CN100351210C - High carbon high strength fireproof board - Google Patents
High carbon high strength fireproof board Download PDFInfo
- Publication number
- CN100351210C CN100351210C CNB2006100873770A CN200610087377A CN100351210C CN 100351210 C CN100351210 C CN 100351210C CN B2006100873770 A CNB2006100873770 A CN B2006100873770A CN 200610087377 A CN200610087377 A CN 200610087377A CN 100351210 C CN100351210 C CN 100351210C
- Authority
- CN
- China
- Prior art keywords
- present
- siccative
- high strength
- graphite
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 9
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 239000004113 Sepiolite Substances 0.000 claims abstract description 6
- 239000010439 graphite Substances 0.000 claims abstract description 6
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 6
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 6
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 6
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 6
- 239000010455 vermiculite Substances 0.000 claims abstract description 6
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 6
- 239000004033 plastic Substances 0.000 claims description 9
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003063 flame retardant Substances 0.000 claims description 7
- 235000011194 food seasoning agent Nutrition 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 210000000085 cashmere Anatomy 0.000 claims description 4
- 238000000748 compression moulding Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000005272 metallurgy Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001007 puffing effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a fireproof plate with high carbon and high strength. The present invention adopts the main raw materials of graphite which is a functional material and is the most refractory in known elements at present, and the natural mineral of vermiculite, sepiolite, etc. The present invention takes homemade aqueous high-temperature resistant epoxy resin as adhesives, adopts the existing production facilities, and is formed by stirring, shaping and drying. The present invention has the advantage of very simple and convenient processing, can produce fireproof plate products with high performance, and has the outstanding characteristics of high temperature resistance and high strength. The fire endurance limit reaches 1500 DEGC to 3000 DEGC, and the fire endurance time reaches 60 to 180 minutes according to different requirements, different sizes and different thickness indexes. The present invention can not lose fireproof characteristics in long-term use, and has good weatherproof performance and good environmental protection.
Description
Technical field
The present invention relates to a kind of fire-proof board and manufacture method thereof, relate in particular to a kind of high-carbon, high-strength fire-retardant plate.
Background technology
Fire-proof board of the prior art, most of material that adopts is the fire retardant that contains asbestos or Chemical Composition, adopts the traditional processing technology of drying after immersion treatment.Its drawback is that through the PLASTIC LAMINATED that chemical fire retardant soaks, the weather resisteant extreme difference usually can the phenomenon of getting damp can occur along with the variation of weather.Like this, not only influenced the aesthetic property of sheet material, main is in life-time service, also can cause certain harm to human body.And fire resistance also can be faded along with the prolongation of time or disappear.Thereby lost the fire resistance of PLASTIC LAMINATED product.
Summary of the invention
Purpose of the present invention is to overcome above-mentioned deficiency, and a kind of high-carbon, high-strength fire-retardant plate are provided.
The objective of the invention is to be achieved through the following technical solutions.
A kind of high-carbon, high-strength fire-retardant plate, its making method comprises:
Get weight part graphite 20-35 part, expanded vermiculite 40-55 part, macrofiber sepiolite cashmere 30-40 part, siccative 5-8 part, for starting material stand-by.
Select 20 parts of aqueous epoxy resins for use, Graphite Powder 99 5 powder with 75 parts water, under 50 ℃-70 ℃ temperature action, stir 10min, make the high-temperature plastic solution of aqueous epoxy resins.
With above-mentioned siccative and cementing agent ratio in 1: 8, carry out mixing and stirring after, divide in mold box by required specification, send into compression moulding in the common rolling machine, seasoning forms then.
Outstanding feature of the present invention is: high temperature resistant, high strength.Can be under the requirement of different demands and different size, thickness index, fire endurance can reach 1500 ℃-3000 ℃.Fire resistance period can be from 60-180min.Life-time service can not lose fire performance.And have good weather resisteant, heat insulation, insulation, sound-absorbing, protection against the tide, light body, corrosion-resistant, water-fast dipping, high strength and a good environmental-protecting performance under the high temperature.Because these excellent physics, chemical property are arranged, can be widely used in military, civilian, commercial building, chemical industry, light industry, oil, metallurgy, shipbuilding, space flight, electric power, nuclear industry, etc. the purposes in different fire prevention field.
Embodiment
It is as follows to take raw-material kind and quantity: graphite 20-35 part, expanded vermiculite 40-55 part, macrofiber sepiolite cashmere 30-40 part, other siccative 5-8 part.
Select for use 20 parts of aqueous epoxy resins, Graphite Powder 99 5 powder, with 75 parts water, under the effect of 50 ℃ of-70 ℃ of temperature, stir 10min and make aqueous epoxy resins high-temperature plastic solution.
With above-mentioned siccative and cementing agent ratio in 1: 8, carry out mixing and stirring after, divide in mold box by required specification, send into compression moulding in the common rolling machine.Seasoning forms then.
The technology of the present invention can be widely used in: military, civilian, commercial building, chemical industry, light industry, oil, metallurgy, shipbuilding, space flight, electric power, nuclear industry, etc. different PLASTIC LAMINATED field.Can be at the existing various deficiencies of above-mentioned traditional PLASTIC LAMINATED, provide a kind of sheet material that can environmental protection can play the fire prevention excellent effect again for a long time.
