CN100438120C - Organic electroluminescent panel and its mfg. method - Google Patents
Organic electroluminescent panel and its mfg. method Download PDFInfo
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- CN100438120C CN100438120C CNB2004100306615A CN200410030661A CN100438120C CN 100438120 C CN100438120 C CN 100438120C CN B2004100306615 A CNB2004100306615 A CN B2004100306615A CN 200410030661 A CN200410030661 A CN 200410030661A CN 100438120 C CN100438120 C CN 100438120C
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/874—Passivation; Containers; Encapsulations including getter material or desiccant
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/805—Electrodes
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/8791—Arrangements for improving contrast, e.g. preventing reflection of ambient light
- H10K59/8792—Arrangements for improving contrast, e.g. preventing reflection of ambient light comprising light absorbing layers, e.g. black layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K77/00—Constructional details of devices covered by this subclass and not covered by groups H10K10/80, H10K30/80, H10K50/80 or H10K59/80
- H10K77/10—Substrates, e.g. flexible substrates
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- Electroluminescent Light Sources (AREA)
Abstract
Description
技术领域 technical field
本发明涉及一种有机电致发光(以下称为EL:Electroluminescence)面板及其制造方法。The present invention relates to an organic electroluminescent (hereinafter referred to as EL: Electroluminescence) panel and a manufacturing method thereof.
背景技术 Background technique
有机EL面板是以有机EL元件为基本结构,把该有机EL元件作为单位面发光部件排列在平面基板上而形成的,该有机EL元件是通过在支撑基板上形成第一电极,在其上形成包含由有机化合物构成的发光层的有机层,再在其上形成第二电极而构成的。The organic EL panel is based on an organic EL element, which is formed by arranging the organic EL element as a unit surface light-emitting component on a flat substrate. The organic EL element is formed by forming a first electrode on a supporting substrate, and then forming An organic layer including a light-emitting layer made of an organic compound, on which a second electrode is formed.
已知在所述有机层和电极曝露于外部空气状态下时有机EL面板的特性会劣化。这是由于水分浸入有机层与电极间的交界面,妨碍了电子注入,进而产生作为非发光区域的暗点,或因电极腐蚀现象而造成,为了提高有机EL元件的稳定性和耐久性,使有机EL元件与外部空气隔绝的密封技术是必不可缺的。关于该密封技术,一般采用在形成有电极和有机层的支撑基板上,通过粘接剂将覆盖该电极和有机层的密封部件进行粘合的方法。It is known that the characteristics of an organic EL panel deteriorate when the organic layers and electrodes are exposed to the outside air. This is caused by the infiltration of water into the interface between the organic layer and the electrode, hindering the injection of electrons, and then producing dark spots as non-luminous regions, or by corrosion of the electrodes. In order to improve the stability and durability of organic EL elements, use Sealing technology to isolate organic EL elements from the outside air is essential. Regarding this sealing technique, a method of bonding a sealing member covering the electrodes and the organic layer with an adhesive to a support substrate on which the electrodes and the organic layer are formed is generally employed.
图1表示该有机EL面板的现有技术(参照下述专利文献1)。有机EL面板(有机EL元件)1由成为支撑基板的玻璃基板2、ITO电极3和有机发光材料层4和阴极5构成的叠层体6、成为密封部件的玻璃密封罐7、干燥部件8以及密闭材料9构成。FIG. 1 shows the prior art of this organic EL panel (see Patent Document 1 below). An organic EL panel (organic EL element) 1 is composed of a
干燥部件8是为了在通过玻璃密封罐7密封后,吸收除去存在于其中的初期水分以及随时间释放出的或浸入的水分而设置的。特别是由于形成有机EL元件的有机层抗热能力弱,不能在密封前通过加热处理除去水分,所以不能完全排出这样的初期水分。因此,在使用现有的有机EL材料的面板中,不得不在密封部件内设置这种干燥部件8。在下述专利文献1中有以下记载,作为干燥部件8,使用可以通过化学方式吸附水分并且即使吸湿也能维持固体状态的化合物,使用粘接材料把该干燥部件8安装在玻璃密封罐7的内面(与玻璃基板对置的面)。The
专利文献1 特开平9-148066号公报Patent Document 1 Japanese Patent Laid-Open No. 9-148066
在这种现有的有机EL面板中,采用把有机EL元件的支撑基板(玻璃基板2)侧作成透明基板,从该支撑基板侧发光的方式(底面射出方式)。在这种情况下会产生下述现象,即,外部光从支撑基板等入射到面板内部(由支撑基板和密封部件(玻璃密封罐7)包围而成的密封空间),然后,入射光在密封部件的内面(与支撑基板相对的面)或被设置在该内面上的干燥部件的表面反射,从支撑基板的显示面射出。另外,虽然由有机EL元件发出的光的大部分被设定成从支撑基板的发光面射出,但有时其中一部分光在面板内成为散射光,和上述的外部光相同,该散射光在密封部件的内面或安装在该内面上的干燥部件的表面反射,从支撑基板的显示面射出。In such a conventional organic EL panel, the support substrate (glass substrate 2 ) side of the organic EL element is made a transparent substrate, and light is emitted from the support substrate side (bottom surface emission system). In this case, there will be a phenomenon that external light enters the inside of the panel (the sealed space surrounded by the support substrate and the sealing member (glass can 7)) from the support substrate, etc., and then the incident light enters the sealed space. The inner surface of the member (the surface facing the support substrate) or the surface of the drying member provided on the inner surface is reflected and emitted from the display surface of the support substrate. In addition, although most of the light emitted by the organic EL element is set to be emitted from the light-emitting surface of the supporting substrate, some of the light may become scattered light in the panel, which is the same as the above-mentioned external light. The inner surface of the inner surface or the surface reflection of the drying component installed on the inner surface is emitted from the display surface of the supporting substrate.
