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CA2341175A1 - Synthese de fischer-tropsch utilisant des catalyseurs sur des supports mesoporeux - Google Patents

Synthese de fischer-tropsch utilisant des catalyseurs sur des supports mesoporeux Download PDF

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Publication number
CA2341175A1
CA2341175A1 CA002341175A CA2341175A CA2341175A1 CA 2341175 A1 CA2341175 A1 CA 2341175A1 CA 002341175 A CA002341175 A CA 002341175A CA 2341175 A CA2341175 A CA 2341175A CA 2341175 A1 CA2341175 A1 CA 2341175A1
Authority
CA
Canada
Prior art keywords
catalyst
cobalt
support
group
catalytically active
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002341175A
Other languages
English (en)
Inventor
Leo E. Manzer
Stephan Schwarz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/377,008 external-priority patent/US6235677B1/en
Priority claimed from US09/376,873 external-priority patent/US6319872B1/en
Application filed by Individual filed Critical Individual
Publication of CA2341175A1 publication Critical patent/CA2341175A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne un procédé de production d'hydrocarbures. Ce procédé consiste à placer un débit d'entrée, comprenant de l'hydrogène et du monoxyde de carbone, en contact avec un catalyseur dans une zone de réaction maintenue dans des conditions favorisant la transformation,et permettant de produire un courant d'effluent comprenant des hydrocarbures. Ce procédé consiste ensuite à utiliser un catalyseur comprenant (a) au moins un métal catalytique pour les réactions de Fischer-Tropsch (par exemple, du fer, du cobalt, du nickel et/ou du ruthénium) et (b) une support mésoporeux sans couche qui présente une diffraction des rayons X après calcination dont on moins un pic se situe à un espacement d supérieure à 18 .ANG.ngstrom units.
CA002341175A 1998-08-20 1999-08-19 Synthese de fischer-tropsch utilisant des catalyseurs sur des supports mesoporeux Abandoned CA2341175A1 (fr)

Applications Claiming Priority (13)

Application Number Priority Date Filing Date Title
US9719298P 1998-08-20 1998-08-20
US9719398P 1998-08-20 1998-08-20
US9719498P 1998-08-20 1998-08-20
US60/097,193 1998-08-20
US60/097,192 1998-08-20
US60/097,194 1998-08-20
US37700799A 1999-08-18 1999-08-18
US09/376,873 1999-08-18
US09/377,008 1999-08-18
US09/377,008 US6235677B1 (en) 1998-08-20 1999-08-18 Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
US09/376,873 US6319872B1 (en) 1998-08-20 1999-08-18 Fischer-Tropsch processes using catalysts on mesoporous supports
US09/377,007 1999-08-18
PCT/US1999/018994 WO2000010698A2 (fr) 1998-08-20 1999-08-19 Synthese de fischer-tropsch utilisant des catalyseurs sur des supports mesoporeux

Publications (1)

Publication Number Publication Date
CA2341175A1 true CA2341175A1 (fr) 2000-03-02

Family

ID=27557542

Family Applications (2)

Application Number Title Priority Date Filing Date
CA002341175A Abandoned CA2341175A1 (fr) 1998-08-20 1999-08-19 Synthese de fischer-tropsch utilisant des catalyseurs sur des supports mesoporeux
CA002341174A Abandoned CA2341174A1 (fr) 1998-08-20 1999-08-19 Procedes fischer-tropsch utilisant des catalyseurs a base de xerogel ou d'aerogel formes par la destabilisation de colloides aqueux

Family Applications After (1)

Application Number Title Priority Date Filing Date
CA002341174A Abandoned CA2341174A1 (fr) 1998-08-20 1999-08-19 Procedes fischer-tropsch utilisant des catalyseurs a base de xerogel ou d'aerogel formes par la destabilisation de colloides aqueux

Country Status (4)

Country Link
EP (2) EP1109622A4 (fr)
AU (3) AU5575199A (fr)
CA (2) CA2341175A1 (fr)
WO (3) WO2000010705A1 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6548440B1 (en) 1999-05-26 2003-04-15 Science & Technology Corporation @ Unm Synthesis of attrition-resistant heterogeneous catalysts using templated mesoporous silica
US6730708B2 (en) 2000-07-03 2004-05-04 Conocophillips Company Fischer-Tropsch processes and catalysts using aluminum borate supports
EP1338335A4 (fr) * 2000-11-08 2005-01-19 Idemitsu Kosan Co Catalyseur de reformage pour hydrocarbures et procede de reformage correspondant
EP1363982A1 (fr) 2001-01-12 2003-11-26 Conocophillips Company Catalyseurs favorises par le bore et synthese de fischer-tropsch
EP1380341B1 (fr) 2001-03-29 2008-02-06 Idemitsu Kosan Co., Ltd. Procede catalytique de reformage d'hydrocarbures mettant en oeuvre ledit catalyseur
US7067453B1 (en) 2001-07-13 2006-06-27 Innovatek, Inc. Hydrocarbon fuel reforming catalyst and use thereof
EP2666540A1 (fr) * 2012-05-22 2013-11-27 Karlsruher Institut für Technologie Procédé d'hydrodésoxygénation catalytique de dérivés de furane et/ou d'huiles de pyrolyse, le catalyseur correspondant et son procédé de préparation.
US10875820B2 (en) 2013-06-20 2020-12-29 Standard Alcohol Company Of America, Inc. Catalyst for converting syngas to mixed alcohols
US9290425B2 (en) * 2013-06-20 2016-03-22 Standard Alcohol Company Of America, Inc. Production of mixed alcohols from synthesis gas
FR3018810B1 (fr) * 2014-03-20 2017-06-09 Ifp Energies Now Procede fischer-tropsch utilisant un catalyseur a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice et du phosphore
CN111375439B (zh) * 2020-04-22 2022-09-20 陕西延长石油（集团）有限责任公司 一种液相丙烯一步制备环氧丙烷的方法及催化剂
CN112517019A (zh) * 2020-12-17 2021-03-19 大唐国际化工技术研究院有限公司 一种以TiO2气凝胶为载体的甲烷化催化剂及其制备方法和应用
CN112588292A (zh) * 2020-12-17 2021-04-02 大唐国际化工技术研究院有限公司 一种以TiO2气凝胶为载体的甲烷化催化剂及其制备方法和应用
CN114671452B (zh) * 2022-03-03 2023-09-01 滁州学院 一种以环氧化合物为凝胶促进剂制备块状氧化铈气凝胶的方法

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Also Published As

Publication number Publication date
WO2000010698A3 (fr) 2000-10-26
AU757374B2 (en) 2003-02-20
WO2000010704A1 (fr) 2000-03-02
AU5575199A (en) 2000-03-14
WO2000010698A2 (fr) 2000-03-02
AU5572199A (en) 2000-03-14
AU5681899A (en) 2000-03-14
AU746882B2 (en) 2002-05-02
WO2000010705A1 (fr) 2000-03-02
EP1109622A4 (fr) 2002-01-23
EP1109622A2 (fr) 2001-06-27
EP1128905A1 (fr) 2001-09-05
CA2341174A1 (fr) 2000-03-02

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FZDE Discontinued