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CA2104050A1 - Process for the production of moldings by pressing textile residual materials with simultaneous gluing, moldings obtained by this process and the use thereof - Google Patents

Process for the production of moldings by pressing textile residual materials with simultaneous gluing, moldings obtained by this process and the use thereof

Info

Publication number
CA2104050A1
CA2104050A1 CA002104050A CA2104050A CA2104050A1 CA 2104050 A1 CA2104050 A1 CA 2104050A1 CA 002104050 A CA002104050 A CA 002104050A CA 2104050 A CA2104050 A CA 2104050A CA 2104050 A1 CA2104050 A1 CA 2104050A1
Authority
CA
Canada
Prior art keywords
textile
residual materials
adhesive
molding
moldings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002104050A
Other languages
French (fr)
Inventor
Peter Knobloch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2104050A1 publication Critical patent/CA2104050A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • D04H1/4258Regenerated cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266Natural fibres not provided for in group D04H1/425
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/43Acrylonitrile series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/60Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)
  • Moulding By Coating Moulds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Abstract Process for the production of moldings by pressing textile residual materials with simultaneous gluing, moldings obtained by this process and the use thereof A process for the production of moldings in which a fibrous material is mixed with an adhesive and the mixture is kept in a mold under pressure until the adhesive sets is described. The process comprises employ-ing as the fibrous material comminuted textile residual materials which are obtained during production, during processing and/or after use of clothing and/or home textiles.

The present invention provides a further possibility for utilizing residual materials. The abovementioned textile products can thus be put to renewed use, even after use as specified. In particular, insulating and dumping materials can be built up from the moldings according to the invention.

Description

~V~ J`~O

HOE~HST AXTIEN~ESELLSCHAFT ~OE 92/F249 Dr.AC/St Description Proce~s for the production of molding~ by pre~ing textile residual materi~ls with ~imultaneou~ gluing, moldings obtained by thi~ proce~s and the u~e thereof The invention relates ~o a proces~ for the production of moldings in which certain textile residual material~ are mixed with an adhe~ive and the mixture i3 kept in a ~ld under pressure until the adhe~ive ~et30 13 A proce~s for the production of moldings iB de~cribed, for example, in BP B-0 160 270. The varioua pos~ibilitie~
for building up such materials are dealt with therein~
Shoddy, wood, shavinys and torn ~crap~ of paper ~re mentione~ as fibrous starting n~teri~l~. Re~idual materials from the processing o~ synthetic fib~ra, in particular fibers of polyethylene terephthalate, generally called polye~t~r fiber~, which are employed in the form of shoddy are al~o particularly advantageous.

In the example, the above patent ~ention6 shoddy from polyester spun-bonded residual materials, i.e, a pulled spunbonded.

Pressed moldings, such a~, or ex~mple, ~hipboard, ~urthermore are common in th~ building i~dustxy, as are pre~sed foamed materials, and al80 damping and ineulating material~ built up from, for exampls, fibrou~ inorganic material.

In a compl~tely ~if~erent field, t~at is to ~ay i~ the textil~ industry, ~ertain mixtures have preferentially become accepted in the f ield of clothing and home 30 textiles because of favorable combinations of properties and complementing o~ propertieC. Examples whic:h may be mentivned are textile sheet-l~ke ~tructures~ sucll as :, ~, .,, : , ~ , .. .

.

o woven fabric or knitted fabric based on polyester/cotton mixtures, ~uch as polye~ter/cotton 65%/35~, on poly-ester~wool mixture~, ~uch a~ polyester/wool 55~/45%, on polyesters, such a~ polyethylene tel.ephthalate, on cotton, on wool, on acrylic, on vi~cose ox on mixtures of these types. It i5 furthermore known that in~ulati~g materials, for ex~mple wadding, are al~o prepared from 6uch materials. Textile proce~es ~uch as lead, f~r example, to formation of non-woven~ are u~ed h~re.

It is furthermore known that many textile product~ are a~ailable again after use as ~pecified.

As a result of the disposal po~ibilitie~ becomi~g increasingly more difficult, there i~ a demand for possibilities of returning r~idual material~ formed to the material cycle, i~e. al~o in the home textile lmd clothing ~ector.

The present invention provide~ a further pos~ibility for reducing and avoiding residual materials based on f iber materials.

The pre~ent invention provides a proce~s as ~laLmed in claim 1, with which shaped article~, such as in~ulating and damping materials, which, i~ de~ir~d, can also have load-bearing or at l~ast self -8upporting propertie8 ~ can be built up from ~uch t~xtile productst even after use a~
apecified.

