CA1329102C - Cast detersive systems having a stable halogen source in the presence of readily oxidizable organics - Google Patents

Cast detersive systems having a stable halogen source in the presence of readily oxidizable organics

Info

Publication number: CA1329102C
Authority: CA; Canada
Prior art keywords: detergent; source; detersive; detersive system; sequestering agent
Prior art date: 1989-03-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 607911

Other languages

English (en)

French (fr)

Inventor

Sandra L. Bull

Elizabeth J. Gladfelter

Keith E. Olson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ecolab Inc

Original Assignee

Ecolab Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-03-31

Filing date

1989-08-09

Publication date

1994-05-03

1989-08-09 Application filed by Ecolab Inc filed Critical Ecolab Inc

1994-05-03 Application granted granted Critical

1994-05-03 Publication of CA1329102C publication Critical patent/CA1329102C/en

2011-05-03 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229910052736 halogen Inorganic materials 0.000 title claims abstract description 39
150000002367 halogens Chemical class 0.000 title claims abstract description 39
239000000460 chlorine Substances 0.000 claims abstract description 45
229910052801 chlorine Inorganic materials 0.000 claims abstract description 45
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 44
239000007787 solid Substances 0.000 claims abstract description 22
238000003860 storage Methods 0.000 claims abstract description 17
239000000203 mixture Substances 0.000 claims description 47
239000003599 detergent Substances 0.000 claims description 35
239000010410 layer Substances 0.000 claims description 31
-1 alkyl phenol Chemical compound 0.000 claims description 30
239000003795 chemical substances by application Substances 0.000 claims description 23
239000003352 sequestering agent Substances 0.000 claims description 23
229920000642 polymer Polymers 0.000 claims description 19
235000019832 sodium triphosphate Nutrition 0.000 claims description 19
229910052783 alkali metal Inorganic materials 0.000 claims description 16
125000000217 alkyl group Chemical group 0.000 claims description 15
229920000233 poly(alkylene oxides) Polymers 0.000 claims description 14
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 12
239000002736 nonionic surfactant Substances 0.000 claims description 11
238000005266 casting Methods 0.000 claims description 10
239000002689 soil Substances 0.000 claims description 10
239000003945 anionic surfactant Substances 0.000 claims description 9
229910019142 PO4 Inorganic materials 0.000 claims description 8
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 7
150000001340 alkali metals Chemical class 0.000 claims description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
150000008051 alkyl sulfates Chemical class 0.000 claims description 5
229920002125 Sokalan® Polymers 0.000 claims description 4
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 4
150000004996 alkyl benzenes Chemical class 0.000 claims description 4
150000008052 alkyl sulfonates Chemical class 0.000 claims description 4
229920001400 block copolymer Polymers 0.000 claims description 4
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 3
229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 3
150000008041 alkali metal carbonates Chemical class 0.000 claims description 3
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 3
229940077388 benzenesulfonate Drugs 0.000 claims description 3
239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
229920000609 methyl cellulose Polymers 0.000 claims description 3
239000001923 methylcellulose Substances 0.000 claims description 3
235000010981 methylcellulose Nutrition 0.000 claims description 3
239000012044 organic layer Substances 0.000 claims description 3
239000004584 polyacrylic acid Substances 0.000 claims description 3
239000000377 silicon dioxide Substances 0.000 claims description 3
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
125000002947 alkylene group Chemical group 0.000 claims description 2
235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
239000002979 fabric softener Substances 0.000 claims description 2
239000002304 perfume Substances 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 4
239000010452 phosphate Substances 0.000 claims 4
125000004400 (C1-C12) alkyl group Chemical group 0.000 claims 2
229910052681 coesite Inorganic materials 0.000 claims 2
229910052906 cristobalite Inorganic materials 0.000 claims 2
CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims 2
229920013821 hydroxy alkyl cellulose Polymers 0.000 claims 2
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 2
229920001515 polyalkylene glycol Polymers 0.000 claims 2
IFIDXBCRSWOUSB-UHFFFAOYSA-N potassium;1,3-dichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].ClN1C(=O)NC(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-N 0.000 claims 2
235000012239 silicon dioxide Nutrition 0.000 claims 2
PYILKOIEIHHYGD-UHFFFAOYSA-M sodium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate;dihydrate Chemical compound O.O.[Na+].[O-]C1=NC(=O)N(Cl)C(=O)N1Cl PYILKOIEIHHYGD-UHFFFAOYSA-M 0.000 claims 2
229910052682 stishovite Inorganic materials 0.000 claims 2
