CA2075738C - Co-extruded shock tube - Google Patents
Co-extruded shock tube Download PDFInfo
- Publication number
- CA2075738C CA2075738C CA 2075738 CA2075738A CA2075738C CA 2075738 C CA2075738 C CA 2075738C CA 2075738 CA2075738 CA 2075738 CA 2075738 A CA2075738 A CA 2075738A CA 2075738 C CA2075738 C CA 2075738C
- Authority
- CA
- Canada
- Prior art keywords
- tube
- layer
- inner layer
- extruded
- reactive material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
The invention relates to a method of manufacturing a low-energy shock tube by co-extruding two or more layers simultaneously wherein the inner layer has an adhesive affinity for a powdered reactive material and the outer layer(s) provides abrasion, cut and other environmental resistance to the tube. The wall thickness of the inner layer is less than about 0.3 millimeters. The invention also relates to a low-energy shock tube having such configuration and inner layer thickness.
Description
2~~~~~~
CO-EXTRUDED SHOCK TUBE
The present invention relates to a low-energy fuse or shock tube for propagating a percussion or impact wave within and along the tube for activation of a detonator. More particularly, the present invention relates to a mufti-layer tube that is co-extruded, wherein the innermost layer has adhesive affinity for a reactive material and a wall thickness of less than about 0.3 millimeter. The outer layers) has abrasion and cut resistance, and an optional outermost layer may be resistent to degradation from contact with either ultraviolet rays or liquid organics. By "co-extrusion°' is meant forming the tube and its layers in a continuous, simultaneous operation through an extrusion element as is known in the art.
The invention comprises a method of manufacturing a low-energy shock tube comprising the steps of: (a) heating two or more materials to their respective desired extrusion temperatures; (b) co-extruding the materials to form a layered plastic tube having at least an inner layer with an inner surface and an outer layer, the inner surface of the inner layer having an adhesive affinity for a reactive material and the inner layer having a thickness of less than about 0.3 millimeter and the outer layer having abrasion and cut resistance; (c) feeding a reactive material to the inner surface of the inner layer as it is being co-extruded with the other layer or layers to form a thin layer of the reactive material on the inner surface; and (d) optionally cooling the co-extruded tubing to or below its solidification temperature and/or stretching the tube after i.t has been co-extruded to obtain the desired surface density of the reactive material, to increase the axial orientation of molecules of the plastic materials and thereby increase the tensile strength of the tube and to attain the desired inner layer thickness. The invention further comprises a shock tube whose inner layer has a wall thickness of less than about 0.3 millimeter.
FIG. 1 is a transverse cross section of a preferred embodiment of a tube according to the present invention.
FIG. 2 is a flow diagram of the process steps involved in the method of the present invention.
Reference to FIG. 1 shows a shack tube 1 in accordance with the present invention having an inner layer 2 with an inner surface 3 having an adhesive affinity for a reactive material 3b. The inner layer preferably has an adhesive property of at least 5.5 g/m2 for the reactive material, which preferably is in powdered form. The inner layer 2 preferably is selected from the group consisting of SURLYN, ethylene/acrylic acid copolymers, ethylene vinyl acetate and other plastics and adhesives. In its final form, either as extruded or after stretching, the wall thickness of the inner layer 2 is less than about 0.3 millimeter.
An outer layer 4 is shown having a greater wall thickness than that of inner layer 2. This preferably provides for greater tensile strength and increased abrasion and cut resistance. The outer layer 4 preferably is selected from the group consisting of polyethylene, polyethylene blends 'with ionomer, polypropylene, polybutelyne, nylon and other polyolefins. This outer layer 4 preferably has a tensile strength of at least 35 MPa. An optional outermost layer 5 is shown that preferably provides protection from ultraviolet rays and/or chemicals such as organic liquids. A
problem with shock tubes heretofore has been their susceptibility to degradation upon exposure to ultraviolet rays and/or organic liquids that are commonly found in blasting agents that the shock tube often contacts during application in the field. By reducing the wall thickness and thus the cost of the inner layer 2 and by co-extruding the layers, such optional outer layer 5 can be added without making the finished product overly expensive. The optional outermost layer 5 preferably selected from the group consisting of linear low, medium or high density polyethylene, polyester, polyvinylidene chloride and mixtures thereof.
