CA2471202A1 - Marine diesel cylinder lubricant composition - Google Patents
Marine diesel cylinder lubricant composition Download PDFInfo
- Publication number
- CA2471202A1 CA2471202A1 CA002471202A CA2471202A CA2471202A1 CA 2471202 A1 CA2471202 A1 CA 2471202A1 CA 002471202 A CA002471202 A CA 002471202A CA 2471202 A CA2471202 A CA 2471202A CA 2471202 A1 CA2471202 A1 CA 2471202A1
- Authority
- CA
- Canada
- Prior art keywords
- marine diesel
- lubricant composition
- diesel cylinder
- cylinder lubricant
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000314 lubricant Substances 0.000 title claims abstract 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000005864 Sulphur Substances 0.000 claims abstract 5
- 239000000446 fuel Substances 0.000 claims abstract 5
- 239000003599 detergent Substances 0.000 claims abstract 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims abstract 4
- 229960001860 salicylate Drugs 0.000 claims abstract 4
- 230000001050 lubricating effect Effects 0.000 claims abstract 2
- 239000004094 surface-active agent Substances 0.000 claims abstract 2
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 235000006708 antioxidants Nutrition 0.000 claims 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000000994 depressogenic effect Effects 0.000 claims 1
- 239000002270 dispersing agent Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000005461 lubrication Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/028—Overbased salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/26—Overbased carboxylic acid salts
- C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/28—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbased sulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/52—Base number [TBN]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
- C10N2060/14—Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
A marine diesel cylinder lubricant composition for a marine diesel engine running on fuel having a sulphur content of less than 1.5%, the composition having a total base number, as determined according to ASTM D2896, of more than 30 and less than 70, and comprising at least 40 wt% of an oil of lubricating viscosity, and at least one detergent prepared from at least two surfactants, one of which is a salicylate.
The marine diesel cylinder lubricant composition demonstrates good ability to reduce deposit formation, especially on pistons. The marine diesel cylinder lubricant composition also demonstrates good lubrication at temperatures above 250°C.
The marine diesel cylinder lubricant composition demonstrates good ability to reduce deposit formation, especially on pistons. The marine diesel cylinder lubricant composition also demonstrates good lubrication at temperatures above 250°C.
Claims (8)
1. A marine diesel cylinder lubricant composition for a marine diesel engine running on fuel having a sulphur content of less than 1.5%, the composition having a total base number, as determined according to ASTM D2896, of more than 30 and less than 70, and comprising:
- at least 40 wt% of an oil of lubricating viscosity, and - at least one detergent prepared from at least two surfactants, one of which is a salicylate.
- at least 40 wt% of an oil of lubricating viscosity, and - at least one detergent prepared from at least two surfactants, one of which is a salicylate.
2. The marine diesel cylinder lubricant composition as claimed in claim 1, wherein the detergent includes at least 5 mass% of salicylate, preferably at least mass% of salicylate.
3. The marine diesel cylinder lubricant composition as claimed in claims 1 or 2, wherein the detergent further includes at least 5 mass% of phenate and optionally at least 5 mass% of sulphonate.
4. The marine diesel cylinder lubricant composition as claimed in any one of the preceding claims, wherein the lubricant has a base number of less than 60, and preferably less than 50; and preferably more than 32, more preferably more than 35.
5. The marine diesel cylinder lubricant composition as claimed in any one of the preceding claims, further including at least one of the following: a dispersant, an anti-wear agent, an anti-oxidant, a pour point depressant, an anti-foamant and a demulsifier.
6. A method of operating a marine diesel engine running on fuel having at most 1.5% sulphur, the method including the step of using the marine diesel cylinder lubricant composition claimed in any one of claims 1-5 to lubricate the engine.
7. Use of the marine diesel lubricant composition as claimed in any one of claims 1-5 to reduce deposits in a marine diesel cylinder engine running on fuel having at most 1.5% sulphur.
