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CN100427336C - Seat system and manufacturing method thereof - Google Patents

Seat system and manufacturing method thereof Download PDF

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Publication number
CN100427336C
CN100427336C CNB2004800037655A CN200480003765A CN100427336C CN 100427336 C CN100427336 C CN 100427336C CN B2004800037655 A CNB2004800037655 A CN B2004800037655A CN 200480003765 A CN200480003765 A CN 200480003765A CN 100427336 C CN100427336 C CN 100427336C
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base plate
seat back
reinforcing member
match surface
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CN1747854A (en
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V·古普塔
H·J·克尔曼
E·库尔特茨
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Scarlett Dillon Co.,Ltd.
Trinseo Europe GmbH
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Dow Global Technologies LLC
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Abstract

本发明公开了一种座椅系统,其包括一个座椅靠背(20),其上一个或多个塑料底板(22),该底板(22)沿座椅靠背横向伸展一段距离。座椅靠背(20)包括一个或多个附加到塑料底板(22)上的加固件(30)。

Figure 200480003765

The invention discloses a seat system comprising a seat back (20) on which one or more plastic bottom plates (22) extend for a distance along the transverse direction of the seat back. The seat back (20) includes one or more reinforcements (30) attached to the plastic base (22).

Figure 200480003765

Description

座椅系统及其制作方法 Seat system and manufacturing method thereof

申请日期的权利要求Claims on filing date

本发明要求于2003年2月13日,U.S.临时申请序列号为60/447,118,和2004年1月13日,U.S.申请序列号为10/755,897,的申请的权益。二者在此为各种目的被合并参考。This application claims the benefit of U.S. Provisional Application Serial No. 60/447,118, filed February 13, 2003, and U.S. Application Serial No. 10/755,897, filed January 13, 2004. Both are incorporated herein by reference for all purposes.

技术领域 technical field

本发明涉及一种改良的座椅系统,特别是涉及一种用于机动车的改良座椅系统。本发明还涉及改良的机动车内部系统。The present invention relates to an improved seating system, and more particularly to an improved seating system for motor vehicles. The invention also relates to improved automotive interior systems.

背景技术 Background technique

改良机动车座椅系统的需求日益增强。在有舱门式后背的汽车,运动型多功能车和小型箱式车日益普及的今天,可调节式座椅和多数情况下抑制货物向机动车后部移动的需要,已经对机动车座椅系统提出了独特的设计挑战。考虑到这些交通工具主要用于货物连同乘客(尤其是后座中乘客)的装载和运送,制造者已将注意力转向改良座椅系统的性能,使其具有较高的承重能力。There is an increasing need for improved motor vehicle seating systems. In today's ever-increasing popularity of hatchback cars, sport utility vehicles and small vans, adjustable seats and, in most cases, the need to restrain cargo from moving to the rear of the vehicle, have placed a premium on motor vehicle seats. Chair systems present unique design challenges. Considering that these vehicles are mainly used for loading and transporting cargo together with passengers, especially those in the rear seats, manufacturers have turned their attention to improving the performance of seating systems with higher load-bearing capacity.

为了提高承重能力,座椅系统中可使用一个或多个加固构件。除承重性能以外,需使用低成本的材质和流水线生产过程以保持低的成本。因此,本发明的实施方式将探寻使用低成本构件的座椅加固方法。构件的制作,可采用装配周期,设备费用,劳动力成本均较低的技术。In order to increase the weight bearing capacity, one or more reinforcement members may be used in the seating system. In addition to load-bearing performance, it is necessary to use low-cost materials and an assembly line production process to keep costs low. Accordingly, embodiments of the present invention will seek seat reinforcement using low cost components. The fabrication of components can adopt technologies with low assembly cycle, equipment cost and labor cost.

有多种合适的改良座椅系统已被公开,如:USP6,491,346和U.S.应用序列号分别是:09/766,792(2001年1月22日申请),60/312,874(2001年8月15日申请),60/329,187(2001年10月12日申请),09/766,792(2001年1月22日申请),10/216,970(2002年8月12日申请),60/414,040(2002年9月27日申请)等专利,在本专利中将参考这些相关技术。There are multiple suitable improved seat systems to be disclosed, such as: USP6,491,346 and U.S. application serial numbers are respectively: 09/766,792 (applied on January 22, 2001), 60/312,874 (applied on August 15, 2001 ), 60/329,187 (filed October 12, 2001), 09/766,792 (filed January 22, 2001), 10/216,970 (filed August 12, 2002), 60/414,040 (filed September 27, 2002 Japan application) and other patents, these related technologies will be referred to in this patent.

发明内容 Contents of the invention

现有技术的需求通过本发明提供的一种机动车座椅系统而满足,其包括:一个塑料座椅靠背,座椅靠背至少有一个底板,该底板由外围边界限定并且具有在整个外围边界之间基本上连续跨越的主壁。该至少一个底板包括一个或者多个加固构件以增强座椅靠背的强度。根据一个特别优选的实施方式,底板上的加固构件包括一个用另一种材质制成的加固件。虽然加固件可以采用多种另一种材质制成,但优选的材质为金属,尤其优选的材质是钢。The needs of the prior art are met by the present invention providing a motor vehicle seating system comprising: a plastic seat back having at least one floor defined by a peripheral boundary and having a The main wall that spans substantially continuously. The at least one floor includes one or more reinforcement members to enhance the strength of the seat back. According to a particularly preferred embodiment, the reinforcing element of the base plate comprises a reinforcing element made of another material. Although the reinforcing element can be made from a variety of other materials, the preferred material is metal, and the particularly preferred material is steel.

虽然可以采用其它方法,但优选地采用塑造工艺制成座椅靠背底板。此外,在一特别优选的实施方式中,使用粘合剂将加固件附加到座椅靠背上。在该特别优选的实施方式中,座椅靠背可采用多种材质制成,但优选塑料材质,更优选聚丙烯材质,更加优选玻璃纤维填充的聚丙烯材质。A molding process is preferably used to form the seat back pan, although other methods may be used. Furthermore, in a particularly preferred embodiment, the reinforcement is attached to the seat back using an adhesive. In this particularly preferred embodiment, the seat back can be made of a variety of materials, but is preferably plastic, more preferably polypropylene, and still more preferably glass-fibre-filled polypropylene.

当座椅靠背后放置一个至少36kg重物,加速度高达20到30g时,本发明的座椅系统不会发生碎裂。该系统易于生产,并且包括一个容易连接的加固件,从而可以降低座椅靠背的制作成本。When a heavy object of at least 36kg is placed on the back of the seat and the acceleration is as high as 20 to 30g, the seat system of the present invention will not be broken. The system is easy to produce and includes an easy-to-attach reinforcement, which reduces the manufacturing cost of the seat back.

附图说明 Description of drawings

图1是施加加固件过程中座椅靠背的透视图;Figure 1 is a perspective view of a seat back during application of a reinforcement;

图2A是施加加固件过程中图1的剖视图;FIG. 2A is a cross-sectional view of FIG. 1 during application of a stiffener;

图2B是施加加固件后图1的剖视图;FIG. 2B is a cross-sectional view of FIG. 1 after the reinforcement is applied;

图3是另一个施加加构件过程中座椅靠背的透视图。Figure 3 is a perspective view of the seat back during another process of applying a reinforcement member.

具体实施方式 Detailed ways

本发明提供一种至少包括一个加固构件的座椅靠背系统,特别是包括一个或者多个采用辅助材质制成的加固构件的座椅靠背系统。优选地,加固件沿座椅靠背底板的的一主壁延伸。依本发明,由合适材质(例如金属)制成的加固件易于连接(例如粘着)到由另一种合适材质制成的座椅靠背上,但之前这两种材质的连接是相当困难的。The present invention provides a seat back system comprising at least one reinforcement member, especially a seat back system comprising one or more reinforcement members made of auxiliary materials. Preferably, the reinforcement extends along a major wall of the seat back pan. According to the invention, a reinforcement made of a suitable material, such as metal, is easily attached (eg, glued) to a seat back made of another suitable material, which was previously quite difficult to join.

