CA1179466A - Method of manufacturing luminous textiles - Google Patents
Method of manufacturing luminous textilesInfo
- Publication number
- CA1179466A CA1179466A CA000413370A CA413370A CA1179466A CA 1179466 A CA1179466 A CA 1179466A CA 000413370 A CA000413370 A CA 000413370A CA 413370 A CA413370 A CA 413370A CA 1179466 A CA1179466 A CA 1179466A
- Authority
- CA
- Canada
- Prior art keywords
- mixture
- yarn
- thermoplastic material
- pigments
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004753 textile Substances 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000049 pigment Substances 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 239000004744 fabric Substances 0.000 claims abstract description 11
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 13
- 239000012815 thermoplastic material Substances 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000010025 steaming Methods 0.000 claims description 3
- 229920002301 cellulose acetate Polymers 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 15
- 229920001169 thermoplastic Polymers 0.000 abstract description 12
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 12
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 8
- 238000010348 incorporation Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 208000012641 Pigmentation disease Diseases 0.000 description 1
- WJGAPUXHSQQWQF-UHFFFAOYSA-N acetic acid;hydrochloride Chemical compound Cl.CC(O)=O WJGAPUXHSQQWQF-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D11/00—Other features of manufacture
- D01D11/06—Coating with spinning solutions or melts
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
- D02G3/346—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/10—Decorating textiles by treatment with, or fixation of, a particulate material, e.g. mica, glass beads
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Multicomponent Fibers (AREA)
Abstract
ABSTRACT OF THE DISCLOSURE
A method of manufacturing luminous textiles combines phosphorescent pigments with a thermoplastics material, by heating and homogenizing a mixture of those materials. The mixture is then ground and extruded hot onto a yarn to form a coating on that yarn. The yarn is then steamed at a temperature between 40°C and 70°C to impart the necessary flexibility to the yarn, and then incorporated, together with other yarns into a textile fabric.
Fluorescent pigments may also be included in the mixture.
A method of manufacturing luminous textiles combines phosphorescent pigments with a thermoplastics material, by heating and homogenizing a mixture of those materials. The mixture is then ground and extruded hot onto a yarn to form a coating on that yarn. The yarn is then steamed at a temperature between 40°C and 70°C to impart the necessary flexibility to the yarn, and then incorporated, together with other yarns into a textile fabric.
Fluorescent pigments may also be included in the mixture.
Description
'166 "Method of manufacturing luminous textiles"
BACKGROUND OF THE I~VENTION
FIEL~ OF THE INVENTION
The present invention relates to a method of manufacturing textile products having luminous properties. It is desired that the luminous properties are of a permanent nature and with the possibility of having a multiplicity of ranges, not only of luminosity, but also of colours, by means of which fabrics are obtained exhibiting very characteristic, attractive and, to a certain extent, surprising effects.
DESCRIPTION OF THE PRIOR ART
Many attempts have been made, and technical studies and practical tests have been carried out, to try to impart to fabrics luminous decorative effects, but so far features of luminosity proper to the material, and permanence of effect, have not been achieved.
Silk-screen and other printing has been tried, using special dyesJ coloured and/or phosphorescent pigment-ations, but the best that has been achieved so far has been the obtaining of coloured reflection effects which transform and reflect luminous incidence, but which cannot be described as a luminosity characteristic of the material itself.
As a general rule, these prior art proposals - envisage the use of a paint or dye of coarse texture based on the moistening of pigments with solvents by ordinary mixing, and also endeavouring to ensure that the incorporation of any other opaque pigment, or any other element, cannot subdue, obstruct or prevent the emission of light which, naturally, would bring about a reduction of phosphorescent luminosity.
In actual fact, a great diversity in the preparation of paints or dyes is possible, as well as in their application, as regards proportions of phosphorescent pigments, solvents, elements for i~proving the suspension and nomogenization properties of the dyes, texture and perfection of finish; all of this, however, being directed at the application onto the fabric or plastic material, by printing, impression, painting or the like.
