CN100484905C - Method for preparing composite fertilizer by smelting solid material - Google Patents
Method for preparing composite fertilizer by smelting solid material Download PDFInfo
- Publication number
- CN100484905C CN100484905C CNB2006100268966A CN200610026896A CN100484905C CN 100484905 C CN100484905 C CN 100484905C CN B2006100268966 A CNB2006100268966 A CN B2006100268966A CN 200610026896 A CN200610026896 A CN 200610026896A CN 100484905 C CN100484905 C CN 100484905C
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- China
- Prior art keywords
- urea
- ammonium nitrate
- composite fertilizer
- solid material
- preparing composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000003337 fertilizer Substances 0.000 title claims abstract description 22
- 239000011343 solid material Substances 0.000 title claims abstract description 13
- 238000003723 Smelting Methods 0.000 title claims description 9
- 239000002131 composite material Substances 0.000 title claims description 9
- 239000004202 carbamide Substances 0.000 claims abstract description 22
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 19
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 3
- 239000010452 phosphate Substances 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 14
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 10
- 238000005516 engineering process Methods 0.000 claims description 8
- 210000003608 fece Anatomy 0.000 claims description 6
- 239000010871 livestock manure Substances 0.000 claims description 6
- 238000012216 screening Methods 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 208000006558 Dental Calculus Diseases 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 150000003672 ureas Chemical class 0.000 claims description 2
- 238000005469 granulation Methods 0.000 abstract description 12
- 230000003179 granulation Effects 0.000 abstract description 12
- 238000002844 melting Methods 0.000 abstract description 7
- 230000008018 melting Effects 0.000 abstract description 7
- 239000008187 granular material Substances 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 5
- 239000007921 spray Substances 0.000 abstract description 3
- 239000000155 melt Substances 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 6
- 230000004927 fusion Effects 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000007787 solid Substances 0.000 description 4
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 3
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 235000019837 monoammonium phosphate Nutrition 0.000 description 3
- 239000006012 monoammonium phosphate Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
本发明涉及固体物料熔融生产复合肥料的方法，该方法包括以下工艺：将粉碎至2.0毫米以下的基料与填充料混合，并将该基料与填充料预热升温后加入到熔融的尿素或硝铵溶液中，搅拌3～8分钟，生成熔体料浆，保持料浆温度为100～130℃，然后通过泵喷入到含有返料或者部分磷酸盐、钾盐的固体物料上，使其涂布成粒，成粒后的物料经筛分即得复合肥料成品，细粉或大颗粒再返回。与现有技术相比，本发明具有工艺简单、成本较低、有利于环境保护等特点。The invention relates to a method for producing compound fertilizers by melting solid materials, the method comprising the following steps: mixing base materials crushed to a size below 2.0 mm with fillers, preheating the base materials and fillers and adding them to molten urea or Stir in the ammonium nitrate solution for 3-8 minutes to generate a melt slurry, keep the temperature of the slurry at 100-130°C, and then spray it into the solid material containing the returned material or part of the phosphate and potassium salt through the pump to make it Coating and granulation, the granulated material is sieved to obtain the finished compound fertilizer, and the fine powder or large granules are returned. Compared with the prior art, the present invention has the characteristics of simple process, low cost, favorable environmental protection and the like.
Description
Technical field
The present invention relates to a kind of production of composite fertilizer, particularly relate to a kind of production method of smelting solid material drum granulating compound manure.
Background technology
The production method of existing compound manure mainly adopts slurry process, granulating method, high tower spraying process etc.Slurry process makes with high-concentration phosphoric acid and ammonia react mostly, be characterized in technology, equipment complexity, the production technology difficulty is big, and to drop into huge fund, plant condition harshness, construction period are long, also have part producing factory to spray on the solid objects with the urea fusing, because urea melts the fusing point height separately, if add water-solubleization, then easily cause fertilizer moisture content height, need drying.Melting method is to utilize urea (or ammonium nitrate) solution of urea (or ammonium nitrate) factory dual circulation (concentration is 〉=95%) and phosphorus ammonium and sylvite melting mixing, utilize the high tower spraying process to produce nitrogen-phosphorus-potassium compound fertilizer, fertiliser granulates rounding, intensity height that this method is produced, but exist the regulation range of product particle size narrow, material proportion has certain limitation, only be adapted to the production of the low-phosphorous proportioning of high nitrogen, and prilling tower must have certain height, investment cost is also big.Though granulating method is fairly simple, because granulation moisture content height, drying load is big, and easily sticking flight causes the tails dedusting difficulty.