这样,如果入射到面板内的外部光和来自有机EL元件的散射光在密封部件的内面或干燥部件的表面反射,并从显示面一侧射出,会产生来自有机EL元件的射出光形成的显示对比度降低的问题。In this way, if the external light incident on the panel and the scattered light from the organic EL element are reflected on the inner surface of the sealing member or the surface of the drying member and emitted from the display surface side, a display formed by the emitted light from the organic EL element will be produced. The problem of reduced contrast.
并且,如果在密封部件的内面或干燥部件的表面反射的光从显示面一侧射出,那么在从显示面直接或斜着观看支撑基板的情况下等,有时会看到配置在面板内部的干燥部件,由此产生对外观造成不利的影响的问题。因此,如果把这种外观的缺陷视为次品,则需要针对外部光的入射和散射光的防止进行高精度地设计,并且还必须提高干燥部件的配置位置等的精度,所以存在着产品的成品率降低,产品成本增高的问题。In addition, if the light reflected on the inner surface of the sealing member or the surface of the drying member is emitted from the display surface side, when the supporting substrate is viewed directly or obliquely from the display surface, etc., the dryness arranged inside the panel may sometimes be seen. components, thereby causing a problem of adversely affecting the appearance. Therefore, if such defects in appearance are regarded as defective products, it is necessary to design with high precision to prevent the incidence of external light and scattered light, and it is also necessary to improve the accuracy of the arrangement position of the drying parts, so there is a product gap. The yield rate is reduced and the product cost is increased.
发明内容 Contents of the invention
本发明是以解决上述问题为课题而提出的。即,本发明的目的在于,提供一种有机EL面板及其制造方法,以此来提高显示面的对比度,消除从显示面一侧可看到面板内部的干燥部件的外观缺陷,提高产品的成品率,降低产品成本等。The present invention has been made to solve the above-mentioned problems. That is, the purpose of the present invention is to provide an organic EL panel and its manufacturing method, thereby improving the contrast of the display surface, eliminating the appearance defect of the drying parts inside the panel from the display surface side, and improving the quality of the finished product. rate, reduce product cost, etc.
为了达到上述目的,本发明的有机EL面板及其制造方法至少具有以下各独立技术方案。In order to achieve the above object, the organic EL panel and its manufacturing method of the present invention have at least the following independent technical solutions.
[技术方案1]一种有机EL面板,在支撑基板上,形成在一对电极间夹着至少含有发光层的有机层的有机EL元件,并粘合有使该有机EL元件与外部空气隔绝的密封部件,其特征在于,在所述密封部件的与所述支撑基板相对的面上设置已着色的干燥部件。[Technical solution 1] An organic EL panel, in which an organic EL element having an organic layer including at least a light-emitting layer is formed between a pair of electrodes on a supporting substrate, and an organic EL element is bonded to isolate the organic EL element from the outside air. The sealing member is characterized in that a colored drying member is provided on a surface of the sealing member facing the support substrate.
[技术方案6]一种有机EL面板的制造方法,具有在支撑基板上形成在一对电极间夹着至少含有发光层的有机层的有机EL元件的元件形成工序,和将使该有机EL元件与外部空气隔绝的密封部件粘合在所述支撑基板上的密封工序,其特征在于,在所述密封工序之前,在所述密封部件的与所述支撑基板相对的面上安装已着色的干燥部件。[Technical solution 6] A method of manufacturing an organic EL panel, comprising an element forming step of forming an organic EL element having an organic layer including at least a light-emitting layer sandwiched between a pair of electrodes on a support substrate, and making the organic EL element A sealing step in which a sealing member isolated from the outside air is bonded to the supporting substrate, wherein prior to the sealing step, a colored dry part.
附图说明 Description of drawings
图1是现有技术的说明图。FIG. 1 is an explanatory diagram of the prior art.
