LF refining (3), VD vacuum degassing (4), continuous casting (5), furnace heating (6), rough rolling (7), precision rolling (8), AGC cooling control (9) and finishing warehousing (10).

Description

A kind of high-strength shipbuilding section and production method thereof
Technical field
The present invention relates to a kind of special rolling-mill section and smelting process thereof, particularly relate to a kind of high-strength shipbuilding section and production method thereof that under cold condition, still has good mechanical properties.
Background technology
Development along with marine technology, boats and ships develop towards maximization, lightness, high speed direction, and the exploitation in marine oil gas field, the common intensity ship plate can not satisfy the needs of hull, and high-strength shipbuilding section has the characteristics of high strength, high tenacity, adapted to the specification of quality of modern ships fully to maximization, lightness, high speed development, therefore the ratio of high-strength shipbuilding section is listed as continuous lifting, it is predicted, to bring up to about 30% by present 10%, therefore developing serial high-strength shipbuilding section has vast market prospect.
For guaranteeing the security and the reliability of boats and ships, various countries surveying society has made strict regulation to chemical ingredients, mechanical property and the condition of delivery of the high-strength shipbuilding section of different size, the trade mark.Requiring yield strength to be not less than on the basis of 400MPa as the F40 deck of boat, also require its-60 ℃ of vertical V-type ballistic works to be not less than 41J,-20 ℃ of horizontal V-type ballistic works are not less than 27J, require the steel plate of each trade mark to have good welding property and sea water corrosion resistant simultaneously.
The high-strength shipbuilding section kind of domestic production at present mainly requires relatively low A32, A36, D32, D36 based on quality scale, its yield strength is up to 355Mpa, tensile strength 490Mpa, low-temperature impact toughness can only be protected-20 ℃, production technique adopts electrosmelting mostly, and needs could deliver goods after the normalizing thermal treatment, has increased the production cost of high-strength shipbuilding section greatly, simultaneously also delayed delivery date, seriously restricted high-strength shipbuilding section scale operation and met the need of market.And for the F40 kind that requires high strength and high tenacity simultaneously, the domestic maturation process of never finding out more can not be realized producing in batches.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, provide a kind of yield strength more than 400Mpa, more than the tensile strength 530Mpa, low temperature-60 ℃ impelling strength 〉=120J can satisfy the high-strength shipbuilding section and the production method thereof of 50~200kJ/cm large-line energy requirement of welding.
Purpose of the present invention is achieved by following technical proposals:
High-strength shipbuilding section: comprise alloying element, iron surplus and unavoidable impurities, the chemical component weight per-cent of alloying element is: carbon=0.05%~0.10%, silicon=0.30~0.50%, manganese=1.20%~1.60%, phosphorus≤0.02%, sulphur≤0.010%, niobium=0.02%~0.05%, titanium=0.008~0.02%, aluminium=0.02%~0.06%, nickel=0.0~0.40%, chromium=0~0.70%, molybdenum=0~0.60%, copper=0~0.70%, vanadium=0.0~0.05%, nitrogen≤0.008%.
The high-strength shipbuilding section production method: comprise that raw material is prepared and the finished product warehouse-in, the technical process between raw material preparation and finished product warehouse-in is: converter smelting, LF refining, VD vacuum outgas, continuous casting, process furnace heating, roughing, finish rolling and ACC control are cold.
Described LF purified processing method: refining temperature=1500~1650 ℃, refining time 〉=35 minute, the chemical ingredients fine setting, omnidistance Argon stirs, slag making deoxidation, refining slag basicity CaO/SiO2≤5.0.The processing method of described VD vacuum outgas: under the working vacuum degree condition of 0.5tor, kept vacuum time 15~25 minutes, molten steel is carried out denitrogenation, hydrogen, oxygen processing, nitrogen content≤45PPm in the departures molten steel, hydrogen richness≤2.5PPm, oxygen level≤30PPm.The processing method of described process furnace heating: Heating temperature is between 1170 ℃~1250 ℃, the 220mm thickness slab requires heat-up time 〉=3 hours 30 minutes, soaking time 〉=30 minute, 260mm thickness slab require heat-up time 〉=4 hour, soaking time 〉=40 minute.The processing method that described ACC control is cold: speed of cooling=5~15 ℃/S, final cooling temperature=600~680 ℃.
