CN100429781C - Electroluminescent panels with light extraction elements - Google Patents
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Abstract
Description
技术领域 technical field
本发明涉及一种发光或图像显示板,包括有机发光单元(或OLED)的一维或二维矩阵,具有使其易于提取由这些单元所发出的光的装置,这意味着极大地提高了发光效率。The present invention relates to a luminescent or image display panel comprising a one- or two-dimensional matrix of organic light-emitting cells (or OLEDs), with means making it easy to extract the light emitted by these cells, which means greatly improving the luminous efficiency.
背景技术 Background technique
这种板通常包括:基片,支撑插入在两个电极阵列之间的薄有机电致发光层,所述两个电极阵列之一是阳极阵列,而另一个是阴极阵列,用于对单元供电;每个单元位于阳极和阴极之间的重叠区域;在无源矩阵板的情况下,通常由恒定宽度的平行带形式的电极形成每个阵列;阳极阵列的电极通常垂直于阴极阵列的电极;对于多色显示板,尤其是对于三色显示板,通常将有机电致发光层分为不同发光颜色的交替带。Such a board typically consists of a substrate supporting a thin organic electroluminescent layer interposed between two electrode arrays, one of which is an array of anodes and the other an array of cathodes for powering the cells ; each cell is located in the overlapping area between an anode and a cathode; in the case of a passive matrix panel, each array is usually formed by electrodes in the form of parallel strips of constant width; the electrodes of the anode array are usually perpendicular to the electrodes of the cathode array; For multicolor display panels, especially for three-color display panels, the organic electroluminescent layer is usually divided into alternating bands of different emitting colors.
在有源矩阵板的情况下,基片包含用于驱动单元的电子部件,在无源矩阵板的情况下,基片通常由玻璃或塑料制成;基片的厚度通常在300μm和1500μm之间,即比单元的厚度大500到100倍;单元或象素的尺寸或直径通常在100μm和300μm之间,即比基片的厚度小1到15倍;由于在传统的生产工艺中,在电致发光层之前涂覆插入在基片和电致发光层之间的电极层,因此通常将其称为“下层”;将在电致发光层之后涂覆的另一电极层称为“上层”;上电极层的带平行于其至少部分覆盖的电致发光层,并位于该电致发光层的中心。In the case of an active matrix board, the substrate contains the electronic components for the drive unit, in the case of a passive matrix board the substrate is usually made of glass or plastic; the thickness of the substrate is usually between 300 μm and 1500 μm , that is, 500 to 100 times larger than the thickness of the unit; the size or diameter of the unit or pixel is usually between 100 μm and 300 μm, that is, 1 to 15 times smaller than the thickness of the substrate; The electrode layer interposed between the substrate and the electroluminescent layer is coated before the luminescent layer and is therefore often referred to as the "lower layer"; another electrode layer applied after the electroluminescent layer is referred to as the "upper layer" ; the strip of the upper electrode layer is parallel to the electroluminescent layer it at least partially covers and is located in the center of the electroluminescent layer.
根据情况,板所发出的光必须通过基片,以便使要显示的图像到达观察者(在“背发光”板的情况下),或者不必通过基片,而使其到达观察者(在“顶发光”板的情况下)。Depending on the circumstances, the light emitted by the panel must pass through the substrate in order for the image to be displayed to reach the viewer (in the case of a "back-lit" panel), or it does not have to pass through the substrate so that it reaches the observer (in the case of a "top-lit" panel). in the case of "glow" boards).
通常,板所发出的光在通过其中沿观察者的方向进入空气的板的出口面之前,必须通过一个电极阵列,或者为下层(在背发光板的情况下)或者为上层(在顶发光板的情况下);于是,另一层通常是能反射的,以便恢复从单元沿与观察者相反方向出射的光,并将其重新定向为通过板的出口面朝向板的外侧。Typically, the light emitted by the panel must pass through an array of electrodes, either the lower layer (in the case of a back-emitting panel) or the upper layer (in the case of a top-emitting panel), before passing through the exit face of the panel where it enters the air in the direction of the observer. case); the other layer is then usually reflective in order to recover light exiting the cell in the opposite direction to the observer and redirect it through the exit face of the plate towards the outside of the plate.
因此,电极层之一通常是透明的,例如,基于ITO,以便用作阳极,而另一个优选地由吸光甚或是反光的金属制成。Thus, one of the electrode layers is usually transparent, for example based on ITO, in order to serve as an anode, while the other is preferably made of a light-absorbing or even light-reflecting metal.
电致发光层与空气之间较大的折射率差极大地限制了光提取的水平;这是因为在板内,全反射了以大于临界折射角(或全反射角)的入射角到达发射层与空气之间的界面的任何光线,并通常将其损耗。The large refractive index difference between the electroluminescent layer and air greatly limits the level of light extraction; this is because within the panel, total reflections reach the emissive layer at angles of incidence greater than the critical angle of refraction (or total reflection angle). Any light at the interface with air is generally lost.
为了限制这种损耗,参考文献JP10-223367、等价于US2002-0118271的WO 01/33598、以及JP11-354271给出了如何在OLED型板的出口面上涂覆用于提取光的透镜阵列的启示:In order to limit this loss, references JP10-223367, WO 01/33598 equivalent to US2002-0118271, and JP11-354271 show how to coat the exit face of an OLED type plate with a lens array for light extraction Inspiration:
-每个单元一个球透镜,或者每行单元一个柱透镜;- One ball lens per cell, or one cylindrical lens per row of cells;
-或者每个单元多个微透镜。- or multiple microlenses per unit.
在这些参考文献中描述的光提取系统是基于光在单元出口处的折射的,更精确地,单元出口为板的出口面的形式,其具有适当的曲率,从而从单元发出的光线以小于临界折射角的入射角到达此面,以便通过该面。The light extraction systems described in these references are based on the refraction of light at the exit of the cell, more precisely in the form of an exit face of a plate with an appropriate curvature so that the light emitted from the cell is less than the critical The angle of incidence of the angle of refraction reaches this face in order to pass through it.
如US 6 091 384和US 6 229 160等其他参考文献提出了应用于LED或OLED型电致发光板的光提取系统。Other references such as US 6 091 384 and US 6 229 160 propose light extraction systems applied to LED or OLED type electroluminescent panels.
发明内容 Contents of the invention
本发明的目的是提出另一种提取解决方案,不再基于从单元发出的光线的折射,而是本质上基于其反射。The purpose of the present invention is to propose an alternative extraction solution, no longer based on the refraction of the rays emanating from the cell, but essentially on its reflection.