Summary of the invention
The objective of the invention is the advantage of granulating method and high tower spraying process is put together, and the two shortcoming is overcome, form a kind of method of brand-new preparing composite fertilizer by smelting solid material, make the versatility of fertilizer ratio stronger, the outward appearance of product be improved significantly, and product prevented from caking.
Purpose of the present invention can be achieved through the following technical solutions: the method for preparing composite fertilizer by smelting solid material, it is characterized in that, this method comprises following technology: the base-material that will be crushed to below 2.0 millimeters mixes with stopping composition, and will join behind this base-material and the stopping composition pre-heating temperature elevation in fused urea or the ammonium nitrate solution, stirred 3～8 minutes, generate molten slurry, keeping slurry temperature is 100～130 ℃, be injected to by pump then and contain returning charge or portion phosphate, on the solid materials of sylvite, make its coating granulating, material behind the granulating promptly gets the compound manure finished product through screening, and fine powder or macrobead return again.
Described base-material comprises one or more in ammonium chloride, sulphur ammonium, phosphorus ammonium, Repone K or the vitriolate of tartar.
Described stopping composition comprises rhombspar, lime carbonate, clay.
Described base-material and stopping composition pre-heating temperature elevation to 70 ℃～100 ℃.
The concentration of described urea or ammonium nitrate solution is 90～99.7 weight %, and this urea or ammonium nitrate solution are that temperature is 110～140 ℃ a urea soln in urea or the ammonium nitrate production process, or urea or ammonium nitrate are heated to 110～150 ℃ slip.
Described coating granulating technology is carried out in rotary drum granulator.
Principle of work of the present invention is: urea or ammonium nitrate and potash fertilizer can form the eutectic compound; with the two fusion of putting together; melting temperature is low, and melting charge slurry is injected in the rotary drum granulator by pump, forms the product of the mellow and full light of outward appearance by coating in layer.
In the existing granulating method compound manure production process, all need to replenish steam or water, can't improve prilling temperature like this, thereby material needs drying, and drying needs high temperature, under the well wet condition of high temperature, material easily sticks on the inwall and scraper plate of moisture eliminator, makes material can not get drying.
Method of the present invention does not need make up water when the rotary drum coating granulation, thereby drying-free, need not to remove accordingly dust recovery system yet.
The present invention compared with prior art has following advantage:
1, the present invention adopts the granulation of rotary drum coating method, is not adding water or steam in the granulation process, prilling temperature height, balling ratio height.Got rid of very high drying of investment and process cost and dust-removal system, do not had a large amount of exhaust emissionss when producing simultaneously, good operational environment, the production technique of genus clean and environment-friendly.
2, equipment of the present invention have simple in structure, be easy to installation and maintenance, than advantages such as high tower prilling investment are low.
3, the product of the present invention's production has the outward appearance and the intensity of high tower prilling particle, prevented from caking.But got rid of easy blocking sprayer of high tower prilling and prescription and be difficult for the little shortcoming of adjusting process turndown ratio.
4, the present invention organically combines high tower sprinkling pelleting and traditional rotary drum compound fertilizer production technology, realizes fusion drum granulating production compound manure.
Embodiment
The invention will be further described below in conjunction with specific embodiment, but be not limitation of the present invention.
Embodiment 1
Get urea plant flash evaporator outlet urea melting or melt 380kg; concentration is greater than 99%; temperature is 135 ℃; join tempering tank that has steam coils and the monoammonium phosphate 225kg that is heated to 115 ℃ in advance; vitriolate of tartar 200kg and stopping composition rhombspar 220kg mix, and send into granulation in the rotary drum granulator then, and the material after the granulation is the high-concentration granular NpK complex fertilizer through the cooling screening; this product contains N 20 weight %, P
2O
515 weight %, K
2O10 weight %, moisture 0.5 weight %, the granule strength of product is greater than 25 newton/grains.
Embodiment 2
Get solid urea 600kg and add the melting channel fusing; 135 ℃ of temperature of fusion; add the monoammonium phosphate 200kg that is heated to 100 ℃ in advance then; Repone K 150kg and stopping composition stone flour 50kg mix; slip behind the mixing is injected to granulation in the rotary drum granulator with pump; material after the granulation promptly gets the high-concentration granular NpK complex fertilizer through the cooling screening, and this product contains N30 weight %, P
2O
5Weigh 10 amount %, K
2O 9 weight %, moisture 0.5 weight %, the granule strength of product is greater than 25 newton/grains.
