CA2150086A1 - Fat-free tablespread - Google Patents
Fat-free tablespreadInfo
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- CA2150086A1 CA2150086A1 CA002150086A CA2150086A CA2150086A1 CA 2150086 A1 CA2150086 A1 CA 2150086A1 CA 002150086 A CA002150086 A CA 002150086A CA 2150086 A CA2150086 A CA 2150086A CA 2150086 A1 CA2150086 A1 CA 2150086A1
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- margarine
- accordance
- oil
- fat
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Abstract
The present invention is directed to a substantially saturated fat-free margarine which includes a substantially saturated food grade oil or fat; from 0 to 5% of a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids; inulin; and water.
Description
._ FAT-FREE TABLESPREAD
Field of the Invention The present invention relates generally to a non-fat product that has the appearance of margarine and squeezable margarine. In particular, the invention relates to a non-fat product that has the appearance and taste of margarine and squeezable margarine, but has substantially fewer calories and has no fat.
Background of the Invention In recent years, there has been a substantial research effort directed to reducing or eliminating the fat in various water continuous food products, such as ice cream, pourable dressings, salad dressing, mayonnaise and cheese. To produce these fat reduced products, many fat mimetic materials have been developed.
U.S. Patent No. 4,734,287 to Singer, et al.
describes a proteinaceous, water-dispersible macrocolloid comprising substantially non-aggregated particles of dairy whey protein. U.S. Patent No. 4,911,946 to Singer, et al.
discloses a fat substitute which comprises water-dispersible macrocolloid particles having a substantially spheroidal shape and a particle size distribution effective to impart the substantially smooth organoleptic character of an oil-and-water emulsion. The particles are produced by subjecting carbohydrate materials such as quinoa starch, calcium alginate, cross-linked dextran, gellan gum, konjac, mannan, chitin, schizophyllan and chitosan to high shear forces by introducing a carbohydrate solution into a highly turbulent reaction zone. This treatment produces gelled microparticles - 2 - 2I5D~
having the spheroidal shape and size described in this patent. U.S. Patent No. 5,104,674 to Chen, et al.
describes fat mimetic materials which are produced by subjecting fibers of a polysaccharide gum and various protein sources to high shear forces to microfragment the particles.
While numerous fat mimetic materials have been produced, such fat mimetic materials are almost universally used in a water continuous product, such as a pourable dressing, mayonnaise or salad dressing. Only recently have attempts been made to produce a non-fat substitute for fat continuous systems, such as butter and margarine. U.S. Patent No. 4,956,193 to Cain, et al.
describes a non-fat edible plastic dispersion which is a substitute for butter or margarine. The edible plastic dispersion of the Cain, et al. patent includes at least two condensed phases, at least one of which is continuous. The dispersion includes two gel forming compositions (A) and (B). Gel forming composition A
contains 1-8 times the critical concentration of a gelling agent (a) selected from the group consisting of gelatin, kappa carrageenan, iota carrageenan, alginate, agar, gellan, pectin and mixtures thereof. Gel forming composition B also contains 1-8 times the critical concentration of a gelling agent (b) selected from the group consisting of gelling starch, denatured whey protein, denatured bovine serum protein, denatured soy protein, microcrystalline cellulose and mixtures thereof.
The present invention is directed to providing non-fat or low-fat substitutes for fat-containing spreads, such as margarine. The present invention is also directed to providing a non-fat or low-fat substitute for margarine products which are known in the art as being "squeezable"; meaning that the product can be dispensed by squeezing a plastic container containing the viscous margarine. Such products are available in 2lsoo86 -the marketplace today containing high levels of fat about 64%.
Description of the Drawings FIGURE 1 is a plot of the gel strength of various materials processed in accordance with the invention;
FIGURE 2 is a plot of gel penetration of a 30%
inulin gel; and FIGURE 3 is a plot of the gel penetration of a 25% inulin/5% starch gel.
Summary of the Invention In accordance with an embodiment of the present invention there is provided a substantially saturated fat-free margarine which comprises (a) a substantially saturated food grade oil, or fat; (b) from O to 5% of a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids;
(c) inulin; and (d) water.
In accordance with another embodiment of the present invention there is provided a non-fat squeezable margarine which comprises (a) a substantially saturated food grade oil, or fat; (b) a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids; (c) gum; and (d) water.
In accordance with still another embodiment of the present invention there is provided a method for manufacture of a substantially fat free margarine comprising providing a mixture of food grade fat or oil, inulin and water and subjecting said mixture to high pressure homogenization of at least about 6,000 psig.
There are also disclosed non-fat edible dispersions which have rheological properties similar to either solid margarine or squeezable margarine. The non-fat dispersions include a fat mimetic selected from the group consisting of gelling type maltodextrins, starch 21~0o86 - 3a -modified by acid hydrolysis, and a branched chain amylopectin starch, an optional bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and low DE corn syrup solids and a texturizing agent, which is inulin.
A non-fat edible dispersion which emulates squeezable margarine can also be prepared from compositions which include a fat mimetic selected from the group consisting of gelling type maltodextrins and starch modified by acid hydrolysis, a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and low DE corn syrup solids and a gum.
Detailed Description of the Invention The fat mimetics useful in both the non-fat margarine type formulation and the non-fat squeezable formulation are selected from the group consisting of gelling type maltodextrins, starch modified by acid hydrolysis and branched chain amylopectin starch. An example of a gelling type maltodextrin is marketed under 21 ~008~
_ 4 the tradename PaselliTM by the Avebe Company of the Netherlands. PaselliTM is a potato starch enzymatically modified to produce a maltodextrin having a very low DE, below 5.
Starch modified by acid hydrolysis is a Naegeli amylodextrin. Naegeli amylodextrin is produced by suspending starch granules in 7.5~ to 15~ sulfuric acid and holding the starch at room temperature to 35 C. for several days. During the process, there is gradual erosion of the starch and conversion of the amorphous amylose regions to soluble sugars. The main crystalline granule structure remains intact and is substantially amylopectin, preferably at least 95~ amylopectin. An example of a starch modified by acid hydrolysis is StellarTM, manufactured by A.E. Staley Company. StellarTM
is made by sequential acid hydrolysis and fractionation of granular amylose-amylopectin starch materials. The DE
of StellarTM is between about 6 to 10.
Branched chain amylopectin starches are obtained from waxy grains and are generally referred to as waxy maize starches. Waxy maize starches have substantially no straight chain amylose starch.
