CN100412700C - Red powdered carbon for color copier and its preparing process - Google Patents
Red powdered carbon for color copier and its preparing process Download PDFInfo
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- CN100412700C CN100412700C CNB2006100411220A CN200610041122A CN100412700C CN 100412700 C CN100412700 C CN 100412700C CN B2006100411220 A CNB2006100411220 A CN B2006100411220A CN 200610041122 A CN200610041122 A CN 200610041122A CN 100412700 C CN100412700 C CN 100412700C
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- red
- color copier
- powdered carbon
- compound
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229910052799 carbon Inorganic materials 0.000 title claims description 27
- 238000000034 method Methods 0.000 title description 3
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims abstract description 22
- -1 polypropylene Polymers 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 18
- 239000004743 Polypropylene Substances 0.000 claims abstract description 12
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920001155 polypropylene Polymers 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 11
- 239000001993 wax Substances 0.000 claims description 11
- 235000013312 flour Nutrition 0.000 claims description 10
- 239000012634 fragment Substances 0.000 claims description 10
- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 5
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims description 3
- 229960001860 salicylate Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims 1
- 235000006040 Prunus persica var persica Nutrition 0.000 abstract 1
- 240000006413 Prunus persica var. persica Species 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 239000004645 polyester resin Substances 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000000428 dust Substances 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003738 black carbon Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Developing Agents For Electrophotography (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The disclosed preparation method for red carbon powder of color copier comprises: selecting material as 4-8 pigment red, 2-4 permanent peach, 80-90 polyester resin, 2-8 polypropylene wax, 2-4 charge regulator, 1-3 dimethyldichlorosilane, and 6-7 hexamethyldisilazane; mixing, extruding, smashing, and sieving. This invention can reduce cost and machine fault, and provides sharp file.
Description
(1) technical field
The present invention relates to a kind of carbon dust and preparation method thereof.Specifically, be to be used for red powdered carbon for color copier that duplicates by colored manuscript or colour picture and preparation method thereof.
(2) background technology
At present, the carbon dust that uses on the color copy machine, its Main Ingredients and Appearance resin all are to adopt styrene and acrylic acid bipolymer.There is following problem in the color copy machine carbon dust that utilizes this resin to make as primary raw material: in the production run, be difficult to pulverize the big and out-of-shape of particle.Because particle is big and out-of-shape, during duplicating, is difficult to answering equably on paper, not only imaging effect is relatively poor, and the consumption of carbon dust is many, use cost is higher.Because styrene and acrylic acid bipolymer have peculiar smell, make the carbon dust of making that peculiar smell also be arranged again, be unfavorable for environmental protection.
(3) summary of the invention
The problem to be solved in the present invention provides a kind of red powdered carbon for color copier.This red carbon powder, not only particle is little, regular shape, imaging effect are good, and consumption is few when duplicating, use cost is low.
Another problem that the present invention will solve provides a kind of method for preparing red powdered carbon for color copier.
For addressing the above problem, the present invention takes following technical solution:
Red powdered carbon for color copier of the present invention is made up of the raw material of following parts by weight:
4～8 parts of sun-proof bright red, solid pink 2～4 parts forever; 80～92 parts in vibrin; 2～8 parts of polypropylene waxes; 2～4 parts of charge adjusting agents; 6～7 parts of 1～3 part of dimethyldichlorosilane and hexamethyldisilazanes.Vibrin wherein is in terephthalate: the bipolymer that the ratio reaction of isophthalic acid ester=2: 8 forms.
