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CN100511792C - Integrated fuel cell for optimization design for hydrogen gas access channels and circulating uses - Google Patents

Integrated fuel cell for optimization design for hydrogen gas access channels and circulating uses Download PDF

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CN100511792C
CN100511792C CNB2004100677136A CN200410067713A CN100511792C CN 100511792 C CN100511792 C CN 100511792C CN B2004100677136 A CNB2004100677136 A CN B2004100677136A CN 200410067713 A CN200410067713 A CN 200410067713A CN 100511792 C CN100511792 C CN 100511792C
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hydrogen
fuel cell
fuel battery
cell stack
recycling
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CN1770527A (en
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胡里清
夏建伟
付明竹
章波
赵景辉
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State Grid Corp of China SGCC
Shanghai Municipal Electric Power Co
Shanghai Shenli Technology Co Ltd
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Shanghai Shen Li High Tech Co Ltd
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Abstract

本发明提供了一种对氢气进出通道及循环利用优化设计的集成式燃料电池,其特点是,其中的总进氢气通道为一平滑管道,水平设置在一集流端面板的外侧或集流中间面板内,由总进氢气通道侧面分流出多个支进氢气通道分别与各燃料电池堆模块的支氢气进口相连;其中的各燃料电池堆模块的支出氢气通道分别直接从另一集流端面板或集流中间面板引出;其中的氢气循环利用装置设置了组合电磁阀,组合电磁阀中各单阀的进口分别连通各燃料电池堆模块的支出氢气通道。采用本发明的技术,能避免冷凝水积存在总进氢气通道内,可全部由过量的氢气及时带出燃料电池,还具有节能、降噪和少占空间的有益效果。

The present invention provides an integrated fuel cell with optimized design for hydrogen inlet and outlet passages and recycling, which is characterized in that the total hydrogen inlet passage is a smooth pipe, which is horizontally arranged on the outside of a collector end panel or in the middle of the collector In the panel, a plurality of branch hydrogen channels branched from the side of the main hydrogen inlet channel are respectively connected to the branch hydrogen inlets of each fuel cell stack module; the outgoing hydrogen channels of each fuel cell stack module are directly connected to the other collector end panel. Or lead out from the middle panel of the current collection; the hydrogen recycling device is provided with a combined solenoid valve, and the inlets of each single valve in the combined solenoid valve are respectively connected to the outgoing hydrogen channels of each fuel cell stack module. By adopting the technology of the present invention, it is possible to prevent condensed water from accumulating in the general inlet hydrogen channel, and all the excess hydrogen can be taken out of the fuel cell in time, and it also has the beneficial effects of energy saving, noise reduction and less space occupation.

Description

对氢气进出通道及循环利用优化设计的集成式燃料电池 An integrated fuel cell with optimized design for hydrogen inlet and outlet channels and recycling

技术领域 technical field

本发明涉及一种燃料电池,尤其涉及一种对氢气进出通道及循环利用优化设计的集成式燃料电池。The invention relates to a fuel cell, in particular to an integrated fuel cell with an optimized design for hydrogen inlet and outlet passages and recycling.

背景技术 Background technique

燃料电池是一种能够将燃料与氧化剂发生电化学反应时产生的化学能转变成电能的装置。该装置的核心部件是膜电极(Membrane Electrode Assembly,简称MEA),膜电极由一张质子交换膜和夹在膜两面的两张可导电多孔性扩散材料(如碳纸)组成,在质子交换膜与导电材料接触的两边界面上均匀分布有细小分散的可引发电化学反应的催化剂(如金属铂)。膜电极两边用导电物体将发生电化学反应过程中产生的电子通过外电路引出,就构成了电流回路。A fuel cell is a device that converts the chemical energy generated during the electrochemical reaction of fuel and oxidant into electrical energy. The core component of the device is the membrane electrode (Membrane Electrode Assembly, referred to as MEA). The membrane electrode consists of a proton exchange membrane and two conductive porous diffusion materials (such as carbon paper) sandwiched on both sides of the membrane. A finely dispersed catalyst (such as metal platinum) that can initiate an electrochemical reaction is evenly distributed on the two boundary surfaces that are in contact with the conductive material. On both sides of the membrane electrode, the electrons generated during the electrochemical reaction are drawn out through the external circuit with conductive objects, forming a current loop.

在膜电极的阳极端,燃料可以通过渗透穿过多孔性扩散材料(如碳纸),并在催化剂表面发生电化学反应,失去电子形成正离子,正离子可通过迁移穿过质子交换膜,到达膜电极的另一端—阴极端。在膜电极的阴极端,含有氧化剂(如氧气)的气体(如空气),通过渗透穿过多孔性扩散材料(如碳纸),并在催化剂表面发生电化学反应,得到电子形成负离子,该负离子进一步与从阳极端迁移过来的正离子结合,形成反应产物。At the anode end of the membrane electrode, the fuel can permeate through the porous diffusion material (such as carbon paper), and an electrochemical reaction occurs on the surface of the catalyst, losing electrons to form positive ions, which can migrate through the proton exchange membrane to reach The other end of the membrane electrode - the cathode end. At the cathode end of the membrane electrode, a gas (such as air) containing an oxidant (such as oxygen) penetrates through a porous diffusion material (such as carbon paper) and undergoes an electrochemical reaction on the surface of the catalyst to obtain electrons to form negative ions. It further combines with positive ions migrated from the anode end to form a reaction product.

