CA1259261A - Hair treating composition - Google Patents
Hair treating compositionInfo
- Publication number
- CA1259261A CA1259261A CA000476412A CA476412A CA1259261A CA 1259261 A CA1259261 A CA 1259261A CA 000476412 A CA000476412 A CA 000476412A CA 476412 A CA476412 A CA 476412A CA 1259261 A CA1259261 A CA 1259261A
- Authority
- CA
- Canada
- Prior art keywords
- hair
- composition
- weight
- abrasion
- panthenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/04—Dandruff
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Lubricants (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
HAIR TREATING COMPOSITION
Abstract of the Invention An improved hair treating or conditioning composition that decreases the friction between hairs thereby facilitating in comb-ing and brushing of hair treated therewith contains a formulation which is a mixture of d-panthenyl ethyl ether and d-panthenol in a weight ratio of about 9 parts d-panthenyl ethyl ether to about 1 part d-panthenol. Such hair treating or conditioning compositions also exhibit decreased damaged to hair treated therewith due at least in part to a decrease or reduction in abrasion between hairs.
Abstract of the Invention An improved hair treating or conditioning composition that decreases the friction between hairs thereby facilitating in comb-ing and brushing of hair treated therewith contains a formulation which is a mixture of d-panthenyl ethyl ether and d-panthenol in a weight ratio of about 9 parts d-panthenyl ethyl ether to about 1 part d-panthenol. Such hair treating or conditioning compositions also exhibit decreased damaged to hair treated therewith due at least in part to a decrease or reduction in abrasion between hairs.
Description
- ~ 1;2 S~26~
HAIR TREATING COMPOSITION
Field of the Invention This invention relates to a new formultion for inclusion in hair treating or conditioning compositions and to the resulting hair treating or conditioning compositions containiny such formu-lation.
BACKGROUND OF THE INVENTION
It has been recognized that after shampooing the hair it is desirable to utilize hair treating or conditioning compositions to improve the comb out and hair setting characteristics as well as to provide less entangling of the hair. Although a multitude of products have been suggested and marketed for such use, none have been without their drawbacks and disadvantages. Moreover, there is still a desire for products having improved comb out, hair setting and detangling characteristics.
Hair has also been found to be subject to abrasion damage caused by a multitude of factors such as grooming~ combing, towelling and the like Such hair abrasion is certainly one of the most severe damages a hair fiber is subjected to during its life cycle on the scalp. Such damage results in the removal of the protective cuticle layer and consequent exposure of the more fragile fibril/matrix complex arrangement of the cortex. Hereto-fore it has been the aim of a large number of capillary treatments to prevent or reduce such abrasion damage. This is generally attempted by coating the hair fiber with a polymeric substance designed to protect the hair against further damage.
:, ,,, ,, ~ .. . ~, 2S926~
Users have not generally found such polymeric coating to be that desirable or effective.
It is therefore an object of this invention to provide an improved hair treating or conditioning composition that avoids or substantially lessens these drawbacks and disadvantages in previously employed products and/or which new compositions pre-vent or reduce abrasion damage -to hair and which when used on hair provide improved comb-out, hair setting and detangling due to a reduction in hair friction.
Summary of the Invention According to this invention a formulation of 9 parts by weight d-panthenyl e-thyl ether and 1 part by weight d-panthenol when utilized in a hair conditioning or treating composition provides compositions which impart a decrease in friction be-tween hairs resulting in less difficulty to comb and brush and also in less entangling of hairs. Such compositions allow for improvement in comb-out and hair setting. Additional, such compositions also prevent or reduce abrasion damage between hairs.
Brief Description of the Drawing Figure 1 represents the results obtained from hair fric-tion measurements.
Detailed Description of the Invention The formulation of 9 parts d-panthenyl ethyl ether and 1 part d-panthenol can be incorporated in hair conditioning or treating compositions in an amount generally of from about 0.05% by weight to about 10% by weight of the composition.
Most preferably about 0.1% to 0.5% of the formulation is em-ployed in the composition. It is surprising that hair care compositions containing the 9/1 formulation of this invention do not induce a large increase in ~ V l~
friction immediately (within two minutes) and do decrease hair abrasion after treatment with such compositions since hair treated with a similar hair composition commercially available but con-taining 3 parts by weight d-panthenyl ethyl ether to every seven parts by weight d-panthenol exhibits both a significantly large increase in hair friction immediately after treatment and in-creases rather than decreases hair abrasion damage.