The method for preparing red powdered carbon for color copier may further comprise the steps:
(1) earlier with the sun-proof bright red, solid pink, vibrin, polypropylene wax and charge adjusting agent are poured in the mixing roll forever, through evenly mixing, make compound;
(2) more above-mentioned compound is dropped in the extruding machine, under 90～150 ℃ temperature, compound is extruded compacting in flakes; Then, with sheet compound cooling to 40～45 ℃ and be ground into fragment;
(3) afterwards, with comminutor above-mentioned fragment is ground into the flour that particle diameter is 30～50 μ m;
(4) afterwards, above-mentioned flour is further pulverized with comminutor, and carry out classification successively, separation, collection, obtaining particle diameter is the semi-manufacture particle of 7～9 μ m;
(5) again after, add dimethyldichlorosilane and hexamethyldisilazane, with 850～950 rev/mins mixing rolls mixing 3～4 minutes, make its flowability greater than 20%;
(6) last, sieve with 200～250 eye mesh screens, make red powdered carbon for color copier.
Adopt above scheme, have the following advantages:
Because the used resin of red carbon powder of the present invention is a vibrin, this resin is according to terephthalate: the ratio reaction of isophthalic acid ester=2: 8 forms, with this resin with sun-proof bright red, raw materials such as solid pink, polypropylene wax, charge adjusting agent, dimethyldichlorosilane and hexamethyldisilazane forever, through mixing, extrusion molding, pulverize and red carbon powder that step such as sieve is made, pulverize the less and comparison rule of particle in the production run easily.Because the less and comparison rule of particle during duplicating, is formed four kinds of Essential colour with yellow, black, cyan carbon dust, can be equably attached on the paper, not only imaging effect is good, and consumption is few, use cost is lower.Again because used resin is a vibrin; and this resin is according to terephthalate: the ratio reaction of isophthalic acid ester=2: 8 forms; terephthalate wherein and isophthalic acid ester free from extraneous odour, the feasible black carbon powder of making is free from extraneous odour also, helps environmental protection.
(4) embodiment
First embodiment
Choose solid forever pink, 80 parts the vibrin of 4 parts sun-proof bright red, 2 parts, 2 parts polypropylene wax, 2 parts charge adjusting agent, 1 part dimethyldichlorosilane and 6 parts hexamethyldisilazane, stand-by.
Earlier with the sun-proof bright red, solid pink, vibrin, polypropylene wax, charge adjusting agent are poured in the mixing roll forever, through evenly mixing, make compound;
Above-mentioned compound is dropped in the extruding machine again, under 95 ℃ temperature the compound agent is gone out, compacting in flakes; Then, the sheet compound is cooled off to 40 ℃, and be ground into fragment;
Afterwards, with comminutor above-mentioned fragment is ground into the flour that particle diameter is 30 μ m;
Afterwards, be 7kg/m with pressure
3Pressurized air carries out to above-mentioned flour that air-flow is pulverized and carries out classification, separates, collects with drip catcher with cyclone separator with 5200 rev/mins grader in the fluidized bed comminutor, obtaining particle diameter is the semi-manufacture particle of 7～9 μ m;
Again, add dimethyldichlorosilane and hexamethyldisilazane, mixed 3 minutes, make its flowability greater than 20% with 850 rev/mins mixing rolls;
At last, sieve, make red powdered carbon for color copier with 250 eye mesh screens.
Wherein: vibrin is according to terephthalate: the bipolymer that the ratio reaction of isophthalic acid ester=2: 8 forms; Charge adjusting agent is the metal salicylate complex compound; Said sun-proof bright red is produced by Shanghai Dye Co., Ltd.
Second embodiment
Choose solid forever pink, 85 parts the vibrin of 6 parts sun-proof bright red, 3 parts, 5 parts polypropylene wax, 3 parts charge adjusting agent, 2 parts dimethyldichlorosilane and 6.5 parts hexamethyldisilazane, stand-by.
Earlier with the sun-proof bright red, solid pink, vibrin, polypropylene wax, charge adjusting agent are poured in the mixing roll forever, through evenly mixing, make compound;
Above-mentioned compound is dropped in the extruding machine again, under 125 ℃ temperature the compound agent is gone out, compacting in flakes; Then, the sheet compound is cooled off to 43 ℃, and be ground into fragment;
Afterwards, with comminutor above-mentioned fragment is ground into the flour that particle diameter is 40 μ m;
Afterwards, be 7.5kg/m with pressure
3Pressurized air carries out to above-mentioned flour that air-flow is pulverized and carries out classification, separates, collects with drip catcher with cyclone separator with 5700 rev/mins grader in the fluidized bed comminutor, obtaining particle diameter is the semi-manufacture particle of 7～9 μ m;
Again, add dimethyldichlorosilane and hexamethyldisilazane, mixed 3 minutes, make its flowability greater than 20% with 900 rev/mins mixing rolls;
At last, sieve, make red powdered carbon for color copier with 230 eye mesh screens.
