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CN100505446C - semiconductor laser device - Google Patents

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CN100505446C
CN100505446C CNB200610142108XA CN200610142108A CN100505446C CN 100505446 C CN100505446 C CN 100505446C CN B200610142108X A CNB200610142108X A CN B200610142108XA CN 200610142108 A CN200610142108 A CN 200610142108A CN 100505446 C CN100505446 C CN 100505446C
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semiconductor laser
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CN1941528A (en
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堀口武
池原正博
鸟松文夫
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Sharp Fukuyama Laser Co Ltd
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Sharp Corp
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Abstract

The present invention provides a semiconductor laser device with a ridge waveguide that is excellent in polarization characteristics and easiness of mounting. In its outermost part on which the solder layer (61) is deposited, the incomplete adherent layer (31) is formed at least in the ridge structure (35). In bonding the semiconductor laser device (1) to the mount (62) via the solder layer (61), the incomplete adherent layer (31) is not adhered or adhered incompletely to the solder layer (61). On either side of the incomplete adherent layer (31) is formed the complete adherent layer (33).

Description

半导体激光器件 semiconductor laser device

技术领域 technical field

本发明涉及一种例如光盘系统中的光学拾波器等中所使用的半导体激光器件。The present invention relates to a semiconductor laser device used in, for example, an optical pickup in an optical disc system or the like.

背景技术 Background technique

特开平9—64479号公报中所公开的半导体激光装置中,在半导体基板中设置有肋形波导,由此激光下面电极由以下3层形成:即与保护层欧姆接触的欧姆接触层,形成在欧姆接触层表面的由与焊锡层不进行合金化的高熔点金属构成的非合金化金属层,以及在非合金化金属层表面的从发光区域5长边方向的中心线正下沿左右方向离开给定以上距离的区域中所形成的、与焊锡层8进行合金化的合金化电极层。非合金层和与其相接触的焊锡层不会合金化,而使合金化电极与焊锡层合金化,从而将半导体激光器件粘合在散热片上。In the semiconductor laser device disclosed in Japanese Unexamined Patent Publication No. 9-64479, a rib-shaped waveguide is provided in the semiconductor substrate, so that the lower electrode of the laser is formed by the following three layers: the ohmic contact layer that is in ohmic contact with the protective layer, formed on the The non-alloyed metal layer on the surface of the ohmic contact layer is composed of a high-melting-point metal that does not alloy with the solder layer, and the surface of the non-alloyed metal layer is separated from the center line of the long-side direction of the light-emitting region 5 along the left-right direction. The alloyed electrode layer alloyed with the solder layer 8 formed in the region of the given distance above. The non-alloy layer and the solder layer in contact with it will not be alloyed, but the alloyed electrode and the solder layer will be alloyed, thereby bonding the semiconductor laser device to the heat sink.

特开2004—14659号公报中所公开的半导体激光装置中,具有有源层(active layer)以及位于脊形结构部两侧的凹槽部,电极膜形成为包括脊形结构部及凹槽部的表面并延伸到其两侧。将半导体激光器件与安装基板粘合的焊锡层形成在凹槽部的两侧,由此形成面向脊形结构部及凹槽部的空间。In the semiconductor laser device disclosed in Japanese Unexamined Patent Publication No. 2004-14659, an active layer (active layer) and grooves located on both sides of the ridge structure are provided, and the electrode film is formed to include the ridge structure and the groove. surface and extend to its sides. A solder layer for bonding the semiconductor laser device to the mounting substrate is formed on both sides of the groove portion, thereby forming a space facing the ridge structure portion and the groove portion.

特开平11—87849号公报中所公开的半导体激光装置中,通过焊锡层将半导体激光器件粘合在Si基板上,但在有源层下形成有未焊接的空腔空间。In the semiconductor laser device disclosed in JP-A-11-87849, the semiconductor laser device is bonded to the Si substrate via a solder layer, but an unsoldered cavity space is formed under the active layer.

特开平9—64479号公报中,在具有肋形波导的半导体激光器件中,虽然可降低由散热片与半导体激光器件的热膨胀率之差所引起的作用到发光区域的内部应力,从而提高半导体激光器的寿命以及成品率,但如果应用于具有脊形波导的半导体激光器件中,就无法改善发光特性。In Japanese Patent Application Laid-Open No. 9-64479, in a semiconductor laser device having a rib-shaped waveguide, although the internal stress acting on the light-emitting region caused by the difference in thermal expansion rate between the heat sink and the semiconductor laser device can be reduced, thereby improving the semiconductor laser However, if it is applied to a semiconductor laser device with a ridge waveguide, the light emitting characteristics cannot be improved.

特开2004—14659号公报中,需要形成焊锡层以使面向脊形结构部及凹槽部的空间形成,并且焊锡层不能以遍及半导体激光器件的层积面的全表面的方式层积,由此存在半导体激光器件难于安装到副底座(sub mount)这样的问题。In Japanese Patent Laid-Open No. 2004-14659, it is necessary to form a solder layer to form a space facing the ridge structure and the groove, and the solder layer cannot be laminated over the entire surface of the semiconductor laser device. This has a problem that it is difficult to mount the semiconductor laser device on a sub mount.

另外,特开平11—87849号公报中,也需要在半导体激光器件与基板连接时所形成的焊锡层中设置空腔区域,并且焊锡层不能以遍及半导体激光器件的层积面的全表面的方式层积,由此存在半导体激光器件难于安装到副底座这样的问题。。In addition, in Japanese Patent Laid-Open No. 11-87849, it is also necessary to provide a cavity region in the solder layer formed when the semiconductor laser device is connected to the substrate, and the solder layer cannot spread over the entire surface of the semiconductor laser device. As a result of lamination, there is a problem that the semiconductor laser device is difficult to mount on the submount. .

另外,特开平9—64479号公报以及特开平11—87849号公报中,对于具有比肋形波导易于受到应力影响的脊形波导的半导体激光装置,没有公开任何改善偏振特性的构成。Also, JP-A-9-64479 and JP-A-11-87849 do not disclose any structure for improving polarization characteristics in semiconductor laser devices having ridge waveguides that are more susceptible to stress than rib waveguides.

发明内容 Contents of the invention

因此,本发明的目的在于,提供一种具有提高发光特性尤其是偏振特性并且安装容易的脊形波导的半导体激光器件。Accordingly, an object of the present invention is to provide a semiconductor laser device having a ridge waveguide with improved light emission characteristics, especially polarization characteristics, and easy mounting.

本发明是一种半导体激光器件,其具有设置在半导体基板上的条纹状脊形波导的脊形结构部,其特征在于,该半导体激光器件介由焊锡层与安装部粘合,具有:The present invention is a semiconductor laser device, which has a ridge-shaped structure part of a stripe-shaped ridge-shaped waveguide arranged on a semiconductor substrate. It is characterized in that the semiconductor laser device is bonded to the mounting part through a solder layer, and has:

不完全粘合层,其具有电导性,位于在比上述脊形波导更靠近外侧的半导体激光器件的最表面部分,不完全粘合层上层积有上述焊锡层,不完全粘合层至少在上述脊形结构部上形成,并且与上述焊锡层不完全粘合;以及An incomplete adhesive layer, which has electrical conductivity, is located on the outermost portion of the semiconductor laser device outside the above-mentioned ridge waveguide, the above-mentioned solder layer is laminated on the incomplete adhesive layer, and the incomplete adhesive layer is at least above the above-mentioned formed on the ridge structure and not fully adhered to the above-mentioned solder layer; and

完全粘合层,其具有电导性,且位于比上述脊形波导更靠近外侧的半导体激光器件的最表面部分,完全粘合层上层积有上述焊锡层,完全粘合层在与上述半导体基板的厚度方向以及上述脊形波导的延伸方向垂直的方向上,分别在上述不完全粘合层的两侧形成,并且与上述焊锡层粘合。The complete adhesive layer has electrical conductivity and is located on the outermost part of the semiconductor laser device than the above-mentioned ridge waveguide. The above-mentioned solder layer is laminated on the complete adhesive layer. The thickness direction and the direction perpendicular to the extending direction of the ridge waveguide are respectively formed on both sides of the incomplete adhesion layer and bonded to the solder layer.

通过本发明,由于形成有不完全粘合层,该不完全粘合层在比脊形波导更靠近外侧的层积有上述焊锡层的半导体激光器件的最表面部分,至少在上述脊形结构部上形成,具有电导性并且与焊锡层的粘合不完全,由此在介由焊锡层将半导体激光器件安装到安装部中时,该不完全粘合层就不与焊锡层粘合或以不完全的状态粘合。由此,通过焊锡层的热膨胀与热收缩就可以对脊形结构部均匀地赋予应力,从而能够降低半导体激光器件发光时由半导体激光器件与安装部的热膨胀与热收缩之差所引起并赋予脊形结构部的应力,因而,可以减轻因赋予应力而在脊形结构部中产生的变形。减轻脊形结构部中产生的变形,由此还能够降低赋予有源层的应力并抑制有源层中的变形,从而提高激光的偏振特性。提高激光的偏振特性是指提高偏振比、减小偏振角。According to the present invention, since the incomplete adhesive layer is formed, the incomplete adhesive layer is formed on the outermost portion of the semiconductor laser device on which the above-mentioned solder layer is laminated than the ridge waveguide, at least in the above-mentioned ridge structure portion. formed on the surface, has electrical conductivity and is incompletely bonded to the solder layer, and thus when the semiconductor laser device is mounted in the mounting part via the solder layer, the incompletely bonded layer does not bond to the solder layer or Complete condition bonded. Thus, the stress can be uniformly applied to the ridge structure part by the thermal expansion and thermal contraction of the solder layer, so that the difference caused by the thermal expansion and thermal contraction between the semiconductor laser device and the mounting part when the semiconductor laser device emits light can be reduced. The stress of the ridge-shaped structure portion can be reduced, and thus, the deformation generated in the ridge-shaped structure portion due to the application of stress can be alleviated. Reducing the deformation generated in the ridge structure can also reduce the stress applied to the active layer and suppress the deformation in the active layer, thereby improving the polarization characteristics of laser light. Improving the polarization characteristics of the laser refers to increasing the polarization ratio and reducing the polarization angle.

另外,由于完全粘合层具有电导性,且位于比脊形波导更靠近外侧的半导体激光器件的最表面部分,完全粘合层上层积有上述焊锡层,完全粘合层在与半导体基板的厚度方向以及脊形波导的延伸方向垂直的方向上,分别在不完全粘合层的两侧形成,由此能够使半导体激光器件与安装部牢固地机械连接。In addition, since the perfect bonding layer has electrical conductivity and is located on the outermost part of the semiconductor laser device than the ridge waveguide, the above-mentioned solder layer is laminated on the perfect bonding layer, and the perfect bonding layer has a thickness equal to that of the semiconductor substrate. direction and the direction perpendicular to the extending direction of the ridge waveguide are respectively formed on both sides of the incomplete adhesive layer, whereby the semiconductor laser device and the mounting part can be firmly mechanically connected.

层积有焊锡层的最表面部中设置有上述不完全粘合层与上述完全粘合层,在其上层积焊锡层并将半导体激光器件安装到安装部中,由此能够以遍布最表面部的层积面的全表面的方式层积焊锡层,由于不需对焊锡层进行加工,因此半导体激光器件就易于安装到安装部中。In the outermost part on which the solder layer is laminated, the above-mentioned incomplete adhesion layer and the above-mentioned perfect adhesion layer are provided, and the solder layer is laminated thereon and the semiconductor laser device is mounted in the mounting part, whereby it is possible to spread over the outermost part. The solder layer is laminated on the entire surface of the laminated surface. Since the solder layer does not need to be processed, the semiconductor laser device can be easily mounted in the mounting part.

本发明的特征在于,上述不完全粘合层包括:The present invention is characterized in that the above-mentioned incomplete adhesive layer comprises:

第1不完全粘合层,其在与上述半导体基板的厚度方向以及上述脊形波导的延伸方向垂直的方向上,在半导体激光器件的中央形成;以及The first incomplete adhesive layer is formed in the center of the semiconductor laser device in a direction perpendicular to the thickness direction of the above-mentioned semiconductor substrate and the extending direction of the above-mentioned ridge waveguide; and

第2不完全粘合层,其在与上述半导体基板的厚度方向以及上述脊形波导的延伸方向垂直的方向上,分别在上述第1不完全粘合层的两侧形成,且与形成上述焊锡层的焊锡材料之间的湿润性位于上述第1不完全粘合层的与形成上述焊锡层的焊锡材料之间的湿润性和上述完全粘合层的与形成上述焊锡层的焊锡材料之间的湿润性之中。The second incomplete adhesion layer is formed on both sides of the first incomplete adhesion layer in a direction perpendicular to the thickness direction of the above-mentioned semiconductor substrate and the extending direction of the ridge waveguide, and is connected with the formation of the above-mentioned solder. The wettability between the solder materials of the layers is located between the wettability between the above-mentioned first incomplete adhesion layer and the solder material forming the above-mentioned solder layer and the wettability between the above-mentioned complete adhesion layer and the solder material forming the above-mentioned solder layer. in wetness.

根据本发明,在不完全粘合层中的接近脊形结构部的部分上形成湿润性较差的第1不完全粘合层,该湿润性是与形成焊锡层的焊锡材料的湿润性,在垂直于半导体基板的厚度方向以及上述脊形波导的延伸方向的方向上,在第1不完全粘合层与完全粘合层之间形成:与形成焊锡层的焊锡材料的湿润性具有上述第1不完全粘合层与上述完全粘合层之间的性质的第2不完全粘合层。由此,随着离开脊形结构部,层积焊锡层的最表面部与焊锡层间的粘合力就逐步地增大。通过使粘合力逐步地变化,能够抑制由完全粘合层中所产生的应力与不完全粘合层中所产生的应力引起的完全粘合层与不完全粘合层相邻的部分中的急剧的应力变化,从而缓和赋予脊形结构部的应力,由此降低脊形结构部中产生的变形。According to the present invention, the first incomplete adhesion layer having poor wettability with the solder material forming the solder layer is formed on the portion of the incomplete adhesion layer close to the ridge structure. In the direction perpendicular to the thickness direction of the semiconductor substrate and the extending direction of the above-mentioned ridge waveguide, it is formed between the first incomplete adhesion layer and the complete adhesion layer: the wettability with the solder material forming the solder layer has the above-mentioned first A second incompletely bonded layer having properties between the incompletely bonded layer and the aforementioned fully bonded layer. As a result, the adhesive force between the uppermost surface portion of the laminated solder layer and the solder layer gradually increases as the distance from the ridge structure portion increases. By gradually changing the adhesive force, it is possible to suppress tension in the portion adjacent to the fully bonded layer and the incompletely bonded layer caused by the stress generated in the fully bonded layer and the stress generated in the incompletely bonded layer. The sharp stress change relaxes the stress applied to the ridge structure, thereby reducing the deformation generated in the ridge structure.

另外,本发明的特征在于,上述第1不完全粘合层由钼(Mo)形成;上述第2不完全粘合层由铂(Pt)形成;上述完全粘合层由金(Au)形成。In addition, the present invention is characterized in that the first partial adhesion layer is formed of molybdenum (Mo), the second partial adhesion layer is formed of platinum (Pt), and the perfect adhesion layer is formed of gold (Au).

根据本发明,第1不完全粘合层由钼(Mo)形成,第2不完全粘合层由铂(Pt)形成,完全粘合层由金(Au)形成,由此能够实现上述效果。另外,形成Mo、Pt以及Au的成膜技术以前就一直使用,由此为了形成完全粘合层与不完全粘合层,就不需新的成膜技术,从而能够简单地形成。According to the present invention, the first partial adhesion layer is formed of molybdenum (Mo), the second partial adhesion layer is formed of platinum (Pt), and the perfect adhesion layer is formed of gold (Au), whereby the above effects can be achieved. In addition, film-forming techniques for forming Mo, Pt, and Au have been used in the past, so that forming a perfect adhesion layer and an incomplete adhesion layer does not require a new film-forming technique and can be easily formed.

另外,本发明的特征在于,在与上述半导体基板的厚度方向及上述脊形波导的延伸方向垂直的方向上,在上述脊形波导的两侧,以从上述脊形波导隔开预定距离的方式形成台阶部,并且在该台阶部与脊形波导间形成凹部。In addition, the present invention is characterized in that, in a direction perpendicular to the thickness direction of the semiconductor substrate and the extending direction of the ridge waveguide, on both sides of the ridge waveguide, the ridge waveguide is separated from the ridge waveguide by a predetermined distance. A stepped portion is formed, and a concave portion is formed between the stepped portion and the ridge waveguide.

根据本发明,在通过焊锡层将半导体激光器件粘合到副底座上时,需要以给定的荷重将半导体激光器件压向副底座,但通过设置台阶部,该台阶部在垂直于上述半导体基板的厚度方向与上述脊形波导的延伸方向的方向上,在上述脊形波导的两侧以从上述脊形波导隔开预定距离的方式形成,于是在与脊形波导间形成凹部,由此可使加载到上述脊形结构部的上述荷重分散到台阶部,从而能够降低由按压脊形结构部产生的附加应力,因而,就可以减轻安装到安装部中时所产生的脊形结构部的变形。According to the present invention, when the semiconductor laser device is bonded to the sub-mount through the solder layer, it is necessary to press the semiconductor laser device to the sub-mount with a given load, but by providing a step portion, the step portion is perpendicular to the above-mentioned semiconductor substrate. In the direction of the thickness direction of the above-mentioned ridge-shaped waveguide and the direction of the extending direction of the above-mentioned ridge-shaped waveguide, it is formed on both sides of the above-mentioned ridge-shaped waveguide with a predetermined distance from the above-mentioned ridge-shaped waveguide. By distributing the above-mentioned load applied to the above-mentioned ridge structure to the step portion, the additional stress generated by pressing the ridge structure can be reduced, and therefore, the deformation of the ridge structure when it is installed in the mounting portion can be reduced. .

