CN100560650C - The manufacture method of resin combination and plasthetics thereof - Google Patents
The manufacture method of resin combination and plasthetics thereof Download PDFInfo
- Publication number
- CN100560650C CN100560650C CNB2006100606553A CN200610060655A CN100560650C CN 100560650 C CN100560650 C CN 100560650C CN B2006100606553 A CNB2006100606553 A CN B2006100606553A CN 200610060655 A CN200610060655 A CN 200610060655A CN 100560650 C CN100560650 C CN 100560650C
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- pigment
- plasthetics
- thermal stability
- resin combination
- composition
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- 239000011347 resin Substances 0.000 title claims abstract description 50
- 229920005989 resin Polymers 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 34
- 239000000049 pigment Substances 0.000 claims abstract description 31
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 17
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 17
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 28
- 229920001971 elastomer Polymers 0.000 claims description 20
- 239000005060 rubber Substances 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 11
- 238000000465 moulding Methods 0.000 claims description 8
- 238000007670 refining Methods 0.000 claims description 8
- 238000010147 laser engraving Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 6
- 229920000126 latex Polymers 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 230000001404 mediated effect Effects 0.000 claims description 6
- 241000276425 Xiphophorus maculatus Species 0.000 claims description 5
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 5
- 229920000297 Rayon Polymers 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000011174 green composite Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract description 15
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 abstract description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 15
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000001458 anti-acid effect Effects 0.000 description 2
- LKAVYBZHOYOUSX-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;styrene Chemical compound C=CC=C.CC(=C)C(O)=O.C=CC1=CC=CC=C1 LKAVYBZHOYOUSX-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000000059 patterning Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/014—Stabilisers against oxidation, heat, light or ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The present invention relates to the manufacture method of resin combination and plasthetics thereof, wherein resin combination comprises the composition of following mass percent: 25～90% base resins, 5～70% contain the material of butadienyl, 0.1～5% thermal stability difference pigment.Base resin is a polymethylmethacrylate, polyethyl methacrylate, or the mixture of one or more compositions in the poly-n-butyl methacrylate.This resin combination is applicable to that laser sculpture forms literal or pattern, the literal of formation or pattern difficult drop-off, and environmental protection, and high efficiency, cost is low.
Description
Technical field
The present invention relates to a kind of resin combination of the plastic part that is used to prepare products such as card, telephone set, computor-keyboard, facsimile recorder and prepare the method for plastic part, this kind resin combination is applicable to laser sculpture.
Background technology
The plastic part of products such as preparation card, telephone set, computor-keyboard, facsimile recorder generally uses ABS, HIPS resin raw materials such as (high-impact polystyrene resins) to carry out injection moulding.But when its surface of the plastic part that these raw materials of prior art are made forms literal or pattern, generally can only use the ink silk screen printing method, traditional for many years constant stencil printing method complicated operation, working efficiency is too low, and cost is too high, causes environmental pollution, not environmental protection of product.And this traditional stencil printing method can't operation on irregular platform, can't realize when particularly forming literal or pattern in shelters such as slit or perforates.In addition, literal or pattern that stencil printing method forms do not possess acid-and base-resisting, oiliness, wear no resistance, and are easy to come off.Because the restriction of existing raw material, the plasthetics after the moulding can't be suitable for laser sculpture and form continuous slick literal or pattern.
Summary of the invention
The technical problem to be solved in the present invention is, at the above-mentioned defective of prior art, provides a kind of its plasthetics surface to be easy to form the resin combination of continuous smooth literal or pattern and difficult drop-off and the manufacture method of plasthetics thereof.
The technical solution adopted for the present invention to solve the technical problems is: a kind of resin combination is provided, and it comprises the composition of following mass percent:
Base resin 25～90%
The material 5～70% that contains butadienyl
Thermal stability difference pigment 0.1～5%
Wherein, base resin is to be selected from polymethylmethacrylate, polyethyl methacrylate, or poly-methyl
The mixture of one or more compositions in the butyl acrylate.
