CN100413943C - Emusified fuel oil and preparation method - Google Patents
Emusified fuel oil and preparation method Download PDFInfo
- Publication number
- CN100413943C CN100413943C CNB2005100071192A CN200510007119A CN100413943C CN 100413943 C CN100413943 C CN 100413943C CN B2005100071192 A CNB2005100071192 A CN B2005100071192A CN 200510007119 A CN200510007119 A CN 200510007119A CN 100413943 C CN100413943 C CN 100413943C
- Authority
- CN
- China
- Prior art keywords
- fuel oil
- emulsification
- water
- kerosene
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000295 fuel oil Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003350 kerosene Substances 0.000 claims abstract description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003381 stabilizer Substances 0.000 claims abstract description 15
- 239000002283 diesel fuel Substances 0.000 claims abstract description 7
- -1 and then Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 24
- 239000003599 detergent Substances 0.000 claims description 16
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 11
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 11
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 11
- 239000012467 final product Substances 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical group CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- 125000002252 acyl group Chemical group 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 235000003086 food stabiliser Nutrition 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 235000010413 sodium alginate Nutrition 0.000 claims description 3
- 239000000661 sodium alginate Substances 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 235000020679 tap water Nutrition 0.000 claims description 2
- 239000008399 tap water Substances 0.000 claims description 2
- 235000020681 well water Nutrition 0.000 claims description 2
- 239000002349 well water Substances 0.000 claims description 2
- 239000000446 fuel Substances 0.000 abstract description 10
- 239000002994 raw material Substances 0.000 abstract description 9
- 239000003921 oil Substances 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000000779 smoke Substances 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 150000001412 amines Chemical class 0.000 abstract description 2
- 239000003995 emulsifying agent Substances 0.000 abstract description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract description 2
- 238000004945 emulsification Methods 0.000 abstract 11
- 238000002485 combustion reaction Methods 0.000 abstract 2
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 230000032798 delamination Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention discloses emulsification fuel oil and a preparation method, the existing emulsification fuel oil has the common characteristics that amine, aldehyde or alcohol is added in the fuel oil, and then, fuel oil and water from the water-in-oil type emulsification fuel oil. During preparation, a plurality of complicated devices, such as jet devices, colloid mills, high-pressure homogenizers, ultrasonic emulsifiers, etc., need to be used. The emulsification fuel oil has the advantages of complicated technology, high cost and difficult popularization and use. The emulsification fuel oil uses water, kerosene, cleaning agents, emulsion stabilizing agents, turpentine and xylene as raw materials to prepare the emulsification fuel oil. The emulsification fuel oil has the characteristics of wide raw material source, simple preparation method, stable quality of emulsification fuel oil materials, difficult emulsion breaking, no delamination after the fuel oil is stored for a long time, obvious fuel saving and thorough combustion, and the fuel saving ratio is from 20 to 30%. The cost of the emulsification fuel oil is reduced by 25 to 30% than that of the common kerosene or diesel oil; during combustion, the emulsification fuel oil does not discharge black smoke, and the emulsification fuel oil accords with the requirements of environmental protection.
Description
Technical field
That the present invention relates to is the preparation method of a kind of emulsified fuel oil and this oil fuel.
Background technology
The energy anxiety is a global problem, because present employed petroleum resources are non-renewable resources.Therefore, searching oil fuel substitute reaches the consumption at the prerequisite decline low fuel oil that guarantees fuel value, just become the direction that people make great efforts to solve energy problem, in this respect, the preparation emulsified fuel oil is an outlet, publication number is the Chinese invention patent application of CN1328112, discloses a kind of " emulsion for fuel oil and emulsified fuel thereof "; Publication number is the Chinese invention patent application of CN1120576, discloses a kind of " emulsifying fuel oil with environmental protection and energy saving advantages "; Publication number is the Chinese invention patent application of CN1415703, discloses " a kind of fuel composition that contains cationic emulsifier ", and their common feature all is to add amine, aldehyde or alcohol in oil fuel, forms the emulsified fuel of water-in-oil-type with water.These products a kind of good product of can yet be regarded as, but these products will use jet apparatus, colloidal mill, high pressure homogenisers, ultrasonic emulsator etc. in preparation process, complex process, cost is higher, is difficult to promote the use of.Therefore, deeply excavate some more effective raw materials and simpler preparation method in these areas and seem more meaningful.
