CN100464849C - A catalyst for producing propylene from propane dehydrogenation with alumina-modified mesoporous molecular sieve as carrier - Google Patents
A catalyst for producing propylene from propane dehydrogenation with alumina-modified mesoporous molecular sieve as carrier Download PDFInfo
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- CN100464849C CN100464849C CNB200710025372XA CN200710025372A CN100464849C CN 100464849 C CN100464849 C CN 100464849C CN B200710025372X A CNB200710025372X A CN B200710025372XA CN 200710025372 A CN200710025372 A CN 200710025372A CN 100464849 C CN100464849 C CN 100464849C
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- catalyst
- carrier
- molecular sieve
- mesoporous molecular
- alumina
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 239000003054 catalyst Substances 0.000 title claims abstract description 42
- 239000001294 propane Substances 0.000 title claims abstract description 29
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 17
- 239000002808 molecular sieve Substances 0.000 title claims abstract description 13
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000006356 dehydrogenation reaction Methods 0.000 title abstract description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 37
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 239000002184 metal Substances 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 229910002847 PtSn Inorganic materials 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 2
- FHMDYDAXYDRBGZ-UHFFFAOYSA-N platinum tin Chemical compound [Sn].[Pt] FHMDYDAXYDRBGZ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000003756 stirring Methods 0.000 description 6
- 238000006298 dechlorination reaction Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000001027 hydrothermal synthesis Methods 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 101000809257 Homo sapiens Ubiquitin carboxyl-terminal hydrolase 4 Proteins 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 102100038463 Ubiquitin carboxyl-terminal hydrolase 4 Human genes 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- WHFQAROQMWLMEY-UHFFFAOYSA-N propylene dimer Chemical group CC=C.CC=C WHFQAROQMWLMEY-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
一种用氧化铝改性的中孔分子筛为载体的丙烷脱氢制丙烯的催化剂，用Al2O3改性的中孔分子筛为载体，铂锡双金属催化剂，氧化铝的重量百分比含量为：5.0～30.0%。催化剂的活性组分为金属铂，铂的重量百分比含量为：0.4%，助剂Sn的重量百分比含量为：0.1～2.0%。A catalyst for producing propylene by propane dehydrogenation with alumina-modified mesoporous molecular sieve as carrier, with Al2O3 -modified mesoporous molecular sieve as carrier, platinum-tin bimetallic catalyst, the weight percent content of alumina is: 5.0-30.0%. The active component of the catalyst is metal platinum, the content of platinum is 0.4% by weight, and the content of Sn, an auxiliary agent, is 0.1-2.0% by weight.
Description
Technical field
The present invention relates to a kind of catalyst that is used for preparing propylene by dehydrogenating propane.
Background technology
Propylene except being used to produce the polypropylene, also is used to produce chemical products such as acrylonitrile, butanols, octanol, expoxy propane, isopropyl alcohol, isopropylbenzene, acrylic acid, oxo-alcohols and nonyl phenol as a kind of important Organic Chemicals in large quantities.Propylene is mainly derived from by-product or coproduction such as naphtha pyrolysis and oil plant FCC technology, growing along with the propylene demand, traditional production of propylene can not satisfy the demand growth of petrochemical iy produced to propylene, and special share of producing propylene propylene that technology is produced such as dehydrogenating propane technology will improve constantly.There is abundant petroleum and natural gas resource in China, and it is made up of 60% propane and 20% butane basically, and exploitation is produced low carbon olefin hydrocarbon by low-carbon alkanes can alleviate the not enough problem in propylene source, and to rationally utilizing C
3～C
4Alkane and to open up the new source of alkene significant.Propane catalytic dehydrogenation technology is representative with the Oleflex technology of Uop Inc. and the Catofin technology of U.S. Air Product company.