在以氢气为燃料、以含有氧气的空气为氧化剂(或以纯氧为氧化剂)的质子交换膜燃料电池中,燃料氢气在阳极区发生失去电子的催化电化学反应,形成氢正离子(质子),其电化学反应方程式为:In a proton exchange membrane fuel cell using hydrogen as fuel and oxygen-containing air as oxidant (or pure oxygen as oxidant), fuel hydrogen undergoes a catalytic electrochemical reaction in which electrons are lost in the anode region to form hydride ions (protons), Its electrochemical reaction equation is:

阳极反应:H2→2H++2eAnode reaction: H 2 → 2H + +2e

氧气在阴极区发生得到电子的催化电化学反应,形成负离子,该负离子进一步与从阳极端迁移过来的氢正离子结合,形成反应产物水。其电化学反应方程式为:Oxygen undergoes a catalytic electrochemical reaction in the cathode region to obtain electrons to form negative ions, which are further combined with hydrogen positive ions migrated from the anode terminal to form the reaction product water. Its electrochemical reaction equation is:

阴极反应:1/2O2+2H++2e→H2OCathode reaction: 1/2O 2 +2H + +2e→H 2 O

燃料电池中的质子交换膜除了用于发生电化学反应以及迁移交换反应中产生的质子外,其作用还包括将含有燃料氢气的气流与含有氧化剂(氧气)的气流分隔开来,使它们不会相互混合而产生爆炸式反应。The proton exchange membrane in the fuel cell is not only used for the electrochemical reaction and the protons generated in the transfer exchange reaction, but also to separate the gas flow containing fuel hydrogen from the gas flow containing oxidant (oxygen) so that they do not Will mix with each other to produce an explosive reaction.

在典型的质子交换膜燃料电池中,膜电极一般放在两块导电的极板之间,两极板上均开设有导流槽,因此又称作导流极板。导流槽开设在与膜电极接触的表面上,通过压铸、冲压或机械铣刻形成,其数量在一条以上。导流极板可以由金属材料制成,也可以由石墨材料制成。导流极板上的导流槽的作用是将燃料或氧化剂分别导入膜电极两边的阳极区或阴极区。在一个质子交换膜燃料电池单电池的构造中,只存在一个膜电极和两块导流极板,两块导流极板分设在膜电极两边,一个作为阳极燃料的导流极板,另一个作为阴极氧化剂的导流极板。这两块导流极板既作为电流集流板,也是膜电极两边的机械支撑。导流极板上的导流槽既是燃料或氧化剂进入阳极或阴极表面的通道,也是将电池运行过程中生成的水带走的出水通道。In a typical proton exchange membrane fuel cell, the membrane electrode is generally placed between two conductive plates, and diversion grooves are opened on both plates, so it is also called a diversion plate. The diversion groove is opened on the surface in contact with the membrane electrode, formed by die-casting, stamping or mechanical milling, and its number is more than one. The guide plate can be made of metal material or graphite material. The function of the diversion groove on the diversion plate is to introduce fuel or oxidant into the anode area or cathode area on both sides of the membrane electrode respectively. In the structure of a single proton exchange membrane fuel cell, there is only one membrane electrode and two guide plates, and the two guide plates are arranged on both sides of the membrane electrode, one is used as the guide plate for the anode fuel, and the other As a guide plate for cathode oxidant. These two guide plates are not only used as current collector plates, but also as mechanical support on both sides of the membrane electrode. The diversion groove on the diversion plate is not only a channel for fuel or oxidant to enter the surface of the anode or cathode, but also a water outlet channel to take away the water generated during the operation of the battery.

为了增大质子交换膜燃料电池的功率,通常将两个或两个以上的单电池通过直叠的方式或平铺的方式连在一起组成电池组,或称作电池堆。这种电池组通常通过前端板、后端板及拉杆紧固在一起成为一体。在电池组中,位于两质子交换膜之间的极板的两面都设有导流槽,称为双极板。双极板的其中一面作为一个膜电极的阳极导流面,另一面则作为另一个相邻膜电极的阴极导流面。一个典型的电池组通常还包括:1)、燃料及氧化剂气体的进口和导流通道。其作用是将燃料(如氢气、甲醇或由甲醇、天然气、汽油经重整后得到的富氢气体)和氧化剂(主要是氧气或空气)均匀地分布到各个阳极、阴极面的导流槽中;2)、冷却流体(如水)的进、出口与导流通道。其作用是将冷却流体均匀地分布到各个电池组内的冷却通道中,吸收燃料电池内产生的反应热并将其带出电池组进行散热;3)、燃料与氧化剂气体的出口与导流通道。其作用是将没有参与反应的多余燃料气体和氧化剂排出,同时将反应生成的液态或气态的水带出。上述燃料进出口、氧化剂进出口和冷却流体的进出口通常都开设在燃料电池组的一个端板上或分别开设在两个端板上。In order to increase the power of a proton exchange membrane fuel cell, two or more single cells are usually connected together in a straight stacked or tiled manner to form a cell group, or called a cell stack. Such a battery pack is usually fastened together by a front end plate, a rear end plate and a pull rod to form a whole. In the battery pack, the two sides of the pole plate between the two proton exchange membranes are provided with diversion grooves, which are called bipolar plates. One side of the bipolar plate is used as the anode flow guide surface of one membrane electrode, and the other side is used as the cathode flow guide surface of another adjacent membrane electrode. A typical battery pack usually also includes: 1), inlets and diversion channels for fuel and oxidant gases. Its function is to evenly distribute fuel (such as hydrogen, methanol, or hydrogen-rich gas obtained by reforming methanol, natural gas, and gasoline) and oxidant (mainly oxygen or air) into the diversion grooves on each anode and cathode surface ; 2), the inlet, outlet and diversion channel of cooling fluid (such as water). Its function is to evenly distribute the cooling fluid to the cooling channels in each battery pack, absorb the reaction heat generated in the fuel cell and take it out of the battery pack for heat dissipation; 3), the outlet and guide channel of fuel and oxidant gas . Its function is to discharge the excess fuel gas and oxidant that did not participate in the reaction, and at the same time take out the liquid or gaseous water generated by the reaction. The above-mentioned fuel inlet and outlet, oxidant inlet and outlet and cooling fluid inlet and outlet are usually set on one end plate of the fuel cell stack or respectively set on two end plates.

质子交换膜燃料电池可用作车、船等运载工具的动力系统,又可制作成移动式或固定式的发电装置。The proton exchange membrane fuel cell can be used as the power system of vehicles, ships and other vehicles, and can also be made into mobile or fixed power generation devices.

在质子交换膜燃料电池用作车、船的动力系统和移动式或固定式的发电装置时,必须包括电池堆、燃料氢气供应子系统、空气供应子系统、冷却散热子系统、自动控制机构及电能输出机构各个部分。When the proton exchange membrane fuel cell is used as a power system of a vehicle or a ship and a mobile or fixed power generation device, it must include a battery stack, a fuel hydrogen supply subsystem, an air supply subsystem, a cooling and heat dissipation subsystem, an automatic control mechanism and Various parts of the power output mechanism.

