CH626397A5 - - Google Patents

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Info

Publication number: CH626397A5
Authority: CH; Switzerland
Prior art keywords: detergent; salt; insoluble; phosphoric acid; hydrocarbon
Prior art date: 1976-01-23

Application number

CH77377A

Other languages

German (de)

English (en)

Inventor

Malcolm Nigel Alan Carter

Peter Robert Garrett

Original Assignee

Unilever Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-01-23

Filing date

1977-01-21

Publication date

1981-11-13

1977-01-21 Application filed by Unilever Nv filed Critical Unilever Nv

1981-11-13 Publication of CH626397A5 publication Critical patent/CH626397A5/de

Links

239000003599 detergent Substances 0.000 claims description 123
239000006260 foam Substances 0.000 claims description 64
-1 phosphoric acid ester salt Chemical class 0.000 claims description 37
150000003839 salts Chemical class 0.000 claims description 34
150000002430 hydrocarbons Chemical group 0.000 claims description 28
239000000654 additive Substances 0.000 claims description 27
125000000217 alkyl group Chemical group 0.000 claims description 27
229930195733 hydrocarbon Natural products 0.000 claims description 26
150000001875 compounds Chemical class 0.000 claims description 21
238000000034 method Methods 0.000 claims description 19
239000004215 Carbon black (E152) Substances 0.000 claims description 18
150000003014 phosphoric acid esters Chemical class 0.000 claims description 18
239000007788 liquid Substances 0.000 claims description 17
239000003795 chemical substances by application Substances 0.000 claims description 16
239000002480 mineral oil Substances 0.000 claims description 15
159000000007 calcium salts Chemical group 0.000 claims description 13
235000010446 mineral oil Nutrition 0.000 claims description 13
230000000996 additive effect Effects 0.000 claims description 12
239000000843 powder Substances 0.000 claims description 12
239000007787 solid Substances 0.000 claims description 12
238000002844 melting Methods 0.000 claims description 11
230000008018 melting Effects 0.000 claims description 11
229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
239000008240 homogeneous mixture Substances 0.000 claims description 8
239000011707 mineral Substances 0.000 claims description 8
125000000129 anionic group Chemical group 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 4
239000008187 granular material Substances 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 3
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
229920006395 saturated elastomer Polymers 0.000 claims 1
229930195734 saturated hydrocarbon Natural products 0.000 claims 1
229930195735 unsaturated hydrocarbon Natural products 0.000 claims 1
229960005069 calcium Drugs 0.000 description 37
239000011575 calcium Substances 0.000 description 37
229910052791 calcium Inorganic materials 0.000 description 36
229910019142 PO4 Inorganic materials 0.000 description 33
235000021317 phosphate Nutrition 0.000 description 33
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 32
239000000203 mixture Substances 0.000 description 29
239000010452 phosphate Substances 0.000 description 29
238000005406 washing Methods 0.000 description 27
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 25
239000002518 antifoaming agent Substances 0.000 description 19
239000011734 sodium Substances 0.000 description 15
229910052708 sodium Inorganic materials 0.000 description 15
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 14
239000001993 wax Substances 0.000 description 14
238000005187 foaming Methods 0.000 description 13
235000019271 petrolatum Nutrition 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
238000012360 testing method Methods 0.000 description 11
229910052783 alkali metal Inorganic materials 0.000 description 10
235000011007 phosphoric acid Nutrition 0.000 description 10
239000002002 slurry Substances 0.000 description 9
239000000243 solution Substances 0.000 description 9
239000004115 Sodium Silicate Substances 0.000 description 8
229910000147 aluminium phosphate Inorganic materials 0.000 description 8
239000003921 oil Substances 0.000 description 8
235000019198 oils Nutrition 0.000 description 8
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
239000002585 base Substances 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
239000004615 ingredient Substances 0.000 description 7
239000000463 material Substances 0.000 description 7
229960001922 sodium perborate Drugs 0.000 description 7
235000019832 sodium triphosphate Nutrition 0.000 description 7
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
239000002253 acid Substances 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 6
239000000344 soap Substances 0.000 description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
229910052911 sodium silicate Inorganic materials 0.000 description 6
229910052938 sodium sulfate Inorganic materials 0.000 description 6
235000011152 sodium sulphate Nutrition 0.000 description 6
239000004753 textile Substances 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
239000008233 hard water Substances 0.000 description 5
238000002156 mixing Methods 0.000 description 5
239000012188 paraffin wax Substances 0.000 description 5
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 5
239000008234 soft water Substances 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000001768 carboxy methyl cellulose Substances 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
235000019809 paraffin wax Nutrition 0.000 description 4
239000002245 particle Substances 0.000 description 4
229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
239000005662 Paraffin oil Substances 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000008112 carboxymethyl-cellulose Substances 0.000 description 3
229940105329 carboxymethylcellulose Drugs 0.000 description 3
239000003240 coconut oil Substances 0.000 description 3
235000019864 coconut oil Nutrition 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
230000000694 effects Effects 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
239000004088 foaming agent Substances 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
239000000047 product Substances 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
159000000008 strontium salts Chemical class 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
239000003760 tallow Substances 0.000 description 3
239000012085 test solution Substances 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000003513 alkali Substances 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000010775 animal oil Substances 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