The formulation of this invention can be incorporate into any suitable hair conditioning or treating compositions of non wash-out product form such as lotions, creams/ solutions, gels, spraysand the like, but preferably in lotion compositions. The hair composition can contain other ingredients normally or customarily found in such compositions such as antibacterial agents, emulsi-fiers, dye, colorants, perfumes and the like. Also, the formula-tion may be incorporated into hair washing preparations such asshampoos, hair and scalp conditioners and the like.
The novel formulation of this invention can be prepared by simply mixing 9 parts by weight d-panthenyl ethyl ether with one part by weight of d-panthenol. d-Panthenol is (R)-2,4-dihydroxy-N-(3-hydroxypropyl~-3,3-dimethylbutamide. Such formulations are then suitable for incorporation into any suitable hair care compo-sition in an amount of from about 0.05% by weight to about 1~ by weight, preerably about 0.1~ to 0.5~ by weight.
The unexpected absence of large increases in hair friction immediately after use and decrease in hair abrasion after use of the hair care compvsition of this invention is illustrated by the following comparative tests.
RVL~
1~5~261 Hair Friction Tests -Hair samples were obtained from the same volunteer and washed with a commercially available shampoo. The hair samples were then treated with a commercially available hair composition containing 0.1% by weight of d-panthenyl ethyl ether and d-panthenol in a weight ratio of these two components of 3 to 7 and by a corres-ponding hair care composition of this invention of the identical composition except for the replacement of the 0.1% 3 to 7 ratio components with 0.1% by weight of the formulation of this inven tion, namely a formulation of 9 parts by weight d-panthenyl ethyl ether to 1 part by weight d-panthenol. the composition of these two hair care composition is set out in TABLE 1 hereinafter.
Invention Commercial Composition Composition Containing Containing 0.1 9/1 0.1 3/7 COmDOnentS Ratio w/v Ratio w/v Absolute Ethyl alcohol 35.00 v/v 35.00 v/v Antibacterial agent 0.050 0.050 Perfume 0.100 0.100 Non-ionic Emulsifier 0.075 0.075 d-Panthenyl ethyl ether 0.09 0.03 d-Panthenol 0.01 0.07 Ultraviolet filter agent 0.025 0.D25 Colorant 0.00062 0.00062 Lactic acid q.s. pH 5.5 5.5 Deionised water q.s. 100 ml 100 ml :lZS9~
The test apparatus and methodology consisted of a group of 4 hairs of the treated hair sample which is threaded perpendicularly through a hair bundle made up of about 40 hairs. The hair to hair friction was determined by measuring the force required to pull the group of 6 hairs through the tightly packed hair bundle using an electrodynamometer.
A maximum of 8 grams force was exerted by the electrodyna-mometer to pull the group of 6 hairs, whereas 6.5 grams weight was attached to the opposite end of the group of 6 hairs in order to bring them back to their original position upon release of the tension exerted by the electrodynamometer. During each measure-ment, the force generated by the electrodynamometer to pull the hair through the bundle increased linearly from 5 to 8 grams, at a raee of 6 mg per second, which induced a translation speed of 0.23 mm/second during the movement of the hairs across each other.
The hair care compositions were applied in a standardised manner by wiping each of the 6 hairs using a paper tissue soaked with the composition.
Each measurement which was carried out before and at stan-dardised time intervals after treatment was repeated three times.
Each experiment was carried out 5 times with the same hair care compositions using hair sample from the same donor.
The results of the hair friction measurements are shown in Fig 1 and it will be noted that whereas the commercial composition containing 0.1% of the 3/7 formulation induced a large increase in hair friction at two minutes the composition containing .1% of the RVL-l284 - lZS~Z6~
9/t formulation induced no large increase in hair friction at two minutes, and a substantial decrease in hair friction at five minutes onward, post treatment. Since combing or brushing of the hair generally occurs within five minutes of shampooing and condi-tioning of the hair, the composition of this invention permitsmuch easier combing, brushing and hair setting and much less entangling of the hair.
~air Abrasion Test Hair samples were taken from the same switch in a hair bank and activated. Before conducting the abrasion test, a large hair switch was made radioactive after soaking 1 hour in a solution of 14C labelled amino acids which composition is similar to the com-position of keratin polypeptides.
