CN100567621C - Aminosiloxane Wool Anti-felting Finishing Agent and Its Preparation and Application - Google Patents
Aminosiloxane Wool Anti-felting Finishing Agent and Its Preparation and Application Download PDFInfo
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- CN100567621C CN100567621C CNB2007100472799A CN200710047279A CN100567621C CN 100567621 C CN100567621 C CN 100567621C CN B2007100472799 A CNB2007100472799 A CN B2007100472799A CN 200710047279 A CN200710047279 A CN 200710047279A CN 100567621 C CN100567621 C CN 100567621C
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- Prior art keywords
- wool
- finishing agent
- aminosiloxane
- fabric
- aminopropyl
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- Expired - Fee Related
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- 210000002268 wool Anatomy 0.000 title claims abstract description 44
- -1 Aminosiloxane Chemical class 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000010006 anti-felting Methods 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 239000004744 fabric Substances 0.000 claims abstract description 28
- 238000004546 feltproofing Methods 0.000 claims abstract description 22
- 229920013822 aminosilicone Polymers 0.000 claims abstract description 9
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 4
- 229920002994 synthetic fiber Polymers 0.000 claims description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 2
- HXLAEGYMDGUSBD-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propan-1-amine Chemical compound CCO[Si](C)(OCC)CCCN HXLAEGYMDGUSBD-UHFFFAOYSA-N 0.000 claims description 2
- ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 claims description 2
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 13
- 238000009950 felting Methods 0.000 description 8
- 239000000835 fiber Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 238000003980 solgel method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 150000002896 organic halogen compounds Chemical class 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000000539 amino acid group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of aminosiloxane wool felt-proofing finishing agent and preparation thereof and application, this finishing agent is to be prepared by amino silicone, organic solvent and water, and their mol ratio is respectively 1: 0～10: 1～100; Preparation is that the mixture with amino silicone or itself and organic solvent adds in the entry, stirs to room temperature; Can be used for the Wool fabric anti-felting arrangement.The present invention is with low cost, and preparation is simple, environmental protection and energy saving, and finishing agent gives fabric good anti-felting performance after handling wool fabric.
Description
Technical field
The invention belongs to the feld proofing field, particularly relate to aminosiloxane wool felt-proofing finishing agent, its preparation method and application thereof.
Background technology
Sol-gel process (Sol-Gel method) be the preparation material wet chemical method in emerging method.This method was controlled at the preparation material initial stage, made uniformity can reach submicron order, nano-scale, and goods get the uniformity, the purity height, and treatment temperature is lower than conventional method.Since the eighties in 20th century, sol-gel process is widely used in special glass, fibrous material such as inorfil and film, functionality ceramic material and oxide coating comprise aspects such as nano composite material with the composite that various conventional methods are difficult to prepare, and have become one of focus of material science research.
Woolens' forward leisureization, popular, light and thin type direction develop for many years, summer and wear next to the skin and need the woolen knitwear of frequent washing also popular day by day.In order to make Woolens reach standards such as easy maintenance, machine washable and apparel appearance retentivity are good, be necessary wool fabric is carried out feld proofing.
At present remain chloridizing or chlorination/He Ketefa (Hercosett) method at the most frequently used felt-proofing finishing method of industrial quarters, these two kinds of methods all can produce the adsorbable organohalogen compounds (AOX) that environment had harm.Therefore, it is imperative to develop novel preventing felting and shrinking of wood fabric technology.
Sol-gel technique produces the nanoscale sol particles by the hydrolysis and the polycondensation of metal or nonmetal alkoxide, and the method for adopt dipping, padding or spraying is applied to fabric with it and gets on; It is crosslinked by heating collosol and gelization also further to be taken place again, forms the continuous three-dimensional network structure, covers the wool scale surface with transparent porous membrane form, thereby gives wool fibre durable felt proofing performance.
Summary of the invention
The purpose of this invention is to provide a kind of aminosiloxane wool felt-proofing finishing agent, its preparation method and application thereof.The present invention is based on sol-gel technique, having the dialkoxy silicane of amido functional group or trialkoxy silane and water is main raw material, the wool anti-felting finish agent of preparation nanoscale colloidal sol, after putting in order on the fabric by heat treatment, form transparent porous membrane at wool surface, give its durable felt proofing performance, be used for the Wool fabric anti-felting arrangement.
Aminosiloxane wool felt-proofing finishing agent of the present invention is to be prepared by amino silicone, organic solvent and water, and their mol ratio is respectively 1: 0～10: 1～100.
