CA2155852C - Particulate detergent, bleaching or cleaning compositions containing aluminosilicates - Google Patents

Particulate detergent, bleaching or cleaning compositions containing aluminosilicates

Info

Publication number: CA2155852C
Authority: CA; Canada
Prior art keywords: zeolite; sodium; bleach; ammonium; exchanged
Prior art date: 1993-04-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002155852A

Other languages

English (en)

French (fr)

Other versions

CA2155852A1 (en

Inventor

Andrew Paul Chapple

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-04-19

Filing date

1994-04-07

Publication date

1999-05-11

1994-04-07 Application filed by Unilever PLC filed Critical Unilever PLC

1994-10-27 Publication of CA2155852A1 publication Critical patent/CA2155852A1/en

1999-05-11 Application granted granted Critical

1999-05-11 Publication of CA2155852C publication Critical patent/CA2155852C/en

2014-04-07 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 60
239000003599 detergent Substances 0.000 title claims abstract description 44
229910000323 aluminium silicate Inorganic materials 0.000 title claims abstract description 17
238000004061 bleaching Methods 0.000 title claims abstract description 11
238000004140 cleaning Methods 0.000 title claims abstract description 6
239000010457 zeolite Substances 0.000 claims abstract description 170
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 150
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 137
239000007844 bleaching agent Substances 0.000 claims abstract description 54
239000004615 ingredient Substances 0.000 claims abstract description 37
150000001768 cations Chemical class 0.000 claims abstract description 27
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 23
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims abstract description 19
229940045872 sodium percarbonate Drugs 0.000 claims abstract description 19
-1 hydrogen ions Chemical class 0.000 claims abstract description 18
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 11
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
239000001257 hydrogen Substances 0.000 claims abstract description 11
229910052744 lithium Inorganic materials 0.000 claims abstract description 11
239000004094 surface-active agent Substances 0.000 claims description 13
239000004411 aluminium Substances 0.000 claims description 9
229910052782 aluminium Inorganic materials 0.000 claims description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
229910052710 silicon Inorganic materials 0.000 claims description 6
239000010703 silicon Substances 0.000 claims description 6
239000003054 catalyst Substances 0.000 abstract description 33
239000011734 sodium Substances 0.000 description 47
229910052708 sodium Inorganic materials 0.000 description 44
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 43
239000000843 powder Substances 0.000 description 37
239000008187 granular material Substances 0.000 description 25
238000000034 method Methods 0.000 description 22
239000011572 manganese Substances 0.000 description 19
229910001868 water Inorganic materials 0.000 description 16
230000000052 comparative effect Effects 0.000 description 15
239000002243 precursor Substances 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
239000002585 base Substances 0.000 description 12
229910052748 manganese Inorganic materials 0.000 description 11
239000000463 material Substances 0.000 description 11
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
239000002736 nonionic surfactant Substances 0.000 description 10
239000000344 soap Substances 0.000 description 10
239000002253 acid Substances 0.000 description 9
230000008901 benefit Effects 0.000 description 9
150000001875 compounds Chemical class 0.000 description 9
238000002845 discoloration Methods 0.000 description 9
239000003446 ligand Substances 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 7
238000005342 ion exchange Methods 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
239000000243 solution Substances 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
125000003118 aryl group Chemical group 0.000 description 6
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
150000004965 peroxy acids Chemical class 0.000 description 6
239000000047 product Substances 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
238000009472 formulation Methods 0.000 description 5
230000006872 improvement Effects 0.000 description 5
229910052742 iron Inorganic materials 0.000 description 5
239000002002 slurry Substances 0.000 description 5
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
239000011230 binding agent Substances 0.000 description 4
229910001424 calcium ion Inorganic materials 0.000 description 4
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
239000011521 glass Substances 0.000 description 4
238000005469 granulation Methods 0.000 description 4
230000003179 granulation Effects 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
238000002156 mixing Methods 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
150000004967 organic peroxy acids Chemical class 0.000 description 4
239000002245 particle Substances 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 3
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
239000012190 activator Substances 0.000 description 3
239000000654 additive Substances 0.000 description 3
230000000996 additive effect Effects 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
229940096386 coconut alcohol Drugs 0.000 description 3
150000004966 inorganic peroxy acids Chemical class 0.000 description 3
239000007788 liquid Substances 0.000 description 3
229910001437 manganese ion Inorganic materials 0.000 description 3
239000004570 mortar (masonry) Substances 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
229920005646 polycarboxylate Polymers 0.000 description 3
230000008569 process Effects 0.000 description 3
150000003254 radicals Chemical class 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