S~MMARY OF THE INVENTION
The method of the present invention uses a different principle for imparting luminosity to fabrics by starting from suitably treated yarns or filaments which, on forming the textile, impart to that textile characteristic properties, and permitting of multiple applications, some of which were totally unexpected.
~ ~ ~`t . " ' ~
~7~
The method of the invention consists essent- ;
ially in startinq from a preparation based on thermo-plastics materials, pre-Eerably of the transparent type, such as PVC~ with phosphorescent pigments with s or without the addition of fluorine, the proportions of the ingredient of the mixture being suitable for the formation of a paste able to be extruded at suitable temperatures and under suitable pressure.
By extrusion, a basic yarn, natural or synthetic, is coated with the paste; once cooled the yarn is steamed to impart to it a state of moisture and flexibility suitable for the texture lntended for the fabric. The yaxn thus obtained may have the characteristics of a continuous synthetic yarn.
The thermoplastics materials in which the pigments are incorporated may be any suitable type, such a.c m~thyl methacrv~late, polysty ene, cellulose acetate and vinyl and chloride acetate copolymers.
The incorporation of the pigments into the plastics material is effected preferably at the time of manufacture, the pigment being normally added to the plastics material in paste form. The stability of the luminosity of the phosphorescent pigments is improved by minimising the amount of physical effort 2S exerted on the pigments in the manufacturing process during incorporation into the plastics material '8`'~
- '~
.: .
-~7~
and for this reason excessive grinding is to be avoidedwhen mixing and homogenizing the pigments and the thermoplastics material.
Thus, for example, in the manufacturing process, the pigment and a powder of thermoplastics material may be mixed in a rubber mill, until the temperature reaches the softening point of the thermo-plastics resin, and after the mixture has been cooled, it is ground down to the size of particle or paste grains required.
The invention is broadly claimed herein as a method of manufacturing a luminous textile, comprising:
forming a mixture of at least one thermoplastic materialand at least one phosphorescent pigment; heating said mixture to the softening point of said thermoplastic material;
homogenizing the thus-formed softened mixture; cooling the thus-homogenized mixture; grinding the cooled mixture to form particles thereof; heating said particles and applying the same to a yarn by extrusion so as to coat said yarn; steaming the thus-coated yarn so as to impart flexibility thereto; incorporating said coated yarn, together with other yarns into a textile fabric.
The invention is likewise a luminous textile prepared by the a~oresaid method.
DESCRIPTION OF THE PREFERRED EMBODIMENT
An embodiment of the method of the present invention will now be described by way of example.
A core of basic yarn, natural or synthetic, is coated by extrusion with a thermoplastics coating based on a mixture of, for example, copolymers and chloride acetate with phosphorescent pigments, with or without fluorescent pigments. The proportion of pigments is preferably 5 to 10% in relation to 95 to 90%
of thermoplastics material, but the amount of pigment may be up to 70~, with 30% thermoplastics with all the ,4.
., . , . . .
.
intermediate values being possible. The ratio of pigments to thermoplastics material is chosen to achieve the desired physical properties,-resistance and plasticity on the extrusion of said mixture and the thermoplastics coating of the basic yarn.
The pigments to be mixed may be only phosphorescent to obtain luminosity only, or mixed, to a greater or smaller proportion, with colouring fluorescent elements to achieve luminous colour effects, generally with small proportions of fluorine in relation to the phosphorous material, e.g. from 1 to 10 parts.
It is necessary for the fluorescent pigments to be suited to the luminosity emitted by the phosphorescent pigments so that the incorporation of fluorescent pigments does not subdue the luminosity of the phosphorescent pigments.
Having obtained a continuous yarn by extrusion ln sizes appropriate to the texture to be prepared, e.g. from 0.2 mm to 0.3 mm in diameter, the yarn is steamed at a temperature between ~0 and 70C as to achieve softening of the yarn. The yarn then proceeds in the wet state to the production of the desired textile into which in varying ~uantities threads of this kind are incorporated. The remainder of the threads of the textile fabric to be manufactured will be those suited to the use of same, and they may be of natural or synthetic fibres.
