CN100436705C - Carrier for cold transfer printing paper and production process thereof - Google Patents
Carrier for cold transfer printing paper and production process thereof Download PDFInfo
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- CN100436705C CN100436705C CNB200610023344XA CN200610023344A CN100436705C CN 100436705 C CN100436705 C CN 100436705C CN B200610023344X A CNB200610023344X A CN B200610023344XA CN 200610023344 A CN200610023344 A CN 200610023344A CN 100436705 C CN100436705 C CN 100436705C
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- transfer printing
- printing paper
- carrier
- cold transfer
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- 238000010023 transfer printing Methods 0.000 title claims abstract description 72
- 238000004519 manufacturing process Methods 0.000 title abstract description 11
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000001294 propane Substances 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 9
- 238000009736 wetting Methods 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229920002774 Maltodextrin Polymers 0.000 claims abstract description 5
- 239000005913 Maltodextrin Substances 0.000 claims abstract description 5
- 229940035034 maltodextrin Drugs 0.000 claims abstract description 5
- 235000011837 pasties Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 150000004676 glycans Chemical class 0.000 claims description 57
- 229920001282 polysaccharide Polymers 0.000 claims description 56
- 239000005017 polysaccharide Substances 0.000 claims description 56
- 230000015572 biosynthetic process Effects 0.000 claims description 52
- 239000002562 thickening agent Substances 0.000 claims description 51
- 229920000742 Cotton Polymers 0.000 claims description 27
- 239000000835 fiber Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 239000004677 Nylon Substances 0.000 claims description 12
- 229920001778 nylon Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 10
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 239000006260 foam Substances 0.000 claims description 5
- 239000003230 hygroscopic agent Substances 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 239000004014 plasticizer Substances 0.000 claims description 5
- 229920003043 Cellulose fiber Polymers 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 claims 1
- -1 pyrrolidone sodium carboxylate Chemical class 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 30
- 238000007639 printing Methods 0.000 abstract description 26
- 229920001218 Pullulan Polymers 0.000 abstract description 12
- 239000004373 Pullulan Substances 0.000 abstract description 12
- 235000019423 pullulan Nutrition 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 9
- 229920002472 Starch Polymers 0.000 abstract description 3
- 238000006266 etherification reaction Methods 0.000 abstract description 3
- 239000008107 starch Substances 0.000 abstract description 3
- 235000019698 starch Nutrition 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract 5
- 238000007254 oxidation reaction Methods 0.000 abstract 5
- AYRXSINWFIIFAE-SCLMCMATSA-N Isomaltose Natural products OC[C@H]1O[C@H](OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O)[C@@H](O)[C@@H](O)[C@@H]1O AYRXSINWFIIFAE-SCLMCMATSA-N 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- DLRVVLDZNNYCBX-RTPHMHGBSA-N isomaltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-RTPHMHGBSA-N 0.000 abstract 1
- 238000006384 oligomerization reaction Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 22
- 241000219146 Gossypium Species 0.000 description 17
- 239000003086 colorant Substances 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 6
- 239000000985 reactive dye Substances 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- FQCSIUSICFAMDD-UHFFFAOYSA-N 2-oxopyrrolidine-1-carboxylic acid;sodium Chemical compound [Na].OC(=O)N1CCCC1=O FQCSIUSICFAMDD-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 241000233855 Orchidaceae Species 0.000 description 3
- 239000000980 acid dye Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005092 sublimation method Methods 0.000 description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- GNCJMDBNGRMNHY-UHFFFAOYSA-N 2-[(4,6-diamino-1,3,5-triazin-2-yl)amino]acetic acid Chemical compound NC1=NC(N)=NC(NCC(O)=O)=N1 GNCJMDBNGRMNHY-UHFFFAOYSA-N 0.000 description 1