Described amino silicone is dialkoxy silicane or the trialkoxy silane with amido functional group, as (β-aminoethyl)-γ-An Bingjisanjiayangjiguiwan, (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, (β-aminoethyl)-γ-aminopropyl methyl dimethoxysilane, (β-aminoethyl)-γ-aminopropyl methyldiethoxysilane, γ-An Bingjisanjiayangjiguiwan, gamma-aminopropyl-triethoxy-silane, γ-aminopropyl methyl dimethoxysilane, γ-aminopropyl methyldiethoxysilane, phenylamino MTMS and phenylamino MTES etc.;
Described organic solvent is the organic solvent that dissolves each other with water, as methyl alcohol, ethanol, ethylene glycol, acetone, acetonitrile etc.
The preparation method of aminosiloxane wool felt-proofing finishing agent of the present invention is that the mixture with amino silicone or itself and organic solvent adds in the entry, stirs to room temperature.
Aminosiloxane wool felt-proofing finishing agent of the present invention can be used for the Wool fabric anti-felting arrangement.
Described wool fabric be wool or with the interweaving of other any textile fabric such as natural, artificial and synthetic fiber, BLENDED FABRIC;
Described application process is that wool fabric is flooded in aminosiloxane wool felt-proofing finishing agent, pads or sprays, liquid carrying rate 70-80%, in the dryer 60-100 ℃ preliminary drying 1-3 minute, baked 1-3 minute at 120-180 ℃ then.
The present invention selects for use and contains amino silicone and prepare wool anti-felting finish agent as presoma, can produce multiple bonding with the amino acid residue in the wool fibre, in conjunction with stable, only need common equipment that wool fabric is handled and promptly reach excellent felt proofing index.
Beneficial effect of the present invention:
(1) aminosiloxane wool felt-proofing finishing agent is with low cost, and preparation is simple, environmental protection and energy saving;
(2) finishing agent itself has strong osmosis to fiber, and the heat treatment after-condensation forms tridimensional network and in the fiber surface film forming, thereby gives fabric good anti-felting performance;
(3) select for use and contain amino siloxanes, strengthen the binding ability of finishing agent and wool fibre, improved the durability of putting in order, and further strengthened anti-felting ability as presoma.
Description of drawings
Fig. 1 is the aminosiloxane wool felt-proofing finishing agent particle diameter schematic diagram of embodiment 1;
Fig. 2 is the aminosiloxane wool felt-proofing finishing agent particle diameter schematic diagram of embodiment 2.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in and limit the scope of the invention.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
The finishing agent prescription
(β-aminoethyl)-aminopropyl trimethoxysilane that in the water-bath with mol ratio is 1: 50 adds in the entry, stir to room temperature, use the Britain's Nano-ZS of Ma Erwen instrument company nano particle size and potentiometric analyzer to show that after tested particle is distributed between 1-10nm in the dressing liquid, the result as shown in Figure 1.
Embodiment 2
The finishing agent prescription
According to mol ratio 1: 60, in water-bath, (β-aminoethyl)-aminopropyl trimethoxysilane is added in the entry, stir to room temperature, use the Britain's Nano-ZS of Ma Erwen instrument company nano particle size and potentiometric analyzer to show that after tested particle is distributed between 1-10nm in the dressing liquid, the result as shown in Figure 2.
Embodiment 3
Adopt the finishing agent of embodiment 1,100% (211g/m
2) the feld proofing step of true qualities gabardine is as follows:
Gabardine two soaks two and rolls in aminosiloxane wool felt-proofing finishing agent, liquid carrying rate 70-80%, and 80 ℃ of preliminary dryings are 3 minutes in the dryer, and 180 ℃ baked 3 minutes then.
According to same quadrat method, do not use finishing agent, fabric directly pads water, and preparation is in the same old way.
With reference to I.W.S.TM 31 testing standards, adopt Wascator FQM71 CLS washing machine to use 7A+3 * 5A program washing, measure and calculate the area felting rate of sample.Use " ISO 13934-1 fabric tension characteristic. measure ultimate strength and elongation at break with the galley proof method " the test fabric ultimate strength.
After above-mentioned arrangement, wool fabric felting situation is as shown in table 1.The felt proofing performance of arrangement sample significantly improves, and reaches International Wool Secretariat's machine washable standard (radially felting rate≤3% and broadwise felting rate≤3%).The fabric ultimate strength with the arrangement before be not more or less the same.
