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CN100545951C - Novel Microtip Area Array Device - Google Patents

Novel Microtip Area Array Device Download PDF

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Publication number
CN100545951C
CN100545951C CNB2005100121721A CN200510012172A CN100545951C CN 100545951 C CN100545951 C CN 100545951C CN B2005100121721 A CNB2005100121721 A CN B2005100121721A CN 200510012172 A CN200510012172 A CN 200510012172A CN 100545951 C CN100545951 C CN 100545951C
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China
Prior art keywords
microns
array device
little tip
surface array
tip surface
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CN1897170A (en
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焦斌斌
陈大鹏
欧毅
叶甜春
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Semiconductor Manufacturing International Shanghai Corp
Institute of Microelectronics of CAS
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Institute of Microelectronics of CAS
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Abstract

本发明涉及扫描隧道显微镜技术领域,特别是一种新型微尖端面阵列器件。由夹持框架(1)、支撑膜(2)、悬臂梁(3)微尖端(7)四个部分组成。夹持框架(1)用于夹持整个器件使之与外部系统结合并为整个器件结构提供保护;支撑膜(2)用于支撑悬臂梁结构与导线(4)和内焊盘(5);悬臂梁(3)单元采用顺序平铺的方式构成平面阵列;微尖端(6)由金属电镀生成。

Figure 200510012172

The invention relates to the technical field of scanning tunneling microscopes, in particular to a novel microtip surface array device. It consists of four parts: a clamping frame (1), a support membrane (2), a cantilever beam (3) and a microtip (7). The clamping frame (1) is used to clamp the entire device to combine with the external system and provide protection for the entire device structure; the support film (2) is used to support the cantilever beam structure, wires (4) and inner pads (5); The cantilever beam (3) units are sequentially tiled to form a planar array; the microtip (6) is formed by metal electroplating.

Figure 200510012172

Description

新型微尖端面阵列器件 Novel Microtip Area Array Device

技术领域 technical field

本发明涉及扫描隧道显微镜技术领域,特别是一种新型微尖端面阵列器件。The invention relates to the technical field of scanning tunneling microscopes, in particular to a novel microtip surface array device.

背景技术 Background technique

从1982年IBM公司的G.Bining等人发明隧道显微镜(STM)以来,衍生出的原子力显微镜(AFM)、扫描探针显微镜(SPM)等,已在物理、化学、电子、材料、医药等众多领域得到了广泛的应用,成为人们研究微观世界的强有力的工具。在此基础上,国外已经涌现出各种新型的悬臂梁微尖端器件,目前已经被应用于高密度数据存取、材料表面超微加工、材料表面探知、传感器等诸多方面。Since the invention of the tunneling microscope (STM) by G. Bining et al. of IBM in 1982, the derived atomic force microscope (AFM) and scanning probe microscope (SPM) have been widely used in physics, chemistry, electronics, materials, medicine, etc. The field has been widely used and has become a powerful tool for people to study the microcosm. On this basis, various new types of cantilever beam micro-tip devices have emerged abroad, which have been applied to high-density data access, ultra-micro-machining of material surfaces, detection of material surfaces, sensors and many other aspects.

已有专利:微尖端线列器件申请号:200510011987.8。其结构如图5,这种结构的阵列微尖端器件由于其夹持端(9)厚度大于微尖端的高度,即此器件无法自由加工材料的表面,只能加工在其悬臂梁所能到达的材料边缘部分。而且这种结构器件的悬臂梁完全暴露,容易损坏。Existing patents: micro-tip linear device application number: 200510011987.8. Its structure is shown in Fig. 5, because the thickness of the clamping end (9) of the array microtip device of this structure is greater than the height of the microtip, that is, this device cannot freely process the surface of the material, and can only be processed within the reach of its cantilever beam. The edge of the material. Moreover, the cantilever beam of this structural device is completely exposed and easily damaged.

与这种结构相比,本发明介绍的这种面阵列器件具有效率更高、可以自由加工材料表面不受边界限制、悬臂梁受到石英玻璃材料的夹持框架的保护不易损坏等优点。Compared with this structure, the surface array device introduced by the present invention has the advantages of higher efficiency, free processing of the material surface without border restrictions, and the protection of the cantilever beam by the clamping frame of the quartz glass material, which is not easy to be damaged.