Described resin combination comprises that further mass percent is respectively 0.1～1% oxidation inhibitor, thermo-stabilizer and whipping agent, and the thermostability and the base resin of described thermal stability difference pigment are variant, and thermostability there are differences between the multiple pigment composition.
Described resin combination is made with following method:
(1) base resin is carried out grinding and become finely powdered, be beneficial to other composition thorough mixing even;
(2) the powdery base resin is put into kneader, adds divinyl base class material and thermal stability difference pigment, under vacuum, high pressure, heat 200～220 ℃ and mediated mixing 40～60 minutes,
Until plasticating into uniform soft rubber; And
(3) soft rubber after will mediating is plasticated under 180～200 ℃ with two rollers refining machines, and soft rubber is pressed into sheet.
The material that contains butadienyl is the mixture that is selected from one or more compositions in divinyl, Methacrylate-butadiene-styrene, the acrylonitrile-butadiene-styrene (ABS).
The mass percent of each component is:
Base resin 39～70%
The material 29～60% that contains butadienyl
Thermal stability difference pigment 0.1～1.0%
Oxidation inhibitor 0.1～0.3%
Thermo-stabilizer 0.1～0.3%
Whipping agent 0.1～0.3%.
The present invention solves another technical scheme that its technical problem adopts: the manufacture method of plasthetics mainly may further comprise the steps:
(1) select the composition of following mass percent for use:
Base resin 25～90%
The material 5～70% that contains butadienyl
Thermal stability difference pigment 0.1～5%
Wherein, base resin is to be selected from polymethylmethacrylate, polyethyl methacrylate, or the mixture of one or more compositions in the poly-n-butyl methacrylate;
(2) base resin is carried out grinding and become finely powdered, be beneficial to other composition thorough mixing even;
(3) the powdery base resin is put into kneader, adds and to contain divinyl base class material and thermal stability difference pigment, under vacuum, high pressure heating mediate mixing, until plasticating into uniform soft rubber;
(4) soft rubber after will mediating is plasticated with two roller refining machines heating, and soft rubber is pressed into sheet;
(5) the granular resin composition molding is become plasthetics; And
(6) plasthetics with moulding uses the laser engraving machine engraving to form pattern or literal.
Described step (3) heats 200～220 ℃ under vacuum, high pressure mediated mixing 40～60 minutes, until plasticating into uniform soft rubber; The two roller refining of described step (4) machine is plasticated under 180～200 ℃; In the described step (6), the power of laser engraving machine is selected 50W for use, and laser speed is selected 7Kmm/s for use.
Beneficial effect of the present invention: the plasthetics of resin combination moulding of the present invention is applicable to laser sculpture, and product surface is easy to form continuous smooth literal or pattern, and difficult drop-off.Form literal or method of patterning and have good environmental-protection function, working efficiency can improve more than 30 times, and cost can reduce by 10 times, and the precision height can be on concave plane, and particularly formation mark in shelter such as slit or perforate is used for false proof.In addition, the literal of its formation or pattern resistance to abrasion are more than 50 times of mimeograph, and difficult drop-off has performances such as antiacid, alkali, oiliness, are suitable for different areas and complex environment and use.
Each composition mixes very evenly in the resin composition pellet of the present invention, guarantees that the lines of the literal carved or pattern are uninterrupted.
Embodiment
Resin combination of the present invention mainly comprises the component of following mass percent:
Base resin 25～90%
Contain butadienyl material 5～70%
Thermal stability difference pigment 0.1～5.0%
Oxidation inhibitor 0.1～1%
Thermo-stabilizer 0.1～1%
Whipping agent 0.1～1%
Wherein base resin is polymethylmethacrylate (PMMA), polyethyl methacrylate, or the mixture of one or more compositions in the poly-n-butyl methacrylate.PMMA etc. can be powdery or granular, itself have transparent glossiness, and rigidity is strong, and wear resistance is good, have good foaminess.
