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CN100412009C - A Nitrification Process for Biological Treatment of Sewage - Google Patents

A Nitrification Process for Biological Treatment of Sewage Download PDF

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CN100412009C
CN100412009C CNB2005100945609A CN200510094560A CN100412009C CN 100412009 C CN100412009 C CN 100412009C CN B2005100945609 A CNB2005100945609 A CN B2005100945609A CN 200510094560 A CN200510094560 A CN 200510094560A CN 100412009 C CN100412009 C CN 100412009C
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sewage
aerobic
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anoxic
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CN1772655A (en
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张雁秋
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China University of Mining and Technology CUMT
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Abstract

本发明一种污水生物处理硝化工艺,最适用于城市污水处理。将污水按比例分流同时进入缺氧池、好氧池以及好氧池与二沉池之间,好氧池分三个或三个以上进水点进水,进入缺氧的污水经历缺氧和厌氧过程后再进入到好氧池,与直接进入好氧池中的污水混合进行曝气,混合液在二沉池进行固液分离。与现有技术相比:具有短时高效,工艺简单,土地的占用少,基建投资省,设备少,运行费用低,脱氮效果好,运行稳定,冲击负荷能力强,能有效防止污泥膨胀发生等特点,在该技术领域内具有广泛的实用性。

Figure 200510094560

The invention relates to a sewage biological treatment nitrification process, which is most suitable for urban sewage treatment. Divide the sewage into the anoxic pool, the aerobic pool and between the aerobic pool and the secondary sedimentation tank at the same time in proportion. The aerobic pool is divided into three or more water inlet points. After the oxygen process, it enters the aerobic tank, mixes with the sewage that directly enters the aerobic tank for aeration, and the mixed liquid is separated from solid and liquid in the secondary sedimentation tank. Compared with the existing technology: it has short-term high efficiency, simple process, less land occupation, less capital investment, less equipment, low operating cost, good denitrification effect, stable operation, strong impact load capacity, and can effectively prevent sludge bulking Occurrence and other characteristics have wide applicability in this technical field.

Figure 200510094560

Description

一种污水生物处理硝化工艺 A Nitrification Process for Biological Treatment of Sewage

技术领域 technical field

本发明涉及一种污水生物处理硝化工艺,尤其适用于污水的脱氮除磷处理。The invention relates to a sewage biological treatment nitrification process, which is especially suitable for nitrogen and phosphorus removal treatment of sewage.

背景技术 Background technique

我国氮素污染导致的水体污染问题比较严重,湖泊“水华”、近海“赤潮”时有发生。水体富营养化已危害农业、渔业、旅游业等诸多行业;并对饮水卫生和食品的安全构成威胁。目前治理氮素污染,国内外常见的工程技术有空气吹脱法、选择性离子交换法、折点氯化法、生物脱氮法等,其中,生物脱氮是最经济有效的治理技术。近些年来,许多国家加强了对生物脱氮的研究,并在理论和技术上都取得了很大突破。以“同步硝化-反硝化工艺”、“厌氧氨氧化工艺”等为标志的大批新型生物脱氮技术的先后问世,不仅弥补了传统硝化-反硝化工艺的缺陷,提高了废水脱氮效率,降低了废水脱氮成本,也填补了高浓度含氮废水没有直接生物脱氮技术的空白。但是已有的脱氮工艺要达到很好的脱氮效果,必须保证足够的曝气时间,以满足硝化菌群的大量生长,达到硝化的目的,因此整个反应时间较长,一般在8个小时左右,因此脱氮效率低,成本较高。The problem of water pollution caused by nitrogen pollution in my country is relatively serious, and lake "blooms" and offshore "red tides" occur from time to time. Eutrophication of water body has endangered agriculture, fishery, tourism and many other industries; it also poses a threat to drinking water sanitation and food safety. At present, to control nitrogen pollution, common engineering technologies at home and abroad include air stripping method, selective ion exchange method, breakpoint chlorination method, biological denitrification method, etc. Among them, biological denitrification is the most economical and effective treatment technology. In recent years, many countries have strengthened the research on biological denitrification, and have made great breakthroughs in theory and technology. A large number of new biological denitrification technologies marked by "simultaneous nitrification-denitrification process" and "anammox process" have come out successively, which not only make up for the defects of traditional nitrification-denitrification process, but also improve the efficiency of wastewater denitrification. It reduces the cost of denitrification of wastewater, and also fills the gap that there is no direct biological denitrification technology for high-concentration nitrogen-containing wastewater. However, in order to achieve a good denitrification effect in the existing denitrification process, sufficient aeration time must be ensured to meet the growth of a large number of nitrifying bacteria and achieve the purpose of nitrification, so the entire reaction time is relatively long, generally 8 hours Therefore, the denitrification efficiency is low and the cost is high.