The fat mimetic is used in the spreadable margarine type formulation of the present invention at a level of from about 3.5~ to about 8~ and in the squeezable margarine formulation at a level of from about 4~ to about 10~. All percentages used herein are by weight based on the margarine product unless otherwise indicated.
Inulin is present in the non-fat spreadable margarine product and squeezable margarine at a level of from about 10~ to about 50~. At levels above about 23~, however, the inulin imparts a sweet taste which may be undesirable in some products. The inulin is functional to impart the desired properties of the non-fat margarine substitute of the present invention without any modifying 21 S~08b' components. In an important embodiment of the present invention, it has been determined that the apparent sweetness of inulin can be reduced if calcium citrate or microreticulated microcrystalline cellulose is added to the formulation. The calcium citrate utilized is preferably of the type described in U.S. Patent No.
5,149,552, which issued on September 22, 1992. The calcium citrate of this patent has the formula:
Can (C6H507) 2; wherein n is a value from 2.5 to 2.95.
Microreticulated microcrystalline cellulose is produced by subjecting an aqueous dispersion of microcrystalline cellulose to high pressure homogenization. This process is fully described in U.S.
Patent No. 5,011,701 to Baer, et al. The calcium citrate or microreticulated microcrystalline cellulose, if used, is present at a level of from about 0.75~ to about 3~.
It has also been determined that the sodium salt of racemic 2-(4-methoxyphenoxy) propionic acid can be used to reduce the sweetness of inulin and also mask the starchy flavors of those compositions containing starch. The propanoate salt is used at a level of from about 50 ppm to about 200 ppm.
Inulin is a polysaccharide derived from various plant tubers, such as dahlia, jerusalem artichokes and chicory. Inulin is a polysaccharide of fructose units with a molecular weight of about 5,000. The molecular weight of inulin is dependent upon its source.
Bulking agents useful for both the non-fat margarine type product and the non-fat squeezable product are selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids having a DE of from about 24 to about 42. The bulking agent is present in the non-fat spreadable margarine product and squeezable margarine formulations which contain inulin at a level of from about 0 to about 5~. That is, the bulking agent is optional in the non-fat formulations 21~0o8~
containing inulin. If used in these formulations, the bulking agent is present at a level of from about 1~ to about 5~. The bulking agent is present in the non-fat squeezable margarine product which does not contain inulin at a level of from about 5~ to about 10~.
A gum is used in the non-fat squeezable margarine produced with an enzyme modified starch and a bulking agent, but is optional in the non-fat spreadable margarine and squeezable margarine produced with acid modified starch and inulin. The gum is present at a level of from about 0.1~ to about 2.0~, preferably from about 0.4~ to about 1.75~. The gum may be selected from any of the food grade gums, such as xanthan gum, guar gum, gum acacia, alginates, carrageenans, pectins and gelatin. The preferred gum is xanthan gum.
The non-fat margarine and squeezable margarine of the present invention also contain salt at a level of from about 1.0~ to about 2.5~. The formulations may also contain vitamins, preservatives, flavoring components and coloring components. Water is present at a level of from about 65~ to about 85~.
While a typical spreadable and squeezable margarine type texture and flavor can be attained without the presence of any fat, fats and oils can be included in the formulations at levels up to about 15~, if desired.
Suitable fats include butterfat, vegetable oils hydrogenated vegetable oils, flavored oils known as butter oils and non-digestible fats and oils, such as polyol fatty acid esters, particularly fatty acid esters of sucrose. If used, the fat and oil may be present at a level of from about 0.5~ to about 60~. At levels of fat above about 15~, an emulsifier is required.
Suitable emulsifiers for tablespreads include mono- and di-glycerides, lactic acid esters of monoglycerides, diacetyl tartaric acid esters of monoglycerides (DATEM), propylene glycol esters of 2l~oo86 monoglycerides (PGME), succinylated monoglycerides (SMG), ethoxylated monoglycerides, sodium stearoyl-2-lactylate, polyglycerol esters of saturated fatty acids, Polysorbate 60, Polyglycerate 60 (ethoxylated mono- and diglycerides), mono-, di- and tri- fatty acid esters of sucrose, lecithin, including modified lecithin. Th emulsifier or combination of emulsifiers is used at a level in the range of 0.2 - 12~, basis the fat in the product.
The compositions of the present invention are particularly suitable for marketing a spread which is labeled as a saturated fat-free spread. Under FDA
requirements in the United States, a spread labeled as being saturated fat-free must have less than 0.5 grams of saturated fat per one tablespoon serving. This requirement can be met utilizing various levels of fats and oils. For example, only 5~ butterfat can be present in the composition to meet the 0.5 gram requirement, whereas 45~ of canola oil could be used and still meet the 0.5 gram requirement. Other vegetable oils can be used at various levels within the range of 5~ to 60~ to meet the requirement of 0.5 grams of saturated fat.
Suitable fats and oils include canola oil, soybean oil, corn oil, butterfat, sunflower oil and safflower oil.
In the manufacture of the non-fat spreadable margarine, squeezable margarine containing inulin, a salt solution is first prepared in a holding tank. The preservatives used are also combined with the salt in the salt solution. In general, the salt solution will contain from about 1~ to about 5~ salt. The salt solution is pumped to a second tank where it is mixed with the fat mimetic, the bulking agent, if used, the inulin and any flavors and colorants. The salt solution and other components are metered into the batch mix tank at levels sufficient to provide the desired levels in the finished product.
21~0o8~
After being combined in the batch mix tank, the non-fat spreadable formulation is pumped to a high pressure homogenizer, such as a Rannie homogenizer. It has been determined that the non-fat margarine product S must be processed at a pressure above 6,000 psig to obtain the rheological properties desired in the finished product. The gel strength is rapidly reduced at homogenization pressures below about 6,000 psig.
Homogenization pressures of from about 8,000 psig to about 15,000 psig are desirable. The non-fat margarine product after being homogenized is transferred to the holding tank. Since substantial heat is developed during processing through the high pressure homogenization apparatus, the formulation is then pumped through cooling heat exchangers prior to being packaged at a temperature of 60 F. to provide a non-fat spreadable margarine after a holding period of refrigerated storage at a temperature of from about 35 F. to about 50 F. for from about 10 - hours to about 30 hours.
As shown in FIGURE 1, the gel strength of various materials after being processed in accordance with the above method is shown. As can be seen, the gel strength of the fat mimetic, StellarTM is 0. The gel strength of inulin is 84.5. The combination of 25%
25 inulin and 5% StellarTM is 130.4. This shows that the StellarTM reacts synergistically with the inulin to cause an increase in gel strength of greater than 50%. As shown in FIGURE 2, the gel penetration of a 30% inulin composition displays a brittle profile as seem by the sharp break at the point (1). A composition wherein 5~
of the inulin is replaced with StellarTM displays a smooth non-brittle profile, as seen in FIGURE 3.
The non-fat squeezable margarine without inulin is prepared by a different method. The fat mimetic is first placed into solution and heated to a temperature of about 190 F. to activate the fat mimetic. The fat 2I~oo8~
mimetic is then held in a tank for subsequent formulation. The xanthan gum and bulking agent are mixed in a second tank and held for use in preparing the formulation. A salt solution is prepared in a third tank and is held for preparing the formulation. The three mixtures are proportloned into a fourth tank in proportions sufficient to prepare the final formulation.
The colors and flavors are metered into the fourth tank in suitable amounts. Thereafter, the mixture is processed through a high shear mixer, such as a PentaxTM
mixer, which is a horizontal rotating pin type mixer. It should be understood that high shear mixing is to be distinguished from high shear homogenization. High shear homogenization imparts much more shear force than does lS high shear mixing. The mixture is then transferred to a holding tank from which it is pumped to a cooling heat exchange apparatus prior to being packaged at a temperature of 60 F. The non-fat squeezable margarine product is then held at refrigeration temperatures of from about 35 F. to about 50 F. for a period of between about 10 and about 21 days prior to developing the desired rheological properties similar to that of spreadable full fat margarine.
The following examples further illustrate various features of the invention, but are intended to in no way limit the scope of the invention, which is set forth in the appended claims.
Example 1 A non-fat spreadable margarine type product was 0 prepared from the components set forth in Table 1.
Table 1 Ingredients Percentages Water 70.1755 Inulin 20.0000 StellarTM modified starch 5.0000 Calcium Citrate 1.5000 21Soo8~
Vitamin A (Type 250-S) 0.0148 Salt (Sodium Chloride)2.0000 Sodium Benzoate 0.0500 Potassium Sorbate 0.0500 5 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.2500 Titanium Dioxide (TiO2)0.1000 Yellow #5 0.0016 Yellow #6 0.0006 Mouthfeel (MV04) 0.1500 Butter Flavor 0.7000 TOTAL 100.0000~
The non-fat spreadable margarine was prepared by combining 15% of the water with the salt, the potassium sorbate, the sodium benzoate and the calcium disodium EDTA in a holding tank to provide a salt solution. The salt solution was maintained at a temperature of 120 F. The salt solution was metered, along with the inulin, the StellarTM, the flavor and color components and the remaining water, into a batch mix tank. The mixture was pumped through a Rannie homogenizer and was homogenized at a pressure of 11,000 psig. The formulation emerged from the Rannie homogenizer at a temperature of 150 F. The formulation 2S was transferred to a holding tank and was pumped through cooling heat exchangers to reduce the temperature to 60 F. for packaging. The spreadable margarine formulation was held at a refrigeration temperature of 40 F. for 1 day to attain the desired rheological properties similar to full fat margarine.
Example 2 A non-fat squeezable margarine type product was prepared from the components set forth in Table 2.
Table 2 35 Ingredients Percentages Water 77.9326 Inulin 12.0000 StellarTM modified starch 5.0000 Flavor 2.9000 Salt 2.0000 21SDO~
Lactic Acid 0.0650 Sodium Benzoate 0.0500 Potassium Sorbate 0.0500 Yellow #5 0.0016 Yellow #6 0.0008~
TOTAL 100.0000%
The non-fat squeezable margarine was prepared by combining 15~ of the water with the salt, the potassium sorbate and the sodium benzoate and the calcium disodium EDTA in a holding tank to provide a salt solution. The salt solution was maintained at a temperature of 120 F. The salt solution was metered, along with the inulin, the StellarTM, the flavor and color components and the remaining water, into a batch mix tank. The mixture was pumped through a Rannie homogenizer and was homogenized at a pressure of 11,000 psi. The formulation emerged from the Rannie homogenizer at a temperature of 150 F. The formulation was transferred to a holding tank and was pumped through cooling heat exchangers to reduce the temperature to 60 F. for packaging. The spreadable margarine formulation was held at a refrigeration temperature of 40 F. for 1 day to attain the desired rheological properties.
Example 3 A non-fat squeezable type margarine product was prepared from the formulation set forth hereinbelow in Table 3.
Table 3 30 Ingredients Percentages Water 79.3685 Paselli SA2TM gelling maltodextrin 8.0000 Lodex 15TM non-gelling maltodextrin 8.5000 Xanthan gum 0.5000 Vitamin A 0.0148 Salt 2.0000 Sodium Benzoate 0.0500 21~00~
Potassium Sorbate 0.5000 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.1570 Yellow #5 0.0016 S Yellow #6 0.0006 Sucrose 0.5000 Mouthfeel (MVO4) 0.1500 Butter Flavor 0.7000~
TOTAL 100.0000%
The non-fat squeezable margarine was prepared as follows: The Paselli SA2TM gelling type maltodextrin was added to a mixing tank along with 30~ of the water.
The mixture was stirred and heated to a temperature of 190 F. until required for use. The xanthan gum and non-gelling maltodextrin were added to a second holding tank with 25% of the water and were stirred to provide a mixture. The salt, potassium sorbate, sodium benzoate and calcium disodium EDTA were added to a third mixing tank with the remaining water and were stirred to provide a solution. The Paselli SATM mixture, the xanthan gum mixture and the salt solution were proportioned to a fourth mixing tank where the flavors and colorants were added. The mixture was then processed through a PentaxTM
high shear mixer and transferred to a holding tank. The mixture was transferred through a cooling heat exchanger to provide a temperature of 60 F. and was packaged into squeezable margarine type containers. The containers were held at refrigeration temperatures for 15 days to provide the desired rheological properties.
Example 4 A non-fat spreadable margarine type product was prepared from the components set forth in Table 4 using the procedure of Example 1.
Table 4 35 InqredientsPercentaqes Water 74.3255 Inulin 17.0000 StellarTM modified starch 4.0000 Waxy Maize Starch 1.5000 Vitamin A 0.0148 Salt 0.0500 Sodium Benzoate 0.0500 5 Potassium Sorbate 0.0500 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.2500 Titanium Dioxide (TiO2)0.1000 Yellow #5 0.0016 Yellow #6 0.0006 Butter Flavor 0.7000 TOTAL 100.0000~
The non-fat margarine prepared from the above components including a waxy maize starch had rheological and organoleptic properties similar to full fat margarine.