The excess of solution was then blotted off and the hair samples allowed to dry at ambient conditions. The solution of amino acids employed for activation was the following:
L - Alanine 9.4%
L - Arginine 7.0%
L - Aspartic acid10.0~
L - Flutamic acid9.0%
L - Glycine 6.0~
L - Histidine 1.5%
L - Isoleneine 6.0%
L - Leucine 12.5%
L - Lysine 5.0%
L - Phenylalamine7.5%
L - Proline 5.5~
~ 2~ RVL-1284 ~ ~.
L - Serine 3.0%
L - Threonine 5.5%
L - Thyrosine 6.0 L - Valine 6.0~
Treatment of the hair samples with hair care compositions was done by carefully wiping one half of the previously activated hair switch with a piece of absorbent paper soaked with the composi-tion. The other half of the radioactive hair switch was used as a control and remained untreated.
Two hair care composition treated and two untreated hair switches (about 16 cm in length) were wrapped around a rotating cylinder which had been previously covered with non radioactive hair fibers, using double sided adhesive tape. The contact between the hair samples and the rotating cylinder was achieved by hanging a 9 gram lead weight on the free end of each hair sample~
the other end being maintained in a fixed position by a clamp.
The abrasion was achieved on 7 cm along the hair by rotating the cylinder at 780 rpm in order to induce a significant friction in a direction against the scales of the hair.
After being abraded, each hair sample was cut in 2 cm length segments from the distal end to the proximal part, and its radio-activity assayed by liquid scintillation counting. In such condi-tions, a strong abrasion should result in a significant diminution of the activity of the hair segments which were in contact with the rotating cylinder, i.e, from 4 cm to 11 cm from the hair dis-tal end.
S9~61 The composition of the hair care composition of this inven-tion and of a commercially available hair care composition used in this test are is set forth in the following TABLE 2.
Invention Commercial Composition Composition Containing Containing 0.1% 9/1 0.1% 3/7 Composition Ratio w/v Ratio w/v .
Absolute Ethyl alcohol 35.00 v/v 35.00 v/v Antifungal agent 0.02 0.02 Perfume 0.100 0.100 Non-ionic emulsifier 0.075 0.075 d-Panthenyl ethyl ether 0.09 0.03 d Panthenol 0.01 0.07 Lactic acid q.s. pH 5.5 5.5 Colorant 0.00097 0.00097 Deionised water q.s. 100.00 ml 100.00 ml The average results obtained after the abrasion during 30 minutes of hair treated with the hair care composition of this invention and the untreated hair clearly reveal a significant diminution of activity between segment no. 2 and segment no. 7 as compared to the non-abraded hair. This decrease of the radio-activity has been caused by the removal of radiolabelled cuticle scales and other hair debris during the abrasion, and represents the extent of damage induced by the continuous friction between the hair.
12S~26~
In such conditions, it is possible to define an Abrasion Index (AI) as the ratio of the quantity of keratin lost during the abrasion to the quantity of keratin which would have been removed if the abrasion would have been total.
Paired comparisons of the Abrasion Indices obtained on treated hair and untreated hair indicate a significant (p=0.052) reduction of abrasion of the samples treated with the hair care composition of this invention. This is clearly reflected in the average Abrasion Indices, calculated for the un-treated hair (AI = 18.4 + 5.10) and the treated hairs (AI = 9.7 ~ 3.03).
Similar tests carried out on hair samples treated with the commercial hair care composition revealed in increase of the abra-sion after treatment with the commercial composition as early as as compared to untreated hair. The average Abrasion Index ca culated for 16 experiments confirms this observation, with AI =
13.1 + 1.95 for commercial composition treated hair, and AI = 8.6 + 2.78 for the un-treated hair.
Thus, whereas the commercially available hair care composi-tion induced an increase in hair abrasion, the hair care composition of this invention decreased hair abrasion.
_9_
HAIR TREATING COMPOSITION
Field of the Invention This invention relates to a new formultion for inclusion in hair treating or conditioning compositions and to the resulting hair treating or conditioning compositions containiny such formu-lation.
BACKGROUND OF THE INVENTION
It has been recognized that after shampooing the hair it is desirable to utilize hair treating or conditioning compositions to improve the comb out and hair setting characteristics as well as to provide less entangling of the hair. Although a multitude of products have been suggested and marketed for such use, none have been without their drawbacks and disadvantages. Moreover, there is still a desire for products having improved comb out, hair setting and detangling characteristics.
