CN100348518C - Treatment method of soybean lactalbumin waste water - Google Patents
Treatment method of soybean lactalbumin waste water Download PDFInfo
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- CN100348518C CN100348518C CNB200510019238XA CN200510019238A CN100348518C CN 100348518 C CN100348518 C CN 100348518C CN B200510019238X A CNB200510019238X A CN B200510019238XA CN 200510019238 A CN200510019238 A CN 200510019238A CN 100348518 C CN100348518 C CN 100348518C
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- water
- protein
- nanofiltration
- soybean
- reverse osmosis
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- 244000068988 Glycine max Species 0.000 title claims abstract description 32
- 235000010469 Glycine max Nutrition 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000002351 wastewater Substances 0.000 title claims abstract description 15
- 102000004407 Lactalbumin Human genes 0.000 title claims description 5
- 108090000942 Lactalbumin Proteins 0.000 title claims description 5
- 239000012528 membrane Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 102000007544 Whey Proteins Human genes 0.000 claims abstract description 27
- 108010046377 Whey Proteins Proteins 0.000 claims abstract description 27
- 239000005862 Whey Substances 0.000 claims abstract description 25
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 20
- 238000001728 nano-filtration Methods 0.000 claims abstract description 17
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 8
- 239000003513 alkali Substances 0.000 claims abstract description 6
- 239000000919 ceramic Substances 0.000 claims abstract description 6
- 150000001413 amino acids Chemical class 0.000 claims abstract description 3
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 3
- 238000000926 separation method Methods 0.000 claims description 21
- 239000000706 filtrate Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 8
- 238000011109 contamination Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 4
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 2
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 claims description 2
- 244000005700 microbiome Species 0.000 claims 1
- 229920001542 oligosaccharide Polymers 0.000 abstract description 10
- 150000002482 oligosaccharides Chemical class 0.000 abstract description 10
- 102000004169 proteins and genes Human genes 0.000 abstract description 10
- 108090000623 proteins and genes Proteins 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000011084 recovery Methods 0.000 abstract description 3
- 235000019764 Soybean Meal Nutrition 0.000 abstract description 2
- 230000004907 flux Effects 0.000 abstract description 2
- 239000004455 soybean meal Substances 0.000 abstract description 2
- 101710093543 Probable non-specific lipid-transfer protein Proteins 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 150000002772 monosaccharides Chemical class 0.000 abstract 1
- 239000006188 syrup Substances 0.000 description 6
- 235000020357 syrup Nutrition 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 235000008504 concentrate Nutrition 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000018102 proteins Nutrition 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 108010073771 Soybean Proteins Proteins 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 235000019710 soybean protein Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 235000021119 whey protein Nutrition 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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Abstract
The present invention relates to a treating method of soybean whey wastewater, which comprises the following steps: basic protein is separated from soybean whey wastewater with an inorganic ceramic compound ultrafiltration membrane; oligosaccharide is separated from soybean whey wastewater by nanofiltration; pure water is obtained by removing inorganic salt, monosaccharide, amino acid, etc. in nanofiltration filter liquor by reverse osmosis; pure water can be recovered to be used for the soybean meal process step of alkali dissolution; the protein and the oligosaccharide can be further treated to obtain pure protein and oligosaccharide. Because the pH value of soybean whey water is kept about 4.5 in the present invention, protein in the soybean whey water can be completely separated, and the purity of oligosaccharide the recovery rate of protein are increased; the process step of ultrafiltration uses an inorganic ceramic composite membrane with highly resistance to protein pollution; the process steps of nanofiltration and reverse osmosis use novel membranes with resistance to strong alkali and acid and resistance to protein pollution; compared with common membranes, the membrane flux of the membranes is increased over 20%; the work efficiency is obviously improved; because the water resource of soybean whey is fully used and the water can be used for production, polluted water is not exhausted.
Description
Technical field
The present invention relates to a kind of treatment method of soybean lactalbumin waste water, and from soya whey wastewater, extract oligose and albumen.
