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CN100516260C - Casting technique for aluminium or aluminium alloy - Google Patents

Casting technique for aluminium or aluminium alloy Download PDF

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Publication number
CN100516260C
CN100516260C CNB2007101144113A CN200710114411A CN100516260C CN 100516260 C CN100516260 C CN 100516260C CN B2007101144113 A CNB2007101144113 A CN B2007101144113A CN 200710114411 A CN200710114411 A CN 200710114411A CN 100516260 C CN100516260 C CN 100516260C
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Prior art keywords
slag
aluminum
aluminium
smelting
agent
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CN101157995A (en
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曹新乐
肖亚明
刘俊东
孙敏
刘庆兵
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ALUMINUM Corp OF CHINA QINGDAO LIGHT METAL Co Ltd
China Aluminum Shandong Co Ltd
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Aluminum Corp of China Ltd
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  • Electrolytic Production Of Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention relates to a technique of aluminum or aluminum casting, which is used for solving the problem of aluminum slag comprising a smelting of aluminum raw material. The invention is characterized in that during the smelting process the slag remover and the refining agent are added, the smelted hot aluminum slag is transferred via a sealed and heat preserved transferring chamber to a hopper, then the hot aluminum slag is poured into a high temperature boiler by a lifter via tilted feeding opening and continuously churned, the aluminum liquid flows out from the bottom of the high temperature boiler and returns to a smelting boiler, the solid aluminum slag enters a chilling roller to be cooled, the chilled solid slag is graded via winnowing, crude and fine slag are obtained, return the crude slag to the smelting, and use the fine slag as the raw material for electrolyte. Selectively addition of slag remover the refine agent, enabling the recycle of aluminum slag and ash produced in the recycling process to completely return and recycle. The invention improves the recycle rate of aluminum and avoids environmental pollution of the aluminum ash.

