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CN100396811C - High intensity abrasion resistant arc spraying filament material for circulating fluidized bed boiler - Google Patents

High intensity abrasion resistant arc spraying filament material for circulating fluidized bed boiler Download PDF

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Publication number
CN100396811C
CN100396811C CNB2005100192498A CN200510019249A CN100396811C CN 100396811 C CN100396811 C CN 100396811C CN B2005100192498 A CNB2005100192498 A CN B2005100192498A CN 200510019249 A CN200510019249 A CN 200510019249A CN 100396811 C CN100396811 C CN 100396811C
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CN
China
Prior art keywords
abrasion resistant
crb
present
arc spraying
fluidized bed
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Expired - Fee Related
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CNB2005100192498A
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Chinese (zh)
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CN1730713A (en
Inventor
周华荣
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JIANGXI HENGDA HI-TECH CO LTD
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Individual
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Priority to CNB2005100192498A priority Critical patent/CN100396811C/en
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Publication of CN100396811C publication Critical patent/CN100396811C/en
Expired - Fee Related legal-status Critical Current
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  • Coating By Spraying Or Casting (AREA)

Abstract

The present invention discloses a high-intensity abrasion resistant electric arc spraying wire material for circulating fluidized bed boilers, which takes a low-carbon steel band or a stainless steel band as a wire material housing, and the mixture powder of CrB2 and B4 C is added into a wire core. The content of the mixture of CrB2 and B4 C is from 25 to 48 Wt percent, and CrB2 takes up 70 to 95 Wt percent of the mixture of CrB2 and B4 C. The thickness of the low-carbon steel band or the stainless steel band is from 0.3 to 0.5mm, and the wire core of the wire material contains 0 to 5 Wt% of one kind of the powders, such as Ni, Al, Mo and/or a rare-earth element. The electric arc spraying wire material of the present invention, which is applied to heating surfaces of circulating fluidized bed boilers, has a good abrasion resisting effect and has the service life 2 to 3 times longer than that of a coating layer made of a general abrasion resistant wire material in markets. The present invention can extend the service life of the heating surfaces of the circulating fluidized bed boilers by more than 3 to 10 times. The present invention can stilled be used for continuously making abrasion resistant coating layers on an original residual coating layer after adopting appropriate surface treatment, and accordingly, the present invention has the advantage of long service life.