Example 5 A non-fat spreadable margarine type product was prepared from the components set forth in Table 5 using the procedure of Example 1.
Table 5 Ingredients Percentages Water 74.3255%
Inulin 17.0000 StellarTM modified starch 4.0000 Microreticulated Micro-crystalline cellulose1.5000 Vitamin A 0.0148 Salt 2.0000 Sodium Benzoate 0.0500 Potassium Sorbate 0.0500 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.2500 Titanium Dioxide (TiO2)0.1000 Yellow #5 0.0016 Yellow #6 0.0006 Butter Flavor 0.7000 TOTAL 100.0000~
The non-fat margarine prepared from the above components, including microreticulated microcrystalline cellulose had rheological and organoleptic properties similar to full fat margarine.
21Soo86 Example 6 In accordance with one embodiment of the present invention, a saturated fat-free tablespread was prepared utilizing an oil submix and a salt submix in preparing the product. The oil submix has the following components at the indicated levels:
Oil Submix %
Canola Oil 88.298 Polysorbate 60 11.198 Vitamin #52 0.336 Flavor #512 0.168 Total 100.000 The salt submix has the following components:
Salt Submix %
Water (45F) 79.336 Salt 19.68 Potassium Sorbate 0.492 Sodium Benzoate 0.492 Total 100.000 40% of the oil mix, 10% of the salt mix, 34%
water, 15% inulin and 1% of minor components were then combined to provide a saturated fat-free tablespread having the following composition:
Ingredient %
Canola Oil 37.123 Water 34.074 Inulin 15.000 Water/Salt Submix 10.166 Oil Submix Solubles 1.786 Cream 1.700 Lactic Acid 0.120 CF #1 (Flavor) 0.025 EDTA 0.006 Total 100.000 The process of preparing the saturated fat-free tablespread involves mixing the inulin, water, oil submix, salt submix and minor components in a propeller type mixing chamber. The mixture is then pumped through a high pressure homogenization step, i.e., a RannieTM homogenizer.
The temperature of the mixture is increased to 126F by passage through the high pressure 2lsoo8~
-homogenizer. The mixture is then pumped to a heat exchanger where the temperature of the mixture is reduced to 45-50F, after which the tablespread is packaged.
Example 7 The process of Example 1 was used to prepare a saturated fat-free tablespread having the following composition:
Ingredient % Weight Inulin - instant 17.000% 17.00#
Water 41.732% 41.73#
Stellar 4.000% 4.00#
Water/Salt 10.166% 10.17#
MRC (9%) 22.200% 22.20#
Vitamin #52 0.006% 2.72g Cream 2.000% 907.20g Butteroil 1.600% 725.76g Lactic acid 0.100% 45.36g HFCS 0.100% 453.60g Cypha 0.0001% 0.05g Starter Distillate 0.180% 81.65g Flavor #33 0.016% 7.26g 100.000% 99.82#
The presence of the propanoate salt provided a tablespread with a reduced sweetness and less starchy flavor as compared to the tablespread of Example 1.
Example 8 The method of claim 1 was used to prepare saturated fat-free tablespreads of one embodiment of the present invention, having the following formulations:
21S~og~
In~redients Batch 1 Batch 2 Batch 3 Wei~ht % Wei~ht % Wei~ht %
Water 24.3060 19.3060 14.0360 Inuline 15.0000 15.0000 15.0000 Soybean Oil 50.0000 55.0000 60.0000 Water/Salt Solution' 10.1660 10.1660 10.1660 Lactic Acid .1000 1000 1000 Color (Bowl) .2000 .2000 .2000 Flavor CF1 .0250 .0250 .0250 Flavor 512 .0030 .0030 .0030 Polysorbate 60 .2000 .2000 .2000 Water/Salt Solution' In~redients Batch 1 Wei~ht %
Water 79.3360 Salt 19.6800 Na Benzoate .4920 K Sorbate .4920 After being packaged, the formulations were held at a refrigeration temperature of 40 F. for 1 day to attain the desired rheological properties of full-fat margarine.
Field of the Invention The present invention relates generally to a non-fat product that has the appearance of margarine and squeezable margarine. In particular, the invention relates to a non-fat product that has the appearance and taste of margarine and squeezable margarine, but has substantially fewer calories and has no fat.
Background of the Invention In recent years, there has been a substantial research effort directed to reducing or eliminating the fat in various water continuous food products, such as ice cream, pourable dressings, salad dressing, mayonnaise and cheese. To produce these fat reduced products, many fat mimetic materials have been developed.
U.S. Patent No. 4,734,287 to Singer, et al.
describes a proteinaceous, water-dispersible macrocolloid comprising substantially non-aggregated particles of dairy whey protein. U.S. Patent No. 4,911,946 to Singer, et al.
discloses a fat substitute which comprises water-dispersible macrocolloid particles having a substantially spheroidal shape and a particle size distribution effective to impart the substantially smooth organoleptic character of an oil-and-water emulsion. The particles are produced by subjecting carbohydrate materials such as quinoa starch, calcium alginate, cross-linked dextran, gellan gum, konjac, mannan, chitin, schizophyllan and chitosan to high shear forces by introducing a carbohydrate solution into a highly turbulent reaction zone. This treatment produces gelled microparticles - 2 - 2I5D~
having the spheroidal shape and size described in this patent. U.S. Patent No. 5,104,674 to Chen, et al.
describes fat mimetic materials which are produced by subjecting fibers of a polysaccharide gum and various protein sources to high shear forces to microfragment the particles.
While numerous fat mimetic materials have been produced, such fat mimetic materials are almost universally used in a water continuous product, such as a pourable dressing, mayonnaise or salad dressing. Only recently have attempts been made to produce a non-fat substitute for fat continuous systems, such as butter and margarine. U.S. Patent No. 4,956,193 to Cain, et al.
describes a non-fat edible plastic dispersion which is a substitute for butter or margarine. The edible plastic dispersion of the Cain, et al. patent includes at least two condensed phases, at least one of which is continuous. The dispersion includes two gel forming compositions (A) and (B). Gel forming composition A
contains 1-8 times the critical concentration of a gelling agent (a) selected from the group consisting of gelatin, kappa carrageenan, iota carrageenan, alginate, agar, gellan, pectin and mixtures thereof. Gel forming composition B also contains 1-8 times the critical concentration of a gelling agent (b) selected from the group consisting of gelling starch, denatured whey protein, denatured bovine serum protein, denatured soy protein, microcrystalline cellulose and mixtures thereof.