Contain the mixture that the butadienyl material is meant that one or more materials among divinyl, MBS, the ABS etc. are formed.MBS is a Methacrylate-butadiene-styrene, and ABS is an acrylonitrile-butadiene-styrene (ABS), and divinyl is butadiene latex or is the letex polymerization liquid of principal monomer with the divinyl.Divinyl MBS, ABS etc. have the character of the good rubber aspect of elasticity and resistance to impact shock, can change the soft of PMMA, to adapt to various moulding, the more important thing is with PMMA in conjunction with making resin combination become translucent magnetic white, can be used as a kind of basic look.
The thermostability of thermal stability difference pigment and resin combination thermostability there are differences, and the thermostability between each composition of composite pigment there are differences, its can issue in the condition that moment is heated estranged from, produce distinct colors.
The effect of oxidation inhibitor is to suppress polymkeric substance oxidative degradation in system refining process, stops in the laser sculpture process by engraving part material oxidation, avoids influencing engraving effect, and oxidation inhibitor is generally selected phenolic antioxidant or amine antioxidants for use.The effect of thermo-stabilizer is thermolysis and a thermal ageing when preventing polymer processing, avoids influencing engraving effect, and thermo-stabilizer is generally selected polyvinyl chloride or vinyl chloride copolymer for use.Whipping agent can be other whipping agent of Cellmic C 121 or prior art.
The quality percentage composition of each component is in the screening formulation of above-mentioned composition:
Base resin 39～70%
The material 29～60% that contains butadienyl
Thermal stability difference pigment 0.1～1.0%
Oxidation inhibitor 0.1～0.3%
Thermo-stabilizer 0.1～0.3%
Whipping agent 0.1～0.3%.
The working method of resin combination of the present invention mainly may further comprise the steps:
(1) PMMA carries out grinding and becomes finely powdered, is beneficial to other composition thorough mixing even;
(2) powdery PMMA is put into kneader, add polybutadiene latex or be the letex polymerization liquid of principal monomer with the divinyl, add pigment, oxidation inhibitor, thermo-stabilizer, whipping agent etc., also can add other auxiliary agent as required, under vacuum, high pressure, 200～220 ℃, mediated mixing 40～60 minutes, until plasticating into uniform soft rubber;
(3) soft rubber after will mediating is plasticated under 180～200 ℃ in two roller refining machines, and soft rubber is pressed into sheet;
(4) cooling sheet blob of viscose, and pulverize the tiny platy shaped particle of formation;
(5) use the mixing backguy of grit maker that tiny sheet is cut into the granular of standard.
The composition pellet that above-mentioned (4), (5) step form can directly be packed sale, also can it be molded directly within plasthetics for raw material, further may further comprise the steps when making plasthetics:
(6) other forming method with injection moulding of granular resin composition or prior art forms goods, as is injection molded into the plastic parts of telephone set, mobile phone, counter etc.;
(7) product with moulding uses the laser engraving machine engraving to form pattern or literal, and wherein the power of laser engraving machine can be selected 50W for use, and laser speed can be selected 7Kmm/s for use.
Because of containing following composition and performance in the resin combination of the present invention:
(1) thermal stability difference pigment;
(2) PMMA itself has good foaminess;
(3) divinyl has softening PMMA and is combined into the performance of magnetic white with PMMA;
Therefore, the resin combination pellet that aforesaid method is made has good foaminess, exists thermal stability difference between pigment and resin combination itself and the composite pigment.Under laser is strafed moment high temperature, the position of being strafed is produced be subjected to heat foamable fast, and the strong component of relatively poor component of pigment thermostability and thermostability is separated, thereby produce heterochromaticly, therefore formation has certain relief font or pattern.