Wherein: vibrin is according to terephthalate: the bipolymer that the ratio reaction of isophthalic acid ester=2: 8 forms; Charge adjusting agent is a metal azo complex compound; Said sun-proof bright red is produced by Shanghai Dye Co., Ltd.
The 3rd embodiment
Choose solid forever pink, 90 parts the vibrin of 8 parts sun-proof bright red, 4 parts, 8 parts polypropylene wax, 4 parts charge adjusting agent, 3 parts dimethyldichlorosilane and 7 parts hexamethyldisilazane, stand-by.
Earlier with the sun-proof bright red, solid pink, vibrin, polypropylene wax, charge adjusting agent are poured in the mixing roll forever, through evenly mixing, make compound;
Above-mentioned compound is dropped in the extruding machine again, under 125 ℃ temperature the compound agent is gone out, compacting in flakes; Then, the sheet compound is cooled off to 45 ℃, and be ground into fragment;
Afterwards, with comminutor above-mentioned fragment is ground into the flour that particle diameter is 50 μ m;
Afterwards, be 8kg/m with pressure
3Pressurized air carries out to above-mentioned flour that air-flow is pulverized and carries out classification, separates, collects with drip catcher with cyclone separator with 6000 rev/mins grader in the fluidized bed comminutor, obtaining particle diameter is the semi-manufacture particle of 7～9 μ m;
Again, add dimethyldichlorosilane and hexamethyldisilazane, mixed 4 minutes, make its flowability greater than 20% with 950 rev/mins stirring machines;
At last, sieve, make red powdered carbon for color copier with 200 eye mesh screens.
Wherein: vibrin is according to terephthalate: the bipolymer that the ratio reaction of isophthalic acid ester=2: 8 forms; Charge adjusting agent is the metal salicylate complex compound; Said sun-proof bright red is produced by Shanghai Dye Co., Ltd.
Claims (4)
1. red powdered carbon for color copier is characterized in that being made up of the starting material of following parts by weight:
4～8 parts of sun-proof bright red;
Solid pink 2～4 parts forever;
80～90 parts in vibrin;
2～8 parts of polypropylene waxes;
2～4 parts of charge adjusting agents;
1～3 part of dimethyldichlorosilane;
6～7 parts of hexamethyldisilazanes.
2. red powdered carbon for color copier according to claim 1 is characterized in that said vibrin is according to terephthalate: the bipolymer that the ratio reaction of isophthalic acid ester=2: 8 forms.
3. red powdered carbon for color copier according to claim 1 is characterized in that said charge adjusting agent is metal salicylate complex compound or metal azo complex compound.