Description

The aluminum or aluminum alloy casting technique
Technical field
The present invention relates to a kind of improved aluminum or aluminum alloy casting technique, be used to solve aluminium slag problem.
Background technology
Electrolyzer is produced primary aluminum to casting the production product of getting the raw materials ready, the aluminium ash that Foundry Production goes out is placed directly in open-air cooling, cooled aluminium slag is through simply rolling, sieving, aluminum particulate on the sieve is put into the crucible melting, the recovery part aluminium ingot, and undersized aluminium ash is handled as industrial refuse, produce volume of smoke in the extractive process, discharge a large amount of obnoxious flavoures, outcast two secondary aluminium ash fouling environment, while two secondary aluminium ashes contain a large amount of aluminum oxide and are wasted.
Summary of the invention
The object of the present invention is to provide a kind of aluminum or aluminum alloy casting technique, can make the final aluminium slag that produces, all Returning process application of aluminium ash in the recycling process, improve the rate of recovery of aluminium, avoid environmental pollution.
Aluminum or aluminum alloy casting technique of the present invention, comprise aluminum feedstock (remelting aluminium ingot, industrial silicon, magnesium ingot and metal flux) melting, it is characterized in that in fusion process, adding slagging agent and refining agent, the hot aluminium slag of melting is by the airtight insulation transport box hopper of packing into, by lift hot aluminium slag is poured in the high temperature pot body and constantly by oblique material mouth again and stirs, aluminium liquid wherein flows out from the bottom of high temperature pot body and turns back to the smelting furnace, the solid aluminium slag then enters the cooling drum cooling, cooled solid slag is through the selection by winnowing classification, obtain two kinds of slag charges of thickness, with thick slag charge Returning smelting stove, with the raw material of thin slag charge (also claiming the aluminium ash), wherein as electrolysis production:
Slagging agent is the mixture that following weight is formed:
NaCl 20~40%, Na 3AlF 6(sodium aluminum fluoride) 15~25%, NaF 5~10%, Na 2SiF 6(Sodium Silicofluoride) 20~35% and Na 2CO 315~25%;
Refining agent is the mixture that following weight is formed:
NaCl 20~40%, Na 3AlF 6(sodium aluminum fluoride) 10~25%, MgCl 25~15%, NaF 10~25%, Na 2SiF 6(Sodium Silicofluoride) 15~35%, Na 2CO 35~20%, C 2Cl 6(hexachloroethane) 3~20% and AlF 3(aluminum fluoride) 3~10%.
The constitutive material of slagging agent and refining agent is the commercially available prod, is direct purchase, and technical pure gets final product.
By using improved slagging agent and refining agent, thereby can make final aluminium slag and aluminium ash obtain utilizing again fully.
Wherein, the add-on of slagging agent is the 0.05-0.10% of whole alumiunum amount weight; The add-on of refining agent is the 0.1-0.2% of whole alumiunum amount weight, and refining agent preferably adds by duster, the aluminium slag ingredient good uniformity that advantage is melt refining good purification, obtain.
In the thickness slag charge, thick slag charge is 30 mesh sieve oversizes, and composition is a pure aluminum, and thin slag charge is 30 mesh sieve minus mesh, and weight consists of: SiO 20.8-3.0%, Fe 2O 30.23-0.45%, Al 2O 363.4-78.7%, CaO 0-0.10%, MgO 5-10.07%, TiO 20.33-0.61%, Na 2O 6-12%, K 2O 0.07-0.67%, F -1.4-3.8% and Cl -4.85-9.40%, chloride content is low, can satisfy the electrolysis production requirement.
Aluminum or aluminum alloy casting technique of the present invention, slagging agent and refining agent have optionally been added, can make the final aluminium slag that produces, all Returning process application of aluminium ash in the recycling process, improve the rate of recovery of aluminium, avoid the environmental pollution of aluminium ash again.
The performance analysis situation is as follows:
1) to produce 10 tons of calculating of aluminium ash every day, according to production practice, expectation can be reclaimed than former crucible and be improved the rate of recovery 20%, every month about 6 tons of aluminium ingot that reclaim more.
2) be worth 1.8 ten thousand yuan of calculating by recovery aluminium ingot per ton, deduction reclaims the expense (comprising labour cost, the electricity charge, water rate etc.) of aluminium and estimates 1000 yuan/ton, annual 122.4 ten thousand yuan of the economic benefits that reclaim.
3) produce 10 tons of calculating of aluminium ash every day by my company, the thin aluminium ash that wherein can form has 6 tons, annual 2200 tons of the thin aluminium ashes that reclaim, containing aluminum oxide in the wherein thin aluminium ash calculates by 75%, annual 1650 tons in the aluminum oxide of saving, 3000 yuan of calculating, 4,950,000 yuan of the saving value of pressing per ton.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
Aluminum or aluminum alloy casting technique of the present invention, be used for the production of A356.2 alloy, comprise the melting of aluminum feedstock, in fusion process, add the slagging agent of whole alumiunum amount weight 0.08% and add the refining agent of whole alumiunum amount weight 0.12% by duster, the hot aluminium slag of melting is by the airtight insulation transport box hopper of packing into, by lift hot aluminium slag is poured in the high temperature pot body and constantly by oblique material mouth again and stirs, aluminium liquid wherein flows out from the bottom of high temperature pot body and turns back to the smelting furnace, the solid aluminium slag then enters the cooling drum cooling, cooled solid slag is through the selection by winnowing classification, obtain two kinds of slag charges of thickness, thick slag charge is 30 mesh sieve oversizes, and composition is a pure aluminum, thin slag charge is 30 mesh sieve minus mesh, but thick slag charge Returning smelting stove, thin slag charge then can be used as the raw material of electrolysis production, wherein:
Slagging agent is the mixture that following weight is formed:
NaCl 25%, Na 3AlF 620%, NaF 10%, Na 2SiF 625% and Na 2CO 320%;
Refining agent is the mixture that following weight is formed:
NaCl 25%, Na 3AlF 615%, MgCl 210%, NaF 15%, Na 2SiF 620%, Na 2CO 35%, C 2Cl 65% and AlF 35%.
Embodiment 2
Aluminum or aluminum alloy casting technique of the present invention, be used for the production of 6063 alloys, comprise the melting of aluminum feedstock, in fusion process, add the slagging agent of whole alumiunum amount weight 0.07% and add the refining agent of whole alumiunum amount weight 0.1% by duster, the hot aluminium slag of melting is by the airtight insulation transport box hopper of packing into, by lift hot aluminium slag is poured in the high temperature pot body and constantly by oblique material mouth again and stirs, aluminium liquid wherein flows out from the bottom of high temperature pot body and turns back to the smelting furnace, the solid aluminium slag then enters the cooling drum cooling, cooled solid slag is through the selection by winnowing classification, obtain two kinds of slag charges of thickness, thick slag charge is 30 mesh sieve oversizes, and composition is a pure aluminum, thin slag charge is 30 mesh sieve minus mesh, but thick slag charge Returning smelting stove, thin slag charge then can be used as the raw material of electrolysis production, wherein:
Slagging agent is the mixture that following weight is formed:
NaCl 30%, Na 3AlF 615%, NaF 5%, Na 2SiF 630% and Na 2CO 320%;
Refining agent is the mixture that following weight is formed:
NaCl 30%, Na 3AlF 610%, MgCl 210%, NaF 10%, Na 2SiF 615%, Na 2CO 310%, C 2Cl 65% and AlF 310%.
Embodiment 3
Aluminum or aluminum alloy casting technique of the present invention, be used for the production of 6061 alloys, comprise the melting of aluminum feedstock, in fusion process, add the slagging agent of whole alumiunum amount weight 0.06% and add the refining agent of whole alumiunum amount weight 0.15% by duster, the hot aluminium slag of melting is by the airtight insulation transport box hopper of packing into, by lift hot aluminium slag is poured in the high temperature pot body and constantly by oblique material mouth again and stirs, aluminium liquid wherein flows out from the bottom of high temperature pot body and turns back to the smelting furnace, the solid aluminium slag then enters the cooling drum cooling, cooled solid slag is through the selection by winnowing classification, obtain two kinds of slag charges of thickness, thick slag charge is 30 mesh sieve oversizes, and composition is a pure aluminum, thin slag charge is 30 mesh sieve minus mesh, but thick slag charge Returning smelting stove, thin slag charge then can be used as the raw material of electrolysis production, wherein:
Slagging agent is the mixture that following weight is formed:
NaCl 35%, Na 3AlF 615%, NaF 5%, Na 2SiF 620% and Na 2CO 325%;
Refining agent is the mixture that following weight is formed:
NaCl 35%, Na 3AlF 610%, MgCl 25%, NaF 10%, Na 2SiF 615%, Na 2CO 35%, C 2Cl 610% and AlF 310%.
Embodiment 4
Aluminum or aluminum alloy casting technique of the present invention, be used for the production of ZLD102 alloy, comprise the melting of aluminum feedstock, in fusion process, add the slagging agent of whole alumiunum amount weight 0.09% and add the refining agent of whole alumiunum amount weight 0.18% by duster, the hot aluminium slag of melting is by the airtight insulation transport box hopper of packing into, by lift hot aluminium slag is poured in the high temperature pot body and constantly by oblique material mouth again and stirs, aluminium liquid wherein flows out from the bottom of high temperature pot body and turns back to the smelting furnace, the solid aluminium slag then enters the cooling drum cooling, cooled solid slag is through the selection by winnowing classification, obtain two kinds of slag charges of thickness, thick slag charge is 30 mesh sieve oversizes, and composition is a pure aluminum, thin slag charge is 30 mesh sieve minus mesh, but thick slag charge Returning smelting stove, thin slag charge then can be used as the raw material of electrolysis production, wherein:
Slagging agent is the mixture that following weight is formed:
NaCl 20%, Na 3AlF 620%, NaF 10%, Na 2SiF 630% and Na 2CO 320%;
Refining agent is the mixture that following weight is formed:
NaCl 25%, Na 3AlF 610%, MgCl 25%, NaF 10%, Na 2SiF 620%, Na 2CO 315%, C 2Cl 65% and AlF 310%.
Embodiment 5
Aluminum or aluminum alloy casting technique of the present invention, be used for the production of ZLD111 alloy, comprise the melting of aluminum feedstock, in fusion process, add the slagging agent of whole alumiunum amount weight 0.06% and add the refining agent of whole alumiunum amount weight 0.13% by duster, the hot aluminium slag of melting is by the airtight insulation transport box hopper of packing into, by lift hot aluminium slag is poured in the high temperature pot body and constantly by oblique material mouth again and stirs, aluminium liquid wherein flows out from the bottom of high temperature pot body and turns back to the smelting furnace, the solid aluminium slag then enters the cooling drum cooling, cooled solid slag is through the selection by winnowing classification, obtain two kinds of slag charges of thickness, thick slag charge is 30 mesh sieve oversizes, composition is a pure aluminum, thin slag charge is 30 mesh sieve minus mesh, but thick slag charge Returning smelting stove, thin slag charge then can be used as the raw material of electrolysis production, and wherein: slagging agent is the mixture that following weight is formed:
NaCl 37%, Na 3AlF 618%, NaF 7%, Na 2SiF 623% and Na 2CO 315%;
Refining agent is the mixture that following weight is formed:
NaCl 32%, Na 3AlF 613%, MgCl 25%, NaF 13%, Na 2SiF 617%, Na 2CO 310%, C 2Cl 64% and AlF 36%.