The final surface density of the reactive material 3b on the inner surface of the inner layer can be varied as desired as known in the art. Typically, at least 2.7 g of reactive material per m2 of the inner surface is desired. If the tube is stretched, the initial surface density before stretching may not be significantly changed after stretching, since the inner diameter may be reduced as the tube length is increased. The reactive material preferably is a powder mixture of such materials as PETN, RDX, HMX, powdered aluminum or other fuels and mixtures thereof.
Reference to FIG. 2 illustrates the method of the present invention. The inner layer material is extruded by an extruder 6 through the crosshead die 9. Simultaneously, the outer layer Y
material is extruded by extruder 7 also through crosshead die 9.
Crosshead die 9 is configured as known in the art so as to regulate the f low of the extruded materials and to position the material from extruder 6 internal and concentric to the material from extruder 7 thereby forming the two-layered tube configuration as the materials simultaneously exit from crosshead die 9.
Optionally, a third, ultimate outer layer material can be fed to crosshead die 9 from extruder 13. Simultaneously with the feeding of the inner and outer layer materials from extruders 6 and 7, reactive material, preferably in powder form, is fed by reactive material feeder 8 through crosshead die 9 and to the inner surface of the inner layer to thereby coat the same.
The layer materials that are extruded through extruders 6 and 7 are pre--heated to their respective desired extrusion temperatures, and optionally, the two-layered tube exiting from crosshead die 9 is passed through a cooler 10, such as a water bath. Further optionally, the co-extruded tube may be stretched through stretcher 11 for purposes previously described. Stretcher 11 may comprise two pulleys, one which takes tubing from the crosshead die 9 and then acts as a brake or anchor for a second pulley which operates at a faster rate and thus stretches the tubing between the two pulleys. Still further optionally, the tube may be wound on a take-up reel l2 by conventional means or otherwise gathered or collected as desired:
The invention can be further described by reference to the following examples.
Example 1. A co-extruded tube was formed by heating SURLYN to a temperature of about 230°C and extruding it by means of a 1-inch single screw extruder through a crosshead die while simultaneously heating linear low density polyethylene to a temperature of about 220°C and extruding this material by means of a 1.5-inch single screw extruder through the same crosshead die. The SURLYN material formed the inner layer. The co-extruded tube that exited from the crosshead die had an outside diameter of 3.0 mm and an inside diameter of 1.1 mm. The ~URLYN* inner layer had a uniform wall thickness of 0.05 mm. The tube was cooled to a temperature of about 25°C and then wound on a take-up reel.
Example 2. A co-extruded tube was formed using the same extruders and inner and outer layer materials employed in Example 1 above. In this example, however, a differently sized crosshead die was used. The result was a two-layered tube having an outside diameter of 4.5 mm and an inside diameter of 2.1 mm. After cooling to a temperature of about 30°C, the tube was then stretched so that its outside diameter was reduced to 3.0 mm and its inside diameter was reduced to 1.2 mm. The final wall thickness of the SURLYN
inner layer was 0.25 mm. This stretched tube had a much higher tensile strength than the tube produced in Example 1. The increased tensile strength was the result of orientation of the plastic molecules by the stretching process.
While the present invention has been described with reference to certain illustrative examples and preferred embodiments, various modifications will be apparent to those skilled in the art and any * Trade-mark 2~~~~~8 modifications are intended to be within the scope of the inTrention as ,set forth in the appended claims.
CO-EXTRUDED SHOCK TUBE
The present invention relates to a low-energy fuse or shock tube for propagating a percussion or impact wave within and along the tube for activation of a detonator. More particularly, the present invention relates to a mufti-layer tube that is co-extruded, wherein the innermost layer has adhesive affinity for a reactive material and a wall thickness of less than about 0.3 millimeter. The outer layers) has abrasion and cut resistance, and an optional outermost layer may be resistent to degradation from contact with either ultraviolet rays or liquid organics. By "co-extrusion°' is meant forming the tube and its layers in a continuous, simultaneous operation through an extrusion element as is known in the art.
