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CN100414667C - Storage capacitor, forming method thereof and display comprising storage capacitor - Google Patents

Storage capacitor, forming method thereof and display comprising storage capacitor Download PDF

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Publication number
CN100414667C
CN100414667C CNB2006101107158A CN200610110715A CN100414667C CN 100414667 C CN100414667 C CN 100414667C CN B2006101107158 A CNB2006101107158 A CN B2006101107158A CN 200610110715 A CN200610110715 A CN 200610110715A CN 100414667 C CN100414667 C CN 100414667C
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layer
electrode
dielectric layer
doping
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CN1905129A (en
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丘大维
郑逸圣
廖盈奇
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AUO Corp
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AU Optronics Corp
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Abstract

A method for forming a storage capacitor includes: sequentially forming a semiconductor layer and a first dielectric layer on a substrate; forming a patterned photoresist layer on the first dielectric layer, the patterned photoresist layer including a first region and a second region adjacent to the first region; removing the first dielectric layer and the semiconductor layer which are not shielded by the patterned photoresist layer; removing the first region to expose the first dielectric layer; carrying out a doping process by taking the second region as a shield to form at least one doped region in a part of the semiconductor layer to be used as a first electrode; removing the second region; forming a second dielectric layer and a conductive layer in sequence to cover the substrate and the first dielectric layer; and patterning the conductive layer to form a second electrode substantially corresponding to the first electrode.

Description

储存电容及其形成方法与包括该储存电容的显示器 Storage capacitor, method for forming the same, and display including the storage capacitor

技术领域 technical field

本发明涉及一种储存电容,特别是涉及一种可减少光掩模的储存电容的制造工艺及其所形成的储存电容。The invention relates to a storage capacitor, in particular to a manufacturing process capable of reducing the storage capacitor of a photomask and the formed storage capacitor.

背景技术 Background technique

图1至3显示传统有源元件基板的薄膜晶体管与电容的制造工艺剖面图,如图1所示,提供基板100,包括晶体管区100A和电容区100B。在基板100上沉积并图案化形成半导体层101,分别位于晶体管区100A和电容区100B。如图2所示,在半导体层101和基板100上沉积绝缘层103,分别在晶体管区100A作为薄膜晶体管的栅极绝缘层和在电容区100B作为储存电容的介电层。接着,在绝缘层103上形成光致抗蚀剂,并图案化形成图案化光致抗蚀剂105,并露出晶体管区100A中半导体层101的两端和储存电容区100B的半导体层101。之后,再以掺杂工艺107在晶体管区100A半导体层101的两端形成源极/漏极102,并且掺杂电容区100B的半导体层101形成储存电容的下电极。完成掺杂工艺107后移除图案化光致抗蚀剂105。1 to 3 show cross-sectional views of the manufacturing process of thin film transistors and capacitors of conventional active element substrates. As shown in FIG. 1 , a substrate 100 is provided, including a transistor region 100A and a capacitor region 100B. The semiconductor layer 101 is deposited and patterned on the substrate 100 , respectively located in the transistor region 100A and the capacitor region 100B. As shown in FIG. 2 , an insulating layer 103 is deposited on the semiconductor layer 101 and the substrate 100 , serving as the gate insulating layer of the TFT in the transistor region 100A and as the dielectric layer of the storage capacitor in the capacitor region 100B. Next, a photoresist is formed on the insulating layer 103 , and a patterned photoresist 105 is patterned to expose both ends of the semiconductor layer 101 in the transistor region 100A and the semiconductor layer 101 in the storage capacitor region 100B. After that, source/drain electrodes 102 are formed at both ends of the semiconductor layer 101 in the transistor region 100A by doping process 107 , and the semiconductor layer 101 in the capacitor region 100B is doped to form the lower electrode of the storage capacitor. The patterned photoresist 105 is removed after the doping process 107 is completed.

接着,在绝缘层103上沉积并图案化形成导电层109,分别作为晶体管区100A的栅极和电容区100B的上电极。最后再以晶体管区100A的导电层109为屏蔽,进行轻掺杂工艺111,形成轻掺杂区115。Next, a conductive layer 109 is deposited and patterned on the insulating layer 103 to serve as the gate of the transistor region 100A and the upper electrode of the capacitor region 100B, respectively. Finally, with the conductive layer 109 of the transistor region 100A as a shield, a lightly doped process 111 is performed to form a lightly doped region 115 .

传统上在形成薄膜晶体管和储存电容的工艺步骤中需要三道光掩模,首先在图案化形成半导体层101中需要第一道光掩模。接着在图案化形成光致抗蚀剂105作为掺杂区102掺杂时的屏蔽则需要第二道光掩模,而掺杂区102也可称为源极区/漏极区。最后在图案化形成导电层109作为栅极和上电极时需要第三道光掩模。Traditionally, three photomasks are required in the process steps of forming thin film transistors and storage capacitors. Firstly, the first photomask is required in patterning the semiconductor layer 101 . Then, a second photomask is required when the photoresist 105 is patterned to form a mask for doping the doped region 102 , and the doped region 102 can also be called a source region/drain region. Finally, a third photomask is required when patterning the conductive layer 109 as the gate and the upper electrode.

在工艺中,光掩模数量是决定工艺成本的重要因素,因此本领域亟需一种能减少光掩模的方法来降低其制造成本。In the process, the number of photomasks is an important factor determining the cost of the process, so there is an urgent need in the art for a method that can reduce the number of photomasks to reduce its manufacturing cost.

发明内容Contents of the invention

鉴于此,本发明的目的是提供一种储存电容的形成方法,利用具有不同光穿透度的光掩模来减少薄膜晶体管和储存电容制造工艺所需的光掩模数。In view of this, the object of the present invention is to provide a method for forming a storage capacitor, which uses photomasks with different light transmittances to reduce the number of photomasks required for the manufacturing process of thin film transistors and storage capacitors.

