CA2368600C - Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition - Google Patents
Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition Download PDFInfo
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- CA2368600C CA2368600C CA002368600A CA2368600A CA2368600C CA 2368600 C CA2368600 C CA 2368600C CA 002368600 A CA002368600 A CA 002368600A CA 2368600 A CA2368600 A CA 2368600A CA 2368600 C CA2368600 C CA 2368600C
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- colored
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- polymeric material
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- 239000007788 liquid Substances 0.000 title claims abstract description 80
- 239000002245 particle Substances 0.000 title claims abstract description 61
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 35
- 239000003599 detergent Substances 0.000 title claims abstract description 32
- 238000010186 staining Methods 0.000 title claims abstract description 16
- 238000004851 dishwashing Methods 0.000 title claims description 30
- 239000000049 pigment Substances 0.000 claims abstract description 26
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 239000011248 coating agent Substances 0.000 claims abstract description 24
- 239000007844 bleaching agent Substances 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000011246 composite particle Substances 0.000 claims abstract description 16
- 239000006185 dispersion Substances 0.000 claims abstract description 16
- 238000005507 spraying Methods 0.000 claims abstract description 8
- 238000010348 incorporation Methods 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 229920013820 alkyl cellulose Polymers 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 4
- 239000000693 micelle Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 239000000047 product Substances 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 229920000609 methyl cellulose Polymers 0.000 description 8
- 239000001923 methylcellulose Substances 0.000 description 8
- 235000010981 methylcellulose Nutrition 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 235000011181 potassium carbonates Nutrition 0.000 description 2
- 235000015424 sodium Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 125000000185 sucrose group Chemical group 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 229920003105 Methocel™ A15 LV Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- DERZBLKQOCDDDZ-JLHYYAGUSA-N cinnarizine Chemical compound C1CN(C(C=2C=CC=CC=2)C=2C=CC=CC=2)CCN1C\C=C\C1=CC=CC=C1 DERZBLKQOCDDDZ-JLHYYAGUSA-N 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000007771 core particle Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 229940001593 sodium carbonate Drugs 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- CEWNUSPMSSUSJA-AATRIKPKSA-N ustin Chemical compound O1C(=O)C2=C(C)C(Cl)=C(O)C(Cl)=C2OC2=C(Cl)C(C(/C)=C/C)=C(O)C(C)=C21 CEWNUSPMSSUSJA-AATRIKPKSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B63/00—Lakes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0097—Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
A process for forming a non-staining colored composite particle suitable for incorporation in a bleach-containing or a non-bleach-containing liquid detergent composition is disclosed. The process includes the steps of forming a colored liquid dispersion of pigment particles in a first liquid medium wherein the size of the pigment particles in the colored liquid dispersion is no greater than about µm. The process includes the step of mixing the colored liquid dispersion with a polymeric material and a second liquid medium to form a sprayable colored polymeric material. The process also includes the step of spraying the colored polymeric material on a composite particle and forming a colored polymeric coating on the composite particle. A
non-staining colored particle and a liquid ADW detergent composition are also disclosed.
non-staining colored particle and a liquid ADW detergent composition are also disclosed.
Description
PROCESS FOR MAKING NON-STAINING COLORED PARTICLES FOR IMPROVING
AESTHETICS OF A LIOUID AUTOMATIC DISHWASHING DETERGENT PRODUCT THE
PARTICLES, AND A COMPOSITION
TECHNICAL FIELD
The present invention generally relates to liquid automatic dishwashing detergent compositions. More particularly, the invention relates to a process for making colored particles that can be incorporated into a bleach-containing or non-bleach-containing liquid automatic dishwashing detergent composition for improving the aesthetics of the liquid composition wherein the colored particles do not stain the plastic surfaces of dishware or an automatic dishwasher.
BACKGROUND OF THE INVENTION
Consumers of liquid ADW products have a preference for such products having a certain color or appearance. The addition of solid particles suspended into a liquid ADW composition can improve the aesthetics of the product by simply improving the physical appearance of the product. This is particularly true if the particles are colored and their color is matched effectively to the base color of the liquid ADW composition.
Previously used particles in liquid ADW products have had a major disadvantage of contributing negatively to unwanted filming, particularly on glass, stainless steel and plastic surfaces. This is because the previously used particles have been coated with water-insoluble coatings, such as waxes, which melt and are released into the wash solution due to the high temperature encountered during the automatic dishwashing process.
Further, in the arena of bleach containing liquid ADWs, the particles cannot be colored by simply using a dye, because during storage of the liquid ADW product, the dye gets bleached.