图1为燃料电池发电系统的基本组成示意图。图中标号,1为燃料电池堆,2为储氢瓶或其它储氢装置,3为减压阀,4为空气过滤装置,5为空气压缩供应装置,6、6’为水-汽分离器,7为水箱,8为冷却流体循环泵,9为散热器,10为氢循环泵,11、12为增湿装置,13为氢稳压阀。Figure 1 is a schematic diagram of the basic components of a fuel cell power generation system. In the figure, 1 is a fuel cell stack, 2 is a hydrogen storage bottle or other hydrogen storage device, 3 is a pressure reducing valve, 4 is an air filter device, 5 is an air compression supply device, 6, 6' are water-steam separators , 7 is a water tank, 8 is a cooling fluid circulation pump, 9 is a radiator, 10 is a hydrogen circulation pump, 11 and 12 are humidifying devices, and 13 is a hydrogen pressure stabilizing valve.

为了提高燃料电池整个发电系统的能量转换效率,除了提高燃料电池的电极性能以外,提高燃料电池发电系统的氢气利用率非常重要。氢气供应及循环利用对提高燃料电池发电系统的氢气利用率,及保证燃料电池发电系统的运行稳定性有关键作用。燃料氢气经过减压、稳压后,又经过增湿装置输送进入燃料电池堆与电极另一侧的氧化剂发生电化学发应。在电极的氢气供应一侧随着反应不断进行,会慢慢产生水。这些水主要来自二个方面,一是增湿后的氢气携带一部分水进入燃料电池堆,氢气反应掉后,水就留下来;另一部分是在电极阴极侧由电化学反应生成的水经过膜电极反渗透到电极阳极侧。为了将这二部分水从电极阳极侧带出燃料电池堆,必须向燃料电池堆供应大于1.0计量比的氢气流量,使氢气过量,通过过量的氢气在离开燃料电池堆时将这二部分水带出。In order to improve the energy conversion efficiency of the entire fuel cell power generation system, in addition to improving the electrode performance of the fuel cell, it is very important to improve the hydrogen utilization rate of the fuel cell power generation system. Hydrogen supply and recycling play a key role in improving the hydrogen utilization rate of the fuel cell power generation system and ensuring the operation stability of the fuel cell power generation system. After the fuel hydrogen has been decompressed and stabilized, it is transported into the fuel cell stack through the humidification device to react electrochemically with the oxidant on the other side of the electrode. Water is slowly produced on the hydrogen supply side of the electrode as the reaction proceeds. The water mainly comes from two aspects. One is that the humidified hydrogen carries part of the water into the fuel cell stack. After the hydrogen reacts, the water remains; the other part is the water generated by the electrochemical reaction on the cathode side of the electrode through the membrane electrode. Reverse osmosis into the anode side of the electrode. In order to take these two parts of water out of the fuel cell stack from the anode side of the electrode, it is necessary to supply the fuel cell stack with a hydrogen flow rate greater than 1.0 stoichiometric ratio, so that the hydrogen is in excess, and the two parts of the water will be carried by the excess hydrogen when leaving the fuel cell stack. out.

为了同时做到既可以将过量的氢气循环使用,又可以将燃料电池堆中电极的氢气供应一侧的水带出,目前采用的技术是利用氢气循环泵或氢气循环装置的技术。如图1所示,在氢气出口管路上设置一台水汽分离器6,在水汽分离器6与氢气进口管道之间设置一台氢气循环泵10。通过氢气循环泵将过量的氢气回收,重新进入燃料电池堆参与反应,同时又可以将上述二部分水带出燃料电池堆。如专利技术“一种适合低压运行的燃料电池氢气循环利用装置”,中国专利号为03255444.3。In order to simultaneously recycle excess hydrogen and take out the water on the hydrogen supply side of the electrode in the fuel cell stack, the current technology is to use a hydrogen circulation pump or a hydrogen circulation device. As shown in FIG. 1 , a water vapor separator 6 is arranged on the hydrogen outlet pipeline, and a hydrogen circulation pump 10 is arranged between the water vapor separator 6 and the hydrogen inlet pipeline. The excess hydrogen is recovered by the hydrogen circulation pump, and re-enters the fuel cell stack to participate in the reaction, and at the same time, the above-mentioned two parts of water can be taken out of the fuel cell stack. For example, the patented technology "a fuel cell hydrogen recycling device suitable for low-voltage operation", the Chinese patent number is 03255444.3.

上述氢气循环利用技术对单燃料电池堆是比较合适的。但应用于由多个单燃料电池堆模块经集成方式构成的大型燃料电池堆时,就会出现问题。The hydrogen recycling technology mentioned above is more suitable for a single fuel cell stack. However, when applied to large fuel cell stacks composed of multiple single fuel cell stack modules integrated in an integrated manner, problems arise.

实际上,目前燃料电池发电系统用于运载工具的动力系统或用作发电站,都要求有很高的功率输出。这种高的功率输出要求燃料电池堆必须实现高电压、大电流输出。为了实现大功率的燃料电池堆,有必要将多个单燃料电池堆模块经集成方式构成体积上较紧凑的大燃料电池堆。例如“US Patent5486430”的方法,将多个单燃料电池堆平行排列,每个单燃料电池堆的所有空气、氢气、冷却水的进口、出口统一集成到一块共用的前端面板上或后端面板上。前端面板与后端面板上设有供所有单燃料电池堆上的所有空气、氢气、冷却流体的进、出口共用的六大流体通道。再例如上海神力科技有限公司的专利“一种集成式的燃料电池(专利号:02265512.3)”所描述的方法,由多个燃料电池堆共用一块集流面板,该集流面板上的前、后集成了多个燃料电池堆。该集流面板设置在多个燃料电池堆的中间,所有燃料电池堆的空气、氢气、冷却流体的进、出口都统一集成到这块共用集流面板上。该集流面板上设有供所有燃料电池堆上的所有空气、氢气、冷却流体的进、出口共用的六大流体通道。In fact, the current fuel cell power generation system is used as a power system of a vehicle or as a power station, which requires a high power output. This high power output requires that the fuel cell stack must achieve high voltage and high current output. In order to realize a high-power fuel cell stack, it is necessary to integrate multiple single fuel cell stack modules to form a relatively compact large fuel cell stack. For example, the method of "US Patent5486430" arranges multiple single fuel cell stacks in parallel, and integrates all air, hydrogen, and cooling water inlets and outlets of each single fuel cell stack into a common front panel or rear panel. . The front panel and the rear panel are provided with six fluid passages shared by the inlets and outlets of all air, hydrogen, and cooling fluids on all single fuel cell stacks. Another example is the method described in the patent "An Integrated Fuel Cell (Patent No.: 02265512.3)" of Shanghai Shenli Technology Co., Ltd., a plurality of fuel cell stacks share a collector panel, and the front and rear panels on the collector panel Multiple fuel cell stacks are integrated. The collector panel is arranged in the middle of multiple fuel cell stacks, and the inlets and outlets of air, hydrogen, and cooling fluid of all fuel cell stacks are uniformly integrated on this common collector panel. The collecting panel is provided with six common fluid passages for the inlets and outlets of all air, hydrogen, and cooling fluids on all fuel cell stacks.

