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CN100411853C - Pressure Shock Wave Degassing Device for Resin Transfer Molding Process - Google Patents

Pressure Shock Wave Degassing Device for Resin Transfer Molding Process Download PDF

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Publication number
CN100411853C
CN100411853C CNB2005100412021A CN200510041202A CN100411853C CN 100411853 C CN100411853 C CN 100411853C CN B2005100412021 A CNB2005100412021 A CN B2005100412021A CN 200510041202 A CN200510041202 A CN 200510041202A CN 100411853 C CN100411853 C CN 100411853C
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shock wave
wave generator
rtm
resin
transfer molding
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CN1718414A (en
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汪炜
刘正勋
刘浏
董歧
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Nanjing University of Aeronautics and Astronautics
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Nanjing University of Aeronautics and Astronautics
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Abstract

一种树脂传递模塑工艺的压力激波除气装置,属复合材料制造技术领域,其装置包括激波发生器(5),激波发生器电源(6),RTM模具(7),所述激波发生器,由轻质壳体(1),压电陶瓷薄片(2),端盖(3),接线座(4)组成;具体实现方法,采用脉冲超声波技术,利用激波发生器(5)在模腔内形成具有瞬时高压效应的压力激波,促进树脂流动,起到提高树脂对纤维的浸润性、排除多余气体和去除微气泡的作用。该发明结构简单,使用方便,是航空航天领域复合材料构件树脂传递模塑成型工艺(RTM)的有效除气装置,同时,也适用于其他复合材料模具成型工艺的除气需求。

A pressure shock wave degassing device for a resin transfer molding process, which belongs to the technical field of composite material manufacturing, and the device includes a shock wave generator (5), a shock wave generator power supply (6), an RTM mold (7), and the shock wave generator (5). The wave generator is composed of a light shell (1), a piezoelectric ceramic sheet (2), an end cover (3), and a terminal block (4); the specific implementation method adopts pulsed ultrasonic technology, and utilizes a shock wave generator (5 ) forms a pressure shock wave with instantaneous high pressure effect in the mold cavity, promotes the flow of the resin, improves the wettability of the resin to the fiber, removes excess gas and removes microbubbles. The invention is simple in structure and easy to use, and is an effective degassing device for resin transfer molding (RTM) of composite material components in the aerospace field, and is also applicable to the degassing requirements of other composite material mold molding processes.

Description

树脂传递模塑工艺的压力激波除气装置 Pressure Shock Wave Degassing Device for Resin Transfer Molding Process

一、技术领域 1. Technical field

本发明的树脂传递模塑工艺的压力激波除气装置,属RTM模具成型工艺的除气装置及方法。The pressure shock wave degassing device of the resin transfer molding process of the present invention belongs to the degassing device and method of the RTM mold forming process.

二、背景技术 2. Background technology

随着聚合物基复合材料工业的发展,树脂传递模塑(RTM)工艺在国内外得到了越来越广泛的应用。RTM工艺过程是将液态树脂体系在一定压力下,注入预先铺放了纤维增强材料的闭合模腔内,树脂在模腔内浸润纤维增强材料后固化成型。由于在成型过程中空气不易排尽,复合材料制品中容易产生缺陷,从而降低其弯曲强度、拉伸强度、冲击强度和层间强度等。因此,提高成型过程中树脂对纤维的浸润性和减少孔隙率非常重要。With the development of the polymer matrix composites industry, the resin transfer molding (RTM) process has been more and more widely used at home and abroad. The RTM process is to inject a liquid resin system under a certain pressure into a closed mold cavity pre-laid with fiber reinforced materials, and the resin infiltrates the fiber reinforced materials in the mold cavity and then solidifies and forms. Since the air is not easy to exhaust during the molding process, defects are prone to occur in composite products, thereby reducing their bending strength, tensile strength, impact strength and interlayer strength. Therefore, it is very important to improve the wettability of the resin to the fiber and reduce the porosity during the molding process.

为了减少RTM成型复合材料的孔隙率和提高成型过程中树脂对纤维的浸润性,国内外研究者们做了大量工作。In order to reduce the porosity of RTM molding composites and improve the wettability of resin to fibers during the molding process, researchers at home and abroad have done a lot of work.