Thus, the formulators have to use bleach-safe pigments to impart an aesthetically pleasing color.
Before this invention, the incorporation of pigments posed a major problem:
the color of the pigment is found to detrimentally stain plastic surfaces, such as plastic dishware and the internal plastic surfaces of a dishwasher.
It has been desirable to have a process by which colored pigment based particles can be made for incorporation in bleach-containing or non-bleach-containing liquid ADW product, such that the particles are non-staining. It has also been desirable that the solid particles do not dissolve in the liquid ADW product, but dissolve rapidly in the wash solution during automatic dishwashing. It has been desirable to have a liquid ADW product having solid particles that do not cause a significant amount of unwanted filming on glass, stainless steel and plastic.
The inventors of the present invention have discovered a process of coating the particles with a pigment in a manner such that the particles are non-staining. This invention is not limited to just bleach-containing liquid ADWs and is also applicable to non-bleach-containing liquid ADWs that are incorporated with prills or particles colored with pigments. The present invention is thus directed to overcome one or more of the problems as set forth before.
SUMMARY OF THE INVENTION
1 S The invention meets the needs above by providing a process for forming a non-staining colored composite particle suitable for incorporation in a bleach-containing or non-bleach-containing liquid detergent composition, a non-staining colored composite particle and a liquid dishwashing detergent composition.
In one aspect of the present invention, the process includes the steps of forming a colored liquid dispersion of pigment particles in a first liquid medium. The size of the pigment particles in the colored liquid dispersion is no greater than about S Vim. The process includes the step of mixing the colored liquid dispersion with a polymeric material and a second liquid medium to form a sprayable colored polymeric material. The polymeric material being selected from the group consisting of alkyl cellulose ethers and polyvinyl alcohol. The process also includes the step of spraying the colored polymeric material on a composite particle and forming a colored polymeric coating on the composite particle.
In another aspect of the present invention, a non-staining colored composite particle suitable for incorporation in a bleach-containing liquid detergent composition is disclosed. The particle is made by the process as set forth above.
In yet another aspect of the present invention, a liquid automatic dishwashing detergent product is disclosed. The product includes a liquid dishwashing detergent composition containing chlorine bleach, and non-staining colored composite particles. The particles are made by the process as set forth above.
DETAILED DESCRIPTION OF THE INVENTION
In the preferred embodiment of the present invention, the process includes the steps of forming a colored liquid dispersion of pigment particles in a first liquid medium.
Pigment processine The size of the pigment particles in the colored liquid dispersion is desirably no greater than about 5 Vim, preferably no greater than about 1 Vim, more preferably no greater than about 0.1 Vim, and most preferably no greater than about 0.01 Vim. It has been surprisingly discovered that when the pigment particle size in the pigment-liquid dispersion is maintained within the above size limitations, the resultant pigment, when deposited on a particle as a part of the sprayable polymeric slurry, is essentially non-staining. i.e., its color does not transfer onto plastic surfaces. The selection of the pigment particle size is the key to the present invention. One skilled in the art can apply other means for achieving a pigment particle size in the size limitation as disclosed above.
In the preferred embodiment, the first liquid medium is preferably water.
Optionally, a minor amount of a nonionic surfactant is added to the water to improve the dispersion of the pigment. Typically, this surfactant is added in an amount no greater than about 10% by weight.
In the preferred embodiment, the process includes the step of maintaining the amount of surfactants used in the bleach-containing liquid detergent composition at a preselected value such that when the bleach-containing liquid detergent composition is diluted in a wash solution, the amount of surfactant delivered in the wash solution is less than critical micelle concentration.
The term "critical micelle concentration" is well known to those skilled in the art and need not be explained any further for purposes of brevity.
Polymeric coating In the preferred embodiment, the colored polymeric coating is insoluble in the liquid automatic dishwashing detergent composition but soluble in automatic dishwashing wash solution. The coating is prepared from materials which are insoluble in the liquid automatic dishwashing detergent composition but soluble in automatic dishwashing wash solution. The coating is prepared from materials selected from the group consisting of alkyl cellulose ethers and polyvinyl alcohol. Alternatively, the coating is prepared from alginate.