Description

The circular fluid bed high intensity abrasion resistant arc spraying filament material
Technical field
The present invention relates to a kind of circular fluid bed arc spraying filament material, relate in particular to a kind of circular fluid bed high intensity abrasion resistant arc spraying filament material.
Background technology
Circular fluid bed is that China recent years is advocated and the type of furnace with fastest developing speed energetically because of three big characteristics such as clean, efficient and coal-fired wide adaptability enjoy favor.But because of warm circulating combustion wherein and a large amount of low grade coals of burning, heating surface exists extremely serious erosive wear, abrasive wear and eddy current wearing and tearing, and its degree of wear is much more serious than common coal-powder boiler.Most of circular fluid bed local heating face just occurred wearing and tearing booster problem in 1-3 month in operation, and it is shorter that the circular fluid bed heating surface that has grinds the quick-fried life-span, can safe operation half a year above circular fluid bed rarely found.
In order to solve circular fluid bed heating surface wear problem, people have done multiple trial, but from a large amount of practices, High Speed Electric Arc Spraying technology is the effective technology that the most suitable present on-the-spot big area solves its heating surface abrasionproof.Yet existing in the market arc spraying filament material all is difficult to reach the requirement of circular fluid bed heating surface abrasionproof, and the coating macrogamy is bad, and work-ing life is extremely short.The coating that the silk material that has is made is hard and crisp, hard is poor with matching property of adhesion, be easy to be washed away, though the coating toughness that the silk material that has is made is good, but too soft, not wear-resisting, the silk material that also has is difficult to meet the electric arc spraying process requirement, melt bad, easily current interruption and coating is inhomogeneous, unfairness or the like.Therefore, be necessary very much to develop the High Speed Electric Arc Spraying silk material of a kind of suitable circular fluid bed operation and wearing and tearing characteristics,, improve the abrasionproof effect to satisfy its abrasionproof requirement.
Summary of the invention
The objective of the invention is to: overcome the above-mentioned defective of prior art, a kind of circular fluid bed high intensity abrasion resistant arc spraying filament material of abrasionproof better effects if is provided.
The present invention realizes by following scheme: with mild-carbon steel strip or Stainless Steel Band is a material crust, is added with CrB in the silk core 2And B 4The mix powder of C.
CrB of the present invention 2And B 4The content of C mixture is: 25-48Wt%.
CrB of the present invention 2And B 4CrB in the C mixture 2Account for 70-95Wt%.
Mild-carbon steel strip of the present invention or stainless steel tape thickness are: contain the Ni of 0-5Wt% and/or any one powder in Al and/or Mo and/or the rare earth element in the silk core of the described silk of 0.3-0.5mm material.
CrB of the present invention 2And B 4In the C powder, CrB 2Account for 85Wt%, B 4C accounts for 15Wt%.
It is fine that the present invention program is applied to circular fluid bed heating surface abrasionproof effect, is 2-3 times that general wear-resisting silk material is made coating life on the market, the life-span of circular fluid bed heating surface can be improved more than 3-10 times.If can also on former residual coating, continue to make the abrasionproof coating after adopting suitable surface treatment, thereby its life-span is prolonged greatly.
Embodiment
Be elaborated below in conjunction with the embodiment of the invention.
Embodiment 1:
The described silk of present embodiment material is a material crust with mild-carbon steel strip, is added with 25Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 70: 30.
Embodiment 2:
The described silk of present embodiment material is a material crust with mild-carbon steel strip, is added with 25Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 70: 30, and is added with the 5Wt%Ni powder.
Embodiment 3:
The described silk of present embodiment material mild-carbon steel strip is a silk material crust, is added with 30Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 75: 25.
Embodiment 4:
The described silk of present embodiment material is a material crust with the thick mild-carbon steel strip of 0.5mm, is added with 30Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 75: 25, and is added with 3Wt%Ni and Al mix powder.
Embodiment 5:
The described silk of present embodiment material is a material crust with the thick mild-carbon steel strip of 0.3mm, is added with 35Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 80: 20, also is added with 2%Ni, Al and Mo mix powder.
Embodiment 6:
The described silk of present embodiment material is a material crust with the thick mild-carbon steel strip of 0.4mm, is added with 35Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 80: 20.
Embodiment 7:
The described silk of present embodiment material is a material crust with the thick mild-carbon steel strip of 0.45mm, is added with 40Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 85: 15, also is added with 2%Ni, Al, Mo, scandium Sc mix powder.
Embodiment 8:
The described silk of present embodiment material is a material crust with the thick mild-carbon steel strip of 0.35mm, is added with 40Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 85: 15.
Embodiment 9:
The described silk of present embodiment material is a material crust with the thick mild-carbon steel strip of 0.5mm, is added with 45Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 95: 5, also is added with 5%Ni, Al, yttrium Y mix powder.
Embodiment 10:
The described silk of present embodiment material is a material crust with the thick mild-carbon steel strip of 0.45mm, is added with 45Wt%CrB in the silk core 2And B 4The mix powder of C, wherein CrB 2With B 4The C weight ratio is 95: 5, also is added with 5%Al, Mo, cerium Ce mix powder.