- RJCUNTCBNNWRMP-UHFFFAOYSA-N 2-methyloxirane Chemical compound CC1CO1.CC1CO1 RJCUNTCBNNWRMP-UHFFFAOYSA-N 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009290 primary effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- Coloring (AREA)
Abstract
The present invention relates to a carrier for cold transfer printing paper and a production process thereof. The carrier for cold transfer printing paper is mainly composed of pullulan polyose class substances. Oligomerization isomaltose alcohol and maltodextrin (a starch class) with a DE value which is less than or equal to 15% are dissolved according to the proportion of (a mass proportion) of 1 to 4 (+/-) 2.98% of chemical pure oxidation propane is slowly dipped under the condition of the low temperature which is lower than or equal to 30 DEG C, and dipping time is 30 to 40 minutes. The condition of the low temperature is kept for three hours, and stirring is started. The temperature of an oxidation propane wetting raw material is raised to 50 DEG C to 60 DEG C to be in an initial pasty shape after four hours, and the temperature of the oxidation propane wetting raw material is kept for four hours to promote etherification under the condition of the temperature of 50 DEG C to 60 DEG C. After an etherification initial condition is finished, the temperature of the oxidation propane wetting raw material is raised to 75 DEG C, and is kept for two hours under the condition of the temperature of 75 DEG C. The temperature of the oxidation propane wetting raw material is lowered below 30 DEG C to be statically placed for 10 hours, after polymerization reaction is finished, a pullulan polyose class structure paste material can be formed. The pullulan polyose class structure paste material and a proper amount of dye are used for forming a combination color material. The combination color material is suitable for the printing requirements of a printing machine. Cold transfer printing paper which is printed can be applied to a fabric transfer printing process.
Description
Technical field
The present invention relates to textile printing and dyeing industry, specifically be meant the carrier of used dyestuff when a kind of fabric cold transfer printing paper prints, i.e. the union body of dyestuff.
Background technology
Use sublimation process and realize that the textiles transfer printing has been very ripe, in recent years, annual all have the synthetic fiber of tens meters amounts to carry out transfer printing production by sublimation process.But, relating to cotton, when hair and silk wait natural fabric and cellulose fibre, can't produce with the sublimed method transfering printing process.This is because the dyestuff of vaporization is instead absorbed by fiber surface, can't spread in fiber, forms ring and dyes state, can't reach due COLOR FASTNESS and vividness.Germany BASF AG is proposing a method to cellulosic fabric evolution transfer printing during with sublimation dye among the patent BP 1,532,823.This method comprises compound water solution impregnate fabric, drying and the stamp that can make transferred dyes solvent and cellulose crosslinked dose with a kind of.Illustrating in the patent, is the carboxymethyl melamine of methanol etherification and the mixture of carbamic acid methoxy ethyl ester with regard to this solvent with as the aqueous solution of the compound of crosslinking agent.Japanese Cangfu companies in 1975 adopt the arrangement of a kind of " Mermaiduni " by name, in conjunction with distillation DISPERSE DYES and application swelling agent and crosslinking agent, and with this type of chemicals at transfer printing pre-treatment fabric.Similar this class elder generation chemical treatment fiber, the technology of carrying out transfer printing again is a lot, but the common drawback of this class technology is to have destroyed the natural style of fiber, also can produce a large amount of harmful wastewater from chemical industry.A kind of catalysis transfer printing paper with separation layer has been invented by Shanghai Difang Textile Science ﹠ Technology Co., Ltd, granted Chinese utility model patent, and the patent No. is ZL200420022026.8.This cold transfer printing paper with separation layer can be applicable to cellulose fibre, hair and azelon such as silk grade, and on the natural fabric such as cotton, equally also can be used on the synthetic fabrics, not only the transfer printing effect is better, and simple to operation.