Background technology
The soya whey wastewater of indication of the present invention is to be in the raw material production soybean protein isolate process with the defatted soybean meal, and dregs of beans is molten through alkali, acid is heavy, the organic waste water that produces behind the albumen is extracted in centrifugation, wherein contains class materials such as albumen, oligose.Protein content 0.4～0.6%; Water-soluble sugar 0.6～0.8%; Suspended substance 0.7%; PH=4.4～4.8; Chemical oxygen demand COD: 18000～20000mg/L; Biochemical oxygen demand (BOD) BOD:8000～9000mg/L.Manufacturing enterprise generally adopts traditional pollution treatment technologies such as anaerobism, oxygen consumption that soya whey wastewater is handled the back discharging at present.Subject matter is:
1, effective ingredients such as the albumen in the soya whey wastewater, oligose are discharged with water, the waste resource;
2, not recycle of water resources;
3, the waste water disposal facility investment is big, operational management cost height;
4, the water after the processing is difficult for the stably reaching standard discharging.
Chinese patent application number 01101965 " extracting the method for soybean oligosaccharide from soybean whey water ", application number 01101967 " method of extracting soybean whey protein by super filtering " have been introduced a kind of method of extracting soybean oligosaccharide and soybean whey protein from soybean whey water respectively.The problem that this method exists is:
1, the organic membrane that adopts in its scheme, because the limitation of material, can not acid and alkali-resistance, and working temperature can not influence the film working efficiency greater than 45 ℃;
2, the pH value is 2～4 during ultrafiltration, belongs to strongly-acid, has a strong impact on the work-ing life of the ultra-filtration membrane that its scheme selects for use, and the albumen in the soybean whey can not be separated out fully, causes that oligose purity is not enough, albumen reclaims not exclusively;
3, this scheme does not relate to the advanced treatment and the reuse of water.
Summary of the invention
The present invention provides a kind of treatment method of soybean lactalbumin waste water in order to overcome defective and the problem that above-mentioned prior art exists, and this method is extracted oligose and albumen continuously from soya whey wastewater on a production line, and accomplishes the recycling of water.
Technological line of the present invention comprises following steps as shown in Figure 1:
1, ultrafiltration: soya whey wastewater with being pumped into the ultra-filtration membrane separation system, is held back sphaeroprotein and white protein in the soybean whey water, and the used film of this ultrafiltration system is that molecular weight cut-off is the inorganic ceramic composite membrane of the high anti-protein-contamination of 10KD, and this type of film is at TiO
2Carry out on the face and covered one deck ZrO
2, its pore size distribution is narrow, separation efficiency is high, chemical stability is good, the anti-protein-contamination ability is good, acid and alkali-resistance, high temperature resistant, and ultra-filtration membrane separation system operating pressure is 0.8～1.0MPa, and working temperature is 55～65 ℃;
2, nanofiltration: the filtrate that above-mentioned ultra-filtration and separation goes out is paid the filtration of filter membrane separation system, hold back the oligose in the soybean whey water, the used film of this nanofiltration system is the composite nanometer filtering film of 0.8～1.2nm for seeing through the aperture, this type of film acid and alkali-resistance, anti-protein-contamination, nanofiltration membrane separation system works pressure is 1.0～3.0MPa, and working temperature is 40～45 ℃;
3, reverse osmosis: the filtrate that above-mentioned nanofiltration separation goes out is handed over the reverse osmosis membrane separation system filtration, remove the class materials such as inorganic salt, monose and amino acid in the nanofiltration filtrate, reverse osmosis filtrate is pure water, can be back to the molten operation of dregs of beans alkali, film separating system operating pressure 2.5～3.2MPa that this reverse osmosis system is used, working temperature is 40～45 ℃;
4, decolouring: with the concentrated solution of nanofiltration oligosaccharide syrup activated carbon decolorizing just, the used gac of the present invention is 100～120 order powderies, and add-on is the 2nd to go on foot 2～3% of gained oligosaccharide syrup, and bleaching time is 10～20 minutes;
5, take off charcoal: the oligosaccharide syrup that will add gac enters strainer and filters, and holds back gac, and the used strainer of the present invention is the PE accurate filter in 0.1～0.8 μ m aperture;
6, the present invention extracts and also includes in the process program of oligose oligosaccharide syrup adjust pH spray-dired operation to neutral, the double-effect evaporation;
7, the present invention extracts and also includes albumen adjust pH that ultrafiltration is held back spray-dired operation to neutral, the double-effect evaporation in the proteic process program.