The present invention is directed to providing non-fat or low-fat substitutes for fat-containing spreads, such as margarine. The present invention is also directed to providing a non-fat or low-fat substitute for margarine products which are known in the art as being "squeezable"; meaning that the product can be dispensed by squeezing a plastic container containing the viscous margarine. Such products are available in 2lsoo86 -the marketplace today containing high levels of fat about 64%.
Description of the Drawings FIGURE 1 is a plot of the gel strength of various materials processed in accordance with the invention;
FIGURE 2 is a plot of gel penetration of a 30%
inulin gel; and FIGURE 3 is a plot of the gel penetration of a 25% inulin/5% starch gel.
Summary of the Invention In accordance with an embodiment of the present invention there is provided a substantially saturated fat-free margarine which comprises (a) a substantially saturated food grade oil, or fat; (b) from O to 5% of a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids;
(c) inulin; and (d) water.
In accordance with another embodiment of the present invention there is provided a non-fat squeezable margarine which comprises (a) a substantially saturated food grade oil, or fat; (b) a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids; (c) gum; and (d) water.
In accordance with still another embodiment of the present invention there is provided a method for manufacture of a substantially fat free margarine comprising providing a mixture of food grade fat or oil, inulin and water and subjecting said mixture to high pressure homogenization of at least about 6,000 psig.
There are also disclosed non-fat edible dispersions which have rheological properties similar to either solid margarine or squeezable margarine. The non-fat dispersions include a fat mimetic selected from the group consisting of gelling type maltodextrins, starch 21~0o86 - 3a -modified by acid hydrolysis, and a branched chain amylopectin starch, an optional bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and low DE corn syrup solids and a texturizing agent, which is inulin.
A non-fat edible dispersion which emulates squeezable margarine can also be prepared from compositions which include a fat mimetic selected from the group consisting of gelling type maltodextrins and starch modified by acid hydrolysis, a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and low DE corn syrup solids and a gum.
Detailed Description of the Invention The fat mimetics useful in both the non-fat margarine type formulation and the non-fat squeezable formulation are selected from the group consisting of gelling type maltodextrins, starch modified by acid hydrolysis and branched chain amylopectin starch. An example of a gelling type maltodextrin is marketed under 21 ~008~
_ 4 the tradename PaselliTM by the Avebe Company of the Netherlands. PaselliTM is a potato starch enzymatically modified to produce a maltodextrin having a very low DE, below 5.
Starch modified by acid hydrolysis is a Naegeli amylodextrin. Naegeli amylodextrin is produced by suspending starch granules in 7.5~ to 15~ sulfuric acid and holding the starch at room temperature to 35 C. for several days. During the process, there is gradual erosion of the starch and conversion of the amorphous amylose regions to soluble sugars. The main crystalline granule structure remains intact and is substantially amylopectin, preferably at least 95~ amylopectin. An example of a starch modified by acid hydrolysis is StellarTM, manufactured by A.E. Staley Company. StellarTM
is made by sequential acid hydrolysis and fractionation of granular amylose-amylopectin starch materials. The DE
of StellarTM is between about 6 to 10.
Branched chain amylopectin starches are obtained from waxy grains and are generally referred to as waxy maize starches. Waxy maize starches have substantially no straight chain amylose starch.
The fat mimetic is used in the spreadable margarine type formulation of the present invention at a level of from about 3.5~ to about 8~ and in the squeezable margarine formulation at a level of from about 4~ to about 10~. All percentages used herein are by weight based on the margarine product unless otherwise indicated.
Inulin is present in the non-fat spreadable margarine product and squeezable margarine at a level of from about 10~ to about 50~. At levels above about 23~, however, the inulin imparts a sweet taste which may be undesirable in some products. The inulin is functional to impart the desired properties of the non-fat margarine substitute of the present invention without any modifying 21 S~08b' components. In an important embodiment of the present invention, it has been determined that the apparent sweetness of inulin can be reduced if calcium citrate or microreticulated microcrystalline cellulose is added to the formulation. The calcium citrate utilized is preferably of the type described in U.S. Patent No.
5,149,552, which issued on September 22, 1992. The calcium citrate of this patent has the formula:
Can (C6H507) 2; wherein n is a value from 2.5 to 2.95.
Microreticulated microcrystalline cellulose is produced by subjecting an aqueous dispersion of microcrystalline cellulose to high pressure homogenization. This process is fully described in U.S.
Patent No. 5,011,701 to Baer, et al. The calcium citrate or microreticulated microcrystalline cellulose, if used, is present at a level of from about 0.75~ to about 3~.
It has also been determined that the sodium salt of racemic 2-(4-methoxyphenoxy) propionic acid can be used to reduce the sweetness of inulin and also mask the starchy flavors of those compositions containing starch. The propanoate salt is used at a level of from about 50 ppm to about 200 ppm.
Inulin is a polysaccharide derived from various plant tubers, such as dahlia, jerusalem artichokes and chicory. Inulin is a polysaccharide of fructose units with a molecular weight of about 5,000. The molecular weight of inulin is dependent upon its source.
Bulking agents useful for both the non-fat margarine type product and the non-fat squeezable product are selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids having a DE of from about 24 to about 42. The bulking agent is present in the non-fat spreadable margarine product and squeezable margarine formulations which contain inulin at a level of from about 0 to about 5~. That is, the bulking agent is optional in the non-fat formulations 21~0o8~
containing inulin. If used in these formulations, the bulking agent is present at a level of from about 1~ to about 5~. The bulking agent is present in the non-fat squeezable margarine product which does not contain inulin at a level of from about 5~ to about 10~.
A gum is used in the non-fat squeezable margarine produced with an enzyme modified starch and a bulking agent, but is optional in the non-fat spreadable margarine and squeezable margarine produced with acid modified starch and inulin. The gum is present at a level of from about 0.1~ to about 2.0~, preferably from about 0.4~ to about 1.75~. The gum may be selected from any of the food grade gums, such as xanthan gum, guar gum, gum acacia, alginates, carrageenans, pectins and gelatin. The preferred gum is xanthan gum.
The non-fat margarine and squeezable margarine of the present invention also contain salt at a level of from about 1.0~ to about 2.5~. The formulations may also contain vitamins, preservatives, flavoring components and coloring components. Water is present at a level of from about 65~ to about 85~.
While a typical spreadable and squeezable margarine type texture and flavor can be attained without the presence of any fat, fats and oils can be included in the formulations at levels up to about 15~, if desired.
Suitable fats include butterfat, vegetable oils hydrogenated vegetable oils, flavored oils known as butter oils and non-digestible fats and oils, such as polyol fatty acid esters, particularly fatty acid esters of sucrose. If used, the fat and oil may be present at a level of from about 0.5~ to about 60~. At levels of fat above about 15~, an emulsifier is required.
Suitable emulsifiers for tablespreads include mono- and di-glycerides, lactic acid esters of monoglycerides, diacetyl tartaric acid esters of monoglycerides (DATEM), propylene glycol esters of 2l~oo86 monoglycerides (PGME), succinylated monoglycerides (SMG), ethoxylated monoglycerides, sodium stearoyl-2-lactylate, polyglycerol esters of saturated fatty acids, Polysorbate 60, Polyglycerate 60 (ethoxylated mono- and diglycerides), mono-, di- and tri- fatty acid esters of sucrose, lecithin, including modified lecithin. Th emulsifier or combination of emulsifiers is used at a level in the range of 0.2 - 12~, basis the fat in the product.
The compositions of the present invention are particularly suitable for marketing a spread which is labeled as a saturated fat-free spread. Under FDA
requirements in the United States, a spread labeled as being saturated fat-free must have less than 0.5 grams of saturated fat per one tablespoon serving. This requirement can be met utilizing various levels of fats and oils. For example, only 5~ butterfat can be present in the composition to meet the 0.5 gram requirement, whereas 45~ of canola oil could be used and still meet the 0.5 gram requirement. Other vegetable oils can be used at various levels within the range of 5~ to 60~ to meet the requirement of 0.5 grams of saturated fat.
Suitable fats and oils include canola oil, soybean oil, corn oil, butterfat, sunflower oil and safflower oil.
In the manufacture of the non-fat spreadable margarine, squeezable margarine containing inulin, a salt solution is first prepared in a holding tank. The preservatives used are also combined with the salt in the salt solution. In general, the salt solution will contain from about 1~ to about 5~ salt. The salt solution is pumped to a second tank where it is mixed with the fat mimetic, the bulking agent, if used, the inulin and any flavors and colorants. The salt solution and other components are metered into the batch mix tank at levels sufficient to provide the desired levels in the finished product.
21~0o8~
After being combined in the batch mix tank, the non-fat spreadable formulation is pumped to a high pressure homogenizer, such as a Rannie homogenizer. It has been determined that the non-fat margarine product S must be processed at a pressure above 6,000 psig to obtain the rheological properties desired in the finished product. The gel strength is rapidly reduced at homogenization pressures below about 6,000 psig.
Homogenization pressures of from about 8,000 psig to about 15,000 psig are desirable. The non-fat margarine product after being homogenized is transferred to the holding tank. Since substantial heat is developed during processing through the high pressure homogenization apparatus, the formulation is then pumped through cooling heat exchangers prior to being packaged at a temperature of 60 F. to provide a non-fat spreadable margarine after a holding period of refrigerated storage at a temperature of from about 35 F. to about 50 F. for from about 10 - hours to about 30 hours.
As shown in FIGURE 1, the gel strength of various materials after being processed in accordance with the above method is shown. As can be seen, the gel strength of the fat mimetic, StellarTM is 0. The gel strength of inulin is 84.5. The combination of 25%
25 inulin and 5% StellarTM is 130.4. This shows that the StellarTM reacts synergistically with the inulin to cause an increase in gel strength of greater than 50%. As shown in FIGURE 2, the gel penetration of a 30% inulin composition displays a brittle profile as seem by the sharp break at the point (1). A composition wherein 5~
of the inulin is replaced with StellarTM displays a smooth non-brittle profile, as seen in FIGURE 3.
The non-fat squeezable margarine without inulin is prepared by a different method. The fat mimetic is first placed into solution and heated to a temperature of about 190 F. to activate the fat mimetic. The fat 2I~oo8~
mimetic is then held in a tank for subsequent formulation. The xanthan gum and bulking agent are mixed in a second tank and held for use in preparing the formulation. A salt solution is prepared in a third tank and is held for preparing the formulation. The three mixtures are proportloned into a fourth tank in proportions sufficient to prepare the final formulation.
The colors and flavors are metered into the fourth tank in suitable amounts. Thereafter, the mixture is processed through a high shear mixer, such as a PentaxTM
mixer, which is a horizontal rotating pin type mixer. It should be understood that high shear mixing is to be distinguished from high shear homogenization. High shear homogenization imparts much more shear force than does lS high shear mixing. The mixture is then transferred to a holding tank from which it is pumped to a cooling heat exchange apparatus prior to being packaged at a temperature of 60 F. The non-fat squeezable margarine product is then held at refrigeration temperatures of from about 35 F. to about 50 F. for a period of between about 10 and about 21 days prior to developing the desired rheological properties similar to that of spreadable full fat margarine.
The following examples further illustrate various features of the invention, but are intended to in no way limit the scope of the invention, which is set forth in the appended claims.
Example 1 A non-fat spreadable margarine type product was 0 prepared from the components set forth in Table 1.
Table 1 Ingredients Percentages Water 70.1755 Inulin 20.0000 StellarTM modified starch 5.0000 Calcium Citrate 1.5000 21Soo8~
Vitamin A (Type 250-S) 0.0148 Salt (Sodium Chloride)2.0000 Sodium Benzoate 0.0500 Potassium Sorbate 0.0500 5 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.2500 Titanium Dioxide (TiO2)0.1000 Yellow #5 0.0016 Yellow #6 0.0006 Mouthfeel (MV04) 0.1500 Butter Flavor 0.7000 TOTAL 100.0000~
The non-fat spreadable margarine was prepared by combining 15% of the water with the salt, the potassium sorbate, the sodium benzoate and the calcium disodium EDTA in a holding tank to provide a salt solution. The salt solution was maintained at a temperature of 120 F. The salt solution was metered, along with the inulin, the StellarTM, the flavor and color components and the remaining water, into a batch mix tank. The mixture was pumped through a Rannie homogenizer and was homogenized at a pressure of 11,000 psig. The formulation emerged from the Rannie homogenizer at a temperature of 150 F. The formulation 2S was transferred to a holding tank and was pumped through cooling heat exchangers to reduce the temperature to 60 F. for packaging. The spreadable margarine formulation was held at a refrigeration temperature of 40 F. for 1 day to attain the desired rheological properties similar to full fat margarine.
Example 2 A non-fat squeezable margarine type product was prepared from the components set forth in Table 2.