6g~
The fabrics obtained with the process according to the invention exhibit outstanding luminous effects, with many variations and effects being possible, opening wide fields to the application of the fabrics obtained, not only on account of their decorative and attractive effect in the clothing and upholstery industries, but also because of their diverse applications, e.g~ in photography, signs and imaginative and fanciful creations.
,~r
BACKGROUND OF THE I~VENTION
FIEL~ OF THE INVENTION
The present invention relates to a method of manufacturing textile products having luminous properties. It is desired that the luminous properties are of a permanent nature and with the possibility of having a multiplicity of ranges, not only of luminosity, but also of colours, by means of which fabrics are obtained exhibiting very characteristic, attractive and, to a certain extent, surprising effects.
DESCRIPTION OF THE PRIOR ART
Many attempts have been made, and technical studies and practical tests have been carried out, to try to impart to fabrics luminous decorative effects, but so far features of luminosity proper to the material, and permanence of effect, have not been achieved.
Silk-screen and other printing has been tried, using special dyesJ coloured and/or phosphorescent pigment-ations, but the best that has been achieved so far has been the obtaining of coloured reflection effects which transform and reflect luminous incidence, but which cannot be described as a luminosity characteristic of the material itself.
As a general rule, these prior art proposals - envisage the use of a paint or dye of coarse texture based on the moistening of pigments with solvents by ordinary mixing, and also endeavouring to ensure that the incorporation of any other opaque pigment, or any other element, cannot subdue, obstruct or prevent the emission of light which, naturally, would bring about a reduction of phosphorescent luminosity.
In actual fact, a great diversity in the preparation of paints or dyes is possible, as well as in their application, as regards proportions of phosphorescent pigments, solvents, elements for i~proving the suspension and nomogenization properties of the dyes, texture and perfection of finish; all of this, however, being directed at the application onto the fabric or plastic material, by printing, impression, painting or the like.
S~MMARY OF THE INVENTION
The method of the present invention uses a different principle for imparting luminosity to fabrics by starting from suitably treated yarns or filaments which, on forming the textile, impart to that textile characteristic properties, and permitting of multiple applications, some of which were totally unexpected.
~ ~ ~`t . " ' ~
~7~
The method of the invention consists essent- ;
ially in startinq from a preparation based on thermo-plastics materials, pre-Eerably of the transparent type, such as PVC~ with phosphorescent pigments with s or without the addition of fluorine, the proportions of the ingredient of the mixture being suitable for the formation of a paste able to be extruded at suitable temperatures and under suitable pressure.
By extrusion, a basic yarn, natural or synthetic, is coated with the paste; once cooled the yarn is steamed to impart to it a state of moisture and flexibility suitable for the texture lntended for the fabric. The yaxn thus obtained may have the characteristics of a continuous synthetic yarn.
The thermoplastics materials in which the pigments are incorporated may be any suitable type, such a.c m~thyl methacrv~late, polysty ene, cellulose acetate and vinyl and chloride acetate copolymers.
The incorporation of the pigments into the plastics material is effected preferably at the time of manufacture, the pigment being normally added to the plastics material in paste form. The stability of the luminosity of the phosphorescent pigments is improved by minimising the amount of physical effort 2S exerted on the pigments in the manufacturing process during incorporation into the plastics material '8`'~
- '~
.: .
-~7~
and for this reason excessive grinding is to be avoidedwhen mixing and homogenizing the pigments and the thermoplastics material.
Thus, for example, in the manufacturing process, the pigment and a powder of thermoplastics material may be mixed in a rubber mill, until the temperature reaches the softening point of the thermo-plastics resin, and after the mixture has been cooled, it is ground down to the size of particle or paste grains required.
The invention is broadly claimed herein as a method of manufacturing a luminous textile, comprising:
forming a mixture of at least one thermoplastic materialand at least one phosphorescent pigment; heating said mixture to the softening point of said thermoplastic material;
homogenizing the thus-formed softened mixture; cooling the thus-homogenized mixture; grinding the cooled mixture to form particles thereof; heating said particles and applying the same to a yarn by extrusion so as to coat said yarn; steaming the thus-coated yarn so as to impart flexibility thereto; incorporating said coated yarn, together with other yarns into a textile fabric.