Load type platinum is catalyst based to be a class important in the alkane dehydrogenating catalyst, utilizes advanced technology to add various auxiliary agents and is prepared from, and production method is also open in the art.With platinum group is the catalyst such as the USP4 of main active component, 914,075, and USP 4,353,815, USP 4,420,649, USP 4,506, and 032, USP 4,595, and 673, EP 562,906, and EP 98,622, the catalyst based dehydrogenation that can be used for propane and other low-carbon alkanes of the Pt that relates to, above-mentioned catalyst has used Al without exception
2O
3Carrier as catalyst.Alexander etc. comprise platinum group metal and zinc on borosilicate and the alkali metal carrier at disclosed catalyst among the USP 6,103, and from the conversion ratio of alkane, the selectivity of alkene and the productive rate of alkene, this catalyst has excellent dehydrogenation.(the patent number of accepting: 200610086006.0) relate to a kind of is the catalyst for dehydrogenation of low-carbon paraffin of carrier with ZSM-5 to Chinese patent, and the stability and the alkane conversion of catalyst all are higher than with Al
2O
3Catalyst as carrier.With alumina modified mesoporous molecular sieve material is that the document of carrier loaded platinum tin bi-component alkane dehydrogenating catalyst does not appear in the newspapers.
Summary of the invention
The purpose of this invention is to provide a kind of catalyst that is used for dehydrogenating propane, this catalyst has higher conversion of propane and better dehydrogenation stability, has obvious social and economic benefit.
The invention is characterized in that the propane dehydrogenation catalyst that relates to is a carrier with the mesoporous molecular sieve that the surface is coated with aluminium oxide.With platinum as the activity of such catalysts component, with the auxiliary agent of Sn as catalyst.
Feature of the present invention also is, mesoporous molecular sieve SBA-15 or MCM-41 are wherein preferable with MCM-41.The weight percent content of each component in the catalyst, aluminium oxide: 5.0～30.0%, preferred 9.0～23.0%; Active metal component platinum: 0.4%; Auxiliary agent Sn:0.1～2.0%, preferred 0.2～1.2%.
Active component platinum in the catalyst and auxiliary agent Sn load on the carrier by the technology of soaking altogether.Carrier impregnation behind active component Pt and the auxiliary agent Sn, need be through super-dry, roasting and dechlorination are handled.The used roasting condition of this work is: 500 ℃, and air, 4h; The dechlorination condition: 500 ℃, (air+water vapour), 4h.
The specific embodiment
Enforcement below by dehydrogenating propane is described further technology of the present invention.
Embodiment 1:
By hydrothermal synthesis method, the MCM-41 mesopore material of preparation pure silicon.With ion-exchange with the Na among the baked MCM-41
+All be exchanged into H
+After dry, the calcination process, impregnated in the aluminum nitrate solution, stirring at room 1h, stir in 60 ℃ of oil baths and be evacuated to dried, 100 ℃ of dried overnight, 550 ℃ of roasting 10h.The weight percent content of aluminium oxide is in the sample that obtains: 9.1%.The carrier compressing tablet that will contain aluminium oxide, sieve (20～40 order) impregnated in chloroplatinic acid and SnCl
4Mixed solution in, be evacuated to dried.120 ℃ of oven dry 3h, roasting 4h in 500 ℃ of following air, 500 ℃ of steam dechlorination 4h then.Catalyst consists of: Pt 0.4%, and Sn 0.59%.The catalyst of making is through H
2Be used for the test of dehydrogenating propane reactivity worth after the prereduction.590 ℃ of reaction temperatures, pressure are 0.1MPa, propane mass space velocity 6h
-1, hydrogen/propane mol ratio is 1:4.During reaction 10h, the salic PtSn/Al of carrier of the present invention
2O
3The conversion of propane of/MCM-41 catalyst is 10%, propylene selectivity 88%.