Table 2 35 Ingredients Percentages Water 77.9326 Inulin 12.0000 StellarTM modified starch 5.0000 Flavor 2.9000 Salt 2.0000 21SDO~
Lactic Acid 0.0650 Sodium Benzoate 0.0500 Potassium Sorbate 0.0500 Yellow #5 0.0016 Yellow #6 0.0008~
TOTAL 100.0000%
The non-fat squeezable margarine was prepared by combining 15~ of the water with the salt, the potassium sorbate and the sodium benzoate and the calcium disodium EDTA in a holding tank to provide a salt solution. The salt solution was maintained at a temperature of 120 F. The salt solution was metered, along with the inulin, the StellarTM, the flavor and color components and the remaining water, into a batch mix tank. The mixture was pumped through a Rannie homogenizer and was homogenized at a pressure of 11,000 psi. The formulation emerged from the Rannie homogenizer at a temperature of 150 F. The formulation was transferred to a holding tank and was pumped through cooling heat exchangers to reduce the temperature to 60 F. for packaging. The spreadable margarine formulation was held at a refrigeration temperature of 40 F. for 1 day to attain the desired rheological properties.
Example 3 A non-fat squeezable type margarine product was prepared from the formulation set forth hereinbelow in Table 3.
Table 3 30 Ingredients Percentages Water 79.3685 Paselli SA2TM gelling maltodextrin 8.0000 Lodex 15TM non-gelling maltodextrin 8.5000 Xanthan gum 0.5000 Vitamin A 0.0148 Salt 2.0000 Sodium Benzoate 0.0500 21~00~
Potassium Sorbate 0.5000 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.1570 Yellow #5 0.0016 S Yellow #6 0.0006 Sucrose 0.5000 Mouthfeel (MVO4) 0.1500 Butter Flavor 0.7000~
TOTAL 100.0000%
The non-fat squeezable margarine was prepared as follows: The Paselli SA2TM gelling type maltodextrin was added to a mixing tank along with 30~ of the water.
The mixture was stirred and heated to a temperature of 190 F. until required for use. The xanthan gum and non-gelling maltodextrin were added to a second holding tank with 25% of the water and were stirred to provide a mixture. The salt, potassium sorbate, sodium benzoate and calcium disodium EDTA were added to a third mixing tank with the remaining water and were stirred to provide a solution. The Paselli SATM mixture, the xanthan gum mixture and the salt solution were proportioned to a fourth mixing tank where the flavors and colorants were added. The mixture was then processed through a PentaxTM
high shear mixer and transferred to a holding tank. The mixture was transferred through a cooling heat exchanger to provide a temperature of 60 F. and was packaged into squeezable margarine type containers. The containers were held at refrigeration temperatures for 15 days to provide the desired rheological properties.
Example 4 A non-fat spreadable margarine type product was prepared from the components set forth in Table 4 using the procedure of Example 1.
Table 4 35 InqredientsPercentaqes Water 74.3255 Inulin 17.0000 StellarTM modified starch 4.0000 Waxy Maize Starch 1.5000 Vitamin A 0.0148 Salt 0.0500 Sodium Benzoate 0.0500 5 Potassium Sorbate 0.0500 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.2500 Titanium Dioxide (TiO2)0.1000 Yellow #5 0.0016 Yellow #6 0.0006 Butter Flavor 0.7000 TOTAL 100.0000~
The non-fat margarine prepared from the above components including a waxy maize starch had rheological and organoleptic properties similar to full fat margarine.
Example 5 A non-fat spreadable margarine type product was prepared from the components set forth in Table 5 using the procedure of Example 1.
Table 5 Ingredients Percentages Water 74.3255%
Inulin 17.0000 StellarTM modified starch 4.0000 Microreticulated Micro-crystalline cellulose1.5000 Vitamin A 0.0148 Salt 2.0000 Sodium Benzoate 0.0500 Potassium Sorbate 0.0500 Calcium Disodium EDTA 0.0075 Lactic Acid (50~) 0.2500 Titanium Dioxide (TiO2)0.1000 Yellow #5 0.0016 Yellow #6 0.0006 Butter Flavor 0.7000 TOTAL 100.0000~
The non-fat margarine prepared from the above components, including microreticulated microcrystalline cellulose had rheological and organoleptic properties similar to full fat margarine.
21Soo86 Example 6 In accordance with one embodiment of the present invention, a saturated fat-free tablespread was prepared utilizing an oil submix and a salt submix in preparing the product. The oil submix has the following components at the indicated levels:
Oil Submix %
Canola Oil 88.298 Polysorbate 60 11.198 Vitamin #52 0.336 Flavor #512 0.168 Total 100.000 The salt submix has the following components:
Salt Submix %
Water (45F) 79.336 Salt 19.68 Potassium Sorbate 0.492 Sodium Benzoate 0.492 Total 100.000 40% of the oil mix, 10% of the salt mix, 34%
water, 15% inulin and 1% of minor components were then combined to provide a saturated fat-free tablespread having the following composition:
Ingredient %
Canola Oil 37.123 Water 34.074 Inulin 15.000 Water/Salt Submix 10.166 Oil Submix Solubles 1.786 Cream 1.700 Lactic Acid 0.120 CF #1 (Flavor) 0.025 EDTA 0.006 Total 100.000 The process of preparing the saturated fat-free tablespread involves mixing the inulin, water, oil submix, salt submix and minor components in a propeller type mixing chamber. The mixture is then pumped through a high pressure homogenization step, i.e., a RannieTM homogenizer.
The temperature of the mixture is increased to 126F by passage through the high pressure 2lsoo8~
-homogenizer. The mixture is then pumped to a heat exchanger where the temperature of the mixture is reduced to 45-50F, after which the tablespread is packaged.
Example 7 The process of Example 1 was used to prepare a saturated fat-free tablespread having the following composition:
Ingredient % Weight Inulin - instant 17.000% 17.00#
Water 41.732% 41.73#
Stellar 4.000% 4.00#
Water/Salt 10.166% 10.17#
MRC (9%) 22.200% 22.20#
Vitamin #52 0.006% 2.72g Cream 2.000% 907.20g Butteroil 1.600% 725.76g Lactic acid 0.100% 45.36g HFCS 0.100% 453.60g Cypha 0.0001% 0.05g Starter Distillate 0.180% 81.65g Flavor #33 0.016% 7.26g 100.000% 99.82#
The presence of the propanoate salt provided a tablespread with a reduced sweetness and less starchy flavor as compared to the tablespread of Example 1.