Summary of the invention
Realize many shortcomings that the textiles transfer printing is brought in order to solve with sublimation process, now adopt a kind of cold transfer printing paper with separation layer, it is with the carrier of pulullan polysaccharide (Pullulan) class material as dyestuff, it is the union body of dyestuff, in conjunction with other auxiliary formula, by on the fabric wetting moisture, dissolving dye is printed the link stuff in the China ink fast, cooperate the separation layer on the cold transfer printing paper, make cold transfer printing paper at suitable pressures, by fiting of fabric and cold transfer printing paper second interface, realize the new technology of cold-transfer printing.
Patent of the present invention is entitled as cold-transfer printing Paper with carrier and using method, the carrier of used dyestuff, the i.e. union body of dyestuff and using method thereof when being meant a kind of fabric cold transfer printing paper printing.Cold-transfer printing Paper mainly is made of pulullan polysaccharide (Pullulan) class material with carrier, it is characterized in that by the Maltodextrin maltodextrin (starch based) of oligoisomaltose alcohol with DE value≤15%, both mix with the ratio of 1: 4 ± 2 (mass ratioes), by 98% chemical pure propylene oxide (1,2-epoxypropane), capacity is 0.5% of a total amount (1+4 ± 2), and " i.e. 0.005 * (1+4)=0.025 (mass ratio) (convenience of calculation omits ± 2) " is polymerized.The feature of its production technology is by oligoisomaltose pure 1 part (mass ratio) Maltodextrin4 part (mass ratio) with DE value≤15%, both mix with the ratio of 1: 4 ± 2 (mass ratioes), under ℃ condition of low temperature≤30,98% chemical pure slowly instils, capacity is the propane oxide of gross mass 0.5%, 30～40 minutes instillation time, kept above-mentioned cryogenic conditions following three hours, start stirring, make the wetting raw material of propane oxide, be warming up to 50 ℃-60 ℃ and be pasty state just after four hours, etherificate was facilitated in insulation in four hours under 50 ℃ of-60 ℃ of conditions, after the etherificate original state is finished, be warming up under 75 ℃ of conditions and be incubated two hours, be cooled to again below 30 ℃, left standstill 10 hours, treat that polymerisation finishes, pulullan polysaccharide class formation thickener.The cold-transfer printing Paper carrier that pulullan polysaccharide (Pullulan) class formation thickener constitutes, it is a kind of union body of dyestuff, it is the Newtonian fluid of glue-like, and its primary effect is the carrier as colorant (dyestuff or pigment), pulverous colorant dissolved matter is mixed linking up.Secondly as an adhesive, make colorant finally can temporarily anchor on the body paper of undertaking the printing of, under suitable linear pressure,, impel the quick bat printing of the colorant (dyestuff or pigment) that is cured on the cold-transfer printing Paper to fabric then by the wetting link stuff of the finishing agent on the fabric.
In order to guarantee the requirement when the printing of cold-transfer printing Paper and the fabric transfer printing process of carrier that pulullan polysaccharide (Pullulan) class formation thickener become, need add following material during use as the printing adaptability adjustment.Prescription is by mass percentage:
A. cotton type pulullan polysaccharide class formation thickener
Pulullan polysaccharide (Pullulan) class formation thickener is 65%--85%;
Plasticizer can be selected glycerol for use, triethanolamine, and polyethylene glycol is 2%--3%;
Hygroscopic agent is used the pyrrolidone carboxylic acid sodium, is 5%--6%;
Foam inhibitor with phosphoric acid fourth three esters, is 4%--5%;
Adjust to 100% with pure water at last.
B. pure type pulullan polysaccharide class formation thickener
Pulullan polysaccharide class formation thickener is 65%--80%
Ethanol (or isopropyl alcohol) is 20%--35%
The purpose of above-mentioned prescription A is the pliability of regulating pulullan polysaccharide (Pullulan) class formation carrier, good thixotropy is arranged when facilitating printing, promote it and contain damp rate and hydroscopicity, the fragility behind the reduction film-forming, and the foaming phenomenon in prevention and the reduction printing process; The purpose of B be with scribble alcohols barrier transfer printing paper when printing, it is low excessively to solve the paper interfacial free energy, the problem of influence printing printability rate.The mixture of the pulullan polysaccharide class formation thickener that above-mentioned prescription constitutes is fit to fabric cold-transfer printing Paper, mixture and an amount of REACTIVE DYES with this pulullan polysaccharide class formation thickener constitute synthetic colorant, be fit to printing machine and print needs, be printed to cold-transfer printing Paper and can be used for cotton and cellulose base fiber fabric.
