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CA2232737A1 - Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes - Google Patents

Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes

Info

Publication number
CA2232737A1
CA2232737A1 CA002232737A CA2232737A CA2232737A1 CA 2232737 A1 CA2232737 A1 CA 2232737A1 CA 002232737 A CA002232737 A CA 002232737A CA 2232737 A CA2232737 A CA 2232737A CA 2232737 A1 CA2232737 A1 CA 2232737A1
Authority
CA
Canada
Prior art keywords
solid electrolytes
concentration sensors
fuel cells
well
oxygen concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002232737A
Other languages
French (fr)
Other versions
CA2232737C (en
Inventor
Shigeyuki Kawatsu
Takehisa Fukui
Satoshi Ohara
Mitsue Ogawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Japan Fine Ceramics Center
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Fine Ceramics Center, Toyota Motor Corp filed Critical Japan Fine Ceramics Center
Publication of CA2232737A1 publication Critical patent/CA2232737A1/en
Application granted granted Critical
Publication of CA2232737C publication Critical patent/CA2232737C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4073—Composition or fabrication of the solid electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • H01M2300/0074—Ion conductive at high temperature
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Fuel Cell (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Conductive Materials (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

A solid electrolyte of the present invention has a perovskite structure including an alkaline earth metal site, a rare earth element site, and oxygen, wherein barium (Ba) exists in the alkaline earth metal site, and praseodymium (Pr) and at least one other rare earth element exist in the rare earth element site. This solid electrolyte has excellent proton conductivity and oxide ion conductivity and shows high electrical conductivity in a temperature range of 400 to 700°C .
This solid electrolyte is applied to construct fuel cells, a hydrogen pump, an oxygen concentration sensor, and a steam concentration sensor, which are favorably driven in the above temperature range.
CA002232737A 1997-03-31 1998-03-19 Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes Expired - Fee Related CA2232737C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP9-98072 1997-03-31
JP09807297A JP3680232B2 (en) 1997-03-31 1997-03-31 Solid electrolyte and fuel cell, hydrogen pump, oxygen concentration sensor and water vapor concentration sensor using the same

Publications (2)

Publication Number Publication Date
CA2232737A1 true CA2232737A1 (en) 1998-09-30
CA2232737C CA2232737C (en) 2005-06-14

Family

ID=14210152

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002232737A Expired - Fee Related CA2232737C (en) 1997-03-31 1998-03-19 Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes

Country Status (3)

Country Link
JP (1) JP3680232B2 (en)
CA (1) CA2232737C (en)
DE (1) DE19814106B4 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2543071C1 (en) * 2014-03-19 2015-02-27 Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук Fabrication method of electrodes in cells with solid electrolyte
US9958338B2 (en) 2011-10-25 2018-05-01 Guenther Heisskanaltechnik Gmbh Thermocouple with a heater on a substrate
EP3425088A1 (en) * 2017-07-05 2019-01-09 Panasonic Intellectual Property Management Co., Ltd. Hydrogen supply system
CN114509472A (en) * 2022-04-19 2022-05-17 佛山速敏智能仪器科技有限公司 Gas detection system, detection method and gas detection device in transformer oil

Families Citing this family (30)