229950009390 symclosene Drugs 0.000 claims 2
229910052905 tridymite Inorganic materials 0.000 claims 2
229910052751 metal Inorganic materials 0.000 claims 1
239000002184 metal Substances 0.000 claims 1
229920001451 polypropylene glycol Polymers 0.000 claims 1
239000000463 material Substances 0.000 abstract description 57
238000000034 method Methods 0.000 abstract description 12
238000004519 manufacturing process Methods 0.000 abstract description 11
239000011368 organic material Substances 0.000 abstract description 8
238000009826 distribution Methods 0.000 abstract description 4
230000008569 process Effects 0.000 abstract description 3
239000011248 coating agent Substances 0.000 description 55
238000000576 coating method Methods 0.000 description 52
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 40
239000011162 core material Substances 0.000 description 20
239000000243 solution Substances 0.000 description 20
239000000126 substance Substances 0.000 description 17
239000000047 product Substances 0.000 description 14
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 12
239000007844 bleaching agent Substances 0.000 description 12
238000004140 cleaning Methods 0.000 description 12
239000002245 particle Substances 0.000 description 12
229910052938 sodium sulfate Inorganic materials 0.000 description 12
235000011152 sodium sulphate Nutrition 0.000 description 12
150000001875 compounds Chemical class 0.000 description 10
239000011734 sodium Substances 0.000 description 10
229910052708 sodium Inorganic materials 0.000 description 10
239000008234 soft water Substances 0.000 description 10
229920001577 copolymer Polymers 0.000 description 9
229920001223 polyethylene glycol Polymers 0.000 description 9
239000004094 surface-active agent Substances 0.000 description 9
239000004115 Sodium Silicate Substances 0.000 description 8
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
239000004615 ingredient Substances 0.000 description 8
MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 8
229910052911 sodium silicate Inorganic materials 0.000 description 8
239000007921 spray Substances 0.000 description 8
239000000271 synthetic detergent Substances 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000012141 concentrate Substances 0.000 description 6
238000005538 encapsulation Methods 0.000 description 6
150000004760 silicates Chemical class 0.000 description 6
235000019795 sodium metasilicate Nutrition 0.000 description 6
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
239000002202 Polyethylene glycol Substances 0.000 description 5
239000001506 calcium phosphate Substances 0.000 description 5
238000002156 mixing Methods 0.000 description 5
230000001590 oxidative effect Effects 0.000 description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
230000007935 neutral effect Effects 0.000 description 4
WLGDAKIJYPIYLR-UHFFFAOYSA-N octane-1-sulfonic acid Chemical compound CCCCCCCCS(O)(=O)=O WLGDAKIJYPIYLR-UHFFFAOYSA-N 0.000 description 4
235000021317 phosphate Nutrition 0.000 description 4
150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
239000011591 potassium Substances 0.000 description 4
235000019353 potassium silicate Nutrition 0.000 description 4
238000011012 sanitization Methods 0.000 description 4
239000000344 soap Substances 0.000 description 4
239000011780 sodium chloride Substances 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 4
239000004698 Polyethylene Substances 0.000 description 3
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000003513 alkali Substances 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
229910021538 borax Inorganic materials 0.000 description 3
229910052794 bromium Inorganic materials 0.000 description 3
JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 description 3
229940043256 calcium pyrophosphate Drugs 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
235000010980 cellulose Nutrition 0.000 description 3
150000001805 chlorine compounds Chemical class 0.000 description 3
238000001816 cooling Methods 0.000 description 3
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical class [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
235000019838 diammonium phosphate Nutrition 0.000 description 3
235000019821 dicalcium diphosphate Nutrition 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 3
239000000975 dye Substances 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
CADNYOZXMIKYPR-UHFFFAOYSA-B ferric pyrophosphate Chemical compound [Fe+3].[Fe+3].[Fe+3].[Fe+3].[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O CADNYOZXMIKYPR-UHFFFAOYSA-B 0.000 description 3
239000006260 foam Substances 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 3
239000004137 magnesium phosphate Substances 0.000 description 3
229910000157 magnesium phosphate Inorganic materials 0.000 description 3
229960002261 magnesium phosphate Drugs 0.000 description 3
235000010994 magnesium phosphates Nutrition 0.000 description 3
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
239000008204 material by function Substances 0.000 description 3
239000004200 microcrystalline wax Substances 0.000 description 3
235000019808 microcrystalline wax Nutrition 0.000 description 3
229920000573 polyethylene Polymers 0.000 description 3
229920001296 polysiloxane Polymers 0.000 description 3