Desirably, the alkyl cellulose ethers are selected from one of methyl cellulose and hydroxypropyl methyl cellulose (HPMC). Preferably, the coating is prepared from methyl cellulose having a number average molecular weight desirably in a range of from about 5000 to about 100,000, more preferably from about 10,000 to about 20,000, and most preferably, about 14,000. The preferred methyl cellulose is one sold under the trade name MethocelT~' A l SLV. and manufactured by Dow Chemicals Alternatively, the polymeric coating is polyvinyl alcohol (PVA) having a molecular weight, desirably in a range of from about 5000 to about 100,000, and preferably from about 13,000 to about 23,000. The preferred PVA is from about 87% to about 89% hydrolyzed, such as a commercially available product having a trade name AirvolT"' 205. Further. the particles are insoluble in the liquid automatic dishwashing detergent composition and only soluble in the wash solution during automatic dishwashing.
Process for snraving colored polymeric coatine on particles The process by which the colored polymeric coating is prepared and deposited upon the particle is critical in order for the particles to remain undissolved in the liquid automatic dishwashing detergent composition and only become soluble in the wash solution during automatic dishwashing. It is desirable that the panicles dispersed in the liquid ADW
compositions do not break up or dissolve in the composition. It is also desirable that this be achieved without depositing an unduly thick coating of a polymeric material on the panicle. It has been surprisingly discovered that when the polymeric material, such as methyl cellulose is sufficiently hydrated before spraying on the particle or prill, the polymer coated particle or prill remains stable, unbroken and undissolved in the liquid ADW composition. This hydration is achieved by forming a sprayable aqueous solution of the polymer (alkyl cellulose ether and/or polyvinyl alcohol) having a polymer concentration desirably in a range of from about 1 % to about 30% by weight, preferably in a range of about 3°J° to about 20 %, more preferably in a range of about 3% to about 10 %, and most preferably, about 5%. Further, the temperature of aqueous solution of the polymer is desirably maintained within a range of from about 30 °C to about 40 °C
while spraying the polymer solution on the particle, and preferably in a range of from about 32 °C
to about 38 °C, and most preferably at a temperature of about 35 °C. It has been surprisingly found that by using a combination of the above process steps, i.e., the polymer solution being in a range of from about 1 % to 30% by weight, and the spray temperature being in a range of from about 30 °C to about 40 °C, that a very stable, unbroken, continuous coating is formed on the panicle or prill which is undissolved in the liquid ADW composition but soluble in the wash solution, while at the same time, requiring only about 5% polymer by weight of the panicle. In the preferred embodiment, the coating is desirably present in an amount in a range of from about 1 % to about 25% by weight of the particle, preferably from about 4% to about 10% by weight of the particle, and most preferably, about 5°.o by weight of the panicle.
The reduced coating weight levels are desirable so that the least effective coating amount is used in order to accomplish the objective to having a protective coating without unnecessary polymer that might detrimentally contribute to unwanted residue deposition in the washing machine.
Color In one embodiment, the panicles are colored and the automatic dishwashing liquid detergent composition is clear or translucent, so as to make the liquid automatic dishwashing product aesthetically pleasing. In another embodiment. the panicles and the liquid automatic dishwashing detergent composition are both colored and the color of the particles is matched to the base color of the liquid composition. In one embodiment, the paniclcs have a dark green color whereas the liquid composition has a light green color. Other preferred color combinations for the polymeric coating on the particles and the liquid automatic dishwashing composition are:
blue:blue, blue:white, green:green, green:white and green:yellow, respectively.
Desirably, the particles comprise from about 0.1 % to about 5.0% by weight of the liquid composition, and preferably, from about 0.2% to about 1.0% by weight of the liquid composition.
In another embodiment of the present invention, a non-staining colored composite particle suitable for incorporation in a bleach-containing liquid detergent composition is disclosed. The panicle is made by the process as set forth above.
Particles The particles can be formed from various materials that do not cause any detrimental affect upon the performance of the liquid detergent. Preferably, the particles are in the form of prills. The prills typically have a core which is coated with a polymeric coating as described before. The core can be made from sucrose, as an example. The method of forming prills is well known to those skilled in the art and is disclosed in the literature, such as for example, in U.S.
Patent No. 4,965,012,.
The particles can be of various sizes and shapes, such as spherical, oval, cylindrical or polygonal and desirably have a particle size in a range of from about 200 Elm to about 5000 E<m, preferably, from about 400 Elm to about 2000 Elm, and most prefer ably, from about 500 Elm to about 850 E<m.
In yet another embodiment of the present invention, a liquid automatic dishwashing detergent product is disclosed. The product includes a liquid dishwashing detergent composition containing chlorine bleach, and non-staining colored composite particles, The particles are made by the process as set forth above.