为达上述目的,本发明提供一种储存电容的形成方法,包括:依次形成半导体层和第一介电层在基板上;形成图案化光致抗蚀剂层在该第一介电层上,且该图案化光致抗蚀剂包括第一区和第二区邻近于该第一区;移除未被该图案化光致抗蚀剂层所遮蔽的该第一介电层和该半导体层;移除该第一区,用以露出该第一介电层;以该第二区作为屏蔽进行掺杂工艺,形成至少一个掺杂区在部分该半导体层中,用以作为第一电极;移除该第二区;依次形成第二介电层和导电层,覆盖该基板和该第一介电层;并且图案化该导电层,用以形成第二电极,且基本上对应于该第一电极。To achieve the above object, the present invention provides a method for forming a storage capacitor, comprising: sequentially forming a semiconductor layer and a first dielectric layer on a substrate; forming a patterned photoresist layer on the first dielectric layer, and the patterned photoresist includes a first region and a second region adjacent to the first region; removing the first dielectric layer and the semiconductor layer not shielded by the patterned photoresist layer ; removing the first region to expose the first dielectric layer; performing a doping process using the second region as a mask to form at least one doped region in part of the semiconductor layer to serve as a first electrode; removing the second region; sequentially forming a second dielectric layer and a conductive layer covering the substrate and the first dielectric layer; and patterning the conductive layer to form a second electrode substantially corresponding to the first an electrode.

本发明还提供一种储存电容,包括:第一电极,设置在基板上,且该第一电极具有耗尽区位于该第一电极的两端其中之一上和至少一个掺杂区邻近于该耗尽区;介电层,设置在该第一电极上;和第二电极,设置在该介电层上,且基本上对应于该第一电极。The present invention also provides a storage capacitor, comprising: a first electrode disposed on a substrate, and the first electrode has a depletion region located on one of two ends of the first electrode and at least one doped region adjacent to the first electrode. A depletion region; a dielectric layer disposed on the first electrode; and a second electrode disposed on the dielectric layer substantially corresponding to the first electrode.

本发明尚提供一种显示器,具有基板,包括:半导体图案层,分别形成在该基板的至少一个晶体管区和至少一个电容区上,其中,位于该电容区上的该半导体图案层具有至少一个耗尽区位于该第一电极的两端其中之一上和至少一个掺杂区邻近于该耗尽区,且位于该晶体管区上的该半导体图案层的二端,具有高浓度掺杂区;第一介电层,形成在该半导体图案层上;第一导体图案层,形成在第一介电层上,且分别对应位于该电容区上和晶体管区上的该半导体图案层;保护层,形成在该基板上,且覆盖该第一导体图案层;和第二导体图案层,形成在该保护层上,且分别电连接在该晶体管区上的该半导体图案层的二端的该高浓度掺杂区。The present invention still provides a display, which has a substrate, including: a semiconductor pattern layer, respectively formed on at least one transistor region and at least one capacitor region of the substrate, wherein the semiconductor pattern layer on the capacitor region has at least one power dissipation The depletion region is located on one of the two ends of the first electrode and at least one doped region is adjacent to the depletion region, and the two ends of the semiconductor pattern layer on the transistor region have a high-concentration doped region; A dielectric layer, formed on the semiconductor pattern layer; a first conductor pattern layer, formed on the first dielectric layer, and respectively corresponding to the semiconductor pattern layer located on the capacitor region and the transistor region; a protective layer formed on the substrate, covering the first patterned conductor layer; and a second patterned conductor layer, formed on the protection layer, and respectively electrically connected to the high-concentration-doped two ends of the semiconductor patterned layer on the transistor region district.

为了让本发明的上述和其它目的、特征和优点能更明显易懂,下文特举一优选实施例,并结合附图作详细说明。In order to make the above and other objects, features and advantages of the present invention more comprehensible, a preferred embodiment is given below and described in detail with reference to the accompanying drawings.

附图说明 Description of drawings

图1至3显示传统有源元件基板上薄膜晶体管与电容的制造工艺剖面图。1 to 3 show cross-sectional views of the manufacturing process of thin film transistors and capacitors on conventional active device substrates.

图4至15显示本发明优选实施例有源元件基板的工艺流程剖面图。4 to 15 show cross-sectional views of the process flow of the active device substrate according to the preferred embodiment of the present invention.

图16至19显示本发明实施例的变化例的剖面图。16 to 19 show cross-sectional views of variations of the embodiments of the present invention.

简单符号说明simple notation

基板~100;                 晶体管区~100A;Substrate ~ 100; Transistor area ~ 100A;

电容区~100B;              绝缘层~103;Capacitance area ~ 100B; Insulation layer ~ 103;

源极区/漏极区~102;        导电层~109;Source region/drain region ~ 102; Conductive layer ~ 109;

图案化光致抗蚀剂~105;     基板~400;Patterned photoresist ~ 105; Substrate ~ 400;

晶体管区~400A;            电容区~400B;Transistor area ~ 400A; Capacitance area ~ 400B;

半导体层~401;             介电层~403;Semiconductor layer ~ 401; Dielectric layer ~ 403;

光致抗蚀剂~405A和405B;    厚光致抗蚀剂区~405a;Photoresist ~ 405A and 405B; Thick photoresist area ~ 405a;

薄光致抗蚀剂区~405b;      掺杂工艺~407;Thin photoresist region ~ 405b; Doping process ~ 407;

掺杂区~409;               耗尽区~408;Doping region ~ 409; Depletion region ~ 408;

阶梯差~402a、402b;        导电层~413;Step difference ~ 402a, 402b; Conductive layer ~ 413;

介电层~411;               光致抗蚀剂~415A、415B;Dielectric layer ~ 411; Photoresist ~ 415A, 415B;

掺杂区~419;               掺杂工艺~417;Doping area ~ 419; Doping process ~ 417;

轻掺杂区~421;             轻掺杂工艺~418;Lightly doped region ~ 421; Lightly doped process ~ 418;

介电层~423;               接触窗~425;Dielectric layer ~ 423; Contact window ~ 425;

源极区/漏极区接触~427;    保护层~429;Source region/drain region contact ~ 427; Protective layer ~ 429;

接触窗~431;               导电层~433;Contact window ~ 431; Conductive layer ~ 433;

介电层~437;               发光层~435。Dielectric layer ~ 437; Light emitting layer ~ 435.