上述通过各种方法实现的集成式燃料电池,每个燃料电池堆模块虽然共用各流体通道,但每个模块都有自己的正、负集流母板,通过对所有的燃料电池模块上的正、负极母板进行串、并联连接,整个集成式燃料电池可以输出符合实际需要的高电压、大电流的要求。For the above-mentioned integrated fuel cells realized by various methods, although each fuel cell stack module shares each fluid channel, each module has its own positive and negative current collector motherboards. , Negative motherboards are connected in series and in parallel, and the entire integrated fuel cell can output high voltage and high current requirements that meet actual needs.

对更大功率输出的燃料电池发电系统,原则上可以通过集成更多的燃料电池堆模块,并让所有的燃料电池堆模块上的所有空气、氢气、冷却流体的进、出口共用六大流体通道,即集成后的大燃料电池堆同样是一种具有总空气、总氢气、总冷却流体进、出口的六大流体通道的一体化结构。For a fuel cell power generation system with a higher power output, in principle, it is possible to integrate more fuel cell stack modules, and let all the air, hydrogen, and cooling fluid inlets and outlets on all fuel cell stack modules share six fluid channels , that is, the integrated large fuel cell stack is also an integrated structure with six fluid channels for total air, total hydrogen, and total cooling fluid inlets and outlets.

为了使集成式燃料电池具有更高的体积、重量、功率密度,必须将集成式燃料电池前端集流面板、后端集流面板或中间总集流面板进行最紧凑的工程设计,例如:US Patent 6159629,对一种集成式燃料电池前端集流面板与后端集流面板,采用了一种导流层面结构歧管设计,如图2、图3、图4所示。In order to make the integrated fuel cell have higher volume, weight, and power density, the most compact engineering design must be carried out on the integrated fuel cell front-end collector panel, rear-end collector panel or intermediate total collector panel, for example: US Patent 6159629, for an integrated fuel cell front-end collector panel and rear-end collector panel, a diversion layer structure manifold design is adopted, as shown in Figure 2, Figure 3, and Figure 4.

上述集成式燃料电池集流面板上的导流层面歧管设计技术可以让集成式燃料电池中每个燃料电池堆模块上的所有空气、氢气、冷却流体的进、出口共用六大流体通道,每一总流体通道构成了集流面板内部的一个层面,而每一个层面都有单独的导流管道口引出,构成集成式燃料电池总空气、总氢气、总冷却流体进出口的六大流体口。The diversion level manifold design technology on the above-mentioned integrated fuel cell manifold panel allows all the inlets and outlets of air, hydrogen, and cooling fluid on each fuel cell stack module in the integrated fuel cell to share six fluid channels. A total fluid channel constitutes a layer inside the collector panel, and each layer has a separate guide pipe outlet to form six fluid ports for the total air, total hydrogen, and total cooling fluid inlet and outlet of the integrated fuel cell.

上述技术虽然在设计上使集成式燃料电池达到了体积紧凑,大大提高体积功率密度的目的,但是在进行氢燃料循环利用时,会有以下技术缺陷:Although the above-mentioned technology enables the integrated fuel cell to achieve a compact size and greatly improve the volume power density in terms of design, it will have the following technical defects when hydrogen fuel is recycled:

1、每种流体先从集成式燃料电池集流面板的总进流体口进入,先充满—个层面,再分流到各个燃料电池模块。为了增加集成式燃料电池体积功率密度,往往这个总进流体通道构成的整个层面比较窄,而各个燃料电池模块的各个支进流体口并不是完全占据了整个层面的面积,而是只占据了整个层面的一小部分(如图3、图4、图5所示)。当总进流体是单一相的流体,如冷却流体—水时,由流体完全充满整个窄层层面的总进流体通道,然后均匀地从各个燃料电池模块的各个分进流体口进入,不会产生什么问题。但是当流体是由大部分气、少量液组成的二相流动状态时,气相流体很容易充满整个窄层层面的总进流体通道,并可以均匀地在各个燃料电池模块的各个分进流体口进入,而少量液态流体(往往是冷凝水)则会积留在窄层层面的总进流体通道中,并且当积聚很多后,往往会导致随机分配到某个燃料电池模块中,造成气相流动的导流槽充满液态水而堵塞。1. Each fluid first enters from the main fluid inlet of the integrated fuel cell manifold panel, fills one layer first, and then distributes to each fuel cell module. In order to increase the volumetric power density of the integrated fuel cell, the overall level formed by the main inlet fluid channel is often relatively narrow, and the branch inlet fluid ports of each fuel cell module do not completely occupy the area of the entire level, but only occupy the entire level. A small part of the layer (as shown in Figure 3, Figure 4, and Figure 5). When the inlet fluid is a single-phase fluid, such as cooling fluid—water, the inlet fluid channel of the entire narrow layer is completely filled by the fluid, and then enters evenly from each inlet fluid port of each fuel cell module, and no what is the problem. However, when the fluid is in a two-phase flow state composed of most of the gas and a small amount of liquid, the gas-phase fluid can easily fill the general inlet fluid channel at the entire narrow layer level, and can evenly enter the inlet fluid at each inlet fluid port of each fuel cell module. , and a small amount of liquid fluid (often condensed water) will accumulate in the general inlet fluid channel at the narrow layer level, and when accumulated in a large amount, it will often lead to random allocation to a certain fuel cell module, resulting in the conduction of gas phase flow. Launder filled with liquid water and clogged.

