CA2274579A1 - Catalyst/wax separation device for slurry fischer-tropsch reactor - Google Patents
Catalyst/wax separation device for slurry fischer-tropsch reactor Download PDFInfo
- Publication number
- CA2274579A1 CA2274579A1 CA002274579A CA2274579A CA2274579A1 CA 2274579 A1 CA2274579 A1 CA 2274579A1 CA 002274579 A CA002274579 A CA 002274579A CA 2274579 A CA2274579 A CA 2274579A CA 2274579 A1 CA2274579 A1 CA 2274579A1
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- settler
- wax
- reactor
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 239000002002 slurry Substances 0.000 title abstract 5
- 238000000926 separation method Methods 0.000 title 1
- 239000002245 particle Substances 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 1
- 238000010926 purge Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Catalyst particles are separated from the wax in a Fisher-Tropsch reactor by feeding a portion of the reactor slurry to a dynamic settler which does not require any pump. As the slurry flows down a pipe in the center of the settler, the slurry flows into the surrounding annular region at the bottom of the settler. The heavier catalyst particles settle down and are removed as the slurry at the bottom of the settler is recycled back to the reactor. The wax rises up in the annular section and this clarified wax is removed by a wax outlet pipe. In an embodiment with an expanded diameter section above the Fisher-Tropsch reactor an additional dynamic settler can be placed inside this section. The Fischer-Tropsch catalyst can be regenerated by purging the catalyst with an inert gas for a period of time and by treating the catalyst with naphtha.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3337596P | 1996-12-16 | 1996-12-16 | |
| US60/033,375 | 1996-12-16 | ||
| PCT/US1997/023191 WO1998027181A1 (en) | 1996-12-16 | 1997-12-15 | Catalyst/wax separation device for slurry fischer-tropsch reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2274579A1 true CA2274579A1 (en) | 1998-06-25 |
| CA2274579C CA2274579C (en) | 2008-08-05 |
Family
ID=21870069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002274579A Expired - Lifetime CA2274579C (en) | 1996-12-16 | 1997-12-15 | Catalyst/wax separation device for slurry fischer-tropsch reactor |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0951521A1 (en) |
| AU (1) | AU720266B2 (en) |
| CA (1) | CA2274579C (en) |
| WO (1) | WO1998027181A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6800579B2 (en) * | 2002-01-29 | 2004-10-05 | Exxonmobil Research And Engineering Company | Catalyst regeneration |
| EP1754769A1 (en) | 2005-08-16 | 2007-02-21 | Research Institute of Petroleum | Continuous catalyst /wax separation method |
| DE102011013470A1 (en) | 2010-07-26 | 2012-01-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Process and means for removing metals from high boiling hydrocarbon fractions |
| DE102013104696A1 (en) | 2013-05-07 | 2014-11-13 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Process for removing metals from high boiling hydrocarbon fractions |
| DE102013106439A1 (en) | 2013-06-20 | 2014-12-24 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Process for removing metals from high boiling hydrocarbon fractions |
| DE102013106441A1 (en) | 2013-06-20 | 2014-12-24 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Process for removing metals from high boiling hydrocarbon fractions |
| DE102014107374A1 (en) | 2014-05-26 | 2015-11-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Process for removing metals from high boiling hydrocarbon fractions |
| DE102014107375A1 (en) | 2014-05-26 | 2015-11-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Process for removing metal from high-boiling hydrocarbon fractions |
| RU2017118397A (en) | 2014-10-30 | 2018-11-30 | Сабик Глобал Текнолоджиз Б.В. | REACTOR CONTAINING COOLING PLATES LOCATED IN THE RADIAL DIRECTION, AND WAYS OF ITS APPLICATION |
| JP2017536445A (en) | 2014-10-31 | 2017-12-07 | サビック グローバル テクノロジーズ ベスローテン フエンノートシャップ | Reactor for separating wax product from light gaseous product of reaction |
| EP3103858A1 (en) | 2015-06-08 | 2016-12-14 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Method for washing organic liquids with a liquid comprising flurohydrocarbons |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2038774C (en) * | 1990-04-04 | 2001-09-25 | Eric Herbolzheimer | Slurry bubble column |
| GB9203959D0 (en) * | 1992-02-25 | 1992-04-08 | Norske Stats Oljeselskap | Method of conducting catalytic converter multi-phase reaction |
| NZ250750A (en) * | 1993-01-27 | 1995-02-24 | Sasol Chem Ind Pty | Reacting gases in a slurry bed which contains a filtration zone to separate liquid product |
-
1997
- 1997-12-15 AU AU56061/98A patent/AU720266B2/en not_active Expired
- 1997-12-15 CA CA002274579A patent/CA2274579C/en not_active Expired - Lifetime
- 1997-12-15 EP EP97952465A patent/EP0951521A1/en not_active Withdrawn
- 1997-12-15 WO PCT/US1997/023191 patent/WO1998027181A1/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0951521A1 (en) | 1999-10-27 |
| AU720266B2 (en) | 2000-05-25 |
| AU5606198A (en) | 1998-07-15 |
| WO1998027181A1 (en) | 1998-06-25 |
| CA2274579C (en) | 2008-08-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20171215 |