239000004408 titanium dioxide Substances 0.000 description 3
ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229920006243 acrylic copolymer Polymers 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
239000011575 calcium Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000013078 crystal Substances 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
LVZAVNQYRZXWLS-UHFFFAOYSA-N dodecaaluminum dodecasodium oxygen(2-) silicon(4+) heptacosahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4].[Si+4] LVZAVNQYRZXWLS-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
238000007580 dry-mixing Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
229940071106 ethylenediaminetetraacetate Drugs 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
229920001983 poloxamer Polymers 0.000 description 2
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 2
239000001103 potassium chloride Substances 0.000 description 2
235000011164 potassium chloride Nutrition 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
239000002994 raw material Substances 0.000 description 2
150000004671 saturated fatty acids Chemical class 0.000 description 2
239000003352 sequestering agent Substances 0.000 description 2
QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 2
229960001922 sodium perborate Drugs 0.000 description 2
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
239000007787 solid Substances 0.000 description 2
241000894007 species Species 0.000 description 2
239000007858 starting material Substances 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
238000005406 washing Methods 0.000 description 2
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
HYZQBNDRDQEWAN-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;manganese(3+) Chemical compound [Mn+3].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O HYZQBNDRDQEWAN-LNTINUHCSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
LVVZBNKWTVZSIU-UHFFFAOYSA-N 2-(carboxymethoxy)propanedioic acid Chemical class OC(=O)COC(C(O)=O)C(O)=O LVVZBNKWTVZSIU-UHFFFAOYSA-N 0.000 description 1
WREFNFTVBQKRGZ-UHFFFAOYSA-N 2-decylbutanediperoxoic acid Chemical compound CCCCCCCCCCC(C(=O)OO)CC(=O)OO WREFNFTVBQKRGZ-UHFFFAOYSA-N 0.000 description 1
LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 description 1
FCZZQVBGZFNATF-UHFFFAOYSA-N 6-(octylamino)-6-oxohexaneperoxoic acid Chemical compound CCCCCCCCNC(=O)CCCCC(=O)OO FCZZQVBGZFNATF-UHFFFAOYSA-N 0.000 description 1
ITCICEGAURIGTM-UHFFFAOYSA-N 6-aminohexaneperoxoic acid Chemical compound NCCCCCC(=O)OO ITCICEGAURIGTM-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
229910002012 Aerosil® Inorganic materials 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
FYJQFTDDXICKAM-UHFFFAOYSA-N CC[Na].OC(OC(C=C1)=CC=C1S(O)(=O)=O)=O.Cl Chemical compound CC[Na].OC(OC(C=C1)=CC=C1S(O)(=O)=O)=O.Cl FYJQFTDDXICKAM-UHFFFAOYSA-N 0.000 description 1
101100225553 Caenorhabditis elegans epg-4 gene Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
229940120146 EDTMP Drugs 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 description 1
241000257303 Hymenoptera Species 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical class OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
241000950638 Symphysodon discus Species 0.000 description 1
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
239000001166 ammonium sulphate Substances 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
238000001479 atomic absorption spectroscopy Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
150000004696 coordination complex Chemical class 0.000 description 1
239000011162 core material Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
239000004148 curcumin Substances 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
UNWDCFHEVIWFCW-UHFFFAOYSA-N decanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCC(=O)OO UNWDCFHEVIWFCW-UHFFFAOYSA-N 0.000 description 1
238000000280 densification Methods 0.000 description 1
BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
239000004744 fabric Substances 0.000 description 1
150000002194 fatty esters Chemical class 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
229930182478 glucoside Natural products 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
150000002431 hydrogen Chemical group 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
238000007654 immersion Methods 0.000 description 1
229910052610 inosilicate Inorganic materials 0.000 description 1
150000004698 iron complex Chemical class 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
159000000002 lithium salts Chemical class 0.000 description 1
235000001055 magnesium Nutrition 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000002304 perfume Substances 0.000 description 1
125000005342 perphosphate group Chemical group 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical class [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
YDLQSTFHBCVEJV-UHFFFAOYSA-M sodium;2-(3,5,5-trimethylhexanoyloxy)benzenesulfonate Chemical compound [Na+].CC(C)(C)CC(C)CC(=O)OC1=CC=CC=C1S([O-])(=O)=O YDLQSTFHBCVEJV-UHFFFAOYSA-M 0.000 description 1
OVONNAXAHAIEDF-UHFFFAOYSA-M sodium;4-benzoyloxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC(=O)C1=CC=CC=C1 OVONNAXAHAIEDF-UHFFFAOYSA-M 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
125000005156 substituted alkylene group Chemical group 0.000 description 1
125000005650 substituted phenylene group Chemical group 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA002155852A 1993-04-19 1994-04-07 Particulate detergent, bleaching or cleaning compositions containing aluminosilicates Expired - Lifetime CA2155852C (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
GB939308047A GB9308047D0 (en)	1993-04-19	1993-04-19	Particulate detergent,bleaching or cleaning compositions containing aluminosilicates
GB9308047.1		1993-04-19
PCT/EP1994/001115 WO1994024251A1 (en)	1993-04-19	1994-04-07	Particulate bleaching or cleaning compositions containing aluminosilicates