发明内容 Contents of the invention

本发明的目的在于提出一种基于MEMS加工方法制备的一种面阵列氮化硅悬臂梁支撑的金属微尖端器件。此器件的目的在于通过“平面阵列化”最大限度的提高STM单探针在进行表面探知、材料表面微纳加工、高密度数据存取时的效率,同时解决线阵列器存在的边界限制等缺点。面阵列单元的个数既是其所提高效率的倍数。The purpose of the present invention is to propose a metal microtip device supported by a surface array silicon nitride cantilever beam prepared based on a MEMS processing method. The purpose of this device is to maximize the efficiency of STM single probes in surface detection, material surface micro-nano processing, and high-density data access through "planar arraying", and at the same time solve the shortcomings of line array devices such as boundary limitations. . The number of area array units is the multiple of its improved efficiency.

附图说明 Description of drawings

图1是本发明的微尖端面阵列器件的俯视示意图。FIG. 1 is a schematic top view of the microtip surface array device of the present invention.

图2是本发明的微尖端面阵列器件的俯视剖面示意图。Fig. 2 is a schematic cross-sectional top view of the microtip surface array device of the present invention.

图3是本发明的微尖端面阵列器件的侧视剖面示意图。Fig. 3 is a schematic cross-sectional side view of the microtip surface array device of the present invention.

图4是本发明的微尖端面阵列器件的仰视示意图。Fig. 4 is a schematic bottom view of the microtip surface array device of the present invention.

图5是已有技术的微尖端线列器件图。Fig. 5 is a diagram of a microtip linear device in the prior art.

具体实施方式 Detailed ways

如图1、2、3、4所示,此器件大体上由:夹持框架(1)、支撑膜(2)、悬臂梁(3)微尖端(6)四个部分组成。夹持框架(1),材料为石英玻璃,尺寸为3厘米×2厘米、顶壁厚0.3厘米、侧壁厚0.5厘米、顶壁上有0.5厘米×1厘米的引线窗口,此结构用于夹持整个器件使之与外部系统结合并为整个器件结构提供保护,其上拥有外焊盘(8)。外焊盘(8),由3毫米×1毫米、厚100埃的金膜构成,用于与外围电路相连的。支撑膜(2),厚2微米,用于支撑悬臂梁结构与导线(4)和内焊盘(5)。其上的导线由宽3微米、厚100埃的金膜构成,用于将悬臂梁(3)与内焊盘(5)相连。内焊盘(5),由1毫米×1毫米、厚100埃的金膜构成,内焊盘(5)与外焊盘(8)之间依靠引线键合工艺通过金线(7)连接。悬臂梁(3),为高400微米、底边100微米的中空等腰三角形,中间空心部分为高200微米,底边50微米的等腰三角形,所述的微悬臂梁单元采用顺序平铺的方式构成平面阵列。微尖端面阵列器件,其主体材料为低应力氮化硅,厚2微米,其上附着金膜,厚100埃。这层金膜的作用在将微尖端与内焊盘电学连接,其同时与氮化硅构成了一种双变体结构。这种结构基于热膨胀系数的巨大差异,可以在需要的情况下通过改变悬臂梁温度使微尖端在z轴方向运动。微尖端(6),由金属镍电镀生成,底切面尺寸5微米×5微米、高7微米,其尖端处曲率半径小于50纳米。依靠尖端放电的原理,当在焊盘上于其所要加工的材料之间加上微小电压时(如5v),就可以在尖端处产生很大的电场(约109V/m,反比于尖端与衬底间距离),从而使空气电离产生隧道电流。这种镍尖端不光可以通过隧道电流加工和感知材料表面,还可以被热电阻加热依靠高温来加工材料,或直接用其进行纳米压印。As shown in Figures 1, 2, 3, and 4, the device is generally composed of four parts: a clamping frame (1), a supporting film (2), a cantilever beam (3) and a microtip (6). Clamping frame (1), the material is quartz glass, the size is 3 cm x 2 cm, the thickness of the top wall is 0.3 cm, the thickness of the side wall is 0.5 cm, and there is a lead window of 0.5 cm x 1 cm on the top wall. This structure is used for clamping Holds the entire device to combine with external systems and provides protection for the entire device structure, having external pads (8) thereon. The outer pad (8) is composed of a gold film with a thickness of 3 mm x 1 mm and a thickness of 100 angstroms, and is used for connecting with peripheral circuits. The support film (2), with a thickness of 2 microns, is used to support the cantilever beam structure, wires (4) and inner pads (5). The wires on it are composed of a gold film with a width of 3 microns and a thickness of 100 angstroms, and are used to connect the cantilever beam (3) to the inner pad (5). The inner pad (5) is composed of a gold film with a thickness of 1 mm×1 mm and 100 angstroms, and the inner pad (5) and the outer pad (8) are connected through a gold wire (7) by a wire bonding process. The cantilever beam (3) is a hollow isosceles triangle with a height of 400 microns and a base of 100 microns, and the hollow part in the middle is an isosceles triangle with a height of 200 microns and a base of 50 microns. The micro-cantilever unit adopts sequential tiling form a planar array. Micro-tip area array device, the main body material is low stress silicon nitride with a thickness of 2 microns, and a gold film with a thickness of 100 angstroms is attached on it. The role of this gold film is to electrically connect the microtip to the inner pad, and it also forms a double-variant structure with silicon nitride. This structure is based on the large difference in the thermal expansion coefficient, and the microtip can be moved in the z-axis direction by changing the temperature of the cantilever beam when needed. The microtip (6) is produced by metal nickel electroplating, the size of the undercut surface is 5 microns×5 microns, the height is 7 microns, and the radius of curvature at the tip is less than 50 nanometers. Relying on the principle of tip discharge, when a small voltage (such as 5v) is applied between the pad and the material to be processed, a large electric field (about 10 9 V/m, inversely proportional to the tip distance from the substrate), so that air ionization produces tunnel current. This kind of nickel tip can not only process and sense the surface of materials through tunnel current, but also can be heated by thermal resistance to process materials at high temperature, or directly use it for nanoimprinting.