The technology of the present invention theoretical basis: utilize known inorganic elements graphite to have high strength, corrosion-resistant under high temperature resistant, the high temperature, and can bear fierce chemical reaction, and have excellent specific property such as nontoxic, environmental protection.Binding fiber shape sepiolite 3 D stereo bond structure and absorption property are extremely strong, the performance that thermal stability is high, add through the high temperature puffing vermiculite as aggregate, under the gummed of self-control water-base epoxy fire resistant resin caking agent, pave after stirring in Die and mould plate, form through rolling the typing seasoning.
Concrete implementation detail is provided by following examples.
Step 1:
With known inorganic elements: graphite 20-35 part, expanded vermiculite 40-55 part, macrofiber sepiolite cashmere 30-40 part, other siccative 5-8 part, through give mix stir stand-by.
Step 2:
Will from 20 parts of preparing aqueous epoxy resins, Graphite Powder 99 5 powder, with 75 parts water, under the effect of 50 ℃ of-70 ℃ of temperature, stir 10min and make aqueous epoxy resins high-temperature plastic solution.
Step 3:
Above-mentioned siccative and the high-temperature plastic ratio in 1: 8 is fully stirred, make the mixture of siccative and glue.
Step 4: said mixture divided in the mould of desired product thickness, size seasoning gets final product after rolling machine compression moulding.
Claims (1)
1, a kind of high-carbon, high-strength fire-retardant plate is characterized in that: its making method comprises,
Get weight part graphite 20-35 part, expanded vermiculite 40-55 part, macrofiber sepiolite cashmere 30-40 part, siccative 5-8 part, for the starting material siccative stand-by;
Select 20 parts of aqueous epoxy resins for use, 5 parts of Graphite Powder 99s with 75 parts water, under 50 ℃-70 ℃ temperature action, stirred 10 minutes, made the high-temperature plastic solution of aqueous epoxy resins;
With above-mentioned siccative and sol solution ratio in 1: 8, carry out mixing and stirring after, divide in mold box by required specification, send into compression moulding in the common rolling machine, seasoning forms then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100873770A CN100351210C (en) | 2006-06-13 | 2006-06-13 | High carbon high strength fireproof board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100873770A CN100351210C (en) | 2006-06-13 | 2006-06-13 | High carbon high strength fireproof board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1868969A CN1868969A (en) | 2006-11-29 |
| CN100351210C true CN100351210C (en) | 2007-11-28 |
Family
ID=37442770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100873770A Expired - Fee Related CN100351210C (en) | 2006-06-13 | 2006-06-13 | High carbon high strength fireproof board |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100351210C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101909870A (en) * | 2007-12-19 | 2010-12-08 | 巴斯夫欧洲公司 | The moulded parts of making by the carrier material that contains the foaming activity resin |
| CN102464469B (en) * | 2010-11-19 | 2013-12-04 | 山东鲁阳股份有限公司 | Dry formed hydrophobic ceramic fiber building fireproof plate and preparation method thereof |
| CN104944846B (en) * | 2015-05-19 | 2017-03-22 | 林文堡 | Compression-resistant fireproof board and preparation method thereof |
| CN104961384B (en) * | 2015-06-25 | 2016-11-09 | 朱利雄 | A kind of carbon plate and manufacturing process thereof |
| CN106565194A (en) * | 2016-10-28 | 2017-04-19 | 芜湖浩权建筑工程有限公司 | High-strength and high-temperature-resistant building fireproof plate material and preparation method thereof |
| CN110204860A (en) * | 2019-04-18 | 2019-09-06 | 浙江上青元电力科技有限公司 | A kind of electric shaft expansion fire-proof partition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1108634A (en) * | 1994-08-25 | 1995-09-20 | 武汉钢铁(集团)公司 | Fired microporous carbon-aluminium brick |
| JP2005179569A (en) * | 2003-12-22 | 2005-07-07 | Toshiba Corp | Fiber reinforced composite material for sulfur hexafluoride gas insulation equipment and method for producing the same |
| CN1769239A (en) * | 2004-11-01 | 2006-05-10 | 武汉科技大学 | Carbon brick for ironmaking blast furnace lining and preparation method thereof |
-
2006
- 2006-06-13 CN CNB2006100873770A patent/CN100351210C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1108634A (en) * | 1994-08-25 | 1995-09-20 | 武汉钢铁(集团)公司 | Fired microporous carbon-aluminium brick |
| JP2005179569A (en) * | 2003-12-22 | 2005-07-07 | Toshiba Corp | Fiber reinforced composite material for sulfur hexafluoride gas insulation equipment and method for producing the same |
| CN1769239A (en) * | 2004-11-01 | 2006-05-10 | 武汉科技大学 | Carbon brick for ironmaking blast furnace lining and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 无机纳米粒子/环氧树脂基复合材料的研究现状 崔益华等.宇航材料工艺，第4期 2003 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1868969A (en) | 2006-11-29 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |