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CA1253327A - Air jet texturing system - Google Patents

Air jet texturing system

Info

Publication number
CA1253327A
CA1253327A CA000448607A CA448607A CA1253327A CA 1253327 A CA1253327 A CA 1253327A CA 000448607 A CA000448607 A CA 000448607A CA 448607 A CA448607 A CA 448607A CA 1253327 A CA1253327 A CA 1253327A
Authority
CA
Canada
Prior art keywords
yarn
feed
drawn
continuous filament
roll system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000448607A
Other languages
French (fr)
Inventor
Samuel T. Price
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enterprise Machine & Development Corp
Original Assignee
Enterprise Machine & Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enterprise Machine & Development Corp filed Critical Enterprise Machine & Development Corp
Application granted granted Critical
Publication of CA1253327A publication Critical patent/CA1253327A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/16Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam
    • D02G1/165Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam characterised by the use of certain filaments or yarns
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/16Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam
    • D02G1/162Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam with provision for imparting irregular effects to the yarn

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)

Abstract

ABSTRACT OF THE DISCLOSURE
A new process is provided for producing highly resilient, textured, continuous multifilament polymeric yarns and combinations of such yarns with other continuous filament yarns and with spun yarns. The unstable or wild loops which form in conventional air jet textured yarns are substantially eliminated in the product yarns of this invention. The product yarns are formed by continuously drawing polymetic yarn under controlled temperature conditions, texturing the yarn in an air jet texturizer and subjecting the textured yarn to saturated steam while restraining the linear shrinkage of the yarn in the presence of the steam, followed by continuous take-up of the yarn on a package.

Description

~:533:~
BACKGROIJND OF THE INVENTION

This invention relates generally to a yarn texturing air jet system and the products produced ~hereby. More specifically, the invention relates to the textured yarn products produced by a process of continuously drawing continuous ilament synthetic poiymeric yarn undet controlled temperature conditions, air jet texturing the drawn yarn and then subjecting the textured yarn to saturated steam while restraining the yarn from shrinking during steam treatment.
Bulky or crimped yarns composed of continuous synthetic fiber-forming polymers such as polyester and polyamide can be produced by feeding yarn filaments with overfeed to an air jet eexturizer to produce a large nurnber of random loops or crimps in the yarn. The type and degree o texture in the product yarn produced by such techniques depends upon the amount Gf twist in the feed yarn and on the amount of overeed in the texturing jet. The product yarn is generally spooied under tension and this product generally has poor linear stability and high boiling shrinkage values. The yarns are characterized by the presence of many ring-like or crunodal loops at irregular intervals along the surface of the yarn and internally in the yarn bundle.
When prior air jet texturing techniques according to the abovc are employed, a certain number of unstable or "wild" loops are generated in a random fashion along the yarn. These unstable loops can extend outwardly from the yarn bundle and adversely affect the yarn take off in subsequent textile mill operations. In fabrics made 2S ~rom such yarns, a "Velcro" or picky type charactçristic may appear, and this is generally distasteful in apparel.
*
TRADEMARR

A

~L;2S3327 I\/lethods are known for controlling these unstable loops to varying degrees. U.S. Patent 4,338,776 (Krenzer) describes a process and apparatus for producing a crimped continuous multifilament yarn by the sequential steps of air-jet texturi~ing to form multiple random filamentary loops, immediately pulling out metastable loops formed in the yarn without heating and without stretching or deforming the yarn filaments, next shrinking and heat setting the yarn at a temperature of about Is0-24sC., ar.d then winding the yarn onto a spool at a predetermined yarn tension. The non-crimped multifilament feed yarn I0 is conducted through an air jet texturizing nozzle at an overfeed ratesaid to be sufficient to form multiple random loops in the individual filaments, including some proportion of unstable loops. Following passage through the air jet, the yarn is conducted to feed and draw rolls in a heat free condition such that at least some of the unstable loops IS are pulled out of the yarn.
Prior known methods of controlling the unstable or wild loops are generally expensive and marginally effective. The present invention provides an effective and inexpensive method and apparatus for producing air jet textured yarns with substantially no unstable or wild lO0pS. One product of this invention results from the phenomenally high shrinkage inherent in cold-drawn partially oriented polyester, polyamide and similar yarns. The ;inear behavior of these yarns accordin~ to ehe invention is controllcd by tcnsion at thc cntrancc an(l cxit cnds of a steam chamber whercin a moclcst latent stretch is dcliberately retaincd in order to improve the transverse fibcr propcrtics resulting in enhanced fabric resilience.