Li4uid automatic dishwashin~~composition components 'The liquid automatic dishwashing detergent product is highly viscous in a aui~scent state and has a relatively high yield stress values, when subjected to sheaf stresses, however, such as being shaken in a container or squeezed through an orifice, the product quickly fluidizes and upon cessation of the applied shear stress, quickly revens to a high viscosity state. The above liquid automatic dishwashing detergent product is preferably low foaming, readily soluble in the washing medium and most effective at pH values best conducive to improved cleaning performance, such as in a range of desirably from about pH 7.0 to about pH
13.0, and preferably from about pH 8.0 to about pH 12Ø
The physical stability of the liquid product may be improved and the thickness of the liquid product may be altered by the addition of a cross linking polyacrylate thickener to the liquid detergent product as a thixotropic thickener.
PH adj,ustin~ components i The pH adjusting components are desirably selected from sodium or potassium carbonate or sesquicarbonate, sodium or potassium silicate, citric acid, sodium or potassium bicarbonate, sodium or potassium borate, sodium or potassium hydroxide, and mixtures thereof. NaOH or KOH are the preferred ingredients for increasing the pH to within the above ranges. Other IS preferred pH adjusting ingredients are sodium carbonate, potassium carbonate, and mixtures thereof.
Low FoamingSurfactant Chlorine bleach stable low foaming surfactants are preferred and such surfactants are present in a range of from about 0.1 % to about 10% by weight of the liquid composition. Such surfactants are generally known to one skilled in the art and need not be elaborated here, for purposes ofbrevity. One example of such a surfactant is an anionic surfactant commercially available under the trade name - DowfaxTM
Other ingredients ?he liquid automatic dishwashing detergent composition optionally also contains from about 0.5% to about 20°!° of a dispersant polymer selected from the group consisting of polyacrylates and polyacrylate copolymers, and from about 0.1% to about 5% of a chlorine bleach stable foam suppressant. Such foam suppressants are well known to those skilled in the ari.
To exemplify various embodiments of the present invention, Sample A of the liquid automatic dishwashing detergent product composition is formulated using the below named ingredients, as set forth in Example A.
EXAMPLE A
)~redient (weight % activel A
_7_ Sodium Tripolyphosphate 17.5 Potassium Tripolyphosphate---Sodium Silicate 6.0 Potassium hydroxide 3.6 Sodium hydroxide 2.0 Polyacrylate polymer 1.0 Nitric Acid 0.012 Perfume 0.03 Nonionic surfactant ---Sodium Benzoate 0.75 Sodium hypochlorite 1.15 Polyacrylate polymer thickener1.5 Dye solution ---Solid Prill 0.5 Water Bal.
TOTAL 100:0 In the above composition, the non-staining colored particles having a spherical shape, and a diameter of about 750 Vim, are formed from a sucrose core coated with a polymeric coating formed from methyl cellulose (Methocel A15LV), and having a bluish-green color. The bluish-green color is imparted by adding a pigment into the methyl cellulose coating before spraying it on the particle according to the process of the present invention. The particles comprise about 0.1 % to about 5% by weight of the liquid composition. The optimum methyl cellulose coating is about 5% by weight of the particle. The coating is sprayed on the sucrose core particle by spraying a 5% by weight aqueous solution of methyl cellulose with pigment. The aqueous solution temperature being carefully maintained at about 35 °C. The size of the pigment particles in the aqueous solution is no greater than about 1 Vim.
The resultant particles are insoluble in the liquid composition but are soluble in the wash solution during automatic dishwashing. The resultant colored particles are also non-staining to plastic surfaces.
Accordingly, having thus described the invention in detail, it will be obvious to those skilled in the art that various changes may be made without departing from the scope of the invention and the invention is not to be considered limited to what is described in the specification.
AESTHETICS OF A LIOUID AUTOMATIC DISHWASHING DETERGENT PRODUCT THE
PARTICLES, AND A COMPOSITION
TECHNICAL FIELD
The present invention generally relates to liquid automatic dishwashing detergent compositions. More particularly, the invention relates to a process for making colored particles that can be incorporated into a bleach-containing or non-bleach-containing liquid automatic dishwashing detergent composition for improving the aesthetics of the liquid composition wherein the colored particles do not stain the plastic surfaces of dishware or an automatic dishwasher.
BACKGROUND OF THE INVENTION
Consumers of liquid ADW products have a preference for such products having a certain color or appearance. The addition of solid particles suspended into a liquid ADW composition can improve the aesthetics of the product by simply improving the physical appearance of the product. This is particularly true if the particles are colored and their color is matched effectively to the base color of the liquid ADW composition.