具体实施方式 Detailed ways

以下将结合图4-15说明本发明的优选实施例,应注意的是,虽然以下实施例是以储存电容与顶部栅极晶体管(top gate transistor)的制作说明,但本领域的技术人员可以理解的是,本发明的储存电容并不限于搭配特定类型的薄膜晶体管(TFT),也不限定应用在显示面板的储存电容。The preferred embodiment of the present invention will be described below in conjunction with FIGS. It is worth noting that the storage capacitor of the present invention is not limited to be matched with a specific type of thin film transistor (TFT), nor is it limited to the storage capacitor applied to a display panel.

如图4所示,提供基板400,包括晶体管区400A和电容区400B,其中基板400可为透明基板,例如是:玻璃或石英,也可为不透明基板,例如是:晶片(wafer)或陶瓷,或是除了上述刚性基板外也可为可挠性基板,例如:塑料、聚酯(polyester)或橡胶。在基板400上依次形成半导体层401,其材料包括多晶硅、单晶硅、非晶硅、微晶硅或上述材料的组合,和介电层403,其材料包括无机化合物(如:氧化硅、氮化硅、氮氧化硅、碳化硅、碳氧化硅或上述材料的组合)、有机化合物(如:聚酯、环氧类聚合物、有机硅化合物、丙烯类聚合物、类似的材料或上述材料的组合)。接着,在介电层403上形成光致抗蚀剂层,并以光刻工艺分别在晶体管区400A和电容区400B形成光致抗蚀剂405A和405B,其中电容区400B的光致抗蚀剂405B是通过具有不同光穿透度的光掩模(如:半阶式光掩模(half-tone photomask)、灰阶式光掩模(gray-level photomask)、栅状图案光掩模(slit-pattern photomask)、绕(衍)射式光掩模(diffraction photomask))图案化形成,具有厚光致抗蚀剂区405a和薄光致抗蚀剂区405b,且厚光致抗蚀剂区405a邻近于薄光致抗蚀剂区405b。如图5所示,以光致抗蚀剂405A和405B为屏蔽进行蚀刻工艺,优选为各向同性蚀刻工艺,可为干式蚀刻或是湿式蚀刻,用来移除未被光致抗蚀剂405A和405B遮蔽的介电层403。而湿式蚀刻的方法包括浸泡蚀刻、喷雾蚀刻或其它类似的蚀刻方法,且干式蚀刻的方法包括反应式离子蚀刻、等离子蚀刻或其它类似的蚀刻方法。As shown in FIG. 4 , a substrate 400 is provided, including a transistor region 400A and a capacitor region 400B, wherein the substrate 400 can be a transparent substrate, such as glass or quartz, or an opaque substrate, such as a wafer (wafer) or ceramics, Alternatively, in addition to the above-mentioned rigid substrate, it may also be a flexible substrate, such as plastic, polyester or rubber. Form semiconductor layer 401 sequentially on substrate 400, its material comprises polycrystalline silicon, monocrystalline silicon, amorphous silicon, microcrystalline silicon or the combination of above-mentioned material, and dielectric layer 403, its material comprises inorganic compound (such as: silicon oxide, nitrogen silicon carbide, silicon oxynitride, silicon carbide, silicon oxycarbide or a combination of the above materials), organic compounds (such as: polyesters, epoxy polymers, organosilicon compounds, acrylic polymers, similar materials or combinations of the above materials combination). Next, a photoresist layer is formed on the dielectric layer 403, and photoresists 405A and 405B are respectively formed in the transistor region 400A and the capacitor region 400B by a photolithography process, wherein the photoresist of the capacitor region 400B 405B is through a photomask with different light penetration (such as: half-tone photomask, gray-level photomask, grid pattern photomask (slit photomask), etc. -pattern photomask), around (diffraction) photomask (diffraction photomask)) patterned formation, have thick photoresist region 405a and thin photoresist region 405b, and thick photoresist region 405a is adjacent to thin photoresist region 405b. As shown in FIG. 5, the etching process is carried out with the photoresist 405A and 405B as a mask, preferably an isotropic etching process, which can be dry etching or wet etching, and is used to remove the uncoated photoresist. 405A and 405B shield the dielectric layer 403 . The wet etching method includes immersion etching, spray etching or other similar etching methods, and the dry etching method includes reactive ion etching, plasma etching or other similar etching methods.

接着,如图6A所示,再以各向同性蚀刻步骤,例如是干式蚀刻或湿式蚀刻,将未被光致抗蚀剂405A和405B遮蔽的半导体层401移除。或者如图6B所示,以各向异性蚀刻工艺,例如是干式蚀刻工艺或是湿式工艺,将未被光致抗蚀剂405A和405B遮蔽的半导体层401移除。而湿式蚀刻的方法包括浸泡蚀刻、喷雾蚀刻或其它类似的蚀刻方法,且干式蚀刻的方法包括反应式离子蚀刻、等离子蚀刻或其它类似的蚀刻方法。接着如图7A及7B所示,其中图7A接续图6A的工艺,而图7B接续图6B的工艺,进行等离子处理工艺(plasma trimming process,如:灰化工艺(ashing process))至光致抗蚀剂405B的薄光致抗蚀剂区405b完全移除为止,并露出电容区400B中部分介电层403的顶部表面,而厚光致抗蚀剂区405a则残留在介电层403上,并遮蔽半导体层401的两端。之后,进行掺杂工艺407,例如是N型掺杂或P型掺杂,在电容区400B未被厚光致抗蚀剂405a遮蔽的半导体层401中形成掺杂区409,作为储存电容的第一电极。如图7A和图7B所示,由于厚光致抗蚀剂区405a遮住半导体层401的两端,因此在掺杂工艺407后会在电容区400B的半导体层401的两端形成耗尽区408,因在耗尽区408中没有存在掺杂工艺407中所使用的N型或P型掺杂的掺杂物质,所以,耗尽区408也可称之为非掺杂区。Next, as shown in FIG. 6A , the semiconductor layer 401 not covered by the photoresists 405A and 405B is removed by an isotropic etching step, such as dry etching or wet etching. Alternatively, as shown in FIG. 6B , the semiconductor layer 401 not covered by the photoresists 405A and 405B is removed by an anisotropic etching process, such as a dry etching process or a wet etching process. The wet etching method includes immersion etching, spray etching or other similar etching methods, and the dry etching method includes reactive ion etching, plasma etching or other similar etching methods. Then as shown in Figures 7A and 7B, where Figure 7A continues the process of Figure 6A, and Figure 7B continues the process of Figure 6B, a plasma trimming process (plasma trimming process, such as: ashing process (ashing process)) is performed to photoresist The thin photoresist region 405b of the etchant 405B is completely removed, exposing a portion of the top surface of the dielectric layer 403 in the capacitor region 400B, while the thick photoresist region 405a remains on the dielectric layer 403, And shield both ends of the semiconductor layer 401 . Afterwards, a doping process 407 is performed, such as N-type doping or P-type doping, to form a doping region 409 in the semiconductor layer 401 that is not covered by the thick photoresist 405a in the capacitor region 400B, as the first capacitor of the storage capacitor. an electrode. As shown in FIGS. 7A and 7B, since the thick photoresist region 405a covers both ends of the semiconductor layer 401, a depletion region will be formed at both ends of the semiconductor layer 401 in the capacitor region 400B after the doping process 407. 408 , because there is no N-type or P-type doping substance used in the doping process 407 in the depletion region 408 , so the depletion region 408 can also be called a non-doped region.