Claims (8)

1. little tip surface array device; by holding frame (1); support membrane (2); (7) four parts in semi-girder (3) and little tip are formed; holding frame (1) is used for the clamping entire device to be made it to merge into the entire device structure with external system knot protection is provided; have outer pad (8) on it; outer pad (8) is used for linking to each other with peripheral circuit; support membrane (2) is used for supporting cantilever girder construction and lead (4) and interior pad (5); rely on lead key closing process to be connected between interior pad (5) and the outer pad (8) by gold thread (7); the mode that semi-girder (3) unit employing is tiled in proper order constitutes planar array, and little tip (6) are generated by metal plating.
2. according to little tip surface array device of claim 1, it is characterized in that, holding frame (1), material is a quartz glass, is of a size of the lead-in wire window that 1 centimetre of 0.5 cm x is arranged on 2 centimetres of 3 cm x, thick 0.3 centimetre of roof, 0.5 centimetre of side thickness, the roof.
3. according to little tip surface array device of claim 1, it is characterized in that outer pad (8) is made of 3 millimeters * 1 millimeter, the golden film of thick 100 dusts.
4. according to little tip surface array device of claim 1, it is characterized in that, support membrane (2), thick 2 microns, the lead on it is made of golden films wide 3 microns, thick 100 dusts, is used for semi-girder (3) is linked to each other with interior pad (5).
5. according to little tip surface array device of claim 1, it is characterized in that interior pad (5) is made of 1 millimeter * 1 millimeter, the golden film of thick 100 dusts.
6. according to little tip surface array device of claim 1, it is characterized in that semi-girder (3) is the hollow isosceles triangle on 100 microns on high 400 microns, base, intermediate hollow partly is high 200 microns, the isosceles triangle that the base is 50 microns.
7. according to little tip surface array device of claim 1, it is characterized in that, little tip surface array device, its material of main part is a low stress nitride silicon, thick 2 microns, adhere to golden film on it, thick 100 dusts, acting on of the golden film of this layer is connected little tip with interior pad electricity, it has constituted a kind of pair of variant structure with silicon nitride simultaneously.
8. according to little tip surface array device of claim 1, it is characterized in that little tip (6) electroplate generation by metallic nickel, 5 microns * 5 microns of undercut surfaces sizes, high 7 microns, its most advanced and sophisticated place radius-of-curvature is less than 50 nanometers.
CNB2005100121721A 2005-07-14 2005-07-14 Novel Microtip Area Array Device Expired - Fee Related CN100545951C (en)

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CN100545951C true CN100545951C (en) 2009-09-30

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020072136A1 (en) * 1999-09-27 2002-06-13 Masatoshi Kanamaru Method for manufacturing semiconductor device utilizing semiconductor testing equipment
CN1554119A (en) * 2001-07-26 2004-12-08 ����ŵ����ѧ���й���ίԱ�� Parallel, individually addressable probes for nanolithography
US20050092709A1 (en) * 2003-03-24 2005-05-05 Seoul National University Industry Foundation Microprobe for testing electronic device and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020072136A1 (en) * 1999-09-27 2002-06-13 Masatoshi Kanamaru Method for manufacturing semiconductor device utilizing semiconductor testing equipment
CN1554119A (en) * 2001-07-26 2004-12-08 ����ŵ����ѧ���й���ίԱ�� Parallel, individually addressable probes for nanolithography
US20050092709A1 (en) * 2003-03-24 2005-05-05 Seoul National University Industry Foundation Microprobe for testing electronic device and manufacturing method thereof

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