Previously used particles in liquid ADW products have had a major disadvantage of contributing negatively to unwanted filming, particularly on glass, stainless steel and plastic surfaces. This is because the previously used particles have been coated with water-insoluble coatings, such as waxes, which melt and are released into the wash solution due to the high temperature encountered during the automatic dishwashing process.
Further, in the arena of bleach containing liquid ADWs, the particles cannot be colored by simply using a dye, because during storage of the liquid ADW product, the dye gets bleached.
Thus, the formulators have to use bleach-safe pigments to impart an aesthetically pleasing color.
Before this invention, the incorporation of pigments posed a major problem:
the color of the pigment is found to detrimentally stain plastic surfaces, such as plastic dishware and the internal plastic surfaces of a dishwasher.
It has been desirable to have a process by which colored pigment based particles can be made for incorporation in bleach-containing or non-bleach-containing liquid ADW product, such that the particles are non-staining. It has also been desirable that the solid particles do not dissolve in the liquid ADW product, but dissolve rapidly in the wash solution during automatic dishwashing. It has been desirable to have a liquid ADW product having solid particles that do not cause a significant amount of unwanted filming on glass, stainless steel and plastic.
The inventors of the present invention have discovered a process of coating the particles with a pigment in a manner such that the particles are non-staining. This invention is not limited to just bleach-containing liquid ADWs and is also applicable to non-bleach-containing liquid ADWs that are incorporated with prills or particles colored with pigments. The present invention is thus directed to overcome one or more of the problems as set forth before.
SUMMARY OF THE INVENTION
1 S The invention meets the needs above by providing a process for forming a non-staining colored composite particle suitable for incorporation in a bleach-containing or non-bleach-containing liquid detergent composition, a non-staining colored composite particle and a liquid dishwashing detergent composition.
In one aspect of the present invention, the process includes the steps of forming a colored liquid dispersion of pigment particles in a first liquid medium. The size of the pigment particles in the colored liquid dispersion is no greater than about S Vim. The process includes the step of mixing the colored liquid dispersion with a polymeric material and a second liquid medium to form a sprayable colored polymeric material. The polymeric material being selected from the group consisting of alkyl cellulose ethers and polyvinyl alcohol. The process also includes the step of spraying the colored polymeric material on a composite particle and forming a colored polymeric coating on the composite particle.
In another aspect of the present invention, a non-staining colored composite particle suitable for incorporation in a bleach-containing liquid detergent composition is disclosed. The particle is made by the process as set forth above.
In yet another aspect of the present invention, a liquid automatic dishwashing detergent product is disclosed. The product includes a liquid dishwashing detergent composition containing chlorine bleach, and non-staining colored composite particles. The particles are made by the process as set forth above.
DETAILED DESCRIPTION OF THE INVENTION
In the preferred embodiment of the present invention, the process includes the steps of forming a colored liquid dispersion of pigment particles in a first liquid medium.
Pigment processine The size of the pigment particles in the colored liquid dispersion is desirably no greater than about 5 Vim, preferably no greater than about 1 Vim, more preferably no greater than about 0.1 Vim, and most preferably no greater than about 0.01 Vim. It has been surprisingly discovered that when the pigment particle size in the pigment-liquid dispersion is maintained within the above size limitations, the resultant pigment, when deposited on a particle as a part of the sprayable polymeric slurry, is essentially non-staining. i.e., its color does not transfer onto plastic surfaces. The selection of the pigment particle size is the key to the present invention. One skilled in the art can apply other means for achieving a pigment particle size in the size limitation as disclosed above.
In the preferred embodiment, the first liquid medium is preferably water.
Optionally, a minor amount of a nonionic surfactant is added to the water to improve the dispersion of the pigment. Typically, this surfactant is added in an amount no greater than about 10% by weight.
In the preferred embodiment, the process includes the step of maintaining the amount of surfactants used in the bleach-containing liquid detergent composition at a preselected value such that when the bleach-containing liquid detergent composition is diluted in a wash solution, the amount of surfactant delivered in the wash solution is less than critical micelle concentration.
The term "critical micelle concentration" is well known to those skilled in the art and need not be explained any further for purposes of brevity.
Polymeric coating In the preferred embodiment, the colored polymeric coating is insoluble in the liquid automatic dishwashing detergent composition but soluble in automatic dishwashing wash solution. The coating is prepared from materials which are insoluble in the liquid automatic dishwashing detergent composition but soluble in automatic dishwashing wash solution. The coating is prepared from materials selected from the group consisting of alkyl cellulose ethers and polyvinyl alcohol. Alternatively, the coating is prepared from alginate.