229940077388 benzenesulfonate Drugs 0.000 description 2
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
229910001424 calcium ion Inorganic materials 0.000 description 2
235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
238000000151 deposition Methods 0.000 description 2
JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
238000009472 formulation Methods 0.000 description 2
210000002837 heart atrium Anatomy 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
229940057995 liquid paraffin Drugs 0.000 description 2
239000000155 melt Substances 0.000 description 2
230000003472 neutralizing effect Effects 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
150000003016 phosphoric acids Chemical class 0.000 description 2
230000026731 phosphorylation Effects 0.000 description 2
238000006366 phosphorylation reaction Methods 0.000 description 2
239000011591 potassium Substances 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
238000012545 processing Methods 0.000 description 2
239000000429 sodium aluminium silicate Substances 0.000 description 2
235000012217 sodium aluminium silicate Nutrition 0.000 description 2
235000019351 sodium silicates Nutrition 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
150000003871 sulfonates Chemical class 0.000 description 2
150000004685 tetrahydrates Chemical class 0.000 description 2
229940099259 vaseline Drugs 0.000 description 2
239000008158 vegetable oil Substances 0.000 description 2
235000013311 vegetables Nutrition 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
241000251468 Actinopterygii Species 0.000 description 1
244000144725 Amygdalus communis Species 0.000 description 1
235000011437 Amygdalus communis Nutrition 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
241000283690 Bos taurus Species 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
241001097678 Candelina Species 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
239000004166 Lanolin Substances 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
UTNBYFXEOIUQQJ-UHFFFAOYSA-L P(=O)(OCCCCCCCCCCCCCCCCCC)([O-])[O-].[Sr+2] Chemical compound P(=O)(OCCCCCCCCCCCCCCCCCC)([O-])[O-].[Sr+2] UTNBYFXEOIUQQJ-UHFFFAOYSA-L 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
239000004365 Protease Substances 0.000 description 1
235000019774 Rice Bran oil Nutrition 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
150000008052 alkyl sulfonates Chemical class 0.000 description 1
239000008168 almond oil Substances 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
230000003254 anti-foaming effect Effects 0.000 description 1
238000004380 ashing Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
235000013871 bee wax Nutrition 0.000 description 1
239000012166 beeswax Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229960002713 calcium chloride Drugs 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 1
229940052299 calcium chloride dihydrate Drugs 0.000 description 1
XVCYJJSHYKJNHB-UHFFFAOYSA-L calcium;octadecyl phosphate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCOP([O-])([O-])=O XVCYJJSHYKJNHB-UHFFFAOYSA-L 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000004203 carnauba wax Substances 0.000 description 1
235000013869 carnauba wax Nutrition 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
210000000078 claw Anatomy 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
235000005687 corn oil Nutrition 0.000 description 1
239000002285 corn oil Substances 0.000 description 1
235000012343 cottonseed oil Nutrition 0.000 description 1
239000002385 cottonseed oil Substances 0.000 description 1
230000008021 deposition Effects 0.000 description 1
YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
238000004851 dishwashing Methods 0.000 description 1
BNVZBQVIMPLFNA-UHFFFAOYSA-L disodium;2-(carboxymethoxy)butanedioate Chemical compound [Na+].[Na+].OC(=O)COC(C([O-])=O)CC([O-])=O BNVZBQVIMPLFNA-UHFFFAOYSA-L 0.000 description 1
NPCCEUVRYRJOLM-UHFFFAOYSA-L disodium;2-(carboxymethoxy)propanedioate Chemical compound [Na+].[Na+].OC(=O)COC(C([O-])=O)C([O-])=O NPCCEUVRYRJOLM-UHFFFAOYSA-L 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
239000003623 enhancer Substances 0.000 description 1
229940088598 enzyme Drugs 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000002979 fabric softener Substances 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
125000005456 glyceride group Chemical group 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
229910052900 illite Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229940045996 isethionic acid Drugs 0.000 description 1
235000019388 lanolin Nutrition 0.000 description 1
229940039717 lanolin Drugs 0.000 description 1
238000010412 laundry washing Methods 0.000 description 1
210000004185 liver Anatomy 0.000 description 1
150000004668 long chain fatty acids Chemical class 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000012170 montan wax Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
150000004028 organic sulfates Chemical class 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
235000015927 pasta Nutrition 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
239000012169 petroleum derived wax Substances 0.000 description 1
235000019381 petroleum wax Nutrition 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
230000000865 phosphorylative effect Effects 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000137 polyphosphoric acid Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
239000002243 precursor Substances 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
239000008165 rice bran oil Substances 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
239000008159 sesame oil Substances 0.000 description 1
235000011803 sesame oil Nutrition 0.000 description 1
229910021647 smectite Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000007655 standard test method Methods 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
229940117986 sulfobetaine Drugs 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
230000001629 suppression Effects 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
238000010998 test method Methods 0.000 description 1
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000010497 wheat germ oil Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CH77377A 1976-01-23 1977-01-21 CH626397A5 (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB2670/76A GB1571502A (en)	1976-01-23	1976-01-23	Detergent compositions