The invention is likewise a luminous textile prepared by the a~oresaid method.
DESCRIPTION OF THE PREFERRED EMBODIMENT
An embodiment of the method of the present invention will now be described by way of example.
A core of basic yarn, natural or synthetic, is coated by extrusion with a thermoplastics coating based on a mixture of, for example, copolymers and chloride acetate with phosphorescent pigments, with or without fluorescent pigments. The proportion of pigments is preferably 5 to 10% in relation to 95 to 90%
of thermoplastics material, but the amount of pigment may be up to 70~, with 30% thermoplastics with all the ,4.
., . , . . .
.
intermediate values being possible. The ratio of pigments to thermoplastics material is chosen to achieve the desired physical properties,-resistance and plasticity on the extrusion of said mixture and the thermoplastics coating of the basic yarn.
The pigments to be mixed may be only phosphorescent to obtain luminosity only, or mixed, to a greater or smaller proportion, with colouring fluorescent elements to achieve luminous colour effects, generally with small proportions of fluorine in relation to the phosphorous material, e.g. from 1 to 10 parts.
It is necessary for the fluorescent pigments to be suited to the luminosity emitted by the phosphorescent pigments so that the incorporation of fluorescent pigments does not subdue the luminosity of the phosphorescent pigments.
Having obtained a continuous yarn by extrusion ln sizes appropriate to the texture to be prepared, e.g. from 0.2 mm to 0.3 mm in diameter, the yarn is steamed at a temperature between ~0 and 70C as to achieve softening of the yarn. The yarn then proceeds in the wet state to the production of the desired textile into which in varying ~uantities threads of this kind are incorporated. The remainder of the threads of the textile fabric to be manufactured will be those suited to the use of same, and they may be of natural or synthetic fibres.
6g~
The fabrics obtained with the process according to the invention exhibit outstanding luminous effects, with many variations and effects being possible, opening wide fields to the application of the fabrics obtained, not only on account of their decorative and attractive effect in the clothing and upholstery industries, but also because of their diverse applications, e.g~ in photography, signs and imaginative and fanciful creations.
,~r
Claims (9)
1. A method of manufacturing a luminous textile, comprising:
forming a mixture of at least one thermo-plastic material and at least one phosphorescent pigment;
heating said mixture to the softening point of said thermoplastic material;
homogenizing the thus-formed softened mixture;
cooling the thus-homogenized mixture;
grinding the cooled mixture to form particles thereof;
heating said particles and applying the same to a yarn by extrusion so as to coat said yarn;
steaming the thus-coated yarn so as to impart flexibility thereto;
incorporating said coated yarn, together with other yarns into a textile fabric.
forming a mixture of at least one thermo-plastic material and at least one phosphorescent pigment;
heating said mixture to the softening point of said thermoplastic material;
homogenizing the thus-formed softened mixture;
cooling the thus-homogenized mixture;
grinding the cooled mixture to form particles thereof;
heating said particles and applying the same to a yarn by extrusion so as to coat said yarn;
steaming the thus-coated yarn so as to impart flexibility thereto;
incorporating said coated yarn, together with other yarns into a textile fabric.
2. A method according to claim 1, wherein said mixture includes fluorescent pigments.
3. A method according to claim 2, wherein the quantity of said fluorescent pigments in said mixture is less than the quantity of said phosphorescent pigments.
4. A method according to claim 1, wherein said mixture comprises 70% to 5% of said pigment and 30% to 95% of said at least one thermoplastic material.
5. A method according to claim 4 wherein said mixture comprises 10% to 5% of said pigment and 90%
to 95% of said at least one thermoplastic material.
to 95% of said at least one thermoplastic material.
6. A method according to claim 1, wherein said at least one thermoplastic material is selected from the group consisting of: methyl methacrylate, poly-styrene, cellulose acetate, polyvinyl chloride.
7. A method according to claim 1 wherein said at least one thermoplastic material is a copolymer of vinyl chloride and acetate.
8. A method according to claim 1 wherein the step of steaming said coated yarn is carried out at a temperature between 40°C and 70°C.