Product after the moulding of use said composition is applicable to that laser sculpture forms the literal or the pattern of various lines smooth and continuous; can carve out white writing or pattern as black product; the purple product can be carved out blueness or red literal or pattern; green product can be carved out yellow literal or pattern, and mazarine can be carved out red-purple etc.Compare with the traditional oils impression method, this formation literal or method of patterning have good environmental-protection function, and working efficiency can improve more than 30 times, cost can reduce by 10 times, the precision height can be on concave plane, and particularly formation mark in shelter such as slit or perforate is used for false proof.In addition, the literal of its formation or pattern resistance to abrasion are more than 50 times of mimeograph, and difficult drop-off has performances such as antiacid, alkali, oiliness, are suitable for different areas and complex environment and use.
Preparation method's technology of resin combination of the present invention is simple, and each composition mixes very evenly in the composition grain of formation, guarantees that the lines of the literal carved or pattern are uninterrupted.
Example one
This example forms white text with the black product engraving or pattern is the manufacture method that example illustrates resin combination of the present invention, its preparation method and product.Wherein resin combination carries out proportioning by following mass percent:
Powdery PMMA resin 75%
Butadiene latex liquid 24.5%
The black pigment 0.5% of Heat stability is good
The manufacture method of product may further comprise the steps:
(1) drops in the kneader by above-mentioned formulation selection material, under vacuum, high pressure, 200～220 ℃, mediated mixing 40～60 minutes, until plasticating into uniform soft rubber;
(2) soft rubber after will mediating is plasticated under 180～200 ℃ heating condition with two rollers refining machines, and soft rubber is pressed into sheet;
(3) cooling sheet blob of viscose, and pulverize the tiny platy shaped particle of formation;
(4) particle with step (3) is that raw material is injection molded into telephone key;
(5) telephone key is put into laser engraving machine, with power 50W, laser speed 7Kmm/s carries out laser sculpture, thereby forms the white numeral on telephone key, and also forms white marker and pattern on shell.
The principle that forms white numeral, sign and pattern is: under laser is strafed moment high temperature; the telephone key material of this black is that these resin true qualities add carbon black look pigment and make; it selects for use the thermostability of carbon black look pigment to be higher than this resin combination; the moment of laser high temperature strafe under the condition; resin moment is foamed by heat of solution; the magnetic white of resin own is separated with the carbon black toner, strafes position white composition protrusion generation and have relief white writing or pattern.
Example two
This example carves out yellow literal with the light green product or pattern is the manufacture method that example illustrates resin combination of the present invention, its preparation method and product.Wherein resin combination carries out proportioning by following mass percent:
Powdery PMMA resin 75%
Butadiene latex liquid 24.5%
Green composite pigment 0.5%
The green composite pigment of this thermal stability difference, be by titanium blue or green blue and yellow ultramarine by making green at 3: 1, if will make product carve out yellow literal or pattern, then the thermostability of yellow ultramarine is identical with the thermostability of resin own easily molten in the composite pigment, and their thermostability is lower than the blue or green blue pigment of titanium.
The manufacture method of product may further comprise the steps:
(1) drops in the kneader by above-mentioned formulation selection material, under vacuum, high pressure, 200～220 ℃, mediated mixing 40～60 minutes, until plasticating into uniform soft rubber;
(2) soft rubber after will mediating is plasticated under 180～200 ℃ heating condition with two rollers refining machines, and soft rubber is pressed into sheet;
(3) cooling sheet blob of viscose, and pulverize the tiny platy shaped particle of formation;
(4) particle with step (3) is that raw material is injection molded into green plastic shell;
(5) green plastic shell is put into laser engraving machine, with power 50W, laser speed 7Kmm/s carries out laser sculpture, thereby engraving forms yellow literal or pattern on plastic shell.
Its principle that forms yellow literal or pattern is: the position moment high-temperature heating dissolving foaming that utilizes laser to strafe, their molten point of yellow ultramarine and magnetic white resin is identical, phased soln forms yellow, separates with the strong blue form and aspect of thermostability under foaming effect, forms xanchromatic literal or pattern.
Claims (2)
1, resin combination, it comprises the composition of following mass percent:
Powdery polymethylmethacrylate 75%
Butadiene latex liquid 24.5%
Thermal stability difference pigment 0.5%
Wherein, described thermal stability difference pigment be selected from carbon black look pigment or blue or green blue and yellow ultramarine is made in 3: 1 ratios by titanium green composite pigment in a kind of.
2, the manufacture method of plasthetics mainly may further comprise the steps:
(1) select the composition of following mass percent for use:
Powdery polymethylmethacrylate 75%
Butadiene latex liquid 24.5%
Thermal stability difference pigment 0.5%
Wherein, described thermal stability difference pigment be selected from carbon black look pigment or blue or green blue and yellow ultramarine is made in 3: 1 ratios by titanium green composite pigment in a kind of;
(2) described each composition is put into kneader by described mass percent, under vacuum, high pressure, 200～220 ℃, mediated mixing 40～60 minutes, until plasticating into uniform soft rubber;
(3) soft rubber after will mediating is plasticated under 180～200 ℃ heating condition with two rollers refining machines, and soft rubber is pressed into sheet;
(4) the resulting sheet blob of viscose of cooling is pulverized the formation platy shaped particle with it;
(5) platy shaped particle is molded into plasthetics; And
(6) plasthetics with moulding uses laser engraving machine to form pattern or literal with power 50W, laser speed 7Kmm/s engraving.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100606553A CN100560650C (en) | 2006-05-22 | 2006-05-22 | The manufacture method of resin combination and plasthetics thereof |
| PCT/CN2007/001664 WO2007134544A1 (en) | 2006-05-22 | 2007-05-22 | Resin composition, a method of preparing plastic-rubber article from it and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100606553A CN100560650C (en) | 2006-05-22 | 2006-05-22 | The manufacture method of resin combination and plasthetics thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1884365A CN1884365A (en) | 2006-12-27 |
| CN100560650C true CN100560650C (en) | 2009-11-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100606553A Expired - Fee Related CN100560650C (en) | 2006-05-22 | 2006-05-22 | The manufacture method of resin combination and plasthetics thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN100560650C (en) |
| WO (1) | WO2007134544A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254488A (en) * | 2013-05-17 | 2013-08-21 | 江海波 | Resin combined material capable of being carved in vacuum through transparent object and preparation method of resin combined material |
| CN104004311B (en) * | 2014-06-05 | 2016-06-22 | 东莞市瀛通电线有限公司 | A kind of plasthetics laser engraving material and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0827980B1 (en) * | 1996-09-10 | 2003-05-21 | Daicel Chemical Industries, Ltd. | A resin composition for a white marking |
| JP2000129070A (en) * | 1998-10-26 | 2000-05-09 | Techno Polymer Kk | Laser-markable thermoplastic resin composition which develops chromatic color |
| JP3892983B2 (en) * | 1999-01-25 | 2007-03-14 | ダイセル化学工業株式会社 | Resin composition for white marking |
| DE19961304A1 (en) * | 1999-12-18 | 2001-06-21 | Merck Patent Gmbh | Laser-markable plastics |
| WO2003046073A1 (en) * | 2001-11-30 | 2003-06-05 | Zeon Corporation | Rubber vulcanizate, process for its production, and polymer composition, rubber composition and vulcanizable rubber composition used in the process |
-
2006
- 2006-05-22 CN CNB2006100606553A patent/CN100560650C/en not_active Expired - Fee Related
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2007
- 2007-05-22 WO PCT/CN2007/001664 patent/WO2007134544A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007134544A1 (en) | 2007-11-29 |
| CN1884365A (en) | 2006-12-27 |
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