Hair has also been found to be subject to abrasion damage caused by a multitude of factors such as grooming~ combing, towelling and the like Such hair abrasion is certainly one of the most severe damages a hair fiber is subjected to during its life cycle on the scalp. Such damage results in the removal of the protective cuticle layer and consequent exposure of the more fragile fibril/matrix complex arrangement of the cortex. Hereto-fore it has been the aim of a large number of capillary treatments to prevent or reduce such abrasion damage. This is generally attempted by coating the hair fiber with a polymeric substance designed to protect the hair against further damage.
:, ,,, ,, ~ .. . ~, 2S926~
Users have not generally found such polymeric coating to be that desirable or effective.
It is therefore an object of this invention to provide an improved hair treating or conditioning composition that avoids or substantially lessens these drawbacks and disadvantages in previously employed products and/or which new compositions pre-vent or reduce abrasion damage -to hair and which when used on hair provide improved comb-out, hair setting and detangling due to a reduction in hair friction.
Summary of the Invention According to this invention a formulation of 9 parts by weight d-panthenyl e-thyl ether and 1 part by weight d-panthenol when utilized in a hair conditioning or treating composition provides compositions which impart a decrease in friction be-tween hairs resulting in less difficulty to comb and brush and also in less entangling of hairs. Such compositions allow for improvement in comb-out and hair setting. Additional, such compositions also prevent or reduce abrasion damage between hairs.
Brief Description of the Drawing Figure 1 represents the results obtained from hair fric-tion measurements.
Detailed Description of the Invention The formulation of 9 parts d-panthenyl ethyl ether and 1 part d-panthenol can be incorporated in hair conditioning or treating compositions in an amount generally of from about 0.05% by weight to about 10% by weight of the composition.
Most preferably about 0.1% to 0.5% of the formulation is em-ployed in the composition. It is surprising that hair care compositions containing the 9/1 formulation of this invention do not induce a large increase in ~ V l~
friction immediately (within two minutes) and do decrease hair abrasion after treatment with such compositions since hair treated with a similar hair composition commercially available but con-taining 3 parts by weight d-panthenyl ethyl ether to every seven parts by weight d-panthenol exhibits both a significantly large increase in hair friction immediately after treatment and in-creases rather than decreases hair abrasion damage.
The formulation of this invention can be incorporate into any suitable hair conditioning or treating compositions of non wash-out product form such as lotions, creams/ solutions, gels, spraysand the like, but preferably in lotion compositions. The hair composition can contain other ingredients normally or customarily found in such compositions such as antibacterial agents, emulsi-fiers, dye, colorants, perfumes and the like. Also, the formula-tion may be incorporated into hair washing preparations such asshampoos, hair and scalp conditioners and the like.
The novel formulation of this invention can be prepared by simply mixing 9 parts by weight d-panthenyl ethyl ether with one part by weight of d-panthenol. d-Panthenol is (R)-2,4-dihydroxy-N-(3-hydroxypropyl~-3,3-dimethylbutamide. Such formulations are then suitable for incorporation into any suitable hair care compo-sition in an amount of from about 0.05% by weight to about 1~ by weight, preerably about 0.1~ to 0.5~ by weight.
The unexpected absence of large increases in hair friction immediately after use and decrease in hair abrasion after use of the hair care compvsition of this invention is illustrated by the following comparative tests.
RVL~
1~5~261 Hair Friction Tests -Hair samples were obtained from the same volunteer and washed with a commercially available shampoo. The hair samples were then treated with a commercially available hair composition containing 0.1% by weight of d-panthenyl ethyl ether and d-panthenol in a weight ratio of these two components of 3 to 7 and by a corres-ponding hair care composition of this invention of the identical composition except for the replacement of the 0.1% 3 to 7 ratio components with 0.1% by weight of the formulation of this inven tion, namely a formulation of 9 parts by weight d-panthenyl ethyl ether to 1 part by weight d-panthenol. the composition of these two hair care composition is set out in TABLE 1 hereinafter.
Invention Commercial Composition Composition Containing Containing 0.1 9/1 0.1 3/7 COmDOnentS Ratio w/v Ratio w/v Absolute Ethyl alcohol 35.00 v/v 35.00 v/v Antibacterial agent 0.050 0.050 Perfume 0.100 0.100 Non-ionic Emulsifier 0.075 0.075 d-Panthenyl ethyl ether 0.09 0.03 d-Panthenol 0.01 0.07 Ultraviolet filter agent 0.025 0.D25 Colorant 0.00062 0.00062 Lactic acid q.s. pH 5.5 5.5 Deionised water q.s. 100 ml 100 ml :lZS9~
The test apparatus and methodology consisted of a group of 4 hairs of the treated hair sample which is threaded perpendicularly through a hair bundle made up of about 40 hairs. The hair to hair friction was determined by measuring the force required to pull the group of 6 hairs through the tightly packed hair bundle using an electrodynamometer.
