CA2828585C - Catalyseur de production d'hydrogene contenant un compose intermetallique a base de ni3si, procede d'activation de celui-ci, et procede de production d'hydrogene et dispositif d'utilisation du catalyseur - Google Patents
Catalyseur de production d'hydrogene contenant un compose intermetallique a base de ni3si, procede d'activation de celui-ci, et procede de production d'hydrogene et dispositif d'utilisation du catalyseur Download PDFInfo
- Publication number
- CA2828585C CA2828585C CA2828585A CA2828585A CA2828585C CA 2828585 C CA2828585 C CA 2828585C CA 2828585 A CA2828585 A CA 2828585A CA 2828585 A CA2828585 A CA 2828585A CA 2828585 C CA2828585 C CA 2828585C
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- ni3si
- methanol
- reaction
- intermetallic compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 179
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 84
- 229910000765 intermetallic Inorganic materials 0.000 title claims abstract description 68
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 49
- 239000001257 hydrogen Substances 0.000 title claims description 48
- 238000004519 manufacturing process Methods 0.000 title claims description 48
- 238000000034 method Methods 0.000 title claims description 34
- 230000003213 activating effect Effects 0.000 title claims description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 378
- 229910003217 Ni3Si Inorganic materials 0.000 claims abstract description 118
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 61
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 44
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 44
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 44
- 238000006243 chemical reaction Methods 0.000 claims description 81
- 239000007789 gas Substances 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 30
- 238000010438 heat treatment Methods 0.000 claims description 18
- 239000012535 impurity Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 5
- 230000004913 activation Effects 0.000 claims 1
- 238000000629 steam reforming Methods 0.000 abstract description 27
- 230000003197 catalytic effect Effects 0.000 abstract description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 114
- 238000012360 testing method Methods 0.000 description 57
- 230000000694 effects Effects 0.000 description 53
- 238000002474 experimental method Methods 0.000 description 33
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 22
- 230000008569 process Effects 0.000 description 21
- 229910002091 carbon monoxide Inorganic materials 0.000 description 15
- 238000005530 etching Methods 0.000 description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 13
- 229910001868 water Inorganic materials 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 229910001873 dinitrogen Inorganic materials 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 230000035484 reaction time Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000003513 alkali Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000012159 carrier gas Substances 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 238000004817 gas chromatography Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 238000011946 reduction process Methods 0.000 description 4
- 230000004043 responsiveness Effects 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- 229910005155 Ni5Si3 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010892 electric spark Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000004868 gas analysis Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- GXMBHQRROXQUJS-UHFFFAOYSA-N (2-hept-2-ynylsulfanylphenyl) acetate Chemical compound CCCCC#CCSC1=CC=CC=C1OC(C)=O GXMBHQRROXQUJS-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229910005883 NiSi Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000001651 catalytic steam reforming of methanol Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000001165 gas chromatography-thermal conductivity detection Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0081—Preparation by melting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J7/00—Apparatus for generating gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1217—Alcohols
- C01B2203/1223—Methanol
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-055626 | 2011-03-14 | ||
| JP2011055626 | 2011-03-14 | ||
| PCT/JP2012/055984 WO2012124605A1 (fr) | 2011-03-14 | 2012-03-08 | CATALYSEUR DE PRODUCTION D'HYDROGÈNE CONTENANT UN COMPOSÉ INTERMÉTALLIQUE À BASE DE Ni3Si, PROCÉDÉ D'ACTIVATION DE CELUI-CI, ET PROCÉDÉ DE PRODUCTION D'HYDROGÈNE ET DISPOSITIF D'UTILISATION DU CATALYSEUR |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2828585A1 CA2828585A1 (fr) | 2012-09-20 |
| CA2828585C true CA2828585C (fr) | 2015-06-16 |
Family
ID=46830678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2828585A Expired - Fee Related CA2828585C (fr) | 2011-03-14 | 2012-03-08 | Catalyseur de production d'hydrogene contenant un compose intermetallique a base de ni3si, procede d'activation de celui-ci, et procede de production d'hydrogene et dispositif d'utilisation du catalyseur |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9833773B2 (fr) |
| EP (1) | EP2687289A4 (fr) |
| JP (1) | JP5900894B2 (fr) |
| KR (1) | KR20140046409A (fr) |
| CN (1) | CN103459019B (fr) |
| CA (1) | CA2828585C (fr) |