~.253327 Tile following definitions apply to terms of the art as used in this specification. The term "fully oriented yarn" denotes a polymeric yarn drawn to such an extent that its molecules are fully oriented and very little further extensibility is possible in a cold, i.e. unheated, condition without breaking. This is the most stable yarn condition, total recovery or relaxation occurs on heating in an unrestrained state, however there is a loss of transverse quality or resilience of the yarn.
"Undrawn yarn" denotes continuous filament yarn in a totally undrawn state or as-spun condition.
IO The term "partially oriented yarn" denotes a polymeric yarn drawn to an extent such that its molecules are somewhat or "partially"
oriented, but the extent of draw is less than that for fully drawn yarn.
Thè resilience of partially drawn yarn is improved compared to fully drawn yarn, resulting in improved wrinkle resistance in fabrics made IS from such yarn.
The term "spun yarn" as used herein denotes any yarn made from relatively short discontinuous yarn ends that are reconstituted by twist or other means to form continuous lengths of yarn of commercial usefulness. These yarns can be made of synthetics or of natural fibers such as cotton or wool.

~L253327 SU1~1MARY OF TH~ INVENT101~
_ A process is provided for the production of highly resilient textured continuous multif ilament yarn or combinations of spun and multifilament yarn comprising feeding at least one end of a continuous filament synthetic polyrneric feed yarn to and through a feed roll system and thence to and through a draw roll system whereby the feed yarn is drawn, conducting the drawn yarn to a texturing air jet system, either singly or combining the drawn yarn at the entrance end of the jet with at least one other yarn, conducting the yarn end or combined I0 ends through the jet, thereby forming multiple random loops in the individual filament(s), including a proportion of random unstable loops, conducting the yarn end or combined ends leaving the air jet to and through a second feed roll systern which feeds the yarn at a eontrolled rate into and through a steam chamber containing saturated steam, the IS yarn exiting the steam chamber being conducted to and through a fourth roll system operating in cooperation with the second feed roll system to restrain and control the shrinkage of the yarn within the steam chamber, and thence guiding the drawn, textured and steam treated yarn to a take-up system, thereby producing a highly resilient textured product having substantially no unstable loops, with some or all of the yarn exhibiting less than fully orientecl fiber birefringcnce.
When the feed yarn is paltially oricnted polyestcr, polyamidc or similar yarn, it is drawn cold, i.e. in ambient condi~ions in thc absence of heat. When fully oriented yarn is employedl the drawing is carried oLlt at an elevated temperature to an extent of about 20 to about 35 percent.

~1 2~33~7 Preferred feed yarns are polyester, polyamide, polyolefin and similar yarns, in combination with polyester, polyamide, polyolefin, cellulose acetate and other continuous multifilamen$ yarns and in combination with spun yarns, both synthetic and natural such as cotton.
A process is also provided fc>r the prc>duction of a highly resilient continuous fil~E~t yarn of very high ~ ~age p~tential oomprising feeding at least one end of a oontinuous fil~t ~ially oriented synthetic polymeric feed yarn to and through a feed roll system and thence to and through a draw roll system whereby o the feed yarn is cold-drawn, i.e. in the absence of heat, conducting the drawn yarn to and through a second~feed roll system which feeds the yarn at a controlled tate into and through a steam chamber containing saturated steam, the yarn exiting the steam chamber b~ ing conducted to and through a fourth roll system operating IS in cooperation with the second feed roll system to restrain and control the shrinl:age of the yarn within the steam chamber and thence guiding the drawn and steam treated yarn to a take-up system, thereby producing a highly resilient yarn filament exhibiting less than fully oriented fiber bireringence. This yarn is then fed to a process {or the production of a highly resilient textured continuous multifilament core and effect yarn. Preferred feed yarns and combinations are as described above.
Also claimed are thc products produced by thcse processes.
BRIEF DESCRIPTION OF THE_RAWINGS
Fig. I is a schematic diagram of the yarn drawing, tcxturing and steam treating process of this invention.
Fig. 2 is a schematic diagrarn of a conventional textured multifilament yarn having stable and unstable loops.
Fig. 3 is a schematic diagram o a ~extured multifilament yarn according to this invention having substantially no unstablc loops.

