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CH249795A - Process for the preparation of a substantive azo dye. - Google Patents

Process for the preparation of a substantive azo dye.

Info

Publication number
CH249795A
CH249795A CH249795DA CH249795A CH 249795 A CH249795 A CH 249795A CH 249795D A CH249795D A CH 249795DA CH 249795 A CH249795 A CH 249795A
Authority
CH
Switzerland
Prior art keywords
azo dye
oxy
weight
parts
acid
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellschaft Ciba
Original Assignee
Ciba Geigy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy filed Critical Ciba Geigy
Publication of CH249795A publication Critical patent/CH249795A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/14—Monoazo compounds
    • C09B45/18—Monoazo compounds containing copper
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B33/00—Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
    • C09B33/02—Disazo dyes
    • C09B33/08—Disazo dyes in which the coupling component is a hydroxy-amino compound
    • C09B33/10—Disazo dyes in which the coupling component is a hydroxy-amino compound in which the coupling component is an amino naphthol
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B43/00—Preparation of azo dyes from other azo compounds
    • C09B43/12—Preparation of azo dyes from other azo compounds by acylation of amino groups
    • C09B43/136—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents
    • C09B43/16—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents linking amino-azo or cyanuric acid residues

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Paper (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Description

  

  <B>Zusatzpatent</B> zum Hauptpatent Nr. 245067.    Verfahren zur Herstellung eines     substantiven        Azofarbstoffes.       Gegenstand des vorliegenden Zusatz,  patentes ist ein     Verfahren    zur     Herstellung     eines     substantiven        Azofarbstoffes,        dadurch     gekennzeichnet, dass man .das     diazotierte        CTe-          mis6h    aus.

   je 1     Möl        1-Oxy-2'-aminobenizol-4-          carbo@nsäure-p'henylamid    und     1-Oxy-2-amino-          b,enzol-6=chlor-4-sulfonsäure    mit 1     Mol    des  symmetrischen     Harnstoffes,    aus     2-Amino-5,

  -          oxynaphtha!lin-7-sulfousäure    in     afkalisidhem          Medium    vereinigt und den neuen     Fambatoff     durch Behandeln     mit        kupferabgebenden    Mit  teln in eine     komplexe        Kupferverbindung          überführt.    Diese färbt     Baumwolle    in echten       rotvimletten    Tönen.  



  <I>Beispiel:</I>       2'2,8        Gewichtsteile        1-Oxy-2-aminobenzol-          4-üarbonsäurephenyl.amid    und     2'3,3        Gewichts-          teile        1-Oxy-        2-aminob@enizol-@6i-ühI;or-4-:

  su-Ifon-          säure    werden     unter    Zusatz von 14     Gewichts-          teilen        Natriumnitrit    und     b6    Gewichtsteilen  konzentrierter     Salzsäure    bei     0,         diazoti@ert    und  die     Diaizoverbindung    mit     5'0,4        Gewiehtsteilen     des symmetrischen Harnstoffes aus     2@Amino-          5-oxyna]yhthalin-7-su'lfonsäure,

      die als     Na-          triuam.alz    unter Zusatz von     20'0        Gewichtstei-          len    20 %     i:gem        Calciumhydroxyd:    in 2000     Ge-          wichtsteilen    Wasser     ;

  gelöst    wurden,     vereinigt.       Nach 4 Stunden wird der     gebildete        Farbstoff          durch    Zusatz von     Salzsäure        abgeszhieden          und        filtriert.        Der    Filterrückstand wird in     be-          kannter    Weise     durdh        Behandeln    mit     einer     Lösung von 5'0     Gewic#tsteilen        kristalfsier-          tem    Kupfersulfat in 200  <RTI  

   ID="0001.0080">   Gewichtsteilen     25 %     ig-em    Ammoniak in 2000     Gewiohtsteilen     Wasser ei     3:5-40     in seine     Kupferverbin-          dun!ö        überb    führt. Die gebildete Kupferver  bindung fällt     aus,    wird     filtriert    und getrock  net. Der neue Farbstoff bildet ein     dunkles     Pulver, das Baumwolle in     eohten    rotvioletten  Tönen färbt.



  <B> Additional patent </B> to main patent no. 245067. Process for the production of a substantive azo dye. The subject of the present addendum, patent is a process for the production of a substantive azo dye, characterized in that one .diazotized CTemis6h from.

   1 mol each of 1-oxy-2'-aminobenizole-4-carbonic acid-p'henylamide and 1-oxy-2-amino-b, enzene-6 = chloro-4-sulfonic acid with 1 mol of the symmetrical urea, from 2 -Amino-5,

  - Oxynaphtha! lin-7-sulfous acid combined in afkalisidhem medium and the new Fambatoff converted into a complex copper compound by treatment with copper-releasing agents. This dyes cotton in real red-purple tones.



  <I> Example: </I> 2'2.8 parts by weight of 1-oxy-2-aminobenzene-4-carboxylic acid phenyl.amide and 2'3.3 parts by weight of 1-oxy-2-aminob @ enizol- @ 6i- ühI; or-4-:

  su-Ifonic acid with the addition of 14 parts by weight of sodium nitrite and b6 parts by weight of concentrated hydrochloric acid are diazotized at 0, and the diaizo compound with 5'0.4 parts by weight of the symmetrical urea is made from 2 @ amino-5-oxyna] ythalene-7 -sulfonic acid,

      that as sodium salt with the addition of 20.0 parts by weight of 20% i: according to calcium hydroxide: in 2000 parts by weight of water;

  were dissolved, combined. After 4 hours, the dye formed is separated off by adding hydrochloric acid and filtered. The filter residue is treated in a known manner by treating with a solution of 5 parts by weight of crystallized copper sulfate in 200 <RTIgt;

   ID = "0001.0080"> parts by weight of 25% ammonia in 2000 parts by weight of water ei 3: 5-40 into its copper compound! The formed copper compound precipitates, is filtered and net getrock. The new dye forms a dark powder that dyes cotton in similar red-violet tones.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines sübstan- tiven Azofarbstoffes, dadurdh gekennzeich- net, dass man .das,diazotierte Gemisch aus je 1 Mal 1-Oxy-2t-aminobenzol-4--ca@Ao@nsäure- phenyl.amid und 1 - Oxy - 2 - aminobenzol, PATENT CLAIM: Process for the production of a sweetening azo dye, characterized by the fact that the diazotized mixture of 1-oxy-2t-aminobenzene-4-ca @ Ao @ n-acid-phenyl.amide and 1 - Oxy - 2 - aminobenzene, - 6- chlor-4-sülfonoäure mit 1 Mäl des symmetri- sdhen Harnstoffes aus 2'-Amino-5-oxyn:aph- thalin-7 sulfonsäure in alkalischem Medium vereinigt und den neuen Farbstoff durch Be handeln mit 'kupferabgebeeden Mitteln in eine komplexe Kupferverbindung überführt. - 6-chloro-4-sulphonic acid with 1 times the symmetrical urea from 2'-amino-5-oxyn: aphthalin-7-sulfonic acid combined in an alkaline medium and the new dye by treatment with 'copper-depleted agents into a complex Copper compound transferred. Diese färbt Baumwolle in echten rotvioletten Tönen. This dyes cotton in real red-violet tones.
CH249795D 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye. CH249795A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH245067T 1946-01-18

Publications (1)

Publication Number Publication Date
CH249795A true CH249795A (en) 1947-07-15

Family

ID=4464679

Family Applications (14)

Application Number Title Priority Date Filing Date
CH249787D CH249787A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249792D CH249792A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249795D CH249795A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249790D CH249790A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249785D CH249785A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249786D CH249786A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249794D CH249794A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249793D CH249793A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249788D CH249788A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249789D CH249789A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH245067D CH245067A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249791D CH249791A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH252072D CH252072A (en) 1946-01-18 1946-01-18 Process for the preparation of a substantive azo dye.
CH269047D CH269047A (en) 1946-01-18 1946-01-18 Process for the preparation of a substantive azo dye.

Family Applications Before (2)

Application Number Title Priority Date Filing Date
CH249787D CH249787A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249792D CH249792A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.

Family Applications After (11)

Application Number Title Priority Date Filing Date
CH249790D CH249790A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249785D CH249785A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249786D CH249786A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249794D CH249794A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249793D CH249793A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249788D CH249788A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249789D CH249789A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH245067D CH245067A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH249791D CH249791A (en) 1946-01-18 1945-02-20 Process for the preparation of a substantive azo dye.
CH252072D CH252072A (en) 1946-01-18 1946-01-18 Process for the preparation of a substantive azo dye.
CH269047D CH269047A (en) 1946-01-18 1946-01-18 Process for the preparation of a substantive azo dye.

Country Status (1)

Country Link
CH (14) CH249787A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3320972A1 (en) * 1982-06-19 1983-12-22 Sandoz-Patent-GmbH, 7850 Lörrach Metal-containing disazo compounds, process for preparation and process for dyeing or printing

Also Published As

Publication number Publication date
CH249788A (en) 1947-07-15
CH249792A (en) 1947-07-15
CH249791A (en) 1947-07-15
CH249793A (en) 1947-07-15
CH249789A (en) 1947-07-15
CH249790A (en) 1947-07-15
CH249786A (en) 1947-07-15
CH249794A (en) 1947-07-15
CH269047A (en) 1950-06-15
CH245067A (en) 1946-10-31
CH249787A (en) 1947-07-15
CH249785A (en) 1947-07-15
CH252072A (en) 1947-11-30

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