图2是说明本发明的一实施方式的有机EL面板的说明图。FIG. 2 is an explanatory diagram illustrating an organic EL panel according to an embodiment of the present invention.
图3是说明本发明的其它实施方式的有机EL面板的说明图。FIG. 3 is an explanatory diagram illustrating an organic EL panel according to another embodiment of the present invention.
图4是表示本发明的其它实施方式的有机EL面板的说明图。FIG. 4 is an explanatory view showing an organic EL panel according to another embodiment of the present invention.
图5是表示本发明的实施方式的有机EL面板的制造方法的概略流程的说明图。5 is an explanatory diagram showing a schematic flow of a method for manufacturing an organic EL panel according to an embodiment of the present invention.
图中:10、20、30:有机EL面板;11:支撑基板;12:有机EL元件;13、21、31:密封部件;14:干燥部件;15:粘接剂;15A:间隔团;16、21、31、41、51:密封部件;21A、31A:密封凹部;31B:安装凹部。In the figure: 10, 20, 30: organic EL panel; 11: supporting substrate; 12: organic EL element; 13, 21, 31: sealing part; 14: drying part; 15: adhesive; 15A: spacer; 16 , 21, 31, 41, 51: sealing parts; 21A, 31A: sealing recesses; 31B: mounting recesses.
具体实施方式 Detailed ways
以下,参照附图说明本发明的实施方式。图2~4是本发明的一实施方式的有机EL面板的说明图。该有机EL面板10、20、30在支撑基板11上形成有在一对电极间夹着至少含有发光层的有机层的有机EL元件12。而且,通过粘接剂15把密封部件13、21、31粘合在支撑基板11上,从而利用由支撑基板11和密封部件13、21、31包围而成的密封空间覆盖有机EL元件12,使其与外部空气隔绝。在该密封部件13、21、31内,在与支撑基板11相对的面上与有机EL元件12分离开设置干燥部件14。Hereinafter, embodiments of the present invention will be described with reference to the drawings. 2 to 4 are explanatory diagrams of an organic EL panel according to an embodiment of the present invention. In the
此处,在图2所示的实施方式的有机EL面板10中,使用平板的密封部件13,通过在粘接剂15内混入间隔团15A来形成所述的密封空间。在图3所示的实施方式的有机EL面板20中,在密封部件21的支撑基板11侧形成密封凹部21A,在支撑基板11和密封凹部21A之间形成所述的密封空间。在图4所示的实施方式的有机EL面板30中,在密封部件31的支撑基板11侧形成密封凹部31A,在支撑基板11和密封凹部31A之间形成所述的密封空间,并且在密封凹部31A内形成用于安装干燥部件14的安装凹部31B。该安装凹部31B被用透湿性薄膜32堵塞着,用于防止干燥部件14的脱落。Here, in the organic EL panel 10 of the embodiment shown in FIG. 2 , the sealing space described above is formed by mixing the spacers 15A into the
并且,在本发明的实施方式的有机EL面板10、20、30中,作为干燥部件14使用已着色为光吸收性颜色的部件。光吸收性颜色只要是能够吸收可见光区域的波长的颜色即可,优选黑色、灰色、深茶色等能够均匀吸收可见光的所有波长的颜色。作为一个实施方式,使用被着色成大致黑色或灰色的干燥部件。In addition, in the
该干燥部件14是在粘接密封部件13、21、31后安装设置的,用于吸收除去存在于其中的初期水分以及随时间放出或浸入的水分,只要具有这种功能即可,没有特别限定。作为一个实施方式,使用下述的吸湿性模塑体,通过向该模塑体内分散颜料来进行所述着色。The
另外,作为密封部件13、21、31,只要能够保持气密性即可,可以利用金属或树脂等形成,但作为一个实施方式,优选利用玻璃制基板来形成。In addition, the sealing
根据这种实施方式的有机EL面板10、20、30,利用来自支撑基板11侧的射出光进行显示,在支撑基板11上形成显示面。并且,由于把已着色的干燥部件14设在密封部件13、21、31中的与支撑基板11相对的表面上,所以已着色的干燥部件14吸收入射到面板内的外部光或来自有机EL元件12的散射光,可以防止这些光被反射后从显示面一侧射出。由此,可以提高利用有机EL元件12的射出光而进行显示的对比度,同时可以消除从支撑基板11侧可看到设在面板内部的干燥部件14的外观不良。According to the
为了防止在密封部件13、21、31内面的反射,也可以考虑在密封部件内面涂覆光吸收性涂料,但根据这种方法,额外需要涂覆密封部件内面的工序,同时由于所涂覆的涂料在密封空间内产生有机EL元件12的劣化因素(水分或有机材料),导致降低有机EL元件12寿命的不良情况。如果根据本发明的实施方式,通过将干燥部件14着色,不会影响制造工序的工序数目,也不会在密封空间内产生有机EL元件12的劣化因素。In order to prevent reflection on the inner surface of the sealing
并且,特别是通过把干燥部件14的颜色作成高可见光吸收率的黑色或灰色,可以均匀吸收上述的外部光或散射光的可见光区域的所有波长,能够更可靠地发挥上述作用。这样,特别是在进行彩色显示的有机EL面板中,可以有效改善该显示面的对比度及外观不良。In addition, by making the color of the drying