Compared with prior art, the present invention has the following advantages: under cold condition, still have good mechanical property, and good welding performance, the finished product steel plate does not need thermal treatment just can directly use.Be suitable for making novel ship and offshore platform.
Description of drawings
Fig. 1 is a process flow sheet of the present invention.
Among the figure: the 1-raw material is prepared, the 2-converter smelting, and the 3-LF refining, the 4-VD vacuum outgas, the 5-continuous casting, the heating of 6-process furnace, the 7-roughing, 8-finish rolling, the 9-ACC control is cold, 10-finished product warehouse-in.
Embodiment
The invention will be further described below in conjunction with drawings and Examples:
The present invention includes alloying element, iron surplus and unavoidable impurities, the chemical component weight per-cent of alloying element is: carbon=0.05%~0.10%, silicon=0.30~0.50%, manganese=1.20%~1.60%, phosphorus≤0.02%, sulphur≤0.010%, niobium=0.02%~0.05%, titanium=0.008~0.02%, aluminium=0.02%~0.06%, nickel=0.0~0.40%, chromium=0~0.70%, molybdenum=0~0.60%, copper=0~0.70%, vanadium=0.0~0.05%, nitrogen≤0.008%.
With reference to accompanying drawing:
Technical process of the present invention is: raw material prepares 1, converter smelting 2, LF refining 3, VD vacuum outgas 4, continuous casting 5, process furnace heating 6, roughing 7, finish rolling 8, ACC control cold 9 and finished product warehouse-in 10.
Described raw material is prepared 1 processing method: routine operation.
The processing method of described converter smelting 2: add molten iron and steel scrap in the converter steelmaking process, molten iron and steel scrap proportioning are 85%~95%: 5%~15%; Add iron alloy ferrosilicon: Si 〉=72.0% then, Mn≤0.5%, S≤0.02%, P≤0.04%, C≤0.2%, Cr≤0.5%, iron surplus; Ferromanganese: Si≤1.5%, Mn 〉=78.0%, S≤0.03%, P≤0.20%, C≤1.5%, iron surplus; Ferrotianium: 25.0%≤Ti≤35.0%, Al≤8.0%, Si≤4.50%, Mn≤2.50%, P≤0.05%, S≤0.03%, C≤0.10%, Cu≤0.40%, iron surplus; Ferro-niobium: carbon≤0.05%, niobium 60~70%, silicon≤2%, aluminium≤2.5%, iron surplus; Ferro-aluminum: 55.0%≤Mo≤65.0%, Si≤1.5%, S≤0.10%, P≤0.05%, C≤0.10%, Cu≤0.50%, Sb≤0.05%, Sn≤0.06%, iron surplus; Ferrochrome: Cr 〉=60.0%, C≤2.0%, Si≤2.5%, P≤0.04%, S≤0.03%, iron surplus; Nickel plate: nickel 99.9%~100%, impurity surplus; Vanadium iron: 0.0~0.05%; Add the complex deoxidization alloy at last: aluminium ferromanganese: Si≤2.0%, 30.0%≤Mn≤35.0%, S≤0.05%, P≤0.20%, C≤2.0%, 20.0%≤Al≤26.0%, Cu≤0.5%, Fe surplus; Sial barium: Si 〉=35.00%, Al 〉=12.00%, Ba 〉=18.00%, Al+Ba 〉=30.00%, P≤0.05%, S≤0.10%.
The processing method of described LF stove refining 3: refining temperature: 1500~1650 ℃; Trimming, the slag making deoxidation, refining time 〉=35min, omnidistance Argon stirs, refining slag basicity CaO/SiO2≤5.0; Chemical ingredients is finely tuned, make it reach the internally controlling requirement of steel.
The processing method of described VD stove vacuum outgas 4: under the working vacuum degree condition of 0.5tor, keep vacuum time 15~25min, molten steel is carried out denitrogenation, hydrogen, oxygen processing, make departures molten steel nitrogen content≤45PPm, hydrogen richness≤2.5PPm, oxygen level≤30PPm increases substantially the molten steel purity.
The processing method of described continuous casting 5: adopt the whole process protection cast, carry out continuous casting at 1520~1550 ℃.
The processing method of described process furnace heating 6: the process furnace Heating temperature is between 1170 ℃~1250 ℃, the 220mm thickness slab requires heat-up time 〉=3 hours 30 minutes, soaking time 〉=30 minute, 260mm thickness slab require heat-up time 〉=4 hour, soaking time 〉=40 minute.