图1,2A和2B所示的是一种改良的座椅靠背系统20,这种座椅靠背系统20典型地包括:一个或者多个底板22(例如60/40等分,整个座椅等),其跨越座椅靠背系统的横向距离。优选地,每个底板22包括一个主壁26,以下仅对一个主壁26加以详尽描述。Illustrated in FIGS. 1, 2A and 2B is a modified seat back system 20 that typically includes one or more bottom panels 22 (e.g., 60/40 split, entire seat, etc.) , which spans the lateral distance of the seat back system. Preferably, each bottom plate 22 includes one main wall 26, only one main wall 26 being described in detail below.

座椅靠背底板包括一个或者多个加固构件(例如加固件,肋材,二者的组合等等),其连接到且至少部分伸出主壁。优选地,每个底板的主壁基本上连续地跨越在该底板的周边,并带有加固构件基本上延主壁伸展。优选地,加固构件至少包括一个采用不同于主壁的另一种材质制成的加固构件。然而,加固构件也可以采用与主壁或者座椅靠背相近或者相同的材质制成。这里采用的另一种材质是指一种材质或材质的组成与座椅靠背材质的化学组分至少有些微小的不同。The seat back pan includes one or more reinforcement members (eg, reinforcements, ribs, a combination of the two, etc.) attached to and at least partially projecting from the main wall. Preferably, the main wall of each base plate is substantially continuous across the periphery of the base plate, with stiffening members extending substantially along the main wall. Preferably, the reinforcing member includes at least one reinforcing member made of another material than the main wall. However, the reinforcing member may also be made of a material similar to or the same as that of the main wall or the seat back. Another material as used herein means a material or composition of material that differs at least slightly from the chemical composition of the seat back material.

座椅靠背底板可由任意合适的材质制成,包括但不限于金属,塑料(强化或者非强化塑料均可),其它复合材质等等。优选地,至少要有一个底板是塑料的。更优选地,所有底板均是塑料(例如热塑性塑料,热固塑料或其组合)的。The seat back bottom can be made of any suitable material, including but not limited to metal, plastic (reinforced or non-reinforced), other composite materials, and the like. Preferably, at least one base plate is plastic. More preferably, all base plates are plastic (eg thermoplastic, thermoset or combinations thereof).

依本发明,加固构件包括一个或者多个由成分或者结构不同于底板的材质制成的加固构件。According to the invention, the reinforcing elements comprise one or more reinforcing elements made of a material different in composition or structure from the base plate.

微孔泡沫塑料的应用也落入本发明的范围之内。与之相对应,一种预先制成的气体/聚合物溶液,在非稳态的热力学条件下精炼进而成核为微孔。可根据需要控制核子的生长。The use of microcellular foams also falls within the scope of the present invention. In contrast, a prefabricated gas/polymer solution is refined under non-steady-state thermodynamic conditions to nucleate micropores. The growth of nuclei can be controlled as desired.

座椅靠背底板的制作,可采用所选材质已有的制作技术,例如成型加工,塑造,车床加工或者其它方法,从而将底板加工成所需形状。底板是塑料材质时,可采用任何合适的塑料制作技术,包括但不限于:注射成型法(包括但不限于外部或者内部注气模塑法),吹塑法,压缩模塑法,旋转模塑法,热成型法,挤出,真空成型,发泡法等等。也可采用一种或者多种其它制作技术,例如嵌件模塑,外部模塑(over-molding)或其组合。因此,如前所述,在一个实施方式中,利用不同材质和不同制作技术的优势,以及有利于设计附加性能,可以制作出混合型座椅装置。The production of the seat back bottom plate can adopt the existing production technology of the selected material, such as forming, molding, lathe processing or other methods, so that the bottom plate can be processed into the desired shape. Where the base plate is made of plastic, any suitable plastic manufacturing technique may be used, including but not limited to: injection molding (including but not limited to external or internal gas injection molding), blow molding, compression molding, rotational molding method, thermoforming method, extrusion, vacuum forming, foaming method and so on. One or more other fabrication techniques may also be used, such as insert molding, over-molding, or combinations thereof. Therefore, as mentioned above, in one embodiment, taking advantage of different materials and different manufacturing techniques, as well as facilitating the design of additional features, a hybrid seat device can be manufactured.

本发明提出了加固构件的使用,以增强座椅靠背装置的刚性,韧性和抗冲性能,或局部改进构件的挠矩。The present invention proposes the use of reinforcing members to enhance the rigidity, toughness and impact resistance of the seat back device, or locally improve the bending moment of the members.

加固构件的结构或模式包括“C”形,“D”形,“H”形,“I”形,“J”形,“L”形,“M”形,“N”形,“O”性,“S”形,“T”形,“U”形,“V”形,“W”形,“X”形,“Y”形,“Z”形,曲线形(例如正弦曲线),之字形,“+”形等等。Structures or patterns of reinforcement members include "C" shape, "D" shape, "H" shape, "I" shape, "J" shape, "L" shape, "M" shape, "N" shape, "O" shape Sex, "S" shape, "T" shape, "U" shape, "V" shape, "W" shape, "X" shape, "Y" shape, "Z" shape, curved shape (such as a sinusoidal curve), Zigzag, "+" and more.

在一个实施方式中,底板加固构件是由另一种材质制成的,并连接到座椅靠背上的加固构件。座椅靠背底板加固构件应根据主壁的加固要求进行加工,该加工方式则取决于具体机动车的座椅靠背设计(例如形状,尺寸,强度要求等等)。根据座椅靠背的设计要求,加固构件可以是或平坦,或弯曲,或大,或小,或短,或长。此外,加固构件数量的多少取决于具体的需要或要求。In one embodiment, the floor reinforcement is made of another material and is connected to the reinforcement on the seat back. The reinforcement member of the seat back bottom plate should be processed according to the reinforcement requirements of the main wall, and the processing method depends on the design of the seat back of the specific motor vehicle (such as shape, size, strength requirements, etc.). Depending on the design requirements of the seat back, the reinforcing member can be flat, curved, large, small, short, or long. Furthermore, the number of reinforcement members depends on specific needs or requirements.

在一个高度优选的实施方式中,加固构件包括一个或者多个加固构件,如由一整体材质制成的肋材。作为例子,肋材可以是实心或凹槽形结构,并连接到座椅靠背的主壁上。优选地,对于凹槽形肋材,其可采用专利60/414,040(2002年9月27日申请)中所描述的注气模塑法制作In a highly preferred embodiment, the stiffening member comprises one or more stiffening members, such as ribs made of a unitary material. As an example, the ribs may be solid or grooved structures and attached to the main wall of the seat back. Preferably, for grooved ribs, it is made by injection molding as described in patent 60/414,040 (filed September 27, 2002)

图1,2A和2B所示的是至少包括一个加固构件30的座椅靠背系统20,所述构件有一个加固件32连接到底板22上。优选地,加固件32至少部分地由另一种材质构成。Illustrated in FIGS. 1 , 2A and 2B is a seat back system 20 including at least one reinforcement member 30 having a reinforcement member 32 attached to the floor 22 . Preferably, the reinforcing element 32 is formed at least partially from another material.

加固件32可制作成各种形状和结构。例如,根据靠背系统20中加固设备32的应用以及加固方式,加固构件可以是扁平,或弯曲,或细长,或短粗,或几何,或其它形状。在一个特定实施方式中,加固件32是一个长度是L,宽度是W,厚度是T的细弯曲长条。其中长度,宽度和厚度均是常值,这些尺寸随加固构件的不同而改变,该尺寸也可因单个加固键而改变。The stiffener 32 can be made in various shapes and configurations. For example, depending on the application and reinforcement method of the reinforcement device 32 in the backrest system 20, the reinforcement member may be flat, or curved, or slender, or short and thick, or geometric, or other shapes. In a particular embodiment, the stiffener 32 is a thin curved strip having a length L, a width W, and a thickness T. Where length, width and thickness are constant values, these dimensions vary from reinforcement member to reinforcement member, and the dimensions may also vary from individual reinforcement keys.

一般来说,加固件32的尺寸不是被严格限定的,其可取决于加固件32所需跨越的距离或面积。然而,一般地是维持加固件32小的尺寸,尤其是厚度应尽可能小以减轻其重量。优选的厚度应小于大约5mm,更优选地,小于大约2mm,最优选地,小于大约1mm。为减轻加固件32的重量,其上优选地有一个或多个空隙(例如通孔)。在该实施方式中,为使加固件32的中空部分占有较大体积,加固件基本上是骨架结构。In general, the size of the reinforcing member 32 is not strictly limited and may depend on the distance or area that the reinforcing member 32 is required to span. However, it is generally desirable to keep the reinforcement 32 small in size, especially in thickness, as small as possible in order to reduce its weight. The preferred thickness should be less than about 5 mm, more preferably less than about 2 mm, most preferably less than about 1 mm. In order to reduce the weight of the reinforcing member 32, there are preferably one or more voids (eg, through holes) thereon. In this embodiment, in order to make the hollow part of the reinforcement 32 occupy a larger volume, the reinforcement is basically a skeleton structure.

优选地,但不要求,加固件32上包括一个与座椅靠背系统20底板22上的表面40相匹配的表面36。图1-2B中所示的加固件22上包括一对长度是L的肋材50,和连接肋材50的一个连接板52,从而形成表面36,其包括一个平坦部分54和一对槽沟56。对应地,座椅靠背系统20底板22上的匹配表面40限定的一对加固件60插入槽沟52,并且平坦部64与加固件32的平坦部54基本吻合相配。Preferably, but not required, reinforcement member 32 includes a surface 36 thereon that mates with surface 40 on bottom panel 22 of seat back system 20 . The stiffener 22 shown in FIGS. 1-2B includes a pair of ribs 50 of length L and a web 52 connecting the ribs 50 to form a surface 36 that includes a flat portion 54 and a pair of grooves. 56. Correspondingly, a pair of stiffeners 60 defined by the mating surface 40 on the chassis 22 of the seat back system 20 is inserted into the slot 52 and the flat portion 64 substantially mates with the flat portion 54 of the stiffener 32 .

加固件32的另一种材质,可选自多种材质,如聚合物,玻璃,金属,纤维(例如玻璃,碳纤维,芳族聚酰胺金属(aramid metal)等等),编织材质,非编织材质,以及它们的复合物等等。在一优选的实施方式中,所述另一种材质是至少一部分或基本上全部是一种或多种金属,例如铝,铁,钨,镁,钢,锡,铜,钛,合金等等。根据一优选实施方式所述另一种材质基本上完全是低碳钢。Another material of the reinforcing member 32 can be selected from various materials, such as polymer, glass, metal, fiber (such as glass, carbon fiber, aramid metal, etc.), woven material, non-woven material , and their complexes, etc. In a preferred embodiment, the other material is at least a part or substantially all of one or more metals, such as aluminum, iron, tungsten, magnesium, steel, tin, copper, titanium, alloys and the like. According to a preferred embodiment the other material is substantially entirely low carbon steel.

加固件32的制作,可采用各种制作技术,如滚压,铸造,冲轧等等。也可采用铸模,挤出等技术制作。The reinforcement 32 can be manufactured using various manufacturing techniques, such as rolling, casting, stamping and the like. It can also be made by casting, extrusion and other techniques.

合适的底板可包括一种塑料模塑品。塑料材质优选地包括一种均聚物,如聚烯烃,聚酰胺,聚苯醚(polyphenylene oxide)和聚苯乙烯,或一种具有低表面能的共聚物,如聚亚烷基对苯二甲酸酯(polyalkylene terephthalate),共聚物也可能具有高的表面能。A suitable base plate may comprise a plastic moulding. The plastic material preferably comprises a homopolymer such as polyolefin, polyamide, polyphenylene oxide and polystyrene, or a copolymer with low surface energy such as polyalkylene terephthalmic Polyalkylene terephthalate, copolymers may also have high surface energies.

优选的塑料材质包括聚丙烯,聚酰胺,聚酰胺合金,聚苯醚聚合物,聚苯醚合金,聚苯乙烯聚合物,聚苯乙烯合金,聚对苯二甲酸丁二醇酯聚合物和聚对苯二甲酸丁二醇酯合金。塑料材质中可含有纤维,如短玻璃纤维,长玻璃纤维,短天然纤维或长天然纤维。Preferred plastic materials include polypropylene, polyamide, polyamide alloys, polyphenylene ether polymers, polyphenylene ether alloys, polystyrene polymers, polystyrene alloys, polybutylene terephthalate polymers, and poly Butylene terephthalate alloy. The plastic material may contain fibers such as short glass fibers, long glass fibers, short natural fibers or long natural fibers.

特别优选的塑料材质包括填充了短玻璃纤维的聚丙烯,填充了长玻璃纤维的聚丙烯,填充了玻璃的聚酰胺和填充了玻璃的聚酰胺合金。特别优选地用于如EAU缓冲系统的塑料材质包括无填充物的聚丙烯,填充了云母的聚丙烯,填充了矿物的聚丙烯。Particularly preferred plastic materials include short glass filled polypropylene, long glass filled polypropylene, glass filled polyamide and glass filled polyamide alloys. Particularly preferred plastic materials for cushioning systems such as EAU include unfilled polypropylene, mica-filled polypropylene, mineral-filled polypropylene.

在某些优选地实施方式中,聚合物材质中可以填充纤维以增加强度。虽然可以使用各种尺寸(例如长度)的纤维,而研究发现纤维越长,相对增加的强度越高。因此,在优选实施方式中,聚合物材质,如ABS,PCABS,聚丙烯,SMA(苯乙烯-顺丁烯二酸酐),PPO(聚苯醚)或其它合适的塑料填充有玻璃纤维,其平均长度大约超过2mm的,较优选的大约超过4mm,更加优选的大约超过6mm,最优选的大约在8-20mm之间。In some preferred embodiments, the polymer material may be filled with fibers to increase strength. While fibers of various sizes (eg, lengths) can be used, studies have found that the longer the fibers, the greater the relative increase in strength. Therefore, in a preferred embodiment, a polymeric material such as ABS, PCABS, polypropylene, SMA (styrene-maleic anhydride), PPO (polyphenylene oxide) or other suitable plastic is filled with glass fibers, the average The length is about more than 2mm, more preferably about more than 4mm, more preferably about more than 6mm, and most preferably about between 8-20mm.

为形成加固构件30,加固件32与座椅靠背系统20其它部分的连接或集成,可采用各种连接或集成技术,如螺丝钉,扣钩,铆钉,它们的组合等等机械扣件。此外,采用前已提及的制作技术,至少在座椅靠背系统20上相应位置塑造出加固件32,即可将二者集成在一起。加固件32与底板22的连接,也可以采用热桩(heat staking),振动焊接,声波焊接,它们的组合等技术。To form the reinforcement member 30, the reinforcement member 32 can be connected or integrated with other parts of the seat back system 20, various connection or integration techniques can be used, such as screws, clasps, rivets, combinations thereof and other mechanical fasteners. In addition, the two can be integrated together by molding the reinforcement 32 at least at the corresponding position on the seat back system 20 by using the manufacturing technology mentioned above. The connection between the reinforcing member 32 and the bottom plate 22 may also adopt techniques such as heat staking, vibration welding, sonic welding, or combinations thereof.

在一个实施方式中,采用粘合剂66将加固件32粘着到座椅靠背系统20的底板22上。优选地,粘合剂66分别涂抹到底板22和加固件32的匹配表面40,36中的一个或两个上。然后将表面40和36相互挤压,即将加固件32和底板22连接到一起。当然可以将粘合剂66涂抹到加固件32或座椅靠背系统20的任意表面上,继而将二者粘合在一起。In one embodiment, the reinforcement member 32 is adhered to the bottom panel 22 of the seat back system 20 using an adhesive 66 . Preferably, the adhesive 66 is applied to one or both of the mating surfaces 40, 36 of the chassis 22 and stiffener 32, respectively. The surfaces 40 and 36 are then pressed against each other, ie the stiffener 32 and the base plate 22 are joined together. It is of course possible to apply the adhesive 66 to any surface of the reinforcement member 32 or the seat back system 20, thereby bonding the two together.

本发明中可采用任意合适的粘合剂。优选的粘合剂66与底板22和加固件32的材质相容(即,易于粘合)。若粘合剂66与其中一种材质不相容,则需要对由不相容材质制成的底板22或加固件32的表面进行处理。典型的处理方法包括应用底漆,等离子辐射,二者的组合等。Any suitable binder may be employed in the present invention. The preferred adhesive 66 is compatible with (ie, readily adheres to) the materials of the base plate 22 and stiffener 32 . If the adhesive 66 is incompatible with one of the materials, it is necessary to treat the surface of the base plate 22 or the reinforcing member 32 made of the incompatible material. Typical treatments include application of a primer, plasma radiation, a combination of the two, etc.

在一实施例中,粘合剂是基于氨基甲酸乙酯的粘合剂,优选的是氨基甲酸乙酯粘合剂(例如聚氨酯粘合剂)。供选择地,该粘合剂中可包括一种功能组分,选自于甲基丙烯酸甲酯(MMA),丙烯腈-丁二烯-苯乙烯(ABS),聚碳酸酯(PC),或它们的混合物(例如PC-ABS)。在进一步供选的实施方式中,粘合剂是硅烷粘合剂,硅氧烷粘合剂或它们的混合物。在另一实施方式中,粘合剂是丙烯酸粘合剂。粘合剂还可以是环氧基的,可以包括聚烯烃类(polyolefinics),苯乙烯类(styrenics),丙烯酸类(acrylics)或它们的混合物。而在另一个实施方式中,优选的粘合剂包括烷基硼烷。USP09/466,321(1999年12月17日申请)以及专利发布号分别是:20020058764和20030001410的专利中均公布了合适的粘合剂实例。这些粘合剂中含有适当的改性物,包括增粘剂,弹性体,抗冲改性剂等。In one embodiment, the adhesive is a urethane based adhesive, preferably a urethane adhesive (eg polyurethane adhesive). Alternatively, the adhesive may include a functional component selected from methyl methacrylate (MMA), acrylonitrile-butadiene-styrene (ABS), polycarbonate (PC), or Their mixtures (eg PC-ABS). In a further alternative embodiment, the adhesive is a silane adhesive, a silicone adhesive or a mixture thereof. In another embodiment, the adhesive is an acrylic adhesive. The adhesive may also be epoxy based and may include polyolefins, styrenics, acrylics or mixtures thereof. In yet another embodiment, preferred binders include alkylboranes. Examples of suitable adhesives are disclosed in USP 09/466,321 (filed December 17, 1999) and in Patent Publication Nos. 20020058764 and 20030001410, respectively. These adhesives contain suitable modifiers, including tackifiers, elastomers, impact modifiers, etc.

在一个特别优选的实施方式中,为牢固粘结加固件32与底板22,采用了两组分的有机硼烷/胺配合物粘合剂或其它粘合剂。已经被发现,该粘合剂与金属(例如钢)和塑料,尤其是聚丙烯,是相容的。照此,可直接使用该粘合剂连接由金属制成的加固件32和由塑料或聚丙烯制成的座椅靠背系统20,而无需预先处理加固件32或座椅靠背系统20的表面。In a particularly preferred embodiment, a two-part organoborane/amine complex adhesive or other adhesive is used to securely bond reinforcement member 32 to base plate 22 . The adhesive has been found to be compatible with metals (eg steel) and plastics, especially polypropylene. As such, the adhesive can be used directly to join the reinforcement 32 made of metal and the seat back system 20 made of plastic or polypropylene without pre-treating the surface of the reinforcement 32 or the seat back system 20 .

在本发明的一个特别优选的实施方式提供一种由模塑的填充了玻璃的聚丙烯和/或填充了玻璃的聚酰胺制成的底板,其表面能低于45mJ/m2;和一种由钢,锌和/或铝制成的加固件。照此,优选的粘合剂是适于连接表面能低于45mJ/m2底层的粘合剂,将其涂抹到匹配表面上,即可将二者粘合在一起。该粘合剂是一种具有以下可聚合的成分生成,该成分包括:In a particularly preferred embodiment of the present invention there is provided a base plate made of molded glass-filled polypropylene and/or glass-filled polyamide having a surface energy below 45 mJ/m 2 ; and a Reinforcements made of steel, zinc and/or aluminium. As such, the preferred adhesive is one suitable for joining substrates with a surface energy below 45 mJ/ m2 , which can be applied to a mating surface to bond the two together. The adhesive is produced with the following polymerizable ingredients, which include:

i)一种有机硼烷/胺配合物;i) an organoborane/amine complex;

ii)一种或多种具有烯键不饱和的单体、低聚物或聚合物,其可通过自由基聚合聚合;及可任选ii) one or more monomers, oligomers or polymers having ethylenic unsaturation, which can be polymerized by free radical polymerization; and optionally

iii)一种能使所述配合物分离,以释放出硼烷,以引发具有烯键不饱和的一种或多种单体、低聚物或聚合物的聚合的化合物。iii) A compound capable of dissociating said complex to release borane to initiate polymerization of one or more monomers, oligomers or polymers having ethylenic unsaturation.

本发明的尤其特别优选的方面是如前所述的机动车装配制作方法和装配过程中粘合剂的使用。A particularly particularly preferred aspect of the invention is the method of manufacturing a motor vehicle assembly and the use of adhesives in the assembly process as described above.

专利PCT/US00/33806中提出的粘合剂和和可聚合成分非常适用于本发明,以将结构构件和加固构件粘结在一起。Adhesives and polymerizable compositions as taught in patent PCT/US00/33806 are well suited for use in the present invention to bond structural and reinforcing members together.