~Z533;27 Fig. 4 is a schematic side elevational view of apparatus for making a core and effect yarn according to this invention.
Fig. 5 is an end elevation of the apparatus of Fig. ~.
DETAILED DESCRlPTlON OF THE INVENTION
AND PREFERRED EMBODIMENTS WITH
REFERENCE TO THE DRAWINGS
A new process is provided for producing highly resilient, textured, continuous multifilament polymeric yarns and combinations of such yarns with other continuous filament yarns and with spun yarns. The I0 unstable or wild loops which form in conventional air jet textured yarns are substantially eliminated in the product yarns of this invention. The product yarns are formed by continuously drawing polymeric yarn under controlled temperature conditions, texturing the yarn in an air jet texturizer and subjecting the textured yarn to saturated steam while I5 restraining the linear shrinkage of the yarn in the presence of the steam, followed by continuous take-up of the yarn on a package.
A fundamental physical concept leading to the present invention was the recognition of the phenomenal shrinkage which takes place when partially oriented or fully oriented polyester yarn is exposed to a hot wet medium. Initial experiments indicated that cold drawn polyester yarn sarnples drawn to approximately a I.45 or as much as I.6 draw ratio and exposed to boiling water at open atmospheric conditions (approximately 2I0 degrees Fahrenheit) shrank virtually instantalleollsly and wild loops prescnt in thc yarn prior to immcrsioll disappcared completely.
In a continuous process, which is preferred, it was deterrnined that partially oriented polyester yarn could be cold drawn, i.e. in the ~253327 absence of heat, bulked with an air jet texturizer and then passed through a steam chamber using steam at 25 to 3o pounds per square inch, there being restraining rolls at the entrance and exit ends of the steam chamber to restrain and control the shrinkage of the yarn while in the steam chamber. According to the principles of this invention, the linear speed of the yarn t~rough the exit rolls is in the range of about o.8 to 2.0 times the linear speed of the yarn through the entrance rolls, the linear shrinkage of the yarn being in the range of about 20 to about I00 percent.
I0 The highly resilient yarns produced according to this invention arecharacterized by having less than complete fiber orientation as manifested, ~or example, by exhibiting less than fully drawn fiber birefringence. This characteristic is defined as the difference between the principal refractive index in the stretch direction and the principal I5 refractive index perpendicular to the stretch direction.
The yarn produced according to this invention may be combined with virtually any other yarn including, without limitation, continuous filament polyester, polyamide, polyolefin, cellulose acetate, and other similar yarns, as well as spun yarns including synthetics and natural fibers such as cotton. While not fully understood, it is believed that, upon restrained linear shrinkage in the steam chamber, the wild loops in the drawn yarn gather in the companion yarn such as cotton and hold the latter in intimate contact.
Cold drawn, unte~turcd but stcam trcatcd yarns according to this invention are believed to be uscful in otherwise conventional core and effect yarn systems to economically produce synthetic yarns which are silk-like both in tactile and in visual character. In general, the yarns ,, ~1.25332~7 produced according to this invention include conventional fine denier applications of single or multiple ends of continuous filaments for use in apparel and other applications including sewing thread and fenestra-tion yarns. The system may provide an ideal approach in combining spun yarns with continuous filament yarns by employing the shrinkage of the filament loops to trap filament ends in the spun yarn and establish an integrated product. The process also includes a method by which fully drawn yarns can be destablilized by drawing with a subsequent reduction of the wild loops by steam treating resulting in o improved yarns for sewing thread, upholstery and fenestration yarns.
Means are further provided by which short, but random, non-uni-formities can be introduced to overcome the plastic appearance of conventional continuous filament products.
A detailed description of the process and products of this invention is best provided with reference to the accompanying draw-ings. Fig. I is a schematic diagram of one preferred embodiment of the process of the invention. Fig. I shows continuous filament polymeric yarns 3Z and 34 being fed from Supply yarn packages 4 and 2 respectively to feed rolls lo and lol and thence to and through draw rolls I2 and I21 which run at a faster speed than the feed rolls and thereby impart draw to the yarn. Preferred draw ratios range from about I.45 to about I.6 when partially oriented yarn is used as thc feed yarn. If fully oriented yarn is fcd as filamellts 32 alld 34, this yarn is preferably drawn about 20 to about 35/~ at an elcvated tcmperature 2S in the range of about 2IS to about 280 degrees Pahrcnheit for polyester yarns. The heating can be accomplished by using heated feed rolls I0 and I0l and draw rolls I2 and I21 (or an intermediate heating device) and wrapping the filaments about these rolls several times to provide ~2~3;~2~