The textile residual material~ to be employed include, in particular, textile ~heets, ~uch a~ wove~ fabric, knitted fabric, loop fabric, laid fabric a~d Qon-wovens.

If appropriate, the ma~erials are fir t dry cleaned or washed or ~ubjected to a c~binatlon o both claaning processes. Subsequent comminution i8 effe~ted by mean~ of chopper~ and/or vla pulling units.

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~h~`~U

Depending on the nature of the ~oiling re~ulting ~rom use, it may be expedient ~irst to chop or tear the 6tarting material coarsely and then to apply the wa~hing or cleaning ~tage mentioned or the combined cleaning process. Further dlminution to 8mall pieces of ~heet, individual pieces o~ the yarn or multifi.lament and al~o individual filament~ can then be carried out.

The comminuted material is mixed inti.mately with an adhesive or binder, preferably such as il3 e~tabli~hed in the building and decor ector~ Preferred adhe~ive~ are customary an~ established products from other field~ of work, the operating temperature of which is below the melting point of the fiber material~ employed. In addi-tion to liquid adhe~ives, pulverulent adhe~ive~ are particularly suitable. It i~ al~o po~ible to use reac-tive adhesives, in addition to pulverulent hot melt adhesives. There are no re~txiction~ on khe choice of adhe~ive in respect of chemlstry. ~hermopla~ti~s which are liquefied by heating and bond the fibrous material after cooling are also partieularly preferably suitable.

The amount of adhe6ive i~ chs~en according to the intended use purpose, the ~malle6t po~sible amount~ of adhesive being aimed for. The amount of adhesive i~
preferably not more than 10~ by weight~ The use of h~t mslt adhesives in ~mall proportional amounts, for example those ba3ed on a copolymer o~ vinyl e~ter, allows renewed xecyclability and i8 therefore particul~rly preferred.

~he mixture of textile products and adhesive i~ spread out to a sheet uniformly according to the later w~ight per m2 and iæ heated in a pre~ until the adhe~ive display~ its full activity. ~he thickness of the ~olding formed follow~ from the platen ~eparation. The preasure is released when the adhe ive has displayed its adhesive power to the extent that no further change in t~i~kness occurs after th~ relea~e~ Wi$h hot ~elt adhesive~, this i8 the case below a certain temperature.

: - :

The composition of the t~xtile materi~ based on prov~n textile mixture~ such as are ~u~tomary in the commodity and home textile ~ector. Prefexred examples of ~uch mixtures are re6idual materials o~ polye~ter/cotton 65~/35%, polyester/wool 55%/45~t acrylic/~wool mixtures or also 100~ polyester, cotton, wool, acrylic or vi~cose.

The molding~ thus ob~ainable can b~ employed, in parti-cular, as insula~ing and damping material~ and have k~own textile properties. Thi~ applie~ to, for exa~pl~, the moisture uptake, th~ dimensional stability, the temp~ra-ture properties and the like. Like the corre~ponding textile products, these insulating and damping material~
are comparably insulating and permeable to air and moisture. As with th~ corresponding textile products, thermally insulating, temperature-compen~ating and ~ou~d-damping properties are typically co~bined with one another.

The term "molding" in the context of this invention i~ to be understood as meaning sheet-like material, a8 well as products onto which a certain ~hape corresponding to later use is embossed.

Such insulating and damping material6, which are, for example, 0.5-5 cm thick, are usually flexible and ~elf-. supporting and can be cut. In a~dition, if formulated25 densely, they assume load-bearing fu~ction~, i.e. they can be loaded mechanically beyond accommodation of their own weight.

They can optio~ally be provided with a covering, for example with a decorative, surface. So that renewed recyclability i8 not limited, such a decorative sur~ace will preferably be achi~ved on the ba~is of textile products, such as, for example, by the use of non-woven~, woven fabrics, knitted fabric~ or laid fabric~

For th~ insulating ~ector~ covering with a waterproof -h ~iJ r~

~urface, permeable to vapor if required, i~ preferred, such a~ i~ cu~tomary, for example, with conventional mineral damping substance~.

The shaped article according to the invention can have ~
surface covering on either one or both ~ide~. A eurface covering on one ~ide will pxeferably ~erve to Lmpart an additional pxoperty, ~uch as modification of the decor-ation of the ~urace and/or Lmpermeability thereof ko water r while ~urface cov2ring on both ~i.dea can help to make a ~ub3tantial c~ntribution to stiffening the product.