The processing method of described roughing 7: start rolling temperature 〉=1000 ℃, the single pass draught requires 〉=7%.
The processing method of described finish rolling 8: start rolling temperature≤900 ℃, accumulative total draught 〉=25% of last three passages, 790~850 ℃ of finish rolling finishing temperatures.
Described ACC is controlled cold 10 processing method: speed of cooling=5~15 ℃/S, final cooling temperature=600~680 ℃.
The processing method of described finished product warehouse-in 10: routine operation.
Embodiment 1:
Add molten iron and steel scrap in the converter steelmaking process, molten iron is 85%~95% to 5%~15% with the steel scrap proportioning; Add iron alloy ferrosilicon: Si 〉=72.0% then, Mn≤0.5%, S≤0.02%, P≤0.04%, C≤0.2%, Cr≤0.5%, iron surplus; Ferromanganese: Si≤1.5%, Mn 〉=78.0%, S≤0.03%, P≤0.20%, C≤1.5%, iron surplus; Ferrotianium: 25.0%≤Ti≤35.0%, Al≤8.0%, Si≤4.50%, Mn≤2.50%, P≤0.05%, S≤0.03%, C≤0.10%, Cu≤0.40%, iron surplus; Ferro-niobium: carbon≤0.05%, niobium 60~70%, silicon≤2%, aluminium≤2.5%, iron surplus; Molybdenum-iron: 55.0%≤Mo≤65.0%, Si≤1.5%, S≤0.10%, P≤0.05%, C≤0.10%, Cu≤0.50%, Sb≤0.05%, Sn≤0.06%, iron surplus; Nickel plate: nickel 99.9%~100%, impurity surplus; Add at last than classifying Si≤2.0%, 30.0%≤Mn≤35.0% as, S≤0.05%, P≤0.20%, C≤2.0%, 20.0%≤Al≤26.0%, Cu≤0.5%, Fe surplus complex deoxidization alloy aluminum ferromanganese is smelted.Through the refining of LF stove, refining temperature: 1500~1650 ℃; Trimming, the slag making deoxidation, refining time 〉=35min, omnidistance Argon stirs, and refining slag basicity CaO/SiO2 is 3.0; Chemical ingredients is finely tuned, make it reach the internally controlling requirement of steel; The vacuum outgas of VD stove is handled: under the vacuum of 0.5tor, keep vacuum time 20~25min, make departures molten steel hydrogen richness≤1.5PPm; Carry out continuous casting at 1520~1550 ℃, cast 260mm * 1860mm, 220mm * 2060mm slab.The process furnace Heating temperature is between 1200 ℃~1230 ℃; Roughing start rolling temperature 〉=1000 ℃, the single pass draught requires 〉=15%; Finish rolling start rolling temperature≤880 ℃, accumulative total draught 〉=45% of last three passages, 800~820 ℃ of finish rolling finishing temperatures, 5~8 ℃/S of ACC speed of cooling, 600~630 ℃ of final cooling temperatures.Adopt the high strength hull steel of above-mentioned explained hereafter, has tiny acicular ferrite+pearlitic structure, grain fineness number is controlled at 10~11 grades, organize grain fineness number difference to be controlled in 1.5 grades, mechanical property is even, and mechanical property reaches following index: yield strength 450Mpa, tensile strength 590Mpa, low-temperature impact toughness-60 ℃, the performance of Akv 240J can satisfy the superperformance of 100-200kJ/cm large-line energy welding.