配合有机硼烷化合物的胺,可是任何既能与有机硼烷配合,又能在解缔合介质存在时分离的胺。优选的胺包括如Zharov在专利USP5,539,070中第5列的41-53行,Skoultchi在专利USP5,106,928中第2列的29-58行,和Pocius在专利USP5,686,544中第7列的29行至第10列的36行中提出的伯胺,仲胺,含有伯胺或仲胺基团的多元胺,或氨;monthanolamine,仲二烷基二胺或聚氧化亚烷基多元胺;Deviny在专利USP5,883,208中第7列的30行至第8列的56行中提出的二胺与具有两个或多个能与胺反应的基团的化合物的胺封端反应产物。关于Deviny所述的反应产物,优选的二伯胺(diprimary amines)包括烷基二伯胺,芳基二伯胺,烷基芳基二伯胺和聚氧化亚烷基二胺;所述的能与胺反应的化合物包括含有两个或多个羧酸,羧酸酯,羧酸卤化物,醛,环氧化物,醇和丙烯酸酯基团的化合物。优选的胺包括正辛胺,1,6-二氨基己烷(1,6-己二胺),二乙胺,二丁胺,二亚乙基三胺,二亚丙基二胺,1,3-亚丙基二胺(1,3-丙二胺),1,2-亚丙基二胺,1,2-乙二胺,1,5-戊二胺,1,12-十二烷二胺,2-甲基-1,5-戊二胺,3-甲基-1,5-戊二胺,三亚乙基四胺,二亚乙基三胺。优选的聚氧化亚烷基多元胺包括聚环氧乙烷二胺,聚环氧丙烷二胺,三甘醇亚丙基二胺,聚四氢呋喃二胺和聚The amine that complexes the organoborane compound is any amine that both complexes with the organoborane and dissociates in the presence of a disassociation medium. Preferred amines include lines 41-53, column 5, USP 5,539,070 by Zharov, lines 29-58, column 2, USP 5,106,928 by Skoultchi, and 29, column 7, column 7, USP 5,686,544 by Pocius. Primary amines, secondary amines, polyamines containing primary or secondary amine groups, or ammonia as set forth in lines 36 through column 10; monthanolamine, secondary dialkyldiamine or polyoxyalkylene polyamine; Deviny An amine-terminated reaction product of a diamine and a compound having two or more groups capable of reacting with amines proposed in the patent USP 5,883,208 from column 7, line 30 to column 8, line 56. Regarding the reaction product described by Deviny, preferred diprimary amines include alkyl diprimary amines, aryl diprimary amines, alkylaryl diprimary amines and polyoxyalkylene diamines; Compounds that react with amines include compounds containing two or more carboxylic acid, carboxylic acid ester, carboxylic acid halide, aldehyde, epoxide, alcohol and acrylate groups. Preferred amines include n-octylamine, 1,6-diaminohexane (1,6-hexanediamine), diethylamine, dibutylamine, diethylenetriamine, dipropylenediamine, 1, 3-propylenediamine (1,3-propylenediamine), 1,2-propylenediamine, 1,2-ethylenediamine, 1,5-pentanediamine, 1,12-dodecane Diamine, 2-methyl-1,5-pentanediamine, 3-methyl-1,5-pentanediamine, triethylenetetramine, diethylenetriamine. Preferred polyoxyalkylene polyamines include polyethylene oxide diamine, polypropylene oxide diamine, triethylene glycol propylene diamine, polytetrahydrofuran diamine and poly

环氧乙烷共聚环氧丙烷二胺。Ethylene oxide copolymerized propylene oxide diamine.

特别地,有机硼烷/胺配合物中的胺可选自具有脒结构组分的胺;在杂环中具有至少一个氮的脂肪族杂环,其中该杂环化合物在杂环中也可有一个或者多个氮原子,氧原子,硫原子或双键;附加有一个或多个氢键接受基团的伯胺,其中在伯胺与氢键接受基团之间至少要有两个碳原子,优选地至少有三个碳原子,配合物中分子间或分子内作用可增加B--N键的强度;或共轭亚胺。In particular, the amine in the organoborane/amine complex can be selected from amines having an amidine structural component; an aliphatic heterocycle having at least one nitrogen in the heterocycle, wherein the heterocycle compound can also have One or more nitrogen atoms, oxygen atoms, sulfur atoms or double bonds; primary amines appended with one or more hydrogen bond accepting groups, wherein there are at least two carbon atoms between the primary amine and the hydrogen bond accepting group , preferably at least three carbon atoms, the intermolecular or intramolecular interaction in the complex can increase the strength of the B--N bond; or a conjugated imine.

优选的氢键接受基团包括:伯胺,仲胺,叔胺,醚,卤素,聚醚或多元胺。所述杂环是含有一个或多个脂环的化合物,其中的一个环上含有氮。所述脒或共轭亚胺可以是直链的,支链的或环状的。Preferred hydrogen bond accepting groups include: primary amines, secondary amines, tertiary amines, ethers, halogens, polyethers or polyamines. The heterocycle is a compound containing one or more alicyclic rings, one of which contains nitrogen. The amidine or conjugated imine can be linear, branched or cyclic.

配合物中优选的有机硼烷是三烷基硼烷或烷基环烷基硼烷。该硼烷最好具有分子式1:Preferred organoboranes in the complex are trialkylboranes or alkylcycloalkylboranes. The borane preferably has the formula 1:

B--(R1)3    分子式1B--(R 1 ) 3 molecular formula 1

其中:B是硼;R1是一个C1-10烷基,C3-10环烷基,或由两个或多个R1结合而成的脂环。Where: B is boron; R 1 is a C 1-10 alkyl group, C 3-10 cycloalkyl group, or an alicyclic ring formed by combining two or more R 1s .

优选的R1是C1-4烷基,较优选的是C2-4烷基,最优选的是C3-4烷基。优选的有机硼烷包括三乙基硼烷,三异丙基硼烷和三正丁基硼烷。Preferred R 1 is C 1-4 alkyl, more preferably C 2-4 alkyl, most preferably C 3-4 alkyl. Preferred organoboranes include triethylborane, triisopropylborane and tri-n-butylborane.

在一个优选的实施方式中,配合物中的胺由含有一个伯胺和一个或多个氢键接受基团的化合物,其中在伯胺和氢键接受基团之间至少要有两个碳原子,优选地至少有三个碳原子。In a preferred embodiment, the amine in the complex consists of a compound containing a primary amine and one or more hydrogen bond accepting groups, wherein there are at least two carbon atoms between the primary amine and the hydrogen bond accepting group , preferably at least three carbon atoms.

优选地,该胺具有分子式2:Preferably, the amine has the formula 2:

NH2(CH2)b(C(R2)2)aX    分子式2NH 2 (CH 2 ) b (C(R 2 ) 2 ) a X Formula 2

其中:R2是氢,C1-4烷基或C3-10环烷基;X是半个氢键接受基团;a是一个介于1和10之间的整数;b是0或1,并且a与b之和介于2和10之间。Wherein: R 2 is hydrogen, C 1-4 alkyl or C 3-10 cycloalkyl; X is half a hydrogen bond accepting group; a is an integer between 1 and 10; b is 0 or 1 , and the sum of a and b is between 2 and 10.

优选的R2是氢或甲基。Preferred R2 is hydrogen or methyl.

优选的X是半个氢键接受基团,当氢键接受基团是胺时,优选的X是一个叔胺或仲胺。更优选的X是--N(R8)e,--OR10,或卤素,其中:R8是C1-10烷基,C3-10环烷基或-(C(R2)2)d--W;R10是C1-10烷基,C3-10环烷基或-(C(R2)2)d--W;e等于0,1或2。更加优选的X是--N(R8)2或--OR10Preferably X is half a hydrogen bond accepting group, and when the hydrogen bond accepting group is an amine, preferably X is a tertiary or secondary amine. More preferred X is --N(R 8 )e, --OR 10 , or halogen, wherein: R 8 is C 1-10 alkyl, C 3-10 cycloalkyl or -(C(R 2 ) 2 ) d --W; R10 is C 1-10 alkyl, C 3-10 cycloalkyl or -(C(R 2 ) 2 ) d --W; e is equal to 0, 1 or 2. More preferably X is --N(R 8 ) 2 or --OR 10 .

优选的R8和R10是C1-4烷基或--(C(R2)2)d-W,较优选的是C1-4烷基,最优选的是甲基。W是氢,C1-10烷基或X,较优选的是氢或C1-4烷基。Preferred R 8 and R 10 are C 1-4 alkyl or --(C(R 2 ) 2 ) d -W, more preferably C 1-4 alkyl, most preferably methyl. W is hydrogen, C 1-10 alkyl or X, more preferably hydrogen or C 1-4 alkyl.