Summary of the invention
Purpose of the present invention just provides a kind of emulsified fuel oil, and the preparation method of this oil fuel.To overcome existing method for preparing emulsified fuel oil complexity, the cost height is difficult for the deficiency of promoting.
For achieving the above object, the present invention has taked such measure, and a kind of emulsified fuel oil is prepared from by following weight percentages:
Water 16-40% kerosene or diesel oil 55-78% detergent 3-4.5%
Emulsion stabilizer 0.2-2.2% rosin 0-4.5% dimethylbenzene 0-2.0%
Described water refers to tap water, well water or the river through filtering cleaning;
Described kerosene refers to commercially available kerosene;
Described detergent refers to commercially available without phosphorus detergent, and major ingredient is linear alkylbenzene sulphonic acid, ethoxylated alkyl sulfate and diethanolamine of fat acyl;
Described emulsion stabilizer refers to food stabiliser, and major ingredient is sodium alginate, mono-glycerides or sucrose ester;
Above-mentioned raw materials prepares with following method:
1. earlier water intaking is heated to 75-80 ℃, adds detergent and stirs, be warming up to 85-95 ℃ standby;
2. when temperature being controlled at 70-80 ℃, in above-mentioned mixed solution, adding kerosene or diesel oil and stir, add emulsion stabilizer again, stir and reduce to 30 ℃ until temperature;
3. above-mentioned emulsion left standstill 3-5 days, and the emulsive water not on a small quantity that removes that bottom separates out adds rosin, dimethylbenzene stirs and gets final product again.
Adopt the present invention of above-mentioned measure, use more common feedstock production emulsified fuel oil, raw material sources are extensive, and the preparation method is simple, and the emulsified fuel oil stable in properties is difficult for breakdown of emulsion, and long-term storage is not stratified.Fuel-economizing is obvious, and burning is thorough, and rate of economizing gasoline reaches 20-30%, and cost reduces 25-30% than common kerosene or diesel oil, and the no black smoke that burns is discharged compliance with environmental protection requirements.
Embodiment
Embodiment 1
Composition of raw materials
3 kilograms of 55 kilograms of detergents of 40 kilograms of kerosene of water
1.2 kilograms of 2 kilograms of dimethylbenzene of 0.2 kilogram of rosin of emulsion stabilizer
The preparation method
1. earlier water intaking is heated to 80 ℃, adds detergent and stirs, be warming up to 90 ℃ standby;
2. when temperature being controlled at 70-80 ℃, in above-mentioned mixed solution, adding kerosene and stir, add emulsion stabilizer again, stir and reduce to 30 ℃ until temperature;
3. above-mentioned emulsion left standstill 3-5 days, and the emulsive water not on a small quantity that removes that bottom separates out adds rosin, dimethylbenzene stirs and gets final product again.
Embodiment 2
Described detergent refers to commercially available without phosphorus detergent, and major ingredient is linear alkylbenzene sulphonic acid, ethoxylated alkyl sulfate, diethanolamine of fat acyl:
Described emulsion stabilizer refers to food stabiliser, and major ingredient is sodium alginate, mono-glycerides, sucrose ester;
Above-mentioned raw materials prepares with following method:
1. earlier water intaking is heated to 75-80 ℃, adds detergent and stirs, be warming up to 85-95 ℃ standby:
2. when temperature being controlled at 70-80 ℃, in above-mentioned mixed solution, adding kerosene and stir, add emulsion stabilizer again, stir and reduce to 30 ℃ until temperature:
3. above-mentioned emulsion left standstill 3-5 days, removed a small amount of last emulsive water that bottom is separated out, and added rosin again, dimethylbenzene stirs and gets final product.