The cold-transfer printing Paper that is fit to azelon, a kind of azelon type pulullan polysaccharide class formation thickener.Prescription is by mass percentage:
Cotton type pulullan polysaccharide class formation thickener is 55%--75%;
Urea is 6%--8%;
15% concentration ammonium sulfate is 2%--4%;
Adjust to 100% with pure water at last.
Dye the synthetic colorant of formation with this azelon type pulullan polysaccharide class formation thickener and an amount of acidity, be fit to printing machine and print needs, the cold-transfer printing Paper that is printed to can be used for all kinds of azelon fabrics.
The cold-transfer printing Paper that is fit to nylon fibre, a kind of nylon fibre type pulullan polysaccharide class formation thickener.Prescription is by mass percentage:
Cotton type pulullan polysaccharide class formation thickener is 55%--70%;
15% concentration ammonium sulfate is 5%--8%;
Adjust to 100% with pure water at last.
Receive unrestrainedness (LANASET) dyestuff with this nylon fibre pulullan polysaccharide class formation thickener and an amount of orchid and constitute synthetic colorant, be fit to printing machine and print needs, the cold-transfer printing Paper that is printed to can be used for all kinds of nylon fibre fabrics.
The beneficial effect of patent of the present invention is that the carrier by pulullan polysaccharide class formation thickener is become can be used for cotton, cellulose fibre, azelon and polyamide fiber (nylon fibre) production and the transfer printing process of cold-transfer printing Paper; Pulullan polysaccharide class formation thickener can with REACTIVE DYES, direct dyes, ACID DYES and cation dyes etc. all has excellent compatibility, can electrolyte-resistant; Pulullan polysaccharide class formation thickener belongs to nonionic, and pH value is neutral, as long as adjust viscosity, can adapt to intaglio plate, gentle version, typographies such as relief printing plate and hole version; Because it has water-soluble fast (about 5s), is the crucial materials of cold-transfer printing.The present invention has solved the difficult problem of the rate of transform in the cold transfer process of fabric conscientiously, the perfect in a creative way cold shifting process of fabric.
Description of drawings
Below in conjunction with drawings and Examples patent of the present invention is described further.
Fig. 1 is the technological process of production figure of pulullan polysaccharide (Pullulan) class structure of matter carrier.
The specific embodiment
Embodiment 1
The production technology of (1218 type) pulullan polysaccharide class formation thickener
See shown in Figure 1,
1. be that the Maltodxtrin starch based of 100Kg and DE value≤15% is 400Kg for 4 parts by 1 part of oligoisomaltose alcohol, both mix with the ratio of 1: 4 (mass ratio), put into reactor;
2. under ℃ condition of low temperature≤30,98% chemical pure that slowly instils, capacity are the propane oxide of total amount 0.5%; Promptly 0.005 * (100+400)=2.5Kg propane oxide instiled time 30--40 minute.
3. kept above-mentioned cryogenic conditions following three hours;
4. under the above-mentioned cryogenic conditions, start stirring, make the wetting raw material of propane oxide;
5. be warming up to 50 ℃-60 ℃ after four hours, and be pasty state just;
6. under 50 ℃ of-60 ℃ of conditions, be incubated four hours and facilitate etherificate;
7. after the etherificate original state is finished, be warming up under 75 ℃ of conditions and be incubated two hours;
8. be cooled to below 30 ℃ and left standstill 10 hours, treat that polymerisation finishes.