235000007686 potassium Nutrition 0.000 description 3
229910000028 potassium bicarbonate Inorganic materials 0.000 description 3
239000011736 potassium bicarbonate Substances 0.000 description 3
235000015497 potassium bicarbonate Nutrition 0.000 description 3
GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 3
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 3
230000000717 retained effect Effects 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 3
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
235000010339 sodium tetraborate Nutrition 0.000 description 3
239000002904 solvent Substances 0.000 description 3
238000009718 spray deposition Methods 0.000 description 3
235000019818 tetrasodium diphosphate Nutrition 0.000 description 3
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
229940078499 tricalcium phosphate Drugs 0.000 description 3
229910000391 tricalcium phosphate Inorganic materials 0.000 description 3
235000019731 tricalcium phosphate Nutrition 0.000 description 3
WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 3
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical class OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
229920000168 Microcrystalline cellulose Polymers 0.000 description 2
JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
239000004111 Potassium silicate Substances 0.000 description 2
239000002250 absorbent Substances 0.000 description 2
230000002745 absorbent Effects 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000009471 action Effects 0.000 description 2
239000003463 adsorbent Substances 0.000 description 2
238000013019 agitation Methods 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
239000004599 antimicrobial Substances 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 2
150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
239000011247 coating layer Substances 0.000 description 2
230000001276 controlling effect Effects 0.000 description 2
230000008878 coupling Effects 0.000 description 2
238000010168 coupling process Methods 0.000 description 2
238000005859 coupling reaction Methods 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
150000004683 dihydrates Chemical class 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
235000019441 ethanol Nutrition 0.000 description 2
150000002366 halogen compounds Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
239000001863 hydroxypropyl cellulose Substances 0.000 description 2
235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
239000011256 inorganic filler Substances 0.000 description 2
229910003475 inorganic filler Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
235000019813 microcrystalline cellulose Nutrition 0.000 description 2
239000008108 microcrystalline cellulose Substances 0.000 description 2
229940016286 microcrystalline cellulose Drugs 0.000 description 2
235000019691 monocalcium phosphate Nutrition 0.000 description 2
229910000150 monocalcium phosphate Inorganic materials 0.000 description 2
229920000847 nonoxynol Polymers 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
239000012766 organic filler Substances 0.000 description 2
150000003014 phosphoric acid esters Chemical class 0.000 description 2
229920001281 polyalkylene Polymers 0.000 description 2
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
229910052913 potassium silicate Inorganic materials 0.000 description 2
IFIDXBCRSWOUSB-UHFFFAOYSA-M potassium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate Chemical compound [K+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-M 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000012545 processing Methods 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
239000011343 solid material Substances 0.000 description 2
241000894007 species Species 0.000 description 2
238000005507 spraying Methods 0.000 description 2
150000003871 sulfonates Chemical class 0.000 description 2
239000000454 talc Substances 0.000 description 2
229910052623 talc Inorganic materials 0.000 description 2
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 2
POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 description 2
239000002562 thickening agent Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
KEPNSIARSTUPGS-UHFFFAOYSA-N 2-n,4-n,6-n-trichloro-1,3,5-triazine-2,4,6-triamine Chemical compound ClNC1=NC(NCl)=NC(NCl)=N1 KEPNSIARSTUPGS-UHFFFAOYSA-N 0.000 description 1
DKUBZUDRKXPHQI-UHFFFAOYSA-N 2-n-chloro-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NCl)=N1 DKUBZUDRKXPHQI-UHFFFAOYSA-N 0.000 description 1
PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
RFGQQOASRSVRPV-UHFFFAOYSA-N 3-carbamoyl-1,1-dichlorourea Chemical compound NC(=O)NC(=O)N(Cl)Cl RFGQQOASRSVRPV-UHFFFAOYSA-N 0.000 description 1
CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
239000005696 Diammonium phosphate Substances 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229920002774 Maltodextrin Polymers 0.000 description 1
239000005913 Maltodextrin Substances 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
241000022563 Rema Species 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
229920000147 Styrene maleic anhydride Polymers 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
125000005599 alkyl carboxylate group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