本发明涉及一种发光或图像显示板,包括设置在基片上并至少分为行的有机电致发光单元的一维或二维矩阵,其特征在于对于每个单元或每组单元,其包括光学光提取元件,所述光学光提取元件自身包括:The invention relates to a luminescent or image display panel comprising a one-dimensional or two-dimensional matrix of organic electroluminescent cells arranged on a substrate and divided into at least rows, characterized in that for each cell or group of cells it comprises an optical A light extraction element, the optical light extraction element itself includes:
-入口界面,与所述单元或所述组中的单元或基片的发射表面光学耦合,从而捕获由所述单元发出的光线;- an inlet interface optically coupled to an emitting surface of said cell or cells in said set or substrate, thereby capturing light emitted by said cell;
-出口界面,其形状具有适当的曲率,从而从此入口界面发出的光线在此出口界面处以小于临界折射角的入射角撞击所述出口界面,从而通过所述出口界面;以及- an exit interface, the shape of which has a suitable curvature so that light rays emanating from the entrance interface strike said exit interface at this exit interface at an angle of incidence less than the critical angle of refraction, thereby passing through said exit interface; and
-可选地,中间反射面,具有适当的曲率,从而向所述出口界面发送从所述入口界面发出的、撞击所述中间反射面的光线,从而使其在所述出口界面处具有小于临界折射角的入射角,以便通过所述出口界面。- Optionally, the intermediate reflective surface has a suitable curvature, so as to send the light emitted from the inlet interface and hits the intermediate reflective surface to the outlet interface, so that it has less than a critical The angle of incidence is the angle of refraction in order to pass through the exit interface.
总之,所述板的每个光学光提取元件包括:In summary, each optical light extraction element of the panel consists of:
-入口界面,与所述板的单元或基片的发射表面光学耦合,从而捕获由这些单元发出的光线;- an entrance interface optically coupled to the cells of said plate or to the emitting surface of the substrate so as to capture the light emitted by these cells;
-适当形状的出口界面,从而单元所发出的光线通过该出口界面;以及- an exit interface of suitable shape so that the light emitted by the cell passes through the exit interface; and
-可选地,反射面,修改这些光线的光路,从而减少在该出口界面处的入射角。- Optionally, a reflective surface, modifying the optical path of these rays, thereby reducing the angle of incidence at the exit interface.
在二维单元矩阵的情况下,还将其分组为列;因此,可以每列一个光学提取元件。In the case of a two-dimensional cell matrix, it is also grouped into columns; thus, one optical extraction element per column is possible.
优选地,由具有与光学元件的折射率可比较的折射率的粘接层提供与单元或与基片的光学耦合。Preferably, the optical coupling to the unit or to the substrate is provided by an adhesive layer having a refractive index comparable to that of the optical element.
光学提取元件的材料是透明的;例如,从传统的折射率为1.52的钠钙玻璃、折射率为1.49的聚甲基丙烯酸甲酯或者折射率为1.57的聚对苯二甲酸乙二醇酯中选择;由于此材料具有高于空气且接近电致发光层的折射率,板的单元所发出的光在通过提取元件的入口界面之后,处于比其通过相同形状的空气界面所处的立体角大的立体角,这意味着此光学元件捕获了由单元发出的部分辐射,大于没有此光学其他元件时,直接通过这些单元到达空气的辐射;因此,该光学元件极大地增加了光提取的水平。The material of the optical extraction element is transparent; for example, from conventional soda lime glass with a refractive index of 1.52, polymethylmethacrylate with a refractive index of 1.49, or polyethylene terephthalate with a refractive index of 1.57 Choice; since this material has a refractive index higher than that of air and close to that of the electroluminescent layer, the light emitted by the cells of the plate, after passing through the inlet interface of the extraction element, is in a larger solid angle than it would be through the air interface of the same shape , which means that this optic captures a portion of the radiation emitted by the cells that is greater than the radiation that would pass directly through the cells to the air without the optics; thus, the optic greatly increases the level of light extraction.
根据本发明,对所述光学元件进行特别的设计,从而通过出口界面发出穿透入口界面的几乎全部光线,According to the invention, said optical element is specially designed so that almost all the light rays penetrating the entrance interface are emitted through the exit interface,
-或者通过修改这些光线的朝向,尤其是通过反射,从而使其在出口界面处具有小于临界折射角的入射角,尤其是如果此界面是平坦的且平行于所述基片的表面;- or by modifying the orientation of these rays, in particular by reflection, so that they have an angle of incidence at the exit interface that is less than the critical angle of refraction, especially if this interface is planar and parallel to the surface of the substrate;
-或者通过调整出口界面的形状,尤其是通过赋予其凸形,从而使这些光线在此界面处的入射角小于此界面处的临界折射角;- or by adjusting the shape of the exit interface, in particular by giving it a convex shape, so that the angle of incidence of these rays at this interface is smaller than the critical angle of refraction at this interface;
-或者通过同时采用这两种措施。— or by employing both measures at the same time.
这些措施的采用意味着对于每个光学提取元件,其出口界面的面积大于其入口界面的面积;这种结构能够增加多个单元或象素的发光区域的边缘之间的距离,这是尤为有利的,尤其是在有源矩阵板的情况下;将在稍后展开这一点。The adoption of these measures means that for each optical extraction element, the area of its exit interface is larger than the area of its entrance interface; this structure can increase the distance between the edges of the light-emitting areas of multiple units or pixels, which is particularly advantageous Yes, especially in the case of active matrix boards; will expand on this later.
优选地,对于每个提取元件,如果没有反射表面,或者适当地,所述反射表面,则出口界面不具有平面元件;这是因为非平面曲面最适用于获得最高的光提取水平;如果提取元件具有反射表面,本发明因而延伸到其中出口表面为平坦的情况,与以下所给出的大多数示例相一致。Preferably, for each extraction element, if there is no reflective surface, or suitably said reflective surface, the exit interface has no planar elements; this is because non-planar curved surfaces are best suited to obtain the highest light extraction levels; if the extraction element With reflective surfaces, the invention thus extends to the case where the exit surface is flat, consistent with most of the examples given below.
在提取元件的第一组实施例中,提取元件形成了凸微透镜阵列。In a first group of embodiments of the extraction element, the extraction element forms an array of convex microlenses.
出口元件的凸透镜的形状非常好地适用于从入口界面发出的光线,利用此界面,使得入射角小于此界面为平坦且平行于板的基片的情况;通过减小与空气的界面处的入射角,极大地增加了光提取的水平。The shape of the convex lens of the exit element is very well adapted to the rays emanating from the entrance interface, with which the angle of incidence is smaller than if the interface were flat and parallel to the substrate of the plate; by reducing the incidence at the interface with air angle, greatly increasing the level of light extraction.
每个微透镜的面积大于发光区域或板的象素的面积。The area of each microlens is larger than the area of the light emitting area or pixel of the panel.
可以每个单元一个微透镜,在这种情况下,每个微透镜具有两个对称面,其交点最好位于单元的中心,或者每单元行或每单元列一个微透镜,在这种情况下,每个微透镜具有一个对称面,最好位于单元行或单元列的中心。Either one microlens per cell, in which case each microlens has two planes of symmetry, the intersection of which is preferably at the center of the cell, or one microlens per cell row or cell column, in which case , each microlens has a plane of symmetry, preferably at the center of the cell row or cell column.