Technical scheme beneficial effect provided by the present invention is:
1, total system adopts membrane separation technique, has avoided the traditional heating flocculence destruction to material properties.
2, ultrafiltration operation has been selected the inorganic ceramic composite membrane for use, and the anti-protein-contamination film of novel anti-high soda acid has been selected in nanofiltration and reverse osmosis for use, improves membrane flux respectively more than 20%, obviously increases working efficiency.
3, this programme concentrates with the film system and has reduced conventional economic benefits and social benefits or the spissated load of multiple-effect evaporation, has reduced a large amount of energy consumptions.
4, made full use of the water resources of soybean whey, made water be back among the production without sewage discharge.
Description of drawings
Fig. 1 is a process route view of the present invention.
Embodiment
A factory that produces 2500 tons of soybean protein isolates per year produces soybean whey water 250m every day
3, wherein albumen is 0.41%, and total reducing sugar is 0.77%, comprises that oligose is 0.63%, and sucrose is 0.14%, designs in 20 hours by working every day, on average per hour handles whey 12.5m
3At first whey water is handled with being pumped into the ultra-filtration membrane separation system, ultra-filtration membrane is that molecular weight cut-off is the inorganic ceramic composite membrane of the high anti-protein-contamination of 10KD, and system pressure is 0.8～1.0MPa, and working temperature is 60 ℃, and the enriched material after the ultra-filtration and separation has 15m
3, wherein contain albumen 5.8%, send into albumen storage tank adjust pH and transfer to neutrality, concentrate back friendship spraying drying through double-effect evaporation, obtain protein content and be 1.3 tons of 65% protein powders; Filtrate 230m after the ultra-filtration and separation
3Pay the filter membrane separation system and handle, nanofiltration membrane is the composite nanometer filtering film in 1.0nm aperture, and system pressure is 2.0MPa, and working temperature is 45 ℃, concentrate about 10 times after, its concentrated solution has 23m
3, for containing the syrup of oligose 7.9%, with turning over a finished item property of syrup carbon decoloring, after 0.5 μ m aperture PE strainer took off charcoal, adjust pH transferred to neutrality, and double-effect evaporation concentrates the back, and to hand over spraying drying to obtain total sugar content be 1.5 tons in 90% oligose dry powder; The isolated filtrate of nanofiltration system is 207m
3, the reverse osmosis system of handing over reverse osmosis membrane to form is handled, and system pressure is 3.0MPa, and working temperature is 45 ℃, obtains about 180m after treatment
3Pure water can return the molten operation of alkali of dregs of beans.
After adopting technical scheme provided by the invention, the oligose rate of recovery of soybean whey water is greater than 75%, and protein recovery is greater than 85%.Calculate 450 tons in this factory's year production of high purity oligose dry powder at 300 days on working days per year; 390 tons of protein powders; Year is saved water resources 5.4 ten thousand m
3And realized without sewage discharge.