Embodiment 2:
By hydrothermal synthesis method, the MCM-41 mesopore material of preparation pure silicon.With ion-exchange with the Na among the baked MCM-41
+All be exchanged into H
+After dry, the calcination process, impregnated in the aluminum nitrate solution, stirring at room 1h, stir in 60 ℃ of oil baths and be evacuated to dried, 100 ℃ of dried overnight, 550 ℃ of roasting 10h.The weight percent content of aluminium oxide is in the sample that obtains: 23.1%.The carrier compressing tablet that will contain aluminium oxide, sieve (20～40 order) impregnated in chloroplatinic acid and SnCl
4Mixed solution in, be evacuated to dried.120 ℃ of oven dry 3h, roasting 4h in 500 ℃ of following air, 500 ℃ of steam dechlorination 4h then.Catalyst consists of: Pt 0.4%, Sn0.59%.The catalyst of making is through H
2Be used for the test of dehydrogenating propane reactivity worth after the prereduction.590 ℃ of reaction temperatures, pressure are 0.1MPa, propane mass space velocity 6h
-1, hydrogen/propane mol ratio is 1:4.During reaction 10h, the salic PtSn/Al of carrier of the present invention
2O
3The conversion of propane of/MCM-41 catalyst can reach 17%, propylene selectivity 93%.
Embodiment 3:
By hydrothermal synthesis method, the SBA-15 mesopore material of preparation pure silicon.Baked SBA-15 be impregnated in the aluminum nitrate solution, stirring at room 1h, stir in 60 ℃ of oil baths and be evacuated to dried, 100 ℃ of dried overnight, 550 ℃ of roasting 10h.The weight percent content of aluminium oxide is in the sample that obtains: 23.1%.The carrier compressing tablet that will contain aluminium oxide, sieve (20～40 order) impregnated in chloroplatinic acid and SnCl
4Mixed solution in, be evacuated to dried.120 ℃ of oven dry 3h, roasting 4h in 500 ℃ of following air, 500 ℃ of steam dechlorination 4h then.Catalyst consists of: Pt 0.4%, and Sn 0.59%.The catalyst of making is through H
2Be used for the test of dehydrogenating propane reactivity worth after the prereduction.590 ℃ of reaction temperatures, pressure are 0.1MPa, propane mass space velocity 6h
-1, hydrogen/propane mol ratio is 1:4.During reaction 10h, the salic PtSn/Al of carrier of the present invention
2O
3The conversion of propane of/SBA-15 catalyst is 14%, propylene selectivity 86%.
Claims (4)
1. one kind is the catalyst of the preparing propylene by dehydrogenating propane of carrier with alumina modified mesoporous molecular sieve, it is characterized in that as the mesoporous molecular sieve MCM-41 of catalyst carrier or SBA-15 with alumina modified, in the catalyst, the weight percent content of aluminium oxide is: 5.0～30.0%, the activity of such catalysts component is a metal platinum, the weight percent content of platinum is: 0.4%, and the weight percent content of auxiliary agent Sn is: 0.1～2.0%, form PtSn/Al
2O
3/ MCM-41 or PtSn/Al
2O
3/ SBA-15 catalyst.
2. the alumina modified mesoporous molecular sieve of usefulness as claimed in claim 1 is the catalyst of the preparing propylene by dehydrogenating propane of carrier, it is characterized in that mesoporous molecular sieve is MCM-41.
3. the alumina modified mesoporous molecular sieve of usefulness as claimed in claim 1 is the catalyst of the preparing propylene by dehydrogenating propane of carrier, it is characterized in that auxiliary agent Sn weight percent content 0.2～1.2%.