上述情况在集成式燃料电池中的总进氢气通道中经常发生,增湿后的氢气由于发生流速变化及温度变化而冷凝出少部分液态水,长时间积聚很多水后,容易随氢气流动,并造成各个燃料电池模块中某个或数个单电池中的氢气导流槽中发生堵水。某个单电池氢气导流槽中堵水会造成该单电池燃料氢处于饥饿状态,电压急剧下降,严重时会烧坏该电极。The above situation often occurs in the total inlet hydrogen channel in the integrated fuel cell. Due to the change of flow rate and temperature, the humidified hydrogen condenses a small part of liquid water. After accumulating a lot of water for a long time, it is easy to flow with the hydrogen and Cause water blockage in the hydrogen guide groove in one or several single cells in each fuel cell module. Blockage of water in the hydrogen diversion tank of a single cell will cause the fuel hydrogen of the single cell to be starved, the voltage will drop sharply, and the electrode will be burned out in severe cases.

2、在采用氢气循环泵等氢气循环利用装置时,为了将整个集成式燃料电池堆中每个燃料电池堆模块中氢侧的水带出来,必须采用循环流量很大的氢气循环泵或氢气循环利用装置,这种总循环氢流量很大的装置需要消耗很大的功率,降低了整个燃料电池发电系统的发电效率,即燃料氢气的转换效率。而且这种总循环氢流量很大的装置往往占据了整个燃料电池发电系统中很大的体积空间,并增加了重量,往往噪声也较大。2. When hydrogen recycling devices such as hydrogen circulation pumps are used, in order to bring out the water on the hydrogen side of each fuel cell stack module in the entire integrated fuel cell stack, a hydrogen circulation pump or hydrogen circulation with a large circulation flow rate must be used Using the device, such a device with a large total circulating hydrogen flow rate consumes a lot of power, which reduces the power generation efficiency of the entire fuel cell power generation system, that is, the conversion efficiency of fuel hydrogen. Moreover, such a device with a large total circulating hydrogen flow rate often occupies a large volume space in the entire fuel cell power generation system, increases weight, and often has relatively high noise.

发明内容 Contents of the invention

本发明的目的就是为了解决上述问题而提供一种对氢气进出通道及循环利用优化设计的集成式燃料电池,它能避免冷凝水积存在总进氢气通道内。The object of the present invention is to provide an integrated fuel cell with an optimized design for hydrogen inlet and outlet passages and recycling in order to solve the above problems, which can prevent condensed water from accumulating in the total hydrogen inlet passage.

本发明的目的是这样实现的:一种对氢气进出通道及循环利用优化设计的集成式燃料电池,包括由至少两个燃料电池堆模块组成的集成式燃料电池堆和氢气循环利用装置,在集成式燃料电池堆的两端各设有集流端面板,或在集成式燃料电池堆的中间设有集流中间面板,在一集流端面板上或在集流中间面板内设有总进氢气通道,各燃料电池堆模块分别设有支进氢气通道和支出氢气通道,氢气循环利用装置包括氢循环泵和水汽分离器,其特点是:The object of the present invention is achieved in this way: an integrated fuel cell optimized for hydrogen inlet and outlet channels and recycling, including an integrated fuel cell stack and a hydrogen recycling device composed of at least two fuel cell stack modules, integrated Both ends of the integrated fuel cell stack are provided with collector end panels, or a collector middle panel is provided in the middle of the integrated fuel cell stack, and a total inlet hydrogen gas is provided on a collector end panel or in the collector middle panel. Channels, each fuel cell stack module is respectively provided with a branch hydrogen channel and an outgoing hydrogen channel. The hydrogen recycling device includes a hydrogen circulation pump and a water vapor separator. Its characteristics are:

所述的总进氢气通道为一平滑管道,其水平设置在一集流端面板的外侧或集流中间面板内,由总进氢气通道侧面分流出多个支进氢气通道分别与各燃料电池堆模块的支氢气进口相连;The general inlet hydrogen channel is a smooth pipe, which is horizontally arranged on the outside of a collector end panel or in the collector middle panel, and a plurality of branch hydrogen inlet channels are branched from the side of the total inlet hydrogen channel to connect with each fuel cell stack respectively. The hydrogen inlet of the module is connected;

所述的各燃料电池堆模块的支出氢气通道分别直接从另一集流端面板或集流中间面板引出;The outlet hydrogen channels of each of the fuel cell stack modules are respectively directly drawn from another collector end panel or collector middle panel;

所述的氢气循环利用装置还包括一组合电磁阀,组合电磁阀中各单阀的进口分别连通各燃料电池堆模块的支出氢气通道,组合电磁阀中各单阀的出口分别通过一根总管与水汽分离器连通。The hydrogen recycling device also includes a combination solenoid valve, the inlets of each single valve in the combination solenoid valve are respectively connected to the outgoing hydrogen passages of each fuel cell stack module, and the outlets of each single valve in the combination solenoid valve are respectively connected through a main pipe and The water vapor separator is connected.

所述的各支进氢气通道的有效通径小于总进氢气通道的有效通径。The effective diameter of each branch hydrogen inlet channel is smaller than the effective diameter of the main hydrogen inlet channel.

所述的组合电磁阀中的各单阀可以分别依次导通,实现间歇式、脉冲式的对各燃料电池堆模块的氢燃料进行循环。Each of the single valves in the combined solenoid valve can be conducted sequentially to realize intermittent and pulsed hydrogen fuel circulation of each fuel cell stack module.

所述的集成式燃料电池堆由六个燃料电池堆模块组成,相应氢气循环利用装置中的组合电磁阀由六个单电磁阀组合而成。The integrated fuel cell stack is composed of six fuel cell stack modules, and the combined solenoid valve in the corresponding hydrogen recycling device is composed of six single solenoid valves.

所述的集成式燃料电池堆由三个燃料电池堆模块组成,相应氢气循环利用装置中的组合电磁阀由三个单电磁阀组合而成。The integrated fuel cell stack is composed of three fuel cell stack modules, and the combined solenoid valve in the corresponding hydrogen recycling device is composed of three single solenoid valves.