另外,本发明的特征在于,在上述凹部偏向脊形波导处,形成有上述不完全粘合层;上述凹部偏向台阶部处,形成有上述完全粘合层。In addition, the present invention is characterized in that the partial adhesive layer is formed where the concave portion deviates from the ridge waveguide, and the perfect adhesive layer is formed where the concave portion deviates from the step portion.

根据本发明,在凹部偏向脊形波导处形成上述不完全粘合层,因此能够降低从脊形结构部的周围赋予脊形结构部的应力。在脊形结构部与焊锡层的界面中,通过激光出射而在脊形结构部中产生的热就难于释放,但通过在凹部偏向台阶部8处形成完全粘合层,就能够使所产生的热从完全粘合层高效地释放到半导体层。According to the present invention, since the incomplete adhesive layer is formed where the concave portion deviates from the ridge waveguide, the stress applied to the ridge structure portion from around the ridge structure portion can be reduced. In the interface between the ridge structure and the solder layer, it is difficult to release the heat generated in the ridge structure by laser emission, but by forming a complete adhesive layer at the concave portion biased to the step portion 8, the generated heat can be made Heat is efficiently released from the fully bonded layer to the semiconducting layer.

另外,本发明的特征在于,上述不完全粘合层中的形成在上述凹部中的部分,按照在脊形波导与台阶部之间从脊形波导遍布规定范围的方式形成,该规定范围是脊形波导与台阶部之间的距离的30%以上并不满50%的范围。In addition, the present invention is characterized in that the portion of the incomplete adhesive layer formed in the recess is formed so as to extend from the ridge waveguide over a predetermined range between the ridge waveguide and the step portion, and the predetermined range is the ridge waveguide. The distance between the shaped waveguide and the stepped portion is more than 30% and less than 50%.

根据本发明,如果不完全粘合层中的形成在凹部中的部分,按照在脊形波导与台阶部之间在由脊形波导到脊形波导与台阶部之间的距离的30%以上的范围内形成,就能够更可靠地降低应力。另外,如果不完全粘合层中的形成在凹部中的部分,按照在脊形波导与台阶部之间在由脊形波导到脊形波导与台阶部之间的距离的50%以上的范围内形成,则来自脊形结构部的热就难于释放到合金层中,从而使半导体激光器件的电流值特性恶化,也就是使发光效率降低。因此,使不完全粘合层中的形成在凹部中的部分,按照在脊形波导与台阶部之间从脊形波导遍布规定范围的方式形成,该规定范围是脊形波导与台阶部之间的距离的30%以上并不满50%的范围,就不仅能够可靠地降低附加到脊形波导的应力,并且可以抑制半导体激光器件的电流值特性的恶化。According to the present invention, if the portion of the incompletely bonded layer formed in the concave portion, according to 30% or more of the distance between the ridge waveguide and the step portion from the ridge waveguide to the distance between the ridge waveguide and the step portion Formed within the range, the stress can be reduced more reliably. In addition, if the portion of the incomplete adhesive layer formed in the concave portion is within the range of 50% or more of the distance between the ridge waveguide and the step portion from the ridge waveguide to the distance between the ridge waveguide and the step portion If formed, the heat from the ridge structure is difficult to be released into the alloy layer, thereby deteriorating the current value characteristics of the semiconductor laser device, that is, reducing the luminous efficiency. Therefore, the portion of the incomplete adhesive layer formed in the concave portion is formed so as to extend from the ridge waveguide to a predetermined range between the ridge waveguide and the step portion between the ridge waveguide and the step portion. In the range of 30% or more and less than 50% of the distance, not only the stress added to the ridge waveguide can be reliably reduced, but also the deterioration of the current value characteristics of the semiconductor laser device can be suppressed.

另外,本发明的特征在于,上述完全粘合层中的形成在上述凹部中的部分,按照在脊形波导与台阶部之间在由台阶部到脊形波导与台阶部之间的距离的50%以下的范围内形成。In addition, the present invention is characterized in that the part of the above-mentioned complete bonding layer formed in the above-mentioned concave part is divided into 50% of the distance between the ridge waveguide and the step part from the step part to the distance between the ridge waveguide and the step part. % formed within the following range.

根据本发明,在完全粘合层中的形成在凹部中的部分,按照在脊形波导与台阶部之间在由台阶部超过脊形波导与台阶部之间的距离的50%的方式形成的情况下,虽然通过从完全粘合层向焊锡层的放热(heat release)效果能够抑制半导体激光器件的电流值特性的恶化,但完全粘合层中产生的应力易于传递到脊形结构部中。因此,使完全粘合层中的形成在凹部中的部分,按照在脊形波导与台阶部之间由台阶部到脊形波导与台阶部之间的距离的50%以下的范围内的方式形成,就能够抑制半导体激光器件的电流值特性的恶化,并且使完全粘合层中产生的应力难于传递到脊形结构部中,由此抑制脊形结构部中产生的变形。According to the present invention, the part formed in the recess in the fully bonded layer is formed in such a way that the step exceeds 50% of the distance between the ridge waveguide and the step between the ridge waveguide and the step. In this case, although the deterioration of the current value characteristics of the semiconductor laser device can be suppressed by the heat release effect from the complete adhesion layer to the solder layer, the stress generated in the complete adhesion layer is easily transmitted to the ridge structure. . Therefore, the portion formed in the concave portion in the complete bonding layer is formed so as to be within a range of 50% or less of the distance between the ridge waveguide and the step portion from the step portion to the distance between the ridge waveguide and the step portion. , it is possible to suppress the deterioration of the current value characteristics of the semiconductor laser device, and make it difficult for the stress generated in the perfect adhesion layer to be transmitted to the ridge structure portion, thereby suppressing the deformation generated in the ridge structure portion.

另外,本发明的特征在于,具有基底金属层,其由金(Au)形成并且层积有上述完全粘合层与上述不完全粘合层。In addition, the present invention is characterized in that it has a base metal layer formed of gold (Au) and in which the above-mentioned perfect adhesion layer and the above-mentioned incomplete adhesion layer are laminated.

根据本发明,使脊形结构部中所产生的热介由由高热传导率的金(Au)形成的基底金属层而传递到完全粘合层侧,由此可介由焊锡层释放到安装部中。从而,能够消除不完全粘合层与焊锡层之间的放热不足,进一步抑制电流特性的恶化,由此实现半导体激光器件的长寿化。According to the present invention, the heat generated in the ridge structure part is transferred to the complete adhesion layer side through the base metal layer formed of gold (Au) with high thermal conductivity, thereby being released to the mounting part through the solder layer middle. Therefore, it is possible to eliminate the lack of heat release between the incomplete adhesion layer and the solder layer, further suppress deterioration of current characteristics, and thereby achieve a longer life of the semiconductor laser device.

另外,本发明的特征在于,具有基底金属层,其层积有上述完全粘合层与上述不完全粘合层;In addition, the present invention is characterized in that it has a base metal layer in which the above-mentioned perfect adhesion layer and the above-mentioned incomplete adhesion layer are laminated;

上述基底金属层的特征在于,按照顺次层积由金(Au)构成并通过电镀形成的电镀电极层、由预定的金属形成的第1电极层、以及由金(Au)形成的第2电极层的方式形成。The base metal layer is characterized in that a plating electrode layer made of gold (Au) and formed by electroplating, a first electrode layer made of a predetermined metal, and a second electrode made of gold (Au) are laminated in this order. formed in layers.

由金构成的电镀电极层通过电镀形成,因此与通过溅射法形成的由金构成的层相比,就能够以短时间形成厚度较大的层。但是,由金构成的电镀电极层表面平坦性较差,湿润性随电镀条件变化,因此存在粘合特性中产生离散偏差之虞。根据本发明,基底金属层中包括由金构成的电镀电极层,但在该电镀电极层中顺次层积有表面平坦性比上述电镀电极层好且由预定金属形成的第1电极层、和由金形成的第2电极层。由此,能够提高由金构成的第2电极层的表面平坦性。因而,能够提高与层积在第2电极层上的完全粘合层及不完全粘合层之间的粘合特性,由此可抑制基底金属层与完全粘合层及不完全粘合层的剥离。因此,脊形结构部中所产生的热,能够介由包括高热传导率的金(Au)所形成的基底金属层传导到完全粘合层侧,从而能够介由焊锡层可靠地释放到安装部中。由此能够解决不完全粘合层与焊锡层间的放热不足,从而进一步抑制电流特性的恶化来谋求半导体激光器件的长寿化。Since the plating electrode layer made of gold is formed by electroplating, a thicker layer can be formed in a shorter time than a layer made of gold formed by a sputtering method. However, since the plating electrode layer made of gold has poor surface flatness and wettability varies with plating conditions, there is a possibility of discrete variations in adhesion characteristics. According to the present invention, the base metal layer includes a plating electrode layer made of gold, but the plating electrode layer is sequentially laminated with a first electrode layer having a surface flatter than the plating electrode layer and formed of a predetermined metal, and The second electrode layer is made of gold. Thereby, the surface flatness of the second electrode layer made of gold can be improved. Therefore, it is possible to improve the adhesion properties between the perfect adhesion layer and the incomplete adhesion layer laminated on the second electrode layer, thereby suppressing the adhesion between the base metal layer and the complete adhesion layer and the incomplete adhesion layer. peel off. Therefore, the heat generated in the ridge structure part can be conducted to the side of the complete bonding layer through the base metal layer formed of gold (Au) with high thermal conductivity, and can be reliably released to the mounting part through the solder layer. middle. In this way, insufficient heat dissipation between the incomplete adhesion layer and the solder layer can be solved, and the deterioration of current characteristics can be further suppressed to achieve a longer life of the semiconductor laser device.

另外,本发明的特征在于,形成上述第1电极层的预定的金属,从由钼(Mo)、铂(Pt)、钼铂(MoPt)以及钛(Ti)构成的组中选择。In addition, the present invention is characterized in that the predetermined metal forming the first electrode layer is selected from the group consisting of molybdenum (Mo), platinum (Pt), molybdenum platinum (MoPt), and titanium (Ti).

根据本发明,形成第1电极层的预定的金属,从由钼(Mo)、铂(Pt)、钼铂(MoPt)以及钛(Ti)构成的组中选择。钼(Mo)、铂(Pt)、钼铂(MoPt)以及钛(Ti),在形成电极层时表面平坦性优秀,因此能够实现上述效果。According to the present invention, the predetermined metal forming the first electrode layer is selected from the group consisting of molybdenum (Mo), platinum (Pt), molybdenum platinum (MoPt), and titanium (Ti). Molybdenum (Mo), platinum (Pt), molybdenum platinum (MoPt), and titanium (Ti) have excellent surface flatness when forming an electrode layer, and thus can achieve the above-mentioned effects.

另外,本发明的特征在于,上述第1与第2电极层通过溅射法以连续成膜方式形成。In addition, the present invention is characterized in that the first and second electrode layers are formed continuously by sputtering.

根据本发明,第1与第2电极层通过溅射法以连续成膜方式形成,因此能够提高与由金构成的电镀电极层间的密接性,进而即使电镀电极层的表面中有凹凸,也以填补该凹凸部分的方式形成第1与第2电极层,因此能够使基底电极层的厚度尽可能均匀。通过使基底电极层的厚度更加均匀,可以获得更加稳定的接合性及提高粘合性,其效果,能够消除放热不足,由此进一步抑制电流特性的恶化来谋求半导体激光器件的长寿化。According to the present invention, since the first and second electrode layers are continuously formed by sputtering, the adhesion to the plating electrode layer made of gold can be improved, and even if there are irregularities on the surface of the plating electrode layer, Since the first and second electrode layers are formed to fill up the unevenness, the thickness of the base electrode layer can be made as uniform as possible. By making the thickness of the base electrode layer more uniform, more stable bonding and improved adhesion can be obtained. As a result, insufficient heat dissipation can be eliminated, thereby further suppressing deterioration of current characteristics and prolonging the life of the semiconductor laser device.

另外,本发明的特征在于,上述基底金属层的厚度选择为0.5μm以上且不满5.0μm。In addition, the present invention is characterized in that the thickness of the base metal layer is selected to be 0.5 μm or more and less than 5.0 μm.

根据本发明,如果基底金属层的厚度不满0.5μm,就不能充分实现传热效果,如果超过5.0μm,由形成基底金属层产生的应力就传递到脊形波导中,由此脊形波导变形。通过使基底金属层的厚度设为0.5μm以上且不满5.0μm,就能够不仅获得从脊形波导到不完全粘合层的充分传热效果,并且能够降低赋予脊形波导的应力。According to the present invention, if the thickness of the base metal layer is less than 0.5 μm, the heat transfer effect cannot be sufficiently achieved, and if it exceeds 5.0 μm, the stress generated by forming the base metal layer is transmitted to the ridge waveguide, thereby deforming the ridge waveguide. By setting the thickness of the base metal layer to 0.5 μm or more and less than 5.0 μm, not only sufficient heat transfer effect from the ridge waveguide to the incomplete bonding layer can be obtained, but also stress applied to the ridge waveguide can be reduced.

另外,本发明的特征在于,具有背面金属层,其以夹持上述半导体基板的方式在与上述脊形结构部相反侧的上述半导体基板的表面部上由金形成。In addition, the present invention is characterized by having a back metal layer formed of gold on the surface portion of the semiconductor substrate opposite to the ridge structure portion so as to sandwich the semiconductor substrate.

根据本发明,由于具有以夹持上述半导体基板的方式在与上述脊形结构部相反侧的上述半导体基板的表面部上由金形成的背面金属层,因此能够缓和形成在脊形结构部侧的基底金属层所产生的应力。According to the present invention, since there is a back metal layer formed of gold on the surface portion of the semiconductor substrate on the opposite side to the ridge structure portion so as to sandwich the semiconductor substrate, it is possible to relax the damage formed on the ridge structure portion side. The stress induced by the base metal layer.

附图说明 Description of drawings

根据以下的详细说明及附图,能够使本发明的目的、特色、以及优点更加明确。The purpose, features, and advantages of the present invention will become clearer from the following detailed description and accompanying drawings.

图1是本发明的一实施方式的半导体激光器件的剖面图。FIG. 1 is a cross-sectional view of a semiconductor laser device according to an embodiment of the present invention.

图2是半导体激光器件的俯视图。Fig. 2 is a plan view of a semiconductor laser device.

图3A~图3C是表示半导体激光器件的制造工序的剖面图。3A to 3C are cross-sectional views showing manufacturing steps of the semiconductor laser device.

图4A~图4D是表示半导体激光器件的制造工序的剖面图。4A to 4D are cross-sectional views showing manufacturing steps of the semiconductor laser device.

图5A~图5C是表示半导体激光器件的制造工序的剖面图。5A to 5C are cross-sectional views showing manufacturing steps of the semiconductor laser device.

图6是表示将半导体激光器件介由焊锡层安装在安装部中的半导体激光装置的剖面图。6 is a cross-sectional view showing a semiconductor laser device in which a semiconductor laser device is mounted on a mounting portion via a solder layer.

图7是本发明的另一实施方式的半导体激光器件的剖面图。7 is a cross-sectional view of a semiconductor laser device according to another embodiment of the present invention.

图8是半导体激光器件的俯视图。Fig. 8 is a plan view of the semiconductor laser device.

图9是表示将半导体激光器件介由焊锡层安装在安装部中的半导体激光装置的剖面图。9 is a cross-sectional view showing a semiconductor laser device in which a semiconductor laser device is mounted on a mounting portion via a solder layer.

图10是本发明的另一实施方式的半导体激光器件的剖面图。Fig. 10 is a cross-sectional view of a semiconductor laser device according to another embodiment of the present invention.

图11是本发明的另一实施方式的半导体激光器件的剖面图。Fig. 11 is a cross-sectional view of a semiconductor laser device according to another embodiment of the present invention.

具体实施方式 Detailed ways

以下参照附图,对本发明的优选实施方式进行详细的说明。Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the drawings.