发明内容 Contents of the invention

本发明的目的是提供一种工艺简单、反应时间短、效率高、成本低的污水生物处理高效硝化工艺。The object of the present invention is to provide a high-efficiency nitrification process for sewage biological treatment with simple process, short reaction time, high efficiency and low cost.

本发明所采用的技术方案是:污水经历缺氧、厌氧和好氧生物处理过程,再进入二次沉淀池进行泥水分离,沉淀中排出上清液,同时将部分污泥回流。将污水按比例分流同时进入缺氧池、好氧池以及好氧池与二沉池之间,好氧池分三个或者三个以上的进水点进水,进入缺氧池的污水经历缺氧和厌氧作用后,再进入好氧池中,与直接进入好氧池中的污水混合进行曝气,混合液在二沉池进行固液分离。部分污泥回流到不曝气池,控制污泥回流的比例,保证不曝气池和好氧池有足够的污泥浓度。用于污水处理的缺氧池和厌氧池合建或分建;缺氧池、厌氧池和好氧池合建或分建。The technical solution adopted in the present invention is: the sewage undergoes anoxic, anaerobic and aerobic biological treatment processes, and then enters the secondary sedimentation tank for mud-water separation, discharges the supernatant during the sedimentation, and at the same time returns part of the sludge. Divide the sewage into the anoxic pool, the aerobic pool and between the aerobic pool and the secondary sedimentation tank at the same time. The aerobic pool is divided into three or more water inlet points. After anaerobic action, it enters the aerobic tank, mixes with the sewage that directly enters the aerobic tank for aeration, and the mixed solution is separated from solid and liquid in the secondary sedimentation tank. Part of the sludge returns to the non-aerated tank, and the proportion of sludge return is controlled to ensure that the non-aerated tank and the aerobic tank have sufficient sludge concentration. Anoxic pools and anaerobic pools for sewage treatment are built together or separately; anoxic pools, anaerobic pools and aerobic pools are built together or separately.

本发明一种污水生物处理硝化工艺的有益效果是:The beneficial effect of a kind of sewage biological treatment nitrification process of the present invention is:

a.短时高效。本技术工艺需要的曝气时间可以大大缩短,曝气4小时左右将氨氮(35mg/L)去除95%以上的效果,反应时间大约为传统硝化工艺的一半。a. Short-term high efficiency. The aeration time required by the technical process can be greatly shortened, and the effect of removing more than 95% of ammonia nitrogen (35mg/L) by aeration is about 4 hours, and the reaction time is about half of the traditional nitrification process.

b.工艺简单。本技术工艺无论是在结构上还是在工艺流程上都显示出较传统脱氮工艺简单的优点,工艺显得比较流畅。b. The process is simple. The technical process shows the advantage of being simpler than the traditional denitrification process both in structure and process flow, and the process appears to be relatively smooth.