Claims (3)

1, a kind of aluminum or aluminum alloy casting technique, comprise the melting of aluminum feedstock, it is characterized in that in fusion process, adding slagging agent and refining agent, the hot aluminium slag of melting is by the airtight insulation transport box hopper of packing into, by lift hot aluminium slag is poured in the high temperature pot body and constantly by oblique material mouth again and stirs, aluminium liquid wherein flows out from the bottom of high temperature pot body and turns back to the smelting furnace, the solid aluminium slag then enters the cooling drum cooling, cooled solid slag is through the selection by winnowing classification, obtain two kinds of slag charges of thickness, with thick slag charge Returning smelting stove, with the raw material of thin slag charge, wherein as electrolysis production:
Slagging agent is the mixture that following weight is formed:
NaCl 20~40%, Na 3AlF 615~25%, NaF 5~10%, Na 2SiF 620~35% and Na 2CO 315~25%;
The add-on of slagging agent is the 0.05-0.10% of whole alumiunum amount weight;
Refining agent is the mixture that following weight is formed:
NaCl 20~40%, Na 3AlF 610~25%, MgCl 25~15%, NaF 10~25%, Na 2SiF 615~35%, Na 2CO 35~20%, C 2Cl 63~20% and AlF 33~10%;
The add-on of refining agent is the 0.1-0.2% of whole alumiunum amount weight.
2, aluminum or aluminum alloy casting technique according to claim 1 is characterized in that refining agent adds by duster.
3, aluminum or aluminum alloy casting technique according to claim 1 and 2 is characterized in that in the thickness slag charge, and thick slag charge is 30 mesh sieve oversizes, and thin slag charge is 30 mesh sieve minus mesh.
CNB2007101144113A 2007-11-09 2007-11-09 Casting technique for aluminium or aluminium alloy Active CN100516260C (en)

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Application Number Priority Date Filing Date Title
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CN100516260C true CN100516260C (en) 2009-07-22