所述的集成式燃料电池堆由八个燃料电池堆模块组成,相应氢气循环利用装置中的组合电磁阀由八个单电磁阀组合而成。The integrated fuel cell stack is composed of eight fuel cell stack modules, and the combined solenoid valve in the corresponding hydrogen recycling device is composed of eight single solenoid valves.

所述的集成式燃料电池堆由十个燃料电池堆模块组成,相应氢气循环利用装置中的组合电磁阀由十个单电磁阀组合而成。The integrated fuel cell stack is composed of ten fuel cell stack modules, and the combined solenoid valve in the corresponding hydrogen recycling device is composed of ten single solenoid valves.

本发明对氢气进出通道及循环利用优化设计的集成式燃料电池由于采用了上述的技术方案,使之与现有技术相比,具有以下的优点和积极效果:Compared with the prior art, the integrated fuel cell of the present invention has the following advantages and positive effects due to the adoption of the above-mentioned technical scheme for the hydrogen inlet and outlet channels and the optimized design of recycling:

1、燃料氢气先在集流端面板或集流中间面板中一条平滑规则的总进氢通道流入,这条平滑规则的总进氢通道再分流出数条与各个燃料电池模块中的支氢气进相连的支进氢气通道,由于各支进氢气通道的有效通径比总进氢通道小,这样,当增湿后的氢气进入总进氢气通道后,再经支进氢气通道分流到各个燃料电池模块时,即使在最初产生的冷凝态水也无法积聚在总进氢气通道内,可全部由过量的氢气及时带出燃料电池。1. Fuel hydrogen first flows into a smooth and regular general hydrogen inlet channel in the collector end panel or the collector middle panel, and this smooth and regular total hydrogen inlet channel is then divided into several outlets to feed the branch hydrogen in each fuel cell module. The connected branch hydrogen channels, because the effective diameter of each branch hydrogen channel is smaller than the main hydrogen channel, so that when the humidified hydrogen enters the main hydrogen channel, it is then shunted to each fuel cell through the branch hydrogen channels When the module is installed, even the condensed water produced at the beginning cannot accumulate in the total inlet hydrogen channel, and all the excess hydrogen can be taken out of the fuel cell in time.

2、由于对氢气循环利用装置进行了优化设计,增设了一个组合电磁阀,通过组合电磁阀中的各单阀分别与各支出氢气通道直接连通,通过将各单阀依次导通实现间歇性、脉冲式的对各个燃料电池堆模块的氢燃料进行循环,只需采用一个较小氢循环流量的氢气循环泵,并可以更加容易地带出每个燃料电池堆模块中氢侧的水。此外,由于采用了较小氢循环流量的氢气循环泵,还具有节能、降噪和少占空间的有益效果。2. Due to the optimized design of the hydrogen recycling device, a combined solenoid valve is added, and each single valve in the combined solenoid valve is directly connected to each outgoing hydrogen channel, and the intermittent, To circulate the hydrogen fuel of each fuel cell stack module in a pulsed manner, only a hydrogen circulation pump with a small hydrogen circulation flow rate is needed, and the water on the hydrogen side of each fuel cell stack module can be brought out more easily. In addition, due to the use of a hydrogen circulation pump with a relatively small hydrogen circulation flow rate, it also has the beneficial effects of energy saving, noise reduction and less space occupation.

附图说明 Description of drawings

通过以下对本发明对氢气进出通道及循环利用优化设计的集成式燃料电池的一实施例结合其附图的描述,可以进一步理解本发明的目的、具体结构特征和优点。其中,附图为:The purpose, specific structural features and advantages of the present invention can be further understood through the following description of an embodiment of the integrated fuel cell with optimized design of the hydrogen inlet and outlet channels and recycling of the present invention in conjunction with the accompanying drawings. Among them, the attached figure is:

图1是现有技术燃料电池发电系统的基本组成示意图;FIG. 1 is a schematic diagram of the basic composition of a fuel cell power generation system in the prior art;

图2、图3、图4是现有技术对集流端面板导流层面结构采用歧管设计的示意图;Fig. 2, Fig. 3 and Fig. 4 are the schematic diagrams of adopting the manifold design for the diversion layer structure of the collector end panel in the prior art;

图5是本发明中对氢气进出通道进行了优化设计的一种集成式燃料电池堆;Fig. 5 is an integrated fuel cell stack in which the hydrogen inlet and outlet passages are optimally designed in the present invention;

图6是本发明中对氢气进出通道进行了优化设计的另一种集成式燃料电池堆;Fig. 6 is another integrated fuel cell stack in which the hydrogen inlet and outlet passages have been optimally designed in the present invention;

图7是本发明中对氢气循环利用进行了优化设计的氢气循环利用装置的主要组成示意图;7 is a schematic diagram of the main components of a hydrogen recycling device optimized for hydrogen recycling in the present invention;

图8是本发明一实施例的基本组成示意图。Fig. 8 is a schematic diagram of the basic composition of an embodiment of the present invention.

具体实施方式 Detailed ways

参见图5、图6、图7。本发明对氢气进出通道及循环利用优化设计的集成式燃料电池,包括由至少两个燃料电池堆模块组成的集成式燃料电池堆1(如图5、图6所示)和氢气循环利用装置(如图7所示),在集成式燃料电池堆1的两端各设有集流端面板101、102(如图5所示),或在集成式燃料电池堆的中间设有集流中间面板103(如图6所示),在一集流端面板(如101)的外侧(如图5所示)或在集流中间面板103内(如图6所示)设有总进氢气通道104,由总进氢气通道的侧面分出多个支进氢气通道104a、104b......分别与各燃料电池堆模块的氢气进口连通,各燃料电池堆模块的支出氢气通道105a、105b......分别直接从另一集流端面板(如102)或集流中间面板103引出,各支进氢气通道的有效通径小于总进氢气通道的有效通径。See Figure 5, Figure 6, Figure 7. The present invention optimizes the design of the integrated fuel cell for hydrogen inlet and outlet passages and recycling, including an integrated fuel cell stack 1 (as shown in Figures 5 and 6) composed of at least two fuel cell stack modules and a hydrogen recycling device ( As shown in Figure 7), collector end panels 101, 102 (as shown in Figure 5) are respectively provided at both ends of the integrated fuel cell stack 1, or a collector middle panel is provided in the middle of the integrated fuel cell stack 103 (as shown in Figure 6), on the outside of a collector end panel (as shown in Figure 5) or in the collector middle panel 103 (as shown in Figure 6) is provided with a total inlet hydrogen passage 104 , from the side of the main hydrogen inlet channel, a plurality of branch hydrogen gas channels 104a, 104b... are respectively communicated with the hydrogen gas inlets of each fuel cell stack module, and the outgoing hydrogen gas channels 105a, 105b of each fuel cell stack module. .....respectively lead directly from another collector end panel (such as 102) or the collector middle panel 103, and the effective diameter of each branch hydrogen inlet channel is smaller than the effective diameter of the main hydrogen inlet channel.

氢气循环利用装置(参见图7)包括氢循环泵10、水汽分离器6和组合电磁阀14,组合电磁阀中各单阀的进口分别连通各燃料电池堆模块的支出氢气通道,组合电磁阀中各单阀的出口分别通过一根总管与水汽分离器连通。组合电磁阀中的各单阀可以分别依次导通,实现间歇式、脉冲式的对各燃料电池堆模块的氢燃料进行循环。The hydrogen recycling device (referring to Fig. 7) comprises a hydrogen circulation pump 10, a water vapor separator 6 and a combination solenoid valve 14, the inlets of each single valve in the combination solenoid valve are respectively connected to the outlet hydrogen passages of each fuel cell stack module, and the combined solenoid valve The outlet of each single valve communicates with the steam separator through a main pipe respectively. The single valves in the combined solenoid valve can be conducted sequentially respectively to realize the intermittent and pulsed hydrogen fuel circulation of each fuel cell stack module.

本发明一种对氢气进出通道及循环利用优化设计的集成式燃料电池的主要结构组成和工作原理可通过以下实施例作进一步说明:The main structural composition and working principle of an integrated fuel cell with optimized design for hydrogen inlet and outlet passages and recycling utilization of the present invention can be further illustrated by the following examples:

请参见图8,本发明一种对氢气进出通道及循环利用优化设计的集成式燃料电池的一实施例中的集成式燃料电池堆1包括六个燃料电池堆模块,相应的氢气循环利用装置中设有由六个单电磁阀组成的组合电磁阀14。六个燃料电池堆模块共用一块集流中间面板103。增湿后的燃料氢气在集流中间面板上部从一条圆形的总进氢气通道104流入,再分流出六条与六个燃料电池堆模块中的支氢气进相连的支进氢气通道104a、104b、104c......,将增湿后的燃料氢气均匀分流到六个燃料电池堆模块的支进氢气通道;每个燃料电池堆模块的支出氢气通道105a、105b、105c......,分别单独直接从集流中间板104引出,并与组合式电磁阀14中各单阀的进口一一对应连接。图中其它标号,2为储氢瓶或其它储氢装置,3为减压阀,6为水-汽分离器,10为氢循环泵,11为增湿装置,13为氢稳压阀。Please refer to Fig. 8, an integrated fuel cell stack 1 in an embodiment of an integrated fuel cell optimized for the design of hydrogen inlet and outlet passages and recycling of the present invention includes six fuel cell stack modules, and the corresponding hydrogen recycling device A combination solenoid valve 14 consisting of six single solenoid valves is provided. The six fuel cell stack modules share a collector middle panel 103 . The humidified fuel hydrogen flows in from a circular main hydrogen inlet channel 104 on the upper part of the collector middle panel, and then splits out six branch hydrogen gas inlet channels 104a, 104b, 104c......, distribute the humidified fuel hydrogen evenly to the branch hydrogen channels of the six fuel cell stack modules; the outgoing hydrogen channels 105a, 105b, 105c of each fuel cell stack module... ., are respectively directly drawn out from the collecting middle plate 104, and connected with the inlets of each single valve in the combined solenoid valve 14 in one-to-one correspondence. Among other symbols in the figure, 2 is a hydrogen storage bottle or other hydrogen storage devices, 3 is a pressure reducing valve, 6 is a water-steam separator, 10 is a hydrogen circulation pump, 11 is a humidifying device, and 13 is a hydrogen pressure stabilizing valve.

该集成式燃料电池额定输出功率是70千瓦,氢气供应量大约900标准立升/分钟,其中按氢气计量比1.2运行,大约有180标准立升/分钟的过量氢气需要经过氢气循环泵循环回来。如果不采用发明的技术方案,需要有一个循环流量为180升/分钟的大循环流量氢膜片泵,才能满足其循环量的要求。该泵消耗功率为600瓦,而且噪声高达80分贝,重达15公斤。由于各个燃料电池堆模块采用统一总进氢气通道与总出氢气通道,在氢循环流量达到180升/分钟时,平均每个燃料电池堆模块的氢循环流量仅为30升/分钟,该循环流量往往无法保证每个燃料电池堆模块中氢侧水的带出。The rated output power of the integrated fuel cell is 70 kW, and the hydrogen supply is about 900 standard liters per minute. When operating at a hydrogen metering ratio of 1.2, about 180 standard liters per minute of excess hydrogen needs to be circulated back through the hydrogen circulation pump. If the technical scheme of the invention is not adopted, a hydrogen diaphragm pump with a large circulation flow rate of 180 liters/minute is required to meet the requirement of its circulation volume. The pump consumes 600 watts, is as loud as 80 decibels and weighs 15 kilograms. Since each fuel cell stack module adopts a unified general inlet hydrogen channel and a total hydrogen outlet channel, when the hydrogen circulation flow rate reaches 180 liters/minute, the average hydrogen circulation flow rate of each fuel cell stack module is only 30 liters/minute. It is often not possible to guarantee the carryover of hydrogen-side water in each fuel cell stack module.

采用本发明的上述技术方案后,仅需要一个循环流量为90升/分钟的中等循环流量的氢膜片泵,就可满足其循环量的要求。该泵消耗功率仅为250瓦,而且噪声仅为60分贝,重量仅为3公斤。After adopting the above-mentioned technical scheme of the present invention, only one hydrogen diaphragm pump with a medium circulation flow rate of 90 liters/minute is needed to meet the requirement of its circulation volume. The pump consumes only 250 watts, is only 60 decibels quiet, and weighs only 3 kilograms.