A maximum of 8 grams force was exerted by the electrodyna-mometer to pull the group of 6 hairs, whereas 6.5 grams weight was attached to the opposite end of the group of 6 hairs in order to bring them back to their original position upon release of the tension exerted by the electrodynamometer. During each measure-ment, the force generated by the electrodynamometer to pull the hair through the bundle increased linearly from 5 to 8 grams, at a raee of 6 mg per second, which induced a translation speed of 0.23 mm/second during the movement of the hairs across each other.
The hair care compositions were applied in a standardised manner by wiping each of the 6 hairs using a paper tissue soaked with the composition.
Each measurement which was carried out before and at stan-dardised time intervals after treatment was repeated three times.
Each experiment was carried out 5 times with the same hair care compositions using hair sample from the same donor.
The results of the hair friction measurements are shown in Fig 1 and it will be noted that whereas the commercial composition containing 0.1% of the 3/7 formulation induced a large increase in hair friction at two minutes the composition containing .1% of the RVL-l284 - lZS~Z6~
9/t formulation induced no large increase in hair friction at two minutes, and a substantial decrease in hair friction at five minutes onward, post treatment. Since combing or brushing of the hair generally occurs within five minutes of shampooing and condi-tioning of the hair, the composition of this invention permitsmuch easier combing, brushing and hair setting and much less entangling of the hair.
~air Abrasion Test Hair samples were taken from the same switch in a hair bank and activated. Before conducting the abrasion test, a large hair switch was made radioactive after soaking 1 hour in a solution of 14C labelled amino acids which composition is similar to the com-position of keratin polypeptides.
The excess of solution was then blotted off and the hair samples allowed to dry at ambient conditions. The solution of amino acids employed for activation was the following:
L - Alanine 9.4%
L - Arginine 7.0%
L - Aspartic acid10.0~
L - Flutamic acid9.0%
L - Glycine 6.0~
L - Histidine 1.5%
L - Isoleneine 6.0%
L - Leucine 12.5%
L - Lysine 5.0%
L - Phenylalamine7.5%
L - Proline 5.5~
~ 2~ RVL-1284 ~ ~.
L - Serine 3.0%
L - Threonine 5.5%
L - Thyrosine 6.0 L - Valine 6.0~
Treatment of the hair samples with hair care compositions was done by carefully wiping one half of the previously activated hair switch with a piece of absorbent paper soaked with the composi-tion. The other half of the radioactive hair switch was used as a control and remained untreated.
Two hair care composition treated and two untreated hair switches (about 16 cm in length) were wrapped around a rotating cylinder which had been previously covered with non radioactive hair fibers, using double sided adhesive tape. The contact between the hair samples and the rotating cylinder was achieved by hanging a 9 gram lead weight on the free end of each hair sample~
the other end being maintained in a fixed position by a clamp.
The abrasion was achieved on 7 cm along the hair by rotating the cylinder at 780 rpm in order to induce a significant friction in a direction against the scales of the hair.
After being abraded, each hair sample was cut in 2 cm length segments from the distal end to the proximal part, and its radio-activity assayed by liquid scintillation counting. In such condi-tions, a strong abrasion should result in a significant diminution of the activity of the hair segments which were in contact with the rotating cylinder, i.e, from 4 cm to 11 cm from the hair dis-tal end.
S9~61 The composition of the hair care composition of this inven-tion and of a commercially available hair care composition used in this test are is set forth in the following TABLE 2.
Invention Commercial Composition Composition Containing Containing 0.1% 9/1 0.1% 3/7 Composition Ratio w/v Ratio w/v .