本发明的主题是如权利要求中所限定的一种发光或图像显示板,其中提取元件具有反射表面;此反射表面具有适当的形状,从而穿透提取元件的入口界面的任何光线通过此元件的出口界面发出。The subject of the invention is a luminous or image display panel as defined in the claims, wherein the extraction element has a reflective surface; this reflective surface is of such shape that any light rays penetrating the entrance interface of the extraction element pass through the Emitted by the exit interface.
每个光学提取元件的出口界面的形状可以是平面的或曲面的;此形状具有适当的曲率,从而从入口界面直接发出或通过反射表面上的一次或多次反射而发出的光线在出口界面处以小于临界折射角的入射角撞击此出口界面,从而通过此出口界面。The shape of the exit interface of each optical extraction element may be planar or curved; the shape has a suitable curvature so that light emitted directly from the entrance interface or by one or more reflections on a reflective surface is emitted at the exit interface with Angles of incidence less than the critical angle of refraction impinge on the exit interface, thereby passing through the exit interface.
根据提取元件的第二组实施例,其中提取元件具有反射表面,此表面优选地具有适当的形状,从而通过提取元件的入口界面进入的任意光线通过出口界面发出;此条件被表述为“边缘光线”原理,参照题目为“High Collection Nonimaging Optics”的著作第4章第2段,W.T.Wleford & R.Winston,Academic Press,Inc.1989,第54页;优选地,此反射表面具有至少一个对称面,并且此表面与垂直于此对称面的平面的两条交线中的每一条形成了部分抛物线,如该著作第4章第3段所述,尤其是图4.3,其中,与本发明不同,该表面被用作聚能器;该著作中所描述的聚能器的入口面变成了根据本发明的提取元件的出口界面,而该聚能器的出口面变为了入口界面;如该著作第4章第5段所述,两条交线中的每一条形成了连续的抛物线部分;优选地,选择每条交线的抛物线的轴和焦点的位置以及提取元件的厚度L,从而满足该著作在第4章第3段中所给出的条件,具体地,在第56~57页上,从而满足“边缘光线”原理;简而言之,两条交线中的每一条优选地限定了与该著作中所限定的、被称为CPC(复合抛物线聚能器)相一致的反射表面。According to a second set of embodiments of the extraction element, wherein the extraction element has a reflective surface, this surface is preferably of a suitable shape so that any light entering through the entrance interface of the extraction element is emitted through the exit interface; this condition is expressed as "marginal rays "principle, with reference to the book titled "High Collection Nonimaging Optics", Chapter 4, paragraph 2, W.T.Wleford & R.Winston, Academic Press, Inc.1989, page 54; preferably, the reflective surface has at least one plane of symmetry , and each of the two intersections of this surface with a plane perpendicular to this plane of symmetry forms a partial parabola, as described in Chapter 4, paragraph 3 of that work, especially Figure 4.3, where, unlike the present invention, This surface is used as a concentrator; the inlet face of the concentrator described in the work becomes the outlet interface of the extraction element according to the invention, and the outlet face of the concentrator becomes the inlet interface; as in the work As stated in Chapter 4, paragraph 5, each of the two lines of intersection forms a continuous parabolic portion; preferably, the position of the axis and focus of the parabola of each line of intersection and the thickness L of the extraction element are chosen such that the The conditions given in paragraph 3 of chapter 4, in particular, on pages 56-57, so that the "marginal rays" principle is satisfied; in short, each of the two lines of intersection preferably defines A reflective surface consistent with what is defined in this work is called CPC (Compound Parabolic Concentrator).
由于根据本发明,光学提取元件通过反射进行操作,能够提取由单元发出的光的相当高的部分,并获得了具有较高发光效率的板。Since, according to the invention, the optical extraction elements operate by reflection, a considerably high fraction of the light emitted by the cells can be extracted and panels with higher luminous efficiency are obtained.
在不偏离本发明的前提下,可以使用其他形状的反射表面,如其中上述两条交线将具有相同轴的圆锥形或抛物线形。Other shapes of reflective surfaces may be used without departing from the invention, such as conical or parabolic in which the two lines of intersection described above will have the same axis.
反射表面因而形成了反射器;可以每个单元一个反射器,在这种情况下,每个反射器优选地具有两个对称面,通常为相互垂直的,其交线通过单元的中心;可以每个单元行或单元列一个反射器,在这种情况下,每个反射器具有位于行或列的中心的单一对称面。The reflective surfaces thus form reflectors; there may be one reflector per unit, in which case each reflector preferably has two planes of symmetry, usually mutually perpendicular, the intersection of which passes through the center of the unit; Each unit row or unit column has one reflector, in which case each reflector has a single plane of symmetry at the center of the row or column.
本发明还应用于以下情况:其中每个提取元件具有透镜形状的出口界面和反射表面;优选地,此反射表面为上述CPC型表面,在上述著作的第5章第8段中给出了这种元件的示例。The invention also applies to the case where each extraction element has a lens-shaped exit interface and a reflective surface; preferably, this reflective surface is the above-mentioned CPC type surface, which is given in Chapter 5, paragraph 8 of the above-mentioned work An example of a component.
在变体中,提取元件还用于对准光;对于每个提取元件,出口界面和/或,在适当的情况下,反射表面具有适当的形状,从而位于出口界面的光线处于严格小于2π球面度的立体角;于是,出口界面的形状和/或反射表面的形状有利地适用于沿空间的有限区域的方向,尤其是倾向于要显示的图像的观察者的方向,限制由板发出的光线;因此,无需其它成本地、极大地改善了板的效率。In a variant, the extraction elements are also used to collimate the light; for each extraction element, the exit interface and/or, where appropriate, the reflective surface is of a shape such that the light rays lying at the exit interface lie on a spherical surface strictly smaller than 2π degrees; thus, the shape of the exit interface and/or the shape of the reflective surface is advantageously adapted to limit the light emitted by the plate in the direction of a limited area of space, especially towards the viewer of the image to be displayed ; Therefore, without additional costs, the efficiency of the board is greatly improved.
优选地,板的光线提取元件构成形成了提取层的单一部分。Preferably, the light extraction elements of the plate constitute a single part forming the extraction layer.
于是,此部分集合所有透镜或抛物线反射型或其他光提取元件;这种结构尤为有利,因为对于提取元件的生产及其在板上的组装都较为便宜,由于在单一操作中,能够将所有提取元件定位在板的多个单元上;此外,可以使用提取层来保护板的单元,尤其是防止其与环境水和/或氧气的反应。This part then aggregates all lenses or parabolic reflective or other light extraction elements; this structure is particularly advantageous because it is less expensive to manufacture the extraction elements and to assemble them on the board, since in a single operation all extraction The elements are positioned on the cells of the board; moreover, an extraction layer can be used to protect the cells of the board, in particular against their reaction with ambient water and/or oxygen.