A particular type of product ~tabilization i5 poeæible i~, or example, stabilization inside the insulating and damping material i8 effected approximately centrally by mean~ of a laid fabric or woven lattice. In thi ca~e, the ability of the material to be shaped i~ not impaired to the extent as is the ca~e with ~tabilization on the surface.

The adhesive can impart to the moldings according to the invention, ~uch as insulating, dampinq and ~upport materials, further functions which are de~irable for the intended use under di~cu~ion for the~e moldings. Thu~, for example, impregnating propertie~ ~water-r~pell~nt character~ can be Lmparted to the moldings by additives ~5 in the adhe~ive. S~lch addi~ional properties aa~ o~ course also be generated by ~ub~equent treatm~t or by intro-duction of separate component~ into the prel~minary mixture~

A æurface desi~n is al~o pos8ible by ~praying on, for example, a dyestuff.

Such products can be employed a~ in~ulating and damping material in the building indu~itxy, and al~o in machinery constru~tion, as an i~ulati~g and soundproQfing mat~rial, if de~ired i~ combinatio~ with a .

~ . .

-- 6 -- .
self-supporting character or even one which can be ~ub~ected to mechanical load. A preferred field of use i8 insulation and damping in hou~e construction, where known proven combinations o~ textile propertie~ ars transferred to the building in thi6 manner. Proce~ing i~ easy, ~inee these insulating and damping ~aterials ~an be at lea~t ~elf-supporting due to the nature of theLr production.

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Claims (18)

1. A process for the production of moldings in which a fibrous material is mixed with an adhesive and the mixture is kept in a mold under pressure until the adhesive sets, which comprises employing as the fibrous material comminuted textile residual materials which are obtained during production, during processing and/or after use of clothing and/or home textiles.
2. The process as claimed in claim 1, wherein the textile residual materials chosen are proven textile mixtures, such as, preferably, polyester/cotton 65%/35%, polyester/wool 55%/45%, acrylic/wool mix-tures, 100% polyester, 100% cotton, 100% wool, 100%
acrylic and 100% viscose.
3. The process as claimed in claim 1, wherein textile residual materials which are obtained after use of clothing and/or home textiles a specified are employed.
4. The process as claimed in claim 1, wherein the comminution, by means of choppers and/or via tearing units, of the textile residual materials to be employed is preceded by a cleaning stage, in parti-cular is the form of dry cleaning and/or washing.
5. The process as claimed in claim 1, wherein a first comminution of the textile residual materials to be employed is followed by a cleaning stage.
6. The process as claimed in claim 1, wherein pulverulent hot melt adhesives in the form of thermoplastics which are liquefied by heating and bond the textile residual materials after cooling are employed.
7. The process as claimed in one of claims 1 or 6, wherein the amount of adhesive chosen is as small as possible in order to allow renewed recyclability.
8. The process as claimed in one of claims 1 to 7;
wherein the preliminary mixture of textile residual materials and adhesive before pressing or the finished molding is covered with at least one layer of waterproof material which is permeable to vapor.
9. The process as claimed in claim 8, wherein a surface covering takes place on both sides in order to increase the rigidity of the product.
10. The process as claimed in one of claims 8 or 9, wherein the surface covering is achieved with tex-tile products, in particular with comminuted textile residual materials which are obtained during produc-tion, during processing and/or after use of clothing and/ox home textiles.
11. The process as claimed in one of claims 1 to 10, wherein the preliminary mixture of textile residual materials and adhesive is pressed together with a laid fabric or woven lattice positioned inside this mixture in order to achieve stabilization of the product,
12. The process as claimed in one of claims 1 to 11, wherein additional properties, such as water-repellent properties, an improvement in heat resis-tance or a favorable influencing of combustion properties are imparted with the adhesive by corre-ponding additives.
13. The process as claimed in one of claims 1 to 11, wherein a surface design is effected by spraying on a substance which modifies the surface structure and/or the surface properties, in particular a dyestuff, the substance being sprayed onto at least one of the surfaces of the preliminary mixture before pressing or onto at least one of the surfaces of the pressed molding.
14. A molding of fibrous material and an adhesive which bonds said fibrous material to form said molding, wherein the fibrous material essentially comprises comminuted textile residual materials which are obtained during production, during processing and/or after use of clothing and/or home textiles.
15. A molding as claimed in claim 14, which has the shape of a sheet.
16. A molding as claimed in claim 15, which has self-supporting properties.
17. A molding as claimed in one of claims 15 or 16, which can be subjected to a mechanical load, i.e.
can accommodate more than merely its own weight mechanically, without changing its shape.
18. The use of a molding as claimed in claim 14 as an insulating and damping material.
CA002104050A 1992-08-14 1993-08-13 Process for the production of moldings by pressing textile residual materials with simultaneous gluing, moldings obtained by this process and the use thereof Abandoned CA2104050A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4227033.2 1992-08-14
DE4227033 1992-08-14