图1是本发明的一实施方式的半导体激光器件1的剖面图,图2是半导体激光器件1的俯视图。图1是从图2的剖面线I—I所观察到的剖面图。另外,图2表示从半导体基板2厚度方向Z中的设置有脊形结构部35一侧观察的图,图中不完全粘合层31为了易于图解以标注斜线方式被图示。半导体激光器件1是半导体激光器基片(laser chip)。半导体基板2的厚度方向Z,平行于形成半导体激光器件的各半导体层及各金属层的层积方向。半导体激光器件1具有:半导体基板2、第1镀层3、有源层4、第2镀层5、蚀刻停止层6、脊形部7、台阶部8、第1以及第2电介质层17、18、电镀用基底电极层23、电镀电极层27、包括不完全粘合层31的金属层32、以及完全粘合层33。FIG. 1 is a cross-sectional view of a semiconductor laser device 1 according to an embodiment of the present invention, and FIG. 2 is a plan view of the semiconductor laser device 1 . Fig. 1 is a sectional view viewed from the section line II-I in Fig. 2 . In addition, FIG. 2 shows a view viewed from the side where the ridge structure portion 35 is provided in the thickness direction Z of the semiconductor substrate 2 , in which the incomplete adhesion layer 31 is shown with oblique lines for ease of illustration. The semiconductor laser device 1 is a semiconductor laser chip. The thickness direction Z of the semiconductor substrate 2 is parallel to the lamination direction of each semiconductor layer and each metal layer forming the semiconductor laser device. The semiconductor laser device 1 has: a semiconductor substrate 2, a first plating layer 3, an active layer 4, a second plating layer 5, an etching stop layer 6, a ridge portion 7, a step portion 8, the first and second dielectric layers 17, 18, Base electrode layer 23 for plating, plating electrode layer 27 , metal layer 32 including imperfect adhesion layer 31 , and perfect adhesion layer 33 .

半导体基板2可以层积化合物半导体层,在本实施方式中由n型砷化镓(GaAs)形成。半导体基板2厚度方向Z的表面形成为矩形形状。半导体基板2的厚度例如选择为50μm~130μm。The semiconductor substrate 2 may be laminated with compound semiconductor layers, and is formed of n-type gallium arsenide (GaAs) in this embodiment. The surface of the semiconductor substrate 2 in the thickness direction Z is formed in a rectangular shape. The thickness of the semiconductor substrate 2 is selected to be, for example, 50 μm to 130 μm.

第1镀层3,在半导体基板2厚度方向Z的一表面2a上以遍及上述一表面2a全表面的方式进行层积。第1镀层3由n型(AlXGa1-X)YIn1-YP形成,其中0<X<1,0<Y<1。本实施方式中,选择X=0.7,Y=0.5,也就是,第1镀层3由n型(Al0.7Ga0.3)0.5In0.5P形成。第1镀层3的厚度例如选择为2.0μm。The first plated layer 3 is laminated on the one surface 2 a in the thickness direction Z of the semiconductor substrate 2 so as to cover the entire surface of the one surface 2 a. The first coating layer 3 is formed of n-type (Al X Ga 1-X ) Y In 1-Y P, where 0<X<1, 0<Y<1. In this embodiment, X=0.7 and Y=0.5 are selected, that is, the first plating layer 3 is formed of n-type (Al 0.7 Ga 0.3 ) 0.5 In 0.5 P. The thickness of the first plating layer 3 is selected to be, for example, 2.0 μm.

有源层4,在第1镀层厚度方向Z的一表面3a上以遍及上述一表面3a全表面的方式进行层积。有源层4具有量子阱结构,并且包括:层积在第1镀层3厚度方向Z的一表面3a上的第1导向层(guide layer)、层积在第1导向层厚度方向Z的一表面上的第1阱层(well layer)、形成在第1阱层厚度方向Z的一表面上的势垒层、形成在势垒层厚度方向的一表面上的第2阱层、以及形成在第2阱层的厚度方向Z的一表面上的第2导向层。第1及第2阱层由In0.5Ga0.5P形成,其厚度例如选择为

Figure C200610142108D00121
。势垒层由(Al0.7Ga0.3)0.5In0.5P形成,其厚度例如选择为
Figure C200610142108D00122
。导向层由(Al0.7Ga0.3)0.5In0.5P形成,其厚度例如选择为
Figure C200610142108D00123
The active layer 4 is laminated on the one surface 3a in the thickness direction Z of the first plating layer so as to cover the entire surface of the one surface 3a. The active layer 4 has a quantum well structure, and includes: a first guide layer (guide layer) laminated on a surface 3a in the thickness direction Z of the first coating layer 3, a surface laminated in the thickness direction Z of the first guide layer The first well layer (well layer), the barrier layer formed on one surface in the thickness direction Z of the first well layer, the second well layer formed on one surface in the thickness direction Z of the barrier layer, and the second well layer formed in the 2. The second guide layer on one surface in the thickness direction Z of the well layer. The first and second well layers are formed of In 0.5 Ga 0.5 P, and their thickness is selected as
Figure C200610142108D00121
. The barrier layer is formed of (Al 0.7 Ga 0.3 ) 0.5 In 0.5 P, and its thickness is selected as, for example,
Figure C200610142108D00122
. The guide layer is formed of (Al 0.7 Ga 0.3 ) 0.5 In 0.5 P, and its thickness is selected as
Figure C200610142108D00123

第2镀层5,在有源层4厚度方向Z的一表面4a上以遍及上述一表面4a全表面的方式进行层积。。第2镀层5由p型(AlXGa1-X)YIn1-YP形成,其中0<X<1,0<Y<1。本实施方式中,选择X=0.7,Y=0.5,也就是,第2镀层5由p型(Al0.7Ga0.3)0.5In0.5P形成。第2镀层5的厚度例如选择为0.2~0.3μm。The second plating layer 5 is laminated on the one surface 4 a in the thickness direction Z of the active layer 4 so as to cover the entire surface of the one surface 4 a. . The second plating layer 5 is formed of p-type (Al X Ga 1-X ) Y In 1-Y P, where 0<X<1, 0<Y<1. In this embodiment, X=0.7 and Y=0.5 are selected, that is, the second plating layer 5 is formed of p-type (Al 0.7 Ga 0.3 ) 0.5 In 0.5 P. The thickness of the second plating layer 5 is selected to be, for example, 0.2 to 0.3 μm.

蚀刻停止层6,在第2镀层5厚度方向Z的一表面5a上以遍及上述一表面5a全表面的方式进行层积。蚀刻停止层6由p型In0.5Ga0.5P形成。蚀刻停止层6的厚度例如选择为

Figure C200610142108D00131
。蚀刻停止层6防止第2镀层5被蚀刻。The etching stopper layer 6 is laminated on the one surface 5 a in the thickness direction Z of the second plating layer 5 so as to cover the entire surface of the one surface 5 a. Etching stop layer 6 is formed of p-type In 0.5 Ga 0.5 P. The thickness of etch stop layer 6 is selected as
Figure C200610142108D00131
. The etch stop layer 6 prevents the second plating layer 5 from being etched.

脊形部7包括第3镀层11和保护层12。脊形部7层积在蚀刻停止层6厚度方向Z的一表面6a上。脊形部7,在半导体激光器件1宽度方向Y的中央部,从蚀刻停止层6的一表面6a向厚度方向Z的一方突出。半导体激光器件1形成得关于假想平面大致面对称,该假想平面穿过宽度方向Y的中央并沿厚度方向Z平行地延伸。脊形部7沿垂直于上述厚度方向Z以及宽度方向Y的方向即激光的出射方向延伸,形成为条纹状。在激光的出射方向即脊形部7的延伸方向X中,脊形部7以延伸到半导体激光器件1的两端部间的方式形成。The ridge portion 7 includes a third plating layer 11 and a protective layer 12 . The ridge portion 7 is laminated on one surface 6 a in the thickness direction Z of the etching stop layer 6 . The ridge portion 7 protrudes from the one surface 6 a of the etching stop layer 6 toward one side in the thickness direction Z at the center portion in the width direction Y of the semiconductor laser device 1 . The semiconductor laser device 1 is formed substantially plane-symmetrically with respect to an imaginary plane passing through the center in the width direction Y and extending in parallel in the thickness direction Z. The ridge portion 7 extends in a direction perpendicular to the thickness direction Z and the width direction Y, that is, the emission direction of the laser light, and is formed in a stripe shape. The ridge 7 is formed so as to extend between both ends of the semiconductor laser device 1 in the direction X in which the ridge 7 extends, which is the direction in which the laser light is emitted.

第3镀层11层积在蚀刻停止层6厚度方向Z的一表面6a上。第3镀层11由p型(AlXGa1-X)YIn1-YP形成,其中0<X<1,0<Y<1。本实施方式中,选择X=0.7,Y=0.5,也就是说,第3镀层11由p型(Al0.7Ga0.3)0.5In0.5P形成。第3镀层11的厚度例如选择为300nm~5000nm。第3镀层11形成对激光进行导波的脊形波导。The third plated layer 11 is laminated on one surface 6 a of the etching stopper layer 6 in the thickness direction Z. The third plating layer 11 is formed of p-type (Al X Ga 1-X ) Y In 1-Y P, where 0<X<1, 0<Y<1. In this embodiment, X=0.7 and Y=0.5 are selected, that is, the third plating layer 11 is formed of p-type (Al 0.7 Ga 0.3 ) 0.5 In 0.5 P. The thickness of the third plating layer 11 is selected to be, for example, 300 nm to 5000 nm. The third plating layer 11 forms a ridge waveguide for guiding laser light.

保护层12层积在第3镀层11厚度方向Z的一表面11a上。保护层12由砷化镓(GaAs)形成。保护层12用来形成与后述的脊上电极层21的欧姆接触。The protective layer 12 is laminated on one surface 11 a of the third plating layer 11 in the thickness direction Z. The protective layer 12 is formed of gallium arsenide (GaAs). The protective layer 12 is used to form an ohmic contact with the electrode layer 21 on the ridge described later.

脊形部7在宽度方向Y上形成为预定尺寸L1,上述预定尺寸选择为1.5μm~3.0μm。脊形部7的厚度方向Z的一端部即从半导体基板2离开的侧的端部的宽度方向Y的尺寸选择为0.1μm~0.3μm,厚度方向Z的另一端部即与蚀刻停止层6相接触的端部的宽度方向Y的尺寸选择为1.5μm~3.0μm,由此垂直于该脊形部7的延伸方向X的剖面,形成为以半导体基板2侧为下底的梯形状。The ridge portion 7 is formed to have a predetermined dimension L1 in the width direction Y, and the predetermined dimension is selected to be 1.5 μm to 3.0 μm. One end of the ridge 7 in the thickness direction Z, that is, the dimension of the width direction Y of the end of the side away from the semiconductor substrate 2 is selected to be 0.1 μm to 0.3 μm, and the other end of the thickness direction Z is the same as the etching stop layer 6. The dimension of the contact end portion in the width direction Y is selected to be 1.5 μm to 3.0 μm, so that a cross section perpendicular to the extending direction X of the ridge portion 7 is formed into a trapezoid with the semiconductor substrate 2 side as the bottom.

台阶部8包括第1台阶结构层13及第2台阶结构层14。台阶部8在宽度方向Y上,以在脊形部7的两侧即脊形波导的两侧从脊形部7隔开预定距离L2的方式形成,由此在台阶部8与脊形部7之间形成沿脊形部7的延伸方向X延伸的凹部15。上述预定距离L2选择为大致10μm~20μm。台阶部8沿脊形部7的延伸方向X平行地延伸,形成为条纹状。台阶部8以从宽度方向Y上由脊形部7隔开预定距离L2的位置遍布到半导体激光器件1的端部的方式形成。The stepped portion 8 includes a first stepped structure layer 13 and a second stepped structure layer 14 . The step portion 8 is formed on both sides of the ridge portion 7, that is, on both sides of the ridge waveguide in the width direction Y, so as to be separated from the ridge portion 7 by a predetermined distance L2. A concave portion 15 extending in the extending direction X of the ridge portion 7 is formed therebetween. The aforementioned predetermined distance L2 is selected to be approximately 10 μm to 20 μm. The step portion 8 extends parallel to the extending direction X of the ridge portion 7 and is formed in a stripe shape. The stepped portion 8 is formed so as to extend from a position separated by a predetermined distance L2 from the ridge portion 7 in the width direction Y to the end portion of the semiconductor laser device 1 .

第1台阶结构层13,层积在蚀刻停止层6厚度方向Z的一表面6a上,由与第3镀层11相同的材料形成并且形成为相同厚度。第2台阶结构层14按照遍及第1台阶结构层13厚度方向Z的一表面13a的全表面的方式层积,由与保护层12相同的材料形成并且形成为相同的厚度。也就是,使脊形部7的厚度与台阶部8的厚度形成得相等。通过设置台阶部8,能够在制造半导体激光器件1的制造工艺中对形成有半导体激光器件1先驱体的晶片进行处理时以及半导体激光器件1的安装时,减轻脊形部7所受到的机械损伤。The first stepped structure layer 13 is laminated on one surface 6a of the etching stopper layer 6 in the thickness direction Z, and is made of the same material as the third plating layer 11 and has the same thickness. The second stepped structure layer 14 is laminated over the entire surface of one surface 13 a in the thickness direction Z of the first stepped structure layer 13 , is made of the same material as the protective layer 12 , and has the same thickness. That is, the thickness of the ridge portion 7 and the thickness of the step portion 8 are formed to be equal. By providing the step portion 8, the mechanical damage to the ridge portion 7 can be alleviated when the semiconductor laser device 1 precursor is formed in the manufacturing process of the semiconductor laser device 1, and when the semiconductor laser device 1 is mounted. .

脊形部7面向台阶部8的侧面7b由第1电介质层17覆盖。第1电介质层17从脊形部7的侧面7b沿宽度方向Y向着台阶部8延伸预定距离L3为止,覆盖第3镀层11与蚀刻停止层6的接触部分,另外也层积在蚀刻停止层6厚度方向Z的一表面6a上。The side surface 7 b of the ridge portion 7 facing the step portion 8 is covered with a first dielectric layer 17 . The first dielectric layer 17 extends from the side surface 7b of the ridge portion 7 along the width direction Y toward the step portion 8 for a predetermined distance L3, covers the contact portion between the third plating layer 11 and the etching stop layer 6, and is also laminated on the etching stop layer 6. on one surface 6a in the thickness direction Z.

台阶部8厚度方向Z的一表面8a及面向脊形部7的侧面8b由第2电介质层18覆盖。第2电介质层18从台阶部8的侧面8b沿宽度方向Y向着脊形部7延伸预定距离L4为止,覆盖第3镀层11与蚀刻停止层6的接触部分,另外也层积在蚀刻停止层6厚度方向Z的一表面6a上。One surface 8 a of the step portion 8 in the thickness direction Z and a side surface 8 b facing the ridge portion 7 are covered with the second dielectric layer 18 . The second dielectric layer 18 extends from the side surface 8b of the stepped portion 8 along the width direction Y toward the ridge portion 7 for a predetermined distance L4, covers the contact portion between the third plating layer 11 and the etching stop layer 6, and is also laminated on the etching stop layer 6. on one surface 6a in the thickness direction Z.

第1与第2电介质层17、18由SiO2形成,其厚度选择为1000

Figure C200610142108D0014191009QIETU
~3000
Figure C200610142108D0014191009QIETU
。The 1st and the 2nd dielectric layer 17,18 are formed by SiO 2 , and its thickness is selected as 1000
Figure C200610142108D0014191009QIETU
~3000
Figure C200610142108D0014191009QIETU
.

在脊形部7的厚度方向Z的一表面即保护层12的厚度方向Z的一表面12a上,以遍布全表面方式层积有脊上电极层21。脊上电极层21由AuZn形成,在氮气环境下进行合金化而形成。脊上电极层21,垂直于脊形部7的延伸方向X的剖面形成为以半导体基板2侧为下底的梯形状。On one surface of the ridge portion 7 in the thickness direction Z, that is, one surface 12a of the protective layer 12 in the thickness direction Z, the ridge upper electrode layer 21 is laminated over the entire surface. The upper ridge electrode layer 21 is made of AuZn, and is formed by alloying in a nitrogen atmosphere. The ridge upper electrode layer 21 is formed in a trapezoidal shape with the semiconductor substrate 2 side as the lower base in a cross section perpendicular to the extending direction X of the ridge portion 7 .