4. according to the preparation method of the described red powdered carbon for color copier of claim 1, it is characterized in that may further comprise the steps successively:
(1) earlier with the sun-proof bright red, solid pink, vibrin, polypropylene wax and charge adjusting agent are poured in the mixing roll forever, through evenly mixing, make compound;
(2) more above-mentioned compound is dropped in the extruding machine, under 90～150 ℃ temperature, compound is extruded compacting in flakes; Then, with sheet compound cooling to 40～45 ℃ and be ground into fragment;
(3) afterwards, with comminutor above-mentioned fragment is ground into the flour that particle diameter is 30～50 μ m;
(4) afterwards, above-mentioned flour is further pulverized with comminutor, and carry out classification successively, separation, collection, obtaining particle diameter is the semi-manufacture particle of 7～9 μ m;
(5) again after, add dimethyldichlorosilane and hexamethyldisilazane, with 850～950 rev/mins mixing rolls mixing 3～4 minutes, make its flowability greater than 20%;
(6) last, sieve with 200～250 eye mesh screens, make red powdered carbon for color copier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100411220A CN100412700C (en) | 2006-08-02 | 2006-08-02 | Red powdered carbon for color copier and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100411220A CN100412700C (en) | 2006-08-02 | 2006-08-02 | Red powdered carbon for color copier and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1908820A CN1908820A (en) | 2007-02-07 |
| CN100412700C true CN100412700C (en) | 2008-08-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100411220A Active CN100412700C (en) | 2006-08-02 | 2006-08-02 | Red powdered carbon for color copier and its preparing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100412700C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008061414A1 (en) * | 2006-11-19 | 2008-05-29 | Xueliang Zhou | Durable and anti fake toner for laser printer and its preparation method |
| CN101788774B (en) * | 2009-11-13 | 2011-11-02 | 无锡佳腾磁性粉有限公司 | Red durability anti-counterfeit developer of colored laser printer and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0718703A2 (en) * | 1994-12-21 | 1996-06-26 | Canon Kabushiki Kaisha | Toner for developing electrostatic image |
| CN1131284A (en) * | 1994-12-05 | 1996-09-18 | 佳能株式会社 | Toner for electrostatic image development |
| US5773183A (en) * | 1995-11-20 | 1998-06-30 | Canon Kabushiki Kaisha | Toner for developing electrostatic images |
| US5976752A (en) * | 1997-08-21 | 1999-11-02 | Canon Kabushiki Kaisha | Toner and image forming method |
| CN1420393A (en) * | 2001-07-11 | 2003-05-28 | 精工爱普生株式会社 | Mono-component non-magnetic toner, its mfg. method and image forming device using same |
| US6579653B1 (en) * | 1999-03-03 | 2003-06-17 | Matsushita Electric Industrial Co., Ltd. | Binding resin for toner, toner, and electrophotograph |
| JP2004093735A (en) * | 2002-08-30 | 2004-03-25 | Seiko Epson Corp | Toner and image forming apparatus using the same |
-
2006
- 2006-08-02 CN CNB2006100411220A patent/CN100412700C/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1131284A (en) * | 1994-12-05 | 1996-09-18 | 佳能株式会社 | Toner for electrostatic image development |
| EP0718703A2 (en) * | 1994-12-21 | 1996-06-26 | Canon Kabushiki Kaisha | Toner for developing electrostatic image |
| US5773183A (en) * | 1995-11-20 | 1998-06-30 | Canon Kabushiki Kaisha | Toner for developing electrostatic images |
| US5976752A (en) * | 1997-08-21 | 1999-11-02 | Canon Kabushiki Kaisha | Toner and image forming method |
| US6579653B1 (en) * | 1999-03-03 | 2003-06-17 | Matsushita Electric Industrial Co., Ltd. | Binding resin for toner, toner, and electrophotograph |
| CN1420393A (en) * | 2001-07-11 | 2003-05-28 | 精工爱普生株式会社 | Mono-component non-magnetic toner, its mfg. method and image forming device using same |
| JP2004093735A (en) * | 2002-08-30 | 2004-03-25 | Seiko Epson Corp | Toner and image forming apparatus using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1908820A (en) | 2007-02-07 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Wuxi Jiateng Magnetic Powder Co., Ltd. Assignor: Zhou Xueliang Contract record no.: 2011320000282 Denomination of invention: Red powdered carbon for color copier and its preparing process Granted publication date: 20080820 License type: Exclusive License Open date: 20070207 Record date: 20110316 |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170706 Address after: 1 No. 214192 Jiangsu province Wuxi city Xishan District Tin New Village Beizhen Bada Road Patentee after: Wuxi Jiateng Magnetic Powder Co., Ltd. Address before: 214101 Jiangsu city in Wuxi Province Economic Development Zone Xishan Xinming Road No. 38 Patentee before: Zhou Xueliang |