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Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101423910B (en) * 2008-12-12 2010-06-09 机械科学研究总院先进制造技术研究中心 Refining agent for aluminum and low magnesium aluminum alloy
CN101423909B (en) * 2008-12-12 2010-06-09 葛学元 Refining agent for alloy and method for producing the same
CN102009164B (en) * 2010-12-07 2012-07-04 陕西宏远航空锻造有限责任公司 Casting method for ZL205 aluminium alloy investment casting
CN102181657B (en) * 2011-03-23 2012-09-19 四川鑫星铝业有限责任公司 Aluminum-magnesium alloy slag removing agent, method for producing aluminum-magnesium alloy ingot and aluminum-magnesium alloy ingot
CN102644002B (en) * 2012-05-16 2013-09-04 山东滨州渤海活塞股份有限公司 Aluminium alloy solution refined chlorine-free slag remover
CN102925732B (en) * 2012-09-26 2014-05-07 霍山县龙鑫金属制品有限公司 Method for smelting aluminium alloy doped with magnesium element
CN103695656A (en) * 2013-12-04 2014-04-02 台澳铝业(台山)有限公司 Method for recycling aluminum ash
CN103725914A (en) * 2013-12-31 2014-04-16 焦作市圣昊铝业有限公司 Aluminum alloy refining agent
CN105087991A (en) * 2015-08-24 2015-11-25 重庆旗能电铝有限公司 Method for comprehensively recycling aluminum slag in aluminum casting production
CN105483403B (en) * 2015-11-27 2017-09-05 贵州航天风华精密设备有限公司 A kind of aluminium alloy smelting method
CN106399693A (en) * 2016-10-08 2017-02-15 淄博海慧工程设计咨询有限公司 Overall treatment and utilization method for aluminum ash
CN106498213A (en) * 2016-10-25 2017-03-15 嘉善蓝欣涂料有限公司 A kind of high fluidity aluminium alloy refining agent and preparation method thereof
CN108754182B (en) * 2018-06-26 2020-09-08 云南省环境科学研究院(中国昆明高原湖泊国际研究中心) Resource treatment method for aluminum alloy casting aluminum slag
CN112481512B (en) * 2020-10-20 2021-10-12 保定隆达铝业有限公司 Method for treating yellowing of aluminum alloy ingot surface
CN113832345A (en) * 2021-08-12 2021-12-24 肖呈辉 Municipal administration environmental protection is with aluminium product rubbish recovery founding equipment
CN113699404B (en) * 2021-08-25 2022-06-24 苏州大学 Composite salt for purifying aluminum waste and preparation and use methods thereof
CN115058614B (en) * 2022-08-05 2022-11-08 广东鸿邦金属铝业有限公司 Preparation method and smelting device of high-strength high-heat-conductivity aluminum alloy
CN115595454B (en) * 2022-10-27 2024-01-05 广东邦普循环科技有限公司 Method for recycling aluminum from waste lithium battery positive plate to generate aluminum ingot

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Effective date of registration: 20170706

Address after: Nam Dinh town Zhangdian District Shandong city Zibo province 255052 five km road No.

Co-patentee after: China Aluminum Shandong Co., Ltd.

Patentee after: Shandong Aluminium Industry Co.

Address before: 100082 No. 62 North Main Street, Beijing, Xizhimen

Patentee before: Aluminum Corporation of China Limited

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Effective date of registration: 20190510

Address after: 266431 No. 889 Dazhushan North Road, Huangdao District, Qingdao City, Shandong Province, Lingang Economic Development Zone

Co-patentee after: China Aluminum Shandong Co., Ltd.

Patentee after: Aluminum Corporation of China, Qingdao Light Metal Co., Ltd.

Address before: 255052 No. 1, Wukm Road, Nanding Town, Zhangdian District, Zibo City, Shandong Province

Co-patentee before: China Aluminum Shandong Co., Ltd.

Patentee before: Shandong Aluminium Industry Co.

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