c.土地占用少,基建投资省。由于本技术工艺各反应器内的污泥浓度较高,反应速率提高使反应时间较短,所以对应的反应容积就可以比较小,也即是可以减少构筑物的建设以及减少整个污水处理厂对土地的占用。同时,本工艺比较简单,所需要的设备可以减少,相应的费用也可以降低。一般使用本工艺,基建以及设备投资费用可以比传统工艺节省约1/4左右。c. Less land occupation, less investment in infrastructure. Because the concentration of sludge in each reactor of this technical process is high, the reaction rate is increased to make the reaction time shorter, so the corresponding reaction volume can be relatively small, that is, the construction of structures and the impact on the land of the entire sewage treatment plant can be reduced. occupancy. At the same time, the process is relatively simple, the required equipment can be reduced, and the corresponding cost can also be reduced. Generally using this process, infrastructure and equipment investment costs can be saved by about 1/4 compared with traditional processes.

d.运行稳定,抗冲击负荷能力强,能有效防止污泥膨胀发生。d. Stable operation, strong impact load resistance, and can effectively prevent sludge bulking.

e.节省运行费用,传统脱氮工艺为实现良好的脱氮效果,需要对曝气池的硝化液进行大比率(通常在100-400%)回流,同时要保证足够长的曝气时间促使氨氮硝化,因此能耗较大,运行费用较高。在实际运行中没有内回流,同时大大缩短了曝气时间,因此可以大大降低能耗,节省运行费用。e. Save operating costs. In order to achieve a good denitrification effect in the traditional denitrification process, a large ratio (usually 100-400%) of the nitrification liquid in the aeration tank must be refluxed, and at the same time, a long enough aeration time must be ensured to promote ammonia nitrogen Nitrification, so the energy consumption is larger and the operating cost is higher. In actual operation, there is no internal backflow, and the aeration time is greatly shortened, so energy consumption can be greatly reduced and operating costs can be saved.

附图说明 Description of drawings

附图是本发明污水生物处理硝化工艺流程图。Accompanying drawing is the flow chart of nitrification process of sewage biological treatment of the present invention.

具体实施方式 Detailed ways

下面将结合附图对本发明的一个实施例作进一步的描述:An embodiment of the present invention will be further described below in conjunction with accompanying drawing:

本发明一种污水生物处理硝化工艺,主要构筑物为由缺氧池、厌氧池构成的不曝气池和好氧池,不曝气池中的缺氧池和厌氧池可以合建也可以分建,不曝气池和好氧池可以合建也可以分建。将污水分流同时进入不曝气池和好氧池,好氧池分四个进水点进水,好氧池与二沉池之间设有一个进水点。进入不曝气池的污水经历缺氧和厌氧作用后,再进入好氧池中,与直接进入好氧池中的污水混合进行曝气,然后混合液进入二沉池进行泥水分离,部分污泥回流到不曝气池。The present invention is a sewage biological treatment nitrification process, the main structure is a non-aeration pool and an aerobic pool composed of anoxic pool and anaerobic pool, and the anoxic pool and anaerobic pool in the non-aerated pool can be built together or can be Separate construction, non-aerated pool and aerobic pool can be built together or separately. Divert the sewage into the non-aerated tank and the aerobic tank at the same time. The aerobic tank is divided into four water inlet points, and there is a water inlet point between the aerobic tank and the secondary sedimentation tank. The sewage entering the non-aerated tank undergoes anoxic and anaerobic effects, then enters the aerobic tank, mixes with the sewage directly entering the aerobic tank for aeration, and then the mixed solution enters the secondary sedimentation tank for mud-water separation, and part of the sewage Mud returns to the non-aerated tank.

整个污水处理系统的运行过程如下:The operation process of the whole sewage treatment system is as follows:

(1)由缺氧池和厌氧池构成的不曝气池进水量45%,好氧池进水量50%,好氧池与二沉池之间的进水点进水量为5%;好氧池进水点可以是多个,若好氧池进水点为四个,则第一个和第四个进水点进水量各为10%,第二个和第三个进水点进水量各为15%;根据实际进水水质情况可以具体调整所有进水点的进水比例,以此提高氨氮氧化的效率;(1) The water intake of the non-aerated tank consisting of anoxic tank and anaerobic tank is 45%, the water intake of the aerobic tank is 50%, and the water intake of the water intake point between the aerobic tank and the secondary sedimentation tank is 5%; There can be multiple water inlet points in the pool. If there are four water inlet points in the aerobic pool, the water inlet of the first and fourth water inlet points is 10% each, and the water inlet of the second and third water inlet points is 10%. Each is 15%; according to the actual water quality, the proportion of water inflow to all water inflow points can be adjusted in order to improve the efficiency of ammonia nitrogen oxidation;