Desirably, the alkyl cellulose ethers are selected from one of methyl cellulose and hydroxypropyl methyl cellulose (HPMC). Preferably, the coating is prepared from methyl cellulose having a number average molecular weight desirably in a range of from about 5000 to about 100,000, more preferably from about 10,000 to about 20,000, and most preferably, about 14,000. The preferred methyl cellulose is one sold under the trade name MethocelT~' A l SLV. and manufactured by Dow Chemicals Alternatively, the polymeric coating is polyvinyl alcohol (PVA) having a molecular weight, desirably in a range of from about 5000 to about 100,000, and preferably from about 13,000 to about 23,000. The preferred PVA is from about 87% to about 89% hydrolyzed, such as a commercially available product having a trade name AirvolT"' 205. Further. the particles are insoluble in the liquid automatic dishwashing detergent composition and only soluble in the wash solution during automatic dishwashing.
Process for snraving colored polymeric coatine on particles The process by which the colored polymeric coating is prepared and deposited upon the particle is critical in order for the particles to remain undissolved in the liquid automatic dishwashing detergent composition and only become soluble in the wash solution during automatic dishwashing. It is desirable that the panicles dispersed in the liquid ADW
compositions do not break up or dissolve in the composition. It is also desirable that this be achieved without depositing an unduly thick coating of a polymeric material on the panicle. It has been surprisingly discovered that when the polymeric material, such as methyl cellulose is sufficiently hydrated before spraying on the particle or prill, the polymer coated particle or prill remains stable, unbroken and undissolved in the liquid ADW composition. This hydration is achieved by forming a sprayable aqueous solution of the polymer (alkyl cellulose ether and/or polyvinyl alcohol) having a polymer concentration desirably in a range of from about 1 % to about 30% by weight, preferably in a range of about 3°J° to about 20 %, more preferably in a range of about 3% to about 10 %, and most preferably, about 5%. Further, the temperature of aqueous solution of the polymer is desirably maintained within a range of from about 30 °C to about 40 °C
while spraying the polymer solution on the particle, and preferably in a range of from about 32 °C
to about 38 °C, and most preferably at a temperature of about 35 °C. It has been surprisingly found that by using a combination of the above process steps, i.e., the polymer solution being in a range of from about 1 % to 30% by weight, and the spray temperature being in a range of from about 30 °C to about 40 °C, that a very stable, unbroken, continuous coating is formed on the panicle or prill which is undissolved in the liquid ADW composition but soluble in the wash solution, while at the same time, requiring only about 5% polymer by weight of the panicle. In the preferred embodiment, the coating is desirably present in an amount in a range of from about 1 % to about 25% by weight of the particle, preferably from about 4% to about 10% by weight of the particle, and most preferably, about 5°.o by weight of the panicle.
The reduced coating weight levels are desirable so that the least effective coating amount is used in order to accomplish the objective to having a protective coating without unnecessary polymer that might detrimentally contribute to unwanted residue deposition in the washing machine.
Color In one embodiment, the panicles are colored and the automatic dishwashing liquid detergent composition is clear or translucent, so as to make the liquid automatic dishwashing product aesthetically pleasing. In another embodiment. the panicles and the liquid automatic dishwashing detergent composition are both colored and the color of the particles is matched to the base color of the liquid composition. In one embodiment, the paniclcs have a dark green color whereas the liquid composition has a light green color. Other preferred color combinations for the polymeric coating on the particles and the liquid automatic dishwashing composition are:
blue:blue, blue:white, green:green, green:white and green:yellow, respectively.
Desirably, the particles comprise from about 0.1 % to about 5.0% by weight of the liquid composition, and preferably, from about 0.2% to about 1.0% by weight of the liquid composition.
In another embodiment of the present invention, a non-staining colored composite particle suitable for incorporation in a bleach-containing liquid detergent composition is disclosed. The panicle is made by the process as set forth above.
Particles The particles can be formed from various materials that do not cause any detrimental affect upon the performance of the liquid detergent. Preferably, the particles are in the form of prills. The prills typically have a core which is coated with a polymeric coating as described before. The core can be made from sucrose, as an example. The method of forming prills is well known to those skilled in the art and is disclosed in the literature, such as for example, in U.S.
Patent No. 4,965,012,.
The particles can be of various sizes and shapes, such as spherical, oval, cylindrical or polygonal and desirably have a particle size in a range of from about 200 Elm to about 5000 E<m, preferably, from about 400 Elm to about 2000 Elm, and most prefer ably, from about 500 Elm to about 850 E<m.