residence time under temperature. Following drawing, the drawn yarn is guided to an air jet texturizer I4 by guides 8 where it may be combined with another yarn 3o fed from package 6 as shown which may be a spun yarn, not drawn, for example. The textured multifilament yarn 36 exiting the air jet is guided to and through feed rolls I6 and I61 and into and through the steam chamber I8 where it is subjected to saturated steam at about 220 to about 3oo degrees Fahrenheit. The steam treated yarn passes through rolls 20 and 20' which, as aforesaid, control the speed, tension and thus the linear shrinkage of the yarn I0 bundle at desired degrees. The highly resilient drawn, textured and steam treated yarn 38 is then wound upon yarn package 22, with the aid of stabilizer roll 24, thus proYiding the product yarn according to this invention .
Fig. 2 illustrates schematically the stable crunodal loops 39 in S multifilament yarn 36 produced by conventional texturing means and random unstable loops 37. Following steam treatment according to this invention the unstable loops are substantially eliminated as depicted in Fig. 3.
In another embodiment using the yarn of this invention, a core and effect yarn is produced as depicted in Figs. 4 and 5. Therein, feed yarns 44 and 46 fed from yarn supplys 40 and 42, respectively, proceed through otherwise convcntional core ancl cf fcct yarn appar,ltlls. At least onc of thc fccd yarlls is rlladc as dcscribcd in conncctioll with Fig.
I but eliminating the air jet texturing. That is, at least onc of the feed yarns in Fig. 4 has been drawn but not steam treated or textured as shown in Fig. T. The core yarn 44 shown in Fig. 4 is fed at a con-.

stant rate through the roll system and to and through the air jet texturizer 66. The effect yarn 46 is caused to create thick sections by overfeeding this yarn at desired time intervals by means of roll 60 and roll 58 causing yarn 46 to overfeed to jet 66. When thin sections are desired, rocker arm 56 is caused to disengage roll 58 from roll 60 and roll 54 in cooperation with roll 5~ slows the speed of filament 46, thereby producing a thin section. The engagement or disengagement of rolls 54 and S8 can be controlled as desired using known fluidics techniques, not shown except for air signal tube 55. Upon removal of I0 the air signal, spring mechanisrn 57 causes rolls 52 and 54 to disengage and rolls 5~ and 60 to engage to overfeed yarn 46. The textured yarn 68 exiting the air jet is guided to and through feed rolls I6 and I61 and into and through the steam chamber I 8 where it is subjected to saturated steam. The steam treated yarn passes through rolls 20 and I5 201 which control the speed, tension and linear shrinkage of the yarn at desired degrees. The thick and thin core and effect yarn 68 produced according to this method is collected on take-up roll 7o with the aid of stabilizer roll 72. This yarn so produced should have a broad range of more exotic end uses, with a broad range of appearance and slub density tailored for style, having tactile and visual characteristics of silk.
While the invention has heen disclosed herein irl conrlectioll with certain embodimel-ts and dctailed descriptiolls, it will bc clear tc one skilled in the art that modifications or variations of SlJCh details can be made without deviating from the gist of this invention, and such modifications or variations are considered to be within the scope of the claims hereinbelow.

