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CA2414197A1 - Thermoplastic superabsorbent polymer blend compositions and their preparation - Google Patents

Thermoplastic superabsorbent polymer blend compositions and their preparation Download PDF

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Publication number
CA2414197A1
CA2414197A1 CA002414197A CA2414197A CA2414197A1 CA 2414197 A1 CA2414197 A1 CA 2414197A1 CA 002414197 A CA002414197 A CA 002414197A CA 2414197 A CA2414197 A CA 2414197A CA 2414197 A1 CA2414197 A1 CA 2414197A1
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CA
Canada
Prior art keywords
superabsorbent polymer
nonwoven web
extruded
polymer blend
molded article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002414197A
Other languages
French (fr)
Other versions
CA2414197C (en
Inventor
Felix Achille
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2414197A1 publication Critical patent/CA2414197A1/en
Application granted granted Critical
Publication of CA2414197C publication Critical patent/CA2414197C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/12—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
    • C08L101/14—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/225—Mixtures of macromolecular compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/48—Surfactants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28023—Fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/246—Intercrosslinking of at least two polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/44—Materials comprising a mixture of organic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
    • G02B6/4401—Optical cables
    • G02B6/4429—Means specially adapted for strengthening or protecting the cables
    • G02B6/44384—Means specially adapted for strengthening or protecting the cables the means comprising water blocking or hydrophobic materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/68—Melt-blown nonwoven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/681—Spun-bonded nonwoven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/699—Including particulate material other than strand or fiber material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • Hematology (AREA)
  • Analytical Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

An extrudable thermoplastic superabsorbent polymer blend composition is disclosed. The blend compositions are especially well suited for preparation of extruded or molded articles such as monolayer films, multilayer films, nonwoven webs, sheets, foams, profiles, multilayer laminates, fibers, tubes, rods or pipes which in turn are well suited for preparation of power and communication cables or disposable absorbent articles such as diapers, sanitary napkins, tampons, incontinence products, hospital gowns or bed pads .

Claims (31)