Publications (1)

Publication Number Publication Date
CA2104050A1 true CA2104050A1 (en) 1994-02-15

Family

ID=6465623

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002104050A Abandoned CA2104050A1 (en) 1992-08-14 1993-08-13 Process for the production of moldings by pressing textile residual materials with simultaneous gluing, moldings obtained by this process and the use thereof

Country Status (6)

Country Link
EP (1) EP0583671A1 (en)
JP (1) JPH06182883A (en)
BR (1) BR9303274A (en)
CA (1) CA2104050A1 (en)
FI (1) FI933571L (en)
NO (1) NO932882L (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2607352A (en) * 2021-06-04 2022-12-07 Avena Environmental Ltd Process for manufacturing a solid product

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4307056A1 (en) * 1993-03-06 1994-09-08 Hoechst Ag Process for producing molded parts based on fibrous material and adhesive, and molded part produced by this process
CH686785A5 (en) * 1993-10-06 1996-06-28 Matec Holding Ag Odour Armer, sound and waermedaemmender Formkoerper and method for its manufacture.
EP0878589A3 (en) * 1997-05-14 2000-03-29 Arne Petersohn Method for manufactoring a sound absorbing element for buildings
JP4962342B2 (en) * 2008-02-12 2012-06-27 株式会社カネカ Synthetic fiber nonwoven fabric production method and cloth-like and / or cotton-like fiber separation device

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US3741863A (en) * 1971-08-27 1973-06-26 Rust Eng Co Method of recycling waste cellulosic materials
DE2457848A1 (en) * 1974-12-06 1976-06-10 Klaus Lesti COMPRESSED BODY
DD146911A1 (en) * 1979-11-19 1981-03-11 Fritz Endler METHOD AND DEVICE FOR PREPARING THERMOPLASTIC DEVICES, IN PARTICULAR HOME POPULATION DEVICES
JPS5714016A (en) * 1980-06-30 1982-01-25 Hitachi Heating Appliance Co Ltd Manufacture of cushioning and thermal insulating material
US4418031A (en) * 1981-04-06 1983-11-29 Van Dresser Corporation Moldable fibrous mat and method of making the same
DD211592A1 (en) * 1982-11-17 1984-07-18 Textiltech Forsch METHOD AND DEVICE FOR PRODUCING A STRESSFUL MATERIAL
GB2180565B (en) * 1985-09-20 1989-01-18 In Bow Fann A method for producing fiberboard using waste textile material
JPH0263703A (en) * 1988-08-30 1990-03-05 Howa Seni Kogyo Kk Manufacture of high elastic sound insulating material for automobile
DE4009364A1 (en) 1990-03-23 1991-09-26 Faser Und Vliesstoffwerk Maure Vehicle dampener felting - is composed of waste carpeting fibres with cotton and thermoplastic, bonding fibres
DE4021628A1 (en) 1990-07-06 1992-01-16 Kiha Textilien Gmbh FIBER STRUCTURE AND MOLDING OBTAINED FROM IT, AND METHOD FOR THE PRODUCTION THEREOF
ES2068449T3 (en) 1990-09-15 1995-04-16 Beyer Franz Polyvlies FIBROUS MAT AND PROCEDURE FOR OBTAINING MOLDING PARTS.
DE4034915A1 (en) 1990-11-04 1992-05-07 Kinkel Werner Helmut METHOD FOR PRODUCING SANDWICH-LIKE TEXTILES FIBER STRUCTURES IN THE FORM OF PLATES AND MOLDED PARTS

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2607352A (en) * 2021-06-04 2022-12-07 Avena Environmental Ltd Process for manufacturing a solid product
GB2607352B (en) * 2021-06-04 2024-04-03 Avena Environmental Ltd Process for manufacturing a solid product

Also Published As

Publication number Publication date
FI933571L (en) 1994-02-15
NO932882L (en) 1994-02-15
NO932882D0 (en) 1993-08-13
FI933571A0 (en) 1993-08-12
BR9303274A (en) 1994-03-08
JPH06182883A (en) 1994-07-05
EP0583671A1 (en) 1994-02-23

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Legal Events

Date Code Title Description
FZDE Discontinued