优选地,a值大约为1或大于1,较优选2或大于2。优选的a为大约6或小于6,最优选的为大约4或小于4。优选的b值是大约为1。优选的a与b之和是2或大约2的整数,更优选的大约为3或大于3。优选的a与b之和大约为6或小于6,更优选的大约为4或小于4。优选的d是一个介于1和4之间的整数,较优选的介于2和4之间,更加优选的介于2和3之间。Preferably, the value of a is about 1 or greater than 1, more preferably 2 or greater. Preferably a is about 6 or less, most preferably about 4 or less. A preferred value of b is about 1. Preferably the sum of a and b is an integer of 2 or about 2, more preferably about 3 or more. Preferably the sum of a and b is about 6 or less, more preferably about 4 or less. Preferably d is an integer between 1 and 4, more preferably between 2 and 4, more preferably between 2 and 3.

优选具有分子式2的胺是二甲胺基丙胺,甲氧基丙胺,二甲胺基乙胺,二甲胺基丁胺,甲氧基丁胺,甲氧基乙胺,乙氧基丙胺,丙氧基丙胺,胺封端聚亚烷基醚(例如三羟甲基丙烷-三(聚丙二醇,胺封端)醚),氨丙基吗啉,异佛尔酮二胺,和氨丙基丙二胺。Preferred amines of formula 2 are dimethylaminopropylamine, methoxypropylamine, dimethylaminoethylamine, dimethylaminobutylamine, methoxybutylamine, methoxyethylamine, ethoxypropylamine, propylamine Oxypropylamines, amine-terminated polyalkylene ethers (such as trimethylolpropane-tris(polypropylene glycol, amine-terminated) ether), aminopropylmorpholine, isophoronediamine, and aminopropylpropyl diamine.

在另一个实施方式中,胺可以是杂环上至少有一个氮原子的脂肪族杂环。该杂环化合物中也可含有一个或多个氮原子,氧原子,硫原子或双键。此外,该杂环可包括多个环,其中至少一个环上含有氮。优选的这类化合物包括吗啉,哌啶,pyrolidine,哌嗪,1,3,3三甲基6-(氮杂二环)[3,2,1]辛烷,噻唑烷,高哌嗪(homopiperazine),氮丙啶,1,4-(二氮杂二环)[2,2,2]辛烷(DABCO),1-氨基-4-甲基哌嗪,和3-吡咯啉。In another embodiment, the amine can be an aliphatic heterocycle having at least one nitrogen atom on the heterocycle. The heterocyclic compound may also contain one or more nitrogen atoms, oxygen atoms, sulfur atoms or double bonds. In addition, the heterocycle may comprise multiple rings, at least one of which contains nitrogen. Preferred compounds of this class include morpholine, piperidine, pyrolidine, piperazine, 1,3,3 trimethyl 6-(azabicyclo)[3,2,1]octane, thiazolidine, homopiperazine ( homopiperazine), aziridine, 1,4-(diazabicyclo)[2,2,2]octane (DABCO), 1-amino-4-methylpiperazine, and 3-pyrroline.

在另外一个实施方式中,能和有机硼烷适当配合的胺是一种脒,可以是任何带有脒结构的化合物,为与有机硼烷配合,该脒必须具有足够的键能。合适的脒包括1,8-(二氮杂二环)[5,4]十一碳-7-烯;四氢嘧啶;2-甲基-2-咪唑啉;和1,1,3,3-四甲基胍。In another embodiment, the amine capable of properly coordinating with the organoborane is an amidine, which can be any compound with an amidine structure. In order to coordinate with the organoborane, the amidine must have sufficient bond energy. Suitable amidines include 1,8-(diazabicyclo)[5,4]undec-7-ene; tetrahydropyrimidine; 2-methyl-2-imidazoline; and 1,1,3,3 - Tetramethylguanidine.

在一个进一步的实施方式中,能和有机硼烷适当配合的胺是共轭亚胺,可以是带有共轭亚胺结构的各种化合物,如专利PCT/US00/33806所述,为与有机硼烷配合,亚胺必须具有足够的键能。该共轭亚胺可以是直链,支链亚胺或者环亚胺。优选的共轭亚胺为4-二甲氨基吡啶;2,3-双(二甲氨基)环-丙烯亚胺;3-(二甲基胺)丙烯醛亚胺;3-(二甲氨基)异丁烯醛亚胺(3-(dimethylamino)methacrole-inimine)。In a further embodiment, the amine that can be properly coordinated with the organoborane is a conjugated imine, which can be various compounds with a conjugated imine structure, as described in the patent PCT/US00/33806. For borane to complex, the imine must have sufficient bond energy. The conjugated imine can be straight chain, branched imine or cyclic imine. Preferred conjugated imines are 4-dimethylaminopyridine; 2,3-bis(dimethylamino)cyclo-propyleneimine; 3-(dimethylamine)acrylimine; 3-(dimethylamino) Methacryl aldimine (3-(dimethylamino)methacrole-inimine).

优选的胺化合物与有机硼烷化合物的摩尔比是1.0∶1.0-3.0∶1.0。当摩尔比低于1.0∶1.0时,聚合,配合物稳定性和粘性等方面会有问题。虽然摩尔比高于3.0∶1.0并不会带来更多优势,但仍可采用。而胺过多会对粘合剂或聚合物混合物的稳定性产生消极影响。较优选的胺化合物与有机硼烷化合物的摩尔比是1.0∶1.0-2.0∶1.0。A preferred molar ratio of amine compound to organoborane compound is 1.0:1.0-3.0:1.0. When the molar ratio is lower than 1.0:1.0, there are problems in polymerization, complex stability and viscosity. Although molar ratios higher than 3.0:1.0 do not confer any additional advantages, they can still be used. Too much amine can negatively affect the stability of the adhesive or polymer mixture. A more preferred molar ratio of amine compound to organoborane compound is 1.0:1.0-2.0:1.0.

采用如专利PCT/US00/33806提供的技术,很容易配制有机硼烷/胺配合物。Organoborane/amine complexes are readily formulated using techniques such as those provided in patent PCT/US00/33806.

优选地,聚合物材质包括丙烯酸酯和/或甲基丙烯酸酯化合物。尤其优选丙烯酸酯和甲基丙烯酸酯化合物,其包括甲基丙烯酸甲酯,甲基丙烯酸丁酯,甲基丙烯酸乙基己酯,甲基丙烯酸异冰片酯,甲基丙烯酸四氢糠酯和甲基丙烯酸环己基甲酯。Preferably, the polymer material comprises acrylate and/or methacrylate compounds. Especially preferred are acrylate and methacrylate compounds, which include methyl methacrylate, butyl methacrylate, ethylhexyl methacrylate, isobornyl methacrylate, tetrahydrofurfuryl methacrylate and methyl Cyclohexyl methyl acrylate.

可聚合物的成分可进一步包括能与胺发生反应的适量化合物(一种解缔合介质),所释放出的硼烷可使聚合反应发生。所需胺反应化合物是在室温或低于室温,最好是在室温条件下易于生成反应产物的材质,继而提供一种在环境条件下易于使用和固化的混合物。通常这类化合物包括酸,醛,异氰酸酯,酸性氯化物,硫酰氯化物,它们的混合物等。优选的胺反应混合物是酸,尤其是布朗斯特酸和路易斯酸,和专利USP5,718,977中所述的化合物,更优选的是丙烯酸和甲基丙烯酸。The polymerizable component may further include an appropriate amount of a compound capable of reacting with an amine (a disassociation medium), the liberated borane allowing polymerization to occur. The desired amine reactive compound is a material that readily forms a reaction product at or below room temperature, preferably at room temperature, thereby providing a mixture that is easy to use and cure at ambient conditions. Typically such compounds include acids, aldehydes, isocyanates, acid chlorides, sulfuryl chlorides, mixtures thereof, and the like. Preferred amine reaction mixtures are acids, especially Bronsted and Lewis acids, and the compounds described in USP 5,718,977, more preferably acrylic acid and methacrylic acid.