9. reaction can be emitted from reactor after finishing, (1218 type) pulullan polysaccharide class formation thickener, be a kind of cold-transfer printing Paper with carrier (connecting material).
Embodiment 2
All-cotton fabric cold-transfer printing Paper carrier, a kind of cotton type pulullan polysaccharide class formation thickener.
A. prescription is by mass percentage:
1. pulullan polysaccharide (Pullulan) class formation thickener (1218 type) is 65%--85%;
2. plasticizer can be selected glycerol for use, triethanolamine, and polyethylene glycol is 2%--3%;
3. hygroscopic agent is used the pyrrolidone carboxylic acid sodium, is 5%--6%;
4. foam inhibitor with phosphoric acid fourth three esters, is 4%--5%;
5. adjust to 100% with pure water at last.
Above-mentioned prescription constitutes cotton type pulullan polysaccharide class formation thickener, be fit to cotton cold-transfer printing Paper, constitute synthetic colorant with this cotton type pulullan polysaccharide class formation thickener and an amount of REACTIVE DYES and be fit to printing machine printing needs, the cold-transfer printing Paper that is printed to can be used for all-cotton fabric and cellulose base fiber fabric.
B. prescription is by mass percentage:
1.B the type REACTIVE DYES is golden yellow is 15%;
2. pulullan polysaccharide (Pullulan) class formation thickener (1218 type) is 68%;
3. plasticizer is used glycerol, is 2%;
4. hygroscopic agent is used the pyrrolidone carboxylic acid sodium, is 5%;
5. foam inhibitor is used tributyl phosphate, is 4%;
6. pure water is 6%.
The pulullan polysaccharide class formation thickener (cotton type pulullan polysaccharide class formation thickener) that above-mentioned prescription constitutes and the mixture of dyestuff are fit to cotton cold-transfer printing Paper print production and use.
Embodiment 3
All-cotton fabric cold-transfer printing Paper carrier, a kind of pure type pulullan polysaccharide class formation thickener.
A. pure type Shandong blue polysaccharide structure thickener, prescription is by mass percentage:
1. pulullan polysaccharide class formation thickener 65%--80%;
2. ethanol (or isopropyl alcohol) 20%--35%.
Above-mentioned prescription constitutes pure type pulullan polysaccharide class formation thickener, constitute synthetic colorant with this pure type pulullan polysaccharide class formation thickener and an amount of REACTIVE DYES and be fit to printing machine printing needs, with scribble alcohols barrier transfer paper when printing, the cold-transfer printing Paper that is printed to can be used for all-cotton fabric and cellulose base fiber fabric.
B. prescription is by mass percentage:
1. the REACTIVE DYES Huang is 15%;
2. pulullan polysaccharide class formation thickener is 65%;
3. ethanol (or isopropyl alcohol) is 20%.
The pulullan polysaccharide class formation thickener (pure type pulullan polysaccharide class formation thickener) that above-mentioned prescription constitutes and the mixture of dyestuff are fit to scribble alcohols barrier transfer paper printing usefulness, are fit to cotton cold-transfer printing Paper print production.
Embodiment 4
The cold-transfer printing Paper carrier of azelon, a kind of azelon type pulullan polysaccharide class formation thickener.
A. prescription is by mass percentage:
1. cotton type pulullan polysaccharide class formation thickener is 55%--75%;
2. urea is 6%--8%;
3.15% concentration ammonium sulfate is 2%--4%;
4. adjust to 100% with pure water at last.
The pulullan polysaccharide class formation thickener (azelon type pulullan polysaccharide class formation thickener) that above-mentioned prescription constitutes is fit to all kinds of azelon fabric cold-transfer printing Paper, constitute synthetic colorant with this pulullan polysaccharide class formation thickener and an amount of ACID DYES and be fit to printing machine printing needs, the cold-transfer printing Paper that is printed to can be used for all kinds of azelon fabrics.