Embodiment 2:
Add molten iron and steel scrap in the converter steelmaking process, molten iron is 85%~95% to 5%~15% with the steel scrap proportioning; Add iron alloy ferrosilicon: Si 〉=72.0% then, Mn≤0.5%, S≤0.02%, P≤0.04%, C≤0.2%, Cr≤0.5%, iron surplus; Ferromanganese: Si≤1.5%, Mn 〉=78.0%, S≤0.03%, P≤0.20%, C≤1.5%, iron surplus; Ferrotianium: 25.0%≤Ti≤35.0%, Al≤8.0%, Si≤4.50%, Mn≤2.50%, P≤0.05%, S≤0.03%, C≤0.10%, Cu≤0.40%, iron surplus; Ferro-niobium: carbon≤0.05%, niobium 60~70%, silicon≤2%, aluminium≤2.5%, iron surplus; Molybdenum-iron: 55.0%≤Mo≤65.0%, Si≤1.5%, S≤0.10%, P≤0.05%, C≤0.10%, Cu≤0.50%, Sb≤0.05%, Sn≤0.06%, iron surplus; Ferrochrome: Cr 〉=60.0%, C≤2.0%, Si≤2.5%, P≤0.04%, S≤0.03%, iron surplus; Add at last than classifying Si 〉=35.00% as, Al 〉=12.00%, Ba 〉=18.00%, Al+Ba 〉=30.00%, P≤0.05%, the complex deoxidization alloy sial barium of S≤0.10% is smelted, and passes through the refining of LF stove, refining temperature: 1500~1650 ℃; Trimming, the slag making deoxidation, refining time 〉=35min, omnidistance Argon stirs, and refining slag basicity CaO/SiO2 is 4.0; Chemical ingredients is finely tuned, make it reach the internally controlling requirement of steel; The vacuum outgas of VD stove is handled: under the vacuum of 0.5tor, keep vacuum time 15~22min, make departures molten steel hydrogen richness≤2.0PPm; Carry out continuous casting at 1520~1550 ℃.Cast 260mm * 1860mm, 220mm * 2060mm slab.The process furnace Heating temperature is between 1170 ℃~1200 ℃; Roughing start rolling temperature 〉=1000 ℃, the single pass draught requires 〉=11%; Finish rolling start rolling temperature≤1000 ℃, accumulative total draught 〉=35% of last three passages, 820~840 ℃ of finish rolling finishing temperatures, 8~10 ℃/S of ACC speed of cooling, 630~650 ℃ of final cooling temperatures.
Adopt the high-strength shipbuilding section of above-mentioned explained hereafter, have tiny acicular ferrite and pearlitic structure, grain fineness number is controlled at 9~10 grades, organize grain fineness number difference to be controlled in 1.5 grades, mechanical property is even, and mechanical property reaches following index: yield strength 455Mpa, tensile strength 600Mpa, low-temperature impact toughness-60 ℃, the performance of Akv 165J can satisfy the superperformance of 50~150kJ/cm large-line energy welding.

Claims (1)

1. high-strength shipbuilding section production method, the chemical ingredients mass percent of described high-strength shipbuilding section is: carbon=0.05%~0.10%, silicon=0.30~0.50%, manganese=1.20%~1.60%, phosphorus≤0.02%, sulphur≤0.010%, niobium=0.02%~0.05%, titanium=0.008~0.02%, aluminium=0.02%~0.06%, nickel=0.0~0.40%, chromium=0~0.70%, molybdenum=0~0.60%, copper=0~0.70%, vanadium=0.0~0.05%, nitrogen≤0.008%, iron surplus and unavoidable impurities, the production method of the above-mentioned high-strength shipbuilding section of described preparation is: comprise raw material preparation (1), converter smelting (2), LF refining (3), VD vacuum outgas (4), continuous casting (5), process furnace heating (6), roughing (7), finish rolling (8), ACC control cold (9) and finished product warehouse-in (10); The processing method of described LF refining (3): refining temperature=1500~1650 ℃, refining time 〉=35 minute, the chemical ingredients fine setting, omnidistance Argon stirs, slag making deoxidation, refining slag basicity CaO/SiO 2≤ 5.0; It is characterized in that:
The processing method of described VD vacuum outgas (4): under the working vacuum degree condition of 0.5tor, kept vacuum time 15~25 minutes, molten steel is carried out denitrogenation, hydrogen, oxygen processing, nitrogen content≤45ppm in the departures molten steel, hydrogen richness≤2.5ppm, oxygen level≤30ppm;
The processing method of described process furnace heating (6): Heating temperature is between 1170 ℃~1250 ℃, the 220mm thickness slab requires heat-up time 〉=3 hours 30 minutes, soaking time 〉=30 minute, 260mm thickness slab require heat-up time 〉=4 hour, soaking time 〉=40 minute;
The processing method of described ACC control cold (9): speed of cooling=5~15 ℃/S, final cooling temperature=600~680 ℃.
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VD钢中[H]和[N]的控制. 吴伟勤.南钢科技与管理,第4期. 2006 *
转炉流程轴承钢连铸坯非金属夹杂物的行为. 王硕明等.东北大学学报(自然科学版),第27卷第2期. 2006
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