Table 1 arrangement back wool fabric performance table
Embodiment 4
Adopt the finishing agent of embodiment 2,100% (211g/m
2) the feld proofing step of true qualities gabardine is as follows:
Gabardine two soaks two and rolls in aminosiloxane wool felt-proofing finishing agent, liquid carrying rate 70-80%, and 80 ℃ of preliminary dryings are 3 minutes in the dryer, and 160 ℃ baked 3 minutes then.
According to same quadrat method, do not use finishing agent, fabric directly pads water, and preparation is in the same old way.
With reference to I.W.S.TM 31 testing standards, adopt Wascator FQM71 CLS washing machine to use 7A+3 * 5A program washing, measure and calculate the area felting rate of sample.After above-mentioned arrangement, wool fabric felting situation is as shown in table 2.
Table 2 wool fabric felting information slip
Claims (5)
1. aminosiloxane wool felt-proofing finishing agent, it is characterized in that: this finishing agent is to be prepared by amino silicone, organic solvent and water, and their mol ratio is respectively 1: 0～10: 1～100;
Described amino silicone is (β-aminoethyl)-γ-An Bingjisanjiayangjiguiwan, (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, (β-aminoethyl)-γ-aminopropyl methyl dimethoxysilane, (β-aminoethyl)-γ-aminopropyl methyldiethoxysilane, γ-An Bingjisanjiayangjiguiwan, gamma-aminopropyl-triethoxy-silane, γ-aminopropyl methyl dimethoxysilane, γ-aminopropyl methyldiethoxysilane, phenylamino MTMS or phenylamino MTES;
Described organic solvent is methyl alcohol, ethanol, ethylene glycol, acetone or acetonitrile.
2. the preparation method of aminosiloxane wool felt-proofing finishing agent according to claim 1 is characterized in that: the mixture of amino silicone or itself and organic solvent is added in the entry, stir to room temperature.
3. aminosiloxane wool felt-proofing finishing agent according to claim 1 is used for the Wool fabric anti-felting arrangement.
4. application according to claim 3 is characterized in that: described wool fabric is the interweaving of wool or wool and natural, artificial and synthetic fiber, BLENDED FABRIC.
5. application according to claim 3, it is characterized in that: described application is that wool fabric is flooded in aminosiloxane wool felt-proofing finishing agent, pads or sprays, liquid carrying rate 70-80%, in the dryer 60-100 ℃ preliminary drying 1-3 minute, baked 1-3 minute at 120-180 ℃ then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100472799A CN100567621C (en) | 2007-10-19 | 2007-10-19 | Aminosiloxane Wool Anti-felting Finishing Agent and Its Preparation and Application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100472799A CN100567621C (en) | 2007-10-19 | 2007-10-19 | Aminosiloxane Wool Anti-felting Finishing Agent and Its Preparation and Application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101148822A CN101148822A (en) | 2008-03-26 |
| CN100567621C true CN100567621C (en) | 2009-12-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100472799A Expired - Fee Related CN100567621C (en) | 2007-10-19 | 2007-10-19 | Aminosiloxane Wool Anti-felting Finishing Agent and Its Preparation and Application |
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| Country | Link |
|---|---|
| CN (1) | CN100567621C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277747A (en) * | 2011-07-19 | 2011-12-14 | 吴江多艺纺织有限公司 | Treatment method for preventing shrinkage of wool fabric |
| CN110565431B (en) * | 2019-09-04 | 2020-12-11 | 锐智信息科技(滨州)有限公司 | Special paper with stable size and excellent recovery performance and preparation method thereof |
| CN112609456A (en) * | 2020-11-28 | 2021-04-06 | 无锡市丹怡纺织品有限公司 | Preparation method of felt-shrinkage-resistant woolen overcoat |
-
2007
- 2007-10-19 CN CNB2007100472799A patent/CN100567621C/en not_active Expired - Fee Related
Non-Patent Citations (2)
| Title |
|---|
| 溶胶-凝胶技术在羊毛防毡缩整理中的应用. 叶早萍，阎克路.印染，第32卷第7期. 2006 |
| 溶胶-凝胶技术在羊毛防毡缩整理中的应用. 叶早萍，阎克路.印染，第32卷第7期. 2006 * |
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| CN101148822A (en) | 2008-03-26 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Guangdong Mingshu Dress Co., Ltd. Assignor: Donghua University Contract record no.: 2010440000621 Denomination of invention: Aminosiloxane wool felt-proofing finishing agent and its preparation and application Granted publication date: 20091209 License type: Exclusive License Open date: 20080326 Record date: 20100603 |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091209 Termination date: 20131019 |