并且,在利用吸湿性模塑体形成干燥部件14,在其中分散颜料来进行所述着色的实施方式中,不论干燥部件14的种类或材料,均可着色成所需要的颜色。这样,可以在不影响干燥部件14的吸湿功能的情况下确保上述作用。In addition, in the embodiment in which the drying
并且,在把密封部件13、21、31作成玻璃制基板的实施方式中,在上述作用的基础上,可以获得以下作用。即,第一,由于利用和支撑基板11一般使用的玻璃制基板相同的材料形成密封部件13、21、31,所以,支撑基板11和密封部件13、21、31的热膨胀系数相同,从而可以提高面板相对于温度变化的机械强度。第二,玻璃制基板的表面平滑性高于金属制等的密封部件,所以在与粘接剂15的交界面处难以形成间隙,从而能够提高粘接力。因此,水分等难以从外部浸入,从而可以提高密封性。第三,由于与采用金属制密封部件的情况相比,通过利用玻璃制基板形成密封部件13、21、31,可以使面板薄壁化和轻量化。Furthermore, in the embodiment in which the sealing
下面,说明本发明的实施方式涉及的有机EL面板的制造方法。图5是表示其概略流程的说明图。首先,作为元件形成工序S1A,在支撑基板11上形成叠层了第一电极、有机层、第二电极的有机EL元件12,形成在一对电极间夹着至少含有发光层的有机层的有机EL元件12。此处,有机EL元件的形成采用一般使用的众所周知的成膜工序和图案形成工序。Next, a method of manufacturing an organic EL panel according to an embodiment of the present invention will be described. FIG. 5 is an explanatory diagram showing a schematic flow thereof. First, as the element forming step S1A, an
另一方面,作为干燥部件安装工序S1B,把干燥部件14安装到密封部件13、21、31上。在该干燥部件安装工序S1B,准备好预先经颜料的分散等已着色的干燥部件14,与通常的干燥部件安装工序相同地将其安装在密封部件13、21、31的内面(与支撑基板11相对的面)。On the other hand, the drying
作为密封工序S2,通过在支撑基板11的周边或密封部件13、21、31的粘接面上涂覆粘接剂15,在支撑基板11上粘合密封部件13、21、31,对有机EL元件12进行密封。然后,根据需要经过适当的检查工序S3,获得实施方式的有机EL面板10、20、30。As the sealing step S2, the adhesive 15 is applied to the periphery of the supporting
根据这种实施方式的制造方法,对以往的面板制造方法不做任何变更,按照前面所述,就可以获得高对比度且没有外观不良的有机EL面板10、20、30。According to the manufacturing method of this embodiment, the
下面,把本发明的实施方式涉及的有机EL面板及其制造方法的特征总结如下。Hereinafter, the characteristics of the organic EL panel and its manufacturing method according to the embodiment of the present invention are summarized as follows.
第一,一种有机EL面板,在支撑基板上,形成在一对电极间夹着至少含有发光层的有机层的有机EL元件,并粘合有使该有机EL元件与外部空气隔绝的密封部件,其特征在于,在所述密封部件的与所述支撑基板相对的面上设置已着色的干燥部件。另外还涉及一种有机EL面板的制造方法,具有在支撑基板上形成在一对电极间夹着至少含有发光层的有机层的有机EL元件的元件形成工序,和将使该有机EL元件与外部空气隔绝的密封部件粘合在所述支撑基板上的密封工序,其特征在于,在所述密封工序之前,在所述密封部件的与所述支撑基板相对的面上安装已着色的干燥部件。First, an organic EL panel in which an organic EL element having an organic layer including at least a light-emitting layer is sandwiched between a pair of electrodes on a support substrate, and a sealing member is bonded to isolate the organic EL element from the outside air. , characterized in that a colored drying member is provided on the surface of the sealing member opposite to the supporting substrate. It also relates to a method of manufacturing an organic EL panel, comprising an element forming step of forming an organic EL element having an organic layer including at least a light-emitting layer sandwiched between a pair of electrodes on a support substrate, and connecting the organic EL element to the outside The sealing step of bonding an air-insulated sealing member to the support substrate, wherein prior to the sealing step, a colored drying member is attached to a surface of the sealing member opposite to the support substrate.