In yet another embodiment of the present invention, a liquid automatic dishwashing detergent product is disclosed. The product includes a liquid dishwashing detergent composition containing chlorine bleach, and non-staining colored composite particles, The particles are made by the process as set forth above.
Li4uid automatic dishwashin~~composition components 'The liquid automatic dishwashing detergent product is highly viscous in a aui~scent state and has a relatively high yield stress values, when subjected to sheaf stresses, however, such as being shaken in a container or squeezed through an orifice, the product quickly fluidizes and upon cessation of the applied shear stress, quickly revens to a high viscosity state. The above liquid automatic dishwashing detergent product is preferably low foaming, readily soluble in the washing medium and most effective at pH values best conducive to improved cleaning performance, such as in a range of desirably from about pH 7.0 to about pH
13.0, and preferably from about pH 8.0 to about pH 12Ø
The physical stability of the liquid product may be improved and the thickness of the liquid product may be altered by the addition of a cross linking polyacrylate thickener to the liquid detergent product as a thixotropic thickener.
PH adj,ustin~ components i The pH adjusting components are desirably selected from sodium or potassium carbonate or sesquicarbonate, sodium or potassium silicate, citric acid, sodium or potassium bicarbonate, sodium or potassium borate, sodium or potassium hydroxide, and mixtures thereof. NaOH or KOH are the preferred ingredients for increasing the pH to within the above ranges. Other IS preferred pH adjusting ingredients are sodium carbonate, potassium carbonate, and mixtures thereof.
Low FoamingSurfactant Chlorine bleach stable low foaming surfactants are preferred and such surfactants are present in a range of from about 0.1 % to about 10% by weight of the liquid composition. Such surfactants are generally known to one skilled in the art and need not be elaborated here, for purposes ofbrevity. One example of such a surfactant is an anionic surfactant commercially available under the trade name - DowfaxTM
Other ingredients ?he liquid automatic dishwashing detergent composition optionally also contains from about 0.5% to about 20°!° of a dispersant polymer selected from the group consisting of polyacrylates and polyacrylate copolymers, and from about 0.1% to about 5% of a chlorine bleach stable foam suppressant. Such foam suppressants are well known to those skilled in the ari.
To exemplify various embodiments of the present invention, Sample A of the liquid automatic dishwashing detergent product composition is formulated using the below named ingredients, as set forth in Example A.
EXAMPLE A
)~redient (weight % activel A
_7_ Sodium Tripolyphosphate 17.5 Potassium Tripolyphosphate---Sodium Silicate 6.0 Potassium hydroxide 3.6 Sodium hydroxide 2.0 Polyacrylate polymer 1.0 Nitric Acid 0.012 Perfume 0.03 Nonionic surfactant ---Sodium Benzoate 0.75 Sodium hypochlorite 1.15 Polyacrylate polymer thickener1.5 Dye solution ---Solid Prill 0.5 Water Bal.
TOTAL 100:0 In the above composition, the non-staining colored particles having a spherical shape, and a diameter of about 750 Vim, are formed from a sucrose core coated with a polymeric coating formed from methyl cellulose (Methocel A15LV), and having a bluish-green color. The bluish-green color is imparted by adding a pigment into the methyl cellulose coating before spraying it on the particle according to the process of the present invention. The particles comprise about 0.1 % to about 5% by weight of the liquid composition. The optimum methyl cellulose coating is about 5% by weight of the particle. The coating is sprayed on the sucrose core particle by spraying a 5% by weight aqueous solution of methyl cellulose with pigment. The aqueous solution temperature being carefully maintained at about 35 °C. The size of the pigment particles in the aqueous solution is no greater than about 1 Vim.
The resultant particles are insoluble in the liquid composition but are soluble in the wash solution during automatic dishwashing. The resultant colored particles are also non-staining to plastic surfaces.
Accordingly, having thus described the invention in detail, it will be obvious to those skilled in the art that various changes may be made without departing from the scope of the invention and the invention is not to be considered limited to what is described in the specification.
