CN100339445C - 一种纳米二氧化硅乳液及其制造方法和用途 - Google Patents
一种纳米二氧化硅乳液及其制造方法和用途 Download PDFInfo
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- CN100339445C CN100339445C CNB031099157A CN03109915A CN100339445C CN 100339445 C CN100339445 C CN 100339445C CN B031099157 A CNB031099157 A CN B031099157A CN 03109915 A CN03109915 A CN 03109915A CN 100339445 C CN100339445 C CN 100339445C
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- water
- titanium dioxide
- emulsion
- nanometer titanium
- tensio
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- 239000000839 emulsion Substances 0.000 title claims abstract description 52
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000005543 nano-size silicon particle Substances 0.000 title claims abstract description 32
- 235000012239 silicon dioxide Nutrition 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000013543 active substance Substances 0.000 claims description 34
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- 238000000576 coating method Methods 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 229960001866 silicon dioxide Drugs 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 230000003287 optical effect Effects 0.000 abstract description 3
- 239000000725 suspension Substances 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 108010010803 Gelatin Proteins 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 239000008273 gelatin Substances 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 235000011852 gelatine desserts Nutrition 0.000 abstract 1
- 239000004530 micro-emulsion Substances 0.000 description 8
- 229920001214 Polysorbate 60 Polymers 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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Abstract
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CNB031099157A CN100339445C (zh) | 2003-04-07 | 2003-04-07 | 一种纳米二氧化硅乳液及其制造方法和用途 |
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CNB031099157A CN100339445C (zh) | 2003-04-07 | 2003-04-07 | 一种纳米二氧化硅乳液及其制造方法和用途 |
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CN1536032A CN1536032A (zh) | 2004-10-13 |
CN100339445C true CN100339445C (zh) | 2007-09-26 |
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CNB031099157A Expired - Fee Related CN100339445C (zh) | 2003-04-07 | 2003-04-07 | 一种纳米二氧化硅乳液及其制造方法和用途 |
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Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101058689B (zh) * | 2006-09-05 | 2010-08-11 | 陕西科惠化工有限公司 | 免研磨乳胶漆系列表面改性专用粉及其制备方法 |
DE102007023555A1 (de) * | 2007-05-21 | 2008-11-27 | Siemens Ag | Hydrophobe Oberflächenbeschichtung für elektronische und elektrotechnische Komponenten sowie Verwendungen dazu |
CN101338082A (zh) * | 2007-07-06 | 2009-01-07 | 安集微电子(上海)有限公司 | 改性二氧化硅溶胶及其制备方法和应用 |
CN101565296B (zh) * | 2009-06-08 | 2011-09-14 | 河北理工大学 | 一种制备疏水SiO2-TiO2-ZrO2干凝胶的方法 |
CN101735787A (zh) * | 2009-12-22 | 2010-06-16 | 上海大学 | 一种基于纳米材料的水基油田增注剂及其制备方法 |
CN101914313B (zh) * | 2010-08-13 | 2012-10-31 | 南通纳威数码材料科技有限公司 | 阳离子水性纳米二氧化硅及其制备方法和用途 |
CN103131275A (zh) * | 2012-12-06 | 2013-06-05 | 常州大学 | 一种纳米SiO2改性的氟碳涂料及其制备方法 |
CN103013197B (zh) * | 2012-12-19 | 2014-09-17 | 江苏博斯腾纳米涂层有限公司 | 一种纳米防雾剂的制备方法 |
CN103013198A (zh) * | 2012-12-19 | 2013-04-03 | 江苏博斯腾纳米涂层有限公司 | 一种纳米防雾剂及其制备方法 |
CN103360795A (zh) * | 2013-06-25 | 2013-10-23 | 安徽敬业纳米科技有限公司 | 一种特种橡胶用纳米二氧化硅的改性生产方法 |
CN103436140B (zh) * | 2013-08-23 | 2016-06-01 | 苏州长盛机电有限公司 | 一种铜材用防腐蚀涂料 |
CN103572656B (zh) * | 2013-11-20 | 2016-03-16 | 江南大学 | 包装纸和纸板用疏水剂的制备方法及其应用 |
CN103755304B (zh) * | 2014-01-23 | 2015-04-22 | 北京宇阳泽丽防水材料有限责任公司 | 一种渗透结晶防水剂及其制备方法 |
JP6317472B2 (ja) * | 2014-04-03 | 2018-04-25 | エルジー・ケム・リミテッド | シアネート系樹脂に対する分散性に優れたシリカゾル組成物及びその製造方法 |
CN104693850A (zh) * | 2015-03-04 | 2015-06-10 | 江苏东剑材料科技有限公司 | 一种纳米二氧化硅水溶液的制备方法 |
JP6662601B2 (ja) * | 2015-10-09 | 2020-03-11 | セコ コーポレイション リミテッド | 防曇剤 |
JP6666680B2 (ja) * | 2015-10-09 | 2020-03-18 | セコ コーポレイション リミテッド | 防曇剤 |
CN105419412B (zh) * | 2015-12-17 | 2017-12-26 | 三棵树涂料股份有限公司 | 一种高附着力超疏水罩面漆及其制备方法 |
CN109485051A (zh) * | 2018-11-02 | 2019-03-19 | 中国林业科学研究院林产化学工业研究所 | 一种改性硅溶胶的快速制备方法 |
CN111454591A (zh) * | 2019-01-22 | 2020-07-28 | 北京化工大学 | 一种改性二氧化硅的方法、改性二氧化硅及应用 |
CN110592603B (zh) * | 2019-10-30 | 2021-06-08 | 湖南金裕环保科技有限公司 | 不锈钢表面乳化液、制备方法及其应用 |
CN112226221B (zh) * | 2020-10-19 | 2022-03-01 | 河南大学 | 一种纳米二氧化硅驱油剂及其制备方法和应用 |
CN115975617B (zh) * | 2021-10-15 | 2024-06-14 | 中国石油化工股份有限公司 | 一种高界面张力高界面模量复合乳液及其制备方法和应用 |
CN114195158B (zh) * | 2021-12-20 | 2023-11-17 | 上海大学 | 一种高纯单分散纳米球形二氧化硅粉体的制备方法 |
CN115340102B (zh) * | 2022-07-25 | 2024-03-22 | 中建西部建设建材科学研究院有限公司 | 一种微纳米材料制备方法、微纳米材料及其应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0478433A (ja) * | 1990-07-20 | 1992-03-12 | Matsushita Electric Works Ltd | 無機粉体の表面処理方法 |
EP0585951A2 (en) * | 1992-09-04 | 1994-03-09 | Ajinomoto Co., Inc. | Agent for filler surface treatment in water |
CN1118605A (zh) * | 1993-02-12 | 1996-03-13 | 卡伯特公司 | 用表面活性剂改性的二氧化硅 |
WO1999032554A1 (en) * | 1997-12-22 | 1999-07-01 | J. M. Huber Corporation | Modified mineral filler for thermosets |
-
2003
- 2003-04-07 CN CNB031099157A patent/CN100339445C/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0478433A (ja) * | 1990-07-20 | 1992-03-12 | Matsushita Electric Works Ltd | 無機粉体の表面処理方法 |
EP0585951A2 (en) * | 1992-09-04 | 1994-03-09 | Ajinomoto Co., Inc. | Agent for filler surface treatment in water |
CN1118605A (zh) * | 1993-02-12 | 1996-03-13 | 卡伯特公司 | 用表面活性剂改性的二氧化硅 |
WO1999032554A1 (en) * | 1997-12-22 | 1999-07-01 | J. M. Huber Corporation | Modified mineral filler for thermosets |
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Assignee: Zhejiang Yuda Chemical Industry Co., Ltd. Assignor: Zhang Haolong Contract fulfillment period: 2008.10.6 to 2018.10.5 contract change Contract record no.: 2008330001862 Denomination of invention: Nano silicon dioxide emulsion, its preparation method and application Granted publication date: 20070926 License type: Exclusive license Record date: 20081110 |
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