Adopt the present invention of above-mentioned measure, use more common former section to prepare emulsified fuel oil, raw material sources are extensive, and the preparation method is simple, and the emulsified fuel oil stable in properties is difficult for breakdown of emulsion, and long-term storage is not stratified.Fuel-economizing is obvious, and burning is thorough, and rate of economizing gasoline reaches 20-30%, and cost reduces 25-30% than common kerosene or diesel oil, and the no black smoke that burns is discharged compliance with environmental protection requirements.
Embodiment
Embodiment 1
Composition of raw materials
3 kilograms of 55 kilograms of detergents of 40 kilograms of kerosene of water
1.2 kilograms of 2 kilograms-toluene of 0.2 kilogram of rosin of emulsion stabilizer
The preparation method
1. earlier water intaking is heated to 80 ℃, adds detergent and stirs, be warming up to 90 ℃ standby:
2. when temperature being controlled at 70-80 ℃, in above-mentioned mixed solution, adding kerosene and stir, add emulsion stabilizer again, stir and reduce to 30 ℃ until temperature;
3. above-mentioned emulsion left standstill 3-5 days, and the emulsive water not on a small quantity that removes that bottom separates out adds rosin, dimethylbenzene stirs and gets final product again.
Embodiment 2
4.15 kilograms in 0.35 kilogram of rosin of emulsion stabilizer
The preparation method
1. earlier water intaking is heated to 80 ℃, adds detergent and stirs, be warming up to 90 ℃ standby;
2. when temperature being controlled at 70-80 ℃, in above-mentioned mixed solution, adding people's kerosene and stir, add emulsion stabilizer again and go into, stir and reduce to 30 ℃ until temperature;
3. above-mentioned emulsion left standstill 3-5 days, and the emulsive water not on a small quantity that removes that bottom separates out adds rosin again and stirs and get final product.
Claims (2)
1. emulsified fuel oil is characterized in that described emulsified fuel oil is prepared from by following weight percentages:
Water 16-40% kerosene or diesel oil 55-78% detergent 3-4.5%
Emulsion stabilizer 0.2-2.2% rosin 0-4.5% dimethylbenzene 0-2.0%
Described water refers to through filtering clean tap water, well water or river;
Described kerosene refers to commercially available kerosene;
Described detergent refers to commercially available without phosphorus detergent, and major ingredient is linear alkylbenzene sulphonic acid, ethoxylated alkyl sulfate and diethanolamine of fat acyl;
Described emulsion stabilizer refers to food stabiliser, and major ingredient is sodium alginate, mono-glycerides or sucrose ester.