9. A luminous textile prepared by the method of claim 1.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES506.765 | 1981-10-13 | ||
ES506765A ES506765A0 (en) | 1981-10-13 | 1981-10-13 | PROCEDURE FOR TEXTILE MANUFACTURING WITH OWN LUMINOSITY. |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1179466A true CA1179466A (en) | 1984-12-18 |
Family
ID=8483161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000413370A Expired CA1179466A (en) | 1981-10-13 | 1982-10-13 | Method of manufacturing luminous textiles |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS5898456A (en) |
CA (1) | CA1179466A (en) |
DE (1) | DE3237748A1 (en) |
ES (1) | ES506765A0 (en) |
FR (1) | FR2514377A1 (en) |
GB (1) | GB2108544B (en) |
IT (1) | IT1157067B (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6197445A (en) * | 1984-10-16 | 1986-05-15 | ユニチカ株式会社 | Special visually discernible cloth |
US4884990A (en) * | 1989-01-23 | 1989-12-05 | Lovik Craig J | Luminescent balloon and method of manufacture thereof |
DE3912738C2 (en) * | 1989-04-19 | 1993-12-09 | Lippmann Tauwerk Gmbh Hanf U K | Process for the production of afterglowing synthetic spinning materials and their use |
DE3933903A1 (en) * | 1989-10-11 | 1991-04-18 | Basf Ag | FLUORESCENT PIGMENTS |
FR2709764B1 (en) * | 1993-09-06 | 1996-08-02 | Christian Buret | Ornamental threads covered with resin. |
GB9926770D0 (en) * | 1999-11-12 | 2000-01-12 | Int Net & Twine Ltd | A luminous line and a net incorporating a luminous line |
FR2811663B1 (en) | 2000-07-13 | 2003-05-02 | Commenplus | LUMINESCENT RIPING MATERIAL AND METHOD FOR PLACING SUCH MATERIAL |
ITBG20070002A1 (en) * | 2007-01-15 | 2008-07-16 | Bruno Bosio | PROCEDURE FOR THE REALIZATION OF AN ARTICLE IN TEXTILE MATERIAL WITH PHOSPHORESCENT EFFECT, RIBBON IN TEXTILE MATERIAL OBTAINED WITH THIS PROCEDURE AND PLANT FOR THE REALIZATION OF SUCH A RIBBON. |
FR2939152B1 (en) * | 2008-12-01 | 2011-05-06 | Porcher Ind | PHOTOLUMINESCENT COMPOSITE FIL, PROCESS FOR OBTAINING AND TEXTILE STRUCTURE OBTAINED |
CN110318109A (en) * | 2019-08-26 | 2019-10-11 | 刘奇 | A kind of RE luminous fiber and its application |
CH720187A2 (en) * | 2022-11-01 | 2024-05-15 | Swatch Group Res & Dev Ltd | Composite textile yarn, process for manufacturing such a composite textile yarn, textile article made from such composite textile yarns. |
-
1981
- 1981-10-13 ES ES506765A patent/ES506765A0/en active Granted
-
1982
- 1982-10-07 GB GB08228668A patent/GB2108544B/en not_active Expired
- 1982-10-08 IT IT68187/82A patent/IT1157067B/en active
- 1982-10-12 DE DE19823237748 patent/DE3237748A1/en not_active Withdrawn
- 1982-10-13 JP JP57179695A patent/JPS5898456A/en active Pending
- 1982-10-13 FR FR8217151A patent/FR2514377A1/en not_active Withdrawn
- 1982-10-13 CA CA000413370A patent/CA1179466A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
ES8206672A1 (en) | 1982-08-16 |
FR2514377A1 (en) | 1983-04-15 |
DE3237748A1 (en) | 1983-04-21 |
GB2108544A (en) | 1983-05-18 |
ES506765A0 (en) | 1982-08-16 |
JPS5898456A (en) | 1983-06-11 |
GB2108544B (en) | 1985-09-25 |
IT1157067B (en) | 1987-02-11 |
IT8268187A0 (en) | 1982-10-08 |
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Legal Events
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MKEC | Expiry (correction) | ||
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