Publications (1)

Publication Number	Publication Date
CH626397A5 true CH626397A5 (fr)	1981-11-13

Family

ID=9743706

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH77377A CH626397A5 (fr)	1976-01-23	1977-01-21

Country Status (16)

Country	Link
US (1)	US4362642A (fr)
JP (1)	JPS5291007A (fr)
AT (1)	AT365637B (fr)
BE (1)	BE850458A (fr)
BR (1)	BR7700399A (fr)
CA (1)	CA1098408A (fr)
CH (1)	CH626397A5 (fr)
DE (1)	DE2701663C3 (fr)
FI (1)	FI63440C (fr)
FR (1)	FR2338990A1 (fr)
GB (1)	GB1571502A (fr)
IT (1)	IT1082456B (fr)
NL (1)	NL185853C (fr)
NO (1)	NO146401C (fr)
SE (1)	SE423636B (fr)
ZA (1)	ZA77343B (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5794969A (en) *	1980-12-04	1982-06-12	Oki Electric Ind Co Ltd	Card locking device
NZ199235A (en) *	1980-12-17	1985-02-28	Unilever Plc	Controlled-sudsing detergent compositions
AU547364B2 (en) *	1981-09-16	1985-10-17	Unilever Plc	Antifoam composition
DE3144470A1 (de) *	1981-11-09	1983-05-19	Unilever N.V., 3000 Rotterdam	Schaumkontrollierte waschmittel
JPS5884899A (ja) *	1981-11-17	1983-05-21	住友化学工業株式会社	洗剤組成物
US4591502A (en) *	1982-11-24	1986-05-27	Schlossman Mitchell L	Compressing aid for cosmetic powders
US4601844A (en) *	1984-08-31	1986-07-22	The Procter & Gamble Company	Granular automatic dishwasher detergent with alkyl phosphate and calcium ion source
GB8521956D0 (en) *	1985-09-04	1985-10-09	Unilever Plc	Antifoam ingredient
US4793942A (en) *	1987-01-08	1988-12-27	Ecolab Inc.	Detersive systems with a dispersed aqueous-organic softening agent for hardness removal
GB8716899D0 (en) *	1987-07-17	1987-08-26	Unilever Plc	Detergent compositions
US4971714A (en) *	1988-11-30	1990-11-20	Ecolab Inc.	Detersive system with an improved hardness ion complexing agent
US4911856A (en) *	1988-11-30	1990-03-27	Ecolab Inc.	Low acid, soluble salt containing aqueous-organic softening agents for detersive systems
DE19850983A1 (de) *	1998-11-05	2000-05-11	Henkel Kgaa	Wasch- und Reinigungsmittelformkörper mit Entschäumergranulat

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE596798A (fr)	1959-11-05
NL302478A (fr)	1962-12-24
CA789509A (en) *	1964-05-27	1968-07-09	R. Schmolka Irving	Low foaming detergent
US3523902A (en) *	1965-04-07	1970-08-11	Wyandotte Chemicals Corp	Controlled suds detergent
CA810158A (en) *	1966-01-04	1969-04-08	D. Hathaway Harley	Defoaming agent
NO121968C (fr)	1966-06-23	1977-06-13	Mo Och Domsjoe Ab
US3562168A (en) *	1966-09-02	1971-02-09	Stamford Chemical Ind Inc	Alkaline earth and amine salts of phosphate ester surfactants in dry cleaning compositions
US3770855A (en) *	1967-12-15	1973-11-06	Witco Chemical Corp	Process for producing phosphate ester surface active compositions
CA936782A (en) *	1970-12-18	1973-11-13	M. Kaneko Thomas	Biodegradable detergent for automatic car wash systems
FR2193869B1 (fr) *	1972-07-25	1977-04-01	Colgate Palmolive Co

1976
- 1976-01-23 GB GB2670/76A patent/GB1571502A/en not_active Expired
1977
- 1977-01-10 FI FI770058A patent/FI63440C/fi not_active IP Right Cessation
- 1977-01-17 DE DE2701663A patent/DE2701663C3/de not_active Expired
- 1977-01-17 BE BE174139A patent/BE850458A/fr not_active IP Right Cessation
- 1977-01-20 ZA ZA00770343A patent/ZA77343B/xx unknown
- 1977-01-20 AT AT0033077A patent/AT365637B/de not_active IP Right Cessation
- 1977-01-20 NO NO770180A patent/NO146401C/no unknown
- 1977-01-21 IT IT67139/77A patent/IT1082456B/it active
- 1977-01-21 CA CA270,233A patent/CA1098408A/fr not_active Expired
- 1977-01-21 JP JP572977A patent/JPS5291007A/ja active Granted
- 1977-01-21 BR BR7700399A patent/BR7700399A/pt unknown
- 1977-01-21 CH CH77377A patent/CH626397A5/de not_active IP Right Cessation
- 1977-01-21 SE SE7700674A patent/SE423636B/xx not_active IP Right Cessation
- 1977-01-21 FR FR7701782A patent/FR2338990A1/fr active Granted
- 1977-01-24 NL NLAANVRAGE7700713,A patent/NL185853C/xx not_active IP Right Cessation
1981
- 1981-07-07 US US06/280,973 patent/US4362642A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
SE7700674L (sv)	1977-07-24
US4362642A (en)	1982-12-07
NL185853C (nl)	1990-08-01
AT365637B (de)	1982-02-10
CA1098408A (fr)	1981-03-31
ATA33077A (de)	1981-06-15
FI770058A (fr)	1977-07-24
SE423636B (sv)	1982-05-17
NO146401C (no)	1982-09-22
FI63440C (fi)	1983-06-10
NO146401B (no)	1982-06-14
DE2701663B2 (fr)	1980-05-29
BE850458A (fr)	1977-07-18
NL7700713A (nl)	1977-07-26
JPS5646519B2 (fr)	1981-11-04
DE2701663C3 (de)	1981-02-05
DE2701663A1 (de)	1977-07-28
FR2338990B1 (fr)	1980-07-18
IT1082456B (it)	1985-05-21
JPS5291007A (en)	1977-08-01
NL185853B (nl)	1990-03-01
NO770180L (no)	1977-07-26
FR2338990A1 (fr)	1977-08-19
FI63440B (fi)	1983-02-28
ZA77343B (en)	1978-08-30
BR7700399A (pt)	1977-09-20
GB1571502A (en)	1980-07-16

Publication	Publication Date	Title
DE2857300C2 (fr)	1989-01-05
DE2820990C2 (fr)	1987-10-15
DE2533758C2 (de)	1984-03-01	Waschmittel
DE2525778C2 (fr)	1991-05-29
DE2342461B2 (de)	1977-08-11	Reinigungsmittelzusammensetzungen
DE2903058C2 (fr)	1987-09-10
DE2637890C2 (de)	1987-01-22	Reinigungsmittel-Zusammensetzung
DE2701664C2 (fr)	1991-03-07
DE2240309A1 (de)	1973-03-01	Waschmittel
DE2701663C3 (de)	1981-02-05	Waschmittel und Verfahren zu ihrer Herstellung
DE2439058A1 (de)	1975-02-27	Reinigungsmittelzusammensetzungen
DE69225677T2 (de)	1998-10-15	Flüssige Reinigungsmittel
DE69032814T2 (de)	1999-04-29	Reinigungsverstärkeradditiv und dies enthaltendes Detergentsystem
DE2025238B2 (de)	1974-01-17	Pulverförmige Wasch- und Reinigungsmittel
DE2645881A1 (de)	1977-04-21	Waschmittel und ihre herstellung
DE2239646C2 (de)	1984-12-13	Waschmittel
DE2544242A1 (de)	1976-04-08	Verfahren zum waschen von textilien, sowie mittel zur durchfuehrung des verfahrens
DE2657517C2 (fr)	1987-12-17
DE1936843B2 (de)	1978-05-11	Schwach bis mäßig schäumendes Waschmittel
EP0079105B1 (fr)	1985-06-19	Agents de lavage à mousse contrôlée
DE2722988C2 (de)	1985-11-21	Flüssige Waschmittel
DE2847826A1 (de)	1979-05-17	Waschmittel
DE2305074C2 (de)	1983-12-29	Waschmittel mit reduziertem Phosphatgehalt
DE2213156A1 (de)	1972-09-28	Waschmittel
DE2539071A1 (de)	1976-04-08	Verfahren zum waschen von textilien sowie mittel zur durchfuehrung des verfahrens

Legal Events

Date	Code	Title	Description
1997-02-14	PL	Patent ceased