如果提取元件由塑料制成,则可以通过如压模或注模等传统的速率转换方法非常便宜地生产此单一部分。If the extraction element is made of plastic, this single part can be produced very cheaply by conventional rate conversion methods such as compression molding or injection molding.
通常,单元矩阵包括位于两个电极阵列层之间的电致发光层,两个电极阵列层之一被称为“下”层,位于面向基片侧,而另一个被称为“上”层,位于另一侧,每个单元位于下层电极和上层电极之间的重叠区域;该板可以包括其他电极阵列,尤其是在有源矩阵板的情况下。Typically, the cell matrix includes an electroluminescent layer between two electrode array layers, one of which is referred to as the "lower" layer, on the side facing the substrate, and the other, referred to as the "upper" layer , on the other side, each cell is located in the overlapping area between the lower and upper electrodes; the board may include other arrays of electrodes, especially in the case of active matrix boards.
当上层电极是透明或半透明的时,则将板称为“顶发光”板;于是,将提取元件定位在该上层的顶部;优选地,根据第一或第二组实施例,提取元件构成单一部分,形成提取层,并形成相对于基片密封的封装层,从而防止如氧气或水蒸气等气体侵入单元,从而防止了电致发光层受到这些气体的损坏的危险;这样进行封装的空间可以包括能够吸收这些气体的吸附剂或干燥剂。When the upper electrode is transparent or translucent, the plate is then referred to as a "top-emitting" plate; the extraction element is then positioned on top of this upper layer; preferably, according to the first or second set of embodiments, the extraction element constitutes A single part, forming the extraction layer and forming the encapsulation layer sealed relative to the substrate, thereby preventing the intrusion of gases such as oxygen or water vapor into the cell, thereby preventing the electroluminescent layer from being damaged by these gases; the space for encapsulation Adsorbents or desiccants capable of absorbing these gases may be included.
优选地,将此干燥剂放置在沿提取层的厚度方向构成的孔中,所述孔沿电致发光层的方向向板的内部开口,并位于提取元件之间,从而使吸附剂并不阻碍光的通过。Preferably, this desiccant is placed in pores formed in the thickness direction of the extraction layer, which open towards the interior of the plate in the direction of the electroluminescent layer, and are located between the extraction elements, so that the adsorbent does not hinder the passage of light.
当下层电极是透明或半透明的时,则将板称为“背发光”板;于是,将提取元件定位在基片与下层相对的相对面上。When the underlying electrode is transparent or translucent, the panel is referred to as a "back-emitting" panel; the extraction element is then positioned on the opposite side of the substrate from the underlying layer.
优选地,此时,提取层本身形成了板的基片;考虑到板的制造,于是,在提取层上、在入口界面侧设置多个层,尤其是电极层和电致发光材料层,这些层构成了二维板单元矩阵;于是,提取层优选地由玻璃制成。Preferably, at this time, the extraction layer itself forms the substrate of the plate; considering the manufacture of the plate, then, on the extraction layer, on the side of the inlet interface, a plurality of layers, especially electrode layers and layers of electroluminescent material, are arranged, these The layers constitute a two-dimensional matrix of plate cells; thus, the extraction layer is preferably made of glass.
根据本发明的变体,基片具有纤维状结构,其纤维适用于从所述基片的一面向另一面导引光。According to a variant of the invention, the substrate has a fibrous structure, the fibers of which are adapted to guide light from one side of said substrate to the other.
每个提取元件的入口界面可以覆盖单元组,尤其是单元行,或者如果矩阵是二维的,例如单元列;在这种情况下,每个提取元件优选地具有位于此单元组、单元行或单元列的中心的对称面。The entry interface of each extraction element may cover a cell group, especially a cell row, or if the matrix is two-dimensional, such as a cell column; in this case, each extraction element preferably has an The plane of symmetry at the center of the cell column.
优选地,此组的每个单元发出相同原色的光;换句话说,则每个单元组对应于发出相同颜色光的单元。Preferably, each cell of the group emits light of the same primary color; in other words, each group of cells then corresponds to cells emitting light of the same color.
另一方面,每个提取元件的入口界面可以覆盖单一的单元;在这种情况下,每个提取元件优选地具有两个对称面,其交线通过此单元的中心;在具有二维单元矩阵的板的情况下,则提取元件形成二维阵列。On the other hand, the inlet interface of each extraction element may cover a single cell; in this case, each extraction element preferably has two planes of symmetry, the intersection of which passes through the center of the cell; In the case of a plate, the extracted elements form a two-dimensional array.
在本发明的变体中,提取元件的表面密度可以大于单元组或板单元的表面密度。In a variant of the invention, the surface density of the extraction elements may be greater than the surface density of the unit pack or plate unit.
在无源矩阵板的情况下,阵列电极优选地为恒定宽度的平行导体带的形式;于是,优选地,将电致发光层分为发出不同原色光的平行带,并以交替的方式排列;于是,优选地,上层的每个电极带平行于电致发光层带,并位于电致发光层带的中心。In the case of a passive matrix panel, the array electrodes are preferably in the form of parallel conductor strips of constant width; then, preferably, the electroluminescent layer is divided into parallel strips emitting light of different primary colors and arranged in an alternating manner; Then, preferably, each electrode strip of the upper layer is parallel to the strip of the electroluminescent layer and is located in the center of the strip of the electroluminescent layer.
但是,本发明在其中板的基片形成有源矩阵的情况下尤为有利;这是因为为了集成有源矩阵和电致发光板,经常需要限制专用于每个单元的电致发光的面积;在使用根据本发明的光提取元件时,这种限制不再是缺点。However, the invention is particularly advantageous in the case where the substrate of the panel forms an active matrix; this is because in order to integrate active matrix and electroluminescent panels it is often necessary to limit the area dedicated to the electroluminescence of each cell; in This limitation is no longer a disadvantage when using the light extraction element according to the invention.
最后,本发明尤其应用于图像显示板。Finally, the invention applies in particular to image display panels.