这样,已着色的干燥部件吸收入射到面板内的外部光或来自有机EL元件的散射光,可以防止这些光被反射后从显示面一侧射出,可以提高利用来自有机EL元件的射出光而进行显示的对比度,同时可以消除从支撑基板侧能看到设在面板内部的干燥部件的外观不良。并且,可以不影响制造精度而获得这种优点,所以能够简单地减少低对比度或外观不良的次品,提高产品的成品率,降低产品成本。另外,本发明的制造方法无须对以往的制造方法做任何变更,就可以获得上述的具有本发明的效果的有机EL面板。In this way, the colored drying member absorbs the external light incident on the panel or the scattered light from the organic EL element, which can prevent these lights from being reflected and then emitted from the display surface side, and can improve the performance by using the emitted light from the organic EL element. The contrast of the display can be improved, and at the same time, it can eliminate the appearance defect that the drying parts installed inside the panel can be seen from the support substrate side. Moreover, this advantage can be obtained without affecting the manufacturing accuracy, so it is possible to easily reduce defective products with low contrast or poor appearance, improve product yield, and reduce product cost. In addition, the production method of the present invention can obtain the above-mentioned organic EL panel having the effect of the present invention without any modification to the conventional production method.
第二,在上述的有机EL面板及其制造方法中,其特征在于,上述干燥部件被着色成光吸收性颜色,特别是被着色成大致黑色或大致灰色。这样,在上述特征的基础上,可以均匀地吸收上述的外部光或散射光的可见光区域的所有波长,能够更可靠地实施上述作用。并且,特别是在进行彩色显示的有机EL面板中,可以有效改善该显示面的对比度及外观不良。Second, in the above-mentioned organic EL panel and its manufacturing method, the drying member is colored in a light-absorbing color, in particular, in substantially black or substantially gray. In this way, in addition to the above features, it is possible to uniformly absorb all the wavelengths of the visible light region of the above-mentioned external light or scattered light, and it is possible to perform the above-mentioned operation more reliably. In addition, especially in an organic EL panel for color display, it is possible to effectively improve the contrast and appearance defects of the display surface.
第三,在上述的有机EL面板及其制造方法中,其特征在于,所述干燥部件是吸湿性模塑体,通过向该吸湿性模塑体内分散颜料来进行所述着色。这样,在上述特征的基础上,不论干燥部件的种类或材料,均可着色成所需要的颜色,可以在不影响干燥部件的吸湿功能的情况下获得上述的效果。Thirdly, in the above-mentioned organic EL panel and its manufacturing method, the drying member is a hygroscopic molded body, and the coloring is performed by dispersing a pigment into the hygroscopic molded body. In this way, on the basis of the above features, regardless of the type or material of the drying member, it can be colored into a desired color, and the above effects can be obtained without affecting the moisture absorption function of the drying member.
第四,在上述的有机EL面板及其制造方法中,其特征在于,所述密封部件是玻璃制基板。这样,在上述特征的基础上,可以获得相对温度变化的机械强度高、密封性能良好的薄壁化和轻量化的有机EL面板。Fourth, in the above-mentioned organic EL panel and its manufacturing method, the sealing member is a glass substrate. Thus, in addition to the above features, a thinner and lighter organic EL panel with high mechanical strength against temperature changes and good sealing performance can be obtained.
[实施例][Example]
以下,作为本发明的实施例,列举与上述实施方式的构成部件相关的具体示例。Hereinafter, as an embodiment of the present invention, specific examples related to the constituent members of the above-mentioned embodiment will be given.
[干燥部件14]作为干燥部件14,可以使用物理干燥剂(沸石、硅胶、碳、碳纳米管等)、后述的化学吸湿剂、把有机金属络合物溶解到石油类溶剂(甲苯、二甲苯、脂肪族有机溶剂等)的干燥剂等单体,也可以使用以下所示的吸湿性模塑体。[Drying unit 14] As the drying
所说的吸湿性模塑体是向树脂成分(粘合剂)中分散了吸湿剂的模塑体。作为吸湿剂,只要是具有至少可以吸附水分的功能的物质即可,但特别优选可以通过化学方式吸附水分并且即使吸湿也能维持固体状态的化合物。作为这种化合物,例如可以列举金属氧化物、金属的无机酸盐和有机酸盐等,但特别优选使用碱土类金属氧化物和硫酸盐的至少一种。作为碱土类金属氧化物,例如可以列举氧化钙(CaO)、氧化钡(BaO)、氧化镁(MgO)等。作为硫酸盐,例如可以列举硫酸锂(Li2SO4)、硫酸钠(Na2SO4)、硫酸钙(CaSO4)、硫酸镁(MgSO4)、硫酸钴(CoSO4)、硫酸镓(Ga2(SO4)3)、硫酸钛(Ti(SO4)2)、硫酸镍(NiSO4)等。其它也可以使用具有吸湿性的有机材料作为吸湿剂。The hygroscopic molded article is a molded article in which a hygroscopic agent is dispersed in a resin component (binder). As the hygroscopic agent, any substance may be used as long as it has a function of at least absorbing moisture, but a compound that can chemically adsorb moisture and maintain a solid state even after absorbing moisture is particularly preferable. Examples of such compounds include metal oxides, metal salts of inorganic acids and organic acids, and it is particularly preferable to use at least one of alkaline earth metal oxides and sulfates. Examples of alkaline earth metal oxides include calcium oxide (CaO), barium oxide (BaO), magnesium oxide (MgO), and the like. Examples of sulfates include lithium sulfate (Li 2 SO 4 ), sodium sulfate (Na 2 SO 4 ), calcium sulfate (CaSO 4 ), magnesium sulfate (MgSO 4 ), cobalt sulfate (CoSO 4 ), gallium sulfate (Ga 2 (SO 4 ) 3 ), titanium sulfate (Ti(SO 4 ) 2 ), nickel sulfate (NiSO 4 ), etc. Other hygroscopic organic materials can also be used as hygroscopic agents.