在可聚合的成分中,合适的聚合组分质量分数至少占20%,优选的至少占30%,更优选的至少占40%。单独地,,合适的可聚合组分质量分数不超过95%,优选地不超过90%,尤其优选的不超过85%。Among the polymerizable components, suitable polymeric components account for at least 20% by mass, preferably at least 30%, more preferably at least 40%. Individually, the suitable polymerizable component mass fraction is not more than 95%, preferably not more than 90%, especially preferably not more than 85%.

合适的有机硼烷/胺配合物质量分数至少占0.2%,优选的至少占1%,更优选的至少占2%。此外,合适的配合物质量分数应不超过8%,最好不超过6%,若不超过4%更好。The mass fraction of suitable organoborane/amine complex is at least 0.2%, preferably at least 1%, more preferably at least 2%. In addition, the suitable mass fraction of the complex should not exceed 8%, preferably not exceed 6%, even better if not exceed 4%.

如果有解缔合化合物存在,其合适的质量分数至少占1%,最好至少占1.5%,若至少占2%最好。单独地,合适的解缔合化合物质量分数不超过8%,优选的不超过6%,尤其优选的不超过4%。If a disassociation compound is present, it suitably accounts for at least 1%, preferably at least 1.5%, and most preferably at least 2%. Individually, the mass fraction of suitable disassociated compounds does not exceed 8%, preferably does not exceed 6%, and especially preferably does not exceed 4%.

经ASTM D1002体制的检测表明:本发明所提供的粘合剂,可以将填充了30%玻璃的聚丙烯构件和加固构件牢固地粘合在一起,而无需对任何构件表面进行预处理。此外,该粘合剂还可在热循环和高湿度条件下使用。合适的热循环温度是-40-120℃以上。湿度可以从干燥变化至充分饱和。The test of the ASTM D1002 system shows that the adhesive provided by the invention can firmly bond the polypropylene component filled with 30% glass and the reinforcement component together without pretreatment on the surface of any component. Additionally, the adhesive can withstand thermal cycling and high humidity conditions. The suitable thermal cycle temperature is above -40-120°C. Humidity can vary from dry to fully saturated.

该粘合剂的使用,可采用专利PCT/US00/33806中提到的方式。此外,还可以在混合物中加入其它添加剂。专利PCT/US00/33806中已给出了合适的添加剂。The adhesive can be used in the manner mentioned in the patent PCT/US00/33806. In addition, other additives can also be added to the mixture. Suitable additives are given in patent PCT/US00/33806.

合适的装配可以经受100-120℃,甚至更高温度的热辐射。此外,该装配还可以承受生产过程以及使用当中所施加的重物,例如:猛力撞击引擎顶盖,在引擎顶盖把手上放置重物,以及路面行驶过程中的震动和老化。实际应用当中,根据机动车的设计和构造选择粘合剂的用量和位置。A suitable assembly can withstand heat radiation at 100-120°C, or even higher. In addition, the assembly can withstand the heavy loads imposed during production and use, such as: slamming the hood, placing heavy objects on the hood handle, vibration and aging during road driving. In practice, the amount and location of the adhesive is selected according to the design and construction of the vehicle.

一旦在座椅靠背系统20上使用了粘合剂66以及加固件32,则必须留出足够的时间固化(例如部分固化,整体固化,按需固化,空气固化,热固化,湿气固化,化学固化,光固化等)粘合剂66,以确保加固件32连接到底板26上。粘合剂最好在室温(大概20-30℃)下固化,也可在更高或更低温度条件下固化,以加快或减慢固化时间。为确保加固件32连接到座椅靠背系统20上,可在固化过程中使用扣件(例如高顶图钉,夹子等)。在座椅靠背系统20的使用当中,这些扣件可以是可拆卸的,并可辅助加固件32连接到其上。Once adhesive 66 and reinforcement 32 have been applied to seat back system 20, sufficient time must be allowed to cure (e.g., partial cure, full cure, on-demand cure, air cure, heat cure, moisture cure, chemical curing, photocuring, etc.) adhesive 66 to secure reinforcement 32 to base plate 26. The adhesive is best cured at room temperature (approximately 20-30°C), but can be cured at higher or lower temperatures to speed up or slow down the curing time. To secure the reinforcement member 32 to the seat back system 20, fasteners (eg, push pins, clips, etc.) may be used during the curing process. During use of the seat back system 20, these fasteners may be removable and may facilitate attachment of the reinforcement member 32 thereto.

一般来说,希望该粘合剂能表现出适度的固化后延性。优选的粘合剂的延性,与加固件32材质的延性,或构成座椅靠背系统20或底板22的材质的的延性,二延性值之中较低的一样高。然而更优选的粘合剂的延性,与加固件32材质的延性,或构成座椅靠背系统20或底板22的材质的的延性,二延性值之中较高的一样高。In general, it is desirable for the adhesive to exhibit moderate ductility after cure. The ductility of the adhesive is preferably as high as the ductility of the material of the reinforcement member 32 or the ductility of the material comprising the seat back system 20 or the bottom panel 22 , whichever is lower. More preferably, however, the ductility of the adhesive is as high as the ductility of the material of the reinforcement member 32, or the ductility of the material comprising the seat back system 20 or the bottom panel 22, whichever is higher.

有利的结果表明:制作带有由另一种材质构成的加固构件的座椅靠背,根据本发明可以达到较低制作周期。例如,该座椅靠背系统的制作周期可以不超过一分钟,优选的不超过40秒钟,更优选的不超过30秒钟,更加优选的不超过20秒钟。The favorable results show that according to the invention a relatively low production cycle can be achieved for the production of a seat back with a reinforcement element made of another material. For example, the manufacturing cycle of the seat back system may not exceed one minute, preferably not exceed 40 seconds, more preferably not exceed 30 seconds, and still more preferably not exceed 20 seconds.

在图1-2B所示实施方式中,加固件32连接到座椅靠背系统20的背面(即:座椅靠背上乘客的反面)。此外,如图所示的构件还可以设置到座椅靠背系统上或其内部的多个位置。一个或多个加固构件可以设置在座椅靠背底板的背面,一个或多个可以设置在前面,或集成在座椅靠背底板的内部。一个或多个加固构件还可以沿着座椅靠背底板的外边界设置。也可考虑将这些加固构件沿座椅靠背底板横向,纵向,水平,垂直,倾斜或它们的组合形式设置。In the embodiment shown in FIGS. 1-2B , the reinforcement member 32 is attached to the back of the seat back system 20 (ie, the side opposite the occupant of the seat back). In addition, the components as shown may also be provided at various locations on or within the seat back system. One or more reinforcement members may be provided on the back of the seat back pan, one or more may be provided on the front, or integrated into the interior of the seat back pan. One or more reinforcement members may also be disposed along the outer boundary of the seat back pan. It is also conceivable to arrange these reinforcing members along the seat back floor laterally, longitudinally, horizontally, vertically, obliquely or a combination thereof.

在该实施方式中,加固件32连接到座椅靠背系统20的集成加固构件上。而加固件32也可设置于空隙(例如模槽或通孔)内或平面上。In this embodiment, the reinforcement 32 is connected to an integrated reinforcement member of the seat back system 20 . The reinforcement 32 can also be disposed in the gap (such as a mold cavity or a through hole) or on a plane.

依本发明,座椅靠背底板,加固构件上均可包括一个或多个突起,以辅助加固构件设置并连接到座椅靠背底板上。优选地,突起可以插入相应的空隙(例如模槽或通孔)内,其可以是加固件,座椅靠背底板或者两者兼有的形式。图3所示的是从肋材60中伸出的多个突起70,这些突起70可以插入加固件32上的通孔72。According to the present invention, both the seat back bottom and the reinforcement member may include one or more protrusions to assist the reinforcement member to be positioned and connected to the seat back bottom. Preferably, the protrusions can be inserted into corresponding voids (such as molded grooves or through holes), which can be in the form of reinforcements, seat back pans or both. Illustrated in FIG. 3 are a plurality of protrusions 70 protruding from the ribs 60 , and these protrusions 70 can be inserted into the through holes 72 on the stiffener 32 .