Absolute Ethyl alcohol 35.00 v/v 35.00 v/v Antifungal agent 0.02 0.02 Perfume 0.100 0.100 Non-ionic emulsifier 0.075 0.075 d-Panthenyl ethyl ether 0.09 0.03 d Panthenol 0.01 0.07 Lactic acid q.s. pH 5.5 5.5 Colorant 0.00097 0.00097 Deionised water q.s. 100.00 ml 100.00 ml The average results obtained after the abrasion during 30 minutes of hair treated with the hair care composition of this invention and the untreated hair clearly reveal a significant diminution of activity between segment no. 2 and segment no. 7 as compared to the non-abraded hair. This decrease of the radio-activity has been caused by the removal of radiolabelled cuticle scales and other hair debris during the abrasion, and represents the extent of damage induced by the continuous friction between the hair.
12S~26~
In such conditions, it is possible to define an Abrasion Index (AI) as the ratio of the quantity of keratin lost during the abrasion to the quantity of keratin which would have been removed if the abrasion would have been total.
Paired comparisons of the Abrasion Indices obtained on treated hair and untreated hair indicate a significant (p=0.052) reduction of abrasion of the samples treated with the hair care composition of this invention. This is clearly reflected in the average Abrasion Indices, calculated for the un-treated hair (AI = 18.4 + 5.10) and the treated hairs (AI = 9.7 ~ 3.03).
Similar tests carried out on hair samples treated with the commercial hair care composition revealed in increase of the abra-sion after treatment with the commercial composition as early as as compared to untreated hair. The average Abrasion Index ca culated for 16 experiments confirms this observation, with AI =
13.1 + 1.95 for commercial composition treated hair, and AI = 8.6 + 2.78 for the un-treated hair.
Thus, whereas the commercially available hair care composi-tion induced an increase in hair abrasion, the hair care composition of this invention decreased hair abrasion.
_9_
Claims (6)
- The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
l. A hair care composition comprising 9 parts by weight d-panthenyl ethyl ether and 1 part by weight d-panthenol. - 2. In a hair care composition for the treatment of hair the improvement comprising employing in said composition 9 parts by weight d-panthenyl ethyl ether per 1 part by weight d-panthenol.
- 3. A hair care composition of claim 2 wherein there is present in said composition from about 0.05% by weight to ab-out 1.0% by weight of a formulation of 9 parts d-panthenyl ethyl ether and 1 part d-panthenol.
- 4. A hair care composition of claim 3 wherein the for-mulation is present in the composition at about 0.1% to 0.5%
by weight. - 5. A hair care composition of claim 3 comprising about
- 6. A hair care composition of claim 3 comprising about
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP84103104A EP0155333B1 (en) | 1984-03-21 | 1984-03-21 | Hair treating composition |
| EP84103104.0 | 1984-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1259261A true CA1259261A (en) | 1989-09-12 |
Family
ID=8191836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000476412A Expired CA1259261A (en) | 1984-03-21 | 1985-03-13 | Hair treating composition |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4705681A (en) |
| EP (1) | EP0155333B1 (en) |
| JP (1) | JPS60209512A (en) |
| AT (1) | ATE45085T1 (en) |
| AU (1) | AU566817B2 (en) |
| CA (1) | CA1259261A (en) |
| DE (1) | DE3479187D1 (en) |
| DK (1) | DK165163C (en) |
| ES (1) | ES8602394A1 (en) |
| IE (1) | IE57731B1 (en) |
| NO (1) | NO165526C (en) |
| NZ (1) | NZ211276A (en) |
| ZA (1) | ZA851775B (en) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63502104A (en) * | 1985-11-22 | 1988-08-18 | アゲイブ・コスメティックス・プロプライアタリ−・リミテッド | hair treatment |
| US5069898A (en) * | 1989-04-24 | 1991-12-03 | Revlon, Inc. | Hair enrichment composition and method of use |