另一方面,作为树脂成分(粘合剂),只要不妨碍吸湿剂的水分去除作用,就不做特别限定,优选使用透气性高的材料(即屏蔽性低的材料,特别是透气性树脂)。作为这种材料,例如可以列举聚烯烃类、聚丙烯酸类、聚丙烯腈类、聚酰胺类、聚酯类、环氧类、聚碳酸酯类等高分子材料。其中,在本发明中优选聚烯烃类。具体而言,可以列举聚乙烯、聚丙烯、聚丁二烯、聚异戊间二烯等,以及它们的共聚物等。On the other hand, the resin component (binder) is not particularly limited as long as it does not interfere with the moisture removal function of the moisture absorbent, and it is preferable to use a material with high air permeability (that is, a material with low barrier properties, especially an air-permeable resin). . Examples of such materials include polymer materials such as polyolefins, polyacrylics, polyacrylonitriles, polyamides, polyesters, epoxies, and polycarbonates. Among them, polyolefins are preferable in the present invention. Specifically, polyethylene, polypropylene, polybutadiene, polyisoprene, etc., their copolymers, etc. are mentioned.
吸湿剂和树脂成分的含有量根据它们的种类等可以适当设定,但通常把吸湿剂和树脂成分的合计含量设为100重量%时,吸湿剂约30重量%~85重量%,树脂成分约70重量%~15重量%即可。优选吸湿剂约40重量%~80重量%,树脂成分约60重量%~20重量%,最优选吸湿剂约50重量%~70重量%,树脂成分约50重量%~30重量%。The content of the hygroscopic agent and the resin component can be appropriately set according to their types, etc., but generally, when the total content of the hygroscopic agent and the resin component is 100% by weight, the moisture absorbent is about 30% by weight to 85% by weight, and the resin component is about 30% by weight. 70% by weight to 15% by weight will suffice. Preferably, the hygroscopic agent is about 40% to 80% by weight, and the resin component is about 60% to 20% by weight. Most preferably, the moisture absorbent is about 50% to 70% by weight, and the resin component is about 50% to 30% by weight.
吸湿性模塑体可以通过均匀混合所述各成分,模塑成所需形状而得到。该情况时,优选吸湿剂、气体吸附剂等预先充分干燥后再混合。另外,在与树脂成分混合时,可以根据需要加热形成熔融状态。A hygroscopic molded body can be obtained by uniformly mixing the above components and molding into a desired shape. In this case, it is preferable to dry the hygroscopic agent, the gas adsorbent, etc. sufficiently beforehand before mixing. Moreover, when mixing with a resin component, it can heat and make it into a molten state as needed.
作为本发明的实施例,吸湿性模塑体优选是把由吸湿剂和树脂成分构成的混合物进行模塑而得到的物质。即,使用不包含溶剂等第三成分的材料制造吸湿性模塑体,由此可以避免因这些第三成分残存在模塑体中而带来的弊端(例如,所残存的溶剂被吸湿剂吸附,降低吸附剂的性能,或由于所残存的溶剂在密封部件内随时间而挥发所造成的弊端)。As an embodiment of the present invention, the hygroscopic molded article is preferably one obtained by molding a mixture composed of a hygroscopic agent and a resin component. That is, using materials that do not contain third components such as solvents to produce hygroscopic moldings can avoid the disadvantages caused by these third components remaining in the moldings (for example, the remaining solvent is absorbed by the hygroscopic agent) , reduce the performance of the adsorbent, or the disadvantages caused by the volatilization of the remaining solvent in the sealing part over time).
在向密封部件13、21、31上进行安装时,只要是能够可靠地固定在密封部件内的方法就不做特别限定,例如,可以列举利用公知的粘合剂、粘接剂(优选无溶剂型粘接剂)等粘合吸湿性模塑体和密封部件的方法,把吸湿性模塑体热熔覆在密封部件上的方法,利用螺钉等固定部件把模塑体固定在密封部件上的方法等。When mounting on the sealing
虽然用于着色而分散的颜料与无机类及有机类的类属无关,但适宜选择不会排出使有机EL元件劣化的因素的材料。The pigment to be dispersed for coloring is not related to the type of inorganic or organic, but it is appropriate to select a material that does not emit factors deteriorating the organic EL element.