Claims (4)

1. circular fluid bed high intensity abrasion resistant arc spraying filament material is characterized in that: be to be a material crust with mild-carbon steel strip or Stainless Steel Band, be added with CrB in the silk core 2And B 4The mix powder of C, CrB 2And B 4The content of C mixture is: 25-48Wt%, CrB 2And B 4CrB in the C mixture 2Account for 70-95Wt%.
2. circular fluid bed high intensity abrasion resistant arc spraying filament material according to claim 1 is characterized in that: mild-carbon steel strip or stainless steel tape thickness are: 0.3-0.5mm.
3. circular fluid bed high intensity abrasion resistant arc spraying filament material according to claim 1 and 2 is characterized in that: contain the Ni of 0-5Wt% and/or any one powder in Al and/or Mo and the rare earth element in the silk core of described silk material.
4. circular fluid bed high intensity abrasion resistant arc spraying filament material according to claim 1 and 2 is characterized in that: CrB 2And B 4In the C powder, CrB 2Account for 85Wt%, B 4C accounts for 15Wt%.
CNB2005100192498A 2005-08-05 2005-08-05 High intensity abrasion resistant arc spraying filament material for circulating fluidized bed boiler Expired - Fee Related CN100396811C (en)

Priority Applications (1)

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CNB2005100192498A CN100396811C (en) 2005-08-05 2005-08-05 High intensity abrasion resistant arc spraying filament material for circulating fluidized bed boiler

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005100192498A CN100396811C (en) 2005-08-05 2005-08-05 High intensity abrasion resistant arc spraying filament material for circulating fluidized bed boiler

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CN100396811C true CN100396811C (en) 2008-06-25

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102994935B (en) * 2012-11-16 2014-07-16 北京球冠科技有限公司 Electric arc spraying powder core wire with high-temperature resistance and chlorine corrosion resistance
CN114351073A (en) * 2021-11-24 2022-04-15 华能济宁运河发电有限公司 Nickel-chromium carbide metal ceramic spraying wire and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1224678A (en) * 1969-06-30 1971-03-10 Inst Elektroswarki Patona Electrode for building up abrasion-resistant deposits on steel articles
CN87103718A (en) * 1986-05-20 1987-12-09 珀金—埃尔默公司 The clad metal wire that is used for scuff-resistant coating
US20030106198A1 (en) * 1999-11-11 2003-06-12 Shear Tool, Inc. Methods of making wear resistant tooling systems to be used in high temperature casting and molding
RU2220225C1 (en) * 2002-11-10 2003-12-27 Открытое акционерное общество "Магнитогорский металлургический комбинат" Method of boron chromium plating of steel articles
CN1582264A (en) * 2001-11-06 2005-02-16 独立行政法人产业技术总合研究所 Boron carbide based sintered compact and method for preparation thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1224678A (en) * 1969-06-30 1971-03-10 Inst Elektroswarki Patona Electrode for building up abrasion-resistant deposits on steel articles
CN87103718A (en) * 1986-05-20 1987-12-09 珀金—埃尔默公司 The clad metal wire that is used for scuff-resistant coating
US20030106198A1 (en) * 1999-11-11 2003-06-12 Shear Tool, Inc. Methods of making wear resistant tooling systems to be used in high temperature casting and molding
CN1582264A (en) * 2001-11-06 2005-02-16 独立行政法人产业技术总合研究所 Boron carbide based sintered compact and method for preparation thereof
RU2220225C1 (en) * 2002-11-10 2003-12-27 Открытое акционерное общество "Магнитогорский металлургический комбинат" Method of boron chromium plating of steel articles

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
化学成分对铁-铬碳系堆焊材料抗磨性能的影响. 斯重遥等.焊接学报,第7卷第1期. 1986
化学成分对铁-铬碳系堆焊材料抗磨性能的影响. 斯重遥等.焊接学报,第7卷第1期. 1986 *
硼对Fe-Cr-C耐磨堆焊合金组织的影响. 王智慧等.材料工程,第2001卷第10期. 2001
硼对Fe-Cr-C耐磨堆焊合金组织的影响. 王智慧等.材料工程,第2001卷第10期. 2001 *

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