230000003625 amylolytic effect Effects 0.000 description 1
239000003242 anti bacterial agent Substances 0.000 description 1
230000000845 anti-microbial effect Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
239000001045 blue dye Substances 0.000 description 1
238000005282 brightening Methods 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
ZBZJARSYCHAEND-UHFFFAOYSA-L calcium;dihydrogen phosphate;hydrate Chemical compound O.[Ca+2].OP(O)([O-])=O.OP(O)([O-])=O ZBZJARSYCHAEND-UHFFFAOYSA-L 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
SURLGNKAQXKNSP-DBLYXWCISA-N chlorin Chemical compound C\1=C/2\N/C(=C\C3=N/C(=C\C=4NC(/C=C\5/C=CC/1=N/5)=CC=4)/C=C3)/CC\2 SURLGNKAQXKNSP-DBLYXWCISA-N 0.000 description 1
238000004891 communication Methods 0.000 description 1
230000001010 compromised effect Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000007771 core particle Substances 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
239000007822 coupling agent Substances 0.000 description 1
150000004691 decahydrates Chemical class 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
229910000388 diammonium phosphate Inorganic materials 0.000 description 1
MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical class C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 1
JSYGRUBHOCKMGQ-UHFFFAOYSA-N dichloramine Chemical compound ClNCl JSYGRUBHOCKMGQ-UHFFFAOYSA-N 0.000 description 1
QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical class NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
HFCSXCKLARAMIQ-UHFFFAOYSA-L disodium;sulfate;hydrate Chemical compound O.[Na+].[Na+].[O-]S([O-])(=O)=O HFCSXCKLARAMIQ-UHFFFAOYSA-L 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
229960001484 edetic acid Drugs 0.000 description 1
239000008393 encapsulating agent Substances 0.000 description 1
125000001033 ether group Chemical group 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000004744 fabric Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
238000011049 filling Methods 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
239000011888 foil Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000003205 fragrance Substances 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000000174 gluconic acid Substances 0.000 description 1
235000012208 gluconic acid Nutrition 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
230000005484 gravity Effects 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
229940005740 hexametaphosphate Drugs 0.000 description 1
HUBKGVIIAXRGDJ-UHFFFAOYSA-N hexane-1,6-diol;oxirane Chemical compound C1CO1.OCCCCCCO HUBKGVIIAXRGDJ-UHFFFAOYSA-N 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical class OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
150000003893 lactate salts Chemical class 0.000 description 1
239000011344 liquid material Substances 0.000 description 1
LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
229940035034 maltodextrin Drugs 0.000 description 1
239000000155 melt Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
244000005700 microbiome Species 0.000 description 1
239000002991 molded plastic Substances 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
239000000178 monomer Substances 0.000 description 1
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
TYEDJDJUXHBKNV-UHFFFAOYSA-N n-carbamoyl-n-chloroacetamide Chemical compound CC(=O)N(Cl)C(N)=O TYEDJDJUXHBKNV-UHFFFAOYSA-N 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
231100000956 nontoxicity Toxicity 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical class CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
235000019809 paraffin wax Nutrition 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
150000003009 phosphonic acids Chemical class 0.000 description 1
229920001983 poloxamer Polymers 0.000 description 1
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
230000002797 proteolythic effect Effects 0.000 description 1
229940048084 pyrophosphate Drugs 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
230000000284 resting effect Effects 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000000779 smoke Substances 0.000 description 1
QHFDHWJHIAVELW-UHFFFAOYSA-M sodium;4,6-dioxo-1h-1,3,5-triazin-2-olate Chemical compound [Na+].[O-]C1=NC(=O)NC(=O)N1 QHFDHWJHIAVELW-UHFFFAOYSA-M 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
125000003107 substituted aryl group Chemical group 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
239000013638 trimer Substances 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
229940117958 vinyl acetate Drugs 0.000 description 1
239000004034 viscosity adjusting agent Substances 0.000 description 1
239000001993 wax Substances 0.000 description 1
GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
229940100530 zinc ricinoleate Drugs 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0052—Cast detergent compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Confectionery (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA 607911 1989-03-31 1989-08-09 Cast detersive systems having a stable halogen source in the presence of readily oxidizable organics Expired - Lifetime CA1329102C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US33169589A	1989-03-31	1989-03-31
US07/331,695		1989-03-31