[密封部件]密封部件13、21、31优选用玻璃(钠玻璃或非碱盐玻璃)制基板来形成。所述的密封凹部21A、31A,例如通过实施加压成形、蚀刻、喷砂处理等加工而形成。[Sealing member] The sealing
[粘接剂]粘接剂15使用热固化型、化学固化型(二液混合)、光(紫外线)固化型等粘接剂,其材料可以使用丙烯酸树脂、环氧树脂、聚酯、聚烯烃等。特别优选使用紫外线固化型环氧树脂。向这种粘接剂中,混合适量(约0.1重量%~0.5重量%)的粒径为1~100μm的隔离物(优选玻璃或塑料隔离物),使然后用配合器等进行涂覆。[Adhesives]
[有机EL元件]形成在支撑基板11上,在一对电极间夹着至少含有发光层的有机层的有机EL元件12的具体结构和材料的示例如下所述。[Organic EL element] The specific structure and material examples of the
(a)支撑基板:(a) Support substrate:
作为支撑基板11,优选为具有透明性的平板状或薄片状,其材质可以使用玻璃或塑料等。The
(b)电极(b) electrode
以从支撑基板11侧射出光的方式(底面射出方式)为前提的情况下,把支撑基板11侧的电极设为由透明电极构成的阳极,把另一方电极设为由金属电极构成的阴极。作为可以适用的阳极材料,可以使用ITO、ZnO等,通过蒸镀、溅射等成膜方法形成。作为阴极,使用功函数小的金属、金属氧化物、金属氟化物、合金等,具体讲可以使用Al、In、Mg等的单层结构、LiO2/Al等的叠层结构,通过蒸镀、溅射等成膜方法来形成。In the case of a method of emitting light from the
(c)有机层(c) Organic layer
有机层在以支撑基板11侧的电极为阳极、以另一方电极为阴极的情况下,一般是空穴输送层/发光层/电子输送层的叠层结构,也可以设置各自不只一层的多层叠层的发光层、空穴输送层、电子输送层,还可以省略空穴输送层和电子输送层任何一层,也可以两层均省略只剩下发光层。作为有机层,可以根据用途插入空穴注入层、电子注入层、空穴屏蔽层、电子屏蔽层等的有机功能层。When the electrode on the side of the supporting
有机层的材料可以根据有机EL元件12的用途适当选择。以下列举出示例,但不限于此。The material of the organic layer can be appropriately selected according to the use of the
作为空穴输送层,只要具有高空穴迁移率的功能即可,其材料可以选择使用以往公知的化合物中的任意物质。作为具体示例,可以使用铜酞菁蓝等血卟啉化合物、4,4’-双[N-(1-萘基)-N-苯氨基]-联苯(NPB)等芳香族叔胺、4-(二对甲苯氨基)-4’-[4-(二对甲苯氨基)苯乙烯基]二苯乙烯等二苯乙烯化合物、三唑衍生物或苯乙烯基胺化合物等有机材料。另外,也可以使用聚碳酸酯等高分子中分散有低分子的空穴输送用有机材料的高分子分散类材料。As the hole transport layer, it is only necessary to have a function of high hole mobility, and the material thereof can be selected from any of conventionally known compounds. As specific examples, hematoporphyrin compounds such as copper phthalocyanine blue, aromatic tertiary amines such as 4,4'-bis[N-(1-naphthyl)-N-phenylamino]-biphenyl (NPB), 4 Organic materials such as stilbene compounds such as -(di-p-tolylamino)-4'-[4-(di-p-tolylamino)styryl]stilbene, triazole derivatives, and styrylamine compounds. In addition, a polymer dispersion type material in which a low molecular weight organic material for hole transport is dispersed in a polymer such as polycarbonate can also be used.