Claims (23)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A process for the production of a highly resilient textured continuous multifilament core and effect yarn comprising:
feeding at least one end of a continuous filament partially oriented synthetic polymeric feed yarn to and through a feed roll system and thence to and through a draw roll system whereby said feed yarn is cold-drawn, i.e. in the absence of heat, conducting said feed yarn and at least one other yarn in combination to a core and effect yarn system having means for overfeeding either core or effect yarn, thence conducting the combined yarn ends to and through a texturing air jet, conducting the yarn leaving said air jet to and through a second feed roll system which feeds said yarn at a controlled rate into and through a steam chamber containing saturated steam, the yarn exiting the steam chamber being conducted to and through a fourth roll system operating in cooperation with said second feed roll system to restrain and control the linear shrinkage of said yarn within the steam chamber, wherein said core and effect is produced by overfeeding either the core yarn or the effect yarn at desired and controlled time intervals, and.
guiding the textured core and effect yarn to a take-up system, thereby producing a highly resilient textured core and effect yarn, said feed yarn exhibiting less than fully oriented fiber birefringence.
2. The process of claim 1 wherein said feed yarn is selected from the class consisting of polyester, polyamide, vinyl and acrylic polymers.
3. The process of claim 1 wherein said other yarn is continuous filament polyester yarn.
4. The process of claim 1 wherein said other yarn is continuous filament polyamide yarn.
5. The process of claim 1 wherein said other yarn is continuous filament polyolefin yarn.
6. The process of claim 1 wherein said other yarn is continuous filament cellulose acetate yarn.
7. The process of claim 1 wherein said other yarn is a spun yarn.
8. The process of claim 7 wherein said other yarn is cotton.
9. The yarn product produced by the process of claim 1.
10. A process for the production of highly resilient textured continuous filament yarn comprising:
feeding at least one end of a continuous filament, at least partially oriented synthetic polymeric feed yarn to and through a feed roll system and thence to and through a draw roll system whereby the feed yarn is drawn, conducting said drawn yarn to a texturing air jet system, conducting said yarn end through said jet, thereby forming multiple random loops in the yarn end including a proportion of random unstable loops, conducting the yarn leaving said air jet to and through a second feed roll system which feeds said yarn at a controlled rate into and through a steam chamber containing saturated steam at about 220 to 300 degrees Fahrenheit thereby substantially eliminating said random unstable loops, the yarn exiting the steam chamber being conducted to and through a fourth roll system operating in cooperation with said second feed roll system to restrain and control the linear shrinkage of said yarn within the steam chamber, and thence guiding the drawn, textured and steam treated yarn to a take-up system, thereby producing a highly resilient textured yarn having substantially no unstable loops, said yarn exhibiting less than fully oriented fiber birefringence.
11. A process according to claim 10 wherein said drawn yarn is combined at an entrance end of said jet with at least one other yarn, conducting the combined yarn ends through said jet, thereby forming multiple random loops in the individual filaments including a proportion of random unstable loops, conducting the multifilament yarn leaving said air jet to and through a second feed roll system which feeds said yarn at a controlled rate into and through a steam chamber containing saturated steam at about 220 to about 300 degrees Fahrenheit, the yarn exiting the steam chamber being conducted to and through a fourth roll system operating in cooperation with said second feed roll system to restrain and control the linear shrinkage of said yarn within the steam chamber, and thence guiding the drawn, textured and steam treated yarn to a take-up system, thereby producing a highly resilient textured multi-filament yarn having substantially no unstable loops, said yarn exhibiting less than fully oriented fiber birefringence.
12. The process of claim 11 wherein said other yarn is continuous filament polyester yarn.
13. The process of claim 11 wherein said other yarn is continuous filament polyamide yarn.
14. The process of claim 11 wherein said other yarn is continuous filament polyolefin yarn.
15. The process of claim 11 wherein said other yarn is continuous filament cellulose acetate yarn.
16. The process of claim 11 wherein said other yarn is a spun yarn.
17. The process of claim 16 wherein said other yarn is cotton.
18. The process of claim 11 wherein a multiplicity of continuous filament synthetic thermoplastic feed yarns are fed to the system.
19. The yarn produced by the process of claim 11, said feed yarn being a yarn at least partially oriented and drawn without added heat, said feed yarn having less than complete fiber orientation as manifested by exhibiting less than fully drawn fiber birefringence, and exhibiting linear shinkag in the presence of saturated steam in the range of 20% to 100%.
20. The process of claim 10 wherein said feed yarn is partially oriented yarn which is cold-drawn in said process, i.e. without added heat.
21. The process of claim 10 wherein said feed yarn is fully oriented yarn which is drawn in said process about 20 to 35 percent at elevated temperature.
22. The process of claim 10 wherein said feed yarn is selected from the class consisting of polyester, polyamide, polyolefin, vinyl and acrylic polymers.
23. The yarn produced by the process in claim 13 being a yarn at least partially oriented and drawn without added heat, said product having less than complete fiber orientation as manifested by exhibiting less than fully drawn fiber bire-fringence, and exhibiting linear shinkage in the presence of saturated steam in the range of about 20% to 100%.
CA000448607A 1983-03-02 1984-03-01 Air jet texturing system Expired CA1253327A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US47123983A 1983-03-02 1983-03-02
US471,239 1983-03-02