如图8A和图8B所示,其中图8A延续图7A,而图8B延续图7B的工艺,将晶体管区400A和电容区400B的光致抗蚀剂全部移除。由于图5至7B的工艺中,是先以各向同性蚀刻工艺移除未被光致抗蚀剂遮蔽的介电层403,再以各向异性蚀刻工艺移除未被光致抗蚀剂遮蔽的半导体层401,会在晶体管区400A和电容区400B中半导体层401与介电层403的两端产生阶梯差402a和402b,因此在移除晶体管区400A和电容区400B的光致抗蚀剂后,会再进行各相异性蚀刻工艺(未显示),消除如图7B中所示的阶梯差402a和402b,如图8B所示。然而,若为了减低工艺上的需求,则可免除消除如图7B中所示的阶梯差402a和402b的蚀刻工艺,而所形成的结构就大致上如图7B去除光致抗蚀剂图案层405a后所示。As shown in FIGS. 8A and 8B , where FIG. 8A is a continuation of FIG. 7A , and FIG. 8B is a continuation of the process of FIG. 7B , the photoresist in the transistor region 400A and capacitor region 400B is completely removed. 5 to 7B, the dielectric layer 403 not covered by the photoresist is removed by an isotropic etching process, and then the dielectric layer 403 not covered by the photoresist is removed by an anisotropic etching process. The semiconductor layer 401 will produce step differences 402a and 402b at the two ends of the semiconductor layer 401 and the dielectric layer 403 in the transistor region 400A and the capacitor region 400B, so the photoresist in the transistor region 400A and the capacitor region 400B Afterwards, an anisotropic etching process (not shown) is performed again to eliminate the step differences 402a and 402b as shown in FIG. 7B , as shown in FIG. 8B . However, if in order to reduce the requirements on the process, the etching process for eliminating the step differences 402a and 402b as shown in FIG. 7B can be omitted, and the formed structure is substantially removed from the photoresist pattern layer 405a as shown in FIG. 7B shown after.

如图9所示,在基板400和介电层403上依次沉积介电层411和导电层413,其中介电层411包括无机化合物(如:氧化硅、氮化硅、氮氧化硅、碳化硅、碳氧化硅或上述材料的组合)、有机化合物(如:聚酯、环氧类聚合物、有机硅化合物、丙烯类聚合物、类似的材料或上述材料的组合),而导电层413包括透明导电层(如:铟锡氧化物(indium tin oxide,ITO)、铝锌氧化物(aluminum zinc oxide,AZO)、铟锌氧化物(indium zinc oxide,IZO)、镉锡氧化物(cadmium tin oxide,CTO))、非透明导电层(如:钛(titanium,Ti)、钽(tantalum,Ta)、钼(molybdenum,Mo)、铝(aluminum,Al)、钕(neodymium,Nd)、金(golden,Au)、银(silver,Ag)、铜(copper,Cu))或上述材料的组合。接着,在导电层413上沉积并图案化光致抗蚀剂层,分别在晶体管区400A和电容区400B形成图案化光致抗蚀剂415A和415B,如图10所示,其中图案化光致抗蚀剂415A对应至晶体管区400A的半导体层401且未遮蔽晶体管区400A中半导体层401的两端,以利后续的源极和漏极的掺杂工艺。而光致抗蚀剂415B则完全遮蔽电容区400B且遮蔽部分基板400。As shown in FIG. 9, a dielectric layer 411 and a conductive layer 413 are sequentially deposited on the substrate 400 and the dielectric layer 403, wherein the dielectric layer 411 includes an inorganic compound (such as: silicon oxide, silicon nitride, silicon oxynitride, silicon carbide , silicon carbide or a combination of the above materials), organic compounds (such as: polyester, epoxy polymer, organosilicon compound, acrylic polymer, similar materials or a combination of the above materials), and the conductive layer 413 includes transparent Conductive layer (such as: indium tin oxide (ITO), aluminum zinc oxide (aluminum zinc oxide, AZO), indium zinc oxide (indium zinc oxide, IZO), cadmium tin oxide (cadmium tin oxide, CTO)), non-transparent conductive layer (such as: titanium (titanium, Ti), tantalum (tantalum, Ta), molybdenum (molybdenum, Mo), aluminum (aluminum, Al), neodymium (neodymium, Nd), gold (golden, Au), silver (silver, Ag), copper (copper, Cu)) or a combination of the above materials. Next, deposit and pattern a photoresist layer on the conductive layer 413, and form patterned photoresists 415A and 415B in the transistor region 400A and the capacitor region 400B, respectively, as shown in FIG. 10 , wherein the patterned photoresist The resist 415A corresponds to the semiconductor layer 401 of the transistor region 400A and does not cover both ends of the semiconductor layer 401 in the transistor region 400A, so as to facilitate subsequent source and drain doping processes. The photoresist 415B completely covers the capacitor region 400B and partially covers the substrate 400 .