| US5227164A (en) * | 1990-01-29 | 1993-07-13 | Lundmark Larry D | Hair treatment composition and method |
| US5041285A (en) * | 1990-01-29 | 1991-08-20 | Larry D. Lundmark | Method of treating the hair with an allanoyoin-panthenol product |
| WO1993021899A1 (en) * | 1992-05-05 | 1993-11-11 | The Procter & Gamble Company | Acne treating composition |
| AU668559B2 (en) * | 1992-06-03 | 1996-05-09 | Unilever Plc | Improvements relating to cosmetic compositions |
| ES2061407B1 (en) * | 1993-05-17 | 1995-06-16 | Cid Carlos Arturo Castilla | PRODUCT IN THE FORM OF ANTIFUNGAL AND ANTIBACTERIAL SHAMPOO OF RAPID ACTION. |
| FR2714825B1 (en) * | 1994-01-11 | 1996-02-02 | Oreal | Detergent cosmetic compositions for hair use and the use thereof. |
| US6156295A (en) * | 1994-05-10 | 2000-12-05 | Neutrogena Corporation | Heat-safe hair preparation and method of using same |
| US5750122A (en) * | 1996-01-16 | 1998-05-12 | The Procter & Gamble Company | Compositions for treating hair or skin |
| US5674478A (en) * | 1996-01-12 | 1997-10-07 | The Procter & Gamble Company | Hair conditioning compositions |
| JPH11502874A (en) * | 1996-01-16 | 1999-03-09 | ザ、プロクター、エンド、ギャンブル、カンパニー | Hair conditioning composition |
| US7585824B2 (en) | 2002-10-10 | 2009-09-08 | International Flavors & Fragrances Inc. | Encapsulated fragrance chemicals |
| BR0303954A (en) | 2002-10-10 | 2004-09-08 | Int Flavors & Fragrances Inc | Composition, fragrance, method for dividing an olfactory effective amount of fragrance into a non-rinse and non-rinse product |
| FR2851655B1 (en) * | 2003-02-24 | 2006-01-27 | Oreal | DEVICE FOR MAKING A SAMPLING OF MATTER ON KERATIN FIBERS, IN PARTICULAR HAIR |
| US20050112152A1 (en) | 2003-11-20 | 2005-05-26 | Popplewell Lewis M. | Encapsulated materials |
| US7105064B2 (en) | 2003-11-20 | 2006-09-12 | International Flavors & Fragrances Inc. | Particulate fragrance deposition on surfaces and malodour elimination from surfaces |
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| US7419943B2 (en) | 2004-08-20 | 2008-09-02 | International Flavors & Fragrances Inc. | Methanoazuenofurans and methanoazulenone compounds and uses of these compounds as fragrance materials |
| US7594594B2 (en) | 2004-11-17 | 2009-09-29 | International Flavors & Fragrances Inc. | Multi-compartment storage and delivery containers and delivery system for microencapsulated fragrances |
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| US7833960B2 (en) | 2006-12-15 | 2010-11-16 | International Flavors & Fragrances Inc. | Encapsulated active material containing nanoscaled material |
| WO2008143862A1 (en) | 2007-05-14 | 2008-11-27 | Amcol International Corporation | Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles |
| CA2725814A1 (en) | 2008-02-08 | 2009-08-13 | Amcol International Corporation | Compositions containing cationically surface-modified microparticulate carrier for benefit agents |
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| EP2268782A2 (en) | 2008-04-11 | 2011-01-05 | Amcol International Corporation | Multilayer fragrance encapsulation |
| US7915215B2 (en) | 2008-10-17 | 2011-03-29 | Appleton Papers Inc. | Fragrance-delivery composition comprising boron and persulfate ion-crosslinked polyvinyl alcohol microcapsules and method of use thereof |
| CN102120167B (en) | 2009-09-18 | 2014-10-29 | 国际香料和香精公司 | encapsulated active material |
| MX369325B (en) | 2011-03-18 | 2019-11-05 | Int Flavors & Fragrances Inc | Microcapsules produced from blended sol-gel precursors and method for producing the same. |
| MX361658B (en) | 2013-08-15 | 2018-12-13 | Int Flavors & Fragrances Inc | Polyurea or polyurethane capsules. |
| US9610228B2 (en) | 2013-10-11 | 2017-04-04 | International Flavors & Fragrances Inc. | Terpolymer-coated polymer encapsulated active material |
| ES2658226T3 (en) | 2013-10-18 | 2018-03-08 | International Flavors & Fragrances Inc. | Fluid and stable formulation of silica capsules |