发光层可以使用公知的发光材料,作为具体示例,可以使用4,4’-双(2,2’-联苯基乙烯基)-联苯(DPVBi)等芳香族二次甲基化合物、1,4-双(2-甲基苯乙烯基)苯等苯乙烯苯化合物、3-(4-联苯基)-4-苯基-5-叔丁苯基-1,2,4-三唑(TAZ)等三唑衍生物、蒽醌衍生物、芴酮衍生物等的荧光性有机材料、(8-羟基喹啉)铝络合物(Alq3)等荧光性有机金属化合物、聚对苯乙炔(PPV)类、聚芴类、聚乙烯咔唑(PVK)类等的高分子材料、白金络合物或铱络合物等三重激子中可以利用荧光发光的有机材料(特表2001-520450)。发光材料可以是仅用上述的发光材料构成的物质,也可以含有空穴输送材料、电子输送材料、添加剂(供体、受体等)或发光性掺杂物等。另外,这些物质也可以分散到高分子材料或无机材料中。Known light-emitting materials can be used for the light-emitting layer. As specific examples, aromatic dimethyl compounds such as 4,4'-bis(2,2'-biphenylvinyl)-biphenyl (DPVBi), 1, 4-bis(2-methylstyryl) benzene and other styrene benzene compounds, 3-(4-biphenyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole ( Triazole derivatives such as TAZ), fluorescent organic materials such as anthraquinone derivatives and fluorenone derivatives, fluorescent organometallic compounds such as (8-hydroxyquinoline) aluminum complex (Alq 3 ), poly(p-phenylene vinylene) (PPV) type, polyfluorene type, polyvinylcarbazole (PVK) type polymer materials, platinum complexes or iridium complexes and other triplet excitons can use fluorescent organic materials (Special Table 2001-520450 ). The light-emitting material may be composed of only the above-mentioned light-emitting materials, or may contain a hole-transporting material, an electron-transporting material, additives (donors, acceptors, etc.), luminescent dopants, and the like. In addition, these substances can also be dispersed in polymer materials or inorganic materials.
电子输送层只要具有把阴极注入的电子传递到发光层的功能即可,其材料可以选择使用以往公知的化合物中的任意物质。作为具体示例,可以使用硝基取代的芴酮衍生物、蒽金鸡纳甲烷衍生物等的有机材料、8-羟基喹啉衍生物的金属络合物、金属酞菁蓝等。The electron transport layer is only required to have the function of transferring electrons injected from the cathode to the light emitting layer, and its material can be selected from conventionally known compounds. As specific examples, organic materials such as nitro-substituted fluorenone derivatives, anthracenomethane derivatives, metal complexes of 8-hydroxyquinoline derivatives, metal phthalocyanine blue, and the like can be used.
上述的空穴输送层、发光层、电子输送层可以用旋转涂覆法、浸渍法等涂覆法、喷射法、丝网印刷法等湿式工艺、或蒸镀法、激光转印法等干式工艺形成。The above-mentioned hole transport layer, light-emitting layer, and electron transport layer can be coated by spin coating, dipping, etc., wet processes such as spraying, screen printing, or dry processes such as evaporation and laser transfer printing. craft formation.
[有机EL面板的各种方式]有机EL元件12可以是单一结构的有机EL元件,也可以是具有所需的图案结构,构成多个像素的元件。[Various forms of organic EL panel] The
如果是后者的情况,其显示方式可以是单色发光,也可以是2色或2色以上的多色发光,特别是为了实现多色发光的有机EL面板,可以用以下方式来构成,形成包含用于形成对应RGB的3种发光功能层的方式的2色或2色以上的发光功能层的方式(分涂方式)、白色或蓝色等单色发光功能层组合滤色器或由荧光材料形成的色变换层的方式(CF方式、CCM方式)、通过向单色发光功能层的发光区域照射电磁波等实现多色发光的方式(光致褪色方式)等。另外,有机EL元件的驱动方式可以是无源驱动方式或有源驱动方式中的任一种。In the case of the latter, the display method can be single-color light emission, or multi-color light emission of two or more colors, especially in order to realize the organic EL panel of multi-color light emission, it can be constructed in the following way, forming Including the method of forming three kinds of light-emitting functional layers corresponding to RGB, the method of forming two or more light-emitting functional layers (separate coating method), the single-color light-emitting functional layer such as white or blue combined with a color filter, or by fluorescent The method of color conversion layer formed by materials (CF method, CCM method), the method of realizing multi-color light emission by irradiating electromagnetic waves to the light emitting region of the monochromatic light emitting functional layer (photofading method), etc. In addition, the driving method of the organic EL element may be either a passive driving method or an active driving method.
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KR101222968B1 (en) * | 2006-04-25 | 2013-01-17 | 엘지디스플레이 주식회사 | Organic el display device and method for fabricating the same |
KR20120079319A (en) * | 2011-01-04 | 2012-07-12 | 삼성모바일디스플레이주식회사 | Plat panel display apparatus and organic light emitting display apparatus |
KR102370715B1 (en) * | 2014-12-29 | 2022-03-07 | 엘지디스플레이 주식회사 | Organic Light Emitting Diode Display Having Quantum Dot |
GB2538083A (en) * | 2015-05-06 | 2016-11-09 | Cambridge Display Tech Ltd | High contrast light emitting device |
CN107170906B (en) * | 2017-07-19 | 2020-03-24 | 京东方科技集团股份有限公司 | Frame sealing adhesive structure, display panel and display device |
US11411198B2 (en) * | 2019-06-18 | 2022-08-09 | Innolux Corporation | Electronic device |
CN110429206B (en) * | 2019-08-07 | 2021-11-23 | 京东方科技集团股份有限公司 | Packaging cover plate, display device, display panel and packaging method of display panel |
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