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CA2424447A1 - Stabilized liquid compositions - Google Patents

Stabilized liquid compositions Download PDF

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Publication number
CA2424447A1
CA2424447A1 CA002424447A CA2424447A CA2424447A1 CA 2424447 A1 CA2424447 A1 CA 2424447A1 CA 002424447 A CA002424447 A CA 002424447A CA 2424447 A CA2424447 A CA 2424447A CA 2424447 A1 CA2424447 A1 CA 2424447A1
Authority
CA
Canada
Prior art keywords
composition
hydroxyl
liquid
agents
thread
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002424447A
Other languages
French (fr)
Other versions
CA2424447C (en
Inventor
Mark Allen Smerznak
Walter August Maria Broeckx
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Individual
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Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26936117&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2424447(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2424447A1 publication Critical patent/CA2424447A1/en
Application granted granted Critical
Publication of CA2424447C publication Critical patent/CA2424447C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0063—Photo- activating compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/162—Organic compounds containing Si
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Structuring systems, specifically thread-like structuring systems and/or disk-like structuring systems wherein structuring agents aggregate together to form disk-like structures that can interact with other disk-like structures to result in a structuring system, and processes for making such structuring systems, stabilized liquid compositions comprising such structuring systems, systems that utilize such structuring systems for stabilizing liquid compositions, and methods for utilizing the stabilized liquid compositions to provide a benefit, are disclosed.

Claims (22)

What is claimed is:
1. A water-containing liquid detergent composition characterized in that it comprises:
a) a fabric substantive agent having limited solubility in said liquid detergent composition;
b) a crystalline, hydroxyl-containing stabilizer; and optionally, c) a nonsurfactant adjunct suitable for laundry or dishwashing detergents wherein said adjunct is soluble in said liquid detergent composition.
2. The composition according to Claim 1 wherein said composition comprises an effective amount of said crystalline, hydroxyl-containing stabilizer to suspend said fabric substantive agent within said composition.
3. A composition according to Claims 1 or 2 wherein said fabric substantive agent comprises at least one of the following moieties: a silicon-containing moiety; a cationic charged moiety; a nitrogen-containing moiety; a polyethylene glycol moiety.
4. The composition according to any of the preceding claims wherein said crystalline, hydroxyl-containing stabilizer comprises a fatty ester or fatty soap moiety; or wherein said crystalline, hydroxyl-containing stabilizer is derived from castor oil.
5. The composition according to Claims 1 or 2 wherein said fabric substantive agent is selected from the group consisting of silicon-moiety containing agents (preferably aminofunctional silicones or quaternary-nitrogen-containing silicones), anti-abrasion polymers, dye fixative agents, optical brighteners, fabric substantive perfumes, soil release polymers, photobleaches, bleaches, bleach precursors, and mixtures thereof.
6. An aqueous laundry and/or dishwashing liquid composition comprising a thread-like structuring system and a benefit-providing material wherein the thread-like structuring system stabilizes the benefit-providing material such that the benefit-providing material provides its benefit upon use.
7. The aqueous liquid composition according to Claim 6 wherein said material is selected from the group consisting of: fabric substantive agents, defoaming agents (preferably silicone / silica combinations), aesthetic agents and mixtures thereof.
8. A stabilized water-containing liquid laundry detergent composition comprising a thread-like structuring system having an average aspect ratio of from 1.5:1, preferably from at least 10:1, to 200:1.
9. A stabilizing system wherein an aqueous laundry and/or dishwashing liquid composition is stabilized by an effective amount of a thread-like structuring system.
10. The compositions according to Claims 6, 7, or 8, or the stabilizing system according to Claim 9 wherein said thread-like structuring system comprises a crystalline, hydroxyl-containing stabilizing agent.
11. The compositions according to Claims 1-8 or 10, or the stabilizing system according to Claims 9 or 10 Wherein said crystalline, hydroxyl-containing stabilizing agent has a formula selected from the group consisting of:

wherein:

R2 is R1 or H;
R3 is R1 or H;
R4 is independently C10-C22 alkyl or alkenyl comprising at least one hydroxyl group;

ii) wherein:

R4 is as defined above in i);
M is Na+, K+, Mg++ or Al3+, or H; and iii) mixtures thereof.
2. The compositions according to Claims 1-8, 10, or 11 or the stabilizing system according to Claims 9, 10, or 11 wherein said crystalline, hydroxyl-containing stabilizer has the formula:

wherein:

(x + a) is from between 11 and 17; (y + b) is from between 11 and 17; and (z + c) is from between 11 and 17.
13. The compositions or the stabilizing system according to Claim 12 wherein x = y = z =10; or, wherein a = b = c = 5.
14. The compositions according to Claims 1-8, 10, or 11 or the stabilizing system according to Claims 9, 10, or 11 further comprising at least one of the following: a salt and a surfactant, wherein said surfactant, if present, is preferably selected from:
(i) anionic surfactants, preferably selected from alkylbenzenesulfonate surfactants, alkyl alkoxylate sulfate surfactants, alkyl sulfate surfactants and mixtures thereof;
(ii) nonionic surfactants, preferably alkyl alkoxylate surfactants, alkylphenyl alkoxylate surfactants alkylpolyglycosides, and mixtures thereof, and (iii)mixtures thereof.
15. The compositions, or the stabilizing systems according to any of the preceding claims comprising 5% by weight or greater of water, wherein said compositions preferably comprise a heavy-duty laundry detergent.
16. The stabilizing system according to any of Claims 9-15 wherein said material is selected from the group consisting of fabric substantive agents, defoaming agents, aesthetic agents and mixtures thereof.
17. A water-containing liquid detergent composition comprising:
a) a defoaming and/or aesthetic agent having limited solubility in said liquid detergent composition;
b) a crystalline, hydroxyl-containing stabilizer; and optionally, c) a nonsurfactant adjunct suitable for laundry or dishwashing detergents wherein said adjunct is soluble in said liquid detergent composition.
18. The liquid composition according to Claim 17 wherein said aesthetic agent is selected from the group consisting of colored particles, pearlescent agents, dyes and mixtures thereof.
19. The liquid composition according to Claim 17 wherein said defoaming agent comprises a polydimethylsiloxane compounded with silica.
20. A stabilizing system wherein an aqueous laundry and/or dishwashing liquid composition is stabilized by an effective amount of a structuring system comprising a thread-like structuring system and a non-thread-like structuring system.
21. A method for increasing the viscosity of an aqueous laundry and/or dishwashing liquid composition comprising the step of adding an effective amount of a thread-like structuring system to the liquid composition such that the viscosity of the liquid composition is increased compared to the viscosity of the liquid composition without such as structuring system.
22. A water-containing liquid detergent composition comprising:
a) a fabric substantive agent having limited solubility in said liquid detergent composition;
b) a material of the formula:

Z-(CH(OH))a-Z' where a is from 2 to 4; and Z and Z' are hydrophobic groups; and optionally, c) a nonsurfactant adjunct suitable for laundry or dishwashing detergents wherein said adjunct is soluble in said liquid detergent composition.
CA002424447A 2000-10-27 2001-10-23 Stabilized liquid compositions Expired - Lifetime CA2424447C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US24382400P 2000-10-27 2000-10-27
US60/243,824 2000-10-27
US29167901P 2001-05-17 2001-05-17
US60/291,679 2001-05-17
PCT/US2001/046073 WO2002040627A2 (en) 2000-10-27 2001-10-23 Stabilized liquid compositions

Publications (2)

Publication Number Publication Date
CA2424447A1 true CA2424447A1 (en) 2002-05-23
CA2424447C CA2424447C (en) 2009-12-22

Family

ID=26936117

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002424447A Expired - Lifetime CA2424447C (en) 2000-10-27 2001-10-23 Stabilized liquid compositions

Country Status (12)

Country Link
US (1) US6855680B2 (en)
EP (2) EP1328616B2 (en)
JP (1) JP5111718B2 (en)
CN (1) CN100340648C (en)
AT (1) ATE400639T1 (en)
AU (1) AU2002239475A1 (en)
BR (1) BR0114910B1 (en)
CA (1) CA2424447C (en)
DE (1) DE60134760D1 (en)
ES (2) ES2309106T3 (en)
MX (1) MXPA03003739A (en)
WO (1) WO2002040627A2 (en)

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