B. prescription is by mass percentage:
1. weak acid dye is green is 25%;
2. cotton type pulullan polysaccharide class formation thickener is 55%;
3. urea is 6%;
4.15% concentration ammonium sulfate is 2%;
5. pure water is 12%.
The pulullan polysaccharide class formation thickener (azelon type pulullan polysaccharide class formation thickener) that above-mentioned prescription constitutes and the mixture of dyestuff are fit to all kinds of azelon fabric cold-transfer printing Paper print production and use.
Embodiment 5
The cold-transfer printing Paper carrier of polyamide fiber (nylon fibre) usefulness, a kind of nylon fibre type pulullan polysaccharide class formation thickener.
A. prescription is by mass percentage:
1. cotton type pulullan polysaccharide class formation thickener is 55%--70%;
2.15% concentration ammonium sulfate is 5%--8%;
3. adjust to 100% with pure water at last.
Receive unrestrainedness (LANASET) dyestuff with this pulullan polysaccharide class formation thickener (nylon fibre type pulullan polysaccharide class formation thickener) and an amount of orchid and constitute synthetic colorant, be fit to printing machine and print needs, the cold-transfer printing Paper that is printed to can be used for all kinds of nylon fibre fabrics.
B. prescription is by mass percentage:
Orchid to receive the yellow 4GN of unrestrainedness (LANASET) be 20%;
2. cotton type pulullan polysaccharide class formation thickener is 55%;
3.15% concentration ammonium sulfate is 5%;
4. pure water is 20%.
The pulullan polysaccharide class formation thickener (nylon fibre type pulullan polysaccharide class formation thickener) that above-mentioned prescription constitutes and the mixture of dyestuff are fit to all kinds of nylon fibre fabric cold-transfer printing Paper print production and use.
Claims (5)
1. a carrier for cold transfer printing paper is made up of pulullan polysaccharide class, maltodextrin and propane oxide, it is characterized in that:
Described carrier for cold transfer printing paper by parts by mass is: the pulullan polysaccharide class adopts 1 part of oligoisomaltose alcohol, mix for 4 ± 2 parts with the maltodextrin of DE value≤15%, under ℃ condition of temperature≤30,98% chemical pure propane oxide slowly instils, add propane oxide parts by mass be 0.5% of above-mentioned two component additive quantities, the instillation time is controlled at 30～40 minutes, and keeps 3 hours; After start to stir and make the wetting raw material of propane oxide, be warming up to 50 ℃-60 ℃ after 4 hours, and be pasty state just, etherificate was facilitated in insulation in 4 hours under 50 ℃ of-60 ℃ of conditions; After the etherificate original state is finished, be warming up to 75 ℃, and be incubated 2 hours, be cooled to again below 30 ℃ and left standstill 10 hours, become carrier for cold transfer printing paper after polymerisation finishes, i.e. pulullan polysaccharide class formation thickener.
2. at the using method of the described carrier for cold transfer printing paper of claim 1, it is characterized in that:
Described carrier for cold transfer printing paper should add auxiliary agent when using in carrier, comprise that plasticizer, hygroscopic agent, foam inhibitor and water does the applicability adjustment;
Prescription is by mass percentage:
Carrier for cold transfer printing paper is 65%--85%;
Plasticizer is used glycerol, or triethanolamine, or polyethylene glycol, is 2%-3%;
Hygroscopic agent is used pyrrolidone sodium carboxylate, is 5%--6%;
Foam inhibitor with phosphoric acid fourth three esters, is 4%--5%;
Adjust to 100% with pure water;
Be made into and be suitable for the cotton fiber carrier for cold transfer printing paper.
3. at the using method of the described carrier for cold transfer printing paper of claim 1, it is characterized in that:
Adding ethanol or isopropyl alcohol are done the applicability adjustment in the described carrier for cold transfer printing paper;
Prescription is by mass percentage:
Carrier for cold transfer printing paper is 65%--80%;
Ethanol or isopropyl alcohol are 20%--35%;
Be made into and be suitable for cotton and cellulose fibre carrier for cold transfer printing paper.