如图11所示,以各向同性蚀刻工艺,例如是干式蚀刻或湿式蚀刻,蚀刻移除未被光致抗蚀剂415A和光致抗蚀剂415B遮蔽的导电层413,再以掺杂工艺417,例如是N型掺杂或P型掺杂,在晶体管区400A中未被光致抗蚀剂415A遮蔽的半导体层401的两端形成掺杂区419作为晶体管的源极区/漏极区,其中掺杂区419的掺杂浓度可与电容区400B中掺杂区409的掺杂浓度相同或不相同。上述湿式蚀刻的方法包括浸泡蚀刻、喷雾蚀刻或其它类似的蚀刻方法,且干式蚀刻的方法包括反应式离子蚀刻、等离子蚀刻或其它类似的蚀刻方法。如图12所示,移除光致抗蚀剂415A和415B后,再以导电层413为屏蔽,进行轻掺杂工艺418,在晶体管区400A中导电层413与掺杂区419间的半导体层401中形成轻掺杂区(LDD region)421,换句话说,就是在晶体管区400A中导电层413投射在半导体层401上与半导体层401中的掺杂区419之间具有未屏蔽区域,而在进行轻掺杂工艺418后,轻掺杂区(LDD region)421就形成在未屏蔽区域中,其中轻掺杂区421的掺杂浓度可与电容区400B中掺杂区409的掺杂浓度相同或不相同,在另一实施例中电容区400B中掺杂区409的掺杂浓度约介于晶体管区400A中轻掺杂区421与掺杂区419的掺杂浓度之间。相比于传统有源元件基板上薄膜晶体管与电容的工艺中,本发明利用具有不同光穿透度的光掩模在电容区形成薄厚光致抗蚀剂的方式,只用一道光掩模即完成第一电极的图案化与掺杂,使得在后续工艺中只需再一道光掩模(图案化形成光致抗蚀剂415A和415B)即可完成薄膜晶体管中源极区/漏极区和轻掺杂区(LDD)的工艺,大大降低其制造成本。如图12所示,本发明的储存电容具有第一电极,包括掺杂区409及其两端的耗尽区408、第二电极413,介电层403、411,夹设在第二电极与第一电极之间。As shown in FIG. 11 , with an isotropic etching process, such as dry etching or wet etching, the conductive layer 413 that is not covered by the photoresist 415A and the photoresist 415B is etched away, and then the doping process 417, such as N-type doping or P-type doping, forming a doping region 419 at both ends of the semiconductor layer 401 not covered by the photoresist 415A in the transistor region 400A as the source region/drain region of the transistor , wherein the doping concentration of the doping region 419 may be the same as or different from the doping concentration of the doping region 409 in the capacitor region 400B. The aforementioned wet etching methods include immersion etching, spray etching or other similar etching methods, and the dry etching methods include reactive ion etching, plasma etching or other similar etching methods. As shown in FIG. 12 , after removing the photoresists 415A and 415B, the conductive layer 413 is used as a shield to perform a light doping process 418, and the semiconductor layer between the conductive layer 413 and the doped region 419 in the transistor region 400A is A lightly doped region (LDD region) 421 is formed in 401, in other words, there is an unshielded region between the conductive layer 413 projected on the semiconductor layer 401 and the doped region 419 in the semiconductor layer 401 in the transistor region 400A, and After the lightly doped process 418 is performed, a lightly doped region (LDD region) 421 is formed in the unshielded region, wherein the doping concentration of the lightly doped region 421 can be compared with the doping concentration of the doped region 409 in the capacitor region 400B The same or different, in another embodiment, the doping concentration of the doped region 409 in the capacitor region 400B is approximately between the doping concentrations of the lightly doped region 421 and the doped region 419 in the transistor region 400A. Compared with the process of thin-film transistors and capacitors on the traditional active element substrate, the present invention uses photomasks with different light penetration to form thin and thick photoresists in the capacitor area, and only one photomask is used. Complete the patterning and doping of the first electrode, so that only one more photomask (patterned to form photoresist 415A and 415B) is needed to complete the source region/drain region and The process of the lightly doped region (LDD) greatly reduces its manufacturing cost. As shown in Figure 12, the storage capacitor of the present invention has a first electrode, including a doped region 409 and a depletion region 408 at both ends thereof, a second electrode 413, and dielectric layers 403, 411, which are sandwiched between the second electrode and the first electrode. between one electrode.

图13至图15显示利用本发明储存电容的显示器有源元件基板的工艺剖面图。如图13所示,在图12所示的结构上形成介电层423,可为无机化合物(如:氧化硅、氮化硅、氮氧化硅、碳化硅、碳氧化硅或上述材料的组合)、有机化合物(如:聚酯、环氧类聚合物、有机硅化合物、丙烯类聚合物、类似的材料或上述材料的组合),并图案化介电层423、介电层411和介电层403形成接触窗425,且露出晶体管区400A中部分掺杂区419的预部表面。接着,在图13所示的结构上形成导电层,其材料包括透明导电材料(如:铟锡氧化物(indium tin oxide,ITO)、铝锌氧化物(aluminum zinc oxide,AZO)、铟锌氧化物(indium zinc oxide,IZO)、镉锡氧化物(cadmium tin oxide,CTO))、非透明导电材料(如:钛(titanium,Ti)、钽(tantalum,Ta)、钼(molybdenum,Mo)、铝(aluminum,Al)、钕(neodymium,Nd)、金(golden,Au)、银(silver,Ag)、铜(copper,Cu))或上述材料的组合,填满接触窗425并与掺杂区419的顶部表面电连接,之后,将其图案化形成源极区/漏极区接触427,如图14所示。FIG. 13 to FIG. 15 show the cross-sectional process views of the display active element substrate using the storage capacitor of the present invention. As shown in FIG. 13, a dielectric layer 423 is formed on the structure shown in FIG. 12, which can be an inorganic compound (such as silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, silicon oxycarbide or a combination of the above materials) , organic compound (such as: polyester, epoxy polymer, organosilicon compound, acrylic polymer, similar materials or combinations of the above materials), and pattern the dielectric layer 423, the dielectric layer 411 and the dielectric layer 403 forms a contact window 425 and exposes the pre-partial surface of the partially doped region 419 in the transistor region 400A. Next, a conductive layer is formed on the structure shown in FIG. 13, and its material includes a transparent conductive material (such as: indium tin oxide (indium tin oxide, ITO), aluminum zinc oxide (aluminum zinc oxide, AZO), indium zinc oxide (indium zinc oxide, IZO), cadmium tin oxide (cadmium tin oxide, CTO)), non-transparent conductive materials (such as: titanium (titanium, Ti), tantalum (tantalum, Ta), molybdenum (molybdenum, Mo), Aluminum (aluminum, Al), neodymium (neodymium, Nd), gold (golden, Au), silver (silver, Ag), copper (copper, Cu)) or a combination of the above materials, filling the contact window 425 and doping The top surface of region 419 is electrically connected and then patterned to form source/drain region contacts 427 as shown in FIG. 14 .

如图15所示,在图14所示的结构上形成保护层429,其材料包括无机化合物(如:氧化硅、氮化硅、氮氧化硅、碳化硅、碳氧化硅或上述材料的组合)、有机化合物(如:聚酯、环氧类聚合物、有机硅化合物、丙烯类聚合物、类似的材料或上述材料的组合),并将其图案化形成接触窗431,并露出源极区/漏极区接触427的部分顶部表面,接着,在保护层429上形成导电层433,填满接触窗431且与源极/漏极接触427电连接,作为显示器的像素电极,若应用在液晶显示器中,则像素电极包括穿透电极、反射电极或穿透电极与反射电极的组合,并用以控制液晶显示器中的液晶层中的液晶分子转向,其中若液晶显示器为穿透型,则像素电极使用透明导电材料作为穿透电极,则导电层433材料优选为ITO、IZO、CTO、AZO或上述材料的组合,若液晶显示器为反射型,则像素电极使用非透明导电材料作为反射电极其材料可为非透明导电材料,优选为Ti、Ta、Mo、Al、Nd、Au、Ag、Cu或上述材料的组合,若液晶显示器为半穿透半反射型,则像素电极使用非透明导电材料与透明导电材料,则导电层433材料优选为ITO、IZO、CTO、AZO、Ti、Ta、Mo、Al、Nd、Au、Ag、Cu、合金或上述材料的组合。若应用在电激发光显示器(electroluminescence display)例如:有机发光二极管(organicelectroluminescence diode,OLED)、高分子发光二极管(polymerelectroluminescence diode,PLED)、或发光二极管(light emitting diode,LED),则会有发光材料435与导电层433或源极/漏极接触427电连接且发光材料435可为有机材料(包括小分子或聚合物)或无机材料,而发光材料435所发出的光线包含萤光、磷光或上述的组合,或形成液晶层作为液晶显示器。再者,为了能够增加半导体层401与基板400之间的附着力,因此可在半导层401形成在基板之前,先将介电层437形成在基板400上,而后续的步骤如同于本发明所述的图形及步骤,在此不再赘言,如图15所示。As shown in FIG. 15, a protective layer 429 is formed on the structure shown in FIG. 14, and its material includes an inorganic compound (such as: silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, silicon oxycarbide or a combination of the above materials) , organic compound (such as: polyester, epoxy polymer, organosilicon compound, propylene polymer, similar materials or a combination of the above materials), and pattern it to form a contact window 431, and expose the source region/ Part of the top surface of the drain region contact 427, then, form a conductive layer 433 on the protection layer 429, fill the contact window 431 and be electrically connected with the source/drain contact 427, as the pixel electrode of the display, if applied to a liquid crystal display Among them, the pixel electrode includes a penetrating electrode, a reflective electrode, or a combination of a penetrating electrode and a reflective electrode, and is used to control the direction of liquid crystal molecules in the liquid crystal layer in the liquid crystal display. If the liquid crystal display is a penetrating type, the pixel electrode uses Transparent conductive material is used as the penetrating electrode, and the material of the conductive layer 433 is preferably ITO, IZO, CTO, AZO or a combination of the above materials. If the liquid crystal display is reflective, the pixel electrode uses a non-transparent conductive material as the reflective electrode, and its material can be The non-transparent conductive material is preferably Ti, Ta, Mo, Al, Nd, Au, Ag, Cu or a combination of the above materials. If the liquid crystal display is a semi-transparent and semi-reflective type, the pixel electrode uses a non-transparent conductive material and a transparent conductive material. material, the material of the conductive layer 433 is preferably ITO, IZO, CTO, AZO, Ti, Ta, Mo, Al, Nd, Au, Ag, Cu, alloy or a combination of the above materials. If it is applied in an electroluminescence display (electroluminescence display) such as: organic light-emitting diode (organicelectroluminescence diode, OLED), polymer light-emitting diode (polymerelectroluminescence diode, PLED), or light emitting diode (light emitting diode, LED), there will be light-emitting materials 435 is electrically connected to the conductive layer 433 or the source/drain contact 427, and the luminescent material 435 can be an organic material (including small molecules or polymers) or an inorganic material, and the light emitted by the luminescent material 435 includes fluorescence, phosphorescence or the above-mentioned combination, or form a liquid crystal layer as a liquid crystal display. Furthermore, in order to increase the adhesion between the semiconductor layer 401 and the substrate 400, the dielectric layer 437 can be formed on the substrate 400 before the semiconductor layer 401 is formed on the substrate, and the subsequent steps are the same as those of the present invention. The graphics and steps described above are not repeated here, as shown in FIG. 15 .

虽然,本发明实施例所述的二耗尽区408、二掺杂区419和二轻掺杂区421的面积都是对称型,然而,二耗尽区408、二掺杂区419和二轻掺杂区421的面积也可非对称型。如图16所示耗尽区408为不对称型。此外,由于二掺杂区419和二轻掺杂区421的面积都可为对称或不对称,也就是说其组合方式可包含二掺杂区419的面积是不对称型,而二轻掺杂区421的面积是对称的或二掺杂区419的面积是对称型,而二轻掺杂区421的面积是不对称型,如图17a及17b所示。再者,二掺杂区419之间也可只有轻掺杂区421,且二掺杂区419的面积也可为非对称型或对称型,如图18a和18b所示。而该图形的步骤,只差在利用图案化光致抗蚀剂415A和导电层413的设计变化,并没有任何重新设计步骤之虑,且也可使用现在的步骤即可。再者,须说明的是,上述实施例都是以储存电容区400B的二端具有耗尽区408为范例说明,然而,储存电容区400B的二端的其中之一上,也可具有耗尽区408,如图19所示,换句话说,该耗尽区408邻近于掺杂区409。而该图形的步骤,只差别在利用图6至图7中图案化光致抗蚀剂405B的厚光致抗蚀剂区405a与薄光致抗蚀剂区405b的设计变化,并没有任何重新设计步骤之虑,且也可使用现在的步骤即可,在此不再赘言。Although the areas of the second depletion region 408, the second doped region 419 and the second lightly doped region 421 described in the embodiment of the present invention are all symmetrical, however, the second depletion region 408, the second doped region 419 and the second lightly doped region The area of the doped region 421 can also be asymmetric. As shown in FIG. 16, the depletion region 408 is asymmetric. In addition, since the areas of the second doped region 419 and the second lightly doped region 421 can be symmetrical or asymmetrical, that is to say, their combination can include that the area of the second doped region 419 is asymmetrical, and the area of the second lightly doped region 421 can be asymmetrical. The area of the region 421 is symmetric or the area of the second doped region 419 is symmetric, while the area of the second lightly doped region 421 is asymmetric, as shown in FIGS. 17a and 17b. Furthermore, only the lightly doped region 421 may exist between the two doped regions 419, and the area of the second doped region 419 may also be asymmetric or symmetrical, as shown in FIGS. 18a and 18b. The only difference in the steps of the pattern is that the patterned photoresist 415A and the design changes of the conductive layer 413 are used, and there is no need to redesign the steps, and the current steps can also be used. Furthermore, it should be noted that the above-mentioned embodiments are all described with the depletion region 408 at both ends of the storage capacitor region 400B as an example. However, one of the two ends of the storage capacitor region 400B may also have a depletion region. 408 , as shown in FIG. 19 , in other words, the depletion region 408 is adjacent to the doped region 409 . And the step of this figure, only difference is in the thick photoresist region 405a and the thin photoresist region 405b design change of patterned photoresist 405B among Fig. 6 to Fig. 7, and does not have any new The design steps are considered, and the current steps can also be used, so I won’t repeat them here.

虽然本发明已以优选实施例揭示如上,然而其并非用以限定本发明,任何本领域的技术人员,在不脱离本发明的精神和范围内,可对其进行些许的更动与修改,因此本发明的保护范围以所附权利要求所界定的为准。Although the present invention has been disclosed above with preferred embodiments, it is not intended to limit the present invention, and any person skilled in the art can make some changes and modifications to it without departing from the spirit and scope of the present invention, therefore The scope of protection of the present invention is defined by the appended claims.

Claims (22)