2. the preparation method of the described emulsified fuel oil of claim 1 is characterized in that described method comprises the steps:
(1) earlier water intaking is heated to 75-80 ℃, adds detergent and stirs, be warming up to 85-95 ℃ standby;
When (2) temperature being controlled at 70-80 ℃, in above-mentioned mixed solution, adding kerosene or diesel oil and stir, add emulsion stabilizer again, stir and reduce to 30 ℃ until temperature;
(3) above-mentioned emulsion left standstill 3-5 days, and the emulsive water not on a small quantity that removes that bottom separates out adds rosin, dimethylbenzene stirs and gets final product again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100071192A CN100413943C (en) | 2005-01-21 | 2005-01-21 | Emusified fuel oil and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100071192A CN100413943C (en) | 2005-01-21 | 2005-01-21 | Emusified fuel oil and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1657595A CN1657595A (en) | 2005-08-24 |
| CN100413943C true CN100413943C (en) | 2008-08-27 |
Family
ID=35007306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100071192A Expired - Fee Related CN100413943C (en) | 2005-01-21 | 2005-01-21 | Emusified fuel oil and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100413943C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101979864A (en) * | 2010-10-20 | 2011-02-23 | 朴龙根 | High-precision diesel device and method for preparing high-precision diesel |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4808195A (en) * | 1986-03-24 | 1989-02-28 | Aquanon Corp. | Hydrocarbon fuel additive |
| CN1094746A (en) * | 1994-02-26 | 1994-11-09 | 刘绍之 | A kind of oil-water composite fuel and preparation method thereof |
| CN1104242A (en) * | 1994-04-26 | 1995-06-28 | 周毕华 | SCH37 water and diesel oil mixed fuel agent |
| EP1337608A1 (en) * | 2000-09-28 | 2003-08-27 | Clean Diesel Technologies Inc. | Low-emissions diesel fuel emulsions |
-
2005
- 2005-01-21 CN CNB2005100071192A patent/CN100413943C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4808195A (en) * | 1986-03-24 | 1989-02-28 | Aquanon Corp. | Hydrocarbon fuel additive |
| CN1094746A (en) * | 1994-02-26 | 1994-11-09 | 刘绍之 | A kind of oil-water composite fuel and preparation method thereof |
| CN1104242A (en) * | 1994-04-26 | 1995-06-28 | 周毕华 | SCH37 water and diesel oil mixed fuel agent |
| EP1337608A1 (en) * | 2000-09-28 | 2003-08-27 | Clean Diesel Technologies Inc. | Low-emissions diesel fuel emulsions |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1657595A (en) | 2005-08-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Zhang et al. | Direct emulsification of crude glycerol and bio-oil without addition of surfactant via ultrasound and mechanical agitation | |
| CN101475855A (en) | Fuel oil based on petrifaction diesel and coarse biodiesel and preparation thereof | |
| CN101250447A (en) | Environment-friendly and energy-saving micro-emulsified bio-gasoline and diesel oil mixed fuel containing seawater, animal oil, vegetable oil and alcohol and additive | |
| CN102660334A (en) | Biological alcohol oil and preparation method thereof | |
| CN101348748B (en) | Microemulsified biodiesel and preparation thereof | |
| CN101333435A (en) | Viscosity reducer for thickened oil | |
| CN100413943C (en) | Emusified fuel oil and preparation method | |
| US20050262759A1 (en) | Emulsified water/hydrocarbon fuel, preparation and uses thereof | |
| JP2010265334A (en) | Fuel oil, and dispersion-stabilizing agent for use for dissolution of water added in waste oil | |
| CN1286288A (en) | Viscosity-reducing composition for high viscosity crude | |
| CN101007970B (en) | Heavy oil modified fuel oil for substituting for heavy diesel oil and its production method | |
| CN101113368A (en) | Formula of strong compound diesel oil and method for preparing the same | |
| CN1931966B (en) | Fuel emulsifying biomass assistant and its preparation method | |
| US6503286B1 (en) | Fuel composition in the form of an emulsion derived from heterogeneous greasy waste and method for making same | |
| EP3919590B1 (en) | Process for the production of a bipolar diesel fuel and bipolar diesel fuel | |
| EP1257616A1 (en) | Compositions | |
| CN101705123B (en) | Environment friendly and energy-saving heavy oil additive | |
| US20130227877A1 (en) | Three-phase emulsified fuel and methods of preparation and use | |
| CN102295966A (en) | Micro-emulsified biodiesel and preparation method thereof | |
| RU2367683C2 (en) | Fuel-water emulsion | |
| CN100427573C (en) | Micro-emulsion fatty acid diesel oil and its production | |
| CN102911750A (en) | Biological composite diesel | |
| CN104593107A (en) | A kind of preparation technology of microemulsion diesel oil | |
| RU2635664C1 (en) | Method of producing hydrated fuel | |
| CN103205288A (en) | Clean synthetic diesel and synthetic process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080827 Termination date: 20100221 |