(2)通过控制曝气量大小,使好氧池的溶解氧的含量维持在1-2mg/L左右;(2) By controlling the amount of aeration, the content of dissolved oxygen in the aerobic tank is maintained at about 1-2mg/L;

(3)控制回流比,保证不曝气池和好氧池有足够的污泥浓度(>3000mg/L),使好氧池处于高污泥浓度及低营养状态,相对抑制脱碳微生物的增殖,促进硝化菌增殖。(3) Control the reflux ratio to ensure that the non-aerated tank and the aerobic tank have sufficient sludge concentration (>3000mg/L), so that the aerobic tank is in a state of high sludge concentration and low nutrition, and relatively inhibits the proliferation of decarbonizing microorganisms , to promote the proliferation of nitrifying bacteria.

(4)好氧池第一个分水点引进10%污水,污泥浓度维持在较高水平下进行曝气降解有机物实现脱碳,在特定的情况下(如初沉池出水BOD浓度较低时)可以不进行曝气,继续维持反硝化过程。污泥回流到不曝气池进行反硝化和释放磷,运行过程中不断的调节各项运行参数,直到整个系统的运行效果达到最优即可。(4) Introduce 10% sewage at the first water point of the aerobic tank, and maintain the sludge concentration at a relatively high level for aeration to degrade organic matter to achieve decarbonization. ) can continue to maintain the denitrification process without aeration. The sludge is returned to the non-aeration tank for denitrification and release of phosphorus. During the operation, various operating parameters are continuously adjusted until the operating effect of the entire system reaches the optimum.

Claims (2)

1. biological sewage treatment nitration processes, it comprises anoxic, anaerobic and aerobic biological treatment process, and carry out secondary sedimentation, discharge supernatant liquor in the precipitation, falling part mud simultaneously refluxes, it is characterized in that: sewage is shunted in proportion entered simultaneously between anoxic pond, Aerobic Pond and Aerobic Pond and the second pond, Aerobic Pond divides three or three above water entry water inlets, enter into Aerobic Pond again after entering the sewage experience anoxic of anoxic pond and anaerobic process, with directly enter sewage in the Aerobic Pond and mix and carry out aeration, mixed solution carries out solid-liquid separation at second pond.
2. a kind of biological sewage treatment nitration processes according to claim 1 is characterized in that: anaerobic pond and described anoxic pond are built jointly or are divided and build.
CNB2005100945609A 2005-09-27 2005-09-27 A Nitrification Process for Biological Treatment of Sewage Expired - Fee Related CN100412009C (en)

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CN101439917B (en) * 2008-12-10 2011-08-10 中国矿业大学 Anaerobic adsorption dephosphorization and denitrification process
CN101985385A (en) * 2010-12-01 2011-03-16 东南大学 Biological sewage treatment method for enhancing removal of estrogens
CN102276062A (en) * 2011-05-20 2011-12-14 中国矿业大学 Multistage anaerobic and anoxic circulating final segment aerobic activated sludge process
CN102249412B (en) * 2011-05-20 2013-02-13 中国矿业大学 Multistage anoxic and anaerobic circulation tail section anoxic activated sludge treatment process and system
CN104478081B (en) * 2014-12-01 2016-03-23 中国矿业大学 An anaerobic concurrent anoxic and aerobic enhanced phosphorus and nitrogen removal process
CN108585205B (en) * 2018-06-22 2023-06-16 江苏艾特克环境工程设计研究院有限公司 A kind of A/O sewage treatment device and sewage treatment process
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