Publications (2)

Publication Number	Publication Date
CA2155852A1 CA2155852A1 (en)	1994-10-27
CA2155852C true CA2155852C (en)	1999-05-11

Family

ID=10734075

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002155852A Expired - Lifetime CA2155852C (en)	1993-04-19	1994-04-07	Particulate detergent, bleaching or cleaning compositions containing aluminosilicates

Country Status (17)

Country	Link
EP (1)	EP0695341B1 (pt)
JP (1)	JP2677710B2 (pt)
AU (1)	AU684769B2 (pt)
BR (1)	BR9406174A (pt)
CA (1)	CA2155852C (pt)
CZ (1)	CZ290131B6 (pt)
DE (1)	DE69407405T2 (pt)
ES (1)	ES2110232T3 (pt)
GB (1)	GB9308047D0 (pt)
HU (1)	HU217991B (pt)
IN (1)	IN181903B (pt)
MY (1)	MY116334A (pt)
PL (1)	PL177828B1 (pt)
SK (1)	SK281006B6 (pt)
TW (1)	TW333556B (pt)
WO (1)	WO1994024251A1 (pt)
ZA (1)	ZA942679B (pt)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2299097A (en) *	1995-03-24	1996-09-25	Procter & Gamble	Detergent composition
US6235704B1 (en)	1997-07-30	2001-05-22	Basf Aktiengesellschaft	Solid textile detergent formulation based on glycin-N and N-Diacetic acid derivatives
MY133398A (en) *	1999-07-09	2007-11-30	Colgate Palmolive Co	Fabric cleaning composition containing zeolite
BR0016210B1 (pt)	1999-12-08	2013-10-29		Composição detergente em barra
WO2003093405A2 (en) *	2002-05-02	2003-11-13	The Procter & Gamble Company	Detergent compositions and components thereof
TW201031743A (en)	2008-12-18	2010-09-01	Basf Se	Surfactant mixture comprising branched short-chain and branched long-chain components
WO2011003904A1 (de)	2009-07-10	2011-01-13	Basf Se	Tensidgemisch mit kurz- und langkettigen komponenten
US20110237484A1 (en)	2010-03-25	2011-09-29	Basf Se	Electrochemical textile-washing process
MX2012010906A (es)	2010-03-25	2012-10-09	Basf Se	Metodo de lavado electroquimico de textiles.
US20150182960A1 (en) *	2013-12-31	2015-07-02	Ecowater Systems Llc	Zeolite regeneration
EP3724310A4 (en)	2017-12-15	2021-07-21	Rhodia Operations	COMPOSITION WITH LANTHANIDE METAL COMPLEX

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2902236A1 (de) *	1978-01-25	1979-07-26	Kao Corp	Bleichmittelmischung
JPS54100406A (en) *	1978-01-25	1979-08-08	Kao Corp	Bleaching detergent composition comprising aluminosilicate
JPS5858286B2 (ja) *	1979-08-07	1983-12-24	水澤化学工業株式会社	分散性に優れたゼオライトビルダ−の製造方法
ZA805231B (en) *	1980-05-19	1981-08-26	Mobil Oil Corp	Low acidity alkali metal containing zeolites
US4389325A (en) *	1982-01-25	1983-06-21	Monsanto Company	Chloroisocyanurate compositions
JPS6291240A (ja) *	1985-06-05	1987-04-25	Toyo Soda Mfg Co Ltd	モルデナイトのリチウムイオン交換方法
GB8823705D0 (en) *	1988-10-10	1988-11-16	Unilever Plc	Liquid detergent products
ES2100924T3 (es) *	1990-05-21	1997-07-01	Unilever Nv	Activacion de blanqueador.
JPH04219135A (ja) *	1990-12-19	1992-08-10	Kobe Steel Ltd	分子篩性吸着材
GB9104547D0 (en) *	1991-03-05	1991-04-17	Unilever Plc	Detergent compositions