1. 一种储存电容的形成方法,包括:1. A method for forming a storage capacitor, comprising: 依次形成半导体层和第一介电层在基板上;sequentially forming a semiconductor layer and a first dielectric layer on the substrate; 形成图案化光致抗蚀剂层在该第一介电层上,且该图案化光致抗蚀剂包括第一区和邻近于该第一区的第二区;forming a patterned photoresist layer on the first dielectric layer, and the patterned photoresist includes a first region and a second region adjacent to the first region; 移除未被该图案化光致抗蚀剂层所遮蔽的该第一介电层和该半导体层;removing the first dielectric layer and the semiconductor layer not masked by the patterned photoresist layer; 移除该第一区,用以露出该第一介电层;removing the first region to expose the first dielectric layer; 以该第二区作为屏蔽进行掺杂工艺,形成至少一个掺杂区在部分该半导体层中,用以作为第一电极;performing a doping process using the second region as a mask, forming at least one doped region in a part of the semiconductor layer to serve as a first electrode; 移除该第二区;remove the second zone; 依次形成第二介电层和导电层,覆盖该基板和该第一介电层;并且sequentially forming a second dielectric layer and a conductive layer covering the substrate and the first dielectric layer; and 图案化该导电层,用以形成第二电极,且基本上对应于该第一电极。The conductive layer is patterned to form a second electrode substantially corresponding to the first electrode. 2. 如权利要求1所述的储存电容的形成方法,其中在该掺杂工艺中,未掺杂的该半导体层在该第一电极两端其中之一上形成耗尽区。2. The method for forming a storage capacitor according to claim 1, wherein in the doping process, the undoped semiconductor layer forms a depletion region on one of the two ends of the first electrode. 3. 如权利要求1所述的储存电容的形成方法,其中移除该第一区,用以露出该第一介电层的步骤,是以各向同性蚀刻依次移除未被该图案化光致抗蚀剂遮蔽的该第一介电层与该半导体层。3. The method for forming a storage capacitor according to claim 1, wherein the step of removing the first region to expose the first dielectric layer is to sequentially remove the light not patterned by isotropic etching. The first dielectric layer and the semiconductor layer are masked by resist. 4. 如权利要求1所述的储存电容的形成方法,其中移除该第一区,用以露出该第一介电层的步骤,是以各向同性蚀刻移除未被该图案化光致抗蚀剂遮蔽的该第一介电层;并且4. The method for forming a storage capacitor according to claim 1 , wherein the step of removing the first region to expose the first dielectric layer is to remove the photoinduced by the patterning by isotropic etching. resist masking the first dielectric layer; and 各向异性蚀刻移除未被该图案化光致抗蚀剂遮蔽的该半导体层。Anisotropic etching removes the semiconductor layer not masked by the patterned photoresist. 5. 如权利要求1所述的储存电容的形成方法,其中该掺杂工艺包括N型掺杂或P型掺杂。5. The method for forming a storage capacitor as claimed in claim 1, wherein the doping process comprises N-type doping or P-type doping. 6. 如权利要求1所述的储存电容的形成方法,其中图案化该导电层还包括:6. The method for forming a storage capacitor as claimed in claim 1, wherein patterning the conductive layer further comprises: 形成光致抗蚀剂图案在该导电层上,且其基本上对应于该第一电极,其中,该光致抗蚀剂图案的宽度大于该第一电极的宽度;并且forming a photoresist pattern on the conductive layer substantially corresponding to the first electrode, wherein the photoresist pattern has a width greater than that of the first electrode; and 进行各向同性蚀刻工艺,移除未被该光致抗蚀剂图案遮蔽的该导电层。An isotropic etching process is performed to remove the conductive layer not covered by the photoresist pattern. 7. 一种储存电容,包括:7. A storage capacitor, comprising: 第一电极,设置在基板上,且该第一电极具有至少一个耗尽区位于该第一电极的两端其中之一上和至少一个掺杂区邻近于该耗尽区;a first electrode disposed on the substrate, and the first electrode has at least one depletion region on one of the two ends of the first electrode and at least one doping region adjacent to the depletion region; 介电层,设置在该第一电极上;和a dielectric layer disposed on the first electrode; and 第二电极,设置在该介电层上,且基本上对应于该第一电极。The second electrode is arranged on the dielectric layer and basically corresponds to the first electrode. 8. 如权利要求7所述的储存电容,其中该第一电极包括:多晶硅、单晶硅、非晶硅、微晶硅或上述材料的组合。8. The storage capacitor as claimed in claim 7, wherein the first electrode comprises: polycrystalline silicon, single crystal silicon, amorphous silicon, microcrystalline silicon or a combination of the above materials. 9. 如权利要求7所述的储存电容,其中该第一电极的二端,分别具有该耗尽区,且该掺杂区位于该耗尽区之间。9. The storage capacitor according to claim 7, wherein the two ends of the first electrode respectively have the depletion region, and the doped region is located between the depletion regions. 10. 一种显示器,包括:10. A display comprising: 半导体图案层,分别形成在基板的至少一个晶体管区和至少一个电容区上,其中,位于该电容区上的该半导体图案层具有耗尽区及至少一个掺杂区,该耗尽区位于该电容器区上的该半导体图案层的二端其中之一,及该至少一个掺杂区邻近于该耗尽区,且位于该晶体管区上的该半导体图案层的二端具有高浓度掺杂区;The semiconductor pattern layer is respectively formed on at least one transistor region and at least one capacitor region of the substrate, wherein the semiconductor pattern layer located on the capacitor region has a depletion region and at least one doping region, and the depletion region is located on the capacitor One of the two ends of the semiconductor pattern layer on the region, and the at least one doped region is adjacent to the depletion region, and the two ends of the semiconductor pattern layer on the transistor region have a high-concentration doped region; 第一介电层,形成在该半导体图案层上;a first dielectric layer formed on the semiconductor pattern layer; 第一导体图案层,形成在该第一介电层上,且分别对应位于该电容区上和晶体管区上的该半导体图案层;a first conductor pattern layer, formed on the first dielectric layer, and respectively corresponding to the semiconductor pattern layer on the capacitor region and on the transistor region; 保护层,形成在该基板上,且覆盖该第一导体图案层;和a protective layer formed on the substrate and covering the first conductor pattern layer; and 第二导体图案层,形成在该保护层上,且分别电连接在该晶体管区上的该半导体图案层的二端的该高浓度掺杂区。The second conductor pattern layer is formed on the protection layer and electrically connected to the high-concentration doped regions at two ends of the semiconductor pattern layer on the transistor region. 11. 如权利要求10所述的显示器,还包括第二介电层,形成在该基板上,且在该第二介电层上形成该半导体图案层。11. The display device according to claim 10 , further comprising a second dielectric layer formed on the substrate, and the semiconductor pattern layer is formed on the second dielectric layer. 12. 如权利要求11所述的显示器,还包括第三介电层,形成在该基板上,且覆盖该第一介电层。12. The display device according to claim 11 , further comprising a third dielectric layer formed on the substrate and covering the first dielectric layer. 13. 如权利要求10所述的显示器,还包括至少一个低浓度掺杂区,形成在该晶体管区上的该半导体图案层的二端之间,且该低浓度掺杂区,邻近于该高浓度掺杂区的二者之一。13. The display device according to claim 10 , further comprising at least one low-concentration doped region formed between two ends of the semiconductor pattern layer on the transistor region, and the low-concentration doped region is adjacent to the high One of the two concentration doped regions. 14. 如权利要求10所述的显示器,还包括像素电极,电连接在该第二导电图案层。14. The display device according to claim 10 , further comprising a pixel electrode electrically connected to the second conductive pattern layer. 15. 如权利要求14所述的显示器,还包括发光材料,电连接在该像素电极。15. The display device according to claim 14 , further comprising a luminescent material electrically connected to the pixel electrode. 16. 如权利要求10所述的显示器,还包括发光材料,电连接在该第二导体图案层。16. The display device according to claim 10, further comprising a luminescent material electrically connected to the second conductor pattern layer. 17. 如权利要求13所述的显示器,其中该电容区的掺杂区的掺杂浓度与该晶体管区的低浓度掺杂区的掺杂浓度相同。17. The display as claimed in claim 13 , wherein the doping concentration of the doped region of the capacitor region is the same as the doping concentration of the low concentration doped region of the transistor region. 18. 如权利要求13所述的显示器,其中该电容区的掺杂区的掺杂浓度与该晶体管区的低浓度掺杂区的掺杂浓度不相同。18. The display as claimed in claim 13 , wherein the doping concentration of the doped region of the capacitor region is different from the doping concentration of the low concentration doped region of the transistor region. 19. 如权利要求10所述的显示器,其中该电容区的掺杂区的掺杂浓度与该晶体管区的高浓度掺杂区的掺杂浓度相同。19. The display as claimed in claim 10 , wherein the doping concentration of the doped region of the capacitor region is the same as the doping concentration of the highly doped region of the transistor region. 20. 如权利要求10所述的显示器,其中该电容区的掺杂区的掺杂浓度与该晶体管区的高浓度掺杂区的掺杂浓度不相同。20. The display as claimed in claim 10 , wherein the doping concentration of the doped region of the capacitor region is different from the doping concentration of the highly doped region of the transistor region. 21. 如权利要求13所述的显示器,其中该电容区的掺杂区的掺杂浓度介于该晶体管区的该高浓度掺杂区和该低浓度掺杂区的掺杂浓度之间。21. The display as claimed in claim 13 , wherein the doping concentration of the doped region of the capacitor region is between the doping concentrations of the high-concentration doped region and the low-concentration doped region of the transistor region. 22. 如权利要求10所述的显示器,其中该第一电极的二端,分别具有该耗尽区,且该掺杂区位于该耗尽区之间。22. The display device as claimed in claim 10, wherein two ends of the first electrode respectively have the depletion region, and the doping region is located between the depletion regions.
CNB2006101107158A 2006-08-07 2006-08-07 Storage capacitor, forming method thereof and display comprising storage capacitor Expired - Fee Related CN100414667C (en)

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