4. according to the using method of the described carrier for cold transfer printing paper of claim 2, it is characterized in that:
Described being made into is suitable in the cotton fiber carrier for cold transfer printing paper, adds urea, ammonium sulfate and water and does the applicability adjustment;
Prescription is by mass percentage:
The carrier that described suitable cotton fiber cold transfer printing paper is used is 55%--75%;
Urea is 6%--8%;
The ammonium sulfate of 15% concentration is 2%--4%;
Adjust to 100% with pure water;
Be made into and be suitable for the azelon carrier for cold transfer printing paper.
5. according to the using method of the described carrier for cold transfer printing paper of claim 2, it is characterized in that:
Described being made into is suitable in the cotton fiber carrier for cold transfer printing paper, adds ammonium sulfate and water and does the applicability adjustment;
Prescription is by mass percentage:
Described suitable cotton fiber carrier for cold transfer printing paper is 55%--70%;
The ammonium sulfate of 15% concentration is 5%--8%;
Adjust to 100% with pure water;
Be made into and be suitable for the nylon fibre carrier for cold transfer printing paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610023344XA CN100436705C (en) | 2006-01-16 | 2006-01-16 | Carrier for cold transfer printing paper and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610023344XA CN100436705C (en) | 2006-01-16 | 2006-01-16 | Carrier for cold transfer printing paper and production process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1827907A CN1827907A (en) | 2006-09-06 |
| CN100436705C true CN100436705C (en) | 2008-11-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200610023344XA Active CN100436705C (en) | 2006-01-16 | 2006-01-16 | Carrier for cold transfer printing paper and production process thereof |
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| Country | Link |
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| CN (1) | CN100436705C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102199887B (en) * | 2010-09-28 | 2012-07-11 | 刘静 | Transfer printing method for textile pattern |
| CN102936860A (en) * | 2012-11-16 | 2013-02-20 | 刘静 | Fabric pattern transfer method |
| CN107236483B (en) * | 2017-05-10 | 2019-09-20 | 东莞市雄林新材料科技股份有限公司 | A kind of mesh material and preparation method thereof with transfer belt |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0559450A2 (en) * | 1992-03-04 | 1993-09-08 | Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo | Binder and its uses |
| CN1207755A (en) * | 1995-12-21 | 1999-02-10 | 陶氏化学公司 | Compositions comprising hydroxy-functional polymers |
| CN1230581A (en) * | 1998-10-16 | 1999-10-06 | 沈阳化工研究院 | Chlorosuccinic acid modified starch ether used as dye thickening agent |
| CN1563558A (en) * | 2004-03-15 | 2005-01-12 | 江南大学 | Method for preparing printing paste of compound modified starch with adjustable viscosity |
| CN1654482A (en) * | 2005-02-21 | 2005-08-17 | 汕头市富味制果厂有限公司 | A method for producing pullulan |
-
2006
- 2006-01-16 CN CNB200610023344XA patent/CN100436705C/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0559450A2 (en) * | 1992-03-04 | 1993-09-08 | Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo | Binder and its uses |
| CN1207755A (en) * | 1995-12-21 | 1999-02-10 | 陶氏化学公司 | Compositions comprising hydroxy-functional polymers |
| CN1230581A (en) * | 1998-10-16 | 1999-10-06 | 沈阳化工研究院 | Chlorosuccinic acid modified starch ether used as dye thickening agent |
| CN1563558A (en) * | 2004-03-15 | 2005-01-12 | 江南大学 | Method for preparing printing paste of compound modified starch with adjustable viscosity |
| CN1654482A (en) * | 2005-02-21 | 2005-08-17 | 汕头市富味制果厂有限公司 | A method for producing pullulan |
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|---|---|
| CN1827907A (en) | 2006-09-06 |
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