| JP6227799B2 (en) | 2013-11-11 | 2017-11-08 | インターナショナル フレーバーズ アンド フラグランシズ インコーポレイテッド | Multicapsule composition |
| WO2016172699A1 (en) | 2015-04-24 | 2016-10-27 | International Flavors & Fragrances Inc. | Delivery systems and methods of preparing the same |
| US10113943B2 (en) * | 2015-06-02 | 2018-10-30 | Conopco, Inc. | Multiple aggressor hair assessment method |
| US10226544B2 (en) | 2015-06-05 | 2019-03-12 | International Flavors & Fragrances Inc. | Malodor counteracting compositions |
| WO2018053356A1 (en) | 2016-09-16 | 2018-03-22 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
| US20170204223A1 (en) | 2016-01-15 | 2017-07-20 | International Flavors & Fragrances Inc. | Polyalkoxy-polyimine adducts for use in delayed release of fragrance ingredients |
| BR112018016806B1 (en) | 2016-02-18 | 2021-11-16 | International Flavors & Fragrances Inc. | COMPOSITION OF MICROCAPSULA, E, CONSUMER PRODUCTS |
| ES2995338T3 (en) | 2016-07-01 | 2025-02-10 | Int Flavors & Fragrances Inc | Stable microcapsule compositions |
| US20180085291A1 (en) | 2016-09-28 | 2018-03-29 | International Flavors & Fragrances Inc. | Microcapsule compositions containing amino silicone |
| EP3897522A4 (en) | 2018-12-18 | 2023-03-22 | International Flavors & Fragrances Inc. | Microcapsule compositions |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR35919E (en) * | 1926-02-24 | |||
| FR1268412A (en) * | 1957-08-20 | 1961-08-04 | Hoffmann La Roche | Method for the stabilization of panthenol |
| FR1200498A (en) * | 1958-06-26 | 1959-12-22 | Oreal | New hair composition |
| US3322635A (en) * | 1961-03-30 | 1967-05-30 | Hoffmann La Roche | Cosmetic composition exhibiting pantothenic acid activity |
| BE619352A (en) * | 1961-06-26 | |||
| US3251741A (en) * | 1963-01-16 | 1966-05-17 | Hoffmann La Roche | Hair spray comprising tri-(p-aminobenzoyl) esters of pantothenyl alcohol |
| US4201235A (en) * | 1978-01-03 | 1980-05-06 | Mare Corporation | Amino acid-vitamin formulations for skin, hair and scalp conditioners |
| GB1603639A (en) * | 1978-05-26 | 1981-11-25 | Haggar H | Composition for application to the hair and scalp |
| US4478853A (en) * | 1982-05-17 | 1984-10-23 | S. C. Johnson & Son, Inc. | Skin conditioning composition |
-
1984
- 1984-03-21 EP EP84103104A patent/EP0155333B1/en not_active Expired
- 1984-03-21 AT AT84103104T patent/ATE45085T1/en active
- 1984-03-21 DE DE8484103104T patent/DE3479187D1/en not_active Expired
-
1985
- 1985-03-01 NZ NZ211276A patent/NZ211276A/en unknown
- 1985-03-06 AU AU39579/85A patent/AU566817B2/en not_active Ceased
- 1985-03-07 IE IE587/85A patent/IE57731B1/en not_active IP Right Cessation
- 1985-03-08 ZA ZA851775A patent/ZA851775B/en unknown
- 1985-03-13 CA CA000476412A patent/CA1259261A/en not_active Expired
- 1985-03-20 US US06/713,890 patent/US4705681A/en not_active Expired - Lifetime
- 1985-03-20 JP JP60054732A patent/JPS60209512A/en active Granted
- 1985-03-20 NO NO851103A patent/NO165526C/en unknown
- 1985-03-20 DK DK126085A patent/DK165163C/en not_active IP Right Cessation
- 1985-03-21 ES ES541458A patent/ES8602394A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NO851103L (en) | 1985-09-23 |
| NO165526B (en) | 1990-11-19 |
| ATE45085T1 (en) | 1989-08-15 |
| IE850587L (en) | 1985-09-21 |
| US4705681A (en) | 1987-11-10 |
| ES541458A0 (en) | 1985-12-01 |
| IE57731B1 (en) | 1993-03-24 |
| DK126085A (en) | 1985-09-22 |
| NZ211276A (en) | 1987-08-31 |
| DE3479187D1 (en) | 1989-09-07 |
| NO165526C (en) | 1991-02-27 |
| DK165163C (en) | 1993-03-01 |
| ZA851775B (en) | 1985-10-30 |
| EP0155333A1 (en) | 1985-09-25 |
| JPH0473405B2 (en) | 1992-11-20 |
| AU3957985A (en) | 1985-09-26 |
| AU566817B2 (en) | 1987-10-29 |
| ES8602394A1 (en) | 1985-12-01 |
| JPS60209512A (en) | 1985-10-22 |
| DK126085D0 (en) | 1985-03-20 |
| DK165163B (en) | 1992-10-19 |
| EP0155333B1 (en) | 1989-08-02 |
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| MKEX | Expiry | ||
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