如发现在真空条件下充模能使制品的气泡含量减少。If it is found that filling the mold under vacuum conditions can reduce the air bubble content of the product.

通过文献检索,“Vibration Assisted Resin Transfer Molding”(13thInternational Conference on Composite Materials,2001),研究了音频振动对RTM成型工艺的影响。实验表明,音频振动有利于模腔中树脂对纤维的浸润,使浸润速度变快,气泡减少。Through literature search, "Vibration Assisted Resin Transfer Molding" ( 13th International Conference on Composite Materials, 2001), the influence of audio vibration on RTM molding process was studied. Experiments show that the audio frequency vibration is beneficial to the resin in the cavity to infiltrate the fibers, making the infiltration speed faster and reducing the air bubbles.

通过专利检索,哈尔滨工业大学申报的发明专利“超声处理树脂传递模塑方法及所用的装置”(专利申请号:03132430.4),在RTM工艺中对模具内腔中纤维和树脂进行超声处理,以提高树脂对纤维的浸润性和减少复合材料孔隙率,进而改善复合材料的界面性能。Through patent retrieval, the invention patent "Ultrasonic treatment of resin transfer molding method and device" (patent application number: 03132430.4) declared by Harbin Institute of Technology, in the RTM process, the fiber and resin in the cavity of the mold are ultrasonically treated to improve The wettability of the resin to the fiber and the reduction of the porosity of the composite material can improve the interfacial properties of the composite material.

上述专利技术采用的超声波频率在40~60kHz,声功率为0~400W,声功率密度并不大。当RTM模具型腔截面发生突变时,对微气泡的去除作用不明显。The ultrasonic frequency used in the above-mentioned patented technology is 40~60kHz, the sound power is 0~400W, and the sound power density is not large. When the cross-section of the RTM mold cavity changes abruptly, the removal effect on microbubbles is not obvious.

为解决工程实际中各种RTM模具的除气需求,有必要进一步研究新型RTM模具的除气装置及方法。In order to solve the degassing requirements of various RTM molds in engineering practice, it is necessary to further study the degassing device and method of new RTM molds.

三、发明内容 3. Contents of the invention

本发明旨在针对现有技术的现状,研究一种在RTM工艺中,能促进模腔内树脂流动,增强树脂对纤维的浸润性、排除多余气体和去除微气泡的有效方法。本发明的树脂传递模塑工艺的压力激波除气方法,采用脉冲超声波技术,利用压电式激波发生器在液体介质中形成具有瞬时高压效应的压力激波,对模腔内树脂产生定向瞬时压力扰动促进模腔内树脂活动,增强树脂对纤维的浸润性,排除多余气体和除微气泡。采用上述方法,不但可以促进模腔内树脂流动,而且不影响工艺系统的稳定性,有利于提高成型过程中树脂对纤维的浸润性和减少孔隙率,可广泛应用RTM模具除气技术领域。The present invention aims at the current state of the prior art, and researches an effective method that can promote the flow of resin in the mold cavity, enhance the wettability of the resin to fibers, eliminate excess gas and remove microbubbles in the RTM process. The pressure shock wave degassing method of the resin transfer molding process of the present invention adopts the pulse ultrasonic technology, utilizes the piezoelectric shock wave generator to form a pressure shock wave with instantaneous high pressure effect in the liquid medium, and produces directional instant for the resin in the mold cavity. The pressure disturbance promotes the resin movement in the mold cavity, enhances the wettability of the resin to the fibers, and removes excess gas and microbubbles. The above method can not only promote the flow of resin in the mold cavity, but also not affect the stability of the process system, which is beneficial to improve the wettability of resin to fibers and reduce porosity during the molding process, and can be widely used in the field of RTM mold degassing technology.

实现上述目标的树脂传递模塑工艺的压力激波除气装置,由与RTM模具相连的压电式激波发生器连于大功率激波电源组成。其中压电式激波发生器包括压电陶瓷薄片通过安装孔粘接在轻质壳体内表面,端盖与轻质壳体上端相连,通过密封垫密封、进电座位于端盖上。将激波发生器作为RTM模具的组成部分,通过对易于产生缺陷的部位施加定向辐射压力,促进RTM模腔内树脂流动,即可实现液体压力激波去除微气泡的功能。The pressure shock wave degassing device for the resin transfer molding process to achieve the above goals is composed of a piezoelectric shock wave generator connected to the RTM mold and a high-power shock wave power supply. The piezoelectric shock wave generator includes a piezoelectric ceramic sheet bonded to the inner surface of the lightweight housing through a mounting hole, the end cover is connected to the upper end of the lightweight housing, sealed by a gasket, and the power inlet seat is located on the end cover. The shock wave generator is used as an integral part of the RTM mold, and by applying directional radiation pressure to the parts prone to defects to promote the resin flow in the RTM mold cavity, the function of liquid pressure shock wave to remove microbubbles can be realized.