附图说明 Description of drawings
通过阅读以下作为非限制性示例并参照附图给出的描述,将更为清楚地理解本发明,其中:The invention will be more clearly understood by reading the following description given as a non-limiting example with reference to the accompanying drawings, in which:
-图1和图2示出了在应用根据本发明的光提取层之前的背发光电致发光板,分别为具有隔板和不具有隔板;- Figures 1 and 2 show back-emitting electroluminescent panels, respectively with and without spacers, before application of a light extraction layer according to the invention;
-图3和图4示出了在应用根据本发明的光提取层之前的顶发光电致发光板,分别为具有隔板和不具有隔板;- Figures 3 and 4 show top-emitting electroluminescent panels, respectively with and without spacers, before the application of the light extraction layer according to the invention;
-图5到图9以侧视图或剖视图以及后视图和正视图示出了不具有隔板的顶发光板,其具有其中光提取元件为微透镜形式的第一组实施例的光提取元件:图5示出了一般情况;图6示出了其中将渐变折射率板用作提取层的情况;图7和图8示出了平行于行或列放置长透镜的情况;以及图9示出了由二维透镜矩阵形成提取层的情况;- Figures 5 to 9 show a top luminescent panel without partitions, in side or cross-sectional views and in rear and front views, with light extraction elements of a first group of embodiments wherein the light extraction elements are in the form of microlenses: Figure 5 shows the general case; Figure 6 shows the case where a graded-index plate is used as the extraction layer; Figures 7 and 8 show the case where long lenses are placed parallel to the rows or columns; and Figure 9 shows The case where the extraction layer is formed by a two-dimensional lens matrix;
-图11以剖面示出了不具有隔板的背发光电致发光板,其具有根据光提取元件的第二组实施例的、反射器形式的光提取元件;- Figure 11 shows in section a back-emitting electroluminescent panel without partitions, with light extraction elements in the form of reflectors according to a second set of embodiments of light extraction elements;
-图10和图12到图14以侧视图或剖视图以及后视图和正视图示出了不具有隔板的顶发光板,其具有根据第二组实施例的反射器形式的光提取元件:图10示出了一般情况;图12和13分别示出了平行于行或列放置长反射器的情况;以及图14示出了由二维反射器矩阵形成提取层的情况;- Figure 10 and Figures 12 to 14 show a top luminous panel without partitions in side or section view and in rear and front views, with light extraction elements in the form of reflectors according to a second set of embodiments: Fig. 10 shows the general case; Figures 12 and 13 show the case where long reflectors are placed parallel to the rows or columns, respectively; and Figure 14 shows the case where the extraction layer is formed by a matrix of two-dimensional reflectors;
-图15和16示出了背发光电致发光板的剖面图,其基片由用作光导的纤维制成,以便使光通过,其分别具有反射器和微透镜;以及- Figures 15 and 16 show cross-sectional views of back-emitting electroluminescent panels, the substrate of which is made of fibers used as light guides for the passage of light, with reflectors and microlenses, respectively; and
-图17示出了在涂覆光提取层之前的有源矩阵电致发光板的顶视图。- figure 17 shows a top view of an active matrix electroluminescent panel before coating of a light extraction layer.
具体实施方式 Detailed ways
为了简化描述以及阐明本发明与现有技术相比的区别和优点,将使用相同的参考数字来表示实现相同功能的元件。In order to simplify the description and to clarify the differences and advantages of the present invention compared with the prior art, the same reference numerals will be used to denote elements performing the same functions.
因此,根据本发明的板包括:Thus, a board according to the invention comprises:
-二维有机电致发光单元矩阵,设置在基片上,并将其分为行或列;以及- a matrix of two-dimensional organic electroluminescent cells arranged on a substrate and divided into rows or columns; and
-光提取元件,设置在每个单元或单元行或单元列上,形成提取层。- A light extraction element, arranged on each cell or cell row or cell column, forming an extraction layer.
首先,将参照图1到图4,对在无源矩阵板的情况下,不包括专用于本发明的提取层的板的制造进行描述。First, the manufacture of a panel that does not include an extraction layer dedicated to the present invention in the case of a passive matrix panel will be described with reference to FIGS. 1 to 4 .
可以使用多种传统方法在基片上连续沉积阵列形式的下层电极、通常包括发出不同颜色光的交替带的电致发光层以及阵列形式的上层电极:例如,可以使用光刻、利用遮蔽掩模的真空沉积、旋涂沉积和/或喷墨印刷。The lower electrode in the form of an array, the electroluminescent layer usually comprising alternating bands emitting light of different colors, and the upper electrode in the form of an array can be successively deposited on the substrate using a variety of conventional methods: for example, photolithography, Vacuum deposition, spin-on deposition and/or inkjet printing.
由上可见,可以对两类板加以区分:即,更为普通的背发光,即,光通过基片,从而通过下层电极;以及顶发光,即光通过上层电极。As can be seen above, a distinction can be made between two types of panels: namely, the more general back-emitting, ie light passes through the substrate and thus the lower electrode, and top-emitting, ie light passes through the upper electrode.
对于这两种类型中的每一种,传统上,两类结构是可能的,即,在上层电极带与电致发光层带之间具有分离的隔板的结构,和不具有分离的隔板的结构;通常通过采用遮蔽掩模的沉积方法来生产不具有分离的隔板的机构。For each of these two types, two types of structures are conventionally possible, namely, structures with a separate spacer between the upper electrode strip and the electroluminescent layer strip, and structures without a separate spacer structures; structures without separate spacers are typically produced by deposition methods using shadow masks.
分离的隔板的优点在于其提供了单元的行或列之间更好的电隔离;其缺点在于其需要额外的成本。The advantage of separate spacers is that they provide better electrical isolation between rows or columns of cells; the disadvantage is that they require additional cost.
因此,通常将遇到四种板类型,现在,将更为详细地分别进行描述。Thus, four board types will generally be encountered and each will now be described in more detail.
在具有隔板的背发光板的情况下,图1示出了由玻璃板形成的基片100,在其上沉积基于ITO(氧化铟锡)的透明下层,然后,对透明下层进行刻蚀,以形成带状透明电极101;在有源矩阵的情况下,将代替地刻蚀矩形透明电极;接下来,沉积电隔离层102,为每个电致发光单元留下空间或间隙,在此情况下,形状为矩形;将平行于下层电极101并与其方向垂直的线形分离的隔板105放置在隔离层102中的间隙或空间之间;在US 5 701 055(PIONEER)中描述了生产隔板的可能方法;这些隔板由绝缘材料制成,优选地,等同于隔离层102的材料;沉积在隔板105之间以及隔离层102中的每个间隙或空间中的是有机电致发光层形成带103,通常以几个子层的形式构造所述有机电致发光层103本身,所述几个子层尤其包括有机空穴注入子层、有机电致发光子层以及电子注入子层;为了沉积这些有机子层,例如,采用真空工艺;为了获得不同颜色的交替带,通过掩模与其他颜色相对应的隔板间区域来沉积每种颜色;接下来,在有机电致发光带103的上方沉积通常为不透明并优选地为反光的电极带104;这里,同样可以按照几个子层的形式构造这些带,例如,基于氟化锂(LiF)的子层和基于铝的子层,其提供了反射效果;按照这种方式,获得具有隔板的背发光板。In the case of a backlight panel with spacers, Fig. 1 shows a substrate 100 formed from a glass plate, on which a transparent lower layer based on ITO (Indium Tin Oxide) is deposited and then etched, to form strip-shaped transparent electrodes 101; in the case of an active matrix, a rectangular transparent electrode would be etched instead; next, an electrical isolation layer 102 is deposited, leaving a space or gap for each electroluminescent cell, in this case Next, rectangular in shape; line-shaped separators 105 parallel to the lower electrode 101 and perpendicular to its direction are placed between the gaps or spaces in the isolation layer 102; the production of separators is described in US 5 701 055 (PIONEER) possible method; these spacers are made of an insulating material, preferably, the same material as the isolation layer 102; deposited between the spacers 105 and in each gap or space in the isolation layer 102 is an organic electroluminescent layer Forming the strips 103, the organic electroluminescent layer 103 itself is generally structured in the form of several sublayers comprising, inter alia, an organic hole-injection sublayer, an organic electroluminescent sublayer and an electron-injection sublayer; for deposition These organic sublayers are, for example, employed in a vacuum process; in order to obtain alternating bands of different colors, each color is deposited by masking the inter-spacer regions corresponding to the other colors; next, above the organic electroluminescent bands 103 Usually opaque and preferably reflective electrode strips 104 are deposited; here, too, these strips can be structured in the form of several sublayers, for example a sublayer based on lithium fluoride (LiF) and a sublayer based on aluminum, which provides Reflection effect; in this way, a backlit panel with partitions is obtained.