* Cited by examiner, † Cited by third party
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EP0931762B1 (en) * 1998-01-21 2005-05-04 Haldor Topsoe A/S Process for the preparation of hydrogen-rich gas
DE19945668B4 (en) * 1999-09-23 2004-10-07 Siemens Ag Method for starting a PEM fuel cell system and PEM fuel cell system for performing the method
JP4817476B2 (en) * 1999-09-29 2011-11-16 京セラ株式会社 Solid oxide fuel cell
DE19963008B4 (en) * 1999-12-24 2009-07-02 Robert Bosch Gmbh Sensor element of a gas sensor for the determination of gas components
JP2001185190A (en) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc Producing method of hydrogen for fuel cell
JP2001185192A (en) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc Producing method of hydrogen for fuel cell
JP2001185191A (en) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc Producing method of hydrogen for fuel cell
JP4763870B2 (en) * 1999-12-28 2011-08-31 三菱瓦斯化学株式会社 Production method of hydrogen for fuel cell
JP4688263B2 (en) * 2000-08-30 2011-05-25 京セラ株式会社 Solid electrolyte fuel cell and starting method thereof
DE10053986A1 (en) * 2000-10-31 2002-05-08 Forschungszentrum Juelich Gmbh Introducing and removing hydrogen using an electrically contacted proton conductor, comprises applying a current to the conductor so that protons are generated at an anode and recombining the protons at a cathode to form hydrogen
JP4730635B2 (en) * 2001-03-21 2011-07-20 独立行政法人産業技術総合研究所 Hydrocarbon gas sensor and hydrocarbon gas concentration measuring method
JP2003031255A (en) * 2001-07-18 2003-01-31 Matsushita Electric Ind Co Ltd Fuel cell power generation device and feeding method of condensate to water storage tank
JP5200312B2 (en) 2001-09-03 2013-06-05 富士通株式会社 Electronics
JP4743375B2 (en) * 2001-09-12 2011-08-10 独立行政法人産業技術総合研究所 Flammable gas concentration measurement method
JP5088996B2 (en) * 2001-09-27 2012-12-05 中国電力株式会社 Reversible cogeneration system
JP4695826B2 (en) * 2002-06-06 2011-06-08 パナソニック株式会社 Solid oxide fuel cell
US6977121B2 (en) * 2003-04-03 2005-12-20 Utc Fuel Cells, Llc Fuel cell power plant having a fuel concentration sensor cell
US20070184311A1 (en) * 2003-06-30 2007-08-09 Shuichi Ohkubo Fuel cell with reformer
US7252900B2 (en) 2003-09-09 2007-08-07 Plug Power Inc. Combination fuel cell and ion pump, and methods and infrastructure systems employing same
GB2411043B (en) * 2004-02-10 2007-09-19 Ceres Power Ltd A method and apparatus for operating an intermediate-temperature solid-oxide fuel cell stack
JP2005268056A (en) * 2004-03-18 2005-09-29 Central Japan Railway Co Hydrogen supply system and fuel cell system
US8158286B2 (en) 2005-08-17 2012-04-17 Honda Motor Co., Ltd. Energy stations
WO2007105291A1 (en) * 2006-03-13 2007-09-20 Fujitsu Limited Fuel cell
JP5491284B2 (en) * 2010-05-28 2014-05-14 日本電信電話株式会社 FUEL CELL SYSTEM AND METHOD FOR OPERATING FUEL CELL SYSTEM
JP5652602B2 (en) * 2010-09-24 2015-01-14 独立行政法人物質・材料研究機構 Electrolyte material for solid fuel cell and method for producing the same
JP5525463B2 (en) * 2011-01-18 2014-06-18 日本電信電話株式会社 Air electrode material for solid oxide fuel cell and solid oxide fuel cell
JP2013008689A (en) * 2012-08-29 2013-01-10 Ngk Spark Plug Co Ltd Fuel cell
JP6709974B2 (en) * 2018-05-15 2020-06-17 パナソニックＩｐマネジメント株式会社 Electrochemical device and hydrogen system
EP3978651A4 (en) * 2019-05-27 2022-12-21 Panasonic Intellectual Property Management Co., Ltd. Electrochemical device and hydrogen generation method
DE102021203538A1 (en) 2021-04-09 2022-10-13 Robert Bosch Gesellschaft mit beschränkter Haftung Fuel cell system and method for operating the fuel cell system

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Publication number Priority date Publication date Assignee Title
US5244753A (en) * 1990-05-29 1993-09-14 Matsushita Electric Industrial Co., Ltd. Solid electrolyte fuel cell and method for manufacture of same
US5314508A (en) * 1990-05-29 1994-05-24 Matsushita Electric Industrial Co., Ltd. Solid electrolyte fuel cell and method for manufacture of same
KR0165651B1 (en) * 1995-09-28 1999-03-30 모리시타 요이치 Electrochemical devices
DE19634645C2 (en) * 1996-08-27 1999-11-11 Forschungszentrum Juelich Gmbh Layer sequence with a high-temperature superconducting material and their use

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9958338B2 (en) 2011-10-25 2018-05-01 Guenther Heisskanaltechnik Gmbh Thermocouple with a heater on a substrate
RU2543071C1 (en) * 2014-03-19 2015-02-27 Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук Fabrication method of electrodes in cells with solid electrolyte
EP3425088A1 (en) * 2017-07-05 2019-01-09 Panasonic Intellectual Property Management Co., Ltd. Hydrogen supply system
US10722841B2 (en) 2017-07-05 2020-07-28 Panasonic Intellectual Property Management Co., Ltd. Hydrogen supply system
CN114509472A (en) * 2022-04-19 2022-05-17 佛山速敏智能仪器科技有限公司 Gas detection system, detection method and gas detection device in transformer oil

Also Published As

Publication number Publication date
CA2232737C (en) 2005-06-14
DE19814106A1 (en) 1998-10-22
JP3680232B2 (en) 2005-08-10
DE19814106B4 (en) 2004-08-05
JPH10284108A (en) 1998-10-23

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