Publications (1)

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CA1253327A true CA1253327A (en) 1989-05-02

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CA000448607A Expired CA1253327A (en) 1983-03-02 1984-03-01 Air jet texturing system

Country Status (4)

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EP (1) EP0119044B1 (en)
JP (1) JPS59173335A (en)
CA (1) CA1253327A (en)
DE (1) DE3480657D1 (en)

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JPH02139435A (en) * 1988-11-21 1990-05-29 Teijin Ltd Production of false-twisted combined yarn
US5032333A (en) * 1990-02-27 1991-07-16 E. I. Du Pont De Nemours And Company One-line interlacing of bulked continuous filament yarns and low-melting binder fibers
DE4215015A1 (en) * 1992-05-12 1993-11-18 Amann & Soehne Stretching process
GB9323441D0 (en) * 1993-11-13 1994-01-05 Coats Ltd J & P Method for making thread
IT1274759B (en) * 1994-09-06 1997-07-24 Vito Ballarati METHOD TO OBTAIN A MULTIBAVE YARN STRETCHED DURING THE INTERLACING PHASE STARTING FROM THERMOPLATIC YARNS PARTIALLY ORIENTED
US6332253B1 (en) * 2000-02-29 2001-12-25 Prisma Fibers, Inc. Textile effect yarn and method for producing same
US8181438B2 (en) * 2010-10-18 2012-05-22 Pure Fishing, Inc. Composite fishing line
WO2016058987A1 (en) * 2014-10-13 2016-04-21 Ssm Giudici S.R.L. Machine and method for the production of fancy yarns
BR102019012508A2 (en) * 2019-06-17 2020-12-29 Antonio Herminio Marin production process of ecological, sustainable mixed yarns and mixed yarns obtained
BR102021011444A2 (en) 2021-06-11 2022-12-27 Antonio Herminio Marin PRODUCTION PROCESS OF DURABLE BIODEGRADABLE MIXED YARN AND MIXED YARN OBTAINED THROUGH THE SAID PROCESS

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Also Published As

Publication number Publication date
EP0119044A3 (en) 1986-03-26
EP0119044A2 (en) 1984-09-19
JPS59173335A (en) 1984-10-01
JPH0341572B2 (en) 1991-06-24
EP0119044B1 (en) 1989-12-06
DE3480657D1 (en) 1990-01-11

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