在不具有隔板的背发光板的情况下,图2示出了通过玻璃片形成的基片100,在其上,与先前一样,沉积带状透明电极101;利用掩模或一组掩模-每种颜色一个,沉积其结构和成分等同于上述结构和成分的有机电致发光层带103;这些带103平行,其朝向与下层电极101垂直,并对其进行排列从而覆盖单元的矩形区域;接下来,通过位于电致发光带103上方的具有较窄孔径的掩模,沉积等同于上述的电极带104;按照这种方式,获得不具有隔板的背发光板。In the case of a backlight without spacers, Fig. 2 shows a
在具有隔板的顶发光板的情况下,参照图3,所采用的工艺与已经描述的具有隔板的背发光板的情况相同,其中颠倒现在属于上层的透明电极101的位置和现在属于下层的不透明电极104的位置。In the case of a top luminous panel with spacers, referring to Figure 3, the process used is the same as already described in the case of a back luminous panel with spacers, where the position of the
在不具有隔板的顶发光板的情况下,参照图4,所采用的工艺与已经描述的不具有隔板的背发光板的情况相同,其中颠倒现在属于上层的透明电极101的位置和现在属于下层的不透明电极104的位置。In the case of a top luminous plate without spacers, referring to FIG. 4 , the process used is the same as already described in the case of a back luminous plate without spacers, in which the position of the
在不偏离本发明的前提下,可以使用用于获得二维有机电致发光单元矩阵的其他传统工艺,尤其是在有源矩阵的情况下。Other conventional processes for obtaining a matrix of two-dimensional organic electroluminescent cells, especially in the case of active matrices, may be used without departing from the invention.
作为示例,现在将对两组光提取元件进行描述,在每个单元或每个单元行或单元列上沉积:As an example, two sets of light extraction elements will now be described, deposited on each cell or each cell row or cell column:
-微透镜20型的提取元件;- Extraction elements of the
-抛物线反射器30型的提取元件。- Extraction elements of the
图5示出了沉积在如上参照图4所述的顶发光电致发光板上的微透镜20形式的提取元件;在板的每个单元、或每个单元行或单元列处,每个微透镜20包括:Figure 5 shows extraction elements in the form of
-孔径为LE的入口界面21,与此单元或此行或此列单元的发光面光学耦合,从而捕获从电致发光层103发出的通过透明电极101的发出光线;以及- an
-较宽孔径LS的出口界面23,其形状具有适当的曲率,从而从入口界面21发出的光线,如图中的实线箭头所示,在此出口界面23处,以小于临界折射角的入射角撞击此出口界面23。- the
由于该透镜元件20,极大地改善了对单元所发出的光的提取。Thanks to this
优选地,提取元件的集合构成单一部分,并形成提取层200;此提取层可以由透明的聚合物材料制成,其能够通过压模或注模较为便宜地形成该提取层;此提取层可以通过粘接而与板结合;于是,中间粘接层(未示出)用作与板进行光耦合的装置。Preferably, the collection of extraction elements forms a single part and forms the
图6示出了其中提取层200’具有均匀厚度并包含按照与上述光学提取元件相同的方式作用的渐变折射率区域20’的变体。Figure 6 shows a variant in which the extraction layer 200' has a uniform thickness and contains graded index regions 20' which function in the same way as the optical extraction elements described above.
图7到图9示出了与提取元件的微透镜的形状有关的其他变体:Figures 7 to 9 show other variants related to the shape of the microlenses of the extraction elements:
-图7B:每个提取元件20L具有对称面,用作图7A所示的板的单元行,并位于此板的透明电极行101的中心;- FIG. 7B : each extraction element 20L has a plane of symmetry, serves as a cell row of the plate shown in FIG. 7A and is located in the center of the
-图8B:每个提取元件20C具有对称面,用作图8A所示的板的单元列,并位于此板的不透明电极列104的中心;以及- FIG. 8B : each extraction element 20C has a plane of symmetry, serves as a column of cells of the plate shown in FIG. 8A and is located in the center of the column of
-图9B:每个提取元件20P具有位于图9A所示的透明行电极101和不透明列电极104处的单元的中心的对称轴,并实质上用于此单元。- FIG. 9B : each extraction element 20P has an axis of symmetry located in the center of the unit at the
其中提取元件为微透镜形式的这些实施例也应用于不具有隔板的背发光电致发光板,如参照图2所示的那些;提取层200与基片100的表面进行光学耦合;因为基片的厚度,通常在0.3和1.5mm之间,并且比单元或象素的尺寸或直径大,甚或大得多,所以由提取层捕获的光量小于前一种顶发光板的情况;通过将提取层200用作基片,优选地,采用如图6所示的渐变折射率提取层200’来避免此缺点。These embodiments in which the extraction elements are in the form of microlenses also apply to back-emitting electroluminescent panels without spacers, such as those shown with reference to FIG. 2; the
微透镜或提取层形式的提取元件的厚度在光提取的水平、所需的会聚或对准水平(见下文)、机械强度和想要提供给板的保护水平之间进行折中。The thickness of the extraction elements in the form of microlenses or extraction layers is a compromise between the level of light extraction, the level of concentration or alignment required (see below), mechanical strength and the level of protection one wants to provide to the plate.