本发明与现有技术相比,压电式激波发生器能产生高能超声波,频率为(200~2000)kHz,并在模腔内形成具有瞬时高压效应的压力激波,起到增强树脂对纤维的浸润性、排除多余气体和去除微气泡的作用。Compared with the prior art, the present invention can generate high-energy ultrasonic waves with a frequency of (200-2000) kHz, and form a pressure shock wave with instantaneous high-pressure effect in the mold cavity to strengthen the resin against The wettability of fibers, the removal of excess gas and the removal of microbubbles.

根据实际生产中RTM模具的需求,压电式超声换能器的形状可以相应改变。本文将针对一种特殊形式的RTM模具结构,提出设计方案和实施方法。According to the requirements of the RTM mold in actual production, the shape of the piezoelectric ultrasonic transducer can be changed accordingly. This article will propose a design scheme and implementation method for a special form of RTM mold structure.

本发明装置具有结构简单,使用方便,成本低廉的优点。The device of the invention has the advantages of simple structure, convenient use and low cost.

四、附图说明 4. Description of drawings

图1一种RTM模具模腔局部剖视图。Figure 1 is a partial cross-sectional view of an RTM mold cavity.

注:在环型区域易产生孔隙。Note: porosity is easily generated in the annular area.

图2压电式激波发生器结构示意图,其中图2(a)为主视剖视示意图,图2(b)为俯视图。Fig. 2 is a structural schematic diagram of a piezoelectric shock wave generator, in which Fig. 2(a) is a schematic cross-sectional view of the front view, and Fig. 2(b) is a top view.

图中标号名称:1.轻质壳体,2.压电陶瓷薄片,3.端盖,4.进电座Label names in the figure: 1. Lightweight shell, 2. Piezoelectric ceramic sheet, 3. End cover, 4. Power inlet seat

图3轻质壳体示意图之一,其中上图为主视剖视图,下图为俯视图。Figure 3 is one of the schematic diagrams of the lightweight shell, in which the upper figure is a main sectional view, and the lower figure is a top view.

图4轻质壳体示意图之二,其中上图为主视剖视图,下图为俯视图。Figure 4 is the second schematic diagram of the lightweight shell, in which the upper figure is the main sectional view, and the lower figure is the top view.

图5液体压力激波除气装置使用示意图Figure 5 Schematic diagram of liquid pressure shock wave degassing device

图中标号名称:5.压电式激波发生器,6.大功率激波电源,7、RTM模具Label names in the figure: 5. Piezoelectric shock wave generator, 6. High-power shock wave power supply, 7. RTM mold

五、具体实施方式 5. Specific implementation

本发明的具体构成是:如图2所示,在轻质壳体1内表面粘接压电陶瓷薄片2,端盖3与轻质壳体1联接,两者之间用密封垫密封。轻质壳体1如图3所示,在轻质壳体1上,设计压电陶瓷薄片2的安装孔;安装孔底面距轻质壳体1表面的距离d根据公式(1)确定:The specific structure of the present invention is as follows: as shown in Figure 2, the piezoelectric ceramic sheet 2 is bonded to the inner surface of the lightweight housing 1, the end cover 3 is connected with the lightweight housing 1, and the two are sealed with a gasket. The lightweight housing 1 is shown in Figure 3, on the lightweight housing 1, the installation hole of the piezoelectric ceramic sheet 2 is designed; the distance d between the bottom surface of the installation hole and the surface of the lightweight housing 1 is determined according to the formula (1):

dd == nno ff 44 cc -- -- -- (( 11 ))

其中:f为压电陶瓷薄片的纵向谐振频率,c为轻质壳体1材料内声速,f与c可以通过实际测量得到,n是自然数。Where: f is the longitudinal resonance frequency of the piezoelectric ceramic sheet, c is the sound velocity in the material of the lightweight shell 1, f and c can be obtained through actual measurement, and n is a natural number.

压电陶瓷薄片的尺寸、形状和数目根据实际需要设计,并由此确定轻质壳体1的具体形式。图3和图4所示为满足图1所示RTM模具要求的两种轻质壳体具体形式。The size, shape and number of piezoelectric ceramic sheets are designed according to actual needs, and thus determine the specific form of the lightweight housing 1 . Figures 3 and 4 show two specific forms of lightweight shells that meet the requirements of the RTM mold shown in Figure 1.

为保证良好的透声效果,可采用机械加工方法,通过一次装夹,在轻质壳体1上加工出所有压电陶瓷安装孔,保证各孔的形状和位置精度,满足所需表面加工精度和质量,从而保证粘接质量与声学聚焦效果。In order to ensure a good sound transmission effect, the mechanical processing method can be used to process all the piezoelectric ceramic mounting holes on the lightweight shell 1 through one clamping, so as to ensure the shape and position accuracy of each hole and meet the required surface processing accuracy And quality, so as to ensure the bonding quality and acoustic focusing effect.

采用特殊粘接工艺,保证压电陶瓷薄片2与轻质壳体1的粘接质量。A special bonding process is adopted to ensure the bonding quality of the piezoelectric ceramic sheet 2 and the light shell 1 .

图5所示的是液体压力激波除气装置使用示意图,即将大功率激波电源6通过端盖3上的进电座4与压电式激波发生器5相连,压电式激波发生器5作为RTM模具7的组成部分。Figure 5 is a schematic diagram of the use of the liquid pressure shock wave degassing device, that is, the high-power shock wave power supply 6 is connected to the piezoelectric shock wave generator 5 through the power inlet seat 4 on the end cover 3, and the piezoelectric shock wave generator 5 as an integral part of the RTM mold 7.

具体工作方式:The specific working method:

压电式激波发生器5作为RTM模具7的组成部分(具体位置根据实际需求而定),在大功率激波电源6的配合下,工作频率为(200~2000)kHz,功率为(0~2000)W,从而实现除气功能,提高复合材料制品的性能。The piezoelectric shock wave generator 5 is a component of the RTM mold 7 (the specific location depends on the actual demand), and with the cooperation of the high-power shock wave power supply 6, the working frequency is (200-2000) kHz, and the power is (0 ~2000) W, so as to realize the degassing function and improve the performance of composite products.

Claims (2)

1. the pressure shock wave depassing unit of a resin transfer molding (RTM) process, it is characterized in that, comprise piezoelectric type shock wave generator (5), high-power shock wave power supply (6), RTM mould (7), wherein high-power shock wave power supply (6) is connected in piezoelectric type shock wave generator (5), piezoelectric type shock wave generator (5) is connected in RTM mould (7), described piezoelectric type shock wave generator (5) comprises piezoelectric ceramic thin sheet (2), lightweight housing (1), end cap (3), sealing gasket (4), wherein piezoelectric ceramic thin sheet (2) is bonded in lightweight housing (1) inner surface by installing hole, and end cap (3) connects with lightweight housing (1), by sealing gasket (4) sealing, electricity-supply seat is positioned on the end cap (3).
2. the pressure shock wave depassing unit of resin transfer molding (RTM) process according to claim 1 is characterized in that, the installing hole bottom surface that lightweight housing (1) is gone up piezoelectric ceramic thin sheet (2) apart from lightweight housing (1) surface distance d according to formula d = n f 4 c Determine that wherein: n is a natural number, f is vertical resonant frequency of piezoelectric ceramics, and c is the velocity of sound in lightweight housing (1) material.
CNB2005100412021A 2005-07-27 2005-07-27 Pressure Shock Wave Degassing Device for Resin Transfer Molding Process Expired - Fee Related CN100411853C (en)

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CN107097435A (en) * 2017-06-27 2017-08-29 东莞市昌亿复合材料机械科技有限公司 A kind of vacuum forming machine of composite and the forming method of composite
CN107160714B (en) * 2017-07-07 2019-10-22 沈阳斯塔娜航空科技有限公司 A kind of barometric pulse-type pressurization method for composite material
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