1. An extrudable thermoplastic superabsorbent polymer blend composition comprising (a) one or more superabsorbent polymer and (b) one or more thermoplastic resin comprising a functional group which interacts ionically or covalently with (a).
2. The extrudable thermoplastic superabsorbent polymer blend composition of Claim 1 having a melt draw down rate between about 5 and about 100 feet per minute and a melt tension between about 0.1 and about 10 under temperature and applied load conditions that give a melt flow rate of between about 0.1 and about 300 g/10 min.
3. The extrudable thermoplastic superabsorbent polymer blend composition of Claim 1 wherein the superabsorbent polymer is prepared from water-soluble a,(3-ethylenically unsaturated monomers.
4. The extrudable thermoplastic superabsorbent polymer of Claim 3 wherein the .alpha.,.beta.-ethylenically unsaturated monomers is a monocarboxylic acid, a vinyl polycarboxylic acid, an acrylamide or mixtures thereof.
5. The extrudable thermoplastic superabsorbent polymer blend composition of Claim 1 wherein the superabsorbent polymer is a cellulosic-graft copolymer, a starch-graft copolymer, a starch-g-poly(acrylic acid), a polyacrylamide; a polyvinyl alcohol, a poly(acrylic acid), a copolymer of sulfonic acid group containing monomer, or mixtures thereof.
6. The superabsorbent polymer of Claim 5 is crosslinked, partially neutralized, surface treated or combinations thereof.
7. The extrudable thermoplastic superabsorbent polymer blend composition of Claim 1 wherein the thermoplastic resin is a polyacrylic acid, ethylene and acrylic acid copolymer, ethylene, t-butylacrylate and acrylic acid terpolymer, ethylene and methacrylic acid copolymer, ionomers of ethylene and methacrylic acid copolymers, ethylene, vinyl acetate and carbon monoxide terpolymer, ethylene and carbon monoxide copolymer, ethylene, acrylic acid and carbon monoxide terpolymers, ethylene, n-butylacrylate and carbon monoxide terpolymer or blends thereof.
8. The extrudable thermoplastic superabsorbent polymer blend composition of Claim 1 further comprising a surfactant.
9. The extrudable thermoplastic superabsorbent polymer blend composition of Claims 1, 3 or 8 further comprising a polyethylene, a copolymer of polyethylene, a polypropylene, a copolymer of polypropylene or a polystyrene.
10. A method for preparing an extrudable thermoplastic superabsorbent polymer blend composition comprising the step of combining:
(a) one or more superabsorbent polymer and (b) one or more thermoplastic resin comprising a functional group which interacts ionically or covalently with (a).
11. The method of Claim 10 further comprising the step of combining (c) a surfactant.
12. A method for producing an extruded or molded article of an extrudable thermoplastic superabsorbent polymer blend composition comprising the steps of 1) preparing an extrudable thermoplastic superabsorbent polymer composition comprising (c) one or more superabsorbent polymer and (b) one or more thermoplastic resin comprising a functional group which interacts ionically or covalently with (a) and 2) extruding or molding said thermoplastic superabsorbent polymer composition into an extruded or molded article.
13. The method of Claim 12 wherein the superabsorbent polymer composition further comprising (c) a surfactant.
14. The method of Claims 12 or 13 wherein the extruded article is a monolayer film, a multilayer film, a nonwoven web, a sheet, a foam, a profile, a multilayer laminate, a fiber, a tube, a rod or a pipe.
15. The method of Claims 12 or 13 wherein the extruded article is a monofilament fiber, a bicomponent monofilament fiber, a spun bond nonwoven web, a melt blown nonwoven web, or a composite comprising combinations thereof.
16. The method of Claims 12 or 13 wherein the extruded article is a nonwoven web comprising a spun bond nonwoven web comprising one or more bicomponent fiber, a melt blown nonwoven web comprising one or more bicomponent fiber, or a composite structure comprising at least one layer of one or more spun bond nonwoven web and at least one layer of one or more melt blown nonwoven web wherein one or more layers of the composite comprise bicomponent fibers.
17. The composition of Claims 1 or 8 in the form of an extruded or molded article.
18. The extruded or molded article of Claim 17 is a monolayer film, a multilayer film, a nonwoven web, a sheet, a foam, a profile, a multilayer laminate, a fiber, a tube, a rod or a pipe.
19. The extruded or molded article of Claim 17 is a monofilament fiber, a bicomponent monofilament fiber, a spun bond nonwoven web, melt blown nonwoven web, or a composite comprising combinations thereof.
20. The extruded or molded article of Claim 17 is a nonwoven web comprising a spun bond nonwoven web comprising one or more bicomponent fiber, a melt blown nonwoven web comprising one or more bicomponent fiber, or a composite structure comprising at least one layer of one or more spun bond nonwoven web and at least one layer of one or more melt blown nonwoven web wherein one or more layers of the composite comprise bicomponent fibers.
21. The monolayer film or multilayer film of Claim 18 laminated to a metal.
22. A power cable comprising the metal laminate of Claim 21.
23. A communications cable comprising the metal laminate of Claim 21.
24. A power cable comprising the monolayer film or multilayer film of Claim 18.
25. A communications cable comprising the monolayer film or multilayer film of Claim 18.
26. A disposable absorbent device comprising an extruded or molded article of Claim 18.
27. The disposable absorbent device of Claim 26 is a diaper, a sanitary napkin, a tampon, an incontinence product, a hospital gown or a bed pad.
28. A disposable absorbent device comprising an extruded or molded article of Claim 19.
29. The disposable absorbent device of Claim 28 is a diaper, a sanitary napkin, a tampon, an incontinence product, a hospital gown or a bed pad.
30. A disposable absorbent device comprising an extruded or molded article of Claim 20.
31. The disposable absorbent device of Claim 30 is a diaper, a sanitary napkin, a tampon, an incontinence product, a hospital gown or a bed pad.
CA2414197A 2000-07-24 2001-07-11 Thermoplastic superabsorbent polymer blend compositions and their preparation Expired - Fee Related CA2414197C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US22052900P 2000-07-24 2000-07-24
US60/220,529 2000-07-24
PCT/US2001/021869 WO2002007791A2 (en) 2000-07-24 2001-07-11 Thermoplastic superabsorbent polymer blend compositions and their preparation

Publications (2)

Publication Number Publication Date
CA2414197A1 true CA2414197A1 (en) 2002-01-31
CA2414197C CA2414197C (en) 2010-08-24

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Family Applications (1)

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CA2414197A Expired - Fee Related CA2414197C (en) 2000-07-24 2001-07-11 Thermoplastic superabsorbent polymer blend compositions and their preparation

Country Status (11)

Country Link
US (1) US20020039869A1 (en)
EP (1) EP1311620A2 (en)
JP (1) JP2004504446A (en)
KR (1) KR20030031129A (en)
CN (1) CN1180032C (en)
AU (2) AU2002224531B2 (en)
CA (1) CA2414197C (en)
CZ (1) CZ2003176A3 (en)
IL (2) IL154029A0 (en)
MX (1) MXPA03000200A (en)
WO (1) WO2002007791A2 (en)

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