8. Use of the marine diesel cylinder lubricant composition as claimed in any one of claims 1-5 to provide lubricity in a marine diesel engine running on fuel having at most 1.5% sulphur and running at temperatures above 250°C, preferably above 300°C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03253769.8 | 2003-06-13 | ||
EP03253769 | 2003-06-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2471202A1 true CA2471202A1 (en) | 2004-12-13 |
CA2471202C CA2471202C (en) | 2011-11-01 |
Family
ID=33547787
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2471202A Expired - Fee Related CA2471202C (en) | 2003-06-13 | 2004-06-11 | Marine diesel cylinder lubricant composition |
Country Status (6)
Country | Link |
---|---|
US (1) | US20050003972A1 (en) |
JP (1) | JP4928070B2 (en) |
CN (1) | CN100500816C (en) |
AU (1) | AU2004202588B2 (en) |
CA (1) | CA2471202C (en) |
SG (1) | SG126767A1 (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE518939T1 (en) * | 2005-05-11 | 2011-08-15 | Infineum Int Ltd | FUEL COMPOSITIONS |
EP1728849B1 (en) * | 2005-05-27 | 2019-12-18 | Infineum International Limited | A method of lubricating the cylinder liner and the crankcase of a cross-head marine diesel engine |
US8076274B2 (en) * | 2006-07-20 | 2011-12-13 | Infineum International Limited | Lubricating oil composition |
WO2008119936A1 (en) * | 2007-03-30 | 2008-10-09 | Bp P.L.C. | Lubrication methods |
EP2003189A1 (en) * | 2007-06-12 | 2008-12-17 | BP p.l.c. | Lubrication methods |
US20130098322A1 (en) * | 2009-11-30 | 2013-04-25 | The Lubrizol Corporation | Methods of Controlling Sulfur Trioxide Levels in Internal Combustion Engines |
EP2719751B1 (en) * | 2012-06-07 | 2021-03-31 | Infineum International Limited | Marine engine lubrication |
US9434906B2 (en) * | 2013-03-25 | 2016-09-06 | Chevron Oronite Company, Llc | Marine diesel engine lubricating oil compositions |
SG11201603378WA (en) | 2013-11-06 | 2016-05-30 | Chevron Oronite Technology Bv | Marine diesel cylinder lubricant oil compositions |
EP3066180B1 (en) | 2013-11-06 | 2021-01-13 | Chevron Oronite Technology B.V. | Marine diesel cylinder lubricant oil compositions |
JP6386348B2 (en) * | 2014-11-18 | 2018-09-05 | Jxtgエネルギー株式会社 | Cylinder lubricating oil composition for crosshead type diesel engine mounted on scrubber |
WO2016080441A1 (en) * | 2014-11-18 | 2016-05-26 | Jx日鉱日石エネルギー株式会社 | Cylinder lubricating oil composition for scrubber-equipped crosshead diesel engines |
JP6297477B2 (en) * | 2014-11-18 | 2018-03-20 | Jxtgエネルギー株式会社 | Cylinder lubricating oil composition for crosshead type diesel engine mounted on scrubber |
KR20160092963A (en) * | 2016-07-13 | 2016-08-05 | 윤종식 | Method of preventing traffic accidents in crossroad for signal violation and overspeed, and system of the same |
US10603075B1 (en) | 2018-11-30 | 2020-03-31 | Ohana Biosciences, Inc. | Compositions and methods for enhancing sperm function |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9611424D0 (en) * | 1996-05-31 | 1996-08-07 | Exxon Chemical Patents Inc | Overbased metal-containing detergents |
GB9611318D0 (en) * | 1996-05-31 | 1996-08-07 | Exxon Chemical Patents Inc | Overbased metal-containing detergents |
GB9611428D0 (en) * | 1996-05-31 | 1996-08-07 | Exxon Chemical Patents Inc | Overbased metal-containing detergents |
GB9709006D0 (en) * | 1997-05-02 | 1997-06-25 | Exxon Chemical Patents Inc | Lubricating oil compositions |
CN1105165C (en) * | 1997-11-28 | 2003-04-09 | 英菲诺姆美国公司 | Lubricating oil compositions |
US6277794B1 (en) * | 1998-12-28 | 2001-08-21 | Infineum Usa L.P. | Lubricant compositions |
GB9800436D0 (en) * | 1998-01-09 | 1998-03-04 | Exxon Chemical Patents Inc | Marine lubricant compositions |
GB9908771D0 (en) * | 1999-04-17 | 1999-06-09 | Infineum Uk Ltd | Lubricity oil composition |
ATE491775T1 (en) * | 1999-09-13 | 2011-01-15 | Infineum Int Ltd | A METHOD OF LUBRICATION FOR TWO-STROKE MARINE DIESEL ENGINES |
JP4011815B2 (en) * | 2000-02-14 | 2007-11-21 | シェブロンジャパン株式会社 | Lubricating oil composition for two-cycle crosshead diesel internal combustion engine and additive composition for lubricating oil composition |
GB0011115D0 (en) * | 2000-05-09 | 2000-06-28 | Infineum Int Ltd | Lubricating oil compositions |
EP1209218A1 (en) * | 2000-11-27 | 2002-05-29 | Infineum International Limited | Lubricating oil compositions |
EP1229101A1 (en) * | 2001-02-06 | 2002-08-07 | Infineum International Limited | Marine diesel engine lubricant |
EP1229102A1 (en) * | 2001-02-06 | 2002-08-07 | Infineum International LTD | Lubricating oil composition |
EP1236791A1 (en) * | 2001-02-16 | 2002-09-04 | Infineum International Limited | Overbased detergent additives |
EP1236792B1 (en) * | 2001-02-16 | 2007-01-03 | Infineum International LTD | Use of overbased detergent additives to suspend asphaltene compounds |
US6884531B2 (en) * | 2001-05-21 | 2005-04-26 | Saudi Arabian Oil Company | Liquid hydrocarbon based fuels for fuel cell on-board reformers |
-
2004
- 2004-06-08 US US10/863,041 patent/US20050003972A1/en not_active Abandoned
- 2004-06-11 SG SG200404073A patent/SG126767A1/en unknown
- 2004-06-11 AU AU2004202588A patent/AU2004202588B2/en not_active Ceased
- 2004-06-11 CN CNB2004100481099A patent/CN100500816C/en not_active Expired - Fee Related
- 2004-06-11 JP JP2004173663A patent/JP4928070B2/en not_active Expired - Fee Related
- 2004-06-11 CA CA2471202A patent/CA2471202C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1572864A (en) | 2005-02-02 |
US20050003972A1 (en) | 2005-01-06 |
SG126767A1 (en) | 2006-11-29 |
JP2005002341A (en) | 2005-01-06 |
AU2004202588B2 (en) | 2009-05-21 |
JP4928070B2 (en) | 2012-05-09 |
AU2004202588A1 (en) | 2005-01-06 |
CA2471202C (en) | 2011-11-01 |
CN100500816C (en) | 2009-06-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20180611 |