第1与第2电介质层17、18以及脊上电极层21、蚀刻停止层6的厚度方向Z的一表面6a中的从第1及第2电介质层17、18之间露出来的部分上,层积有电镀用基底电极层23。电镀用基底电极层23由第1电镀用基底层24和第2电镀用基底层25构成。第1电镀用基底层24由钛(Ti)形成,以层积在第1和第2电介质层17、18以及脊上电极层21、蚀刻停止层6的厚度方向Z的一表面6a中的从第1和第2电介质层17、18之间露出来的部分上的方式形成。第1电镀用基底层24的厚度,例如选择为

Figure C200610142108D00151
。第2电镀用基底层25由金(Au)形成,层积在第1电镀用基底层24的厚度方向Z的一表面24a上。电镀用基底电极层23设置得为了在制造工艺中通过电镀形成后述的电镀电极层27。第2电镀用基底层25的厚度,例如选择为 On the first and second dielectric layers 17, 18, the ridge upper electrode layer 21, and the portion exposed from between the first and second dielectric layers 17, 18 on one surface 6a of the thickness direction Z of the etching stop layer 6, A base electrode layer 23 for plating is laminated. The plating base electrode layer 23 is composed of a first plating base layer 24 and a second plating base layer 25 . The first base layer 24 for electroplating is formed of titanium (Ti) to be laminated on the first and second dielectric layers 17, 18, the ridge upper electrode layer 21, and the one surface 6a in the thickness direction Z of the etching stop layer 6. The exposed portion between the first and second dielectric layers 17 and 18 is formed. The thickness of the base layer 24 for the first electroplating is, for example, selected as
Figure C200610142108D00151
. The second base layer 25 for electroplating is formed of gold (Au), and is laminated on one surface 24 a in the thickness direction Z of the first base layer 24 for electroplating. The plating base electrode layer 23 is provided in order to form a plating electrode layer 27 described later by plating in the manufacturing process. The thickness of the 2nd electroplating base layer 25 is, for example, selected as

第1电镀用基底层24与蚀刻停止层6相接触的部分成为光的吸收体,由此在脊形部7的附近,通过在第1电镀用基底层24与蚀刻停止层6之间设置第1电介质层17,就能够防止光被吸收。上述预定距离L3选择为3μm~7μm,L4也选择为3μm~7μm。关于L3,如果不满3μm则发光效率就会下降,另外如果超过7μm就会失去远场图形(Far Filed Pattern:简称FFP)改善效果。关于预定距离L4,如果不满3μm就不对台阶部侧面设置电介质膜层,因此失去FFP改善效果,另外,如果超过7μm也失去FFP改善效果。通过在脊形部7与台阶部8之间设置光吸收体,能够改善远场图形(FFP)与波纹(ripple),也就是能够抑制FFP的纹乱(disorder)并降低激光的波纹。The part where the first electroplating base layer 24 is in contact with the etching stop layer 6 becomes a light absorber, thus in the vicinity of the ridge portion 7, the first electroplating base layer 24 and the etching stop layer 6 are provided between the first electroplating base layer 24 and the etching stop layer 6. 1 dielectric layer 17, it is possible to prevent light from being absorbed. The aforementioned predetermined distance L3 is selected to be 3 μm to 7 μm, and L4 is also selected to be 3 μm to 7 μm. Regarding L3, if it is less than 3μm, the luminous efficiency will drop, and if it exceeds 7μm, the far-field pattern (Far Filed Pattern: FFP) improvement effect will be lost. Regarding the predetermined distance L4, if the distance L4 is less than 3 μm, the dielectric film layer is not provided on the side of the step portion, so the FFP improvement effect is lost, and if it exceeds 7 μm, the FFP improvement effect is also lost. By disposing a light absorber between the ridge portion 7 and the step portion 8, the far field pattern (FFP) and ripple can be improved, that is, the disorder of the FFP can be suppressed and the ripple of the laser can be reduced.

在电镀用基底电极层23的厚度方向Z的一表面23a上,以遍布全表面的方式层积有电镀电极层27。电镀电极层27是基底金属层并由金(Au)形成。电镀电极层27的厚度,选择为0.5μm以上且不满5.0μm。On one surface 23 a of the base electrode layer 23 for plating in the thickness direction Z, a plating electrode layer 27 is stacked over the entire surface. The plating electrode layer 27 is a base metal layer and is formed of gold (Au). The thickness of the plating electrode layer 27 is selected to be not less than 0.5 μm and less than 5.0 μm.

在电镀电极层27的厚度方向Z的一表面27a上层积有包括不完全粘合层31的金属层32。金属层32例如由钼(Mo)形成。因此不完全粘合层31具有电导性。金属层32的厚度选择为0.05μm~0.30μm。On one surface 27 a of the plating electrode layer 27 in the thickness direction Z, a metal layer 32 including an incomplete adhesion layer 31 is laminated. Metal layer 32 is formed of, for example, molybdenum (Mo). The incomplete adhesion layer 31 therefore has electrical conductivity. The thickness of the metal layer 32 is selected to be 0.05 μm˜0.30 μm.

不完全粘合层31以包括金属层32中的至少在脊形结构部35上形成的部分的方式形成。不完全粘合层31,比脊形波导更靠近外侧,在层积在焊锡层61的最表面部分,至少在脊形结构部35上形成,该焊锡层61将半导体激光器件1安装到后述的安装部62上。The incomplete adhesion layer 31 is formed to include at least a portion of the metal layer 32 formed on the ridge structure portion 35 . The incomplete adhesive layer 31 is formed on at least the ridge structure portion 35 on the outermost portion of the ridge waveguide layer on the outermost portion of the ridge waveguide. on the mounting part 62 of the

脊形结构部35包括:半导体激光器1中的上述脊形部7;第1电介质层17中的层积在脊形部7上的第1脊形层积部分41;脊上电极层21;电镀用基底电极层23中的介由上述第1电介质层17或脊上电极层21层积在脊形部7上的第2脊形层积部分42;电镀电极层27中的层积在第2脊形层积部分42上的第3脊形层积部分43;以及金属层32中的层积在第3脊形层积部分43上的第4脊形层积部分44。也就是,脊形结构部35,是在半导体激光器件1中的宽度方向Y上层积在蚀刻停止层6的厚度方向Z的一表面6a上的部分、脊形部7在蚀刻停止层6侧的两端部间的范围即图1箭头L1所示的范围。The ridge structure part 35 includes: the above-mentioned ridge part 7 in the semiconductor laser 1; the first ridge-shaped laminated part 41 laminated on the ridge part 7 in the first dielectric layer 17; the electrode layer 21 on the ridge; Use the second ridge-shaped laminated part 42 laminated on the ridge portion 7 through the first dielectric layer 17 or the ridge upper electrode layer 21 in the base electrode layer 23; the third ridge-shaped laminated portion 43 on the ridge-shaped laminated portion 42 ; and the fourth ridge-shaped laminated portion 44 laminated on the third ridge-shaped laminated portion 43 in the metal layer 32 . That is, the ridge structure portion 35 is a portion stacked on one surface 6a of the etching stop layer 6 in the thickness direction Z in the width direction Y of the semiconductor laser device 1, and the portion of the ridge portion 7 on the etching stop layer 6 side The range between both ends is the range indicated by the arrow L1 in FIG. 1 .

不完全粘合层31也形成在上述凹部15偏向脊形波导处。不完全粘合层31中的形成在凹部15中的部分,以在脊形波导即脊形部7与台阶部8之间从脊形部7遍布预定距离L5的方式形成。预定距离L5选择为脊形部7与台阶部8间的距离L2的30%以上并不满50%。The incomplete adhesive layer 31 is also formed where the above-mentioned concave portion 15 deviates toward the ridge waveguide. The portion of the incomplete adhesive layer 31 formed in the recess 15 is formed so as to extend a predetermined distance L5 from the ridge 7 between the ridge waveguide, that is, the ridge 7 and the step 8 . The predetermined distance L5 is selected to be more than 30% and less than 50% of the distance L2 between the ridge portion 7 and the step portion 8 .

不完全粘合层31,在脊形部7的延伸方向X中以遍布到半导体激光器件1两端部间的方式形成,由此以从半导体激光器件1的两端面即出射面隔开预定距离L6的方式形成。上述预定距离L6,选择为可在半导体激光器件1的出射面中形成用于防止出射端面损坏的涂布膜。通过如上那样选择上述预定距离L6,能够防止破坏形成在半导体激光器件1中的上述涂布膜。The incomplete adhesive layer 31 is formed in the extending direction X of the ridge portion 7 so as to spread over the two ends of the semiconductor laser device 1, thereby leaving a predetermined distance from the two ends of the semiconductor laser device 1, that is, the outgoing surface. The way L6 is formed. The aforementioned predetermined distance L6 is selected so that a coating film for preventing damage to the exit end face can be formed in the exit surface of the semiconductor laser device 1 . By selecting the aforementioned predetermined distance L6 as above, damage to the aforementioned coating film formed in the semiconductor laser device 1 can be prevented.

在金属层32的厚度方向Z的一表面32a中,除构成上述不完全粘合层31的部分外,层积有完全粘合层33。完全粘合层33由金(Au)形成。完全粘合层33的厚度选择为0.1μm~0.4μm,优选选择为大致0.12μm。完全粘合层33比脊形波导更靠近外侧,在层积有上述焊锡层61的最表面部分宽度方向Y上分别在不完全粘合层31的两侧形成,并且延伸到半导体激光器件1的宽度方向Y的端部为止。On one surface 32 a in the thickness direction Z of the metal layer 32 , a perfect adhesion layer 33 is laminated except for the part constituting the above-mentioned incomplete adhesion layer 31 . The complete adhesion layer 33 is formed of gold (Au). The thickness of the fully bonded layer 33 is selected to be 0.1 μm to 0.4 μm, preferably approximately 0.12 μm. The perfect bonding layer 33 is closer to the outside than the ridge waveguide, and is formed on both sides of the incomplete bonding layer 31 in the width direction Y of the outermost portion on which the above-mentioned solder layer 61 is laminated, and extends to the edge of the semiconductor laser device 1. end in the width direction Y.

上述凹部15偏向台阶部8处上形成有完全粘合层33。完全粘合层33中的形成在凹部15中的部分,以在脊形部7和台阶部8之间从台阶部8遍布预定距离L7的方式形成。预定距离L7选择为脊形部7和台阶部8之间的预定距离L2的50%以下。A complete adhesive layer 33 is formed on the concave portion 15 offset to the step portion 8 . The portion of the complete adhesive layer 33 formed in the concave portion 15 is formed so as to extend over a predetermined distance L7 from the step portion 8 between the ridge portion 7 and the step portion 8 . The predetermined distance L7 is selected to be 50% or less of the predetermined distance L2 between the ridge portion 7 and the step portion 8 .

半导体基板2的厚度方向Z的另一表面中,形成有作为背面金属层的背面金属层36。背面金属层36以遍布半导体基板2的厚度方向Z的另一表面2b的全表面的方式被层积。背面金属层36由金(Au)形成。背面金属层36的厚度与电镀电极层27的不同,选择为

Figure C200610142108D00171
的厚度。On the other surface in the thickness direction Z of the semiconductor substrate 2, a back metal layer 36 as a back metal layer is formed. The back metal layer 36 is laminated over the entire surface of the other surface 2 b in the thickness direction Z of the semiconductor substrate 2 . The back metal layer 36 is formed of gold (Au). The thickness of the back metal layer 36 is different from that of the electroplating electrode layer 27, and is selected as
Figure C200610142108D00171
thickness of.

图3A~图3C、图4A~图4D以及图5A~图5C,是表示半导体激光器件1的制造工序的剖面图。首先如图3A所示,在厚300μm~350μm的半导体基板2的先驱体50的一表面50a上,通过使用分子束外延(简称MBE)装置或有机金属化学气相淀积(简称MOCVD)装置的外延生长法,按以下顺序顺次层积:厚度2.0μm的第1镀层3、有源层4、厚度0.2μm~0.3μm的第2镀层5、厚

Figure C200610142108D00172
的蚀刻停止层6、用于形成第3镀层11及第1台阶结构层13的由p型(Al0.7Ga0.3)0.5In0.5P构成的第1先驱体层51、用于形成保护层12及第2台阶结构层14的第2先驱体层52。在有源层4中,将第1及第2阱层的厚度分别设为
Figure C200610142108D00173
,将势垒层的厚度设为
Figure C200610142108D00174
第1及第2导向层的厚度分别设为
Figure C200610142108D00175
3A to 3C , FIGS. 4A to 4D , and FIGS. 5A to 5C are cross-sectional views showing manufacturing steps of the semiconductor laser device 1 . First, as shown in FIG. 3A , on a surface 50a of a precursor 50 of a semiconductor substrate 2 with a thickness of 300 μm to 350 μm, epitaxy using a molecular beam epitaxy (abbreviated as MBE) device or an organic metal chemical vapor deposition (abbreviated as MOCVD) device The growth method is sequentially stacked in the following order: the first coating layer 3 with a thickness of 2.0 μm, the active layer 4, the second coating layer 5 with a thickness of 0.2 μm to 0.3 μm, the thickness
Figure C200610142108D00172
The etch stop layer 6, the first precursor layer 51 composed of p-type (Al 0.7 Ga 0.3 ) 0.5 In 0.5 P for forming the third plating layer 11 and the first step structure layer 13, and the first precursor layer 51 for forming the protective layer 12 and The second precursor layer 52 of the second stepped structure layer 14 . In the active layer 4, the thicknesses of the first and second well layers are set to
Figure C200610142108D00173
, set the thickness of the barrier layer to
Figure C200610142108D00174
The thicknesses of the first and second guide layers are set as
Figure C200610142108D00175

接着,使用光刻技术及蚀刻技术,去除第1先驱体层51及第2先驱体层52的一部分,如图3B所示,形成上述脊形部7及台阶部8。Next, parts of the first precursor layer 51 and the second precursor layer 52 are removed using photolithography and etching techniques, and as shown in FIG. 3B , the aforementioned ridge portion 7 and step portion 8 are formed.

接着,覆盖脊形部7和台阶部8及蚀刻停止层6的厚度方向Z的一表面6a,在层积电介质层后,使用光刻技术及蚀刻技术去除该电介质层中的层积在脊形部7上的部分和层积在蚀刻停止层6上的部分中的一部分,由此形成第1与第2电介质层17、18。Next, cover the ridge portion 7 and the step portion 8 and a surface 6a in the thickness direction Z of the etching stop layer 6, after laminating the dielectric layer, use photolithography technology and etching technology to remove the layered layer on the ridge in the dielectric layer. The part on the part 7 and part of the part on the etching stop layer 6 are laminated, thereby forming the first and second dielectric layers 17 and 18.

接着,覆盖第1及第2电介质层17、18、蚀刻停止层6的厚度方向Z的一表面6a中的从第1及第2电介质层17、18中露出的部分、以及脊形部7的厚度方向Z的一表面7a,在涂布抗蚀剂后,使用光刻技术与蚀刻技术去除抗蚀剂中的层积在脊形部7的厚度方向Z的一表面7a上的部分,如图3C所示,由此形成抗蚀图层53。Then, the first and second dielectric layers 17, 18, the portions exposed from the first and second dielectric layers 17, 18, and the ridge portion 7 of one surface 6a in the thickness direction Z of the etching stop layer 6 are covered. One surface 7a in the thickness direction Z, after coating the resist, use photolithography and etching to remove the part of the resist layered on the one surface 7a in the thickness direction Z of the ridge portion 7, as shown in the figure 3C, a resist layer 53 is thus formed.

接着,以覆盖脊形部7的厚度方向Z的一表面7a及抗蚀图层53的方式蒸镀膜厚400

Figure C200610142108D0014191009QIETU
~3000
Figure C200610142108D0014191009QIETU
的由AuZn构成的第3先驱体层,然后通过剥离(1ift—off)法将第3先驱体层中除层积在脊形部7上的部位外的部分与抗蚀图层53一起去除。由此,如图4A所示,脊上电极层21就形成在保护层12的厚度方向Z的一表面12a上。Next, a film thickness of 400 is deposited so as to cover one surface 7a of the ridge portion 7 in the thickness direction Z and the resist layer 53.
Figure C200610142108D0014191009QIETU
~3000
Figure C200610142108D0014191009QIETU
The third precursor layer made of AuZn, and then the part of the third precursor layer except the part laminated on the ridge part 7 is removed together with the resist layer 53 by a lift-off method. Thus, as shown in FIG. 4A , the ridge upper electrode layer 21 is formed on one surface 12 a in the thickness direction Z of the protective layer 12 .

接着,如图4B所示,将半导体基板厚度研磨到半导体基板2的厚度为止。也就是,研磨半导体基板2的先驱体50厚度方向Z的另一表面,从而形成厚50μm~130μm的半导体基板2。Next, as shown in FIG. 4B , the thickness of the semiconductor substrate is ground to the thickness of the semiconductor substrate 2 . That is, the other surface of the precursor 50 in the thickness direction Z of the semiconductor substrate 2 is ground to form a semiconductor substrate 2 with a thickness of 50 μm to 130 μm.

接着如图4C所示,在半导体基板2的厚度方向Z的另一表面2b上,形成背面电极层36,由此,在氮气环境下使脊上电极层21和背面电极层36合金化。Next, as shown in FIG. 4C , on the other surface 2 b in the thickness direction Z of the semiconductor substrate 2 , a back electrode layer 36 is formed, whereby the ridge upper electrode layer 21 and the back electrode layer 36 are alloyed in a nitrogen atmosphere.

接着,从半导体基板2的一表面2a侧,如图4C所示,在第1及第2电介质层17、18、脊形电极层21及蚀刻停止层6上,将Ti以层厚

Figure C200610142108D00181
Figure C200610142108D00182
的方式蒸镀并层积,从而形成第1电镀用基底层24,此后,进一步将Au以层厚
Figure C200610142108D00183
的方式蒸镀,从而形成第2电镀用基底层25。由此,形成电镀用基底电极层23。Next, from the one surface 2a side of the semiconductor substrate 2, as shown in FIG.
Figure C200610142108D00181
Figure C200610142108D00182
The method is evaporated and laminated to form the first base layer 24 for electroplating. After that, Au is further added with a layer thickness
Figure C200610142108D00183
By evaporation, the second base layer 25 for electroplating is formed. Thus, base electrode layer 23 for plating is formed.

接着,给电镀用基底电极层23供电来进行规定时间的电解Au的电镀,由此,如图4D所示那样,形成层厚0.5以上且不满5.0μm的电镀电极层23。Next, by supplying electric power to the plating base electrode layer 23 and performing electrolytic Au plating for a predetermined time, as shown in FIG. 4D , the plating electrode layer 23 having a layer thickness of 0.5 to less than 5.0 μm is formed.

接着,在电镀电极层23的厚度方向Z的一表面23a上,通过蒸镀Mo而如图5A所示那样形成金属层32,然后,在金属层32的厚度方向Z的一表面32a上,通过蒸镀Au形成第4先驱体层57。Next, on one surface 23a in the thickness direction Z of the plating electrode layer 23, a metal layer 32 is formed as shown in FIG. Au is evaporated to form the fourth precursor layer 57 .