Claims (1)
1, a kind of treatment method of soybean lactalbumin waste water, this method is carried out according to the following steps: (1), ultrafiltration: hand over the ultra-filtration membrane separation system to filter in soybean whey water, hold back albumen and other microorganisms in the soybean whey water, the used film of described ultrafiltration system is that molecular weight cut-off is the inorganic ceramic composite membrane of 10KD, ultra-filtration membrane separation system operating pressure is 0.8～1.0MPa, and working temperature is 55～65 ℃; (2), nanofiltration: above-mentioned ultra-filtration and separation is gone out filtrate pay the filtration of filter membrane separation system, hold back the oligose in the soybean whey water, the used film of described nanofiltration system is the composite nanometer filtering film of 0.8～1.2nm for seeing through the aperture, nanofiltration membrane separation system works pressure is 1.0～3.0MPa, and working temperature is 40～45 ℃; (3), reverse osmosis: the filtrate that above-mentioned nanofiltration separation goes out is handed over the reverse osmosis membrane separation system filtration, remove inorganic salt, monose and amino acids material in the nanofiltration filtrate, reverse osmosis filtrate is pure water just, the recyclable molten operation of dregs of beans alkali that is used for, the used film of described reverse osmosis system is the reverse osmosis membrane of the anti-protein-contamination of anti-high soda acid, reverse osmosis membrane separation system works pressure 2.5～3.2MPa, working temperature is 40～45 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510019238XA CN100348518C (en) | 2005-08-05 | 2005-08-05 | Treatment method of soybean lactalbumin waste water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510019238XA CN100348518C (en) | 2005-08-05 | 2005-08-05 | Treatment method of soybean lactalbumin waste water |
Publications (2)
| Publication Number | Publication Date |
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| CN1752036A CN1752036A (en) | 2006-03-29 |
| CN100348518C true CN100348518C (en) | 2007-11-14 |
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| CNB200510019238XA Expired - Fee Related CN100348518C (en) | 2005-08-05 | 2005-08-05 | Treatment method of soybean lactalbumin waste water |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503469B (en) * | 2009-03-06 | 2011-10-26 | 黄山旅游集团佳龙绿色食品有限公司 | Method for extracting soy protein, oligosaccharide and isoflavone from soybean whey by two-stage two-segment film |
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| CN101712715A (en) * | 2009-12-18 | 2010-05-26 | 周鑫 | Method for decolorizing full water-soluble soybean glycoprotein |
| CN101759251B (en) * | 2010-02-12 | 2014-08-13 | 湖州富优得膜分离科技有限公司 | Special membrane treatment plant soaking solution process for anti-fouling integrated material and device thereof |
| CN102559817A (en) * | 2011-12-31 | 2012-07-11 | 哈尔滨商业大学 | Method for recovering protein from soybean whey wastewater |
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| CN103012580B (en) * | 2012-12-07 | 2014-12-17 | 成都连接流体分离科技有限公司 | Method for recycling of soybean whey wastewater by membrane separation technology |
| FR3001362B1 (en) * | 2013-01-31 | 2015-07-10 | Roquette Freres | PROCESS FOR FRACTIONING PEELE SOLUBLES, FRACTIONS OBTAINED AND THEIR USE |
| CN105271576B (en) * | 2015-11-10 | 2017-11-14 | 中国科学院海洋研究所 | A kind of method of wastewater treatment in agar-agar production |
| CN108342438A (en) * | 2017-01-23 | 2018-07-31 | 临沂格瑞食品有限公司 | A method of recycling active material from dairy wastewater |
| CN107361196B (en) * | 2017-08-11 | 2020-12-15 | 临邑禹王植物蛋白有限公司 | Process for simultaneously producing soybean protein isolate and soybean protein concentrate |
| CN107698051A (en) * | 2017-10-13 | 2018-02-16 | 德清明德水处理科技有限公司 | The method that sausage casing heparin produces utilization of wastewater resource |
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| CN112342259A (en) * | 2020-09-28 | 2021-02-09 | 山东省科学院菏泽分院 | Method for extracting soybean polypeptide from soybean whey wastewater |
| CN112552369A (en) * | 2020-09-28 | 2021-03-26 | 山东省科学院菏泽分院 | Method for extracting soybean protein isolate from soybean whey wastewater |
| CN112573737A (en) * | 2020-12-07 | 2021-03-30 | 东北农业大学 | Method for treating soybean yellow pulp wastewater by using vibrating membrane |
| CN112715742A (en) * | 2020-12-31 | 2021-04-30 | 临沂山松药业有限公司 | High-value recycling method for bean clear water |
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| CN1336333A (en) * | 2001-09-25 | 2002-02-20 | 清华同方股份有限公司 | Membrane separation process of treating soybean processing waste water |
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2005
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04117319A (en) * | 1990-09-07 | 1992-04-17 | J R C Kk | Aqueous liquid composition |
| CN1336333A (en) * | 2001-09-25 | 2002-02-20 | 清华同方股份有限公司 | Membrane separation process of treating soybean processing waste water |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503469B (en) * | 2009-03-06 | 2011-10-26 | 黄山旅游集团佳龙绿色食品有限公司 | Method for extracting soy protein, oligosaccharide and isoflavone from soybean whey by two-stage two-segment film |
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| CN1752036A (en) | 2006-03-29 |
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