当集成式燃料电池额定输出功率为70千瓦时,氢气供应量大约为900立升/分钟,按氢气计量比1.1运行,其中仅90升/分钟过量氢气经过氢气循环泵循环回来。由于采用了本发明的技术方案,该集成式燃料电池堆由六个燃料电池堆模块组成,每个模块的支出氢气通道分别从集流中间面板引出,并与组合电磁阀中的六个单电磁阀分别连接。该组合电磁阀在任何时间内仅开启一个电磁阀,仅使一个燃料电池堆模块的氢气出口有氢气进入循环,所以每个燃料电池堆模块的氢气循环流量高达90升/分钟,在这样大的氢气循环流量作用下,该模块中的氢侧水很容易被带出燃料电池堆。When the rated output power of the integrated fuel cell is 70 kWh, the hydrogen supply is about 900 liters per minute, and it operates at a hydrogen metering ratio of 1.1, of which only 90 liters per minute of excess hydrogen is circulated back through the hydrogen circulation pump. Due to the adoption of the technical solution of the present invention, the integrated fuel cell stack is composed of six fuel cell stack modules, and the outlet hydrogen channels of each module are respectively drawn from the middle panel of the current collector, and combined with six single solenoid valves in the combined solenoid valve. The valves are connected separately. The combined solenoid valve only opens one solenoid valve at any time, so that only the hydrogen gas from the hydrogen outlet of one fuel cell stack module enters the circulation, so the hydrogen circulation flow rate of each fuel cell stack module is as high as 90 liters per minute. Under the action of the hydrogen circulation flow, the hydrogen-side water in the module is easily taken out of the fuel cell stack.

组合电磁阀中的各单阀依次按固定顺序循环进行开启,造成每个燃料电池堆模块的氢气循环也是间歇脉冲式的,实际运行的效果证明,这种优化设计的氢气循环利用装置使每个燃料电池堆排水更干净了。并且具有节能和降低噪声的优点。The individual valves in the combined solenoid valve are opened sequentially in a fixed sequence, causing the hydrogen circulation of each fuel cell stack module to be intermittent and pulsed. The actual operation proves that this optimally designed hydrogen recycling device enables each The fuel cell stack drains are cleaner. And it has the advantages of energy saving and noise reduction.

本发明对氢气进出通道及循环利用优化设计的集成式燃料电池中的集成式燃料电池堆可以由两个以上数目的燃料电池堆模块组成,例如3个、8个、10个等等,相应的氢气循环利用装置中的组合电磁阀也由两个以上数目的单电磁阀组成,例如3个、8个、10个等等。The integrated fuel cell stack in the integrated fuel cell of the present invention that optimizes the design of the hydrogen inlet and outlet channels and recycling can be composed of more than two fuel cell stack modules, such as 3, 8, 10, etc., correspondingly The combined solenoid valve in the hydrogen recycling device is also composed of more than two single solenoid valves, such as 3, 8, 10 and so on.

Claims (7)

1. integral type fuel battery to hydrogen access way and recycling optimal design, comprise integrated fuel cell pile and the hydrogen recycle use device formed by at least two fuel battery stack modules, two ends at integrated fuel cell pile respectively are provided with the afflux end plates, or be provided with the afflux centre panel in the centre of integrated fuel cell pile, on afflux end plates or in the afflux centre panel, be provided with and always advance the hydrogen passage, each fuel battery stack module is respectively equipped with and props up hydrogen passage and expenditure hydrogen passage, the hydrogen recycle use device comprises hydrogen circulating pump and steam trap, it is characterized in that:
Described always to advance the hydrogen passage be a level and smooth pipeline, and it is horizontally set in the outside or afflux centre panel of afflux end plates, distributes a plurality of and advance the hydrogen passage and link to each other with a hydrogen inlet of each fuel battery stack module respectively by always entering hydrogen passage side;
The expenditure hydrogen passage of described each fuel battery stack module is directly drawn from another afflux end plates or afflux centre panel respectively;
Described hydrogen recycle use device also comprises a multifunctional electromagnetic valves, the import of each single valve is communicated with the expenditure hydrogen passage of each fuel battery stack module respectively in the multifunctional electromagnetic valves, and the outlet of each single valve is communicated with steam trap by a house steward respectively in the multifunctional electromagnetic valves.
2. the integral type fuel battery to hydrogen access way and recycling optimal design as claimed in claim 1 is characterized in that: described each advance the effective drift diameter of hydrogen passage less than the effective drift diameter that always advances the hydrogen passage.
3. the integral type fuel battery to hydrogen access way and recycling optimal design as claimed in claim 1, it is characterized in that: each single valve in the described multifunctional electromagnetic valves can be distinguished conducting successively, realizes that the hydrogen fuel to each fuel battery stack module of batch (-type), pulsed circulates.
4. the integral type fuel battery to hydrogen access way and recycling optimal design as claimed in claim 1, it is characterized in that: described integrated fuel cell pile is made up of six fuel battery stack modules, and the multifunctional electromagnetic valves in the corresponding hydrogen recycle use device is combined by six single electromagnetically operated valves.
5. the integral type fuel battery to hydrogen access way and recycling optimal design as claimed in claim 1, it is characterized in that: described integrated fuel cell pile is made up of three fuel battery stack modules, and the multifunctional electromagnetic valves in the corresponding hydrogen recycle use device is combined by three single electromagnetically operated valves.
6. the integral type fuel battery to hydrogen access way and recycling optimal design as claimed in claim 1, it is characterized in that: described integrated fuel cell pile is made up of eight fuel battery stack modules, and the multifunctional electromagnetic valves in the corresponding hydrogen recycle use device is combined by eight single electromagnetically operated valves.
7. the integral type fuel battery to hydrogen access way and recycling optimal design as claimed in claim 1, it is characterized in that: described integrated fuel cell pile is made up of ten fuel battery stack modules, and the multifunctional electromagnetic valves in the corresponding hydrogen recycle use device is combined by ten single electromagnetically operated valves.
CNB2004100677136A 2004-11-02 2004-11-02 Integrated fuel cell for optimization design for hydrogen gas access channels and circulating uses Expired - Lifetime CN100511792C (en)

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