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CH234322A - Process for the manufacture of cellulosic fiber cement products. - Google Patents

Process for the manufacture of cellulosic fiber cement products.

Info

Publication number
CH234322A
CH234322A CH234322DA CH234322A CH 234322 A CH234322 A CH 234322A CH 234322D A CH234322D A CH 234322DA CH 234322 A CH234322 A CH 234322A
Authority
CH
Switzerland
Prior art keywords
cement products
cellulose
fiber cement
manufacture
cellulosic fiber
Prior art date
Application number
Other languages
German (de)
Inventor
Hatschek Eternit-Werke Ludwig
Original Assignee
Eternit Werke Hatschek L
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eternit Werke Hatschek L filed Critical Eternit Werke Hatschek L
Publication of CH234322A publication Critical patent/CH234322A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Description

  

  Verfahren zum Herstellen von     zellulosefaserhaltigen        Faserzementerzeugnissen.       Die Erfindung betrifft ein Verfahren  zum Herstellen von     Faserzementerzeugnissen     unter Verwendung von     Zellulosefasern.     



  Die bekannten, unter Verwendung von       Zellulosefasern,    wie Holzschliff, Papierzellu  lose oder dergleichen     hergestellten    Faser  zementerzeugnisse besitzen gegenüber     Asbest-          zementerzeugnvssen        geringere    F     estigkeits-          und        Dichtigkeitseigenschaften,    und zwar  auch dann, wenn die     Zellulosefasern    einer  chemischen oder einer physikalisch wirken  den     Vorbehandlung    unterworfen werden, die  in der sogenannten     Mineralisierung    der Faser  mit Kalkhydrat, Wasserglas,

       Calciumchlorid     oder dergleichen     bezw.    in dem Abschluss der  Fasern gegen äussere     Einwirkung    durch  Überziehen der Fasern mit einer undurchläs  sigen Haut oder durch Imprägnieren mit  wasserabweichenden Stoffen, wie Paraffin,  besteht.  



  Die Erklärung der Zusammenhänge war  und ist nicht einheitlich. Man glaubte ent  weder, dass die Faser im feuchten Beton         quillt,    oder vom Kalk des Zementes geschä  digt wird, oder beides eintritt, oder der Ze  ment von der Faser durch Abgabe schäd  licher, z. B. kolloidaler Stoffe, beeinflusst  wird. Welche dieser Erklärungen die rich  tige ist, liess sich um so schwerer sagen, als  jede mit jeder der oben angeführten Massnah  men in Einklang zu     bringen    war.  



  Die     Erfindung    beruht auf der Erkennt  nis, dass die unbefriedigende Festigkeit und  Dichtigkeit unter Verwendung von Zellulose  fasern hergestellter     Faserzementerzeugnisse     darauf beruht, dass die Zellulose die Zement  erhärtung störende, lösliche Bestandteile ent  hält, insbesondere     Lignin    und wechselnde  Mengen von     Polysacchariden,    nämlich     Hemi-          zellulosen    und     Pentosane.    Eingehende Unter  suchungen haben     ergeben,    dass die     Festigkei-          ten    eines     Fas,

  arzementes    um so     besster        sind,    je  reiner die Faser ist, insbesondere je geringer  der Gehalt derselben nicht nur an     Lignin,          sondern    auch an     Ilemizellulosen    und     Pento-          sanen    ist.

   Reine     Alphazellulöse    ergibt in Mi-           schung        mit        Portlandzement        Faserzementplat-          ten,    die hinsichtlich ihrer Festigkeit und  ihres sonstigen Verhaltens den     Asbestzement-          platten    erheblich näher kommen als die bis  her bekannten, unter Verwendung von     Zellu-          losefasern    hergestellten     Faserzementpla,tten.     



  Die     Erfindung    sieht daher bei der Her  stellung von     zellulosefaserhaltigen    Faser  zementerzeugnissen die Verwendung einer       Zellulose    vor, die vor ihrem Vermischen mit.  dem Zement gereinigt, insbesondere von     Li-          gnin,        Hemizellulosen    und     Pentosanen    weit  gehend befreit sind.  



  Bei Anwendung möglichst reiner Alpha  zellulose kommen die bisher zur     Anwendung     gebrachten chemischen und physikalisch wir  kenden     Vorbehandlungen    der Faser nicht nur  in Wegfall, sondern es wird auch eine Wir  kung erzielt, wie sie mit diesen     Vorbehand-          lungen    niemals erreicht werden konnte.

   Es  ist gleichgültig, auf welchem Wege die       Alphazellulose    erzeugt wird, ob durch saure    oder alkalische Behandlung der     Zellfaser    und  durch welche immer geartete Nachbehand  lung.     \Vesentlich    ist nur,     dass    die Zellulose  einer auf Entfernung der     Hemizellulosen,    der       Pentosane    und des     Lignins    hinzielenden, be  sonderen Behandlung unterworfen wird.



  Process for the manufacture of cellulosic fiber cement products. The invention relates to a method for producing fiber cement products using cellulose fibers.



  The known fiber cement products made using cellulose fibers, such as wood pulp, paper cellulose or the like, have lower strength and tightness properties than asbestos cement products, even if the cellulose fibers are subjected to a chemical or a physical pretreatment in the so-called mineralization of the fiber with hydrated lime, water glass,

       Calcium chloride or the like BEZW. in the termination of the fibers against external influences by covering the fibers with an impermeable skin or by impregnating them with water-repellent substances such as paraffin.



  The explanation of the connections was and is not uniform. It was believed ent neither that the fiber swells in the wet concrete, or is damaged by the lime of the cement, or both occurs, or the Ze ment from the fiber by releasing harmful Licher, z. B. colloidal substances is influenced. It is all the more difficult to say which of these explanations is the right one, as each one could be reconciled with each of the above measures.



  The invention is based on the knowledge that the unsatisfactory strength and tightness of fiber cement products produced using cellulose fibers is based on the fact that the cellulose contains soluble components which interfere with cement hardening, in particular lignin and varying amounts of polysaccharides, namely hemicelluloses and Pentosans. In-depth studies have shown that the strength of a bevel,

  The purer the fiber, in particular the lower its content not only of lignin but also of ilemicelluloses and pentosans, the better.

   Pure alpha cellulose, when mixed with Portland cement, results in fiber cement panels which, in terms of their strength and other behavior, come considerably closer to asbestos cement panels than the previously known fiber cement panels made using cellulose fibers.



  The invention therefore provides cement products in the Her position of cellulosic fiber-containing fiber before the use of a cellulose, which prior to their mixing with. the cement are cleaned, in particular freed from lignin, hemicelluloses and pentosans.



  When using alpha cellulose that is as pure as possible, the chemical and physically effective pre-treatments of the fibers that have been used up to now are not only eliminated, but an effect is also achieved that could never be achieved with these pre-treatments.

   It does not matter in which way the alpha cellulose is produced, whether by acidic or alkaline treatment of the cell fibers and by whatever kind of post-treatment. It is only essential that the cellulose is subjected to a special treatment aimed at removing hemicelluloses, pentosans and lignin.

 

Claims (1)

PATENTANSPRUCH: Verfahren zum Herstellen von zellulose- faserhaltigen Faserzementerzeugnissen, ge kennzeichnet durch die Verwendung einer Zellulose, die vor ihrem Vermischen mit dem Zement .gereinigt, insbesondere von Lignin, Hemizellulosen und Pentosanen weitgehend befreit worden ist. UNTERANSPRUCH: Verfahren nach dem Patentanspruch, ge kennzeichnet durch die Verwendung von Alphazellulose. PATENT CLAIM: Process for the production of cellulose fiber-containing fiber cement products, characterized by the use of a cellulose which, before being mixed with the cement, has been cleaned, in particular freed from lignin, hemicelluloses and pentosans. SUBClaim: Method according to the patent claim, characterized by the use of alpha cellulose.
CH234322D 1942-06-17 1943-05-17 Process for the manufacture of cellulosic fiber cement products. CH234322A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE234322X 1942-06-17

Publications (1)

Publication Number Publication Date
CH234322A true CH234322A (en) 1944-09-30

Family

ID=5890851

Family Applications (1)

Application Number Title Priority Date Filing Date
CH234322D CH234322A (en) 1942-06-17 1943-05-17 Process for the manufacture of cellulosic fiber cement products.

Country Status (1)

Country Link
CH (1) CH234322A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999006337A1 (en) * 1997-07-30 1999-02-11 Construction Research 2000 Ltd. Composite materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999006337A1 (en) * 1997-07-30 1999-02-11 Construction Research 2000 Ltd. Composite materials

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