接着,在第4先驱体层57的厚度方向Z的一表面57a上涂布抗蚀剂后,使用光刻技术及蚀刻技术去除第4先驱体层57中的层积在金属层32上的抗蚀剂的一部分,以使层积在金属层32中的应当成为不完全粘合层31部分中的部分露出来,由此,如图5B所示那样形成抗蚀图层58。由抗蚀图层58产生的掩模宽度即从抗蚀图层58中露出来的金属层32的宽度方向Y的尺寸约为20μm。也就是,金属层32从穿过脊形部7的中央并且垂直于宽度方向Y的一假想平面、向宽度方向Y的一方及另一方露出约10μm。另外,金属层32在脊形部7的延伸方向X中的两端部由抗蚀图层58覆盖。Next, after coating a resist on one surface 57a in the thickness direction Z of the fourth precursor layer 57, the resist laminated on the metal layer 32 in the fourth precursor layer 57 is removed using photolithography and etching techniques. A part of the etchant is removed to expose a part of the metal layer 32 that should be the part of the incompletely bonded layer 31, thereby forming a resist layer 58 as shown in FIG. 5B. The mask width created by the resist layer 58 , that is, the dimension in the width direction Y of the metal layer 32 exposed from the resist layer 58 is about 20 μm. That is, the metal layer 32 is exposed to one side and the other side of the width direction Y by about 10 μm from a virtual plane passing through the center of the ridge portion 7 and perpendicular to the width direction Y. In addition, both end portions of the metal layer 32 in the extending direction X of the ridge portion 7 are covered with a resist layer 58 .

接着,通过蚀刻技术去除从抗蚀图层58露出来的第4先驱体层57,而使金属层32的一部分露出来。金属层32中的该露出来的部分形成不完全粘合层31。另外,去除第4先驱体层57的一部分,进而去除抗蚀图层58,由此,如图5C所示在不完全粘合层31的宽度方向Y的两侧形成完全粘合层33。Next, the fourth precursor layer 57 exposed from the resist layer 58 is removed by an etching technique to expose a part of the metal layer 32 . This exposed portion of the metal layer 32 forms the incompletely bonded layer 31 . In addition, by removing part of the fourth precursor layer 57 and further removing the resist layer 58 , perfect adhesion layers 33 are formed on both sides of the incomplete adhesion layer 31 in the width direction Y as shown in FIG. 5C .

图6是表示介由焊锡层61在安装部62上安装半导体激光器件1后的半导体激光装置60的剖面图。半导体激光器件1,在上述的不完全粘合层31及完全粘合层33上层积焊锡层61,由此通过小片接合(die—bonding)安装在安装部62中。构成焊锡层61的焊锡材料由AuSn形成,在本实施方式中,Au含有70%,并且Sn含有30%。安装部62是所谓的副底座,例如由氮化铝(AlN)等电导率及热传导率高的材料形成。6 is a cross-sectional view showing the semiconductor laser device 60 after the semiconductor laser device 1 is mounted on the mounting portion 62 via the solder layer 61 . The semiconductor laser device 1 is mounted in the mounting portion 62 by die-bonding by laminating the solder layer 61 on the above-mentioned incomplete adhesion layer 31 and perfect adhesion layer 33 . The solder material constituting the solder layer 61 is made of AuSn, and in this embodiment, Au contains 70% and Sn contains 30%. The mounting portion 62 is a so-called sub-mount, and is formed of a material having high electrical conductivity and thermal conductivity such as aluminum nitride (AlN), for example.

半导体激光器件1通过给定的小片接合条件与安装部62小片接合。小片接合条件包括:将半导体激光器件1安装在安装部62中时所加载的荷重的条件,和将半导体激光器件1安装在安装部62中时所附加的加热条件。The semiconductor laser device 1 is die-bonded to the mounting portion 62 under given die-bonding conditions. The die bonding conditions include conditions of load applied when the semiconductor laser device 1 is mounted in the mounting portion 62 , and heating conditions applied when the semiconductor laser device 1 is mounted in the mounting portion 62 .

物理的荷重对于将半导体激光器件1压接在安装部62上的焊锡层61上是必须的,但如果加载较重的荷重例如1.0N(牛顿)等,半导体激光器件1的内部结构即脊形结构部35及第1和第2电介质层17、18等就会被过度加压,由此通过应力使脊形结构部35发生变形,最坏的情况下则导致半导体激光器件1被损坏。相反地,如果加载较轻的荷重例如0.05N,由于加压不足半导体激光器件1就不能接合在安装部62上的焊锡层61上,由此导致剥离。因此,上述荷重条件选择为大于0.05N且不满1.0N,作为优选,不采用较重的荷重区域而采用较轻的荷重区域,例如选择为0.1N~0.3N。A physical load is necessary for crimping the semiconductor laser device 1 on the solder layer 61 on the mounting portion 62, but if a heavier load such as 1.0N (Newton) is applied, the internal structure of the semiconductor laser device 1 is ridge-shaped. The structure portion 35 and the first and second dielectric layers 17 and 18 are excessively stressed, thereby deforming the ridge structure portion 35 due to stress, and in the worst case, destroying the semiconductor laser device 1 . Conversely, if a light load such as 0.05N is applied, the semiconductor laser device 1 cannot be bonded to the solder layer 61 on the mounting portion 62 due to insufficient pressure, thereby causing peeling. Therefore, the above-mentioned load condition is selected to be greater than 0.05N and less than 1.0N. Preferably, a lighter load range is used instead of a heavy load range, for example, 0.1N-0.3N.

另外,为了使安装部62上的焊锡层61熔化,由此在半导体激光器件1的小片接合面的最表面以合金化方式形成由Au构成的完全粘合层33,于是需要将安装部62置于加热器中进行加热,如果加热量较多,例如在360℃(度)下加热30s(秒)后,在使用吹风机以1秒中强制冷却到大致200℃的情况下,半导体激光器件1的内部的层积结构中因热膨胀系数等之差所产生的各层的剥离、分离、物性变化以及合金形成等,就产生应力从而成为变形的原因。相反地,如果加热量较少,例如在280℃下加热0.3s后,在使用吹风机以1秒中强制冷却到大致200℃的情况下,就会没有形成合金,从而半导体激光器件1不能接合到安装部62上的焊锡层61中,由此导致剥离。因此,上述加热条件,加热温度选择为大于200℃不满360℃,并且加热时间选择为长于0.3秒不满30秒,另外因为在加热量较少的区域中的条件有利,所以将加热条件设为300℃下加热大约2s。In addition, in order to melt the solder layer 61 on the mounting portion 62, thereby forming a complete bonding layer 33 made of Au in an alloyed manner on the outermost surface of the die bonding surface of the semiconductor laser device 1, it is necessary to place the mounting portion 62 on the surface. Heating in a heater, if the amount of heating is large, for example, after heating at 360°C (degrees) for 30s (seconds), and then using a blower to forcibly cool to about 200°C in 1 second, the semiconductor laser device 1 Delamination, separation, changes in physical properties, and alloy formation of each layer due to differences in thermal expansion coefficients in the internal laminated structure generate stress and cause deformation. Conversely, if the amount of heating is small, for example, after heating at 280° C. for 0.3 seconds and then forcibly cooling to about 200° C. in 1 second using a blower, no alloy will be formed, and the semiconductor laser device 1 cannot be bonded to In the solder layer 61 on the mounting portion 62, this causes peeling. Therefore, for the above heating conditions, the heating temperature is selected to be greater than 200°C and less than 360°C, and the heating time is selected to be longer than 0.3 seconds and less than 30 seconds. In addition, because the conditions in the area with less heating amount are favorable, the heating condition is set to 300°C. ℃ for about 2s.

上述温度条件,在较大程度上也被位于半导体激光器件1的小片接合面侧的最表面的完全接合层33的厚度所左右,因此,由于加热量较少的区域(300℃下大约2s)有利,所以将不完全粘合层31的厚度薄膜化,例如设为0.12μm并在短时间内形成合金。The above-mentioned temperature conditions are largely influenced by the thickness of the uppermost complete bonding layer 33 located on the side of the die bonding surface of the semiconductor laser device 1. Therefore, in a region with a small amount of heating (about 2s at 300° C.) Advantageously, the thickness of the incomplete adhesion layer 31 is reduced, for example, to 0.12 μm, and the alloy is formed in a short time.

构成焊锡层61的焊锡材料即AuSn与完全粘合层33的Au的合金反应,也就是AuSn与完全粘合层33的Au的合金化,在由荷重加压的状态下通过加热开始。AuSn与Au反应并且进行合金化的流程是:通过加热使AuSn熔化,将该熔化的AuSn附着在完全粘合层33的表面上,由此通过直接加热而使AuSn扩散到完全粘合层33的内部。扩散方向是向着完全粘合层33的厚度方向进行,但由完全粘合层33的表面的数点处开始扩散,如果继续加热,则位于数处的扩散点不仅增加并且该点就从点状扩大成圆形。AuSn向完全粘合层33的厚度方向Z扩散的深度与速度,由焊锡材料AuSn与形成完全粘合层33的Au的绝对量之比即质量比与加热量来确定,到完全扩散结束为止的时间也是同样的。因此,在焊锡材料的量较多而完全粘合层33的Au的量较少、并且加热量较多的情况下,完全粘合层33只需与AuSn瞬间地接触就被合金化,由此,如前形成半导体激光器件1的小片接合面侧的最表面的完全粘合层33,设置较多的焊锡材料的量,由此通过在AuSn开始扩散时就停止加热,从而停止扩散。The alloy reaction of AuSn, which is the solder material constituting the solder layer 61, and Au of the perfect adhesion layer 33, that is, the alloying of AuSn and Au of the perfect adhesion layer 33, starts by heating under the state of being pressed by a load. The flow of AuSn reacting with Au and alloying is: AuSn is melted by heating, and the melted AuSn is attached to the surface of the perfect adhesion layer 33, whereby AuSn is diffused to the surface of the perfect adhesion layer 33 by direct heating. internal. Diffusion direction is to carry out toward the thickness direction of complete adhesive layer 33, but begins to diffuse from several points on the surface of complete adhesive layer 33, if continue to heat, then the diffusion point that is positioned at several places not only increases and this point just from point-like Expand into a circle. The depth and speed of diffusion of AuSn to the thickness direction Z of the complete adhesion layer 33 are determined by the ratio of the absolute amount of the solder material AuSn to the Au forming the complete adhesion layer 33, that is, the mass ratio and the amount of heating. Time is the same. Therefore, when the amount of solder material is large, the amount of Au in the perfect bonding layer 33 is small, and the amount of heating is large, the perfect bonding layer 33 is alloyed only by instantaneous contact with AuSn, thereby By forming the outermost complete bonding layer 33 on the die bonding surface side of the semiconductor laser device 1 as before, a large amount of solder material is provided, and the heating is stopped when AuSn starts to diffuse, thereby stopping the diffusion.

在半导体激光器件1的半导体基板2的厚度方向Z的一方侧的最表面中的、脊形结构部35上,形成由Mo构成的不完全粘合层31,则由于Au自身消失,虽然由AuSn构成的焊锡材料与不完全粘合层31密接,但也没有合金形成。只在完全粘合层33的全表面中,产生与层积在安装部62中的焊锡材料AuSn的合金形成。不完全粘合层31与焊锡层61的粘合不完全,由此,不完全粘合层31与完全粘合层33相比,在将半导体激光器件1安装到安装部62上时,从焊锡层61接受到的应力较小。On the outermost surface of one side of the thickness direction Z of the semiconductor substrate 2 of the semiconductor laser device 1, on the ridge structure portion 35, an incomplete adhesion layer 31 made of Mo is formed, and since Au itself disappears, although AuSn The constituted solder material is in close contact with the incomplete adhesion layer 31, but no alloy is formed. Alloy formation with the solder material AuSn laminated on the mounting portion 62 occurs only on the entire surface of the complete adhesion layer 33 . The adhesion of the incomplete adhesive layer 31 and the solder layer 61 is not complete, thus, the incomplete adhesive layer 31 is more resistant to soldering when the semiconductor laser device 1 is mounted on the mounting portion 62 than the complete adhesive layer 33 . Layer 61 receives less stress.

半导体激光装置60中,在将半导体激光器件1安装到安装部62上时,遍布半导体激光器件1的厚度方向的一表面的全表面中层积焊锡材料,由此与部分地层积焊锡材料的情况相比,安装较容易。In the semiconductor laser device 60, when the semiconductor laser device 1 is mounted on the mounting portion 62, the solder material is deposited over the entire surface of one surface in the thickness direction of the semiconductor laser device 1, thereby being different from the case where the solder material is partially deposited. than, the installation is easier.

制作使用本发明的半导体激光器件1的半导体激光装置60(以下有时也称作实施例1的半导体激光装置),以及制作使用比较例的半导体激光器件的半导体激光装置(以下也称作比较例的半导体激光装置),来测量偏振特性。比较例的半导体激光器件的结构,是在半导体激光器件1的金属层32的厚度方向Z的一表面32a的全表面中形成由Au构成的合金形成层。该合金形成层形成为与完全粘合层33相同的厚度。A semiconductor laser device 60 using the semiconductor laser device 1 of the present invention (hereinafter also referred to as the semiconductor laser device of Embodiment 1) was produced, and a semiconductor laser device using the semiconductor laser device of the comparative example (hereinafter also referred to as the semiconductor laser device of the comparative example) was produced. semiconductor laser device) to measure polarization properties. The structure of the semiconductor laser device of the comparative example is such that an alloy formation layer made of Au is formed on the entire surface of one surface 32 a of the metal layer 32 in the thickness direction Z of the semiconductor laser device 1 . This alloy forming layer is formed to have the same thickness as the complete adhesion layer 33 .

实际制作这些半导体激光器件1与比较例的半导体激光器件时,准备1片由p型GaAs构成的晶片,如图5A所示那样在形成第4先驱体层后,将晶片分割成两份。使用分割成两份后的晶片中的一方,通过上述的工序形成多个形成有不完全电极层31的半导体激光器件1,另外,使用另一方形成多个比较例的半导体激光器件。When actually fabricating these semiconductor laser devices 1 and the semiconductor laser device of the comparative example, one wafer made of p-type GaAs was prepared, and after forming the fourth precursor layer as shown in FIG. 5A , the wafer was divided into two. One of the divided wafers was used to form a plurality of semiconductor laser devices 1 having incomplete electrode layers 31 through the above-mentioned steps, and the other was used to form a plurality of semiconductor laser devices of comparative examples.

将所形成的半导体激光器件1与比较例的半导体激光器件,皆在上述的小片接合条件下,通过焊锡材料焊接到安装部62上。安装在安装部62上的各半导体激光器件,使用Ag浆膏(paste)安装在5.6φ的管座也即直径5.6mm的管座上,经过引线接合·顶盖密封等工序制作出来。在相同条件下对该所制作的半导体激光装置进行老化试验,所测定的激光的偏振特性如表1所示。作为偏振特性测定偏振比以及偏振角。The formed semiconductor laser device 1 and the semiconductor laser device of the comparative example were all soldered to the mounting portion 62 with a solder material under the above-mentioned die bonding conditions. Each semiconductor laser device mounted on the mounting portion 62 is mounted on a 5.6φ stem, that is, a stem with a diameter of 5.6mm, using Ag paste, and is manufactured through processes such as wire bonding and cap sealing. An aging test was carried out on the manufactured semiconductor laser device under the same conditions, and the measured polarization characteristics of the laser are shown in Table 1. The polarization ratio and polarization angle were measured as polarization characteristics.

【表1】【Table 1】

  偏振特性 实施例1 比较例 偏振比(Ave) 343 174 偏振比(σ) 79 112 偏振角(Ave) 1.6 —2.1 偏振角(σ) 1.1 3.5 Polarization characteristics Example 1 comparative example Polarization ratio (Ave) 343 174 Polarization ratio (σ) 79 112 Polarization angle (Ave) 1.6 —2.1 Polarization angle (σ) 1.1 3.5

关于偏振比,测定多个其中30个的半导体激光装置的平均值(Ave)与标准偏差(σ)。关于偏振角,测定多个其中30个的半导体激光装置的平均值(Ave)与标准偏差(σ)。偏振角,是将一定方向的偏振滤光器相对于激光的出射而平行地进行设置并在使偏振滤光器移位90°角时,通过偏振滤光器由受光部接收的光功率成为最大的角度。Regarding the polarization ratio, the average value (Ave) and the standard deviation (σ) of 30 semiconductor laser devices were measured. Regarding the polarization angle, the average value (Ave) and the standard deviation (σ) of 30 semiconductor laser devices were measured. Polarization angle means that when a polarization filter in a certain direction is arranged in parallel with respect to the emission of laser light and the polarization filter is shifted by an angle of 90°, the light power received by the light receiving part through the polarization filter becomes the maximum Angle.