具体应用时,应根据以下部分或所有准则,最优化每个加固构件的设计和位置,或其在座椅靠背中的制作模式。对于每一种应用,用熟练的技术人员会欣赏到:使用该具体的加固构件可以帮助降低由于机动车快加速或快减速或者座椅后部乘客或货物(例如顶装式中心安全带,顶装式儿童安全座以及行李的尖顶)所导致的弯折效应。例如,在一个优选的实施方式中,通常选用的加固结构或模式是将具有较高挠矩的加固构件垂直设置到可扭转的弯曲斜面处。For specific applications, the design and location of each reinforcement member, or its mode of fabrication in the seat back, should be optimized according to some or all of the following criteria. For each application, skilled artisans will appreciate that the use of the specific reinforcement member can help reduce the risk of damage caused by rapid acceleration or deceleration of the motor vehicle or passengers or cargo behind the seat (e.g., top-loaded center belt, top-loaded center belt, installed child safety seat and the peak of the luggage) caused by the bending effect. For example, in a preferred embodiment, the generally selected reinforcement structure or mode is to vertically arrange the reinforcement member with a relatively high bending moment on the twistable curved slope.

本发明提供的座椅靠背系统可应用到前座,后座,折叠椅等处。也可考虑将其加工成适用于儿童安全座椅系绳,中后部安全带的座椅靠背系统。该系统还应符合预先制定的标准(例如强度标准)。专利USP60/414,040中已对座椅,系绳,安全带和标准进行了详尽的讨论。The seat back system provided by the invention can be applied to front seats, rear seats, folding chairs and the like. It can also be considered to be processed into a seat back system suitable for child safety seat tethers and middle and rear seat belts. The system should also meet pre-established standards (such as strength standards). Seats, tethers, safety belts and standards are discussed in detail in USP 60/414,040.

虽然本发明仅涉及了机动车座椅系统,但熟手技工将意识到该系统也可应用于其它座椅,如飞机和公交车座椅或礼堂和体育场座椅。Although the present invention relates only to automotive seating systems, skilled artisans will appreciate that the system is applicable to other seating, such as airplane and bus seating or auditorium and stadium seating.

以上仅是对本发明示例性的实施方式。而本领域技术人员由以上所述内容,附图和权利要求即可意识到,正如以下权利要求所定义的那样,在不偏离本发明性质和范围的前提下,可进行各种变动,改进和变形。尤其是对于所述混合物,装配,装置,组分等表现出的各种功能,在无特定说明的情况下,即便具有特定功能的项与术语所描述结构不等同,也采用该术语描述相应项。另外,一个实施方式中涉及的具体特征,可与其它说明性实施方式中的特征相结合。The above are merely exemplary embodiments of the present invention. Those skilled in the art can appreciate from the above description, the accompanying drawings and the claims that, as defined in the following claims, various changes, improvements and modifications can be made without departing from the nature and scope of the present invention. out of shape. Especially for the various functions exhibited by the mixture, assembly, device, component, etc., in the absence of specific instructions, even if the item with a specific function is not equivalent to the structure described by the term, the term is used to describe the corresponding item . Additionally, specific features referred to in one embodiment may be combined with features in other illustrative embodiments.

Claims (20)

1. motor vehicle seat chair back system method for making comprises:
Provide one at least at first base plate of self-propelled vehicle part lateral extent, this first base plate is limited and is provided with the main wall of crossing over continuously basically between whole peripheral boundary by peripheral boundary;
Provide one to be arranged at reinforcing member on this first base plate, wherein:
I) this first base plate is made by plastic material, has a match surface on it at least;
Ii) reinforcing member is made by the another kind of material that is different from the first base plate plastic material, has a match surface on it at least; And
Adopt a kind of adhesives that the match surface of the match surface of reinforcing member and first base plate is bonding, thus, reinforcing member substantial lateral ground, end wise or two to stretching along main wall with having concurrently.
2. method according to claim 1, wherein, at least one match surface of described reinforcing member or at least one match surface of described first base plate are low-yield surfaces, and adhesives can be bonded on the low-yield surface.
3. method according to claim 2, wherein, the surface energy on the low-yield surface of being made by plastic material is lower than 45mJ/m 2
4. method according to claim 1 and 2, wherein, described plastic material comprises a kind of poly-mer, this poly-mer is selected from polyolefin, polystyrene, polyamide, polybutylene terephthalate, acrylonitrile-butadiene-styrene, polycarbonate or their combination.
5. method according to claim 4, wherein, plastic material comprises a kind of filler.
6. method according to claim 5, wherein, filler is selected from short glass fiber, long glass fibres, short natural fiber or the right fiber of the vast of heaven.
7. according to the described method of claim 1,2 or 3, wherein, described plastic material is selected from the polypropylene of having filled short glass fiber, has filled the polypropylene of long glass fibres, has filled the polyamide and the polyamide alloy of having filled glass of glass.
8. according to any described method among the claim 1-3,5,6, wherein, reinforcing member and match surface thereof are made of metal, and described metal is selected from steel, aluminium or their combination.
9. according to any described method among the claim 1-3,5,6, it further comprises, adhesives is applied directly on the match surface of base plate, and described base plate match surface is not carried out pretreatment.
10. according to any described method among the claim 1-3,5,6, wherein, adhesives comprises: a kind of organo-borane/amine complex and can be by the free radical polymerization polymerization have undersaturated one or more monomers of ethylene linkage, oligomer or a poly-mer.
11. method according to claim 10, wherein, adhesives further comprises a kind of cmpd, and this cmpd can cause complex to separate to discharge organo-borane, has the polymerization of undersaturated one or more monomers of ethylene linkage, oligomer or poly-mer with initiation.
12. method according to claim 10, wherein, the amine moiety in organo-borane/amine complex is selected from: the amine with amidine structural constituent; The aliphatics heterocycle that in heterocycle, has at least one nitrogen; Additional have one or more hydrogen bonds to accept the primary amine of group, wherein accepts to have at least two carbon atoms between the group at primary amine and hydrogen bond; Or conjugated imines.
13. method according to claim 10, wherein, amine is selected from: dimethylaminopropylamine, methoxy propanamine, dimethylaminoethylam,ne, dimethylaminobutylam,ne, methoxybutyl amine, methoxyethyl amine, ethoxy propylamine, propoxypropylamine, the polyalkylene ether of amine end-blocking, aminopropyl morpholine, IPD and aminopropyl propane diamine.
14. method according to claim 13, wherein, amine end-blocking polyalkylene ether is trimethylolpropane-three (polypropylene glycol-amine end-blocking) ether.
15. method according to claim 10, wherein, the organo-borane in organic boron/amine complex partly is selected from trialkylborane or alkyl-cycloalkyl borine.
16. according to any described method among claim 1-3,5,6, the 11-15, wherein, one or more profile phases that at least one match surface limited on one or more profiles that at least one match surface limited on the reinforcing member and the base plate are corresponding.
17. method according to claim 16, wherein, described one or more profiles of reinforcing member are limited by timber or groove at least in part, and described one or more profiles of base plate are limited by timber or groove at least in part.
18. according to any described method among claim 1-3,5,6, the 11-15,17, wherein, the method for making of base plate is selected from compression molding, injection moulding or blow moulding.
19. according to any described method among claim 1-3,5,6, the 11-15,17, wherein, the fabrication cycle of seat back system was no more than for 40 seconds.
20. according to any described method among claim 1-3,5,6, the 11-15,17, wherein, the fabrication cycle of seat back system was no more than for 30 seconds.
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