CH431272A - Photographic layer for the silver dye bleaching process - Google Patents
Photographic layer for the silver dye bleaching processInfo
- Publication number
- CH431272A CH431272A CH240464A CH240464A CH431272A CH 431272 A CH431272 A CH 431272A CH 240464 A CH240464 A CH 240464A CH 240464 A CH240464 A CH 240464A CH 431272 A CH431272 A CH 431272A
- Authority
- CH
- Switzerland
- Prior art keywords
- azo
- formula
- methoxy
- groups
- och3
- Prior art date
Links
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title 1
- 238000004061 bleaching Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910052709 silver Inorganic materials 0.000 title 1
- 239000004332 silver Substances 0.000 title 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 5
- -1 amino-azo Chemical group 0.000 abstract 3
- 239000000987 azo dye Substances 0.000 abstract 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000005749 Copper compound Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 abstract 1
- 150000001880 copper compounds Chemical class 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 230000001335 demethylating effect Effects 0.000 abstract 1
- 239000012954 diazonium Substances 0.000 abstract 1
- 150000001989 diazonium salts Chemical class 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/28—Disazo or polyazo compounds containing copper
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B27/00—Preparations in which the azo group is formed in any way other than by diazotising and coupling, e.g. oxidation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/08—Preparation of azo dyes from other azo compounds by reduction
- C09B43/085—Preparation of azo dyes from other azo compounds by reduction by reacting nitro azo dyes with amine or amino azo dye with nitro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/08—Preparation of azo dyes from other azo compounds by reduction
- C09B43/10—Preparation of azo dyes from other azo compounds by reduction with formation of a new azo or an azoxy bridge
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/28—Silver dye bleach processes; Materials therefor; Preparing or processing such materials
- G03C7/29—Azo dyes therefor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paper (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
Dyes having the general formula <FORM:1002345/C4-C5/1> wherein R1 and R2 are benzine residues having the azo and -O-Cu-O- links in ortho position, the azo and azoxy groups being linked to R2 in para position, are prepared by condensing 1 mol. of 4,41-dinitro-stilbene-2,21-disulphonic acid with two mols. of an amino-azo dye of the formula HO3S-R1(OH)-N = N-R2(OCH3)-NH2 and then demethylating the methoxy groups and metallizing with a copper compound. The amino-azo dye is itself prepared by coupling the diazonium salt of an o-hydroxyamine of the formula HO3S-R1(OH)-NH2 with an amine of the formula H-R2(OCH3)-NH2. The benzene residue R2 may have additional substituents in para position to the methoxy group (i.e. to the -O-Cu-O-linkage in the final dye) such as methyl, methoxy or ethoxy substituents. The benzene residue R1 also may have additional substituents such as chloro, methyl, ethyl, nitro or further sulphonic acid groups.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR4899A FR87423E (en) | 1964-02-27 | 1965-02-09 | Photographic layers for the bleaching process of colored silver images |
GB585465A GB1042300A (en) | 1964-02-27 | 1965-02-10 | Photographic layers for the silver dyestuff bleaching process |
BE660288D BE660288A (en) | 1964-02-27 | 1965-02-26 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH270060A CH386247A (en) | 1960-03-09 | 1960-03-09 | Photographic layer for the silver dye bleaching process |
CH1442162A CH415296A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
CH1442062A CH415295A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
Publications (1)
Publication Number | Publication Date |
---|---|
CH431272A true CH431272A (en) | 1967-02-28 |
Family
ID=27173858
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH1442062A CH415295A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
CH1442162A CH415296A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
CH240464A CH431272A (en) | 1960-03-09 | 1964-02-27 | Photographic layer for the silver dye bleaching process |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH1442062A CH415295A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
CH1442162A CH415296A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
Country Status (6)
Country | Link |
---|---|
US (1) | US3211556A (en) |
BE (2) | BE640911R (en) |
CH (3) | CH415295A (en) |
DE (2) | DE1174613B (en) |
FR (3) | FR1290363A (en) |
GB (3) | GB923265A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0043792A2 (en) * | 1980-06-03 | 1982-01-13 | Ciba-Geigy Ag | Dyeing paper |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL291335A (en) * | 1962-04-10 | |||
CH433979A (en) * | 1964-06-02 | 1967-04-15 | Ciba Geigy | Photographic material for the silver dye bleaching process |
US4235957A (en) * | 1979-01-25 | 1980-11-25 | Eastman Kodak Company | Thermal silver-dye bleach element and process |
DE2948022A1 (en) * | 1979-11-29 | 1981-06-04 | Bayer Ag, 5090 Leverkusen | POLYAZO DYES, METHOD FOR THEIR PRODUCTION AND THEIR USE FOR COLORING VEGETABILIC FIBER MATERIALS AND LEATHER |
CH654588A5 (en) * | 1981-12-31 | 1986-02-28 | Sandoz Ag | METALIZED STYLENE AZO COMPOUNDS, METHOD FOR PRODUCING AND USE. |
US20090246529A1 (en) | 2008-03-28 | 2009-10-01 | Conopco, Inc., D/B/A Unilever | Particle with Bipolar Topospecific Characteristics and Process for Preparation Thereof |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2987513A (en) * | 1958-01-31 | 1961-06-06 | Bayer Ag | Azo dyestuffs and process for their manufacture |
US3148062A (en) * | 1959-04-06 | 1964-09-08 | Eastman Kodak Co | Photographic elements and processes using splittable couplers |
-
1961
- 1961-03-07 FR FR854756A patent/FR1290363A/en not_active Expired
- 1961-03-09 GB GB8681/61A patent/GB923265A/en not_active Expired
-
1962
- 1962-12-07 CH CH1442062A patent/CH415295A/en unknown
- 1962-12-07 CH CH1442162A patent/CH415296A/en unknown
-
1963
- 1963-10-09 GB GB39871/63A patent/GB999996A/en not_active Expired
- 1963-10-09 GB GB39870/63A patent/GB1002345A/en not_active Expired
- 1963-11-25 FR FR954918A patent/FR84793E/en not_active Expired
- 1963-11-25 FR FR954919A patent/FR84794E/en not_active Expired
- 1963-12-06 DE DEC31610A patent/DE1174613B/en active Pending
- 1963-12-06 BE BE640911A patent/BE640911R/fr active
- 1963-12-06 DE DEC31611A patent/DE1173337B/en active Pending
- 1963-12-06 BE BE640912A patent/BE640912R/fr active
-
1964
- 1964-02-27 CH CH240464A patent/CH431272A/en unknown
- 1964-03-13 US US351839A patent/US3211556A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0043792A2 (en) * | 1980-06-03 | 1982-01-13 | Ciba-Geigy Ag | Dyeing paper |
EP0043792A3 (en) * | 1980-06-03 | 1982-01-20 | Ciba-Geigy Ag | A method of dyeing paper |
Also Published As
Publication number | Publication date |
---|---|
DE1173337B (en) | 1964-07-02 |
GB1002345A (en) | 1965-08-25 |
FR84793E (en) | 1965-04-16 |
DE1174613B (en) | 1964-07-23 |
GB923265A (en) | 1963-04-10 |
FR1290363A (en) | 1962-04-13 |
BE640912R (en) | 1964-06-08 |
CH415295A (en) | 1966-06-15 |
BE640911R (en) | 1964-06-08 |
US3211556A (en) | 1965-10-12 |
FR84794E (en) | 1965-04-16 |
CH415296A (en) | 1966-06-15 |
GB999996A (en) | 1965-07-28 |
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