| TW (1) | TW201242661A (fr) |
| WO (1) | WO2012124605A1 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4321598A1 (fr) | 2022-08-12 | 2024-02-14 | Bp P.L.C. | Production fischer-tropsch d'hydrocarbures à partir de dioxyde de carbone par l'intermédiaire de méthanol |
| EP4321597A1 (fr) | 2022-08-12 | 2024-02-14 | Bp P.L.C. | Production fischer-tropsch d'hydrocarbures à partir de méthanol |
| EP4321596A1 (fr) | 2022-08-12 | 2024-02-14 | Bp P.L.C. | Production fischer-tropsch d'hydrocarbures à partir de dioxyde de carbone par l'intermédiaire de méthanol |
| EP4321478A1 (fr) | 2022-08-12 | 2024-02-14 | Bp P.L.C. | Production de gaz de synthèse à partir de dioxyde de carbone par l'intermédiaire de méthanol |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54125195A (en) * | 1978-03-20 | 1979-09-28 | Texaco Development Corp | Method of steam reforming nonaromatic hydrocarbon materials |
| US4507401A (en) * | 1983-04-01 | 1985-03-26 | At&T Bell Laboratories | Intermetallic catalyst preparation |
| US4612407A (en) * | 1983-04-01 | 1986-09-16 | At&T Laboratories | Aliphatic aromatization with intemetallic Group VIII-IIIA, IVA catalyst |
| JPH0328912Y2 (fr) * | 1986-05-13 | 1991-06-20 | ||
| CN1611623A (zh) * | 2003-10-30 | 2005-05-04 | 中国科学院兰州化学物理研究所 | 镍硅基金属间化合物复合材料及其制备方法 |
| JP4701455B2 (ja) | 2005-09-16 | 2011-06-15 | 独立行政法人物質・材料研究機構 | 水素製造用触媒とその製造方法及び水素の製造方法 |
| JP4918646B2 (ja) * | 2007-07-24 | 2012-04-18 | 公立大学法人大阪府立大学 | Ｎｉ３（Ｓｉ，Ｔｉ）系金属間化合物からなるメタノールからの水素製造用触媒，水素製造方法、水素製造装置 |
-
2012
- 2012-03-08 CA CA2828585A patent/CA2828585C/fr not_active Expired - Fee Related
- 2012-03-08 US US14/001,696 patent/US9833773B2/en not_active Expired - Fee Related
- 2012-03-08 EP EP12757826.8A patent/EP2687289A4/fr not_active Withdrawn
- 2012-03-08 CN CN201280013307.4A patent/CN103459019B/zh not_active Expired - Fee Related
- 2012-03-08 KR KR1020137025363A patent/KR20140046409A/ko not_active Withdrawn
- 2012-03-08 JP JP2013504694A patent/JP5900894B2/ja not_active Expired - Fee Related
- 2012-03-08 WO PCT/JP2012/055984 patent/WO2012124605A1/fr active Application Filing
- 2012-03-13 TW TW101108411A patent/TW201242661A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2687289A4 (fr) | 2014-10-22 |
| CN103459019A (zh) | 2013-12-18 |
| JP5900894B2 (ja) | 2016-04-06 |
| US20130330263A1 (en) | 2013-12-12 |
| KR20140046409A (ko) | 2014-04-18 |
| CA2828585A1 (fr) | 2012-09-20 |
| CN103459019B (zh) | 2016-04-27 |
| US9833773B2 (en) | 2017-12-05 |
| EP2687289A1 (fr) | 2014-01-22 |
| WO2012124605A1 (fr) | 2012-09-20 |
| TW201242661A (en) | 2012-11-01 |
| JPWO2012124605A1 (ja) | 2014-07-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Burkhanov et al. | Palladium-based alloy membranes for separation of high purity hydrogen from hydrogen-containing gas mixtures | |
| García-García et al. | High purity hydrogen production by low temperature catalytic ammonia decomposition in a multifunctional membrane reactor | |
| Sehested et al. | Discovery of technical methanation catalysts based on computational screening | |
| TWI477447B (zh) | 透過單矽烷之熱裂解製造二矽烷之方法及裝置 | |
| CA2828585C (fr) | Catalyseur de production d'hydrogene contenant un compose intermetallique a base de ni3si, procede d'activation de celui-ci, et procede de production d'hydrogene et dispositif d'utilisation du catalyseur | |
| Kim et al. | Hydrogen permeability and crystallization kinetics in amorphous Ni–Nb–Zr alloys | |
| Dolan et al. | Ni-based amorphous alloy membranes for hydrogen separation at 400 C | |
| Tosti et al. | Catalytic Membrane Reactor for Dehydrogenation of Water Via gas-Shift: A Review of the Activities for the Fusion Reactor Fuel Cycle | |
| JP2008081385A (ja) | 水素製造方法およびそのための反応管 | |
| Gora et al. | Lower temperature dehydrogenation of methylcyclohexane by membrane-assisted equilibrium shift | |
| JP5102932B2 (ja) | 高純度水素製造方法 | |
| US8765081B2 (en) | Micro-channel reactor for producing synthetic natural gas | |
| Moon et al. | Palladium-copper membrane modules for hydrogen separation at elevated temperature and pressure | |
| US8822746B2 (en) | Ordered cobalt-aluminum and iron-aluminum intermetallic compounds as hydrogenation catalysts | |
| JPS5935898B2 (ja) | シクロペンテン及び樟脳の同時製造法 | |
| KR101978999B1 (ko) | 니켈 알루미늄 합금체, 이를 이용한 장치 및 그 제조 방법 | |
| Lukyanov | Obtaining ultra-pure hydrogen for fuel cells in the reactors with membrane separation | |
| US20240217894A1 (en) | Method for converting co2 into methane | |
| JP2007084378A (ja) | 水素の製造方法およびそれに使用する装置 | |
| Yen | Supported Liquid Metal Membranes for Hydrogen Separation | |
| SE438328B (sv) | Forfarande for framstellning av metan och etan med anvendning av en hydriderad bimetallisk jern-titan-legering | |
| Santucci et al. | Low temperature ethanol steam reforming in a Pd-Ag membrane reformer | |
| Wyse | Investigation of Zr-based amorphous alloy membranes for hydrogen purification | |
| Watanabe et al. | Hydrogen storage using cyclohexane–methylcyclohexane mixtures available in a freezing region | |
| Ma | 8.1 Introduction Hydrogen is the lightest element in the periodic table and is primarily used as a chemical building block in a large number of chemical processes. Currently, about |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20130828 |
|
| EEER | Examination request |
Effective date: 20130828 |
|
| MKLA | Lapsed |
Effective date: 20180308 |