Claims (10)
1. A process for forming a non-staining colored composite particle suitable for incorporation in a bleach-containing liquid detergent composition, characterized by the steps of:
forming a colored liquid dispersion of pigment particles in a first liquid medium, wherein the size of said pigment particles in said colored liquid dispersion is no greater than 5 µm;
mixing said colored liquid dispersion with a polymeric material and a second liquid medium to form a sprayable colored polymeric material; said polymeric material being selected from the group consisting of alkyl cellulose ethers and polyvinyl alcohol; and spraying said colored polymeric material on a composite particle, and forming a colored polymeric coating on said composite particle.
forming a colored liquid dispersion of pigment particles in a first liquid medium, wherein the size of said pigment particles in said colored liquid dispersion is no greater than 5 µm;
mixing said colored liquid dispersion with a polymeric material and a second liquid medium to form a sprayable colored polymeric material; said polymeric material being selected from the group consisting of alkyl cellulose ethers and polyvinyl alcohol; and spraying said colored polymeric material on a composite particle, and forming a colored polymeric coating on said composite particle.
2. The process according to claim 1, wherein the size of said pigment particles in said colored liquid dispersion is no greater than 1 µm.
3. The process according to any one of claims 1-2, wherein the size of said pigment particles in said colored liquid dispersion is no greater than 0.1 µm.
4. The process according to any one of claims 1-3, wherein the size of said pigment particles in said colored liquid dispersion is no greater than 0.01 µm.
5. The process according to any one of claims 1-4, wherein the first liquid medium is water.
6. The process according to any one of claims 1-5, wherein the first liquid medium is water mixed with up to about 10% by weight of a non-ionic surfactant.
7. The process according to any one of claims 1-6, further including the step of maintaining an amount of surfactants used in said bleach-containing liquid detergent composition at a preselected value such that when the bleach-containing liquid detergent composition is diluted in a wash solution, an amount of surfactant delivered in the wash solution is less than critical micelle concentration.
8. The process according to any one of claims 1-7. wherein said composite particle remains insoluble in said bleach-containing liquid detergent composition but soluble in automatic dishwashing wash solution.
9. The process according to any one of claims 1-8, wherein said colored polymeric coating is soluble in an automatic dishwashing wash solution and leaves no significant residue.
10. The process according to any one of claims 1-9, wherein the step of spraying said colored polymeric material on a composite particle includes the step of forming a sprayable aqueous solution of a polymeric material, said polymeric material being present in said sprayable aqueous solution in an amount in a range of from 1%
to 20%
by weight.
to 20%
by weight.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13004499P | 1999-04-19 | 1999-04-19 | |
| US60/130,044 | 1999-04-19 | ||
| PCT/US2000/010386 WO2000063341A1 (en) | 1999-04-19 | 2000-04-18 | Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2368600A1 CA2368600A1 (en) | 2000-10-26 |
| CA2368600C true CA2368600C (en) | 2005-04-05 |
Family
ID=22442798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002368600A Expired - Lifetime CA2368600C (en) | 1999-04-19 | 2000-04-18 | Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1171569A1 (en) |
| JP (1) | JP2002542383A (en) |
| AU (1) | AU4358200A (en) |
| CA (1) | CA2368600C (en) |
| WO (1) | WO2000063341A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI116125B (en) * | 2001-07-02 | 2005-09-30 | Sandvik Tamrock Oy | Type of device |
| EP2248884A1 (en) | 2004-07-22 | 2010-11-10 | The Procter & Gamble Company | Detergent Compositions Comprising Coloured Particles |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE621577A (en) * | 1961-03-10 | |||
| AU8317487A (en) * | 1987-04-17 | 1988-10-20 | Ecolab Inc. | Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches |
| US5879920A (en) * | 1991-10-07 | 1999-03-09 | Genencor International, Inc. | Coated enzyme-containing granule |
| DE4322229A1 (en) * | 1993-07-05 | 1995-01-12 | Cognis Bio Umwelt | Enveloped enzyme preparation for detergents and cleaners |
| WO1998016615A1 (en) * | 1996-10-15 | 1998-04-23 | The Procter & Gamble Company | Colored particulate compositions |
-
2000
- 2000-04-18 EP EP00923464A patent/EP1171569A1/en not_active Withdrawn
- 2000-04-18 JP JP2000612420A patent/JP2002542383A/en active Pending
- 2000-04-18 AU AU43582/00A patent/AU4358200A/en not_active Abandoned
- 2000-04-18 CA CA002368600A patent/CA2368600C/en not_active Expired - Lifetime
- 2000-04-18 WO PCT/US2000/010386 patent/WO2000063341A1/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU4358200A (en) | 2000-11-02 |
| WO2000063341A1 (en) | 2000-10-26 |
| JP2002542383A (en) | 2002-12-10 |
| CA2368600A1 (en) | 2000-10-26 |
| EP1171569A1 (en) | 2002-01-16 |
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| EEER | Examination request | ||
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