4. the alumina modified mesoporous molecular sieve of usefulness as claimed in claim 1 is the catalyst of the preparing propylene by dehydrogenating propane of carrier, it is characterized in that alumina weight degree 9.0～23.0%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200710025372XA CN100464849C (en) | 2007-07-26 | 2007-07-26 | A catalyst for producing propylene from propane dehydrogenation with alumina-modified mesoporous molecular sieve as carrier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200710025372XA CN100464849C (en) | 2007-07-26 | 2007-07-26 | A catalyst for producing propylene from propane dehydrogenation with alumina-modified mesoporous molecular sieve as carrier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101125298A CN101125298A (en) | 2008-02-20 |
| CN100464849C true CN100464849C (en) | 2009-03-04 |
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|---|---|---|---|
| CNB200710025372XA Expired - Fee Related CN100464849C (en) | 2007-07-26 | 2007-07-26 | A catalyst for producing propylene from propane dehydrogenation with alumina-modified mesoporous molecular sieve as carrier |
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Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101590424B (en) * | 2008-05-29 | 2015-01-07 | 北京三聚环保新材料股份有限公司 | Hydrogenation catalyst of distillate oil and preparation method thereof |
| CN102219631B (en) * | 2010-04-15 | 2013-12-25 | 中国石油化工股份有限公司 | Method for selectively oxidizing and catalyzing hydrogen in propane dehydrogenation process |
| CN102463152B (en) * | 2010-11-04 | 2014-01-01 | 中国石油化工股份有限公司 | Method for processing dehydrogenation catalyst before application |
| CN102463148B (en) * | 2010-11-04 | 2014-01-01 | 中国石油化工股份有限公司 | Vulcanization and startup method of dehydrogenation catalyst |
| CN102464542B (en) * | 2010-11-04 | 2015-01-14 | 中国石油化工股份有限公司 | Startup method of dehydrogenation catalyst |
| EP2689843A1 (en) | 2012-07-26 | 2014-01-29 | Saudi Basic Industries Corporation | Alkane dehydrogenation catalyst and process for its preparation |
| CN104591942B (en) * | 2013-11-03 | 2016-04-27 | 中国石油化工股份有限公司 | Method of dehydrogenating |
| CN103816933B (en) * | 2014-02-13 | 2016-05-11 | 中国石油大学(北京) | A kind of catalysis dehydrogenation material and its preparation method and application |
| CN105582979B (en) * | 2014-10-22 | 2018-04-10 | 中国石油化工股份有限公司 | A kind of catalyst for dehydrogenation of low-carbon paraffin and preparation method thereof |
| CN105148979B (en) * | 2015-09-21 | 2017-06-30 | 西南化工研究设计院有限公司 | One kind is for preparing propylene transformed composite carried catalyst of dehydrogenating propane and preparation method thereof |
| CN106607105B (en) * | 2015-10-22 | 2019-12-10 | 中国石油化工股份有限公司 | Activation method of platinum-containing low-carbon alkane dehydrogenation catalyst |
| CN108855066B (en) * | 2017-05-10 | 2019-09-27 | 中国石油化工股份有限公司 | The method of propane dehydrogenation catalyst and preparation method thereof and preparing propylene by dehydrogenating propane |
| CN109647494B (en) * | 2019-02-19 | 2020-03-31 | 西南化工研究设计院有限公司 | Composite carrier catalyst for preparing propylene by propane conversion and preparation method thereof |
| CN115487851A (en) * | 2021-06-18 | 2022-12-20 | 中国石油化工股份有限公司 | Spherical dehydrogenation catalyst, preparation method thereof and application in isobutane dehydrogenation to isobutene reaction |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5344805A (en) * | 1993-05-03 | 1994-09-06 | Phillips Petroleum Company | Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation |
| WO1999046039A1 (en) * | 1998-03-13 | 1999-09-16 | Den Norske Stats Oljeselskap A.S | Improved catalyst support material |
| CN1396146A (en) * | 2002-08-21 | 2003-02-12 | 复旦大学 | Process for preparing nano catalyst used to prepare propene by oxidizing and dehydrogenating propane |
| CN101003458A (en) * | 2006-01-19 | 2007-07-25 | 中国石油化工股份有限公司 | Method for preparing propylene by dehydrogenating propane |
-
2007
- 2007-07-26 CN CNB200710025372XA patent/CN100464849C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5344805A (en) * | 1993-05-03 | 1994-09-06 | Phillips Petroleum Company | Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation |
| WO1999046039A1 (en) * | 1998-03-13 | 1999-09-16 | Den Norske Stats Oljeselskap A.S | Improved catalyst support material |
| CN1396146A (en) * | 2002-08-21 | 2003-02-12 | 复旦大学 | Process for preparing nano catalyst used to prepare propene by oxidizing and dehydrogenating propane |
| CN101003458A (en) * | 2006-01-19 | 2007-07-25 | 中国石油化工股份有限公司 | Method for preparing propylene by dehydrogenating propane |
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| CN101125298A (en) | 2008-02-20 |
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