CH234322A - Process for the manufacture of cellulosic fiber cement products. - Google Patents
Process for the manufacture of cellulosic fiber cement products.Info
- Publication number
- CH234322A CH234322A CH234322DA CH234322A CH 234322 A CH234322 A CH 234322A CH 234322D A CH234322D A CH 234322DA CH 234322 A CH234322 A CH 234322A
- Authority
- CH
- Switzerland
- Prior art keywords
- cement products
- cellulose
- fiber cement
- manufacture
- cellulosic fiber
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/24—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
Verfahren zum Herstellen von zellulosefaserhaltigen Faserzementerzeugnissen. Die Erfindung betrifft ein Verfahren zum Herstellen von Faserzementerzeugnissen unter Verwendung von Zellulosefasern.
Die bekannten, unter Verwendung von Zellulosefasern, wie Holzschliff, Papierzellu lose oder dergleichen hergestellten Faser zementerzeugnisse besitzen gegenüber Asbest- zementerzeugnvssen geringere F estigkeits- und Dichtigkeitseigenschaften, und zwar auch dann, wenn die Zellulosefasern einer chemischen oder einer physikalisch wirken den Vorbehandlung unterworfen werden, die in der sogenannten Mineralisierung der Faser mit Kalkhydrat, Wasserglas,
Calciumchlorid oder dergleichen bezw. in dem Abschluss der Fasern gegen äussere Einwirkung durch Überziehen der Fasern mit einer undurchläs sigen Haut oder durch Imprägnieren mit wasserabweichenden Stoffen, wie Paraffin, besteht.
Die Erklärung der Zusammenhänge war und ist nicht einheitlich. Man glaubte ent weder, dass die Faser im feuchten Beton quillt, oder vom Kalk des Zementes geschä digt wird, oder beides eintritt, oder der Ze ment von der Faser durch Abgabe schäd licher, z. B. kolloidaler Stoffe, beeinflusst wird. Welche dieser Erklärungen die rich tige ist, liess sich um so schwerer sagen, als jede mit jeder der oben angeführten Massnah men in Einklang zu bringen war.
Die Erfindung beruht auf der Erkennt nis, dass die unbefriedigende Festigkeit und Dichtigkeit unter Verwendung von Zellulose fasern hergestellter Faserzementerzeugnisse darauf beruht, dass die Zellulose die Zement erhärtung störende, lösliche Bestandteile ent hält, insbesondere Lignin und wechselnde Mengen von Polysacchariden, nämlich Hemi- zellulosen und Pentosane. Eingehende Unter suchungen haben ergeben, dass die Festigkei- ten eines Fas,
arzementes um so besster sind, je reiner die Faser ist, insbesondere je geringer der Gehalt derselben nicht nur an Lignin, sondern auch an Ilemizellulosen und Pento- sanen ist.
Reine Alphazellulöse ergibt in Mi- schung mit Portlandzement Faserzementplat- ten, die hinsichtlich ihrer Festigkeit und ihres sonstigen Verhaltens den Asbestzement- platten erheblich näher kommen als die bis her bekannten, unter Verwendung von Zellu- losefasern hergestellten Faserzementpla,tten.
Die Erfindung sieht daher bei der Her stellung von zellulosefaserhaltigen Faser zementerzeugnissen die Verwendung einer Zellulose vor, die vor ihrem Vermischen mit. dem Zement gereinigt, insbesondere von Li- gnin, Hemizellulosen und Pentosanen weit gehend befreit sind.
Bei Anwendung möglichst reiner Alpha zellulose kommen die bisher zur Anwendung gebrachten chemischen und physikalisch wir kenden Vorbehandlungen der Faser nicht nur in Wegfall, sondern es wird auch eine Wir kung erzielt, wie sie mit diesen Vorbehand- lungen niemals erreicht werden konnte.
Es ist gleichgültig, auf welchem Wege die Alphazellulose erzeugt wird, ob durch saure oder alkalische Behandlung der Zellfaser und durch welche immer geartete Nachbehand lung. \Vesentlich ist nur, dass die Zellulose einer auf Entfernung der Hemizellulosen, der Pentosane und des Lignins hinzielenden, be sonderen Behandlung unterworfen wird.
Process for the manufacture of cellulosic fiber cement products. The invention relates to a method for producing fiber cement products using cellulose fibers.
The known fiber cement products made using cellulose fibers, such as wood pulp, paper cellulose or the like, have lower strength and tightness properties than asbestos cement products, even if the cellulose fibers are subjected to a chemical or a physical pretreatment in the so-called mineralization of the fiber with hydrated lime, water glass,
Calcium chloride or the like BEZW. in the termination of the fibers against external influences by covering the fibers with an impermeable skin or by impregnating them with water-repellent substances such as paraffin.
The explanation of the connections was and is not uniform. It was believed ent neither that the fiber swells in the wet concrete, or is damaged by the lime of the cement, or both occurs, or the Ze ment from the fiber by releasing harmful Licher, z. B. colloidal substances is influenced. It is all the more difficult to say which of these explanations is the right one, as each one could be reconciled with each of the above measures.
The invention is based on the knowledge that the unsatisfactory strength and tightness of fiber cement products produced using cellulose fibers is based on the fact that the cellulose contains soluble components which interfere with cement hardening, in particular lignin and varying amounts of polysaccharides, namely hemicelluloses and Pentosans. In-depth studies have shown that the strength of a bevel,
The purer the fiber, in particular the lower its content not only of lignin but also of ilemicelluloses and pentosans, the better.
Pure alpha cellulose, when mixed with Portland cement, results in fiber cement panels which, in terms of their strength and other behavior, come considerably closer to asbestos cement panels than the previously known fiber cement panels made using cellulose fibers.
The invention therefore provides cement products in the Her position of cellulosic fiber-containing fiber before the use of a cellulose, which prior to their mixing with. the cement are cleaned, in particular freed from lignin, hemicelluloses and pentosans.
When using alpha cellulose that is as pure as possible, the chemical and physically effective pre-treatments of the fibers that have been used up to now are not only eliminated, but an effect is also achieved that could never be achieved with these pre-treatments.
It does not matter in which way the alpha cellulose is produced, whether by acidic or alkaline treatment of the cell fibers and by whatever kind of post-treatment. It is only essential that the cellulose is subjected to a special treatment aimed at removing hemicelluloses, pentosans and lignin.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE234322X | 1942-06-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH234322A true CH234322A (en) | 1944-09-30 |
Family
ID=5890851
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH234322D CH234322A (en) | 1942-06-17 | 1943-05-17 | Process for the manufacture of cellulosic fiber cement products. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH234322A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999006337A1 (en) * | 1997-07-30 | 1999-02-11 | Construction Research 2000 Ltd. | Composite materials |
-
1943
- 1943-05-17 CH CH234322D patent/CH234322A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999006337A1 (en) * | 1997-07-30 | 1999-02-11 | Construction Research 2000 Ltd. | Composite materials |
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