Example 8 The method of claim 1 was used to prepare saturated fat-free tablespreads of one embodiment of the present invention, having the following formulations:
21S~og~
In~redients Batch 1 Batch 2 Batch 3 Wei~ht % Wei~ht % Wei~ht %
Water 24.3060 19.3060 14.0360 Inuline 15.0000 15.0000 15.0000 Soybean Oil 50.0000 55.0000 60.0000 Water/Salt Solution' 10.1660 10.1660 10.1660 Lactic Acid .1000 1000 1000 Color (Bowl) .2000 .2000 .2000 Flavor CF1 .0250 .0250 .0250 Flavor 512 .0030 .0030 .0030 Polysorbate 60 .2000 .2000 .2000 Water/Salt Solution' In~redients Batch 1 Wei~ht %
Water 79.3360 Salt 19.6800 Na Benzoate .4920 K Sorbate .4920 After being packaged, the formulations were held at a refrigeration temperature of 40 F. for 1 day to attain the desired rheological properties of full-fat margarine.
Claims (32)
1. A substantially saturated fat-freemargarine which comprises:
(a) a substantially saturated food grade oil, or fat, (b) from 0 to 5% of a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids, (c) inulin, and (d) water.
(a) a substantially saturated food grade oil, or fat, (b) from 0 to 5% of a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids, (c) inulin, and (d) water.
2. A margarine in accordance with Claim 1, wherein said margarine also comprises a sweetness masking agent.
3. A margarine in accordance with Claim 2, wherein said sweetness masking agent selected from the group consisting of calcium citrate, microreticulated microcrystalline cellulose and mixtures thereof which is present at a level of from about 0.75% to about 3.0% by weight, dry solids basis.
4. A margarine in accordance with Claim 2, wherein said sweetness masking agent is the sodium salt of racemic 2-(4-methoxyphenoxy) propionic acid which is present at a level of from about 50 ppm to about 200 ppm.
5. A margarine in accordance with Claim 1, wherein said margarine also comprises a gum.
6. A margarine in accordance with Claim 5, wherein said gum is selected from the group consisting of xanthan gum, guar gum, gum acacia, alginates, carrageenans, pectin and gelatin and is present at a level of from about 0.1% to about 2.0%.
7. A margarine in accordance with Claim 1, wherein said oil or fat is present at a level of from about 5% to about 60%.
8. A margarine in accordance with Claim 1, wherein said bulking agent is present at a level of from about 1.0% to about 5%.
9. A margarine in accordance with Claim 1, wherein said margarine also comprises salt at a level of from about 1.0%
to about 2.5%.
to about 2.5%.
10. A margarine in accordance with Claim 1, wherein said oil is soybean oil.
11. A margarine in accordance with Claim 1, wherein said inulin is present at a level of from about 10% to about 23%.
12. A margarine in accordance with Claim 2, wherein said inulin is present at a level of from 10% to about 23%.
13. A margarine in accordance with Claim 1 wherein said fat is butterfat.
14. A margarine in accordance with Claim 1, wherein said oil is selected from the group consisting of canola oil, soybean oil, corn oil, sunflower oil and safflower oil.
15. A margarine in accordance with any one of Claims 1-9, 11 or 12, wherein said oil is canola oil.
16. A non-fat squeezable margarine which comprises:
(a) a substantially saturated food grade oil, or fat, (b) a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids, (c) gum, and (d) water.
(a) a substantially saturated food grade oil, or fat, (b) a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids, (c) gum, and (d) water.
17. A margarine in accordance with Claim 16, wherein said fat or oil is present at a level of from about 5% to about 60%.
18. A margarine in accordance with Claim 15, wherein said gum is selected from the group consisting of xanthan gum, guar gum, gum acacia, alginates, carrageenans, pectin and gelatin and is present at a level of from about 0.1% to about 2.0%.
19. A margarine in accordance with Claim 16, wherein said bulking agent is present at a level of from about 5% to about 10%.
20. A margarine in accordance with Claim 16, wherein said margarine also comprises salt at a level of form about 1.0%
to about 2.5%.
to about 2.5%.
21. A margarine in accordance with Claim 16, wherein said fat or oil is selected from canola oil, soybean oil, corn oil, sunflower oil and safflower oil.
22. A method for manufacture of a substantially fat free margarine comprising providing a mixture of food grade fat or oil, inulin and water and subjecting said mixture to high pressure homogenization of at least about 6,000 psig.
23. A method in accordance with Claim 22, wherein said homogenization pressure is from about 6,000 psig to about 15,000 psig.
24. A method in accordance with Claim 22, where said fat or oil is present at a level of from about 5% to about 60%
and said water is present at a level of from about 65% to about 85%.
and said water is present at a level of from about 65% to about 85%.
25. A method in accordance with Claim 22, wherein said inulin is present at a level of from about 10% to about 23%.
26. A method in accordance with Claim 22, wherein said mixture also includes a sweetness masking agent selected from the group consisting of calcium citrate, microreticulated microcrystalline cellulose and mixtures thereof which is present at a level of from about 0.75% to about 3.0% and the sodium salt of racemic 2-(4-methoxyphenoxy) propionic acid which is present at a level of from about 50 ppm to about 200 ppm.
27. A method in accordance with Claim 22, wherein said mixture also includes gum.
28. A method in accordance with Claim 22, wherein said gum is selected from the group consisting of xanthan gum, guar, gum, gum acacia, alginates, carrageenans, pectin and gelatin and is present at a level of from about 0.1% to about 2.0%.
29. A method in accordance with Claim 22, wherein said mixture also includes a bulking agent selected from the group consisting of non-gelling maltodextrins, polydextrose and corn syrup solids, which is present at a level of from about 1% to about 5%.
30. A method in accordance with Claim 22, wherein said mixture also includes salt at a level of from about 1.0% to about 2.5%.
31. A method in accordance with Claim 22, wherein said mixture also includes from 5% to 60% of a fat or oil selected from canola oil, soybean oil, corn oil, sunflower oil and safflower oil.
32. A method in accordance with Claim 22, wherein said mixture is held at refrigeration temperatures for a period of from about 10 hours to about 30 hours after said high pressure homogenization.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US255,454 | 1994-06-08 | ||
US08/255,454 US5501869A (en) | 1992-12-28 | 1994-06-08 | Fat-free tablespread and method of making |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2150086A1 true CA2150086A1 (en) | 1995-12-09 |
Family
ID=22968404
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002150086A Abandoned CA2150086A1 (en) | 1994-06-08 | 1995-05-24 | Fat-free tablespread |
Country Status (1)
Country | Link |
---|---|
CA (1) | CA2150086A1 (en) |
-
1995
- 1995-05-24 CA CA002150086A patent/CA2150086A1/en not_active Abandoned
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