如表1所示,实施例1的半导体激光装置与比较例的半导体激光装置相比,偏振比较大且偏振角较小,并且偏振比与偏振角的离散偏差也都较小。在比较例的半导体激光装置中,如果通过上述的小片接合条件将半导体激光器件安装到副底座上,则位于小片接合面侧的最表面的由Au构成的合金形成层,就与副底座上的AuSn进行合金形成。在比较例的半导体激光装置中,在脊形结构部35的最表面部也可靠地进行合金化,因此不会发生高温下的Iop(额定电流)上升,从而较稳定,但在常温下的激光特性测量中,在具有相同结构的多个半导体激光器件中,偏振比的Ave(平均值)较低,并且偏振比的σ(标准偏差)的离散偏差幅度增大。另外,偏振角的Ave偏向负侧,并且偏振角的σ的离散偏差幅度增大。其原因是,在从外部向脊形结构部35扩散的焊锡材料与位于半导体激光器件的最表面部的合金形成层形成合金时,对脊形结构部35形成合金同时脊形部7由AuSn覆盖,由于合金形成后应力就被附加,从而发生变形。对于成为该变形根源的应力而言,推测为在由Au构成的合金形成层与由AuSn构成的焊锡材料进行合金形成时,对脊形结构部35的压力和张力的混合力。As shown in Table 1, compared with the semiconductor laser device of Comparative Example, the semiconductor laser device of Example 1 has a larger polarization ratio and a smaller polarization angle, and the dispersion deviation of both the polarization ratio and the polarization angle is also smaller. In the semiconductor laser device of the comparative example, when the semiconductor laser device is mounted on the submount under the above-mentioned die bonding conditions, the alloy formation layer made of Au located on the outermost surface on the die bonding surface side is formed in contact with the submount on the submount. AuSn performs alloy formation. In the semiconductor laser device of the comparative example, the alloying is also reliably carried out at the outermost portion of the ridge structure portion 35, so the Iop (rated current) at high temperature does not rise and is relatively stable, but the laser light at normal temperature In characteristic measurement, in a plurality of semiconductor laser devices having the same structure, Ave (average value) of the polarization ratio is low, and the dispersion width of σ (standard deviation) of the polarization ratio increases. In addition, Ave of the polarization angle is shifted to the negative side, and the dispersion deviation width of σ of the polarization angle is increased. The reason is that when the solder material diffused from the outside to the ridge structure portion 35 forms an alloy with the alloy formation layer positioned at the outermost portion of the semiconductor laser device, the ridge structure portion 35 is alloyed while the ridge portion 7 is covered by AuSn. , since the stress is added after the alloy is formed, deformation occurs. The stress that becomes the source of this deformation is presumed to be a mixed force of pressure and tension on the ridge structure portion 35 when the alloy formation layer made of Au and the solder material made of AuSn are alloyed.

另外,脊形结构部35的表面部中具有由Au形成的合金形成层,作为其基底层形成有:由Mo构成的金属层32、由Au构成的电镀电极层27以及电镀用基底电极层23等,但合金形成层与焊锡材料进行合金形成后所接受到的应力,推测为对其基底层也产生影响,由此推测出压力与张力共同作用。推测上述应力中的压力,在焊锡材料加热引起膨胀时产生,推测张力在焊锡材料加热后进行冷却时产生。因此,在焊锡材料膨胀一定程度,以一定程度与脊形结构部35相接触,并且收缩一定程度的情况下,对脊形结构部35作用均匀的应力,由此能够降低变形的发生,从而在接近裸芯片状态的形式下,就可以将半导体激光器件粘合在副底座上。但是,现实中焊锡材料膨胀及收缩时,并非进行一定程度的膨胀及收缩,而是进行部分地不定的膨胀及收缩。因而,加热时在脊形结构部35中局部地产生较大压力部分和较小压力部分,合金形成也局部地进行,由此使应力局部地产生。在局部地进行合金形成并且停止加热而开始冷却的情况下,这时焊锡材料开始收缩,从而在脊形结构部35中就产生局部地附加有大有小的张力和有大有小的压力的部分。此时,收缩的张力与压力推测为对脊形结构部35施加应力的力。另外冷却时,脊形结构部35的最表面部所形成的合金形成层与焊锡材料发生反应而被合金形成的AuSn层则收缩。AuSn是焊锡材料的一种,但在加热AuSn使其接合的300℃~400℃的温度区域中,难于与基底层即由Mo构成的金属层32进行合金形成,反而变向剥离方向,并且由于合金化形成层与金属层32通过溅射进行层积,因此在比较例的半导体激光装置中,可推定合金化的合金化形成层拉伸金属层32,从而对金属层32的应力增大。这样,在比较例的半导体激光装置中,对金属层32施加应力从而发生变形,由此可推定应力还波及到基底层,最终应力作用到最重要的脊形结构部35的脊形部7上为止,而使脊形部7变形。因而,如果不均匀地赋予脊形结构部35应力,就使激光特性恶化,由此均匀地赋予脊形结构部35应力而使变形降低这方面非常重要。使得附加到脊形结构部35的应力不均匀的要因,推测是由于脊形结构部35的最表面部由AuSn合金形成。也就是,可以推测如果对脊形结构部35的最表面部不进行合金形成,应力就会变得均匀而使变形降低,由此激光特性应当不会恶化。In addition, the surface portion of the ridge structure portion 35 has an alloy formation layer made of Au, and as its base layer, a metal layer 32 made of Mo, a plating electrode layer 27 made of Au, and a base electrode layer 23 for plating are formed. However, the stress received by the alloy forming layer and the solder material after alloying is presumed to affect the base layer as well, and it is presumed that the stress and the tension act together. It is presumed that the pressure among the above stresses is generated when the solder material is heated and expanded, and the tension is presumed to be generated when the solder material is cooled after heating. Therefore, when the solder material expands to a certain extent, contacts the ridge structure portion 35 to a certain extent, and shrinks to a certain extent, a uniform stress acts on the ridge structure portion 35, whereby the occurrence of deformation can be reduced. In the form close to the bare chip state, the semiconductor laser device can be bonded on the submount. However, in actuality, when the solder material expands and contracts, it does not expand and contract to a certain degree, but expands and contracts partially and indefinitely. Therefore, a relatively high pressure portion and a relatively small pressure portion are locally generated in the ridge structure portion 35 during heating, and alloy formation also proceeds locally, whereby stress is locally generated. In the case where alloy formation is performed locally and heating is stopped and cooling is started, the solder material starts to shrink at this time, thereby locally adding large and small tensions and large and small pressures to the ridge structure portion 35 . part. At this time, the contraction tension and pressure are presumed to be forces that apply stress to the ridge structure portion 35 . In addition, during cooling, the alloy-forming layer formed on the outermost portion of the ridge structure portion 35 reacts with the solder material, and the AuSn layer formed by the alloy shrinks. AuSn is a kind of solder material, but in the temperature range of 300°C to 400°C where AuSn is heated to join, it is difficult to form an alloy with the base layer, that is, the metal layer 32 made of Mo, and instead changes to the peeling direction, and because Since the alloyed layer and the metal layer 32 are laminated by sputtering, in the semiconductor laser device of the comparative example, it is presumed that the alloyed alloyed layer stretches the metal layer 32 to increase the stress on the metal layer 32 . In this way, in the semiconductor laser device of the comparative example, stress is applied to the metal layer 32 to cause deformation. From this, it can be estimated that the stress also spreads to the base layer, and finally the stress acts on the ridge portion 7 of the most important ridge structure portion 35. So far, the ridge portion 7 is deformed. Therefore, it is very important to uniformly apply stress to the ridge structure 35 to reduce deformation because the laser characteristics will be deteriorated if the stress is not uniformly applied to the ridge structure portion 35 . The cause of the uneven stress applied to the ridge structure portion 35 is presumed to be that the outermost portion of the ridge structure portion 35 is formed of an AuSn alloy. That is, it is presumed that if alloy formation is not performed on the outermost portion of the ridge structure portion 35, the stress becomes uniform to reduce deformation, and thus the laser characteristics should not be deteriorated.

通过测量实施例1及比较例的半导体激光装置的偏振特性,根据对脊形结构部35应力作用的方式,就能够使脊形结构部35的变形降低,从而改善偏振特性。By measuring the polarization characteristics of the semiconductor laser devices of Example 1 and Comparative Example, the deformation of the ridge structure portion 35 can be reduced according to the way the stress acts on the ridge structure portion 35, thereby improving the polarization characteristics.

另外,实施例1的半导体激光装置60,在观察其实际的剖面时,也可以确认安装部62上的由AuSn构成的焊锡材料与完全粘合层33发生反应而变成合金,上述AuSn与不完全粘合层31不发生合金反应,也就是AuSn不与不完全粘合层31发生反应也就不变成合金。In addition, in the semiconductor laser device 60 of Example 1, when observing its actual cross section, it can also be confirmed that the solder material composed of AuSn on the mounting portion 62 reacts with the complete adhesion layer 33 to form an alloy. The complete bonding layer 31 does not undergo alloying reaction, that is, AuSn does not become an alloy if it does not react with the incomplete bonding layer 31 .

如上所述,在使用半导体激光器件1的半导体激光装置60中,能够谋求组装完成品状态下的激光偏振特性的测定项目偏振比的提高以及偏振比离散偏差的抑制,另外,能够减小偏振角并且谋求偏振角离散偏差的改善。通过提高偏振比,就能够谋求半导体激光装置60的光输出的稳定性。另外,通过减小偏振角并且谋求偏振角的离散偏差的改善,就能够改善FFP辐射特性的功率变化,另外能够谋求所出射的激光辐射噪声的降低。As described above, in the semiconductor laser device 60 using the semiconductor laser device 1, it is possible to improve the polarization ratio of the measurement items of the laser polarization characteristics in the assembled state and to suppress the dispersion of the polarization ratio, and to reduce the polarization angle. In addition, the dispersion of the polarization angle is improved. By increasing the polarization ratio, the stability of the light output of the semiconductor laser device 60 can be achieved. In addition, by reducing the polarization angle and improving the dispersion of the polarization angle, it is possible to improve the power variation of the FFP radiation characteristic, and to reduce the radiation noise of the emitted laser light.

另外,半导体激光装置60中宽度方向Y上不完全粘合层31的两侧,分别形成有完全粘合层33,因此能够牢固地将半导体激光器件1与安装部62机械连接。In addition, perfect adhesion layers 33 are respectively formed on both sides of the incomplete adhesion layer 31 in the width direction Y of the semiconductor laser device 60 , so that the semiconductor laser device 1 and the mounting portion 62 can be firmly mechanically connected.

另外,半导体激光装置60中,凹部15偏向脊形结构部35处形成有不完全粘合层31,因此能够进一步降低从脊形结构部35的周围赋予脊形结构部35的应力。在脊形结构部35与焊锡层61的界面中,因为激光出射而在脊形结构部35中产生的热就难于释放,所以通过在凹部15偏向台阶部8处形成完全粘合层33,就能够使所产生的热从完全粘合层33介由焊锡层61高效地释放到安装部62中。In addition, in the semiconductor laser device 60 , the recess 15 is offset from the ridge structure 35 and the incomplete adhesion layer 31 is formed, so that the stress applied to the ridge structure 35 from the periphery of the ridge structure 35 can be further reduced. In the interface between the ridge structure part 35 and the solder layer 61, it is difficult to release the heat generated in the ridge structure part 35 due to the emission of laser light, so by forming the complete adhesion layer 33 at the place where the concave part 15 deviates to the step part 8, it is possible to The generated heat can be efficiently released from the perfect adhesion layer 33 to the mounting portion 62 via the solder layer 61 .

另外,半导体激光装置60中,将上述的预定距离L5选择为脊形部7与台阶部8之间的预定距离L2的30%以上,就能够更可靠地降低应力,从而将上述预定距离L5设为不满预定距离L2的50%,就使得来自脊形波导的热难于释放到焊锡层中,从而能够抑制半导体激光器件的电流值特性恶化。In addition, in the semiconductor laser device 60, the stress can be more reliably reduced by selecting the above-mentioned predetermined distance L5 to be 30% or more of the predetermined distance L2 between the ridge portion 7 and the step portion 8, so that the above-mentioned predetermined distance L5 is set to If it is less than 50% of the predetermined distance L2, the heat from the ridge waveguide is difficult to be released into the solder layer, so that the deterioration of the current value characteristic of the semiconductor laser device can be suppressed.

另外,在半导体激光装置60中,将上述预定距离L7选择为预定距离的50%以下,就使完全粘合层33中所产生的应力难于传递给脊形结构部35,由此能够进一步降低脊形结构部35中产生的变形。In addition, in the semiconductor laser device 60, selecting the above-mentioned predetermined distance L7 to be 50% or less of the predetermined distance makes it difficult for the stress generated in the complete adhesion layer 33 to be transmitted to the ridge structure portion 35, thereby further reducing the ridge structure. The deformation produced in the shape structure part 35.

另外,半导体激光器件1中脊形部7与台阶部8之间,由Ti构成的第1电镀用基底层24与通过外延生长所形成的蚀刻停止层6相接触,因此,为了使该第1电镀用基底层24与蚀刻停止层6相接触的部分中电流不流动,作为欧姆电极的脊上电极层21就以只层积在脊形部7上的方式形成。第1电镀用基底层24和蚀刻停止层6没有形成低电阻的欧姆接触,由此可使电流以只集中在通过脊上电极层21和保护层12形成有欧姆接触的脊形部7中的方式流动。In addition, between the ridge portion 7 and the step portion 8 in the semiconductor laser device 1, the first plating base layer 24 made of Ti is in contact with the etching stop layer 6 formed by epitaxial growth. Current does not flow in the part where the plating base layer 24 is in contact with the etching stopper layer 6 , and the ridge upper electrode layer 21 as an ohmic electrode is formed so as to be laminated only on the ridge portion 7 . The first electroplating base layer 24 and the etching stop layer 6 do not form a low-resistance ohmic contact, so that the current can be concentrated only in the ridge portion 7 formed with the ohmic contact by the ridge upper electrode layer 21 and the protective layer 12. way flow.

另外,半导体激光装置60中,发光点的正下方即从发光点在厚度方向Z上向着安装部62的部分及其附近,未与焊锡层61合金化,由此该部分中的热放出(heat release)降低。半导体激光装置60中,脊形结构部35的侧面部与焊锡层61之间形成有微小的空腔,而脊形结构部35的顶部与焊锡层61密接,由此该部分中没有形成空腔。在此所谓脊形结构部35的顶部是指脊形结构部35中的层积在脊形部7的厚度方向Z的一表面7a中的部分。另外,脊形结构部35的侧面部是脊形结构部35中的除上述脊形结构部35的端部外剩下的部分。脊形结构部35的顶部(脊形波导的正下部)即使不与焊锡材料合金化,由于存在焊锡层61,也就会有介由焊锡层61从不完全粘合层31到安装部62的热传导。但是,仅利用来自脊形结构部35的顶部的放热是不足的,因此通过加厚由Au构成的电镀电极层27的厚度,就能够使脊形结构部35的发热从由高热传导率的金(Au)形成的电镀电极层27向台阶部8传递,由此谋求热传导路径的旁路化(by—pass),而介由焊锡层61释放到安装部62中。由此,能够消除不完全粘合层61与焊锡层61之间的热放出不足,从而进一步提高电流特性。In addition, in the semiconductor laser device 60, the portion immediately below the luminous point, that is, the portion from the luminous point toward the mounting portion 62 in the thickness direction Z and its vicinity is not alloyed with the solder layer 61, and heat in this portion is released (heat release) is lowered. In the semiconductor laser device 60, a small cavity is formed between the side surface of the ridge structure 35 and the solder layer 61, and the top of the ridge structure 35 is in close contact with the solder layer 61, so no cavity is formed in this portion. . Here, the top of the ridge structure portion 35 refers to a portion of the ridge structure portion 35 that is stacked on one surface 7 a in the thickness direction Z of the ridge portion 7 . In addition, the side surface of the ridge structure part 35 is the remaining part of the ridge structure part 35 except the end part of the above-mentioned ridge structure part 35 . Even if the top of the ridge structure part 35 (right below the ridge waveguide) is not alloyed with the solder material, due to the presence of the solder layer 61, there will be a gap from the incomplete adhesion layer 31 to the mounting part 62 via the solder layer 61. Heat Conduction. However, it is not enough to utilize only the heat radiation from the top of the ridge structure portion 35, so by increasing the thickness of the plating electrode layer 27 made of Au, it is possible to reduce the heat generation of the ridge structure portion 35 from the high thermal conductivity. The plated electrode layer 27 formed of gold (Au) transfers to the stepped portion 8 , thereby bypassing the thermal conduction path, and releasing it to the mounting portion 62 through the solder layer 61 . This eliminates insufficient heat release between the incomplete adhesion layer 61 and the solder layer 61 , thereby further improving current characteristics.

另外,在电镀电极层27的厚度不满0.5μm的情况下,就不能充分地实现传热效果,在超过5.0μm的情况下,当晶片上形成金属层时晶片就会翘曲从而使成品率恶化,并且形成电镀电极层27就使脊形结构部中产生应力,由此脊形波导变形。因而,将电镀电极层27的厚度设为0.5μm以上5.0μm以下,就可以不仅得到从脊形结构部35向完全粘合层33的充分热传导效果,并且能够降低赋予脊形结构部35的应力,从而提高成品率。In addition, when the thickness of the plating electrode layer 27 is less than 0.5 μm, the heat transfer effect cannot be fully realized, and if it exceeds 5.0 μm, the wafer will warp when the metal layer is formed on the wafer, thereby deteriorating the yield. , and forming the plating electrode layer 27 causes stress in the ridge structure portion, whereby the ridge waveguide deforms. Therefore, by setting the thickness of the plating electrode layer 27 to 0.5 μm or more and 5.0 μm or less, not only can a sufficient heat conduction effect be obtained from the ridge structure portion 35 to the complete adhesion layer 33, but also the stress applied to the ridge structure portion 35 can be reduced. , thereby increasing the yield.

在或使上述电镀电极层27与AuSn等焊锡材料反应来进行合金化,或在接近于脊形结构部35的部分中通过焊锡将半导体激光器件1安装到安装部62中时进行加热的情况下,激光特性就存在恶化之虞,但如前所述,通过设置不完全粘合层31与完全粘合层33,而使不完全粘合层31与焊锡材料不反应,也就是能够防止电镀电极层27的合金化而能保护电镀电极层27,并且能介由焊锡使所赋予的热从脊形部7离去,由此能够良好地维持激光特性。In the case where the plating electrode layer 27 is reacted with a solder material such as AuSn for alloying, or when the semiconductor laser device 1 is mounted in the mounting portion 62 by soldering in a portion close to the ridge structure portion 35, heating is performed. , the laser characteristics may be deteriorated, but as mentioned above, by setting the incomplete adhesion layer 31 and the complete adhesion layer 33, the incomplete adhesion layer 31 does not react with the solder material, that is, it is possible to prevent the electrode from being plated. The alloying of the layer 27 protects the plating electrode layer 27 and removes the heat applied from the ridge portion 7 through the solder, thereby maintaining good laser characteristics.

本发明的实施方式中,使用Mo作为形成不完全粘合层31的材料,但是作为形成不完全粘合层31的材料,只要在上述的小片接合条件下使用与形成焊锡材料的金属不形成合金的材料即可。In the embodiment of the present invention, Mo is used as the material for forming the incomplete adhesion layer 31, but as the material for forming the incomplete adhesion layer 31, it is used as long as it does not form an alloy with the metal forming the solder material under the above-mentioned die bonding conditions. materials.

进而,本发明的另一实施方式中,也可以在上述实施方式中,使不完全粘合层31由以下金属形成,即该金属与形成完全粘合层33的金属相比其与焊锡材料的湿润性较低。这样的金属材料例如可以列举出铂(Pt)。Furthermore, in another embodiment of the present invention, in the above-mentioned embodiment, the incomplete adhesion layer 31 may be formed of a metal that has an Wetting is low. Such a metal material includes, for example, platinum (Pt).

上述不完全粘合层31由铂(Pt)形成的半导体激光装置(以下有时也称作实施例2的半导体激光装置)的偏振特性如表2所示。制造条件与上述实施例1的半导体激光装置一样,只是替换了形成不完全粘合层31的材料。Table 2 shows the polarization characteristics of the semiconductor laser device in which the incomplete adhesive layer 31 is formed of platinum (Pt) (hereinafter sometimes referred to as the semiconductor laser device of Example 2). The manufacturing conditions were the same as those of the semiconductor laser device of Embodiment 1 above, except that the material forming the incomplete adhesion layer 31 was replaced.

【表1】【Table 1】

  偏振特性 实施例2 Polarization characteristics Example 2

  偏振比(Ave) 235 偏振比(σ) 86 偏振角(Ave) —1.4 偏振角(σ) 1.4 Polarization ratio (Ave) 235 Polarization ratio (σ) 86 Polarization angle (Ave) —1.4 Polarization angle (σ) 1.4

实施例2的半导体激光装置,虽然效果不如不完全粘合层31由Mo形成的实施例1的半导体激光装置,但与比较例的半导体激光器件相比,就可判明获得了显著的效果。因而,作为形成不完全粘合层31的材料,可以认为Pt是有效的金属。Although the semiconductor laser device of Example 2 is not as effective as the semiconductor laser device of Example 1 in which the incomplete adhesive layer 31 is formed of Mo, it is found that a remarkable effect is obtained compared with the semiconductor laser device of Comparative Example. Therefore, Pt is considered to be an effective metal as a material for forming the incomplete adhesion layer 31 .

短时间激烈发生合金反应的金属即短时间进行反应形成合金的金属,可对半导体激光器件的偏振特性带来坏影响,但是可推定慢慢发生合金反应的金属即难于在短时间内合金化的金属、或不产生合金反应的金属即不发生反应形成合金的金属,对激光的偏振特性不赋予或难以赋予坏影响。因而,不完全粘合层31通过慢慢发生合金反应的金属或不会发生合金反应的金属形成,这样的金属除上述Mo与Pt外,还能够列举出Ti等。这些Mo、Pt、Ti熔点比Au高,并且与焊锡材料AuSn之间的湿润性比Au低。A metal that undergoes a rapid alloying reaction in a short time, that is, a metal that reacts to form an alloy in a short time, may have a bad influence on the polarization characteristics of a semiconductor laser device, but it is presumed that a metal that undergoes a slow alloying reaction is difficult to alloy in a short time Metals, or metals that do not undergo an alloy reaction, that is, metals that do not react to form an alloy, do not or hardly exert a bad influence on the polarization characteristics of laser light. Therefore, the incomplete adhesion layer 31 is formed of a metal that slowly undergoes an alloy reaction or a metal that does not undergo an alloy reaction, and such metals include Ti and the like in addition to the aforementioned Mo and Pt. These Mo, Pt, and Ti have higher melting points than Au, and have lower wettability with solder material AuSn than Au.

图7是本发明的另一实施方式的半导体激光器件100的剖面图,图8是半导体激光器件100的俯视图。图7是从图8的剖面线VII—VII观察到的剖面图。还有,图8表示从半导体基板2的厚度方向Z中的设有脊形结构部35一侧观察,图中为了使第1与第2不完全粘合层31a、31b易于图解,而标注斜线进行表示。7 is a cross-sectional view of a semiconductor laser device 100 according to another embodiment of the present invention, and FIG. 8 is a plan view of the semiconductor laser device 100 . Fig. 7 is a cross-sectional view taken along line VII-VII of Fig. 8 . In addition, FIG. 8 shows a view from the side where the ridge structure portion 35 is provided in the thickness direction Z of the semiconductor substrate 2. In the figure, in order to facilitate the illustration of the first and second incomplete adhesion layers 31a, 31b, oblique labels are marked. line to represent.

半导体激光器件100,在图1所示的上述实施方式的半导体激光器件1中,上述不完全粘合层31由第1不完全粘合层31a与第2不完全粘合层31b构成,其他结构与半导体激光器件1相同,由此对同样的部分赋予相同的参考符号,并省略重复说明。In the semiconductor laser device 100, in the semiconductor laser device 1 of the above-mentioned embodiment shown in FIG. It is the same as the semiconductor laser device 1, and thus the same reference numerals are given to the same parts, and repeated explanations are omitted.

半导体激光器件100中,在上述半导体激光器件1中的金属层32与完全粘合层33之间,形成有包括第2不完全粘合层31b的中间金属层102。中间金属层102层积在金属层32的厚度方向Z的一表面32a上。中间金属层102按照在宽度方向Y上从由脊形结构部35离开预定距离L8的位置遍布到宽度方向Y的端部的方式层积在金属层32上。预定距离L8选择为预定距离L2的30%以上而不满50%。In the semiconductor laser device 100, the intermediate metal layer 102 including the second incomplete adhesion layer 31b is formed between the metal layer 32 and the perfect adhesion layer 33 in the semiconductor laser device 1 described above. The intermediate metal layer 102 is stacked on one surface 32 a of the metal layer 32 in the thickness direction Z. The intermediate metal layer 102 is stacked on the metal layer 32 so as to extend from a position separated by a predetermined distance L8 from the ridge structure portion 35 in the width direction Y to an end in the width direction Y. The predetermined distance L8 is selected to be greater than or equal to 30% and less than 50% of the predetermined distance L2.

在中间金属层102的厚度方向Z的一表面102a上层积有完全粘合层33。完全粘合层33按照从由脊形结构部35离开预定距离L5的位置遍布到宽度方向Y的端部的方式,层积在中间金属层102上。On one surface 102 a of the intermediate metal layer 102 in the thickness direction Z, a complete adhesion layer 33 is laminated. The complete adhesion layer 33 is laminated on the intermediate metal layer 102 so as to extend from a position separated by a predetermined distance L5 from the ridge structure portion 35 to the end in the width direction Y.

金属层32中的从中间金属层102露出来的部分构成第1不完全粘合层31a,中间金属层102中的从完全粘合层33露出来的部分构成第2不完全粘合层31b。半导体激光器件1在安装部62中安装时面临焊锡层61的最表面部中,在宽度方向Y上中央形成有第1不完全粘合层31a,第1不完全粘合层31a的两侧分别形成有第2不完全粘合层31b。The portion of the metal layer 32 exposed from the intermediate metal layer 102 constitutes the first incomplete adhesion layer 31a, and the portion of the intermediate metal layer 102 exposed from the complete adhesion layer 33 constitutes the second incomplete adhesion layer 31b. In the outermost portion facing the solder layer 61 when the semiconductor laser device 1 is mounted in the mounting portion 62, a first incomplete adhesion layer 31a is formed in the center in the width direction Y, and both sides of the first incomplete adhesion layer 31a are respectively The second incomplete adhesion layer 31b is formed.

中间金属层102由以下金属形成,该金属与形成焊锡层61的焊锡材料的湿润性具有上述金属层32和完全粘合层33之间的性质,也就是,比形成金属层32的金属要好即与焊锡材料易于湿润,并且比形成完全粘合层33的金属要差即与焊锡材料难于湿润。本实施方式中,金属层32由Mo形成,完全粘合层33由Au形成,由此中间金属层102例如由铂(Pt)形成。形成中间金属层102的金属,熔点比形成金属层32的金属的低并且比形成完全粘合层33的金属的高。The intermediate metal layer 102 is formed of a metal whose wettability with the solder material forming the solder layer 61 has properties between the above-mentioned metal layer 32 and the complete adhesion layer 33, that is, better than the metal forming the metal layer 32. It is easy to wet with solder material, and is poorer than the metal forming the fully bonded layer 33, that is, difficult to wet with solder material. In the present embodiment, the metal layer 32 is formed of Mo, and the complete bonding layer 33 is formed of Au, whereby the intermediate metal layer 102 is formed of, for example, platinum (Pt). The metal forming the intermediate metal layer 102 has a melting point lower than that of the metal forming the metal layer 32 and higher than that of the metal forming the complete adhesion layer 33 .

中间金属层102通过蒸镀来形成,其厚度例如选择为100

Figure C200610142108D0014191009QIETU
~3000
Figure C200610142108D0014191009QIETU
。The intermediate metal layer 102 is formed by vapor deposition, and its thickness is selected as 100
Figure C200610142108D0014191009QIETU
~3000
Figure C200610142108D0014191009QIETU
.

第1及第2不完全粘合层31a、31b,在脊形部7的延伸方向X上,以遍及到半导体激光器件100的两端部间的方式形成,由此以从半导体激光器件100的两端面即出射面隔开预定距离L6的方式形成。上述预定距离L6,选择为可在半导体激光器件100的出射面中形成用于防止出射端面损坏的涂布膜。。The first and second incomplete adhesive layers 31a, 31b are formed so as to extend between both ends of the semiconductor laser device 100 in the extending direction X of the ridge portion 7, whereby Both end faces, that is, the emitting faces are formed so as to be separated by a predetermined distance L6. The aforementioned predetermined distance L6 is selected so that a coating film for preventing damage to the exit end face can be formed on the exit surface of the semiconductor laser device 100 . .

图9是表示介由焊锡层61在安装部62中安装了半导体激光器件100的半导体激光装置160的剖面图。半导体激光器件100,通过上述的小片接合条件介由由AuSn构成的焊锡层61与安装部62接合。完全粘合层33与焊锡材料合金化,另外第2不完全粘合层31b的一部分也与焊锡材料合金化,但是第2不完全粘合层31b,由与形成焊锡层61的焊锡材料之间的湿润性具有第1不完全粘合层31a与完全粘合层33之间的性质的金属形成,因此第2不完全粘合层31b与焊锡层61间的粘合力,大于第1不完全粘合层31a与焊锡层61间的粘合力,小于完全粘合层33与焊锡层61间的粘合力。9 is a cross-sectional view showing a semiconductor laser device 160 in which a semiconductor laser device 100 is mounted on a mounting portion 62 via a solder layer 61 . The semiconductor laser device 100 is bonded to the mounting portion 62 via the solder layer 61 made of AuSn under the above-mentioned die bonding conditions. The complete adhesive layer 33 is alloyed with the solder material, and part of the second incomplete adhesive layer 31b is also alloyed with the solder material, but the second incomplete adhesive layer 31b is formed between the solder material forming the solder layer 61. Wettability has the property between the first incomplete adhesion layer 31a and the complete adhesion layer 33, so the adhesion force between the second incomplete adhesion layer 31b and the solder layer 61 is greater than that of the first incomplete adhesion layer 31b. The adhesive force between the adhesive layer 31 a and the solder layer 61 is smaller than the adhesive force between the complete adhesive layer 33 and the solder layer 61 .

由此,随着宽度方向Y上离开脊形结构部35,层积有焊锡层61的最表面部与焊锡层61间的粘合力就增大。通过随着宽度方向Y上离开脊形结构部35而使粘合力逐步地变化,从而能够抑制由完全粘合层33中所产生的应力与不完全粘合层31a、31b中所产生的应力引起的完全粘合层33与不完全粘合层31a、31b相邻的部分中的急剧应力变化,由此缓和赋予脊形结构部35的应力,并进一步降低脊形结构部35中产生的变形。Accordingly, the adhesive force between the uppermost surface portion on which the solder layer 61 is laminated and the solder layer 61 increases as the distance from the ridge structure portion 35 in the width direction Y increases. By gradually changing the adhesive force as the distance from the ridge structure portion 35 in the width direction Y, the stress generated in the fully bonded layer 33 and the stress generated in the incompletely bonded layers 31a, 31b can be suppressed. The induced sudden stress change in the portion of the complete adhesive layer 33 adjacent to the incomplete adhesive layers 31a, 31b thereby relaxes the stress applied to the ridge structure portion 35 and further reduces the deformation generated in the ridge structure portion 35 .

另外,形成Mo、Pt以及Au的成膜技术以前就一直在使用,因此通过第1不完全粘合层31a由钼(Mo)形成,第2不完全粘合层31b由铂(Pt)形成,完全粘合层33由金(Au)形成,来形成第1与第2不完全粘合层31a、31b以及完全粘合层33,就不需新的成膜技术,由此能够简单地进行形成。In addition, since the film-forming technology of forming Mo, Pt, and Au has been used until now, the first incomplete adhesion layer 31a is formed of molybdenum (Mo), and the second incomplete adhesion layer 31b is formed of platinum (Pt). The complete adhesion layer 33 is formed of gold (Au) to form the first and second partial adhesion layers 31a, 31b and the complete adhesion layer 33, so that a new film forming technique is not required, and thus it can be easily formed. .

图10是本发明的另一实施方式的半导体激光器件110的剖面图。本实施方式的半导体激光器件110,具有与上述图1所示的实施方式的半导体激光器件1相同的构成,只是电镀电极层27的结构不同,因此对同样的构成标注相同的参考符号,并省略重复说明。FIG. 10 is a cross-sectional view of a semiconductor laser device 110 according to another embodiment of the present invention. The semiconductor laser device 110 of this embodiment has the same structure as the semiconductor laser device 1 of the embodiment shown in FIG. Repeat instructions.

半导体激光器件110具有:半导体基板2、第1镀层3、有源层4、第2镀层5、蚀刻停止层6、脊形部7、台阶部8、第1及第2电介质层17、18、电镀用基底电极层23、基底金属层112、包括不完全粘合层31的金属层32、以及完全粘合层33。The semiconductor laser device 110 has: a semiconductor substrate 2, a first plating layer 3, an active layer 4, a second plating layer 5, an etching stop layer 6, a ridge portion 7, a step portion 8, the first and second dielectric layers 17, 18, Base electrode layer 23 for plating, base metal layer 112 , metal layer 32 including imperfect adhesion layer 31 , and perfect adhesion layer 33 .

基底金属层112具有电镀电极层113、第1电极层114、以及第2电极层115。基底金属层112以顺次层积电镀电极层113、第1电极层114、第2电极层115的方式形成。基底金属层112的厚度选择为0.5μm以上且不满5.0μm。The base metal layer 112 has a plating electrode layer 113 , a first electrode layer 114 , and a second electrode layer 115 . The base metal layer 112 is formed by sequentially stacking the plating electrode layer 113 , the first electrode layer 114 , and the second electrode layer 115 . The thickness of the base metal layer 112 is selected to be greater than or equal to 0.5 μm and less than 5.0 μm.

电镀电极层113与上述电镀电极层27结构相同并通过同样的方法形成。在电镀用基底电极层23的厚度方向Z的一表面23a上以遍布全表面的方式层积电镀电极层113。电镀电极层113的厚度选择为0.5μm以上且不满5.0μm,例如选择为1μm。The plating electrode layer 113 has the same structure as the above-mentioned plating electrode layer 27 and is formed by the same method. The plating electrode layer 113 is laminated on the one surface 23 a in the thickness direction Z of the plating base electrode layer 23 so as to cover the entire surface. The thickness of the plating electrode layer 113 is selected to be greater than or equal to 0.5 μm and less than 5.0 μm, for example, 1 μm.

在电镀电极层113的厚度方向Z的一表面113a上以遍布全表面的方式形成第1电极层114。第1电极层114与电镀电极层113相比表面平坦性出色,并通过预定金属形成。预定金属从由钼(Mo)、铂(Pt)、钼铂(MoPt)以及钛(Ti)构成的组中选择。通过这些金属形成第1电极层114,能就够形成表面平坦性优异的第1电极层114。在第1电极层114例如由钼(Mo)形成的情况下,其厚度选择为0.05μm以上且不满0.30μm,例如选择0.05μm。第1电极层114通过溅射法形成。The first electrode layer 114 is formed over the entire surface on one surface 113 a of the plating electrode layer 113 in the thickness direction Z. The first electrode layer 114 has an excellent surface flatness compared with the plating electrode layer 113 and is formed of a predetermined metal. The predetermined metal is selected from the group consisting of molybdenum (Mo), platinum (Pt), molybdenum platinum (MoPt), and titanium (Ti). By forming the first electrode layer 114 with these metals, the first electrode layer 114 having excellent surface flatness can be formed. When the first electrode layer 114 is formed of, for example, molybdenum (Mo), its thickness is selected to be not less than 0.05 μm and less than 0.30 μm, for example, 0.05 μm. The first electrode layer 114 is formed by sputtering.

在第1电极层114的厚度方向Z的一表面114a上,以遍布全表面的方式形成第2电极层115。第2电极层115由金形成。第2电极层115的厚度选择为0.05μm以上且不满1.0μm,例如选择0.12μm。在第2电极层115的厚度方向Z的一表面115a上,以遍布全表面的方式层积包括不完全粘合层31的金属层32。通过由金形成第2电极层115,能够提高基底金属层112与不完全粘合层31的粘合特性,由此使其难于剥离。另外,第2电极层115与第1电极层114同样地通过溅射法形成后,就连续地进行成膜。第2电极层115与第1电极层114,在将晶片设置在1个溅射装置中的状态下,以连续地使Mo膜与Au膜成膜的方式形成。以前,需要在使Mo膜成膜后,将晶片从装置中取出并将晶片再次放置在其他装置中来使Au膜成膜,但在本实施方式中,在不将晶片从装置中取出的情况下,将两个试料(Mo与Au)配置在装置内,按顺序使Mo膜(第1电极层114)与Au膜(第2电极层115)成膜。由此,不需要破坏真空,即不需要将晶片暂时暴露在大气中,就能够连续地使第2电极层115与第1电极层114成膜。由此,由Mo构成的第1电极层114的表面不被氧化,从而不存在损害与由层积的Au构成的第2电极层115的密接性之虞。On one surface 114a of the first electrode layer 114 in the thickness direction Z, the second electrode layer 115 is formed over the entire surface. The second electrode layer 115 is formed of gold. The thickness of the second electrode layer 115 is selected to be 0.05 μm or more and less than 1.0 μm, for example, 0.12 μm. On one surface 115 a in the thickness direction Z of the second electrode layer 115 , the metal layer 32 including the incomplete adhesion layer 31 is laminated over the entire surface. By forming the second electrode layer 115 from gold, the adhesion property between the base metal layer 112 and the incomplete adhesion layer 31 can be improved, thereby making it difficult to peel off. In addition, after the second electrode layer 115 is formed by the sputtering method similarly to the first electrode layer 114, it is formed into a film continuously. The second electrode layer 115 and the first electrode layer 114 are formed by successively forming a Mo film and an Au film in a state where the wafer is placed in one sputtering apparatus. Conventionally, after forming the Mo film, it was necessary to remove the wafer from the device and place the wafer again in another device to form the Au film. However, in this embodiment, when the wafer is not removed from the device, Next, two samples (Mo and Au) were placed in the apparatus, and a Mo film (first electrode layer 114) and an Au film (second electrode layer 115) were formed in this order. Accordingly, the second electrode layer 115 and the first electrode layer 114 can be continuously formed into films without breaking the vacuum, that is, without temporarily exposing the wafer to the atmosphere. Thereby, the surface of the first electrode layer 114 made of Mo is not oxidized, and there is no possibility of impairing the adhesion with the second electrode layer 115 made of laminated Au.

电镀电极层113、第1电极层114、第2电极层115的厚度,优选其比率为:电镀电极层113(Au)为1μm,第1电极层114(Mo)为0.05μm,第2电极层115(Au)为0.12μm。The thicknesses of the electroplating electrode layer 113, the first electrode layer 114, and the second electrode layer 115 are preferably 1 μm for the electroplating electrode layer 113 (Au), 0.05 μm for the first electrode layer 114 (Mo), and 0.05 μm for the second electrode layer. 115 (Au) is 0.12 μm.

由金构成的电镀电极层113通过电镀形成,因此与通过溅射法形成由金构成的层相比,就能够以短时间形成厚度较大的层。但是,电镀电极层113表面平坦性较差,湿润性随电镀条件变化,因此存在粘合特性中产生离散偏差之虞。根据本发明,在该电镀电极层113上顺次层积第1电极层114与第2电极层115。第1电极层114与上述电镀电极层113相比表面平坦性优异,通过预定的金属形成。由此,能够提高第2电极层115的表面平坦性。因而,能够提高与层积在第2电极层115上的不完全粘合层31间的粘合特性,由此可抑制基底金属层112与不完全粘合层31产生剥离。Since the plating electrode layer 113 made of gold is formed by electroplating, it is possible to form a thicker layer in a shorter time than forming a layer made of gold by a sputtering method. However, the surface flatness of the plating electrode layer 113 is poor, and the wettability varies with plating conditions, so there is a possibility of discrete variations in adhesion characteristics. According to the present invention, the first electrode layer 114 and the second electrode layer 115 are sequentially laminated on the plating electrode layer 113 . The first electrode layer 114 has an excellent surface flatness compared with the above-mentioned plating electrode layer 113 and is formed of a predetermined metal. Thereby, the surface flatness of the second electrode layer 115 can be improved. Therefore, the adhesion property with the incomplete adhesion layer 31 laminated on the second electrode layer 115 can be improved, thereby suppressing the peeling between the base metal layer 112 and the incomplete adhesion layer 31 .

半导体激光器件110与上述半导体激光器件100同样地介由焊锡层61安装在安装部62中,由此制作出半导体激光装置。本实施方式的半导体激光器件110中,可抑制基底金属层112与不完全粘合层31产生剥离,因此脊形结构部35中产生的热,能够介由以包括高热传导率的金(Au)的方式形成的基底金属层112传导到完全粘合层33侧,从而能够介由焊锡层61可靠地释放到安装部62中。由此,能够解决不完全粘合层31与焊锡层61间的放热不足,从而进一步抑制电流特性的恶化来谋求半导体激光器件110的长寿化。The semiconductor laser device 110 is mounted in the mounting portion 62 via the solder layer 61 in the same manner as the semiconductor laser device 100 described above, whereby a semiconductor laser device is fabricated. In the semiconductor laser device 110 of the present embodiment, peeling of the base metal layer 112 and the incomplete adhesion layer 31 can be suppressed, so the heat generated in the ridge structure portion 35 can be mediated by gold (Au) containing high thermal conductivity. The base metal layer 112 formed in such a manner conducts to the side of the complete adhesion layer 33 so that it can be reliably released into the mounting portion 62 via the solder layer 61 . Thereby, the lack of heat dissipation between the incomplete adhesion layer 31 and the solder layer 61 can be solved, and the deterioration of the current characteristics can be further suppressed to achieve a longer life of the semiconductor laser device 110 .

另外,第1与第2电极层114、115通过溅射法以连续成膜方式形成,由此能够提高与电镀电极层113的密接性,进而即使电镀电极层113的表面113a中存在凹凸,而以填补该凹凸部分的方式形成第1与第2电极层114、115,因此能够使基底金属层112的厚度尽可能均匀。通过使基底电极层112的厚度更加均匀,可以获得更加稳定的接合性及提高粘合性,其效果,能够消除放热不足,由此进一步抑制电流特性的恶化来谋求半导体激光器件的长寿化。In addition, the first and second electrode layers 114, 115 are formed in a continuous film-forming manner by sputtering, thereby improving the adhesion to the plating electrode layer 113, and even if there are irregularities in the surface 113a of the plating electrode layer 113, Since the first and second electrode layers 114 and 115 are formed to fill up the unevenness, the thickness of the base metal layer 112 can be made as uniform as possible. By making the thickness of the base electrode layer 112 more uniform, more stable bonding and improved adhesion can be obtained. As a result, insufficient heat dissipation can be eliminated, thereby further suppressing deterioration of current characteristics and prolonging the life of the semiconductor laser device.

图11是本发明的另一实施方式的半导体激光器件120的剖面图。本实施方式的半导体激光器件120,具有与前述的图7所示的实施方式的半导体激光器件100相同的构造,将半导体激光器件100的电镀电极层27替换为上述图10所示的实施方式中的基底电极层112。通过采用这样的构成,除上述半导体激光器件100的效果外,还可以谋求与半导体激光器件120相同的效果。FIG. 11 is a cross-sectional view of a semiconductor laser device 120 according to another embodiment of the present invention. The semiconductor laser device 120 of this embodiment has the same structure as the semiconductor laser device 100 of the embodiment shown in FIG. base electrode layer 112. By employing such a configuration, in addition to the effects of the semiconductor laser device 100 described above, the same effects as those of the semiconductor laser device 120 can be obtained.

本发明的另一实施方式的半导体激光器件中,也可以在上述各实施方式的半导体激光器件中,在不设置蚀刻停止层6的情况下,将第2镀层5、脊形部7以及台阶部12通过相同的半导体材料即例如形成前述的第2与第3镀层5、11的半导体材料以一体化方式形成,并形成层积在有源层4的厚度方向Z的一表面4a中的镀层。采用这样的构成,就使来自外部的应力易于赋予脊形波导,但即使是这样的构成,由于通过上述不完全粘合层31来缓和应力,因此也能够实现与上述实施方式相同的效果,进而由于外延生长的工序减少,从而能够缩短制造时间,由此提高生产性。In the semiconductor laser device of another embodiment of the present invention, in the semiconductor laser device of each of the above-mentioned embodiments, the second plating layer 5, the ridge portion 7, and the step portion may be formed without the etching stop layer 6. 12 is integrally formed by the same semiconductor material, that is, the semiconductor material for forming the aforementioned second and third plating layers 5, 11, and forms a plating layer stacked on one surface 4a of the active layer 4 in the thickness direction Z. With such a configuration, stress from the outside is easily applied to the ridge waveguide, but even with such a configuration, since the stress is relieved by the above-mentioned incomplete adhesive layer 31, the same effect as that of the above-mentioned embodiment can be achieved. Since the number of epitaxial growth steps is reduced, the manufacturing time can be shortened, thereby improving productivity.

本发明还可以在不超越其主要精神或主要特征的情况下,以其他各种各样的方式进行。因此,上述实施方式以其所有方面仅仅是例示,本发明的范围通过权利要求的范围来表示,一点也不受说明书本文的限定。进而,属于权利要求的范围的变形及变更均包括在本发明的范围内。The present invention can also be carried out in other various forms without departing from its main spirit or main characteristics. Therefore, the above-mentioned embodiment is merely an illustration in all points, and the scope of the present invention is shown by the scope of the claim, and is not limited at all by this specification. Furthermore, modifications and changes belonging to the scope of the claims are included in the scope of the present invention.

Claims (12)

1. a semiconductor laser device (1,100,110,120) has the ridge structure portion (35) of the ridge waveguide that is arranged on the striated on the semiconductor substrate (2), it is characterized in that:
This semiconductor laser device is situated between bonding by soldering-tin layer (61) and installation portion (62),
Comprise:
Incomplete adhesive layer (31), it has electrical conductance, be positioned at surface portion than the semiconductor laser device in the more close outside of above-mentioned ridge waveguide, not exclusively adhesive layer (31) is gone up lamination above-mentioned soldering-tin layer (61), not exclusively adhesive layer (31) is gone up in above-mentioned ridge structure portion (35) at least and is formed, and not exclusively bonding with above-mentioned soldering-tin layer (61); And
Complete adhesive layer (33), it has electrical conductance, and be positioned at surface portion than the semiconductor laser device in the more close outside of above-mentioned ridge waveguide, adhesive layer (33) is gone up lamination fully above-mentioned soldering-tin layer (61), fully adhesive layer (33) is on the direction vertical with the bearing of trend of the thickness direction of above-mentioned semiconductor substrate (2) and above-mentioned ridge waveguide, form in the both sides of above-mentioned incomplete adhesive layer (31) respectively, and bonding with above-mentioned soldering-tin layer (61)
Above-mentioned incomplete adhesive layer (31) comprising:
The 1st incomplete adhesive layer (31a), it forms in the central authorities of semiconductor laser device on the direction vertical with the bearing of trend of the thickness direction of above-mentioned semiconductor substrate (2) and above-mentioned ridge waveguide; And
The 2nd incomplete adhesive layer (31b), it is on the direction vertical with the bearing of trend of the thickness direction of above-mentioned semiconductor substrate (2) and above-mentioned ridge waveguide, form in the both sides of the above-mentioned the 1st incomplete adhesive layer (31a) respectively, and and form wettability between the soldering tin material of above-mentioned soldering-tin layer (61) and be positioned among the wettability and the wettability between the soldering tin material above-mentioned complete adhesive layer (33) and the above-mentioned soldering-tin layer of formation (61) between the soldering tin material the above-mentioned the 1st incomplete adhesive layer (31a) and that form above-mentioned soldering-tin layer (61).
2. semiconductor laser device as claimed in claim 1 (100) is characterized in that:
The above-mentioned the 1st incomplete adhesive layer (31a) is formed by molybdenum;
The above-mentioned the 2nd incomplete adhesive layer (31b) is formed by platinum;
Above-mentioned complete adhesive layer (33) is formed by gold.
3. semiconductor laser device as claimed in claim 1 (1,100,110,120) is characterized in that:
On the direction vertical with the bearing of trend of the thickness direction of above-mentioned semiconductor substrate (2) and above-mentioned ridge waveguide, both sides at above-mentioned ridge waveguide, forming stage portion (8), and between this stage portion (8) and ridge waveguide, form recess (15) from above-mentioned ridge waveguide mode spaced apart by a predetermined distance.
4. semiconductor laser device as claimed in claim 3 (1,100,110,120) is characterized in that:
Above-mentioned recess (15) deflection ridge waveguide place is formed with above-mentioned incomplete adhesive layer (31);
Above-mentioned recess (15) deflection stage portion place is formed with above-mentioned complete adhesive layer (33).
5. semiconductor laser device as claimed in claim 4 (1,100,110,120) is characterized in that:
Be formed on part in the above-mentioned recess (15) in the above-mentioned incomplete adhesive layer (31), form according to the mode that between ridge waveguide and stage portion (8), spreads all over prescribed limit from ridge waveguide, this prescribed limit be between ridge waveguide and the stage portion (8) distance more than 30% and discontented 50% scope.
6. semiconductor laser device as claimed in claim 4 (1,100,110,120) is characterized in that:
Be formed on part in the above-mentioned recess (15) in the above-mentioned complete adhesive layer (33), according to forming in the scope below 50% of the distance ridge waveguide and the stage portion (8) by stage portion (8) between ridge waveguide and the stage portion (8).
7. semiconductor laser device as claimed in claim 1 (1,100) is characterized in that:
Have substrate metal layer, it is formed by gold and lamination has above-mentioned complete adhesive layer (33) and above-mentioned incomplete adhesive layer (31).
8. semiconductor laser device as claimed in claim 1 (110,120) is characterized in that:
Having lamination has the substrate metal layer of above-mentioned complete adhesive layer (33) and above-mentioned incomplete adhesive layer (31);
Above-mentioned substrate metal layer is made of gold and the mode of the 2nd electrode layer (115) that forms by the 1st electrode layer (114) electroplating the electroplated electrode layer (113) that forms, formed by the metal of being scheduled to and by gold forms according to lamination in turn.
9. semiconductor laser device as claimed in claim 8 (110,120) is characterized in that:
Form the predetermined metal of above-mentioned the 1st electrode layer (114), from the group that constitutes by molybdenum, platinum, molybdenum platinum and titanium, select.
10. semiconductor laser device as claimed in claim 9 (110,120) is characterized in that:
The the above-mentioned the 1st and the 2nd electrode layer (114,115) forms in the continuous film forming mode by sputtering method.
11., it is characterized in that as claim 7 or 8 described semiconductor laser devices (1,100,110,120):
The thickness of above-mentioned substrate metal layer is chosen as the above and discontented 5.0 μ m of 0.5 μ m.
12., it is characterized in that having as claim 7 or 8 described semiconductor laser devices (1,100,110,120):
Metal layer on back, its with the mode of the above-mentioned semiconductor substrate of clamping (2) with the surface element of the above-mentioned semiconductor substrate (2) of above-mentioned ridge structure portion opposition side on form by gold.
CNB200610142108XA 2005-09-30 2006-09-30 semiconductor laser device Active CN100505446C (en)

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JP4967875B2 (en) * 2007-07-17 2012-07-04 三菱電機株式会社 Semiconductor light emitting device and manufacturing method thereof
CN102709627A (en) * 2012-06-25 2012-10-03 世达普(苏州)通信设备有限公司 Waveguide duplexer device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105229523A (en) * 2013-05-23 2016-01-06 富士通株式会社 Photosemiconductor integrated component and its manufacture method

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