The invention comprises a method of manufacturing a low-energy shock tube comprising the steps of: (a) heating two or more materials to their respective desired extrusion temperatures; (b) co-extruding the materials to form a layered plastic tube having at least an inner layer with an inner surface and an outer layer, the inner surface of the inner layer having an adhesive affinity for a reactive material and the inner layer having a thickness of less than about 0.3 millimeter and the outer layer having abrasion and cut resistance; (c) feeding a reactive material to the inner surface of the inner layer as it is being co-extruded with the other layer or layers to form a thin layer of the reactive material on the inner surface; and (d) optionally cooling the co-extruded tubing to or below its solidification temperature and/or stretching the tube after i.t has been co-extruded to obtain the desired surface density of the reactive material, to increase the axial orientation of molecules of the plastic materials and thereby increase the tensile strength of the tube and to attain the desired inner layer thickness. The invention further comprises a shock tube whose inner layer has a wall thickness of less than about 0.3 millimeter.
FIG. 1 is a transverse cross section of a preferred embodiment of a tube according to the present invention.
FIG. 2 is a flow diagram of the process steps involved in the method of the present invention.
Reference to FIG. 1 shows a shack tube 1 in accordance with the present invention having an inner layer 2 with an inner surface 3 having an adhesive affinity for a reactive material 3b. The inner layer preferably has an adhesive property of at least 5.5 g/m2 for the reactive material, which preferably is in powdered form. The inner layer 2 preferably is selected from the group consisting of SURLYN, ethylene/acrylic acid copolymers, ethylene vinyl acetate and other plastics and adhesives. In its final form, either as extruded or after stretching, the wall thickness of the inner layer 2 is less than about 0.3 millimeter.
An outer layer 4 is shown having a greater wall thickness than that of inner layer 2. This preferably provides for greater tensile strength and increased abrasion and cut resistance. The outer layer 4 preferably is selected from the group consisting of polyethylene, polyethylene blends 'with ionomer, polypropylene, polybutelyne, nylon and other polyolefins. This outer layer 4 preferably has a tensile strength of at least 35 MPa. An optional outermost layer 5 is shown that preferably provides protection from ultraviolet rays and/or chemicals such as organic liquids. A
problem with shock tubes heretofore has been their susceptibility to degradation upon exposure to ultraviolet rays and/or organic liquids that are commonly found in blasting agents that the shock tube often contacts during application in the field. By reducing the wall thickness and thus the cost of the inner layer 2 and by co-extruding the layers, such optional outer layer 5 can be added without making the finished product overly expensive. The optional outermost layer 5 preferably selected from the group consisting of linear low, medium or high density polyethylene, polyester, polyvinylidene chloride and mixtures thereof.
The final surface density of the reactive material 3b on the inner surface of the inner layer can be varied as desired as known in the art. Typically, at least 2.7 g of reactive material per m2 of the inner surface is desired. If the tube is stretched, the initial surface density before stretching may not be significantly changed after stretching, since the inner diameter may be reduced as the tube length is increased. The reactive material preferably is a powder mixture of such materials as PETN, RDX, HMX, powdered aluminum or other fuels and mixtures thereof.
Reference to FIG. 2 illustrates the method of the present invention. The inner layer material is extruded by an extruder 6 through the crosshead die 9. Simultaneously, the outer layer Y
material is extruded by extruder 7 also through crosshead die 9.
Crosshead die 9 is configured as known in the art so as to regulate the f low of the extruded materials and to position the material from extruder 6 internal and concentric to the material from extruder 7 thereby forming the two-layered tube configuration as the materials simultaneously exit from crosshead die 9.
Optionally, a third, ultimate outer layer material can be fed to crosshead die 9 from extruder 13. Simultaneously with the feeding of the inner and outer layer materials from extruders 6 and 7, reactive material, preferably in powder form, is fed by reactive material feeder 8 through crosshead die 9 and to the inner surface of the inner layer to thereby coat the same.