1993
- 1993-04-19 GB GB939308047A patent/GB9308047D0/en active Pending
1994
- 1994-04-07 CA CA002155852A patent/CA2155852C/en not_active Expired - Lifetime
- 1994-04-07 AU AU65669/94A patent/AU684769B2/en not_active Expired
- 1994-04-07 EP EP94913571A patent/EP0695341B1/en not_active Expired - Lifetime
- 1994-04-07 HU HU9501986A patent/HU217991B/hu unknown
- 1994-04-07 JP JP6522722A patent/JP2677710B2/ja not_active Expired - Lifetime
- 1994-04-07 BR BR9406174A patent/BR9406174A/pt not_active IP Right Cessation
- 1994-04-07 PL PL94311163A patent/PL177828B1/pl unknown
- 1994-04-07 ES ES94913571T patent/ES2110232T3/es not_active Expired - Lifetime
- 1994-04-07 CZ CZ19952430A patent/CZ290131B6/cs not_active IP Right Cessation
- 1994-04-07 WO PCT/EP1994/001115 patent/WO1994024251A1/en active IP Right Grant
- 1994-04-07 SK SK1036-95A patent/SK281006B6/sk not_active IP Right Cessation
- 1994-04-07 DE DE69407405T patent/DE69407405T2/de not_active Expired - Lifetime
- 1994-04-18 IN IN166BO1994 patent/IN181903B/en unknown
- 1994-04-18 MY MYPI94000929A patent/MY116334A/en unknown
- 1994-04-19 ZA ZA942679A patent/ZA942679B/xx unknown
- 1994-06-28 TW TW083105848A patent/TW333556B/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
EP0695341B1 (en)	1997-12-17
CA2155852A1 (en)	1994-10-27
GB9308047D0 (en)	1993-06-02
SK281006B6 (sk)	2000-10-09
HU9501986D0 (en)	1995-09-28
DE69407405D1 (de)	1998-01-29
HUT73065A (en)	1996-06-28
PL311163A1 (en)	1996-02-05
JPH08504876A (ja)	1996-05-28
HU217991B (hu)	2000-05-28
DE69407405T2 (de)	1998-04-09
MY116334A (en)	2004-01-31
IN181903B (pt)	1998-10-31
AU6566994A (en)	1994-11-08
CZ290131B6 (cs)	2002-06-12
EP0695341A1 (en)	1996-02-07
CZ243095A3 (en)	1996-01-17
SK103695A3 (en)	1995-12-06
ES2110232T3 (es)	1998-02-01
AU684769B2 (en)	1998-01-08
TW333556B (en)	1998-06-11
JP2677710B2 (ja)	1997-11-17
PL177828B1 (pl)	2000-01-31
ZA942679B (en)	1995-10-19
WO1994024251A1 (en)	1994-10-27
BR9406174A (pt)	1996-01-09

Publication	Publication Date	Title
US5409627A (en)	1995-04-25	Particulate bleaching detergent compositions containing zeolite map and a stable bleach catalyst
EP1558717B1 (en)	2008-12-24	Laundry detergent composition
EP0111963B1 (en)	1988-09-28	Detergent compositions
EP0552054B1 (en)	1995-11-02	Detergent compositions
CA2155852C (en)	1999-05-11	Particulate detergent, bleaching or cleaning compositions containing aluminosilicates
CA2164107C (en)	2000-10-03	Granular detergent compositions containing zeolite and process for their preparation
WO1995030733A1 (en)	1995-11-16	Bleach catalyst composition
CN105473700B (zh)	2021-11-02	漂白和氧化催化剂
CA2248635C (en)	2006-05-16	Particulate aluminosilicate-built detergent compositions comprising cogranules of zeolite map and alkali metal silicate
EP0616029A1 (en)	1994-09-21	Bleach and detergent compositions
CA2463234C (en)	2010-12-14	Detergent compositions comprising an alkali metal carbonate salt and a water soluble-organic acid
AU725258B2 (en)	2000-10-12	Modified aluminosilicate
AU9048098A (en)	1999-01-07	A process for preparing a granular detergent composition containing zeolite

Legal Events

Date	Code	Title	Description
1995-08-28	EEER	Examination request
2014-06-09	MKEX	Expiry	Effective date: 20140407