图10描述了上述“CPC”型抛物线反射器30形式的提取元件,设置在参照图4所示的不具有隔板的顶发光电致发光板上。FIG. 10 depicts an extraction element in the form of a
在板的每个单元、或每单元行或单元列处,每个抛物线反射器30包括:At each cell of the panel, or per cell row or cell column, each
-孔径为LE的入口界面31,与此单元10R、10G、10B或此行中或此列中的单元的发光表面进行光学耦合,从而捕获从这些单元发出的光线;- an
-反射表面32,具有适当的曲率,从而向出口界面33发送从入口界面31发出的、撞击在所述反射表面上的光线,从而在此出口界面处,具有小于临界折射角的入射角,以便通过此出口界面;- a
-较宽孔径LS的出口界面33,在这种情况下,其形式为平面。- The
从入口界面31发出的光线,如图10中的实线箭头所示,在此出口界面33处,以小于临界折射角的入射角撞击此出口界面33,以便通过该出口界面33。The light emitted from the
优选地,提取元件的集合构成单一件,并形成提取层300;优选地,此提取层由透明聚合物材料制成,并通过压模或注模形成。Preferably, the collection of extraction elements constitutes a single piece and forms the
优选地,通过对此层表面上必须反光的区域进行敷铝来形成反射表面32;在一种变体中,通过全反射来提供这种反射。The
利用具有接近于材料的折射率的透明粘结剂层来实现入口界面处的光学耦合;但是,通过以粘结剂涂覆提取层的入口界面31,存在将粘结剂涂覆到反射表面32上的危险,如果反射是通过全反射来提供的,则将是尤为不利的;对反射表面32进行敷铝避免了这种缺点。Optical coupling at the entrance interface is achieved with a transparent adhesive layer having a refractive index close to that of the material; however, by coating the
由于这种反射器元件30,极大地改善了对由板的单元发出的光的提取。Thanks to this
图11示出了其中将包括等同于前述反射器的反射器30在内的提取层300’设置在如先前参照图2所示的不具有隔板的背发光电致发光板上的变体;此变体的不同之处还在于提取元件的密度比先前大得多-事实上,具有单元或单元列甚或单元的数目的两倍的提取元件;此变体的不同之处还在于其包括设置在基片100和提取层300’之间、在相邻提取元件的入口界面31之间的反射器元件阵列28;此反射器元件阵列28使其能够进一步提高提取效率,如图中所示的光线的路径所示。Figure 11 shows a variant in which an extraction layer 300' comprising a
图12到14示出了与提取器元件的反射器的形状有关的其他变体;Figures 12 to 14 show other variants related to the shape of the reflector of the extractor element;
-图12B:每个提取元件30L具有对称面,用作图12A所示的板的单元行,并位于此板的透明电极行101的中心;- FIG. 12B : each extraction element 30L has a plane of symmetry, serves as a cell row of the plate shown in FIG. 12A and is located in the center of the
-图13B:每个提取元件30C具有对称面,用作图13A所示的板的单元列,并位于此板的不透明电极列104的中心;以及- FIG. 13B : each extraction element 30C has a plane of symmetry, serves as a column of cells of the plate shown in FIG. 13A and is located in the center of the column of
-图14B:每个提取元件30P具有位于图14A所示的透明行电极101和不透明列电极104处的单元的中心的对称轴,并实质上用于此单元。- Fig. 14B: each extraction element 30P has an axis of symmetry located in the center of the unit at the
由上可见,刚刚描述的两组光提取元件可应用于背发光提取板,具有由提取层捕获的光量小于前一种顶发光板的情况的缺点;避免此缺点的一种方式在于使用基于纤维(光纤)的板的形式的基片100”,其纤维106与此板的法面正交,并适用于将光沿最短的可能光路从此板的一面导引向另一面。As can be seen above, the two sets of light extraction elements just described can be applied to back-emitting extraction panels, with the disadvantage that the amount of light captured by the extraction layer is smaller than in the case of the former top-emitting panels; one way of avoiding this disadvantage is to use fiber-based A substrate 100'' in the form of a plate (of optical fibers) with
图15和16示出了本实施例的两种变体,分别为由反射器30形成提取层300的情况,以及由微透镜20形成提取层200的情况。15 and 16 show two variants of this embodiment, respectively the case where the
将单一部分200、300形式的提取层与此类基片100”一起使用的优点在于其提供了对板单元的非常好的密封和非常好的保护,因为其基于纤维(光纤)的结构将使其易于渗水和透气,只通过基片将不足以防护水和氧气;事实上,已知电致发光层103的有机材料在水或氧气的作用下会快速退化。The advantage of using an extraction layer in the form of a
通常,在将其制成单一部分时,提取层可以有利地用作封装层,以便实质上改善单元对环境氧气或环境水的防护;此优点尤其可以应用于顶发光板的情况,无论提取元件属于第一和/或第二组实施例。In general, the extraction layer can advantageously be used as an encapsulation layer when it is made in a single part, so as to substantially improve the protection of the unit from ambient oxygen or ambient water; this advantage can especially be applied in the case of top-emitting panels, regardless of the extraction element Belonging to the first and/or second group of embodiments.
已经参照不具有隔板的有机电致发光板,对本发明进行了描述;其也可以应用于如上述图1和图3所示的具有隔板的板;在顶发光板的情况下,通常小于10μm的隔板高度不会成为将光提取元件应用于反射器的阻碍,由于反射器的曲率使其能够保持远离隔板。The invention has been described with reference to organic electroluminescent panels without spacers; it can also be applied to panels with spacers as shown in Figures 1 and 3 above; in the case of top-emitting panels, typically less than The spacer height of 10 μm is not a hindrance for applying the light extraction element to the reflector, which can be kept away from the spacer due to the curvature of the reflector.
已经参照针对第一组实施例的微透镜形式的出口界面形状和针对第二组实施例的抛物线形式的反射表面形状,对两组光提取元件进行了描述,但也可以使用其他几何形状。对于第一组的出口界面和第二组的反射表面,优选的是采用对提取更为有效的曲面,而不采用具有平面区域的表面。Two sets of light extraction elements have been described with reference to exit interface shapes in the form of microlenses for the first set of embodiments and reflective surface shapes in the form of parabolas for the second set of embodiments, but other geometries may also be used. For the first set of exit interfaces and the second set of reflective surfaces, it is preferred to use curved surfaces that are more efficient for extraction, rather than surfaces with flat areas.
在本发明的一般变体中,光提取装置还适用于减小板的发光锥的孔径,从而将其限制在位于板前方的空间区域,尤其是用于观察要显示的图像的区域;按照众所周知的方式调整提取元件的出口界面23、33的几何形状和/或发射表面32的几何形状,以便获得这种会聚效果。In a general variant of the invention, the light extraction means are also adapted to reduce the aperture of the luminous cone of the panel, thereby confining it to the area of space located in front of the panel, in particular for viewing the image to be displayed; according to the well-known The geometry of the
可见,利用如上所述的光提取装置,每个提取元件提供了比相应单元的发射孔径LE大得多的出口孔径LS;在没有会聚效果时,比值LS/LE优选地大约为4,在具有会聚效果时,该比值LS/LE大于4。由于本发明,可以实质上减少每个单元中的电致发光层的实际发光面积,而不会引起板内总光通量的损失;这是因为通过增加光提取水平弥补了每个单元实际发光面积的缩减。It can be seen that, with a light extraction arrangement as described above, each extraction element provides an exit aperture L S much larger than the emission aperture L E of the corresponding cell; in the absence of converging effects, the ratio L S /L E is preferably approximately 4. When there is convergence effect, the ratio L S /L E is greater than 4. Thanks to the invention, it is possible to substantially reduce the actual light-emitting area of the electroluminescent layer in each cell without causing a loss of the total luminous flux in the panel; this is because the increase in the level of light extraction compensates for the increase in the actual light-emitting area of each cell. reduce.
在有源矩阵板的情况下,每个单元实际发光面积的缩减尤为有利,因为在这类板中,在每个单元处,在板的基片上刻蚀了多个用于驱动单元的电子元件,并插入其中;现在,这些元件可能较大,导致了对每个单元实际发光面积的限制;在采用根据本发明的光提取装置时,此限制不再成为阻碍。The reduction of the actual light-emitting area per cell is particularly advantageous in the case of active matrix boards, where, at each cell, multiple electronic components for driving the cells are etched on the substrate of the board , and inserted therein; now, these components may be large, resulting in a limitation on the actual light-emitting area per unit; this limitation is no longer a hindrance when employing the light extraction device according to the invention.
图17示出了有源矩阵电致发光板的三个相邻单元10R、10G、10B,其中每一个均包括:一个与存储部件304相连的下层电极,以及由固态透明或半透明传导层形成在此处的上层单一电极(未示出);尽管下层电极必须彼此分离,相反,对于上层,单一的电极可能就足够了;此时,由下层电极与单一上层电极的重叠区域来限定每个单元的发光面积,而与先前描述的无源矩阵的情况不同,不是由上层电极与下层电极之间的交点来限定;有利地,可以选择有源矩阵板的每个单元的下层电极的面积,从而对应于根据本发明的提取元件的入口界面。Figure 17 shows three
如果通过利用遮蔽掩模或喷墨印刷的沉积方法产生二维单元矩阵,尤其是电致发光层和上层电极,本发明将尤为有利;这是因为由于本发明能够缩减单元的发光面积、分隔电极的距离,因此可以增加用于沉积板的多层子层的掩模的图案宽度;这种具有较宽图案的掩模非常易于定位;因此,在其制造通常采用遮蔽掩模方法或喷墨印刷方法的不具有隔板的板的情况下,本发明尤为有利。The invention is particularly advantageous if a two-dimensional matrix of cells, especially the electroluminescent layer and upper electrodes, is produced by deposition methods using shadow masks or inkjet printing; distance, thus increasing the pattern width of the mask used to deposit multiple sub-layers of the plate; such a mask with a wider pattern is very easy to position; therefore, in its fabrication usually a shadow mask method or inkjet printing The invention is particularly advantageous in the case of a plate of the method without partitions.
本发明还应用于其单元具有光致发光转换器元件的电致发光板的情况,例如,如参考文献US 51216214所述;在这种板中,所有单元的电致发光层发出相同颜色的光,例如,蓝色;设置在电致发光层上方的红色和绿色单元中的是在蓝光的激发下分别发出红光和绿光的光致发光元件;在变体中,可以增加滤光层,尤其是针对蓝光。在这类板的制造中,有利的是在提取元件或提取层上生产光致发光元件;为此目的,可以在提取元件的入口界面处形成孔,并且可以将光致发光材料沉积在这些孔中;接下来,如前所述,将提取元件或提取层粘接在基层电致发光板上。The invention also applies in the case of electroluminescent panels whose cells have photoluminescent converter elements, as described, for example, in reference US 51216214; in such panels, the electroluminescent layers of all cells emit light of the same color , for example, blue; arranged in the red and green units above the electroluminescent layer are photoluminescent elements that emit red and green light respectively under excitation of blue light; in variants, a filter layer can be added, Especially for Blu-ray. In the manufacture of such plates it is advantageous to produce photoluminescent elements on the extraction element or extraction layer; for this purpose holes can be formed at the inlet interface of the extraction element and photoluminescent material can be deposited in these holes Middle; Next, as previously described, the extraction element or extraction layer is bonded to the base electroluminescent plate.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0202476A FR2836584B1 (en) | 2002-02-27 | 2002-02-27 | LIGHT EMITTING PANEL WITH LIGHT EXTRACTION ELEMENTS |
| FR02/02476 | 2002-02-27 |
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| CN1639882A CN1639882A (en) | 2005-07-13 |
| CN100429781C true CN100429781C (en) | 2008-10-29 |
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| CNB038046997A Expired - Fee Related CN100429781C (en) | 2002-02-27 | 2003-01-30 | Electroluminescent panels with light extraction elements |
Country Status (8)
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| US (1) | US7325943B2 (en) |
| EP (1) | EP1495500A1 (en) |
| JP (2) | JP4547157B2 (en) |
| KR (1) | KR100970693B1 (en) |
| CN (1) | CN100429781C (en) |
| AU (1) | AU2003222343A1 (en) |
| FR (1) | FR2836584B1 (en) |
| WO (1) | WO2003073525A1 (en) |
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| JP4893378B2 (en) * | 2007-03-07 | 2012-03-07 | ソニー株式会社 | LIGHT EMITTING DEVICE, DISPLAY DEVICE AND DISPLAY DEVICE MANUFACTURING METHOD |
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| CN105206762A (en) * | 2015-10-21 | 2015-12-30 | 南京先进激光技术研究院 | Novel high-light efficiency OLED display unit |
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- 2003-01-30 CN CNB038046997A patent/CN100429781C/en not_active Expired - Fee Related
- 2003-01-30 US US10/505,527 patent/US7325943B2/en not_active Expired - Lifetime
- 2003-01-30 WO PCT/FR2003/000278 patent/WO2003073525A1/en not_active Ceased
- 2003-01-30 JP JP2003572105A patent/JP4547157B2/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2003073525A1 (en) | 2003-09-04 |
| FR2836584A1 (en) | 2003-08-29 |
| EP1495500A1 (en) | 2005-01-12 |
| KR100970693B1 (en) | 2010-07-16 |
| WO2003073525A8 (en) | 2005-04-28 |
| JP2010118358A (en) | 2010-05-27 |
| CN1639882A (en) | 2005-07-13 |
| US20050253788A1 (en) | 2005-11-17 |
| JP5211089B2 (en) | 2013-06-12 |
| JP4547157B2 (en) | 2010-09-22 |
| US7325943B2 (en) | 2008-02-05 |
| FR2836584B1 (en) | 2004-05-28 |
| AU2003222343A1 (en) | 2003-09-09 |
| JP2005531102A (en) | 2005-10-13 |
| KR20040088537A (en) | 2004-10-16 |
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