The layer materials that are extruded through extruders 6 and 7 are pre--heated to their respective desired extrusion temperatures, and optionally, the two-layered tube exiting from crosshead die 9 is passed through a cooler 10, such as a water bath. Further optionally, the co-extruded tube may be stretched through stretcher 11 for purposes previously described. Stretcher 11 may comprise two pulleys, one which takes tubing from the crosshead die 9 and then acts as a brake or anchor for a second pulley which operates at a faster rate and thus stretches the tubing between the two pulleys. Still further optionally, the tube may be wound on a take-up reel l2 by conventional means or otherwise gathered or collected as desired:
The invention can be further described by reference to the following examples.
Example 1. A co-extruded tube was formed by heating SURLYN to a temperature of about 230°C and extruding it by means of a 1-inch single screw extruder through a crosshead die while simultaneously heating linear low density polyethylene to a temperature of about 220°C and extruding this material by means of a 1.5-inch single screw extruder through the same crosshead die. The SURLYN material formed the inner layer. The co-extruded tube that exited from the crosshead die had an outside diameter of 3.0 mm and an inside diameter of 1.1 mm. The ~URLYN* inner layer had a uniform wall thickness of 0.05 mm. The tube was cooled to a temperature of about 25°C and then wound on a take-up reel.
Example 2. A co-extruded tube was formed using the same extruders and inner and outer layer materials employed in Example 1 above. In this example, however, a differently sized crosshead die was used. The result was a two-layered tube having an outside diameter of 4.5 mm and an inside diameter of 2.1 mm. After cooling to a temperature of about 30°C, the tube was then stretched so that its outside diameter was reduced to 3.0 mm and its inside diameter was reduced to 1.2 mm. The final wall thickness of the SURLYN
inner layer was 0.25 mm. This stretched tube had a much higher tensile strength than the tube produced in Example 1. The increased tensile strength was the result of orientation of the plastic molecules by the stretching process.
While the present invention has been described with reference to certain illustrative examples and preferred embodiments, various modifications will be apparent to those skilled in the art and any * Trade-mark 2~~~~~8 modifications are intended to be within the scope of the inTrention as ,set forth in the appended claims.
Claims (6)
1. A method of reducing the thickness of the inner layer of a multi-layer low-energy shock tube comprising the steps of:
(a) heating at least two plastic materials to their respective, desired extrusion temperatures;
(b) extruding simultaneously by a co-extrusion process the plastic materials to form a layered plastic tube having at least an inner layer with an inner surface and an outer layer, the inner layer being extruded in a thickness of less than 0.3 millimeter and the inner surface of the inner layer having an adhesive affinity for a reactive material, and the outer layer having abrasion and cut resistance; and (c) feeding a reactive material to the inner surface of the inner layer as it is being co-extruded to form a thin layer of the reactive material on the inner surface.
(a) heating at least two plastic materials to their respective, desired extrusion temperatures;
(b) extruding simultaneously by a co-extrusion process the plastic materials to form a layered plastic tube having at least an inner layer with an inner surface and an outer layer, the inner layer being extruded in a thickness of less than 0.3 millimeter and the inner surface of the inner layer having an adhesive affinity for a reactive material, and the outer layer having abrasion and cut resistance; and (c) feeding a reactive material to the inner surface of the inner layer as it is being co-extruded to form a thin layer of the reactive material on the inner surface.
2. A method according to claim 1 comprising the additional step of cooling the co-extruded tubing to or below its solidification temperature.
3. A method according to claim 1 comprising the additional step of stretching the tube to obtain the desired surface density of the reactive material, to increase the axial orientation of molecules of the plastic materials and thereby increase the tensile strength of the tube and to reduce further the inner layer thickness.
4. A method according to claim 2 comprising the additional step of stretching the tube after it has been co-extruded to obtain the desired surface density of the reactive material, to increase the axial orientation of molecules of the plastic materials and thereby increase the tensile strength of the tube and to reduce further the inner layer thickness.