Publications (1)

Publication Number	Publication Date
CA1329102C true CA1329102C (en)	1994-05-03

Family

ID=23294981

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 607911 Expired - Lifetime CA1329102C (en)	1989-03-31	1989-08-09	Cast detersive systems having a stable halogen source in the presence of readily oxidizable organics

Country Status (8)

Country	Link
EP (1)	EP0465461B1 (de)
JP (1)	JP2557991B2 (de)
AU (2)	AU4051289A (de)
CA (1)	CA1329102C (de)
DE (1)	DE68910701T2 (de)
MX (1)	MX170438B (de)
NZ (1)	NZ230421A (de)
WO (1)	WO1990012081A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5397506A (en) *	1993-08-20	1995-03-14	Ecolab Inc.	Solid cleaner
US5474698A (en) *	1993-12-30	1995-12-12	Ecolab Inc.	Urea-based solid alkaline cleaning composition
CA2188256A1 (en) *	1994-06-14	1995-12-21	Steven E. Lentsch	Improved performance cast detergent
JP6468734B2 (ja) *	2013-12-27	2019-02-13	株式会社ニイタカ	カートリッジ洗浄剤
JP5801941B1 (ja) *	2014-11-21	2015-10-28	株式会社ニイタカ	洗浄剤組成物、食器洗浄方法、液体洗浄剤組成物用キット及びカートリッジ洗浄剤
JP6462028B2 (ja) *	2016-03-31	2019-01-30	株式会社Adeka	溶融固形型洗浄剤組成物
EP3447114B1 (de) *	2016-04-22	2023-08-30	Shikoku Chemicals Corporation	Material mit festem bleichmittel und reinigungsmittelzusammensetzung
JP7252601B2 (ja) *	2019-02-08	2023-04-05	株式会社ニイタカ	固形洗浄剤組成物、カートリッジ洗浄剤、洗浄方法、及び、微生物の除菌方法又は菌叢凝塊の除去方法
JP7420873B1 (ja) *	2022-07-04	2024-01-23	ユシロ化学工業株式会社	洗濯槽用洗剤、及び洗濯槽の洗浄方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3637509A (en) *	1970-02-10	1972-01-25	Grace W R & Co	Chlorinated machine dishwashing composition and process
US4078099A (en) *	1976-08-25	1978-03-07	Lever Brothers Company	Encapsulated bleaches and methods for their preparation
IT1110274B (it) *	1978-02-07	1985-12-23	Economics Lab	Articolo contenente detersivo colato e metodo di sua preparazione e suo impiego
DE3634812A1 (de) *	1986-10-13	1988-04-14	Henkel Kgaa	Verfahren zur herstellung schmelzblockfoermiger, alkalihydroxid- und gegebenenfalls auch aktivchlorhaltiger mittel fuer das maschinelle reinigen von geschirr
US4830773A (en) *	1987-07-10	1989-05-16	Ecolab Inc.	Encapsulated bleaches
AU605573B2 (en) *	1987-08-12	1991-01-17	Ecolab Inc.	Solid cast warewashing composition

1989
- 1989-08-01 WO PCT/US1989/003313 patent/WO1990012081A1/en active IP Right Grant
- 1989-08-01 JP JP1508658A patent/JP2557991B2/ja not_active Expired - Lifetime
- 1989-08-01 DE DE68910701T patent/DE68910701T2/de not_active Expired - Fee Related
- 1989-08-01 AU AU40512/89A patent/AU4051289A/en not_active Abandoned
- 1989-08-01 EP EP19890909286 patent/EP0465461B1/de not_active Expired - Lifetime
- 1989-08-09 CA CA 607911 patent/CA1329102C/en not_active Expired - Lifetime
- 1989-08-21 MX MX1726589A patent/MX170438B/es unknown
- 1989-08-24 NZ NZ23042189A patent/NZ230421A/xx unknown
1994
- 1994-02-07 AU AU54966/94A patent/AU657239B2/en not_active Ceased

Also Published As

Publication number	Publication date
MX170438B (es)	1993-08-23
DE68910701T2 (de)	1994-06-01
JPH04504271A (ja)	1992-07-30
AU657239B2 (en)	1995-03-02
AU4051289A (en)	1990-11-05
WO1990012081A1 (en)	1990-10-18
EP0465461A1 (de)	1992-01-15
NZ230421A (en)	1991-09-25
AU5496694A (en)	1994-04-14
JP2557991B2 (ja)	1996-11-27
EP0465461B1 (de)	1993-11-10
DE68910701D1 (de)	1993-12-16

Publication	Publication Date	Title
US5078301A (en)	1992-01-07	Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use
US5234615A (en)	1993-08-10	Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use
US5384364A (en)	1995-01-24	Stabilized detersive-system containing water soluble film article
US5198198A (en)	1993-03-30	Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use
US4931203A (en)	1990-06-05	Method for making an automatic dishwashing detergent powder by spraying drying and post-adding nonionic detergent
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2011-05-03	MKEX	Expiry	Effective date: 20110503