Embodiment 3
Get the evaporator outlet ammonium nitrate melt 400kg of ammonium nitrate factory, concentration is greater than 95%, temperature is 120 ℃, add tempering tank and the monoammonium phosphate 300kg that is heated to 110 ℃ in advance, Repone K 250kg and stopping composition clay 50kg mix, and spray into pump in the returning charge of corresponding proportioning, and coating granulation is after the cooling screening promptly gets the high-concentration granular NpK complex fertilizer, this product contains N 15 weight %, P
2O
515 weight %, K
2O 15 weight %, moisture 1.5 weight %, the granule strength of product is greater than 30 newton/grains.
Embodiment 4
Get solid ammonium nitrate 300kg with 100kg Repone K heat fused; 105 ℃ of temperature of fusion are injected to this solution the diammonium phosphate 210kg that is heated to 80 ℃ in the rotary drum granulator and in advance, Repone K 100kg and wilkinite 300kg mixing granulation then; promptly get and contain N12 weight %, P
2O
510 weight %, K
2O 10 weight %, the middle concentration complex fertilizer product of moisture 2.5 weight %
Embodiment 5
Get solid urea 200kg with 100kg Repone K heat fused; 100 ℃ of temperature of fusion are injected to this solution the normal superphosphate 500kg that is heated to 70 ℃ in the rotary drum granulator and in advance, vitriolate of tartar 60kg, terra alba 140kg mixing granulation then; promptly get and contain N9 weight %, P
2O
57 weight %, K
2O 9 weight %, the lower concentration complex fertilizer product of moisture 2.5 weight %.
Claims (4)
1. the method for preparing composite fertilizer by smelting solid material, it is characterized in that, this method comprises following technology: the base-material that will be crushed to below 2.0 millimeters mixes with stopping composition, and will join behind this base-material and the stopping composition pre-heating temperature elevation in fused urea or the ammonium nitrate solution, stirred 3～8 minutes, generate molten slurry, keeping slurry temperature is 100～130 ℃, be injected on the solid materials that contains returning charge or portion phosphate, sylvite by pump then, make its coating granulating, material behind the granulating promptly gets the compound manure finished product through screening, and fine powder or macrobead return again;
Described base-material comprises one or more in ammonium chloride, sulphur ammonium, phosphorus ammonium, Repone K or the vitriolate of tartar;
Described stopping composition comprises rhombspar, lime carbonate, clay.
2. the method for preparing composite fertilizer by smelting solid material according to claim 1 is characterized in that, described base-material and stopping composition pre-heating temperature elevation to 70 ℃～and 100 ℃.
3. the method for preparing composite fertilizer by smelting solid material according to claim 1, it is characterized in that, the concentration of described urea or ammonium nitrate solution is 90～99.7 weight %, this urea or ammonium nitrate solution are that temperature is 110～140 ℃ a urea soln in urea or the ammonium nitrate production process, or urea or ammonium nitrate are heated to 110～150 ℃ slip.
4. the method for preparing composite fertilizer by smelting solid material according to claim 1 is characterized in that, described coating granulating technology is carried out in rotary drum granulator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100268966A CN100484905C (en) | 2006-05-25 | 2006-05-25 | Method for preparing composite fertilizer by smelting solid material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100268966A CN100484905C (en) | 2006-05-25 | 2006-05-25 | Method for preparing composite fertilizer by smelting solid material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101077841A CN101077841A (en) | 2007-11-28 |
| CN100484905C true CN100484905C (en) | 2009-05-06 |
Family
ID=38905533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100268966A Expired - Fee Related CN100484905C (en) | 2006-05-25 | 2006-05-25 | Method for preparing composite fertilizer by smelting solid material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100484905C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101633582A (en) * | 2008-07-25 | 2010-01-27 | 四川蓥峰实业有限公司 | Method for manufacturing formula compound fertilizer |
| CN103319238B (en) * | 2013-06-19 | 2014-07-23 | 菏泽金正大生态工程有限公司 | Water soluble fertilizer and preparation method thereof |
| CN111574268A (en) * | 2019-02-15 | 2020-08-25 | 王国芳 | Simple and easy new method for producing compound (mixed) fertilizer directly by urea device |
-
2006
- 2006-05-25 CN CNB2006100268966A patent/CN100484905C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101077841A (en) | 2007-11-28 |
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Granted publication date: 20090506 Termination date: 20160525 |