5. A method according to claim 1 wherein a third, ultimate outer layer is co-extruded with the other layers.
6. A method according to claim 5, wherein the third layer has resistance to degradation from contact with ultraviolet rays or liquid organics.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74538591A | 1991-08-15 | 1991-08-15 | |
| US745,385 | 1991-08-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2075738A1 CA2075738A1 (en) | 1993-02-16 |
| CA2075738C true CA2075738C (en) | 2002-02-26 |
Family
ID=24996468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2075738 Expired - Fee Related CA2075738C (en) | 1991-08-15 | 1992-08-11 | Co-extruded shock tube |
Country Status (4)
| Country | Link |
|---|---|
| BR (1) | BR9203169A (en) |
| CA (1) | CA2075738C (en) |
| NO (1) | NO923162D0 (en) |
| ZA (1) | ZA926028B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015021545A1 (en) * | 2013-08-16 | 2015-02-19 | Gd-Ots Canada Valleyfield Inc. | Method of manufacturing multi-layered propellant grains |
-
1992
- 1992-08-11 CA CA 2075738 patent/CA2075738C/en not_active Expired - Fee Related
- 1992-08-11 ZA ZA926028A patent/ZA926028B/en unknown
- 1992-08-13 NO NO923162A patent/NO923162D0/en unknown
- 1992-08-14 BR BR9203169A patent/BR9203169A/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015021545A1 (en) * | 2013-08-16 | 2015-02-19 | Gd-Ots Canada Valleyfield Inc. | Method of manufacturing multi-layered propellant grains |
| JP2016534313A (en) * | 2013-08-16 | 2016-11-04 | ジェネラル ダイナミックス オードナンス アンド タクティカル システムズ−カナダ バレーフィールド インク．Ｇｅｎｅｒａｌ Ｄｙｎａｍｉｃｓ Ｏｒｄｎａｎｃｅ Ａｎｄ Ｔａｃｔｉｃａｌ Ｓｙｓｔｅｍｓ−Ｃａｎａｄａ Ｖａｌｌｅｙｆｉｅｌｄ Ｉｎｃ． | Method for producing multilayer propellant grains |
| US10843979B2 (en) | 2013-08-16 | 2020-11-24 | General Dynamics Ordnance and Tactical Systems—Canada Valleyfield Inc. | Method of manufacturing multi-layered propellant grains |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2075738A1 (en) | 1993-02-16 |
| BR9203169A (en) | 1993-03-30 |
| ZA926028B (en) | 1993-03-10 |
| NO923162D0 (en) | 1992-08-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5212341A (en) | Co-extruded shock tube | |
| US2810424A (en) | Method and apparatus for making reinforced plastic tubing | |
| US3354506A (en) | Apparatus for melt extrusion of multi-wall plastic tubing | |
| CA1205265A (en) | Coextrusion feedblock for making lightweight, rigid thermoplastic pipe | |
| CA2456810C (en) | Medical device with extruded member having helical orientation | |
| US5665284A (en) | Process for manufacturing foam-filled extruded products | |
| EP0454420B1 (en) | Biaxially stretched multilayer film and process for manufacturing same | |
| JPS60224518A (en) | Plastic net consisting of coextrusion composite material strand | |
| CA2477460A1 (en) | Crosslaminate of oriented films, method of manufacturing same, and coextrusion die suitable in the process | |
| JP2006501078A5 (en) | ||
| US5190711A (en) | Methods for processing polymers | |
| KR100863058B1 (en) | Process for the production of an oriented plastic film | |
| EP0076366B1 (en) | Multilayer tubular body with uncentered barrier layer | |
| US3949042A (en) | Method and apparatus for making laminar plastic sheet material | |
| JPS6250300B2 (en) | ||
| CA1191007A (en) | Oriented multi-layer films having a different orientation distribution between layers and process for forming same | |
| US4284458A (en) | Method for producing laminated film | |
| SE500323C2 (en) | Low-energy tube and means for its production | |
| US4289727A (en) | Method for extrusion of tubular films | |
| CA2075738C (en) | Co-extruded shock tube | |
| CA2121165C (en) | Production of cross-laminated film from tube | |
| JP2588484B2 (en) | Method for producing film from semi-crystalline molten polymer by coextrusion blow molding of tube | |
| US4252755A (en) | Co-extrusion method and apparatus | |
| NZ228177A (en) | Extruded polymeric film with adhering strips: method and apparatus for manufacture | |
| EP0345987B1 (en) | Methods of making multiple layer sheet materials, methods of processing polymers, extrusion apparatus, polymeric sheet materials and packaging made therefrom |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |